Aromatic Patents (Class 585/24)
  • Patent number: 4639833
    Abstract: An improved electrical insulating oil and oil-filled electrical appliances impregnated therewith. The electrical insulating oil has a low viscosity, low pour point and other excellent electrical characteristics and it comprises an isomer mixture of dibenzylbenzenes in which the quantity of p-dibenzylbenzene is not more that 10% by weight and the weight ratio of m-dibenzylbenzene/o-dibenzylbenzene is not lower than 3.
    Type: Grant
    Filed: August 12, 1985
    Date of Patent: January 27, 1987
    Assignee: Nippon Petrochemicals Company, Ltd.
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hideyuki Dohi
  • Patent number: 4627933
    Abstract: Compounds of the formulaR.sup.1 --Q.sup.1 --(CH.sub.2).sub.m --(COO).sub.n --(CH.sub.2).sub.p --Q.sup.2 --R.sup.2whereinR.sup.1 and R.sup.2 are each independently alkyl or alkoxy each of 1-12 C atoms, F, Cl, Br, CN or --Q.sup.3 --R.sup.3, or one of R.sup.1 and R.sup.2 can also be H;Q.sup.1, Q.sup.2 and Q.sup.3 are each independently 1,4-phenylene, 1,4-cyclohexylene, 1,4-bicyclo(2,2,2)-octylene or 1,3-dioxane-2,5-diyl, each of which is unsubstituted or substituted by 1-4 fluorine, chlorine or bromine atoms;R.sup.3 is alkyl or alkoxy each of 1-8 C atoms, H, F, Cl, Br or CN;m is 1, 2, 3, 4, 5 or 6; n is 0 or 1; and p is 0, 1, 2, 3, 4 or 5; the sum of (m+p) being 2, 4 or 6 and the sum of (m+n+p) being at least 3;but with the proviso that Q.sup.3 is unsubstituted 1,4-phenylene or 1,4-phenylene substituted by a fluorine, chlorine or bromine atom, only when n=1 or (m+p)=6 or at least one of R.sup.1 or R.sup.3 is F, Cl or Br or none of R.sup.1 to R.sup.3 is CN or two of the radicals R.sup.1 to R.sup.
    Type: Grant
    Filed: July 7, 1983
    Date of Patent: December 9, 1986
    Assignees: Merck Patent Gesellschaft mit beschrankter Haftung, The Secretary of State for Defense in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Rudolf Eidenschink, Joachim Krause, Beatrice M. Andrews, George W. Gray, Neil Carr
  • Patent number: 4570024
    Abstract: An aromatic hydrocarbon in which at least one hydrogen atom on the ring is substituted by a group selected from the class consisting of unsubstituted or lower alkyl-substituted tricyclo[5.2.1.0.sup.2,6 ]dec-3-yl, tricyclo[5.2.1.0.sup.2,6 ]dec-4-yl, tetracyclo[6.2.1.1.sup.3,6.0.sup.2,7 ]dodec-4-yl and tetracyclo[6.2.1.1.sup.3,6.0.sup.2,7 ]dodec-5-yl groups, or its hydrogenation product.The compound is prepared by reacting an aromatic hydrocarbon having at least one hydrogen atom on the ring with a compound selected from the group consisting of unsubstituted or lower alkyl-substituted tricyclo[5.2.1.0.sup.2,6 ]dec-3-ene and tetracyclo[6.2.1.1.sup.3,6.0.sup.2,7 ]dodec-4-ene in the presence of a Friedel-Crafts catalyst, or hydrogenating the thus-obtained compound in the presence of a hydrogenation catalyst.The compound is useful as an additive for adhesives.
    Type: Grant
    Filed: May 7, 1985
    Date of Patent: February 11, 1986
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kinya Mizui, Masami Takeda, Yoshimi Ozaki, Ryosuke Tomita
  • Patent number: 4568793
    Abstract: An electrical insulating oil which can be produced easily at low cost, scarcely contains undesirable components of tarry substance, unsaturated compounds and carbonyl compounds, does neither swell nor dissolve plastic materials, and has excellent electrical properties. The electrical insulating oil is characterized in that it comprises a fraction having boiling points in the range of 270.degree. to 350.degree. C. which is prepared by distilling the heavier products obtained from the process for producing ethyltoluene by alkylating toluene with ethylene in the presence of synthetic zeolite catalyst. Included also in the present invention are oil-filled electrical appliances that are produced by impregnating them with the above insulating oil.
    Type: Grant
    Filed: June 21, 1985
    Date of Patent: February 4, 1986
    Assignee: Nippon Petrochemical Company, Limited
    Inventors: Atsushi Sato, Shigenobu Kawakami, Hideyuki Dohi, Keiji Endo
  • Patent number: 4565886
    Abstract: Ethynyl and substituted ethynyl-terminated polysulfones and a process for preparing the same are disclosed. These polysulfones are thermally cured to induce cross-linking and chain extension, producing a polymer system with improved solvent resistance and use temperatures. Also disclosed are substituted 4-ethynylbenzoyl chlorides as precursors to the substituted ethynyl-terminated polysulfones and a process for preparing the same.
    Type: Grant
    Filed: August 30, 1983
    Date of Patent: January 21, 1986
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventor: Paul M. Hergenrother
  • Patent number: 4513155
    Abstract: A lubricating oil for diesel engines is disclosed. This oil is based on a mixture of lubricating mineral base oil and a highly aromatic light base oil, and is highly effective in reducing the wear of the diesel engine designed to run with heavy fuels having high carbon to hydrogen ratios. The oil is also advantageous in that it does not clog the lubricant filter.
    Type: Grant
    Filed: June 24, 1983
    Date of Patent: April 23, 1985
    Assignees: Nippon Mining Co., Ltd., Mitsui Engineering & Shipbuilding Co., Ltd.
    Inventors: Kunimitsu Tamura, Kunihiko Hosonuma
  • Patent number: 4440965
    Abstract: Hydrogenated 1,3-butadiene polymers are used as synthetic lubricants. The polymers of this invention range in molecular weight from about 150 to about 3,000 and are characterized by a 1,2 addition structure of at least about 60 percent.
    Type: Grant
    Filed: May 18, 1982
    Date of Patent: April 3, 1984
    Assignee: Phillips Petroleum Company
    Inventor: Richard F. Palmer
  • Patent number: 4414406
    Abstract: Molybdenum compounds, particularly molybdenum sulfide, molybdenum silicide, molybdenum selenide and molybdenum telluride are useful Friedel-Crafts catalysts for the aralkylation of aromatics to produce polybenzyls, the manufacture of aromatic ketones, aromatic sulfones and aromatic esters.The foregoing processes are carried out at a temperature of about 60.degree. to 250.degree. C. and at a catalyst concentration of about 0.1 to 15% by weight of reactants. The reaction products are useful as laminates, herbicides and bactericides.
    Type: Grant
    Filed: September 18, 1981
    Date of Patent: November 8, 1983
    Assignee: Standard Oil Company (Indiana)
    Inventor: Ellis K. Fields
  • Patent number: 4319061
    Abstract: Terminally-functional saturated hydrocarbon low molecular weight liquid polymers are prepared by cationic polymerization of a 1-alkene containing at least one tertiary or phenyl substituted carbon in the presence of a transfer agent containing a benzylic or tertiary halogen and at least one primary or secondary halogen wherein the 1-alkene is capable of being polymerized by a Friedel Crafts catalyst.
    Type: Grant
    Filed: January 5, 1981
    Date of Patent: March 9, 1982
    Assignee: Exxon Research and Engineering Co.
    Inventors: Gary Ver Strate, Francis P. Baldwin
  • Patent number: 4239927
    Abstract: In producing synthetic hydrocarbon oils by polymerization of olefins using aluminum halide as the catalyst, organic halides are produced. These are corrosive to metal equipment and are poisonous to certain hydrogenation catalysts. This invention is concerned with reacting such organic halides with an aromatic hydrocarbon in a system also containing the polyolefins thus forming an alkylation product with both reactants prior to removal of the aluminum chloride catalyst.
    Type: Grant
    Filed: April 5, 1979
    Date of Patent: December 16, 1980
    Assignee: Mobil Oil Corporation
    Inventors: James A. Brennan, Henry D. Norris
  • Patent number: 4238343
    Abstract: A synthetic oil useful as an insulating fluid in electrical apparatus is prepared by reacting an aromatic compound with the oligomers of four to 12 carbon alpha-olefins containing predominantly at least about 30 carbon atoms up to about 60 carbon atoms. A synthetic insulating oil for electrical power transformers is prepared by reacting benzene in a 1:1 molar ratio with a tetramerpentamer mixture obtained by the oligomerization of 1-decene.
    Type: Grant
    Filed: October 26, 1978
    Date of Patent: December 9, 1980
    Assignee: Gulf Research & Development Company
    Inventor: John P. Pellegrini, Jr.
  • Patent number: 4219686
    Abstract: A process for preparing alkylbenzenes, according to which benzene is reacted with an olefin (or mixture of olefins) in the presence of a suitable catalyst, according to the Friedel-Crafts reaction. The reactant which is reacted with the benzene is the product of the autocondensation of an olefin or a mixture of olefins, having a number of carbon atoms of between 10 and 15, whereby a mixture of both light and heavy alkylbenzenes is obtained, the heavy alkylbenzenes being useful for lubricating compositions.
    Type: Grant
    Filed: October 27, 1978
    Date of Patent: August 26, 1980
    Assignee: Liquichimica Italiana S.p.A.
    Inventors: Vincenzo Petrillo, Andrea Peditto
  • Patent number: 4211665
    Abstract: Electrical apparatus containing a novel synthetic oil as an insulating fluid which is prepared by reacting an aromatic compound with the oligomers of four to 12 carbon alpha-olefins containing predominantly at least about 30 carbon atoms up to about 60 carbon atoms. For example, an electrical power transformer is provided containing a synthetic insulating oil prepared by reacting benzene in a 1:1 molar ratio with a tetramer-pentamer mixture obtained by the oligomerization of 1-decene.
    Type: Grant
    Filed: October 26, 1978
    Date of Patent: July 8, 1980
    Assignee: Gulf Research and Development Company
    Inventor: John P. Pellegrini, Jr.