Polycyclo, I.e., Fused Patents (Class 585/26)
  • Patent number: 6080888
    Abstract: Arylolefinic compounds are prepared by reacting aryl halide with an olefinic compound in the presence of a polar liquid reaction medium containing (a) secondary or tertiary amine as a hydrogen halide acceptor (b) a catalyst system formed from (i) Pd or Pd(0) compound, and/or Pd(I) salt or Pd(II) salt, and (ii) a tertiary phosphine ligand, and (c) a reaction accelerating amount of water in the range of about 0.5 to about 5 weight percent of the total weight of the reaction mixture. The arylolefinic compounds can be converted to an arylcarboxylic acid by hydrocarboxylation with CO in a reaction medium freed of amine and containing water and a Pd catalyst system as above in which a copper component may be included, and which preferably includes an ether such as THF.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: June 27, 2000
    Assignee: Albemarle Corporation
    Inventors: Tse-Chong Wu, Kannappan C. Chockalingham, W. Dirk Klobucar, Gary D. Focht
  • Patent number: 5942648
    Abstract: Naphthalene derivatives of the fomula I ##STR1## in which: R.sup.1 is an alkyl or alkenyl radical which is unsubstituted, monosubstituted by CH or CF.sub.3 or monosubstituted by halogen and has 1 to 15 carbon atoms, it also being possible for one or more CH.sub.2 groups in these radicals to be replaced, in each case independently of one another, by --O--, --S--, ##STR2## --CO--, --CO--O--, --O--CO-- or --O--CO--O-- in such a manner that oxygen atoms are not linked directly to one another, ##STR3## m is 0, 1 or 2, n is 0 or 1, wherem+n is 1 or 2,Z.sup.1 and Z.sup.2 are each, independently of one another, --CH.sub.2 CH.sub.2 --, --C.tbd.C-- or a single bond,L.sup.1 and L.sup.2 independently of one another, are H or F,x is an alkyl or alkoxy radical which is unsubstituted, monosubstituted by CN or CF.sub.3 or substituted bi halogen and has 1 to 15 carbon atoms, or is OH, CN, SCN, OCN, NCS or Q--Y,whereQ is a single bond, (CF.sub.2).sub.r or O(CF.sub.2).sub.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: August 24, 1999
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: David Coates, Mark Goulding, Simon Greenfield, Volker Reiffenrath, Reinhard Hittich, Herbert Plach
  • Patent number: 5886242
    Abstract: The invention relates to chiral compounds containing at least one divalent or polyvalent chiral group, at least one polymerizable group, at least one spacer and at least one mesogenic group, and to their use as polymerizable, chiral dopes for the preparation of cholesteric networks.The novel compounds are suitable for use in electro-optical displays or as chiral dopes for nematic or cholesteric liquid crystals in order to produce layers which reflect in colors.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: March 23, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Paul Delavier, Karl Siemensmeyer, Gerhard Wagenblast, Lothar Laupichler, Volkmar Vill
  • Patent number: 5866497
    Abstract: A catalyst precursor of the formula: ##STR1## wherein: R.sup.1 is a cycloalkadienyl ligand;R.sup.2, R.sup.3, R.sup.4, and R.sup.5 are independently hydrogen, a hydrocarbyl group containing 1 to 20 carbon atoms, or a silyl group, and may be connected to R.sup.1 through a bridging group comprising at least two Group IVA atoms; with the proviso that one of R.sup.3, R.sup.4, and R.sup.5 is a negative charge stabilizing group selected from the group consisting of Group IVA trialkyl groups, aryl groups, heteroaromatic groups, ethylenically unsaturated hydrocarbon groups, acetylenically unsaturated hydrocarbon groups, ketonic groups, and aromatic organometallic moieties, is provided. When combined with a compound comprising a metal from Groups IIIB to VIII or the Lanthanide series of the Periodic Table of elements and an activating cocatalyst, the catalyst precursor is useful for the polymerization of olefins.
    Type: Grant
    Filed: June 26, 1997
    Date of Patent: February 2, 1999
    Assignee: Univation Technologies LLC
    Inventor: Rex Eugene Murray
  • Patent number: 5856613
    Abstract: The present invention provides a method for producing .beta.-methylnaphthalene from an inexpensive and easily available feed oil. According to the invention, highly pure .beta.-methylnaphthalene adequate for industrial use can be mass-produced at reduced costs. The method comprises catalytic hydrodealkylation of a feed oil containing an alkyl naphthalene having at least two methyl groups in the presence of a catalyst having at least one metal species of selected from the group consisting of vanadium (V), chromium (Cr), nickel (Ni), rhodium (Rh), platinum (Pt), iridium (Ir), and compounds of these metals as an active component and a carrier therefor containing at least one of alumina and silica as its primary component, with a hydrogen partial pressure of 1 to 50 kgf/cm.sup.2, at a temperature of 450.degree. C. to 650.degree. C., and for a contact time of 3 to 35 seconds. The method of the invention is excellent in that it affords .beta.-methylnaphthalene of a chemical grade with a high yield.
    Type: Grant
    Filed: September 25, 1996
    Date of Patent: January 5, 1999
    Assignee: Fuji Oil Company Limited and Petroleum Energy Center
    Inventors: Masaharu Tashiro, Toshio Tsutsui, Osamu Kubota, Shinichi Okada, Toshihito Nakamura
  • Patent number: 5847246
    Abstract: A fluid heat transfer medium and process employing composite mixtures of monocyclic and bicyclic terpenes useful for heat transfer processes in a temperature range down to approximately -165.degree. F., where the fluid heat transfer medium maintains its liquid phase.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: December 8, 1998
    Assignee: Daniel J. Loikits
    Inventors: James T. Hsu, Daniel J. Loikits
  • Patent number: 5834521
    Abstract: Tetracyclic compounds having the following structure are described: ##STR1## wherein R.sub.1 -R.sub.10 are as defined. The tetracyclic compounds are capable of potent effects on steroid sensitive tissues and have demonstrated increased uterine weight, antiovulatory effects and potent steroid receptor binding. The compounds have therapeutic utility in reproductive applications such as fertility control, labor induction, ovulation induction and spermatogenesis. Methods for preparing the tetracyclic compounds from substituted indanones are also described.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: November 10, 1998
    Assignee: Ortho Pharmaceutical Corporation
    Inventors: John H. Dodd, Lisa A. Dixon, James L. Bullington, Charles F. Schwender
  • Patent number: 5744666
    Abstract: A process for preparing an alkynyl fulvene group containing compound and said compound is provided. Said process comprises reacting an alkynyl ketone compound with a cyclopentadienyl-type compound.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: April 28, 1998
    Assignee: Phillips Petroleum Company
    Inventors: M. Bruce Welch, Bernd Peifer, Helmut G. Alt
  • Patent number: 5728908
    Abstract: A process for preparing a bridged ligand, where said bridged ligand has an alkynyl group, and said bridged ligand is provided. Said process comprises reacting an alkynyl fulvene containing compound with an alkali metal salt of a cyclopentadienyl-type compound.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: March 17, 1998
    Assignee: Phillips Petroleum Company
    Inventors: M. Bruce Welch, Bernd Peifer, Helmut G. Alt
  • Patent number: 5599522
    Abstract: A radical compound of formula Ia.C(Ar.sup.12).sub.3 (Ia)wherein:each Ar.sup.12, which may be the same or different, represents a 6-membered carbocyclic, at least one group Ar.sup.12 being a group Ar.sup.1 ;each group Ar.sup.1 represents a 6-membered ring optionally substituted at the or any ortho carbon by a group R.sup.1, R.sup.2, R.sup.3 or R.sup.4, at the or any meta carbon by a group R.sup.2 or R.sup.3, and at any para carbon by a group R.sup.1, R.sup.2, R.sup.3 or R.sup.4,with the proviso that no more than two ring carbons are unsubstituted;each of R.sup.1, R.sup.2, R.sup.3 or R.sup.4, which may be the same or different, independently represents a group of formula --M, --XM, --XAr.sup.2 or --Ar.sup.2 ;M represents a water solubilizing group, each group X, which may be the same or different, represents an oxygen or sulphur atom or a NH or CH.sub.2 group.
    Type: Grant
    Filed: September 2, 1992
    Date of Patent: February 4, 1997
    Assignee: Nycomed Imaging AS
    Inventors: Mikkel J.o slashed.rgensen, Frode Rise, Sven Andersson, Torsten Almen, Klaes Golman
  • Patent number: 5569800
    Abstract: An electrophotographic photoconductor which is composed of an electroconductive support and a photoconductive layer formed thereon comprising a novel pyrene-ring-containing olefin compound having formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 each represent hydrogen or an alkyl group which may have a substituent; Y is an aliphatic hydrocarbon group which may have a substituent, a cyclic hydrocarbon group which may have a substituent, or an aromatic group which may have a substituent; n is an integer of 0 or 1, and m is an integer of 1 to 3, provided that when n is 0, m is 1, R.sup.1 is hydrogen, and Y is an aromatic group with a substituent ##STR2## R.sup.2 and R.sup.3 each represent hydrogen, and Y and R.sup.1 may be bonded to form a ring, a method of synthesizing the pyrene-ring-containing olefin compound and an intermediate therefor are disclosed.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: October 29, 1996
    Assignee: Ricoh Company, Ltd.
    Inventors: Tamotsu Aruga, Masaomi Sasaki, Tomoyuki Shimada, Hiroshi Adachi
  • Patent number: 5534640
    Abstract: Novel 1-alkyl-, 1-alkenyl-, and 1-alkynylaryl-2-amino-1,3-propanediols, intermediates and processes for the preparation thereof, and methods of reducing inflammation and cell proliferation, and relieving memory dysfunction, and inhibiting bacterial and fungal growth are disclosed.
    Type: Grant
    Filed: April 21, 1995
    Date of Patent: July 9, 1996
    Assignee: Hoechst Roussel Pharmaceuticals Inc.
    Inventors: John J. Tegeler, Barbara S. Rauckman, Russell R. L. Hamer, Brian S. Freed, Gregory H. Merriman
  • Patent number: 5512446
    Abstract: To provide a reagent with excellent stability under storage, which can detect a subject compound to be measured with higher specificity and sensitibity.Complexes of a compound represented by the general formula (I): ##STR1## (wherein R.sub.1 through R.sub.7 independently represent hydrogen atom, halogen atom, alkyl group, aryl group, aralkyl group, sulfonate group, amino group, styryl group, nitro group, hydroxyl group, carboxyl group, cyano group, or aryl azo group; R.sub.1 through R.sub.7 may or may not be bonded to each other to form a substituted or an unsubstituted condensed ring; R represents a divalent organic residue; and X.sub.1.sup..crclbar. represents an anion) and the like with immunoglobulin and the like are formed.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: April 30, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takeshi Miyazaki, Kazumi Tanaka, Tsuyoshi Santo, Toshikazu Ohnishi, Tetsuro Fukui, Tadashi Okamoto
  • Patent number: 5510554
    Abstract: In the preparation of 1,1'-binaphthyls substituted in the 2,2'-positions (and optionally substituted in one or more of positions 3 to 7 and/or 3' to 7'), a 1-halo-2-substituted naphthalene is reacted with a 2-substituted-1-naphthyl-magnesium halide in the presence of a catalyst. The catalyst comprises palladium and a phosphine ligand. Typical phosphine ligands include triphenylphosphine, 1,4-bis(diphenylphosphino)butane, 2,2'-bis(diphenylphosphinomethoxy)-1,1'-binaphthyl, and tetrakis(triphonylphosphine).
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: April 23, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Dieter Regnat, Hans-Jerg Kleiner
  • Patent number: 5476977
    Abstract: 1,1,2,3,4,4,6-Heptamethyl-1,2,3,4-tetrahydronaphthalene, a novel naphthalenic compound, is useful as an intermediate for the preparation of 5,6,7,8-tetrahydro-3,5,5,6,7,8,8-heptamethyl-2-naphthalenecarbaldehyde. It is prepared by a process consisting of the addition of an olefin of formula ##STR1## wherein R.sup.1 and R.sup.2 represent different substituents and each defines a hydrogen atom or a methyl radical, with p-cymene. 4,4-Dimethyl-2-pentene [compound (III): R.sup.1 =CH.sub.3 ; R.sup.2 =H] is obtained by the co-metathesis reaction of an olefin of formula ##STR2## wherein R.sup.1 and R.sup.2 represent identical substituents designating each a hydrogen atom or a methyl radical, with an olefin of formula ##STR3## wherein R.sup.3 and R.sup.4 identical or different, designate each a hydrogen atom or a methyl radical in the presence of an appropriate catalyst consisting of Re.sub.2 O.sub.7 on an inert solid carrier, or of WCl.sub.6 /(C.sub.2 H.sub.5))/Bu.sub.4 Sn.
    Type: Grant
    Filed: August 5, 1994
    Date of Patent: December 19, 1995
    Assignee: Firmenich SA
    Inventors: Jean-Paul Leresche, Yves Mentha
  • Patent number: 5397491
    Abstract: Heat is transferred in a thermodynamic system with a heat transfer medium which is at least one fluid of formula I and/or II, ##STR1## wherein R.sub.1 is ethyl or hydrogen, R.sub.2 is ethyl, R.sub.3 is methyl and R.sub.4 is a benzyl radical.
    Type: Grant
    Filed: May 21, 1992
    Date of Patent: March 14, 1995
    Assignee: Huels Aktiengesellschaft
    Inventors: Gerd Hons, Heinz-Werner Voges
  • Patent number: 5384059
    Abstract: Mixtures consisting essentially of cyclohexylbiphenyls, dicyclohexylbenzenes, phenylbicyclohexyls and tercyclohexyls are outstandingly suitable as heat transfer media. The mixtures can be prepared from biphenyl and cyclohexanol in the presence of bleaching earths and subsequent hydrogenation.
    Type: Grant
    Filed: August 20, 1993
    Date of Patent: January 24, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Alfons Klein, Rudolf Kron, Helmut Fiege, Klaus-Christian Paetz
  • Patent number: 5382728
    Abstract: Particular hydrocarbon composition constituted by saturated species, alkylbenzenes and polyaromatics, useful for dissolving asphaltenic residues present in oil wells. Such useful hydrocarbon blends for dissolving asphaltenic residues present in oil wells, are characterized in that said blends are essentially constituted by a composition selected from those which, on a ternary chart, in which the vertex (A) represents 100% of polyaromatics with z<-6, the vertex (B) represents 100% of saturated species, and the vertex (C) represents 100% of alkylbenzenes with z=-6, are comprised between:the vertex (A), i.e., 100% of polyaromatics with z<-6;the point, along the side AB, corresponding to 77% of polyaromatics with z<-6 and 23% of saturated species;the point, along the side AC, corresponding to 45% of alkylbenzenes and 55% of polyaromatics with z<-6;with the further constraint that the initial boiling point of the above said hydrocarbon blend is higher than 150.degree. C.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: January 17, 1995
    Assignees: AGIP S.p.A., Eniricerche S.p.A.
    Inventors: Alberto Del Bianco, Fabrizio Stroppa
  • Patent number: 5354501
    Abstract: A mesomorphic compound of the formula (I) according to Claim 1 and an optically active compound of the formula (II) according to Claim 2 are suitable as a component for a liquid crystal composition providing improved response characteristics and having an improved helical pitch at a cholesteric phase or a chiral smectic C phase. The above liquid crystal composition is useful as an element of a liquid crystal device providing a good display characteristics including a gradation display.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: October 11, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shinichi Nakamura, Takao Takiguchi, Kenji Shinjo, Takashi Iwaki, Takeshi Togano, Yoko Yamada
  • Patent number: 5354929
    Abstract: The invention is a bis-BCB compound of the structure: ##STR1## a method for making same and polymers made therefrom. The novel compounds of this invention are useful in preparing polymers that can form thin film coatings for multichip midules (MCMs) and integrated circuits (ICs). These compounds can be isolated as liquids at room temperature, and can form polymers that are hydrophobic and have low dielectrical and dissipative properties.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: October 11, 1994
    Assignee: The Dow Chemical Company
    Inventors: Robert A. Kirchhoff, P. J. Thomas, R. Garth Pews
  • Patent number: 5344959
    Abstract: Compounds of the formula ##STR1## wherein m is 1-4; R.sub.1 -R.sub.4 independently are hydrogen, lower alkyl of 1 to 6 carbons, Cl, Br, or I; R.sub.5 is hydrogen, lower alkyl of 1 to 6 carbons, Cl, Br, I, lower alkoxy or lower thioalkoxy of 1-6 carbons; R.sub.6 is hydrogen, lower alkyl, Cl, Br, I, OR.sub.11, SR.sub.11, OCOR.sub.11, SCOR.sub.11, NH2, NHR.sub.11, N(R.sub.11).sub.2, NHCOR.sub.11 OR NR.sub.11 --COR.sub.11 ; R.sub.20 is independently hydrogen or lower alkyl; A is (CH.sub.2).sub.n where n is 0-5, lower branched chain alkyl having 3-6 carbons, cycloalkyl having 3-6 carbons, alkenyl having 2-6 carbons and 1 or 2 double bonds, alkynyl having 2-6 carbons and 1 or 2 triple bonds; B is hydrogen, COOH or a pharmaceutically acceptable salt thereof, COOR.sub.8, CONR.sub.9 R.sub.10, --CH.sub.2 OH, CH.sub.2 OR.sub.11, CH.sub.2 OCOR.sub.11, CHO, CH(OR.sub.12).sub.2, CHOR.sub.13 O, --COR.sub.7, CR.sub.7 (OR.sub.12).sub.2, or CR.sub.7 OR.sub.13 O, where R.sub.
    Type: Grant
    Filed: May 18, 1993
    Date of Patent: September 6, 1994
    Assignee: Allergan, Inc.
    Inventor: Roshantha A. Chandraratna
  • Patent number: 5324875
    Abstract: Compound of formula ##STR1## wherein a) indexes m and n are identical and stand each for an integer number equal to zero, symbols R.sup.1 and R.sup.2 are identical and represent each a hydrogen atom, or are different and represent each a hydrogen atom or a methyl radical, symbols R.sup.5 and R.sup.8 stand each for a methyl radical, symbols R.sup.6 and R.sup.7 can be identical or different and designate each a hydrogen atom or a methyl radical and, either symbol R.sup.4 represents a methyl radical and symbol R.sup.3 stands for a hydrogen atom or a methyl radical, or symbols R.sup.3 and R.sup.4 represent each a methylene radical belonging to a ring such as indicated by the dotted line, with the proviso that the following combinations are excluded:1. R.sup.1 =R.sup.2 =R.sup.3 =R.sup.6 =R.sup.7 =H, or2. R.sup.1 =R.sup.2 =R.sup.3 =H and R.sup.6 or R.sup.7 =CH.sub.3, or3. R.sup.2 =CH.sub.3 and R.sup.3 =R.sup.6 =R.sup.7 =H, or4. R.sup.2 =CH.sub.3 and R.sup.3 =H and R.sup.6 or R.sup.7 =CH.sub.3, or5. R.sup.1 =R.sup.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: June 28, 1994
    Assignee: Firmenich SA
    Inventors: Charles Fehr, Jose Galindo
  • Patent number: 5321173
    Abstract: The present invention relates to novel indane compounds, such as, for example, 5-formyl-1,1,2,3,3,4,6-heptamethylindane, a compound of the formula ##STR1## and to compositions including the same, as well as to methods for their preparation. Compounds and compositions of the invention possess a fragrant musk-like aroma and have utility in the perfumery and/or other industries.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: June 14, 1994
    Assignee: Union Camp Corporation
    Inventor: Walter C. Frank
  • Patent number: 5302769
    Abstract: A polycyclic aromatic is contacted with an alkyl-substituted single ring aromatic, such as toluene, o-, m- or p-xylene or mesitylene, over a catalyst comprising a zeolite, such as zeolite beta, USY or ZSM-5 to alkylate the polycyclic aromatic. The polycyclic aromatic can be a fused polynuclear aromatic, e.g. phenanthrene, or an assembly of two or more cyclic systems, e.g. biphenyl. The polycyclic aromatic can also include carbocyclic systems such as fluorene and naphthalene or heterocyclic systems such as benzothiophene and dibenzothiophene. The polycyclic aromatic can be derived from a cycle oil, coker gas oil, extract of lubricant solvent refining or crude distillate fraction. The transalkylating agent can be derived from a reformate, pyrolysis gasoline or coker naphtha.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: April 12, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David O. Marler, Dominick N. Mazzone, L. Deane Rollmann
  • Patent number: 5276228
    Abstract: This invention is directed to a class of arylcyclobutene monomers having the general formula: ##STR1## wherein Ar is aromatic, with the proviso that the carbons of the cyclobutene rings are bonded to adjacent carbon atoms on the same aromatic ring of Ar;and R.sup.1 is a divalent alkyl, cycloaliphatic, aromatic, heteroaromatic, or heterocyclic moiety;polymeric compositions containing these monomers; and articles containing said polymeric compositions.
    Type: Grant
    Filed: January 25, 1993
    Date of Patent: January 4, 1994
    Assignee: The Dow Chemical Company
    Inventors: Kenneth J. Bruza, Robert A. Kirchhoff
  • Patent number: 5276230
    Abstract: There is disclosed a process for efficiently producing 2,6-dimethylnaphthalene used for the production of polyethylene naphthalate which comprises subjecting 2-methyl-1-(p-tolyl)butene and/or 2-methyl-1-(p-tolyl)butane as a starting raw material to cyclization dehydrogenation reaction by the use of a catalyst comprising a platinum component and at least one component selected from the group consisting of alkali metals and alkaline earth metals each being supported on aluminum oxide. The above process enables the production of the objective compound in a high yield at a low cost by using the catalyst having high safety and stability from the widely available starting material, thereby enhancing the industrial significance of the process.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: January 4, 1994
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Kenji Inamasa, Norio Fushimi, Makoto Takagawa
  • Patent number: 5254274
    Abstract: Aromatic compounds are alkylated with C.sub.20 -C.sub.1300 olefinic oligomers using an acidic alkylation catalyst to produce alkylated aromatic products, usually alkylaromatic hydrocarbons. The olefinic oligomers used as alkylating agents are prepared from 1-alkene oligomerization in contact with reduced metal oxide catalyst, preferably reduced chromium oxide on a silica support. The alkylated aromatic hydrocarbons retain the unique features of the alkylating olefinic oligomer and exhibit high viscosity index and low pour point. If the alkylation is carried out under certain combinations of conditions, especially using a Lewis acid catalysts such as aluminum trichloride and at higher temperatures, the alkyl portion of the product will undergo isomerization. The alkylaromatic compositions show improved thermal stability and are useful as lubricant basestocks and additives for improved antiwear properties, antioxidant and other properties.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: October 19, 1993
    Assignee: Mobil Oil Corporation
    Inventors: Suzzy C. Ho, Margaret M. Wu
  • Patent number: 5252253
    Type: Grant
    Filed: July 16, 1991
    Date of Patent: October 12, 1993
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: George W. Gray, Kenneth J. Toyne, David Lacey, Michael Hird
  • Patent number: 5213709
    Abstract: A mesomorphic compound represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 respectively denote an alkyl group having 1-16 carbon atoms optionally substituted; X.sub.1 and X.sub.3 respectively denote a single bond, --O--, ##STR2## X.sub.2 denotes a single bond, ##STR3## A.sub.1 denotes a single bond ##STR4## A.sub.3 denotes ##STR5## A.sub.2 denotes 9, 10-dihydro-2,7-phenanthrenediyl, 2,7-fluorenediyl or 2,7-fluorenonediyl; n is 0 or 1; and X.sub.4 and X.sub.5 respectively denote hydrogen, F, Cl, Br, --CH.sub.3, --CN or --CF.sub.3, with proviso that X.sub.1 is a single bond when A.sub.1 is a single bond.
    Type: Grant
    Filed: April 30, 1991
    Date of Patent: May 25, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takao Takiguchi, Takashi Iwaki, Takeshi Togano, Yoko Yamada, Shinichi Nakamura
  • Patent number: 5149946
    Abstract: The invention relates to a method of authenticating an object by electron paramagnetic resonance spectroscopy, the method being characterized in that at least one authenticating substance is added to the object, said substance having an EPR peak whose width is not greater than about 1.5 gauss, with the spectroscopy being performed in a static field of an amplitude such that the substance has a resonance frequency in the radio-frequency domain, and with the width of the EPR peak of the substance being used as a criterion for discrimination.
    Type: Grant
    Filed: October 10, 1990
    Date of Patent: September 22, 1992
    Assignee: Centre National de la Recherche Scientifique (CNRS)
    Inventors: Denis Jerome, Georges Tevanian, Patrick Batail, Marc Fourmigue
  • Patent number: 5132477
    Abstract: The thermal and oxidative stability of HVI-PAO olefin oligomers is improved by reaction of the oligomerization mixture containing the olefin oligomer, dimer and isomerized but unoligomerized olefin with an aromatic compound such as toluene, xylene or naphthalene. The reaction is carried out in the presence of an acidic catalyst, which may be heterogeneous solid catalyst such as an acidic clay or a crystalline zeolite such as MCM-22, a homogeneous Friedel-Crafts catalyst such as AlCl.sub.3, BF.sub.3 or their complexes or a supported catalyst such as AlCl.sub.3 on graphite or silica. The reaction improves the yield and thermal stability of the lube range products. The olefinic oligomer mixture which is reacted with the aromatic compound is prepared from 1-alkene oligomerization in contact with a reduced metal oxide, preferably reduced chromium oxide, catalyst on support such as silica.
    Type: Grant
    Filed: April 29, 1991
    Date of Patent: July 21, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Suzzy C. Ho, Bruce P. Pelrine, Margaret M. Wu
  • Patent number: 5124464
    Abstract: This invention describes a novel method of preparing metallocene compounds. The invention is based on synthesis of novel bis cyclopentadienides that, under appropriate conditions, will either encapsulate a transition metal to produce a metallocene such as ferrocene, or ferrocene derivative, or will yield a polymeric metallocene. Compounds produced by this process are useful as catalysts in propulsion systems, or as anti-knock compounds in gasolines.
    Type: Grant
    Filed: June 15, 1989
    Date of Patent: June 23, 1992
    Assignee: Brandeis University
    Inventors: Myron Rosenblum, Stephen A. Matchett
  • Patent number: 5107049
    Abstract: The thermal stability of poly alpha-olefin (PAO) lubricant basestocks are improved by reacting an aromatic compound with the alpha-olefin oligomer. The PAO materials are prepared by oligomerization of olefins such as 1-decene in the presence of a Lewis acid oligomerization catalyst. The resulting lubricant basestock product exhibits high viscosity, viscosity index and low pour point in addition to the unique enhancement in thermal stability. The reaction between the PAO and the aromatic is carried out in the presence of a solid, cyrstalline alkylation catalyst identified by a specific X-ray diffraction pattern. The preferred catalyst for this purpose is the material known as MCM-22.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: April 21, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Quang N. Le, Joosup Shim, Stephen S. Wong
  • Patent number: 5059708
    Abstract: A pyrene-ring-containing olefin compound of formula [I]: ##STR1## wherein R is a hydrogen atom, an unsubstituted or substituted alkyl group, or an unsubtituted or substituted aryl group; Y is an unsubstituted or substituted aliphatic hydrocarbon group, a cyclic hydrocarbon group, or an aromatic group; and n is an integer of 1 to 3, and when n is 1, Y and R may be bonded to form a ring; an intermediate for producing the above olefin compound, which is a phosphonic acid ester of formula [II]: ##STR2## wherein R.sup.1 is an alkyl group with 1 to 4 carbon atoms; and a method of producing the above olefin compound are disclosed.
    Type: Grant
    Filed: January 16, 1991
    Date of Patent: October 22, 1991
    Assignee: Ricoh Company, Ltd.
    Inventors: Tamotsu Aruga, Masaomi Sasaki, Tomoyuki Shimada, Hiroshi Adachi
  • Patent number: 5055622
    Abstract: Novel Styryl-tetrahydromaphthalene and indane derivatives useful for treating neoplasms and dermatoses.
    Type: Grant
    Filed: September 12, 1990
    Date of Patent: October 8, 1991
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Michael Klaus, Peter Loeliger, Peter Mohr, Ekkehard Weiss
  • Patent number: 5001276
    Abstract: Novel styryl-tetrahydromaphthalene and indane derivatives useful for treating neoplasms and dermatoses.
    Type: Grant
    Filed: May 11, 1989
    Date of Patent: March 19, 1991
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Michael Klaus, Peter Loeliger, Peter Mohr, Ekkehard Weiss
  • Patent number: 4956508
    Abstract: The invention relates to a process for preparing a polyalkyl perylene which consists in subjecting the corresponding polyalkyl 1,1'-dinaphthalene derivative to a cyclodehydrogenation reaction, by means of an alkali metal. It also relates to the polyalkyl perylene obtained, and to the organic material derived therefrom exhibiting an electron spin resonance spectrum.
    Type: Grant
    Filed: February 8, 1989
    Date of Patent: September 11, 1990
    Assignee: Thomson-CSF
    Inventors: Philippe Michel, Alexandre Moradpour, Paul Penven
  • Patent number: 4937164
    Abstract: A photoresponsive imaging member comprised of a thionated perylene photogeneratoring layer, and a charge transport layer.
    Type: Grant
    Filed: June 29, 1989
    Date of Patent: June 26, 1990
    Assignee: Xerox Corporation
    Inventors: James M. Duff, Ah M. Hor, Cheng K. Hsiao, Gordon K. Hamer, Rafik O. Loutfy
  • Patent number: 4880553
    Abstract: Compositions useful as pour point depressants, novel compounds within such compositions, and processes for making same, as well as lubricant oil compositions containing same, are disclosed. The novel compounds are encompassed by the general structural formula (I)Ar(R)--[Ar'(R')].sub.n --Ar" (I)wherein the Ar, Ar' and Ar" are independently an aromatic moiety containing 1 to 3 aromatic rings and each aromatic moiety is substituted with 0 to 3 substituents, (R) and (R') are independently an alkylene group containing about 1 to 100 carbon atoms with the proviso that at least one of (R) or (R') is CH.sub.2, and n is 0 to about 1000; with the proviso that if n is 0, then (R) is CH.sub.2 and each aromatic moiety is independently substituted with 0 to 3 substituents with one aromatic moiety having at least one substituent, the substituents being selected from the group consisting of a substituent derived from an olefin and a substituent derived from a chlorinated hydrocarbon.
    Type: Grant
    Filed: April 5, 1988
    Date of Patent: November 14, 1989
    Assignee: The Lubrizol Corporation
    Inventors: Joseph L. Kostusyk, Syed Q. A. Rizvi
  • Patent number: 4855520
    Abstract: A process for the preparation of a substituted naphthacene is disclosed wherein a 1,3-diphenylpropargyl alcohol is reacted with an alkanesulfonyl halide, the resultant reaction product is heated in the presence of a hindered amine base and the resultant substituted naphthacene is recovered.
    Type: Grant
    Filed: August 3, 1987
    Date of Patent: August 8, 1989
    Assignee: American Cyanamid Company
    Inventor: Amy P. Essenfeld
  • Patent number: 4800032
    Abstract: A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and a minor amount, effective to inhibit the accumulation of black sludge in a gasoline fueled internal combustion engine, of an aliphatic hydrocarbon substituted aromatic hydrocarbon. The aliphatic hydrocarbon substituted aromatic hydrocarbon comprises a compound of the formulaAr--R--(Ar).sub.nwherein each Ar is independently an aromatic nucleus having from 0 to 3 substituents, R is a hydrocarbyl group, and n is an integer ranging from 1 to about 6. In a further embodiment, the aliphatic hydrocarbon substituted aromatic hydrocarbon further comprises from about 1 to about 50 percent by weight of tetrahydronaphthalene or hydrocarbyl substituted tetrahydronaphthalenes.
    Type: Grant
    Filed: July 8, 1987
    Date of Patent: January 24, 1989
    Assignee: The Lubrizol Corporation
    Inventor: John P. Murphy
  • Patent number: 4767873
    Abstract: The invention describes a helicene compound having the structure ##SPC1##which contains seven six-membered conjugated aromatic rings capped by two five-membered rings which do not superimpose on each other.The invention also describes a helical metallocene oligomer capped by unsaturated five-membered rings, having the structure: ##SPC2##wherein M is a transition metal halide and n=1 to 100.Method for the preparation of these compounds are also presented.
    Type: Grant
    Filed: September 10, 1986
    Date of Patent: August 30, 1988
    Assignee: The Trustees of Columbia University in the City of New York
    Inventors: Thomas J. Katz, Anantha Sudhakar
  • Patent number: 4737297
    Abstract: A sysnthetic lubricating oil comprising at least one monosubstituted naphthalene derivative such as .beta.-t.-amylinaphthalene, .beta.-(1,1-dimethyldecyl) naphthalene or .beta.-(.alpha.,.alpha.-dimethylbenzyl) naphthalene.
    Type: Grant
    Filed: January 29, 1987
    Date of Patent: April 12, 1988
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Toshio Yoshida, Harumichi Watanabe
  • Patent number: 4734824
    Abstract: An electrical insulating oil which is suitable for use in impregnating electrical appliances such as capacitors, cables and transformers, especially those in which plastic materials are used partially or totally as dielectrics or insulating materials, and electrical appliances that are impregnated with the above electrical insulating oil. The electrical insulating oil of the invention contains at least one monoolefin and/or diolefin having three condensed or non-condensed aromatic rings.
    Type: Grant
    Filed: June 23, 1986
    Date of Patent: March 29, 1988
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hitoshi Yanagishita, Shozo Hayashi
  • Patent number: 4714794
    Abstract: A synthetic oil having excellent oxidation stability, comprising a mixture of monoalkylnaphthalenes which have each a secondary alkyl group of 6 to 24 carbon atoms and in which the specific molar ratio of .alpha.- to .beta.-substituted monalkylnaphthalenes is at least 1.0. The synthetic oil is useful as a thermal medium oil or as the main component of a synthetic lubricating oil.
    Type: Grant
    Filed: May 15, 1987
    Date of Patent: December 22, 1987
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Toshio Yoshida, Harumichi Watanabe
  • Patent number: 4707295
    Abstract: Bicyclooctane derivatives of the formula IR.sup.1 --A.sup.1 --A.sup.2 --R.sup.2 IwhereinR.sup.1 and R.sup.2 independently of one another are each an alkyl group which has 1-12 C atoms and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by O atoms and/or CO groups and/or --O13 CO groups and/or --CO--O groups and/or --CH.dbd.CH-- groups, one of the radicals R.sup.1 and R.sup.2 being also --A.sup.3 --R.sup.3,A.sup.1 is a 1,4-cyclohexylene group which is unsubstituted or substituted in the 1-position and/or 2-position and/or 3-position and/or 4-position by alkyl which has in each case 1-5 C atoms and is unsubstituted or substituted or fluorinated, and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by one or two different groupings from the group --O--, --CO--, --CH.dbd.CH--, --S--, --SO-- or --SO.sub.2 --, or is substituted by F, Cl, Br, CN and/or CHO,A.sup.2 is a 1,4-bicyclo[2.2.2] octylene group,--A.sup.3 --R.sup.3 is --Cy--R.sup.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: November 17, 1987
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Ludwig Pohl, Bernhard Scheuble, Andreas Wachtler, Reinhard Hittich, Peter Fuss
  • Patent number: 4687823
    Abstract: Arylcyclobutene resins are comprised of alkynyl groups bridging at least two arylcyclobutene moieties.
    Type: Grant
    Filed: July 1, 1986
    Date of Patent: August 18, 1987
    Assignee: The Dow Chemical Company
    Inventors: Robert A. Kirchhoff, Stephen F. Hahn
  • Patent number: 4665275
    Abstract: A thermal medium oil comprising at least one monosubstituted naphthalene derivative such as .beta.-(1,1-dimethyloctyl) naphthalene, .beta.-(1,1-dimethylhexyl) naphthalene and 2-t.-amylnaphthalene.
    Type: Grant
    Filed: June 17, 1985
    Date of Patent: May 12, 1987
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Toshio Yoshida, Harumichi Watanabe
  • Patent number: 4639833
    Abstract: An improved electrical insulating oil and oil-filled electrical appliances impregnated therewith. The electrical insulating oil has a low viscosity, low pour point and other excellent electrical characteristics and it comprises an isomer mixture of dibenzylbenzenes in which the quantity of p-dibenzylbenzene is not more that 10% by weight and the weight ratio of m-dibenzylbenzene/o-dibenzylbenzene is not lower than 3.
    Type: Grant
    Filed: August 12, 1985
    Date of Patent: January 27, 1987
    Assignee: Nippon Petrochemicals Company, Ltd.
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hideyuki Dohi
  • Patent number: 4621302
    Abstract: An electrical insulating oil which is suitable for use in impregnating electrical appliances such as capacitors, cables and transformers, especially those in which plastic materials are used partially or totally as dielectrics or insulating materials, and electrical appliances that are impregnated with the above electrical insulating oil. The electrical insulating oil of the invention contains at least one monoolefin and/or diolefin having three condensed or non-condensed aromatic rings.
    Type: Grant
    Filed: March 13, 1985
    Date of Patent: November 4, 1986
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hitoshi Yanagishita, Shozo Hayashi