With Hydrocarbon Recycle From Later To Earlier Synthesis Patents (Class 585/315)
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Publication number: 20130281749Abstract: The present invention describes a process for the conversion of a heavy feed which can be used to improve the selectivity for middle distillate. The process employs a catalytic cracking unit followed by one or more units for the oligomerization of C2 to C9 olefins which can preferentially produce an additional cut termed the middle distillate. The light portion of the oligomerate produced which cannot be incorporated into the middle distillate cut is recycled to the FCC unit for cracking into light olefins which are returned to the oligomerization units as a supplement to the olefins of the feed in order to preferentially form heavy oligomerates which can be incorporated into the middle distillate cut.Type: ApplicationFiled: November 3, 2011Publication date: October 24, 2013Applicant: IFP ENERGIES NOUVELLESInventors: Frederic Feugnet, Francois Hugues, Mai Phuong Do, Romain Roux
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Publication number: 20130245221Abstract: The present invention provides a process preparing ethylene and propylene, comprising the step of: a) contacting a feed comprising a tert alkyl ether obtained from an etherification reaction between ethanol and a tertiary iso-olefin with a zeolite-comprising catalyst at a temperature in the range of from 350 to 1000° C. to obtain a olefinic product comprising ethylene and propylene.Type: ApplicationFiled: September 7, 2012Publication date: September 19, 2013Applicant: SHELL OIL COMPANYInventors: Leslie Andrew CHEWTER, Sivakumar SADASIVAN VIJAYAKUMARI, Jeroen VAN WESTRENEN
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Publication number: 20130245294Abstract: The present invention provides a method for start-up of an Oxygenate-to-Olefins process, which process comprises the steps: a) providing an oxygenate-comprising feedstock to an Oxygenate-to-Olefins reaction zone and contacting the feedstock with a zeolite-comprising catalyst at a temperature in the range of from 450 to 700° C. ° C., to obtain an reaction product containing olefins; b) separating the reaction product obtained in step a) in at least a product fraction containing ethylene and/or propylene and a product fraction containing C4+ olefins; c) recycling at least part of the C4+ olefins in the product fraction containing C4+ olefins to the Oxygenate-to-Olefins reaction zone in step (a), characterised in that upon start-up the oxygenate-comprising feedstock initially comprises a first amount of externally supplied tert-alkyl ether and subsequently the amount of externally supplied tert-alkyl ether in the oxygenate-comprising feedstock is reduced.Type: ApplicationFiled: September 7, 2012Publication date: September 19, 2013Applicant: SHELL OIL COMPANYInventors: Leslie Andrew CHEWTER, Rajaram RAMESH, Sivakumar SADASIVAN VIJAYAKUMARI, Jeroen VAN WESTRENEN
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Patent number: 8524970Abstract: In a process for producing synthetic fuels from an educt mixture containing hydrogen and oxygenates, such as methanol and/or dimethyl ether, the educt mixture is reacted on a catalyst in a first process stage to obtain a hydrocarbon product containing olefins with preferably 2 to 8 carbon atoms. In a second process stage the hydrocarbon product is oligomerized to long-chain olefins, from which gasoline and Diesel products are obtained. The hydrocarbon product obtained in the first process stage is separated into a liquid phase and a gaseous phase. The gaseous phase is supplied to the second process stage. The liquid phase is separated into a mixture rich in C6? hydrocarbons and a mixture containing C7+ hydrocarbons and aromatics. The mixture rich in C6? hydrocarbons is supplied to the second process stage. The mixture containing C7+ hydrocarbons ?+ and aromatics can be admixed to the gasoline product for quality improvement.Type: GrantFiled: April 29, 2008Date of Patent: September 3, 2013Assignee: Lurgi GmbHInventors: Martin Rothaemel, Uwe Fincke, Holger Dropsch, Henning Buchold
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Publication number: 20130204057Abstract: The present invention (in a first embodiment) relates to a process for the simultaneous dehydration and skeletal isomerisation of isobutanol to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerise at least a portion of the isobutanol to make a mixture of n- butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, Wherein, the WHSV of the isobutanol is at least 1 h?1 or the temperature is from 200° C. to 600° C. and the catalyst is capable to make simultaneously the dehydration and skeletal isomerization of butene.Type: ApplicationFiled: March 15, 2011Publication date: August 8, 2013Applicant: Total Research & Technology FeluyInventors: Cindy Adam, Delphine Minoux, Nikolai Nesterenko, Sander Van Donk, Jean-Pierre Dath
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Publication number: 20130172644Abstract: The invention relates to a process for preparing lower olefins from an oxygenate, the process comprising: subjecting C4 hydrocarbons obtained in an oxygenate-to-olefins conversion step to extractive distillation to an etherification step to convert isobutene into an alkyl tertiary butyl ether to obtain an isobutene-depleted C4 hydrocarbon stream and alkyl tertiary-butyl ether; subjecting the isobutene-depleted C4 hydrocarbon stream to extractive distillation to obtain a stream enriched in unsaturated C4 hydrocarbons and a stream enriched in saturated C4 hydrocarbons; and recycling at least part of the stream enriched in unsaturated C4 hydrocarbons and/or at least part of the alkyl tertiary-butyl ether to the oxygenate-to-olefins conversion step.Type: ApplicationFiled: December 27, 2012Publication date: July 4, 2013Applicant: SHELL OIL COMPANYInventor: SHELL OIL COMPANY
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Publication number: 20130172645Abstract: The invention relates to a process for preparing lower olefins from an oxygenate, the process comprising subjecting C4 hydrocarbons obtained in an oxygenate-to-olefins conversion step to extractive distillation to obtain a stream enriched in unsaturated C4 hydrocarbons comprising isobutene and n-butenes, and a stream enriched in saturated C4 hydrocarbons; converting the isobutene in the stream enriched in unsaturated C4 hydrocarbons into an alkyl tertiary butyl ether to obtain an isobutene-depleted unsaturated C4 hydrocarbon stream and alkyl tertiary-butyl ether; and recycling at least part of the isobutene-depleted unsaturated C4 hydrocarbon stream and/or at least part of the alkyl tertiary-butyl ether, optionally after conversion into tertiary butanol and/or isobutene, to the oxygenate-to-olefins conversion step.Type: ApplicationFiled: December 27, 2012Publication date: July 4, 2013Applicant: SHELL OIL COMPANYInventor: SHELL OIL COMPANY
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Publication number: 20130165718Abstract: A process for the preparation of an olefin product, which process comprises the steps of: a) converting an oxygenate feedstock in an oxygenate-to-olefins conversion system, comprising a reaction zone in which an oxygenate feedstock is contacted with an oxygenate conversion catalyst under oxygenate conversion conditions, to obtain a conversion effluent comprising ethylene and/or propylene; b) separating at least a portion of the ethylene from the conversion effluent to form an ethylene stream; c) feeding the ethylene stream to an oligomerization step to produce higher molecular weight olefins; d) recycling at least a portion of the olefins as a recycle higher molecular weight olefins stream to step a).Type: ApplicationFiled: December 27, 2012Publication date: June 27, 2013Applicant: SHELL OIL COMPANYInventor: SHELL OIL COMPANY
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Patent number: 8389784Abstract: Ethanol obtained from ordinary biomass resources contains many impurities other than water and these impurities themselves or their decomposition products contaminate ethylene when the ethylene is produced by a dehydration reaction, whereby the activity of metathesis catalyst is adversely affected. A method for producing propylene of the present invention is characterized in that the ethanol obtained from biomass is converted to ethylene by a dehydration reaction, the ethylene is separated from the generated water, the separated ethylene is purified by adsorption in an adsorption tower filled with an adsorbent, and then a metathesis reaction is carried out along with a raw material containing n-butene. With the present invention, propylene having biomass-derived carbon and reduced-environmental burden can be efficiently produced without lowering the catalysis activity.Type: GrantFiled: November 13, 2006Date of Patent: March 5, 2013Assignee: Mitsui Chemicals, Inc.Inventors: Toshihiro Takai, Daisuke Mochizuki, Michiaki Umeno
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Patent number: 8373015Abstract: Catalytic methods for the production of saturated hydrocarbons with 2 to 5 carbon atoms per molecule by conversion of small hydrocarbon halides and/or hydrogenation of carbonaceous material are disclosed that result in high yield of saturated C2 to C5 hydrocarbons at reduced corrosion of the reactors and in good lifetime of the catalyst. The methods are performed in the presence of a Lewis acid comprising catalyst and in the absence of oxygen or oxygen containing compounds, whereby an upper limit of at most 50 parts per million mass of oxygen or oxygen containing compounds can be tolerated.Type: GrantFiled: March 19, 2007Date of Patent: February 12, 2013Assignee: ETH ZürichInventors: Jan Wendelin Stark, Neil Osterwalder
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Patent number: 8367883Abstract: The present invention relates to a method of manufacturing naphtha, wherein, in hydrogenation of a naphtha fraction which is fractionated from synthetic oil (FT synthetic oil) obtained by Fisher-Tropsch synthesis, the hydrogenised component is recycled and the recycled amount thereof is adjusted to reduce a olefin content in a hydro-refining apparatus whereby heat generation is suppressed and unstable operation of the hydro-refining apparatus can be stabilized. Furthermore, the present invention relates to a method of manufacturing naphtha, wherein a cut point for fractionating a naphtha fraction from FT synthetic oil is adjusted to reduce the amount of olefin in a hydro-refining apparatus whereby unstable operation of the hydro-refining apparatus can be stabilized.Type: GrantFiled: September 25, 2008Date of Patent: February 5, 2013Assignees: Japan Oil, Gas and Metals National Corporation, Inpex Corporation, Nippon Oil Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel Engineering Co., Ltd.Inventor: Yuichi Tanaka
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Patent number: 8367886Abstract: Process for producing alkene(s) from a feedstock containing at least one monohydric aliphatic paraffinic alcohol having from 2 to 5 carbon atoms. The process is carried out by 1 converting the monohydric aliphatic paraffinic alcohol(s) containing 2 to 5 carbon atoms in a reactive distillation column at elevated pressure and temperature into a heads stream having the corresponding same carbon number alkene(s) and ether(s), 2 separating the heads stream from step 1 into an ether(s) enriched stream and an alkene(s) enriched stream, 3 recycling at least part of the ether(s) enriched stream from step 2 as a reflux return to the reactive distillation column, 4 simultaneously separating the alkene(s) enriched stream from step 2 into alkene(s) and ether(s), and 5 recycling at least part of the separated ether(s) from step 4 into the reactive distillation column. An alkene(s) stream from step 4 is then recovered.Type: GrantFiled: June 29, 2006Date of Patent: February 5, 2013Assignee: BP Chemicals LimitedInventors: Benjamin Patrick Gracey, Leslie William Bolton
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Publication number: 20120302807Abstract: A process for the production of an ethylene product stream from a reactor effluent stream includes passing the reactor effluent stream and an ethylene recycle stream to a deethanizer zone to provide a light hydrocarbon feedstream and a C3+ stream. The light hydrocarbon stream goes to a demethanizer zone to provide a C2 bottom stream and an overhead stream, then splitting the C2 bottom stream into an ethane stream and an ethylene stream. The ethylene stream is divided into a first ethylene product stream and an ethylene co-feed stream, which is fed subsequently to the overhead stream to a pressure swing adsorption process producing an adsorber effluent stream during an adsorption step and a desorbed stream on desorption. The desorbed stream constitutes all or a portion of the ethylene recycle stream.Type: ApplicationFiled: September 23, 2011Publication date: November 29, 2012Applicant: UOP LLCInventor: Wim Frans Elseviers
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Publication number: 20120271081Abstract: The invention relates to a process for producing distillate from a charge of heteroatomic organic compounds comprising at least one heteroatom chosen from oxygen, sulfur and halogen, alone or in combination, in which the treatment of the charge comprises at least one step of conversion of the heteroatomic organic compounds into olefins performed in a first conversion zone, and, in at least a second oligomerization zone, a step of oligomerization of olefins originating at least partly from the conversion zone, in the presence of at least 0.5% by weight of oxygenated compounds, in order to produce a distillate. By virtue of the presence of oxygenated compounds during the oligomerization, this process makes it possible to improve the yield of distillate, making it possible to obtain a higher degree of oligomerization relative to the oligomerization of the same charge under the same reaction conditions.Type: ApplicationFiled: October 13, 2010Publication date: October 25, 2012Applicant: TOTAL RAFFINAGE MARKETINGInventors: Nikolai Nesterenko, Delphine Minoux, Sander Van Donk, Jean-Pierre Dath
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Publication number: 20120271080Abstract: Embodiments of processes for producing propylene from paraffins are provided. The process comprises the steps of combining an effluent that comprises propylene and propane from a paraffin dehydrogenation reactor with an offgas stream that comprises propane to form a combined effluent stream. The combined effluent stream is separated into a propylene product stream and a propane-rich recycle stream. The propane-rich recycle stream is introduced to the paraffin dehydrogenation reactor operating at dehydrogenation conditions to convert propane in the propane-rich recycle stream to propylene.Type: ApplicationFiled: April 20, 2011Publication date: October 25, 2012Applicant: UOP LLCInventors: Paul A. Sechrist, Gregory Werba, Mohamed Shakur, Steven Lankton, Steven Kozup, Bing Sun
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Patent number: 8273930Abstract: A process for producing ethylene from ethanol combining the catalytic conversion of hydrocarbons: an ethanol feedstock is contacted with a Y-zeolite containing catalyst to give a product stream, and a coked catalyst and an target product of ethylene are obtained after separating the reaction stream; a hydrocarbon feedstock is contacted with a Y-zeolite containing catalyst to give a product stream, a spent catalyst and an oil vapor are obtained after separating the reaction stream, and the oil vapor is further separated to give the products such as gas, gasoline and the like; a part or all of the coked catalyst and a part or all of the spent catalyst enter the regenerator for the coke-burning regeneration, and the regenerated catalyst is divided into two portions, wherein one portion returns to be contacted with the hydrocarbon feedstock, and the other portion, after cooling, returns to be contacted with ethanol feedstock.Type: GrantFiled: July 12, 2007Date of Patent: September 25, 2012Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Zhiguo Wu, Wenhua Xie, Chaogang Xie, Qiang Liu, Xuhong Mu, Jiushun Zhang, Yibin Luo, Xingtian Shu, Chenghan Yan
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Patent number: 8221706Abstract: Apparatuses for processing a hydrocarbonaceous feedstock flows are provided. In one aspect, the method includes providing two or more hydroprocessing stages disposed in sequence, each hydroprocessing stage having a hydroprocessing reaction zone with a hydrogen requirement and each stage in fluid communication with the preceding stage. A hydrogen source is provided substantially free of hydrogen from a hydrogen recycle compressor. The hydrocarbonaceous feedstock flow is separated into an portions of fresh feed for each hydroprocessing stage, and the first portion of fresh feed to the first hydroprocessing stage is heated. The heated first portion of fresh feed is supplied with hydrogen from the hydrogen source in an amount satisfying substantially all of the hydrogen requirements of the hydroprocessing stages to a first hydroprocessing zone. The unheated second portion of fresh feed is admixed with effluent from previous stage to quench the hot reactor effluent before entering a second stage.Type: GrantFiled: June 30, 2009Date of Patent: July 17, 2012Assignee: UOP LLCInventors: John A. Petri, Vedula K. Murty, Peter Kokayeff
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Patent number: 8163967Abstract: Improved processing of an oxygenate-containing feedstock involving increased or enhanced removal or recovery of carbonyls, particularly, acetaldehyde via either or both application of a more stringent stripping regime or addition of a sulfite-containing material.Type: GrantFiled: December 22, 2005Date of Patent: April 24, 2012Assignee: UOP LLCInventor: John J. Senetar
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Patent number: 8148588Abstract: The invention relates to a continuous process for preparing polyolefins having a bimodal or multimodal molar mass distribution in suspension in at least two reactors R1, R2.x, R3.y which are connected in series and in which different reaction conditions are set. In this process, the offgases A1, A2.x, A3.y, A4 and A5 leaving all the reactors connected in series are firstly collected, the collected offgases are then compressed in a compression stage 10, the compressed offgases are subsequently cooled and the cooled material is separated into a gaseous fraction and a liquid fraction. The separated fractions are then recirculated to the polymerization process at different points. The process of the invention allows the total conversion of the polymerization, based on monomer and comonomer used, to be increased to a surprising extent.Type: GrantFiled: January 25, 2005Date of Patent: April 3, 2012Assignee: Basell Polyolefine GmbHInventors: Joachim Berthold, Frank Peter Alt, Kaspar Evertz, Peter Kölle
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Patent number: 8148589Abstract: Process for producing alkene(s) from a feedstock containing at least one monohydric aliphatic paraffinic primary (or secondary) alcohol(s), consisting of ethanol or propanol(s) or a mixture thereof. The process includes the steps of converting the monohydric aliphatic paraffinic primary (or secondary) alcohol(s) into the corresponding same carbon number alkene(s) in a reactive distillation column at elevated pressure and temperature so that the heads stream extracted from the top of the reactive distillation column comprises essentially the alkene(s), cooling the heads stream from the first step to a temperature sufficient to condense at least part of the alkene(s) with the highest boiling point, recycling at least part of the condensed alkene(s) from the second step back into the reactive distillation column, as a reflux return, and simultaneously recovering the remaining alkene(s).Type: GrantFiled: June 29, 2006Date of Patent: April 3, 2012Assignee: BP Chemicals LimitedInventors: Benjamin Patrick Gracey, Leslie William Bolton
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Patent number: 8148587Abstract: The present invention provides a method for producing Lower olefin from the feed of methanol or/and dimethyl ether, characterized in that methanol or/and dimethyl ether are divided proportionally to be fed at 3 reaction zones; and the desired distribution of the olefin product is obtained by modulating the feeding ratio among the 3 reaction zones and the reaction conditions in each reaction zone.Type: GrantFiled: July 27, 2007Date of Patent: April 3, 2012Assignee: Dalian Institute of Chemical Physics, Chinese Academy of SciencesInventors: Yue Qi, Zhongmin Liu, Zhihui Lv, Hua Wang, Changqing He, Lei Xu, Jinling Zhang, Xiangao Wang
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Publication number: 20120004481Abstract: The invention describes a process for the production of middle distillate hydrocarbon bases from an ethanol feedstock that is produced from a renewable source that is obtained from biomass, whereby said process comprises a stage for purification of said feedstock, a stage for transformation of said purified feedstock into a light olefinic effluent that comprises at least 30% by weight of olefins that have between four to six carbon atoms relative to the total mass of the formed hydrocarbon compounds, whereby said stage works in the presence of a catalyst that comprises at least one zeolite that is selected from among the zeolites that have a structural type that appears in the following list: CHA, ERI, MTF, AEI, AEL, FER, EUO, MEL, MFS, TON, MTT and the zeolites ZBM-30, ZSM-48, IM-5 and IZM-2, taken by themselves or in a mixture, a stage for separation of the olefinic effluent that is obtained from stage b) in such a way as to eliminate at least a portion of the water that is formed during stage b) to produceType: ApplicationFiled: May 6, 2011Publication date: January 5, 2012Applicant: IFP Energies nouvellesInventors: Emmanuelle GUILLON, Nicolas Cadran, Natacha Touchais, Laurent Bournay
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Patent number: 8071833Abstract: A process (or steam cracking a hydrocarbon feedstock containing olefins to provide increased light olefins in the steam cracked effluent, the process comprising passing a first hydrocarbon feedstock containing one or more olefins through a reactor containing a crystalline silicate to produce an intermediate effluent with an olefin content of lower molecular weight than that of the feedstock, fractionating the intermediate effluent to provide a lower carbon fraction and a higher carbon fraction, and passing the higher carbon fraction, as a second hydrocarbon feedstock, through a stream cracker to produce a steam cracked effluent.Type: GrantFiled: May 22, 2003Date of Patent: December 6, 2011Assignee: Total Petrochemicals Research FeluyInventors: Jacques Grootjans, Valérie Vanrysselberghe, Walter Vermeiren
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Publication number: 20110282117Abstract: A process for the production of jet and other heavy fuels, the process including: contacting at least one C3 to C5 isoalkanol with a first catalyst to convert at least a portion of the isoalkanol to isoalkene, isoalkene dimers, and water; contacting at least a portion of the isoalkene dimers with a second catalyst to convert at least a portion of the isoalkene dimers to isoalkene trimers; hydrotreating the isoalkene trimers to form isoalkanes useful as a jet fuel, kerosene, or other heavy fuels.Type: ApplicationFiled: May 10, 2011Publication date: November 17, 2011Applicant: CATALYTIC DISTILLATION TECHNOLOGIESInventors: William M. Cross, JR., Gary G. Podrebarac
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Patent number: 7960599Abstract: A process for producing industrially important chemicals from renewable resources is disclosed. This “biobased” process employs readily available, renewable resources comprising fatty acids rather than exploiting fossil sources, such as coal and petroleum. In one embodiment of the process 1-octene, along with methyl-9-decenoate and butadiene, is produced from linoleic acid via an enzymemediated isomerization reaction, followed by a metathesis reaction with ethylene. Linoleic acid can be isolated from vegetable oils, such as soybean oil.Type: GrantFiled: January 13, 2004Date of Patent: June 14, 2011Assignee: Elevance Renewable Sciences, Inc.Inventors: James R. Millis, Michael J. Tupy, Timothy W. Abraham, Mervyn L. De Souza
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Publication number: 20110137094Abstract: Process for producing ethylidenorbornene (ENB) comprising a stage of thermal cracking of DCPD to CPD carried out in an inert fluid to which it is fed a stream of DCPD comprising virgin DCPD from cracking containing up to 10% wt of tetrahydroindene (THI) and recycled DCPD containing THI coming from the subsequent stage of formation of vinylnorbornene. The contact time of DCPD with the heat transfer fluid is of few seconds and it is sufficient to achieve a conversion of said DCPD ?95%, with little formation of oligomers. THI is then separated from the heat transfer fluid substantially free from DCPD and enriched in THI to a fractionation column.Type: ApplicationFiled: August 10, 2009Publication date: June 9, 2011Inventors: Enrico Ammannati, Sergio Foschi, Francesco Guarna
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Patent number: 7923590Abstract: A process for producing a monoalkylation aromatic product, such as ethylbenzene and cumene, utilizing an alkylation reactor zone and a transalkylation zone in series or a combined alkylation and transalkylation reactor zone. This process requires significantly less total aromatics distillation and recycle as compared to the prior art.Type: GrantFiled: June 27, 2008Date of Patent: April 12, 2011Assignees: ExxonMobil Chemical Patents Inc, Stone & Webster, Inc.Inventors: Shiou-Shan Chen, Shyh-Yuan H. Hwang
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Patent number: 7919660Abstract: A method of converting methanol feedstock to olefins is provided and includes contacting the methanol feedstock in a first conversion zone with a catalyst at reaction conditions effective to produce a first reaction zone effluent comprising DME, unreacted methanol and water, and recycling at least a portion of an overhead vapor product to the first conversion zone and/or to the second conversion zone.Type: GrantFiled: December 21, 2007Date of Patent: April 5, 2011Assignee: UOP LLCInventors: Bipin V. Vora, Peter R. Pujado
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Publication number: 20110077439Abstract: Process for the production of ethylene for chemical use starting with a hydrocarbon source according to which: a) the hydrocarbon source is subjected to a first cracking step, namely a pyrolysis step carried out in a cracking oven, thus producing a mixture of cracking products; b) the mixture of cracking products is subjected to a succession of treatment steps, including a compression step, which makes it possible to obtain a purified crude gas stream; c) the purified crude gas stream is then cooled to a temperature where hydrocarbons with 6 and more carbon atoms condense so that they can be removed from the purified crude gas stream; d) the resulting purified gas stream is afterwards supplied to one separating column, where a fraction A containing hydrogen, methane and ethylene is separated at the head of the column and a heavy fraction C is separated at the bottom of the column; e) a part of the reflux of this column is supplied to a refrigeration cycle leading to a fraction B enriched with ethylene; and f)Type: ApplicationFiled: May 28, 2009Publication date: March 31, 2011Applicant: SOLVAY (SOCIETE ANONYME)Inventors: Joachim Kotter, Hans-Dieter Winkler, Peter Mews, Michel Lempereur, Dominique Balthasart, Michel Strebelle
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Patent number: 7897826Abstract: The present invention relates to a process for oligomerization/polymerization of ethylene and/or alpha-olefins, comprising the steps of oligomerizing/polymerizing ethylene and/or alpha-olefins to produce a reaction product which contains undesired reaction by-products, separating the reaction by-product from the reaction product as one or more reaction by-product fractions, and subjecting at least one of the reaction by-product fractions to steam cracking to produce a steam cracking product which comprises ethylene, which may be optionally purified and feed to the oligomerization/polymerization of ethylene and/or alpha olefins step.Type: GrantFiled: June 5, 2007Date of Patent: March 1, 2011Assignees: Saudi Basic Industries Corporation, Linde AGInventors: Peter Fritz, Heinz Bölt, Anton Kirzinger, Wolfgang Müller, Florian Winkler
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Publication number: 20110046425Abstract: Disclosed herein is a process for producing an alpha olefin comprising obtaining a feed stream comprising an internal olefin having a first carbon number and an alpha olefin having a first carbon number, isomerizing the feed stream to increase the quantity of the alpha olefin, fractionating, subjecting the overhead material from fractionation to catalytic metathesis to produce a mixed olefin effluent comprising an internal olefin having a second carbon number and other hydrocarbons, fractionating, preparing the first isomerization reactor and fractionator to receive the olefin having a second carbon number, isomerizing the internal olefin intermediate in the prepared first isomerization reactor, and fractionating the second isomerization effluent in the prepared first fractionator to separate the alpha olefin having the second carbon number from the internal olefin having the second carbon number. A corresponding system also is disclosed, along with a heat pump that can be incorporated into the process.Type: ApplicationFiled: April 2, 2009Publication date: February 24, 2011Applicant: LUMMUS TECHNOLOGY INC.Inventors: Robert J. Gartside, Shaun M. McGovern, Thulasidas Chellppannair
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Publication number: 20110040134Abstract: Processes are provided for the production of butadiene from C4 containing feed stocks that contain isobutene and/or isobutane in addition to n-butene(s) and/or n-butane. The processes of the present invention generally comprise feeding the feed stock to a combination butenes isomerization reaction and distillation tower for conversion of 1-butene to 2-butenes and separation from isobutene and isobutane, followed by an oxydehydrogenation unit to convert n-butenes to butadiene. The processes may also include additional isomerization and/or dehydrogenation steps for the tower overhead and bottoms streams to create additional isobutene and/or n-butenes for valued uses, which may include additional production of butadiene. The feed to the system may comprise any mixture or separate feeding of C4 olefins and C4 paraffins, at least one of which contains isobutene and/or isobutane.Type: ApplicationFiled: August 17, 2009Publication date: February 17, 2011Inventors: Stephen Craig Arnold, Anne Mae Gaffney, Lawrence John Karas, Philip Jay Angevine, Chuen Yuan Yeh, Ruozhi Song
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Publication number: 20110034647Abstract: A system comprising a riser reactor comprising a gas oil feedstock and a first catalyst under catalytic cracking conditions to yield a riser reactor product comprising a cracked gas oil product and a first used catalyst; an intermediate reactor comprising at least a portion of the cracked gas oil product, a raffinate stream, and a second catalyst under high severity conditions to yield a cracked intermediate product and a second used catalyst; and a recycle conduit to send at least a portion of the cracked gas oil product to the riser reactor.Type: ApplicationFiled: November 20, 2008Publication date: February 10, 2011Inventors: Weijian Mo, George A. Hadjigeorge
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Publication number: 20110028771Abstract: The present invention provides a reactor system having: (1) a first reactor receiving an oxygenate component and a hydrocarbon component and capable of converting the oxygenate component into a light olefin and the hydrocarbon component into alkyl aromatic compounds; (2) a separator system for providing a first product stream containing a C3 olefin, a second stream containing a C7 aromatic, and a third stream containing C8 aromatic compounds; (3) a first line connecting the separator to the inlet of the first reactor for conveying the second stream to the first reactor; (4) a second line in fluid communication with the separator system for conveying the C3 olefin to a propylene recovery unit, and (4) a third line in fluid communication with the separator system for conveying the C8 aromatic compounds to a xylene recovery unit.Type: ApplicationFiled: October 12, 2010Publication date: February 3, 2011Applicant: UOP LLCInventors: Andrea G. Bozzano, Timur V. Voskoboynikov, Tom N. Kalnes, Paul T. Barger, Gavin P. Towler, Bryan K. Glover
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Publication number: 20100331590Abstract: Processes for the conversion of both straight- or branched-chain (e.g., paraffinic) as well as cyclic (e.g., naphthenic) hydrocarbons of a hydrocarbon feedstock into value added product streams are disclosed. The processes involve the use of both dehydrogenation and olefin cracking to produce both light olefins and aromatics in varying proportions depending on the feedstock composition and particular processing scheme. The processes are especially applicable to naphtha feedstocks comprising paraffins and naphthenes in the C5-C11 carbon number range.Type: ApplicationFiled: June 25, 2009Publication date: December 30, 2010Inventors: Debarshi Majumder, Bryan K. Glover
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Publication number: 20100305375Abstract: Process for the preparation of an olefinic product, which process comprises reacting an oxygenate feedstock and an olefinic co-feed in a reactor in the presence of an oxygenate conversion catalyst comprising a molecular sieve having one-dimensional 10-membered ring channels, and a further molecular sieve having more-dimensional channels, wherein the weight ratio between the one-dimensional molecular sieve and the further molecular sieve is in the range of from 1:1 to 100:1, to prepare an olefinic reaction effluent; separating the olefinic reaction effluent into at least a first olefinic fraction and a second olefinic fraction; recycling at least part of the second olefinic fraction; and recovering at least part of the first olefinic fraction as olefinic product.Type: ApplicationFiled: November 19, 2008Publication date: December 2, 2010Inventors: Jeroen Van Westrenen, Leslie Andrew Chewter, Ferry Winter
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Patent number: 7803330Abstract: The present invention relates to a process for the production of light weight olefins comprising olefins having from 2 to 3 carbon atoms per molecule from an oxygenate feedstock. The process comprises passing the oxygenate feedstock to an oxygenate conversion zone containing a metal aluminophosphate catalyst to produce a light weight olefin stream. A propylene stream and/or mixed butylene is fractionated from said light weight olefin stream and a medium weight C4 to C7 stream is cracked in a separate olefin cracking reactor to enhance the yield of ethylene and propylene products.Type: GrantFiled: October 18, 2007Date of Patent: September 28, 2010Assignee: UOP LLCInventors: Bipin V. Vora, Peter R. Pujado
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Publication number: 20100240937Abstract: Disclosed is a process for the production of C2 to C3 olefins via the catalytic cracking of feedstocks including C4 and heavier olefins in an integrated reaction/regeneration system.Type: ApplicationFiled: March 10, 2010Publication date: September 23, 2010Applicant: LUMMUS TECHNOLOGY INC.Inventors: Robert J. Gartside, Robert Haines
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Publication number: 20100234655Abstract: In a process for the preparation of C2- to C4-olefins, a feed stream comprising oxygenates and steam is passed through at least one fixed-bed zone comprising zeolite catalyst, where the oxygenates are converted catalytically into olefins with high selectivity for lower olefins, and the reaction mixture leaving the fixed-bed zone is separated into a first product stream comprising C2- to C3-olefins and inert gas components, at least one second product stream comprising C4+-olefins, and a third product stream consisting of aqueous phase. In order to improve the yield of lower olefins, the aim is to regulate the temperature of the catalytic reaction in accordance with a target temperature value in the range from 440 to 520° C. specified for the reaction mixture exiting the fixed-bed zone by means of a supplementary stream consisting of olefins and inert gas components fed into the feed stream.Type: ApplicationFiled: February 28, 2006Publication date: September 16, 2010Applicant: LURGI AGInventors: Martin Rothaemel, Walter Boll, Gerhard Birke, Harald Koempel, Waldemar Liebner, Hermann Bach
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Publication number: 20100168486Abstract: A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor.Type: ApplicationFiled: December 29, 2008Publication date: July 1, 2010Applicant: Fina Technology, Inc.Inventors: James R. Butler, Joseph E. Pelati
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Publication number: 20100160699Abstract: A method for efficient use of hydrogen in aromatics production from heavy aromatic oil. A hydrocarbonaceous stream comprising C9+ hydrocarbons and an essentially pure hydrogen stream are hydrotreated and hydrocracked to produce a hydrocracking zone effluent comprising aromatics. The hydrocracking zone effluent is fractionated to separately recover C4 and lighter hydrocarbons, hydrocarbons boiling between about 180° F. and about 380° F., and diesel. The heavier hydrocarbons are combined with a low purity hydrogen-containing stream and heated, then dehydrogenated or transalkylated to form hydrogen, volatile compounds, and aromatics. The hydrogen and volatile components are separated from the aromatics and treated by pressure swing adsorption to provide an essentially pure hydrogen-containing stream, which is compressed and provided to the hydrotreating and hydrocracking steps. Liquid products are recovered from the aromatics-containing stream.Type: ApplicationFiled: December 23, 2008Publication date: June 24, 2010Inventors: Stanley Joseph FREY, Vasant P. Thakkar
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Publication number: 20100087686Abstract: An integrated process for producing aromatic hydrocarbons and ethylene and/or propylene and optionally other lower olefins from low molecular weight hydrocarbons, preferably methane, which comprises: (a) contacting at least one low molecular weight alkane, preferably methane, with a halogen, preferably bromine. under process conditions sufficient to produce a monohaloalkane, preferably monobromomethane, (b) reacting the monohaloalkane in the presence of a coupling catalyst to produce aromatic hydrocarbons and C2+ alkanes, (c) separating the aromatic hydrocarbons from the product mixture of step (b) to produce aromatic hydrocarbons, and (d) cracking at least part of the C2+ alkanes in an alkane cracking system to produce ethylene and/or propylene and optionally other lower olefins.Type: ApplicationFiled: October 5, 2009Publication date: April 8, 2010Inventors: Howard Lam Ho FONG, Richard Dale SWAIN
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Publication number: 20100087693Abstract: Improved processing of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. In one particular embodiment, the cracked product gas can be treated to remove acid gas therefrom. In another embodiment, the olefin cracking reactor is a moving bed reactor.Type: ApplicationFiled: December 8, 2009Publication date: April 8, 2010Applicant: UOP LLCInventors: Tom N. Kalnes, Robert B. James, JR., Daniel H. Wei, Bryan K. Glover
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Patent number: 7678951Abstract: The subject of the invention is a method for treating a natural gas containing ethane, comprising the following stages: (a) extraction of at least one part of the ethane from the natural gas; (b) reforming of at least one part of the extracted ethane into a synthesis gas; (c) methanation of the synthesis gas into a methane-rich gas; and (d) mixing of the methane-rich gas with the natural gas. Installation for implementing this method.Type: GrantFiled: November 17, 2006Date of Patent: March 16, 2010Assignee: Total S.A.Inventor: Denis Chretien
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Publication number: 20100048965Abstract: Improved processing of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. In one particular embodiment, the cracked product gas can be treated to remove acid gas therefrom. In another embodiment, the olefin cracking reactor is a moving bed reactor.Type: ApplicationFiled: October 30, 2009Publication date: February 25, 2010Applicant: UOP LLCInventors: Tom N. Kalnes, Robert B. James, JR., Daniel H. Wei, Bryan K. Glover
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Patent number: 7655825Abstract: A method is disclosed for producing a synthetic fuel, especially diesel fuel and in addition gasoline, liquefied petroleum gas and heating gas from a gas mixture comprising an oxygenate wherein the oxygenate is methanol and/or dimethyl ether and/or another oxygenate, through a series of steps, including olefin-formation, oligomerization of the olefins, and several separation steps and recycling steps, in particular the recycling of a stream of saturated hydrocarbons following the oligomerization of olefins back to the olefin-forming stage, to obtain the diesel fuel and the other synthetic fuels in high yield.Type: GrantFiled: December 1, 2005Date of Patent: February 2, 2010Assignee: Lurgi AGInventors: Martin Rothämel, Bernd Ahlers, Matthias Wagner, Harold Koempel, Juergen Hofmockel
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Patent number: 7638665Abstract: The benzene content in a gasoline pool is reduced by a process that hydrogenates a benzene-containing isomerization zone feedstream. The additional cyclic hydrocarbons produced by the saturation of benzene can be processed in the isomerization zone for ring opening to increase the available paraffinic feedstock or the isomerization zone can be operated to pass the cyclic hydrocarbons through to a product recovery section. The isomerization zone feedstream is treated to remove contaminants and dried before entering the hydrogenation zone.Type: GrantFiled: April 3, 2009Date of Patent: December 29, 2009Assignee: UOP LLCInventor: David J. Shecterle
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Patent number: 7595427Abstract: Process for production of styrene by dehydrogenation of ethylbenzene in a reactor system comprising a dehydrogenation reactor and a fast riser catalyst regenerator.Type: GrantFiled: May 17, 2004Date of Patent: September 29, 2009Assignee: Snamprogetti S.p.A.Inventors: Domenico Sanfilippo, Ivano Miracca, Guido Capone, Vincenzino Fantinuoli
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Publication number: 20090240093Abstract: An aromatic compound, particularly benzene, is stably produced in the presence of a catalyst from a lower hydrocarbon having 2 or more carbon atoms, particularly from an ethane-containing gas composition such as ethane gas and natural gas. Disclosed is a process for producing an aromatic compound by reacting ethane or an ethane-containing raw gas in the presence of a catalyst. The catalyst may comprise molybdenum carried on metallosilicate such as H-type ZSM-5H or H-type MCM-22. In the reaction, the temperature is from 550 to 750° C., preferably not lower than 600° C. and not higher than 680° C. Additionally, the raw gas further contains methane and hydrogen is added thereto, thereby improving the production efficiency and stability.Type: ApplicationFiled: September 29, 2006Publication date: September 24, 2009Inventors: Masaru Ichikawa, Ryoichi Kojima, Yuji Ogawa, Masamichi Kuramoto
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Patent number: RE41136Abstract: The present invention relates to a process of preparing dialkylnaphthylenes and polyalkylenenaphthyleneates dialkylnaphthalenes and polyalkylenenaphthalates.Type: GrantFiled: January 24, 2002Date of Patent: February 16, 2010Assignees: Kobe Steel, Ltd, ExxonMobil Chemical Patents, Inc.Inventors: Masahiro Motoyuki, Koji Yamamoto, Ajit Vishwanath Sapre, John Paul McWilliams, Susan Patricia Donnelly