Polyolefin Patents (Class 585/326)
  • Patent number: 4957815
    Abstract: Polyarylalkane oligomer compositions consisting essentially of a mixture of isomers of xylyl-xylene and of higher homologues and a mixture of isomers of bis(dimethylphenyl)xylylene and of higher homologues; the method of making such compositions by first reacting toluene, xylene, or a mixture of toluene and xylene with chlorine in the presence of a radical generator, removing the unreacted toluene, and then subjecting the reaction product to the action of an inorganic halide or inorganic acid in the presence of xylene, and microcapsules containing color-forming material wherein the compositions are used as solvents for the color-forming material.
    Type: Grant
    Filed: July 1, 1988
    Date of Patent: September 18, 1990
    Assignee: Societe Atochem
    Inventors: Raymond Commandeur, Bernard Gurtner
  • Patent number: 4950822
    Abstract: Unsaturated .alpha.-olefin oligomers are topped to remove monomer and dimer and then distilled to remove a trimer fraction leaving a residue of tetramer, pentamer and higher oligomers. The trimer fraction is hydrogenated to form saturated .alpha.-olefin oligomer suitable for use as a lubricant.
    Type: Grant
    Filed: June 27, 1988
    Date of Patent: August 21, 1990
    Assignee: Ethyl Corporation
    Inventors: Thomas J. Dileo, Marshall B. Nelson, Matthew J. Lynch
  • Patent number: 4935570
    Abstract: Synlubes having a consistently low pour point are made by feeding a promoter (e.g. water, alcohol) at a controlled rate over an extended time period to an .alpha.-olefin (e.g. 1-decene) in contact with boron trifluoride.
    Type: Grant
    Filed: June 27, 1988
    Date of Patent: June 19, 1990
    Assignee: Ethyl Corporation
    Inventors: Marshall B. Nelson, Matthew J. Lynch, Thomas J. DiLeo
  • Patent number: 4925995
    Abstract: The invention relates to a process for preparing liquid hydrocarbons (e.g., middle distillates or gasoline) comprising at least the following steps:(i) catalytically oligomerizing an olefins-containing feed,(ii) separating effluent from step (i) into at least two fractions of which at least one (e.g., a gasoline fraction) has a boiling range above that of the feed olefins, and(iii) recycling at least part of a higher boiling fraction obtained from step (ii) to step (i).Optionally, in a further step (iv), a higher boiling fraction is hydrocracked, e.g., to prepare additional gasoline and/or middle distillates.
    Type: Grant
    Filed: February 16, 1989
    Date of Patent: May 15, 1990
    Assignee: Shell Oil Company
    Inventor: Karl H. Robschlager
  • Patent number: 4650917
    Abstract: The viscosity index of synthetic lubricant stocks such as those produced by olefin oligomerization is increased by contacting such stocks with a solid acidic isomerization catalyst such as boron trifluoride at elevated temperatures, say above about 200.degree. C. The high viscosity index fractions of the resulting product may be sorbed by a shape-selective zeolite such as ZSM-5 and recovered to produce a high VI lubricant.
    Type: Grant
    Filed: August 19, 1985
    Date of Patent: March 17, 1987
    Assignee: Mobil Oil Corporation
    Inventors: Ralph M. Dessau, David H. Olson
  • Patent number: 4615790
    Abstract: Synthetic hydrocarbon lubricating materials are produced by cross oligomerizing a Dimersol olefin and a linear olefin with a catalyst comprising a metal oxide substrate having tantalum (v) halide/oxide bound to the surface thereof.
    Type: Grant
    Filed: October 28, 1985
    Date of Patent: October 7, 1986
    Assignee: Shell Oil Company
    Inventor: Thomas H. Johnson
  • Patent number: 4523044
    Abstract: Polyarylalkane oligomer compositions comprising a mixture of two oligomers A and B, wherein oligomer A is a mixture of isomers of formula: ##STR1## with n1 and n2=0, 1 and 2, given that n1+n2.ltoreq.3; and oligomer B is a mixture of isomers of formula: ##STR2## with n'1, n"1 and n4=0, 1 and 2, n'2, n"2, n3, n'3 and n5=0 and 1, given that n'1+n"1+n'2+n"2+n3+n'3+n4+n5.ltoreq.2.The invention also comprises the process for the preparation of said oligomer compositions by the action of a halide or inorganic acid on a product of free-radical chlorination of toluene.
    Type: Grant
    Filed: September 13, 1984
    Date of Patent: June 11, 1985
    Assignee: Atochem
    Inventors: Raymond Commandeur, Bernard Gurtner
  • Patent number: 4301315
    Abstract: A stream comprising isobutylene and n-butenes is processed to effect dimerization of the isobutylene, and the resulting isobutylene dimer is fed to an alkylation step.
    Type: Grant
    Filed: September 22, 1977
    Date of Patent: November 17, 1981
    Assignee: Phillips Petroleum Company
    Inventors: Donald M. Haskell, Floyd Farha, Jr.
  • Patent number: 4255605
    Abstract: A process for producing high octane DIP (2,3-dimethylbutane) from mixed C.sub.4 olefins comprising the steps of subjecting the mixed C.sub.4 olefines to double bond isomerization, skeletal isomerization, olefin disproportionation, olefin hydrogenation and fractionation to yield DIP.
    Type: Grant
    Filed: January 2, 1980
    Date of Patent: March 10, 1981
    Assignee: Philliphs Petroleum Company
    Inventor: Rolland E. Dixon