Abstract: An amorphous molecular material having stilbene and benzyl group substituents at both side of stilbene has fluorescent characteristics.

Abstract: A method of making para-xylene or toluene is carried out by: (a) reacting a C5 or C6 linear monoene (itself, or formed from a C5 or C6 linear alkane) with a hydrogen acceptor in the presence of a hydrogen transfer catalyst to produce a C5 or C6 diene; (b) reacting the C5-C6 diene with ethylene to produce a cyclohexene having 1 or 2 methyl groups substituted thereon; and then (c) either (i) dehydrogenating the cyclohexene in the presence of a hydrogen acceptor with a hydrogen transfer catalyst to produce a compound selected from the group consisting of para-xylene and toluene, or (ii) dehydrogenating the cyclohexene in the absence of a hydrogen acceptor with a dehydrogenation catalyst, to produce para-xylene or toluene.

Abstract: Disclosed herein is a process for dehydrogenating a saturated cyclic hydrocarbon and/or 5-membered ring compound with a dehydrogenation catalyst. The dehydrogenation catalyst comprises: (i) 0.05 wt % to 5 wt % of a metal selected from Group 14 of the Periodic Table of Elements; and (ii) 0.1 wt % to 10 wt % of a metal selected from Groups 6 to 10 of the Periodic Table of Elements. The process is conducted under dehydrogenation conditions effective to dehydrogenate at least a portion saturated cyclic hydrocarbon and/or 5-membered ring compound.

Abstract: In a process for producing a methyl-substituted biphenyl compound, at least one methyl-substituted cyclohexylbenzene compound of the formula: is contacted with a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising at least one methyl-substituted biphenyl compound, wherein each of m and n is independently an integer from 1 to 3 and wherein the dehydrogenation catalyst comprises (i) an element or compound thereof from Group 10 of the Periodic Table of Elements and (ii) tin or a compound thereof.

Abstract: In a process for producing a methyl-substituted biphenyl compound, at least one methyl-substituted cyclohexylbenzene compound of the formula: wherein each of m and n is independently an integer from 1 to 3, is contacted with a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising at least one methyl-substituted biphenyl compound. The dehydrogenation catalyst comprises an element or compound thereof from Group 10 of the Periodic Table of Elements deposited on a refractory support, such as alumina.

Abstract: A leaving substituent-containing compound including a partial structure represented by the following General Formula (I): where a pair of X1 and X2 or a pair of Y1 and Y2 each represent a hydrogen atom; the other pair each represent a group selected from the group consisting of a halogen atom and a substituted or unsubstituted acyloxy group having one or more carbon atoms; a pair of the acyloxy groups represented by the pair of X1 and X2 or the pair of Y1 and Y2 may be identical or different, or may be bonded together to form a ring; R1 to R4 each represent a hydrogen atom or a substituent; and Q1 and Q2 each represent a hydrogen atom, a halogen atom or a monovalent organic group, and may be bonded together to form a ring.

Abstract: The present invention produces Cyclic Compound (1) in which organic ring groups including cyclohexane rings and benzene rings are continuously bonded, using a compound having at least one cyclohexane ring and benzene rings with halogen atoms at the two terminuses, in the presence of a nickel compound (bis(1,5-cyclooctadiene)nickel, etc.). Thereafter, by converting the cyclohexane rings in Cyclic Compound (1) into benzene rings, a desired carbon nanoring can be obtained. Thereby, the present invention efficiently produces a carbon nanoring made of a compound having a cyclic structure in which a desired number of organic ring groups are continuously bonded, with a short production process.

Abstract: Processes are provided for producing triphenylene by combining at least dodecahydrotriphenylene, a dehydrogenation catalyst such as palladium on carbon, and an aliphatic solvent having a boiling point greater than 180° C. to form a reaction mixture, heating the reaction mixture to at least about 180° C. but lower than the boiling point of the aliphatic solvent, maintaining the temperature of the reaction mixture at 180° C. but lower than the boiling point of the aliphatic solvent, and passing a purge fluid comprising an inert fluid through the reaction mixture, for a period of time adequate for production of triphenylene.

Abstract: The present invention relates to an improved process for producing tetra-hydro alkyl substituted indanes which are used in the synthesis of fragrance ingredients for perfumery applications.

Abstract: In a process for the transalkylation of polycyclohexylbenzenes, a feed containing at least one polycyclohexylbenzene is contacted with benzene under transalkylation conditions with a catalyst comprising a zeolite USY having a silica to alumina molar ratio in excess of 10 to convert at least part of said polycyclohexylbenzene to cyclohexylbenzene.

Abstract: Processes are provided for producing triphenylene by combining at least dodecahydrotriphenylene, a dehydrogenation catalyst such as palladium on carbon, and an aliphatic solvent having a boiling point greater than 180° C. to form a reaction mixture, heating the reaction mixture to at least about 180° C. but lower than the boiling point of the aliphatic solvent, maintaining the temperature of the reaction mixture at 180° C. but lower than the boiling point of the aliphatic solvent, and passing a purge fluid comprising an inert fluid through the reaction mixture, for a period of time adequate for production of triphenylene.

Abstract: The present invention relates to a process for producing a sulfone compound of the following formula (3), characterized in that an allyl sulfone compound of the formula (1) and an allyl halide compound of the formula (2) are reacted in an organic solvent in the presence of an alkali metal hydroxide and a phase-transfer catalyst: wherein A is CH2 or C?O; Ar is an aryl group optionally having 1 to 3 substitutents; and the wavy line means that the steric relation to the double bond which the wavy line is bound to is of E-form, Z-form or a mixture of E/Z; wherein X is a halogen atom; and the wavy line means the same as defined above; and wherein A, Ar and the wavy line mean the same as defined above. The present invention also relates to a process for producing a carotenoid from the same sulfone compound.

Abstract: Disclosed herein is a process of producing high purity and high yield dimethylnaphthalene by dehydrogenating a dimethyltetralin isomer using a metal catalyst for dehydrogenation. The metal catalyst contains a carrier selected from alumina (Al2O3), silica (SiO2), a silica-alumina mixture and zeolite. The metal catalyst also contains 0.05 to 2.5% by weight of platinum (Pt), 0.1 to 3.0% by weight of tin (Sn) or indium (In), 0.5 to 15.0% by weight of at least one selected from the group consisting of potassium (K), magnesium (Mg) and cesium (Cs), 0.3 to 3.0% by weight of chlorine, and 0.01 to 3.0 % by weight of zinc (Zn) or gallium (Ga) as active components based on an element weight of the final catalyst.

Abstract: Disclosed herein is a process of producing high purity and high yield dimethylnaphthalene by dehydrogenating a dimethyltetralin isomer using a metal catalyst for dehydrogenation. The metal catalyst contains a carrier selected from alumina (Al2O3), silica (SiO2), a silica-alumina mixture and zeolite. The metal catalyst also contains 0.05 to 2.5% by weight of platinum (Pt), 0.1 to 3.0% by weight of tin (Sn) or indium (In), 0.5 to 15.0% by weight of at least one selected from the group consisting of potassium (K), magnesium (Mg) and cesium (Cs), 0.3 to 3.0% by weight of chlorine, and 0.01 to 3.0 % by weight of zinc (Zn) or gallium (Ga) as active components based on an element weight of the final catalyst.

Abstract: The invention relates to a process for the production of aromatic compounds from a hydrocarbon fraction with a catalyst the preferably circulates in a moving bed. In the process, a hydrocarbon feedstock that is treated by a hydrogen-rich gas is transformed. In a particular embodiment, regenerative reforming is conducted, such as for production of BTX (butene, toluene, xylenes) with continuous regeneration of the catalyst. The invention also pertains to the related device for carrying out the process.

Abstract: A moving bed process for producing aromatic compounds comprises at least a first step in which principally naphthene dehydrogenation is carried out in the presence of hydrogen in a mole ratio (H2)1/(HC), said step being followed by at least one subsequent step carried out at a mole ratio (H2)2/(HC)2, the process also comprising reducing the catalyst with hydrogen in a ratio (H2)red/(HC). In accordance with the invention, (H2)1/(HC)+(H2)red/(HC)≦(H2)2/(HC)2, (HC) representing the molar quantity of feed in the first step and (HC)2 that of the subsequent step, or (H2)1/(HC)+(H2)red/(HC)>(H2)2/HC2, but where (H2)1/(HC) is less than (H2)2/(HC)2. Particular application to reforming.

Abstract: The present invention relates to a process for preparing bisindenylalkanes of formula I: wherein R1, R2, R3, and R4 independently represent H or a C1-C6 hydrocarbon group or R1 and R2 or R1 and R3 or R3 and R4 together with the carbon atoms to which they are attached form a saturated or unsaturated 5- or 6-membered ring, said ring being optionally substituted with a C1-C4 hydrocarbon group, and R5 represents a C1-C6 hydrocarbon group, comprising reacting, at a temperature which does not exceed about 5° C., a metallated indene of formula II with a disubstituted hydrocarbon of formula III: wherein R1, R2, R3, R4, and R5 have the same meaning as defined above, M represents a metal ion, and X independently represents a suitable leaving group, in a suitable reaction medium wherein the molar ratio of II to III is 2.05 or higher. The process is particularly suitable for preparing bisindenylethane, i.e., R1-R4 represent H and R5 represents an ethylene group.

Abstract: The invention relates to a process for the production of aromatic compounds from a hydrocarbon fraction with a catalyst the preferably circulates in a moving bed. In the process, a hydrocarbon feedstock that is treated by a hydrogen-rich gas is transformed. In a particular embodiment, regenerative reforming is conducted, such as for production of BTX (butene, toluene, xylenes) with continuous regeneration of the catalyst. The invention also pertains to the related device for carrying out the process.

Abstract: The invention relates to a process for the preparation of an alkyl benzene by catalytic dehydrogenation of the corresponding alkenyl cyclohexene in the gas phase in the presence of a diluent. A characteristic feature is that at least a part of the alkyl cyclohexane in the reaction product is used as diluent. Hydrogen can be used as an additional diluent according to the invention.

Abstract: The present invention relates to a process for preparing a carbon-bridged biscyclopentadiene compound by reacting one or two cyclopentadiene compounds LH with a carbonyl compound in the presence of at least one base and at least one phase transfer catalyst.

Abstract: Hydrocarbon feedstocks containing tetra-hydro-dicyclo-penta-diene (THDCPD) dissolved in a suitable solvent is substantially totally reformed and hydroconverted in a non-catalytic reactor having length/internal diameter ratio between 10/1 and 30/1 at critical controlled reaction conditions, including molar ratio of hydrogen-to-THDCPD of 5.0:1-12.0:1, reaction temperature of 1100.degree.-1350.degree. F., reactor pressure of 550-650 psig, and feedstream reactor residence time of 10-50 seconds so as to yield primarily benzene product together with minor aromatic materials. Suitable solvent materials can be an aromatic solvent, a non-aromatic solvent containing naphthenic and paraffinic compounds, or a combination of each. When the solvent is predominantly an alkyl aromatics mixture, these components are hydrodealkylated while the THDCPD material undergoes simultaneous reformation in the reactor.

Abstract: The present invention provides an electroless process for making a catalyst in a liquid or gaseous medium comprising contacting a base metal with a chemical cleaning agent and simultaneously or sequentially treating said base metal under reducing conditions with a noble metal-containing material, the catalyst prepared using the process, and a method of using the catalyst.

Abstract: Vinylcyclohexene is converted to ethylbenzene by contacting vinylcyclohexene with an alkali metal, liquid ammonia and an initiator.

Abstract: A fluid catalytic cracking method which comprises:(a) cracking a hydrocarbon feed stock in the presence of a mixed catalyst system which comprises particles of a first, amorphous cracking catalyst and/or large crystalline cracking catalyst component which requires frequent regeneration in a catalyst regeneration zone and particles of a second, shape selective crystalline silicate zeolite catalyst component which is less coke deactivated than the first catalyst component and requires less frequent regeneration than the latter, there being a sufficient difference between one or more of the characterizing physical properties of each catalyst component that the rate of circulation of particles of second catalyst component through the regeneration zone is, on the average, less than that of particles of first catalyst component, said cracking providing a product rich in C.sub.2-6 olefins; and,b) catalytically converting C.sub.2 -C.sub.6 olefins obtained from step (a) to a product containing gasoline and distillate.

Abstract: Lower alkanes are converted to olefins in a `third bed` external catalyst cooler (ECC) in which hot catalyst, from a first regenerator (`second bed`) operating in conjunction with a fluid catalytic cracker (`first bed`), thermally cracks and dehydrogenates the alkanes. Because this is an endothermic reaction, the catalyst is autogeneously cooled before it is recirculated to the FCC regenerator. The cracking catalyst is the catalyst of choice in the FCC reactor. Maximum conversion of alkanes to olefins is sought, and can be maintained because the FCC regenerator burns the coke made during alkane dehydrogenation. The olefins produced are then oligomerized in an oligomerization reactor ("fourth" bed) operating in conjunction with a second regenerator ("fifth" bed) to produce a gasoline range stream.

Abstract: An improvement in gasoline octane without substantial decrease in overall yield is obtained in an integrated process combining a fluidized catalytic cracking reaction and a fluidized catalyst olefin oligomerization reaction when crystalline medium pore shape selective zeolite catalyst particles are withdrawn in partially deactivated form from the oligomerization reaction stage and added as part of the active catalyst in the FCC reaction.

Abstract: A process for the production of isobutylbenzenes in particular, isobutylbenzene itself, is provided. The process is in two stages and comprises (1) reacting a vinylcyclohexane with an isoolefin of formula (R)(R.sup.1)C.dbd.C(CH.sub.3).sub.2 in the presence of a dismutation catalyst to produce an isobutenylcyclohexene and (2) contacting the isobutenylcyclohexene with a dehydroisomerisation catalyst to produce an isobutylbenzene. Examples of vinylcyclohexenes which can be used include 4-vinylcyclohexene and styrene.

Abstract: Alkylbenzenes of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.4 -alkyl, preferably methyl, and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, preferably methyl, are prepared by catalytic aromatization of the corresponding alkenylcyclohexenes of the general formula II ##STR2## by carrying out the conversion in the gas phase at 150.degree.-400.degree. C. over a catalyst which contains palladium oxide and sulfur and/or selenium or selenium oxide on active carbon.

Abstract: The alkylation of para-substituted isopropyl benzenes with dipentenes employing an aluminum halide catalyst system produces novel tetracyclic compounds.

Abstract: The present invention provides a process which is adapted for cyclodimerization of 1,3-butadiene to 4-vinylcyclohexene-1 under Diels-Alder conditions in the presence of a copper-containing ZSM-12.

Abstract: Alkylbenzenes are prepared by converting an alkyl-, alkylidene- or alkenylcyclohexene or an alkyl- or alkenylcyclohexadiene in the presence of an acidic zeolite catalyst of the pentasil type, in the gas phase or liquid phase.

Abstract: A process is provided for conducting organic compound conversion over a catalyst comprising a high silica crystalline zeolite which has been treated by contact with aluminum chloride vapor.

Abstract: A process is provided for conducting organic compound conversion over a catalyst composition comprising a specially treated crystalline zeolite having a high initial silica-to-alumina mole ratio, said zeolite having been synthesized from a reaction mixture comprising a diamine as a cation source. The treatment of the zeolite material comprises the sequential steps of reacting the zeolite with a dilute hydrogen fluoride solution, contacting the hydrogen fluoride solution reacted material with aluminum chloride vapor, and then treating the aluminum chloride contacted material to convert it to hydrogen form.

Abstract: This invention relates to a process for converting a feedstock comprising aliphatic or alicyclic hydrocarbons into aromatic hydrocarbons by bringing into contact in a fluid phase a mixture of the feedstock and an oxidizing agent other than molecular oxygen or a gas containing molecular oxygen into contact with a solid acidic catalyst having Bronsted acid sites. The process is particularly suitable for converting methane, ethane and/or ethylene into aromatics. The solid acidic catalyst with Bronsted acid sites may be an aluminosilicate zeolite with a silica to alumina ratio greater than 12:1. The oxidizing agents other than molecular oxygen or a gas containing molecular oxygen may be selected from nitrous oxide, sulphur trioxide, hydrogen peroxide, ozone, nitric oxide, carbon dioxide and nitrogen oxyfluoride. The process yields high octane value aromatics even from methane at relatively low conversion temperatures.

Abstract: The present invention relates to a process for conversion of feedstock comprising C.sub.3.sup.+ olefins in the absence of added hydrogen over a catalyst comprising a crystalline zeolite having large pores and a high silica/alumina mole ratio.

Abstract: Benzene and substituted benzene compounds are alkylated with olefins by contact with a catalyst which comprises a metal oxide substrate having tantalum (V) halide/oxide bound to the surface of the substrate.

Abstract: Oxide complex catalysts comprising Fe-Sb-Bi-O.sub.x promoted with a wide variety of different elements have been found to be especially useful in the ammoxidation of olefins to nitriles such as acrylonitrile and methacrylonitrile. Not only are the desired nitriles obtained with high yields when these catalysts are used, but also the production of unwanted liquid byproducts such as acrolein, acrylic acid and acetonitrile is significantly reduced.

Abstract: 4-Vinylcyclohexene-1 is converted to ethylbenzene by contacting the vinylcyclohexene at a temperature ranging from about 100.degree. C. to about 450.degree. C. with a catalyst prepared by impregnating an alumina with an oxide or decomposable salt of Na, K, Rb, Cs, Ca, Sr and/or Ba and calcining the impregnated material at a temperature ranging from about 450.degree. C. to about 750.degree. C.

Abstract: An oxydehydrogenation process for producing indene and substituted indenes from indene precursors more saturated than indene is described and comprises contacting said precursor with oxygen and a catalyst comprising cobalt oxide and molybdenum oxide at an elevated temperature above about 300.degree. C. Preferably the reaction is conducted at a temperature of about 500.degree.-650.degree. C. for a period of from 0.1 to about 30 seconds.

Abstract: A multi-stage dehydrogenation process for preparing indene and substituted indenes from indene precursors more saturated than indene is described. The process comprises the steps of(a) contacting said indene precursor in a first dehydrogenation zone with a dehydrogenation catalyst at an elevated temperature to form an intermediate product,(b) advancing the product of the first dehydrogenation zone to a second dehydrogenation zone,(c) contacting said product in the second dehydrogenation zone with a second dehydrogenation catalyst at an elevated temperature, and(d) recovering indene or a substituted indene from said second zone.The process of the invention results in yields of indene which are enhanced when compared to single stage, essentially isothermal processes using a single catalyst.

Abstract: A dehydrogenation process for producing indene and substituted indenes from tetrahydroindene or substituted tetrahydroindene is described and comprises contacting said tetrahydroindene or substituted tetrahydroindene with a catalyst comprising cobalt oxide and molybdenum oxide at an elevated temperature for a period of from about 0.1 to 30 seconds. The tetrahydroindene and substituted tetrahydroindenes may be prepared from cyclopentadiene or dicyclopentadiene and a butadiene.

Abstract: A process for the co-production of indene and styrene from a mixture of cyclopentadiene or dicyclopentadiene and butadiene is disclosed. The process comprises the steps of reacting cyclopentadiene or dicyclopentadiene with butadiene in a Diels-Alder reaction to form a mixture of tetrahydroindene, vinylcyclohexene and vinylnorbornene followed by the recovery of the tetrahydroindene and vinylcyclohexene, and the oxydehydrogenation of the tetrahydroindene/vinylcyclohexene mixture utilizing a composite catalyst comprising cobalt oxide and molybdenum oxide.

Abstract: A process for producing a halobiphenyl derivative represented by the following formula (I) comprises dehydrogenating a cyclohexylhalobenzene represented by the following formula (II) under such conditions that substantially no dehalogenation occurs. ##STR1## wherein X represents a halogen atom, and each of R.sup.1 and R.sup.2 independently represents a group represented by the formula ##STR2## wherein A represents carboxyl or an alkoxycarbonyl group and R represents a hydrogen atom or a lower alkyl group; an alkylcarbonyl; alkenyl; alkynyl; alkyl; aryl; arylcarbonyl; hydroxyalkyl; cyanoalkyl or cyanoalkenyl group.

Abstract: A process for preparing corresponding alkyl-substituted aromatic compounds by the gas phase catalytic dehydrogenation of vinylcycloalkenes in the presence of a dehydrogenation catalyst supported on a carrier, said catalytic dehydrogenation being carried out(i) in the presence of a dehydrogenation catalyst in which at least one of elements belonging to periods 5 and 6 in the group VIII of the periodic table selected from the group consisting of palladium, rhodium, platinum, iridium and ruthenium is supported on active carbon(ii) by introducing steam into the reaction system,(iii) but without introducing hydrogen into the reaction system,(iv) at conditions of temperatures ranging from 300.degree. C. to less than 350.degree. C. and pressure less than 2.5 atm (absolute pressure),wherein a liquid hourly space velocity (LHSV) is set at about 5 hr.sup.-1 or less when the catalytic dehydrogenation is effected in the presence of said catalyst in which palladium alone is supported on active carbon.

Abstract: Vinyl cyclohexene is converted to styrene at 170.degree. C.-360.degree. C. in the presence of copper chromite catalyst.