Diol Patents (Class 585/610)
  • Patent number: 11260374
    Abstract: The present invention relates to a Cu-based catalyst, a preparation process thereof and its use as the dehydrogenation catalyst in producing a hydroxyketone compound such as acetoin. Said Cu-based catalyst contains copper, at least one auxiliary metal selected from metal of Group IIA, non-noble metal of Group VIII, metal of Group VIB, metal of Group VIIB, metal of Group IIB and lanthanide metal of periodic table of elements, and an alkali metal, and further contains at least one ketone additive selected from a ketone represented by formula (II) and a ketone represented by formula (II?). Said Cu-based catalyst shows a high the acetoin selectivity as the dehydrogenation catalyst for producing acetoin. R1-C(?O)—CH(OH)—R2??(II) R1-C(?O)—CH(?O)—R2??(II?) In formulae (II) and (II?), each group is defined as in the description.
    Type: Grant
    Filed: November 14, 2018
    Date of Patent: March 1, 2022
    Assignees: China Petroleum & Chemical Corporation, Dalian Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.
    Inventors: Kai Qiao, Feng Zhou, Jie Su, Huixia Ma, Qingtong Zhai, Shumei Zhang
  • Patent number: 9855513
    Abstract: After an aqueous solution containing, at a concentration of less than 40% by mass, an organic compound having two or more hydrophilic groups in a molecule is adjusted to contain the organic compound at a concentration of equal to or greater than 40% by mass, the aqueous solution whose organic compound concentration is adjusted to equal to or greater than 40% by mass is irradiated with an ultrasonic wave to atomize water, and is dehydrated and concentrated.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: January 2, 2018
    Assignee: KAO CORPORATION
    Inventors: Masanori Namba, Junnosuke Saito
  • Publication number: 20020042549
    Abstract: There is provided a process for the preparation of a polymerizable composition comprising a cross-linker and a polymerizable monomer of formula (I) comprising (i) contacting a compound of formula (II) with an acid such as an imobilized acid; and (ii) neutralizing product of (i) such that a crosslinker is formed.
    Type: Application
    Filed: October 15, 2001
    Publication date: April 11, 2002
    Inventors: Barry Charles Holdstock, Trevor Owen Glasey
  • Patent number: 6194019
    Abstract: Delayed release flavorant compositions containing flavor-release additives, namely 1,2-diols of the formula wherein R1 is one of the radicals where R2 is H, lower alkyl R3, R4 are H, lower alkyl, lower alkoxy, hydroxy, or R3+R4 together are methylenedioxy, R5 is lower alkyl and the broken lines represent in the ring one additional bond and in the side chain an optional bond.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: February 27, 2001
    Assignee: Givaudan S.A.
    Inventor: Denise Anderson
  • Patent number: 4507518
    Abstract: This invention relates to an improved process for the dehydration of 2,5-dimethyl-2,5-hexanediol to give good yields of 2,5-dimethyl-2,4-hexadiene with a minimum of by-products. This is accomplished by heating 2,5-dimethyl-2,5-hexanediol with a montmorillonite clay catalyst, preferably in the presence of a lower aliphatic alcohol.
    Type: Grant
    Filed: December 14, 1983
    Date of Patent: March 26, 1985
    Assignee: Penick Corporation
    Inventors: David V. Petrocine, Ronald Harmetz
  • Patent number: 4409419
    Abstract: 2,5-Dimethyl-2,4-hexadiene is prepared by dehydrating 2,5-dimethyl-2,5-hexanediol in liquid phase. The reaction takes place by contacting 2,5-dimethyl-2,5-hexanediol, melted or dissolved in an appropriate solvent, with acids, heating the mixture at a temperature of 100.degree. C.-160.degree. C. and distilling off water from the reaction environment as it is being formed. The pressure can range between 1 and 10 bars.
    Type: Grant
    Filed: August 6, 1981
    Date of Patent: October 11, 1983
    Assignee: Anic S.p.A.
    Inventors: Aldo Prevedello, Edoardo Platone, Morello Morelli
  • Patent number: 4381416
    Abstract: A process for producing isoprene, which comprises decomposing a mixture of at least two compounds represented by the general formula ##STR1## wherein (i) W and Y each represent a hydrogen atom, and X and Z are identical or different and each represent the group OR, (ii) W and X together form a single bond, Y represents a hydrogen atom and Z represents the group OR, (iii) W represents a hydrogen atom, X and Y together form a single bond, and Z represents the group OR, or (iv) W represents a hydrogen atom, X represents the group OR, and Y and Z together form a single bond, in which R represents a hydrogen atom, a methyl group, a methoxymethyl group, a methylbutenyl group, a methylbutenyloxymethyl group, a 1,1-dimethyl-3-hydroxypropyl group, a 1,1-dimethyl-3-hydroxypropyloxymethyl group, a 3-methyl-3-hydroxybutyl group, a 3-methyl-3-hydroxybutyloxymethyl group, a 1,1-dimethyl-3-methoxypropyl group, a 1,1-dimethyl-3-methoxypropyloxymethyl group, a 3-methyl-3-methoxybutyl group or a 3-methyl-3-methoxybutyloxymethy
    Type: Grant
    Filed: December 1, 1980
    Date of Patent: April 26, 1983
    Assignee: Kuraray Co., Ltd.
    Inventors: Sunao Kyo, Tumoru Renge, Katsumi Omura
  • Patent number: 4338478
    Abstract: A process for producing a conjugated diene represented by the general formula ##STR1## wherein R.sub.3, R.sub.4 and R.sub.5 each represent a hydrogen atom, or any one of them represents a methyl group and the other two each represent a hydrogen atom,which comprises heating an alkane-1,3-diol represented by the general formula ##STR2## wherein R.sub.1 and R.sub.2 each represent a hydrogen atom, or one of them represents a hydrogen atom and the other represents a methyl group,to a temperature of at least 130.degree. C. in the liquid phase in the presence of water and a boron-oxyacid or an oxygen-containing boron compound capable of forming a boron-oxyacid it under the reaction conditions.
    Type: Grant
    Filed: December 18, 1980
    Date of Patent: July 6, 1982
    Assignee: Kuraray Co., Ltd.
    Inventors: Sunao Kyo, Katsumi Omura, Ken-ichi Hino