Using O (partial Combustion) Or Steam Patents (Class 585/652)
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Patent number: 11507031Abstract: Apparatus and methods for recovering energy in a petroleum, petrochemical, or chemical plant as described. The invention relates to a recovered electric power measuring system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data from a sensor on an electrical powerline connected to a generator of a power-recovery turbine, the power-recovery turbine located in a petroleum, petrochemical, or chemical process zone wherein a portion of a first process stream flows through the power-recovery turbine and generates recovered electric power as direct current, the power-recovery turbine electrically connected to a single DC to AC inverter and the output of the DC to AC inverter electrically connected to a first substation.Type: GrantFiled: March 18, 2019Date of Patent: November 22, 2022Assignee: UOP LLCInventors: Stanley J. Frey, Gregory A. Schwarzkopf, Thomas A. Ebner
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Patent number: 11407949Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olefins to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.Type: GrantFiled: May 4, 2021Date of Patent: August 9, 2022Assignee: SWIFT FUELS, LLCInventors: Chris D'Acosta, Jeffery Miller, Kurtis Sluss, Benjamin Wegenhart
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Patent number: 11186786Abstract: A method of converting naphtha is disclosed. The method includes heating the naphtha in stages in different heating units. The naphtha is vaporized in the first heating unit. And the vaporized naphtha undergoes the largest temperature change of the process in the second heating unit. A third heating unit can be a part of the reactor. The reactor includes a catalyst which is contacted with the pre-heated naphtha to convert it to C2 to C4 olefins.Type: GrantFiled: November 15, 2018Date of Patent: November 30, 2021Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Talal Al-Shammari, Talal Aldugman
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Patent number: 10941357Abstract: Disclosed is a process for converting C2-5 alkanes to higher-value C5-24+ hydrocarbon fuels and fuel blendstocks including reacting the C2-5 alkanes in a thermal olefination reactor operating at a temperature, pressure and space velocity to convent the alkanes to olefins and in the absence of both a dehydrogenation catalyst and steam. At least a portion of the product olefin stream is oligomerized using a zeolite catalyst to crack, oligomerize and cyclize the product olefins to form the fuel products, which are then recovered. The process is useful in removing sulfur and nitrogen-based compounds in a single step process, while reducing total costs of processing and eliminating the need for additives used in the field.Type: GrantFiled: April 16, 2019Date of Patent: March 9, 2021Assignee: SWIFT FUELS, LLCInventors: Chris D'Acosta, Jeffery Miller, Kurtis Sluss, Benjamin Wegenhart
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Patent number: 10358607Abstract: A filter for filtering pyrolysis oil and an arrangement. The filter is a split-flow filter (1, 1a, 1b), comprising a filter element (12), comprising plurality of apertures (17) extending through the filter element (12), a receiving channel (13) for receiving a flow (F) of pyrolysis oil to be filtered and for supplying said flow on first side (A) of the filter element (12), a main discharge channel (14) arranged on the first side (A) of the filter element (12) for discharging the portion of the flow (F) of pyrolysis oil having not penetrated through the filter element (12), and a filtrate channel (15) arranged on second side (B) of the filter element (12) for discharging the portion of the flow (F) of pyrolysis oil having penetrated through the filter element (12).Type: GrantFiled: December 14, 2016Date of Patent: July 23, 2019Assignee: Valmet Technologies OyInventors: Teppo Riihimaeki, Antti Kaura, Lauri Kokko, Joakim Autio
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Patent number: 8921632Abstract: 1-butene is recovered as a purified product from an MTO synthesis and especially from an integrated MTO synthesis and hydrocarbon pyrolysis system in which the MTO system and its complementary olefin cracking reactor are combined with a hydrocarbon pyrolysis reactor in a way that facilitates the flexible production and recovery of olefins and other petrochemical products, particularly butene-1 and MTBE.Type: GrantFiled: July 29, 2011Date of Patent: December 30, 2014Assignee: UOP LLCInventors: Joseph A. Montalbano, Steven Lee Krupa, John Joseph Senetar, Joseph H. Gregor, Andrea G. Bozzano, Gary S. Sandhu
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Patent number: 8864977Abstract: A process for the on-stream decoking of a steam cracking furnace, the steam cracking furnace including multiple tube banks positioned between a hydrocarbon feedstock inlet and a convection section to radiant section crossover, each tube bank including a plurality of tubes arranged within the tube bank, the process comprising the steps of terminating the flow of hydrocarbon feed to a portion of the plurality of tubes of less than all of the multiple tube banks, and supplying a decoking feed comprising steam to the portion of the plurality of tubes of less than all of the multiple tube banks in sufficient amount to effect removal of coke accumulated on the interior of the radiant coils and quench system components fed by such tubes while maintaining a temperature at the convection section to radiant section crossover of below about 788° C. A furnace for the production of ethylene is also provided.Type: GrantFiled: July 11, 2008Date of Patent: October 21, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventor: David B. Spicer
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Patent number: 8815080Abstract: Processes for production of olefins from hydrocarbon feedstocks are provided. In one aspect, the processes of the present invention utilize coils passing through a pyrolysis furnace to partially convert a hydrocarbon feedstock to olefins, followed by further conversion of the hydrocarbon feedstock in an adiabatic reactor. A portion of the coils in the pyrolysis furnace carry the hydrocarbon feedstock and the remainder carry steam only. After a selected period of time, the material flowing through the coils is switched. By flowing steam through the coils that had previously contained the hydrocarbon feedstock, on-line decoking can occur. In another aspect, a high temperature reactor is used to convert methane or natural gas to olefins.Type: GrantFiled: January 26, 2009Date of Patent: August 26, 2014Assignee: Lummus Technology Inc.Inventor: Kandasamy Meenakshi Sundaram
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Patent number: 8814989Abstract: A process for removing carbon dioxide (CO2) by means of an absorption medium from a cycle gas system, wherein the CO2 occurs within a process in which, in the gas phase, ethylene is oxidized by oxygen (O2) to ethylene oxide (EO) in the presence of a catalyst, in which, as by product, CO2 is generated, by using as absorption medium an aqueous solution of one or more amines, wherein, for further purification of the cycle gas stream obtained downstream of the CO2 absorption step, this cycle gas stream is brought into intimate contact with water to which no mineral acid and no higher glycol was added.Type: GrantFiled: May 17, 2011Date of Patent: August 26, 2014Assignee: BASF SEInventors: Robin Thiele, Gerhard Theis
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Patent number: 8791314Abstract: The present invention concerns an additive for reducing the formation of coke and/or carbon monoxide in thermal hydrocarbon cracking units and/or of other organic compounds in heat exchangers. The additive according to the invention is essentially composed of diethyl disulphide (DEDS) or dipropyl disulphide(s) (DPDS) or dibutyl disulphide(s) (DBDS) and can be used on the metal walls of a cracking reactor and on the metal walls of a heat exchanger placed downstream from the cracking reactor, and during the process of cracking hydrocarbons and/or other organic compounds.Type: GrantFiled: February 20, 2008Date of Patent: July 29, 2014Assignee: Arkema FranceInventors: Georges Fremy, Francis Humblot, Paul-Guillaume Schmitt
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Publication number: 20140194663Abstract: A process for the coupling of hydrocarbons and utilizing the heat energy produced by the reaction is disclosed. In one embodiment the process can include reacting methane with oxygen to form a product stream containing ethane and further processing the ethane to ethylene in an existing ethylene production facility while using the heat energy produced by the reaction within the facility.Type: ApplicationFiled: March 12, 2014Publication date: July 10, 2014Applicant: FINA TECHNOLOGY, INC.Inventor: James R. Butler
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Patent number: 8684384Abstract: A process for cracking a hydrocarbon feedstream containing non-volatile components in a hydrocarbon cracking furnace having upper and lower convection heating sections within a flue of the furnace, a radiant heating section downstream of and connected to said lower convection heating section, a transfer line exchanger downstream of and connected to said radiant heating section, a furnace box containing furnace burners and said radiant heating section, and a vapor/liquid separator vessel connected between the upper and lower convection heating sections, the process comprising (a) passing said hydrocarbon feedstream into said upper convection section to heat said hydrocarbon feedstream to a first temperature sufficient to flash at least a portion of the hydrocarbons within said hydrocarbon feedstream into a vapor phase to form a vapor/liquid stream; (b) passing said vapor/liquid stream out of said upper convection section and into said vapor/liquid separator to separate said vapor/liquid stream into a hydrocarbType: GrantFiled: May 7, 2009Date of Patent: April 1, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: David B. Spicer, Caleb M. Scherer, James M. Frye, Subramanian Annamalai
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Patent number: 8663456Abstract: A hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted intimately with a counter-current steam produce a second vapor stream and a second liquid stream. The first vapor stream and the second vapor stream are cracked in the radiant section of the steam cracker to produce a cracked effluent. The second liquid stream is thermally cracked in a coking drum to produce a coker effluent and coke. The coker effluent is separated into a coker gas and a coker liquid. The coker liquid is reacted with hydrogen in the presence of a catalyst to produce a hydroprocessed product. The hydroprocessed product is separated into a gas product and a liquid product. The liquid product is fed to the vaporization unit.Type: GrantFiled: November 23, 2010Date of Patent: March 4, 2014Assignee: Equistar Chemicals, LPInventors: Robert S. Bridges, Sellamuthu G. Chellappan
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Patent number: 8658023Abstract: A hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted with a counter-current steam to produce a second vapor stream and a second liquid stream. The first vapor stream and the second vapor stream are cracked in the radiant section of the steam cracker to produce a cracked effluent. The second liquid stream is catalytically cracked to produce a cracked product. The cracked product is distilled to produce an overhead stream, a light cycle oil, and a heavy cycle oil. The light cycle oil is reacted with hydrogen in the presence of a catalyst to produce a hydrotreated light cycle oil. The hydrotreated light cycle oil and the overhead stream are fed to the vaporization unit.Type: GrantFiled: December 29, 2010Date of Patent: February 25, 2014Assignee: Equistar Chemicals, LPInventor: Steven T. Coleman
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Patent number: 8658022Abstract: A process for cracking a heavy hydrocarbon feed comprising a vaporization step, a hydroprocessing step, and a steam cracking step is disclosed. The heavy hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted intimately with a counter-current steam to produce a second vapor stream and a second liquid stream. The first vapor stream and the second vapor stream are cracked in the radiant section of the steam cracker to produce a cracked effluent. The second liquid stream is reacted with hydrogen in the presence of a catalyst to produce a hydroprocessed product. A liquid hydroprocessed product is fed to the vaporization unit.Type: GrantFiled: November 23, 2010Date of Patent: February 25, 2014Assignee: Equistar Chemicals, LPInventors: Robert S. Bridges, Sellamuthu G. Chellappan
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Patent number: 8658019Abstract: A process for cracking a heavy hydrocarbon feed comprising a vaporization step, a coking step, a hydroprocessing step, and a steam cracking step is disclosed.Type: GrantFiled: November 23, 2010Date of Patent: February 25, 2014Assignee: Equistar Chemicals, LPInventors: Robert S. Bridges, Sellamuthu G. Chellappan
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Patent number: 8569200Abstract: A catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.Type: GrantFiled: December 1, 2011Date of Patent: October 29, 2013Assignee: LG Chem, Ltd.Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
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Patent number: 8435386Abstract: A process and apparatus for cracking a hydrocarbon feed in a steam cracking furnace by withdrawing a resid-rich stream from a resid knockout vessel and recycling the resid-rich stream through a convection heating section of the furnace.Type: GrantFiled: September 30, 2011Date of Patent: May 7, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Richard C. Stell, David B. Spicer, George Stephens
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Patent number: 8273936Abstract: A process for cracking a heavy hydrocarbon feed is disclosed. The heavy hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted intimately with a countercurrent steam to produce a second vapor stream and a second liquid stream. The second vapor stream is contacted with a wash liquid in a rectification section to form a rectified stream. The first vapor stream and the rectified stream are cracked in the radiant section of the steam cracker to produce a cracked effluent.Type: GrantFiled: November 22, 2010Date of Patent: September 25, 2012Assignee: Equistar Chemicals, LPInventors: Robert S. Bridges, Steven T. Coleman
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Patent number: 8198498Abstract: A method for producing olefins using a carbon nanotube catalyst is disclosed. Initially, a hydrocarbon feedstock is received. The hydrocarbon feedstock, the carbon nanotube catalyst, and steam are mixed in a thermal cracking reactor. The mixture is heated in the thermal cracking reactor to a particular temperature. The olefins are then separated from the mixture. The carbon nanotube catalyst can include carbon nanotubes coated with M1xOy and modified with M2mOn. M1 can be either the element silicon or tungsten, x can be an integer that represents the oxidation number of M1, and y can an integer that represents the number of oxygen atoms required by the oxidation number of M1. M2 can be a metallic element, m can be an integer that represents the oxidation number of M2, and n can be an integer that represents the number of oxygen atoms required by the oxidation number of M2.Type: GrantFiled: August 19, 2010Date of Patent: June 12, 2012Inventors: Kamyar Keyvanloo, Jafar Towfighi Darian, Ali Mohamadalizadeh
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Publication number: 20120142983Abstract: Process for making a bio-diesel and a bio-naphtha and optionally bio-propane from a complex mixture of natural occurring fats & oils, wherein said complex mixture is subjected to a refining treatment for removing the major part of the non-triglyceride and non-fatty acid components, thereby obtaining refined oils; said refined oils are subjected to a fractionation step for obtaining: an unsaturated or substantially unsaturated, liquid or substantially liquid triglyceride part (phase L); and a saturated or substantially saturated, solid or substantially solid triglyceride part (phase S); and said phase L is transformed into alkyl-esters as bio-diesel by a transesterification; said phase S is transformed into linear or substantially linear paraffin's as the bio-naphtha: by an hydrodeoxygenation or from said phase S are obtained fatty acids that are transformed into linear or substantially linear paraffin's as the bio-naphtha by hydrodeoxygenation or decarboxylation of the free fatty acids or from saidType: ApplicationFiled: July 13, 2010Publication date: June 7, 2012Applicant: TOTAL PETROCHEMICALS RESEARCH FELUYInventors: Walter Vermeiren, François Bouvart, Nicolas Dubut
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Patent number: 8158840Abstract: A process and apparatus for steam cracking liquid hydrocarbon feedstocks utilizes a vapor/liquid separation apparatus to treat heated vapor/liquid mixtures to provide an overhead of reduced residue content and includes: i) indirectly heat exchanging liquid bottoms with boiler feed water to provide cooled liquid bottoms and preheated boiler feed water; ii) directing at least a portion of said preheated boiler feed water to a steam drum; and iii) recovering steam having a pressure of at least about 4100 kPa (600 psia) from said steam drum.Type: GrantFiled: June 3, 2008Date of Patent: April 17, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventor: David B. Spicer
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Patent number: 8152993Abstract: Methods are provided for decoking the radiant coils in an ethylene cracking plant. The decoking process is controlled by monitoring the coil outlet temperature to control the rate of burning of coke in the radiant coils. Air flow rates, steam flow rates and coil outlet temperatures are controlled during the decoking process to prevent tube damage, minimize decoking time and maximize coke removal.Type: GrantFiled: May 7, 2008Date of Patent: April 10, 2012Assignee: Lummus Technology Inc.Inventors: Stephen De Haan, Barbara Stancato, Brian K. Sullivan, Charles E. Nagy, Frank McCarthy
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Patent number: 8123931Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.Type: GrantFiled: May 23, 2008Date of Patent: February 28, 2012Assignee: LG Chem, Ltd.Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
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Patent number: 8083932Abstract: A process for making lower olefins from a wide boiling range hydrocarbon feed by use of a combination of one or more vapor/liquid separation devices, and then pyrolytically cracking the vapor phase in separate sets of pyrolysis radiant tubes, thereby producing a higher level of lower olefin product.Type: GrantFiled: August 21, 2008Date of Patent: December 27, 2011Assignee: Shell Oil CompanyInventors: Arthur James Baumgartner, Robert Lawrence Blackbourn, Danny Yuk Kwan Ngan
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Patent number: 8071833Abstract: A process (or steam cracking a hydrocarbon feedstock containing olefins to provide increased light olefins in the steam cracked effluent, the process comprising passing a first hydrocarbon feedstock containing one or more olefins through a reactor containing a crystalline silicate to produce an intermediate effluent with an olefin content of lower molecular weight than that of the feedstock, fractionating the intermediate effluent to provide a lower carbon fraction and a higher carbon fraction, and passing the higher carbon fraction, as a second hydrocarbon feedstock, through a stream cracker to produce a steam cracked effluent.Type: GrantFiled: May 22, 2003Date of Patent: December 6, 2011Assignee: Total Petrochemicals Research FeluyInventors: Jacques Grootjans, Valérie Vanrysselberghe, Walter Vermeiren
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Patent number: 8057663Abstract: A process and apparatus for cracking a hydrocarbon feed in a steam cracking furnace by withdrawing a resid-rich stream from a resid knockout vessel and recycling the resid-rich stream through a convection heating section of the furnace.Type: GrantFiled: May 29, 2009Date of Patent: November 15, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Richard C. Stell, David B. Spicer, George Stephens
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Patent number: 8044254Abstract: A processing scheme and arrangement for enhanced olefin production involves cooling or treating an olefin cracking reactor effluent stream by contacting the olefin cracking reactor effluent stream with a quench oil stream in a single contact cooler contact zone to produce a cooled vapor stream and to form a heated quench oil stream. A pressure differential across the single contact cooler is less than about 3.5 kPa. The heated quench oil stream can be subsequently cooled and returned to the single contact cooler.Type: GrantFiled: March 16, 2009Date of Patent: October 25, 2011Assignee: UOP LLCInventor: Adam J. Kanyuh
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Patent number: 8013196Abstract: The invention relates to a process for the production of ethylene, comprising the steps of a) thermally converting, by a pyrolysis or a partial oxidation process, a feed charge containing methane into an acetylene containing effluent, and b) in situ hydrogenating, by a non-catalytic reaction, the acetylene produced in the first step into ethylene by intimately mixing the acetylene containing effluent with an ethane feed. The process according to the invention is more efficient than other synthesis schemes, while simplifying the overall process design. This process thus offers an economically attractive scheme for mass production of ethylene from natural gas, based on a well-known and proven acetylene route.Type: GrantFiled: June 22, 2006Date of Patent: September 6, 2011Assignee: Saudi Basic Industries CorporationInventors: Aggadin Mamedov, Saeed Al-Wahabi, Yungyi Lin, Mohamed Sabri Abdelghani, Akram Al-Alwan
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Patent number: 7977524Abstract: A process for decoking a convection section of a furnace for cracking a hydrocarbon feed, the furnace comprising a radiant section having burners that generate radiant heat and hot flue gas, and the convection section having at least one heat exchange tube for conveying the hydrocarbon feed. The process includes the step of establishing a flue gas temperature within the convection section of the furnace immediately adjacent the at least one convection section heat exchange tube so as to effect a film surface temperature of less than about 540° C. (about 1000° F.) within at least one convection section heat exchange tube, wherein said flue gas temperature establishing step is effective to decoke the at least one convection section heat exchange tube. A process for cracking hydrocarbon feed in a furnace is also provided.Type: GrantFiled: December 10, 2007Date of Patent: July 12, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: James N. McCoy, Richard Charles Stell
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Patent number: 7972498Abstract: The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is treated by hydroprocessing and visbreaking and then passed to a steam cracker to obtain a product comprising olefins.Type: GrantFiled: October 19, 2006Date of Patent: July 5, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: John S. Buchanan, Paul F Keusenkothen, Stephen H. Brown, Julian A. Wolfenbarger, James E. Graham, James N. McCoy
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Patent number: 7951987Abstract: The present invention relates to a thermal-cracking method of hydrocarbon using a hydrocarbon thermal-cracking apparatus including a tube type furnace having a radiation part for thermally cracking hydrocarbon feedstocks supplied together with steam and a convection part. A hydrocarbon thermal-cracking catalyst is packed in some or entire area of the tube placed in the radiation part of the tube type furnace, wherein the hydrocarbon thermal-cracking catalyst includes an oxide catalyst represented by CrZrjAkOx (wherein, 0.5?j?120 and 0?k?50, A is a transition metal, and x is a number corresponding to the atomic values of Cr, Zr, and A and the numbers of j and k). Therefore, it is possible to improve yield and selectivity of olefin, reduce fuel consumption due to an excellent heat transfer efficiency and extend decoking interval by reduced production of coke deposited to an inside wall of a tube, in steam cracking of hydrocarbon for producing olefin.Type: GrantFiled: July 2, 2008Date of Patent: May 31, 2011Assignee: LG Chem, Ltd.Inventors: Jun-seon Choi, Byoung-gi Park, Jin-do Kim, Hyune-jung Ryu
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Patent number: 7939702Abstract: Disclosed is a process for increasing production of light olefinic hydrocarbons from hydrocarbon feedstock by catalytic cracking. In the process, an effective separation process structure and recycle method of light olefins are used not only to increase the productivity and efficiency of an overall process, thus effectively increasing the production of light olefins, but also to simplify the overall process.Type: GrantFiled: June 1, 2006Date of Patent: May 10, 2011Assignee: SK Energy Co., Ltd.Inventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang
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Patent number: 7923592Abstract: The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200° C. to about 1200° C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.Type: GrantFiled: February 2, 2007Date of Patent: April 12, 2011Assignee: Velocys, Inc.Inventors: Anna Lee Tonkovich, Thomas Yuschak, Timothy J. LaPlante, Scott Rankin, Steven T. Perry, Sean Patrick Fitzgerald, Wayne W. Simmons, Terry Mazanec, Eric Daymo
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Patent number: 7883618Abstract: Systems and processes for producing one or more olefins. A feed containing 90% by weight or more C4 and higher hydrocarbons can be cracked at conditions sufficient to provide an olefinic mixture and an aromatic mixture. The olefinic mixture can comprise 90% by weight or more C1 to C3 hydrocarbons. The aromatic mixture can comprise 90% by weight or more C4 and higher hydrocarbons and one or more aromatics. The aromatic mixture can be contacted with one or more solvents to selectively separate at least a portion of the one or more aromatics therefrom to provide an aromatic-rich mixture and an aromatic-lean mixture. At least a portion of the aromatic-lean mixture can be recycled to the feed prior to cracking.Type: GrantFiled: February 28, 2008Date of Patent: February 8, 2011Assignee: Kellogg Brown & Root LLCInventors: Alan Claude, Anand Subramanian
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Patent number: 7863494Abstract: Provided are a catalyst for hydrocarbon steam cracking for light olefin production and a method for preparing the same. The catalyst is a simple KMgPO4 catalyst, a supported KMgPO4 catalyst, or a KMgPO4-sintered catalyst. The supported KMgPO4 catalyst is prepared by impregnating a carrier with an aqueous solution of a KMgPO4 precursor and the KMgPO4-sintered catalyst is prepared by mixing a KMgPO4 powder or a KMgPO4 precursor powder with metal oxide followed by sintering. Provided is also a method for producing light olefins such as ethylene and propylene by steam cracking in the presence of the catalyst. When the catalyst comprising KMgSO4 as a catalytic component is used in olefin production, the yield of olefins is increased and the amount of cokes deposited on the catalyst is reduced.Type: GrantFiled: May 7, 2004Date of Patent: January 4, 2011Assignees: LG Chem, Ltd., LG Petrochemical Co., Ltd.Inventors: Jun-han Kang, Won-ho Lee, Sang-mun Jeong, Sang-ku Park, Jong-hyun Chae
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Patent number: 7858834Abstract: A method for utilizing a feed comprising condensate and crude oil for an olefin production plant is disclosed. The feed is subjected to vaporization and separated into vaporous hydrocarbons and liquid hydrocarbons. The vaporous hydrocarbons stream is thermally cracked in the plant. The liquid hydrocarbons are recovered.Type: GrantFiled: August 17, 2007Date of Patent: December 28, 2010Assignee: Equistar Chemicals, LPInventor: Donald H. Powers
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Patent number: 7846322Abstract: A high-flux membrane, especially a sieving membrane, is used to separate a naphtha feedstock into a retentate fraction having a reduced concentration of normal paraffins for an enhanced reforming feed and a permeate fraction having an increased concentration of normal paraffins for an enhanced cracking feed.Type: GrantFiled: September 7, 2007Date of Patent: December 7, 2010Assignee: UOP LLCInventor: Lynn H. Rice
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Patent number: 7838712Abstract: Disclosed is a method for steam-cracking naphtha, according to which a charge of hydrocarbons containing a portion of paraffinic naphtha, which is modified by adding a combination of a first component containing a portion of gasoline and a second component containing a portion of at least one hydrocarbonated refinery gas, and a paraffin-rich change containing at least one paraffin selected among propane, butane, or a mixture thereof are fed through a steam cracker in the presence of vapor. Also disclosed is a hydrocarbon composition suitable for steam cracking, containing a portion of a paraffinic naphtha, which is modified by adding a combination of a first component containing a portion of gasoline and a second component containing a portion of at least one hydrocarbonated refinery gas and a paraffin-rich charge containing at least one paraffin selected among propane, butane, or a mixture thereof.Type: GrantFiled: January 9, 2003Date of Patent: November 23, 2010Assignees: Total Petrochemicals Research Feluy, Total Raffinage MarketingInventors: François Bouvart, Robert Duchesnes, Claude Gutle
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Patent number: 7829752Abstract: A process for making lower olefins from a heavy hydrocarbon feed by use of a combination of thermal cracking and vapor-liquid separation, and, then, pyrolytically cracking the light fraction of the thermally-cracked heavy hydrocarbon feed to thereby produce a lower olefin product.Type: GrantFiled: March 22, 2007Date of Patent: November 9, 2010Assignee: Shell Oil CompanyInventors: Arthur James Baumgartner, Danny Yuk-Kwan Ngan
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Patent number: 7820035Abstract: A process for cracking heavy hydrocarbon comprising heating the heavy hydrocarbon feedstock, mixing the heavy hydrocarbon feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase, separating and cracking the vapor phase, and cooling the product effluent in a transfer line exchanger, wherein the amount of the fluid and/or the primary dilution steam stream mixed with the heavy hydrocarbon feedstock is varied in accordance with at least one selected operating parameter of the process, such as the temperature of the flash stream before entering the flash/separator vessel.Type: GrantFiled: February 28, 2005Date of Patent: October 26, 2010Assignee: ExxonMobilChemical Patents Inc.Inventors: James N. McCoy, David B. Spicer, Richard C. Stell
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Patent number: 7807860Abstract: The present invention provides a reactor design that enables an auto-thermal cracking process to be conducted at any suitable pressure wherein the gaseous reactants are preheated separately before mixing and then presented to the reaction zone in a uniformly distributed manner.Type: GrantFiled: February 6, 2004Date of Patent: October 5, 2010Assignee: Ineos Europe LimitedInventors: Derek Alan Colman, Michael John Alexander Matthewman, Ian Allan Beattie Reid, Vaughan Clifford Williams, William Terence Woodfin
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Patent number: 7799963Abstract: A cracking tube (50) for use in thermal cracking furnaces for producing ethylene or the like has fins (1) formed on an inner surface thereof and inclined with respect to an axis of the tube for stirring a fluid inside the tube. The fins are arranged discretely on one or a plurality of helical loci, and the tube inner surface has regions (ZB) wherein no fins are present over the entire axial length of the tube from one axial end of the tube to the other axial end thereof.Type: GrantFiled: March 3, 2009Date of Patent: September 21, 2010Assignee: Kubota CorporationInventors: Masahiro Inui, Kaoru Hamada, Kenji Otsubo
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Patent number: 7767170Abstract: A process is provided for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, optionally further heating the mixture, flashing the mixture within a flash/separation vessel to form a vapor phase and a liquid phase, partially condensing the vapor phase by contacting with a condenser within the vessel, to condense at least some coke precursors within the vapor while providing condensates which add to the liquid phase, removing the vapor phase of reduced coke precursors content as overhead and the liquid phase as bottoms, heating the vapor phase, cracking the vapor phase in a radiant section of a pyrolysis furnace to produce an effluent comprising olefins, and quenching the effluent and recovering cracked product therefrom. An apparatus for carrying out the process is also provided.Type: GrantFiled: June 16, 2006Date of Patent: August 3, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Richard C. Stell, George Stephens, Jennifer L. Bancroft, John R. Messinger
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Patent number: 7763763Abstract: The present invention provides a process for the production of olefins wherein a synthetic naphtha is passed to a steam cracker. The synthetic naphtha is derived from the fractionation of a Fischer-Tropsch product stream. The Fischer-Tropsch product stream may be separated into a lighter fraction and a heavy fraction and the heavy fraction may be hydrotreated prior to fractionation. Optionally the synthetic naphtha may be hydrogenated to produce a saturated synthetic naphtha which can then be subsequently passed to the steam cracker.Type: GrantFiled: November 5, 2002Date of Patent: July 27, 2010Assignee: BP Exploration Operating Company LimitedInventor: Josephus Johannes Helena Maria Font Freide
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Patent number: 7744747Abstract: A method for thermally cracking a feed composed of whole crude oil and/or natural gas condensate using a partitioned vaporizer to gasify the feed before cracking same.Type: GrantFiled: January 2, 2008Date of Patent: June 29, 2010Assignee: Equistar Chemicals, LPInventor: Richard B. Halsey
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Patent number: 7718052Abstract: A process for independently and concurrently cracking at least two different hydrocarbon feedstocks to olefins. The process is carried out in a furnace for cracking hydrocarbon feed which has at least a first and second independent radiant cracking zone to produce a first cracked product and second cracked product that are separately withdrawn from the furnace.Type: GrantFiled: October 9, 2007Date of Patent: May 18, 2010Assignee: Stone & Webster Technology, Inc.Inventors: John Brewer, David Brown, Svend Rumbold
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Patent number: 7718840Abstract: Disclosed is a process for producing light olefins from hydrocarbon feedstock. The process is characterized in that a porous molecular sieve catalyst consisting of a product obtained by evaporating water from a raw material mixture comprising a molecular sieve with a framework of Si—OH—Al— groups, a water-insoluble metal salt, and a phosphate compound, is used to produce light olefins, particularly ethylene and propylene, from hydrocarbon, while maintaining excellent selectivity to light olefins. According to the process, by the use of a specific catalyst with hydrothermal stability, light olefins can be selectively produced in high yield with high selectivity from hydrocarbon feedstock, particularly full-range naphtha. In particular, the process can maintain higher cracking activity than the reaction temperature required in the prior thermal cracking process for the production of light olefins, and thus, can produce light olefins with high selectivity and conversion from hydrocarbon feedstock.Type: GrantFiled: June 27, 2006Date of Patent: May 18, 2010Assignees: SK Energy Co., Ltd., Korea Research Institute of Chemical TechnologyInventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Kwang An Ko, Na Young Kang
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Patent number: 7718839Abstract: A process for making lower olefins from a heavy hydrocarbon feed by use of a combination of two vapor-liquid separation devices, and, then, pyrolytically cracking the light fraction of the heavy hydrocarbon feed to thereby produce a lower olefin product.Type: GrantFiled: March 22, 2007Date of Patent: May 18, 2010Assignee: Shell Oil CompanyInventors: Arthur James Baumgartner, Danny Yuk-Kwan Ngan
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Patent number: 7683231Abstract: A catalyst system capable of supporting combustion beyond the fuel rich limit of flammability comprising a catalytic component, a first support and a second support and wherein the catalytic component is present on both the first and the second support, and a process for the production of an olefin, said process comprising passing a mixture of a hydrocarbon and an oxygen-containing gas over said catalyst system to produce said olefin. The first support and the second support must differ in at least one of the following aspects: support material, support type and/or structural dimension.Type: GrantFiled: May 18, 2004Date of Patent: March 23, 2010Assignee: Ineos Europe LimitedInventors: Ian Allan Beattie Reid, Vaughan Clifford Williams