Abstract: The invention features methods for producing isoprene from cultured cells wherein the cells in the stationary phase. The invention also provides compositions that include these cultured cells and/or increased amount of isoprene. The invention also provides for systems that include a non-flammable concentration of isoprene in the gas phase. Additionally, the invention provides isoprene compositions, such as compositions with increased amount of isoprene or increased purity.
Type:
Grant
Filed:
January 14, 2013
Date of Patent:
December 9, 2014
Assignees:
Danisco US Inc., The Goodyear Tire & Rubber Company
Inventors:
Anthony R. Calabria, Marguerite A. Cervin, Gopal K. Chotani, Richard La Duca, Joseph C. McAuliffe, Michael C. Miller, Timothy A. Sabo, Karl J. Sanford, Erin L. Spring, Gregory M. Whited
Abstract: A method of isolating and purifying cucurbitacin is described. The method involves providing a cucurbitacin-containing liquid obtained from plant matter containing cucurbitacin, which liquid is then sequentially extracted with a non-polar solvent and then a moderately polar solvent. In a preferred embodiment, the cucurbitacin is purified by flash-column chromatography.
Abstract: The invention relates to a process for providing fuels from biomass such as seed oils or plant fruits. Generally the process utilizes a metal catalyzed conversion to step to provide fuel mixtures with compositions that may be varied depending on conditions of temperature, pressure and time of reaction. Mixtures of hydrocarbons produced from limonene feedstocks include alicyclic, alkyl and aromatic species. Monocyclic aromatic compounds may be obtained in high yields depending on the reaction conditions employed.
Abstract: A process for the preparation of 2,6,10,15,19,23-hexamethyl tetracosane and the isomers thereof having a basic hexamethyl tetracosane structure is described. Therein the raw materials are vegetable triglyceride oils and fats or oleins thereof obtained by physical refining. Together with an optional prior refining step, the process comprises a fatty acid and unsaponifiable material separation step, a saponification step giving unsaturated hydrocarbons, a hydrogenation step and a final deparaffining and purification step.
Type:
Grant
Filed:
December 30, 1986
Date of Patent:
June 28, 1988
Assignee:
Hispano Quimica S.A.
Inventors:
Jose Maria Vila Peris, Miguel de los Santos Alamany Soler, Roberto Celades Colom
Abstract: A method of preparing a functionally terminated polymer comprising polymerizing a terpene or an oxygen derivative thereof having a double bond or conjugated double bond available for polymerization with an initiator having a grouping which provides, or is a precursor of, the functional termination for the polymer.
Type:
Grant
Filed:
August 14, 1984
Date of Patent:
January 14, 1986
Assignee:
The University of Manchester Institute of Science and Technology
Inventors:
Richard H. Still, John L. Cawse, John L. Stanford
Abstract: A process for the isomerization of a tertiary double bonded olefin having a hydrogen atom attached to a carbon atom vicinal to the tertiary carbon of the double bond comprises treating the olefin in a solution of dry liquid sulfur dioxide in the presence of a catalyst selected from oxygen, a hydroperoxide or a protic acid or mixtures thereof.
Abstract: There is disclosed a process for the conversion of terpenes to limonene which comprises contacting at least one terpene, selected from the group comprised of mono- and bi-cyclic unsaturated hydrocarbons having the formula C.sub.10 H.sub.16 with an alkali metal sulfide catalyst on a support at a temperature of 300.degree. to 450.degree. C.
Abstract: .alpha.-Thujene is prepared in high yields by isomerizing 1 mole of sabinene with 0.2 to 0.5 moles of an alkali metal, preferably lithium and 0.3 to 0.8 moles of a primary or secondary amine, preferably ethylenediamine. Formation of by-products such as p-cymene is minimized.
Abstract: d-3-Menthene of high optical purity is obtained by the selective isomerization/hydrogenation of d-isolimonene in the presence of minor amounts of a palladium catalyst at temperatures up to 200.degree. C. and pressures of preferably about 100-500 psig.
Type:
Grant
Filed:
December 11, 1979
Date of Patent:
February 3, 1981
Assignee:
SCM Corporation
Inventors:
James O. Bledsoe, Jr., Carlos G. Cardenas
Abstract: Non-conjugated para-menthadienes having one site of unsaturation at the 4(8)- or 8-position are hydrogenated to selectively form 3-menthene in the presence of a homogeneous ruthenium catalyst complex.
Type:
Grant
Filed:
January 22, 1979
Date of Patent:
May 20, 1980
Assignee:
SCM Corporation
Inventors:
James O. Bledsoe, Jr., Carlos G. Cardenas