Using Solid Material In Reaction Zone Patents (Class 60/219)
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Patent number: 11242295Abstract: The present invention provides a particle and a composition for e.g., hypergolic ignition of rocket propellant. The disclosed particle and the composition comprise an energetic fuel additive and an ignition agent wherein the ignition agent is deposited on a surface of the particle.Type: GrantFiled: October 13, 2016Date of Patent: February 8, 2022Assignee: NEWROCKET LTD.Inventors: Avihay Habibi, Zohar Schlagman, Moti Elyashiv
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Patent number: 9303591Abstract: Disclosed is a propulsion system and a rocket having the same. The propulsion system includes: a combustion tube having a propellant therein; a nozzle installed at a rear end of the combustion tube, and configured to discharge combustion gas generated when the propellant is ignited; and a nozzle separation unit coupled to the combustion tube and the nozzle, respectively, and configured to mount the nozzle to the combustion tube, and configured to separate the nozzle from the combustion tube as at least part thereof melts when reaching a preset temperature.Type: GrantFiled: April 17, 2013Date of Patent: April 5, 2016Assignee: AGENCY FOR DEFENSE DEVELOPMENTInventors: Byeong Yeol Park, Song Hoe Koo, Ji Chang Yoo, Young Dae Doh
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Publication number: 20150059314Abstract: According to one aspect, an apparatus and method for electrically igniting and throttling pyroelectric propellant, e.g., in a rocket engine, are provided. In one example, an apparatus includes an injector body for supplying an electrically ignitable propellant to a combustion chamber and a opposing electrodes. A first electrode may be included with the injector body and a second electrode positioned relative to the first electrode to cause ignition of the electrically ignitable propellant as the electrically ignitable propellant flows thereby.Type: ApplicationFiled: August 29, 2014Publication date: March 5, 2015Inventor: Michael D. MCPHERSON
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Patent number: 8789795Abstract: A propulsion system and method are described configured to exert a force upon a vehicle. The system includes a concentrated mass which may be discharged from the vehicle by a propellant typically via an ejection tube. The system is optimized so that the discharged concentrated-mass imparts a large impulse upon the vehicle. The system and method may be used to alter the momentum of vehicles for propulsion, attitude correction, vehicle separation and the like.Type: GrantFiled: March 3, 2010Date of Patent: July 29, 2014Assignee: Technion Research and Development Foundation Ltd.Inventors: Alon Gany, Dan Michales
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Patent number: 8776526Abstract: The present invention provides a motor including a combustion chamber, an oxidizer injector, a vortex generators and a nozzle. The combustion chamber can be used to dispose a solid fuel, and the oxidizer injector is used to control the flow rate of an oxidizer and to inject the oxidizer into the combustion chamber. The vortex generators is disposed on the inner wall of the combustion chamber for generating eddies to enhance the mixing of the fuel and the oxidizer. Additionally, the nozzle is connected with the combustion chamber for exhausting the gas generated by the combustion of the propellants.Type: GrantFiled: February 1, 2011Date of Patent: July 15, 2014Assignee: National Applied Research LaboratoriesInventors: Yen-Sen Chen, Jong-Shinn Wu, Tzu-Hao Chou
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Patent number: 8683933Abstract: The Device object of the present invention is a solid rocket motor integrated into a propulsion system. The system is designed to be effective for most type of transportation including airplanes, submarines, trains, and ships, such as oil tankers. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure.Type: GrantFiled: December 23, 2012Date of Patent: April 1, 2014Inventor: Mario Placido Portela
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Patent number: 8549850Abstract: According to one representative embodiment, an aspirator for cooling exhaust gas from an internal combustion engine includes a nozzle section, an expansion section, and an air entrainment section. The nozzle section is communicable in exhaust receiving communication with the internal combustion engine. The nozzle section includes a plurality of nozzles through which an exhaust gas stream is flowable. The expansion section is communicable in exhaust receiving communication with the plurality of nozzles. The air entrainment section is communicable in air supplying communication with the expansion section. The air is mixable with the exhaust gas within the expansion section.Type: GrantFiled: October 31, 2008Date of Patent: October 8, 2013Assignee: Cummins Filtration IP, Inc.Inventors: Arun Janakiraman, Shiming Feng
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Publication number: 20130097995Abstract: A system for controlling an object traveling through exoatmospheric space is disclosed herein. The system includes, but is not limited to, a pressure vessel, a pair of solid propellant grains associated with the pressure vessel that is configured to direct a gas into the pressure vessel during combustion, an exhaust nozzle that is in fluid communication with the pressure vessel, and a valve that is coupled with the exhaust nozzle and that is configured to selectively obstruct the gas from venting through the exhaust nozzle.Type: ApplicationFiled: October 25, 2011Publication date: April 25, 2013Applicant: General Dynamics Ordnance and Tactical Systems, Inc.Inventor: Richard W. Schroeder
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Patent number: 8407982Abstract: An end burning type gas generator includes a hollow cylindrical combustor, a propellant that is densely charged in the combustor concentrically and in a plurality of layers without leaving a large void in an internal cross section and that has the same sectional area in each of the layers, and an interstructure separating the plurality of layers from each other and connecting only at a turning portion at an axial end. The propellant end burns sequentially, progressing via the turning portion, beginning with an outermost layer or an innermost layer. The turning portion includes an end outer plate continuously surrounding ends of inner propellant and outer propellant, and a burning rate increasing member provided along the inner surface of the end outer plate to increase the burning rate of the propellant. The end outer plate is shaped such that the burning area at the turning portion remains substantially constant.Type: GrantFiled: March 13, 2009Date of Patent: April 2, 2013Assignee: IHI Aerospace Co., Ltd.Inventors: Takemasa Koreki, Ichiro Yamaguchi
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Patent number: 8387361Abstract: The present invention describes a hybrid rocket motor that includes a first solid reactant and at least one thrust nozzle and at least one moveable combustion control member within the hybrid rocket motor that restricts the contact of a first fluid reactant in the combustion chamber. In this way, it is then possible to regulate the exposure of the solid reactant to the fluid reactant and thus control thrust.Type: GrantFiled: December 7, 2006Date of Patent: March 5, 2013Assignee: Rocketone Aerospace Pty Ltd.Inventor: Sook Ying Ho
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Patent number: 8336287Abstract: A solid rocket motor includes a combustion chamber bounded by an outer casing, a propellant grain within the combustion chamber, and an igniter within the outer casing for igniting the propellant grain. A nozzle is coupled to the combustion chamber for releasing hot gasses evolved from burning the propellant grain to provide thrust for propelling the solid rocket motor. The propellant grain is a self-extinguishing propellant grain that includes at least one fuel, at least one oxidizing agent, at least one binder, and at least one surfactant that imparts the self-extinguishing property. The propellant grain provides a burning rate as a function of pressure that includes a negative pressure dependence portion, wherein the burning rate in the negative pressure dependence portion decreases with increasing pressure until a cutoff pressure is reached which results in extinguishment of the propellant grain.Type: GrantFiled: March 27, 2009Date of Patent: December 25, 2012Assignee: University of Central Florida Research Foundation, Inc.Inventors: Eric L. Petersen, Sudipta Seal, Matthew Stephens, David L. Reid, Rodolphe Carro, Thomas Sammet, Alex Lepage
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Publication number: 20120304620Abstract: A catalyst includes a carrier of essentially hafnia, up to an equal part zirconia, and optionally additional stabilizers, upon the surface of which is deposited an active metal suitable to promote the reaction of propellants to be used in gas generators and thrusters.Type: ApplicationFiled: June 1, 2011Publication date: December 6, 2012Applicant: AEROJET-GENERAL CORPORATIONInventors: Robert K. Masse, Silvano R. Saretto, Junli Liu
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Patent number: 8181444Abstract: A motor includes an annular solid fuel between an inside diameter and an outside diameter. The solid fuel has a series of radial notches that define segments of fuel between them. The notches allow for faster burning of the fuel, while still allowing structural integrity of the fuel segments to be retained during the burning process.Type: GrantFiled: September 29, 2008Date of Patent: May 22, 2012Assignee: Raytheon CompanyInventors: James H. Dupont, Richard D. Loehr, Robert N. Renz
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Patent number: 8131406Abstract: One embodiment is directed to a method for testing an aircraft prior to flight. The method includes receiving a user signal from a pre-flight test input source, the user signal indicating that a pilot of the aircraft has directed engine control circuitry, which is arranged to electronically control operation of a set of piston engines of the aircraft during flight, to begin testing the aircraft in an automated manner. The method includes, in response to the user signal, conducting a pre-flight test of the aircraft from the engine control circuitry. The method includes, upon completion of the pre-flight test, outputting a result of the pre-flight test from the engine control circuitry.Type: GrantFiled: April 9, 2008Date of Patent: March 6, 2012Assignee: Lycoming Engines, a division of Avco CorporationInventors: James Paul Morris, Charles Schneider
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Patent number: 8051640Abstract: A solid propellant thrust control system, method, and apparatus for controlling combustion of solid propellants in an opposing grains solid propellant rocket engine (OGRE) is provided. In particular, an opposing grains rocket engine and propulsion system is provided, in which actuator means connected are connected to solid propellant grains disposed in the pressure vessel of the engine. The actuator means are operable to selectively move the solid propellant grains together or apart relative to one another, such that the burning ends of the solid propellant grains decrease or increase relative to one another. This action controls the rate of combustion of the solid propellant grains by varying spacing distance between the burning ends of the solid propellant grains, and enables extinguishment and reignition of the OGRE. Further, a method is providing for controlling the burn rate of solid propellant grains undergoing combustion in an opposing grains rocket engine.Type: GrantFiled: May 9, 2008Date of Patent: November 8, 2011Inventors: Robert L Geisler, Kevin E Mahaffy
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Patent number: 7886519Abstract: Systems and methods of controlling solid propellant burn rate, propellant gas pressure, propellant gas pressure pulse shape, and propellant gas flow rate, rely on pulse width modulation of a control valve duty cycle. A control valve that is movable between a closed position and a full-open position is disposed downstream of, and in fluid communication with, a solid propellant gas generator. The solid propellant in the solid propellant gas generator is ignited, to thereby generate propellant gas. The control valve is moved between the closed position and the full-open position at an operating frequency and with a valve duty cycle. The valve duty cycle is the ratio of a time the control valve is in the full-open position to a time it takes the valve to complete one movement cycle at the operating frequency. The valve duty cycle is controlled to attain a desired solid propellant burn rate, propellant gas pressure, propellant gas pressure pulse shape, and/or propellant gas flow rate.Type: GrantFiled: March 7, 2007Date of Patent: February 15, 2011Assignee: Honeywell International Inc.Inventors: George T. Woessner, Stephen G. Abel, Ronald A. Peck, Mark H. Baker, Donald J. Christensen
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Publication number: 20110023449Abstract: There is disclosed a solid fuel rocket motor including a center-perforated solid fuel grain. The solid fuel grain may be adapted to burn outwardly from a center surface facing the center perforation when ignited by a primary igniter during a normal mode of operation. The solid fuel grain may be further adapted to burn longitudinally from an end face when ignited by a secondary igniter during a safety mode of operation.Type: ApplicationFiled: October 30, 2008Publication date: February 3, 2011Inventors: Richard D. Loehr, Gerald M. Turner, Jeremy C. Danforth
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Publication number: 20100077723Abstract: A motor includes an annular solid fuel between an inside diameter and an outside diameter. The solid fuel has a series of radial notches that define segments of fuel between them. The notches allow for faster burning of the fuel, while still allowing structural integrity of the fuel segments to be retained during the burning process.Type: ApplicationFiled: September 29, 2008Publication date: April 1, 2010Inventors: James H. Dupont, Richard D. Loehr, Robert N. Renz
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Patent number: 7647763Abstract: A vehicle includes at least one polyoxymethylene structural support member. The polyoxymethylene structural support member includes a polyoxymethylene component that is a propellant that provides thrust to the vehicle upon pyrolysis or combustion of the polyoxymethylene component of the product of pyrolysis of the polyoxymethylene component. The vehicle can be a satellite or other type of spacecraft.Type: GrantFiled: March 22, 2005Date of Patent: January 19, 2010Assignees: Physical Sciences, Inc., Alliant Techsystems Inc.Inventors: Prakash B. Joshi, Bernard L. Upschulte, Alan H. Gelb, B. David Green, Dean M. Lester, W. David Starrett, Ingvar A. Wallace
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Publication number: 20090320443Abstract: A solid propellant thrust control system, method, and apparatus for controlling combustion of solid propellants in an opposing grains solid propellant rocket engine (OGRE) is provided. In particular, an opposing grains rocket engine and propulsion system is provided, in which actuator means connected are connected to solid propellant grains disposed in the pressure vessel of the engine. The actuator means are operable to selectively move the solid propellant grains together or apart relative to one another, such that the burning ends of the solid propellant grains decrease or increase relative to one another. This action controls the rate of combustion of the solid propellant grains by varying spacing distance between the burning ends of the solid propellant grains, and enables extinguishment and reignition of the OGRE. Further, a method is providing for controlling the burn rate of solid propellant grains undergoing combustion in an opposing grains rocket engine.Type: ApplicationFiled: May 9, 2008Publication date: December 31, 2009Inventors: Robert L. Geisler, Kevin E. Mahaffy
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Publication number: 20090205311Abstract: An insensitive combined cycle missile propulsion system includes a solid fuel contained within a first section of the missile, a liquid oxidizer contained within a second section of the missile and a solid oxidizer contained within a third section of said missile. A first conduit has a first valve communicating the fuel and the oxidizer and a second conduit, spatially removed from the first conduit, has a second valve communicating the fuel and the oxidizer. An inlet system for delivering atmospheric oxygen for combustion with the fuel rich gases generated within the missile and a nozzle exhausts combustion products that result from combustion of the fuel, the liquid and solid oxidizers, and air.Type: ApplicationFiled: November 8, 2007Publication date: August 20, 2009Inventors: Melvin J. Bulman, Adam Siebenhaar
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Publication number: 20090056305Abstract: A scalable flat-panel nano-particle MEMS/NEMS thruster includes a grid having a plurality of electrodes to establish electrical fields. A liquid is disposed in a liquid reservoir of the grid. The liquid is positioned within the electrical fields. A plurality of nano-particles are suspended in the liquid. A plurality of MEMS and NEMS micron-size vias are disposed in the grid. The electrical fields extract the plurality of nano-particles from the liquid and accelerate the nano-particles in the vias to provide propulsion system thrust.Type: ApplicationFiled: October 6, 2006Publication date: March 5, 2009Inventors: Brian E. Gilchrist, Alec D. Gallimore, Michael Keidar, Louis Musinski, Thomas M. Liu
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Patent number: 7003942Abstract: The invention provides a system for passively controlling pressure oscillations of hydrodynamic origin in a solid propellant thruster comprising a body containing a charge of solid propellant, the system comprising at least one insert disposed in the thruster body transversely relative to the flow direction of the combustion gases of the solid propellant. The insert has an opening of non-axisymmetric shape so as to generate a three-dimensional effect on the flow and prevent axisymmetric turbulent modes from forming in the thruster. Thus, the control system of the invention serves to break the symmetry of the flow and thus prevents axisymmetric turbulence forming which is the source of instability that the present invention seeks to control. The present system is applicable to existing thrusters.Type: GrantFiled: August 27, 2003Date of Patent: February 28, 2006Assignees: Snecma Propulsion Solide, AVIO S.p.A.Inventors: Philippe Le Helley, Louis Jacques, Christophe Magniére, Gilles Uhrig, Bernard Bondon, Jean-Claude Tricot, Didier Boury, Marco Telara, Paolo Bellomi, Georgio Mastrangelo
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Patent number: 6957526Abstract: A pressure-actuated rocket system comprises a bottom base, a detonator and a rocket body. A top base is placed on a top surface of the bottom base. At least one through hole is located on a side of the top base and extended to an opening of the top surface. The hollow detonator has a closed and an opened ends. The rocket body is a bottle with fins. After soda powder is placed inside the detonator and vinegar is filled into the rocket body, the bottom base, the detonator and the rocket body are held inclined. The openings are aimed at the inclined bottom base in turn, the pressure-actuated rocket system is then turned upside down. Soda powder subsequently falls and reacts with vinegar, and gas is generated. A pressure accumulates inside the rocket body until it is high enough to shoot the rocket body up.Type: GrantFiled: July 14, 2004Date of Patent: October 25, 2005Inventor: Chitsan Lin
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Patent number: 6904749Abstract: A vehicle includes at least one polyoxymethylene structural support member. The polyoxymethylene structural support member includes a polyoxymethylene component that is a propellant that provides thrust to the vehicle upon pyrolysis or combustion of the polyoxymethylene component of the product of pyrolysis of the polyoxymethylene component. The vehicle can be a satellite or other type of spacecraft.Type: GrantFiled: October 17, 2003Date of Patent: June 14, 2005Assignee: Physical Sciences, Inc.Inventors: Prakash B. Joshi, Alan H. Gelb, Bernard L. Upschulte, B. David Green
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Patent number: 6807804Abstract: A hybrid rocket motor is provided with a precombustion chamber supplied with propellant from separate fuel and oxidizer sources. The propellant can be in the form of gas or liquid and injected substantially tangentially into the head end of the hybrid motor adjacent the oxidizer injector to form a propellant swirl. As the hybrid motor oxidizer is injected into the swirl, it is heated and gasified, and assumes a swirling motion which increases the oxidizer path length and thereby increases the dwell time of the oxidizer. The increased dwell time increases combustion efficiency and permits multiple restarts of the hybrid motor. The propellant may also be a combination of solid and fluid reactants. In one embodiment, the oxidizer injector is extended into the combustion chamber to form a toroidal precombustion chamber which has an annular nozzle adjacent a face of the oxidizer injector.Type: GrantFiled: September 25, 2003Date of Patent: October 26, 2004Assignee: Hy Pat CorporationInventors: Korey R. Kline, Kevin W. Smith
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Publication number: 20040068976Abstract: A hybrid rocket engine and a method for propelling a rocket utilizing a vortex flow field. The flow field includes an outer fluid vortex spiraling toward a closed end of the flow field generating apparatus and an inner fluid vortex substantially concentric with the outer vortex spiraling away from the closed end and toward an outlet opening in which the inner vortex spirals in the same direction as the outer vortex, but in the opposite axial direction. The invention also relates to a rocket propulsion system utilizing the flow field in which the propulsion system includes a combustion chamber with a fuel source and an oxidizer source that deliver the said fuel and said oxidizer to the said outer and inner vortexes in a manner to support a combustion process while flowing along the flow field.Type: ApplicationFiled: July 30, 2003Publication date: April 15, 2004Inventors: William H. Knuth, Martin J. Chiaverini, Daniel J. Gramer
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Patent number: 6679049Abstract: A hybrid rocket motor is provided with a precombustion chamber supplied with propellant from separate fuel and oxidizer sources. The propellant can be in the form of gas or liquid and injected substantially tangentially into the head end of the hybrid motor adjacent the oxidizer injector to form a propellant swirl. As the hybrid motor oxidizer is injected into the swirl, it is heated and gasified, and assumes a swirling motion which increases the oxidizer path length and thereby increases the dwell time of the oxidizer. The increased dwell time increases combustion efficiency and permits multiple restarts of the hybrid motor. The propellant may also be a combination of solid and fluid reactants. In one embodiment, the oxidizer injector is extended into the combustion chamber to form a toroidal precombustion chamber which has an annular nozzle adjacent a face of the oxidizer injector.Type: GrantFiled: January 22, 2002Date of Patent: January 20, 2004Assignee: Hy Pat CorporationInventors: Korey R. Kline, Kevin W. Smith
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Patent number: 6640536Abstract: A hybrid rocket motor includes a storage tank which stores an oxidizer under relatively low pressure, a turbopump preferably directly coupled to an outlet of the storage tank which pressurizes the oxidizer to a relatively high pressure, a combustion chamber including a solid fuel, and an injector between the turbopump and combustion chamber through which the oxidizer is injected into the combustion chamber. According to a preferred aspect of the invention, the turbopump is operated by an expander cycle of a heat exchanger. According to another preferred aspect of the invention, the fluid flowing through the heat exchanger is oxidizer tapped from the storage tank. A barrier is maintained between an oxidizer feed line from the turbopump and the injector until sufficient pressure is created by the turbopump to pump the oxidizer at the requisite pressure into the injector.Type: GrantFiled: January 22, 2002Date of Patent: November 4, 2003Assignee: Hy Pat CorporationInventors: Korey R. Kline, Kevin W. Smith, Eric E. Schmidt, Thomas O. Bales
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Patent number: 6632378Abstract: A nitrate ester plasticized energetic composition in which the binder is made of, prior to curing, lower alkylene glycol prepolymer blocks end-capped with ethylene glycol monomers and/or oligomers. The end-capped prepolymer blocks are preferably difunctional or trifunctional. The lower alkylene glycol are preferably propylene glycol, butylene glycol, and/or copolymers thereof. The difunctional end-capped alkylene glycol prepolymer blocks are cured with a diisocyanate or polyisocyanate. In the case of a trifunctional (or higher functional) end-capped alkylene glycol prepolymer block, preferably a diisocyanate is used to effect crosslinking.Type: GrantFiled: March 2, 2001Date of Patent: October 14, 2003Assignee: Alliant Techsystems Inc.Inventors: Ingvar A. Wallace, II, Jeffery Oyler
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Patent number: 6601380Abstract: A hybrid rocket engine and a method for propelling a rocket utilizing a vortex flow field. The flow field includes an outer fluid vortex spiraling toward a closed end of the flow field generating apparatus and an inner fluid vortex substantially concentric with the outer vortex spiraling away from the closed end and toward an outlet opening in which the inner vortex spirals in the same direction as the outer vortex, but in the opposite axial direction. The invention also relates to a rocket propulsion system utilizing the flow field in which the propulsion system includes a combustion chamber with a fuel source and an oxidizer source that deliver the said fuel and said oxidizer to the said outer and inner vortexes in a manner to support a combustion process while flowing along the flow field.Type: GrantFiled: September 26, 2001Date of Patent: August 5, 2003Assignee: Orbital Technologies CorporationInventors: William H. Knuth, Martin J. Chiaverini, Daniel J. Gramer
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Publication number: 20030015268Abstract: Novel catalysts capable of rendering both polar and non-polar organic fuels hypergolic with rocket-grade hydrogen peroxide are disclosed. These catalysts are complexes formed by reacting alkyl-substituted diamines or triamines, with metal salts of an aliphatic carboxylic acid or metal 1, 3-dione chelates. In addition, the use of various acetylenic compounds as stability enhancing additives and/or promoters is described.Type: ApplicationFiled: June 26, 2002Publication date: January 23, 2003Inventors: Thomas A. Dobbins, David B. Wiley
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Patent number: 6446427Abstract: The present invention relates to a method and device for controlling the solid fuel regression rate of a solid fuel ramjet engine. In a preferred embodiment of the present invention, pressure oscillations are excited using active, closed-loop control to vary the heat transfer, and in turn the regression rate of a solid fuel ramjet engine. The pressure oscillations are excited by introducing small disturbances into the shear layer. The disturbances are amplified in the shear layer and excite pressure oscillations. The disturbances are introduced at a certain phase relative to the pressure oscillations. This is accomplished by closed-loop control. By varying the phase, the amplitude of the pressure oscillations can also be varied, which in turn will vary the heat transfer, regression rate, and thrust level.Type: GrantFiled: July 18, 2000Date of Patent: September 10, 2002Assignee: The United States of America as represented by the Secretary of the NavyInventors: Kenneth Yu, Klaus C. Schadow, Kenneth Wilson, Timothy Parr
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Patent number: 6367244Abstract: A propulsion system with at least one storage chamber containing at least one solid propellant and at least one fluid propellant is disclosed. The fluid propellant is retained under pressurized conditions, such that depressurization of the storage chamber substantially homogeneously disperses the at least one solid propellant in the at least one fluid propellant. A mixed-phase propellant can thereby be fed to a combustion chamber. The pressurized conditions under which the at least one fluid propellant is retained can include supercritical or critical conditions, saturation conditions, and conditions sufficient to provide a compressed gas.Type: GrantFiled: May 9, 1997Date of Patent: April 9, 2002Assignee: Hy Pat CorporationInventors: Kevin W. Smith, Theodore C. Slack, Jr., Korey R. Kline, Thomas O. Bales, Jr.
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Patent number: 6241281Abstract: Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, sufficient oxidizing anion to balance the charge of the complex, and at least one cool burning organic nitrogen-containing compound. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas generating compositions and to permit efficient combustion of the binder. Such gas generating compositions are adaptable for use in gas generating devices such as automobile air bags.Type: GrantFiled: November 5, 1999Date of Patent: June 5, 2001Assignee: Cordant Technologies Inc.Inventors: Jerald C. Hinshaw, Daniel W. Doll, Reed J. Blau, Gary K. Lund
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Patent number: 6217682Abstract: An energetic solid rocket motor propellant having one or more plateau regions of low operating pressure exponent is disclosed. The propellant is formulated from ingredients including an energetic polyoxetane, an effective amount of a plasticizer, an inorganic oxidizer in at least two discrete particle size ranges, and a refractory oxide burn rate modifier.Type: GrantFiled: October 26, 1998Date of Patent: April 17, 2001Assignee: Cordant Technologies Inc.Inventor: Carol Jean Campbell
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Patent number: 6073438Abstract: A eutectic solution of ammonium nitrate and either aminoguanidiine nitrate (AGN) or guanidine nitrate (AN) in the form of a present pellet is used to generate a particulate-free, non-toxic, odorless and colorless gas that is useful wherever an immediate source of such gas is required, such as the inflation of an occupant restraint air bag. The use of the material in the form of a eutectic totally eliminates pellet cracking. Moreover, the addition of a minor amount of potassium nitrate to the eutectic solution eliminates the ammonium nitrate phase change due to temperature cycling without adversely affecting the pressed pellets' freedom from cracking due to said temperature cycling.Type: GrantFiled: February 10, 1998Date of Patent: June 13, 2000Assignee: Atlantic Research CorporationInventors: Robert S. Scheffee, Brian K. Wheatley
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Patent number: 5970703Abstract: Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the complex. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas generating compositions and to permit efficient combustion of the binder. Such gas generating compositions are adaptable for use in gas generating devices such as automobile air bags.Type: GrantFiled: September 22, 1997Date of Patent: October 26, 1999Assignee: Cordant Technologies Inc.Inventors: Jerald C. Hinshaw, Daniel W. Doll, Reed J. Blau, Gary K. Lund
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Patent number: 5909001Abstract: A high pressure pulsed gas source for accelerating a projectile along a gun barrel comprises a structure including a high voltage electrode for establishing axial electrical discharges in corresponding axial gaps behind an outlet where the projectile is located. Plasma flows at right angles to the discharges into a propellant mass that is converted into a high pressure component of the gas pulse. The gaps are arranged so that after the projectile moves away from its initial position and is in the barrel, power applied to the plasma via gaps close to the outlet is greater than power applied to the plasma via gaps farther from the outlet. To avoid damage to the gun, the gaps are arranged so power applied to the plasma is substantially the same in the discharges when plasma is initially produced. The gaps include walls that are eroded differently by the discharges so gap walls close to the outlet erode faster than gap walls farther from the outlet.Type: GrantFiled: February 5, 1997Date of Patent: June 1, 1999Assignee: General Dynamics Land Systems, Inc.Inventor: Yeshayahu Shyke A. Goldstein
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Patent number: 5850053Abstract: A eutectic solution of ammonium nitrate and either aminoguanidine nitrate (AGN) or guanidine nitrate (AN) in the form of a pressed pellet is used to generate a low particulate non-toxic, odorless and colorless gas that is useful wherever an immediate source of such gas is required, such as the inflation of an occupant restraint air bag. The use of the material in the form of a eutectic totally eliminates pellet cracking. Moreover, the addition of a minor amount of potassium perchlorate to the eutectic solution improves stability at 107.degree. for 400 hours, lowers the pressure exponent and increases the burn rate at 2000 psi.Type: GrantFiled: June 7, 1996Date of Patent: December 15, 1998Assignee: Atlantic Research CorporationInventors: Robert S. Scheffee, Brian K. Wheatley
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Patent number: 5811725Abstract: Hybrid rocket propellants are disclosed that contain azo compounds, i.e., compounds containing the group R--N.dbd.N--R' as part of their structure, where R and R' represent a variety of groups including aliphatic, alicyclic and heterocyclic groups. The azo compounds are mixed with the other solid components of the propellant grain and serve either as plasticizers, binders, fuels, or fillers. The effect of including the azo compounds is an increase in the regression rate of the grain as the propellant burns.Type: GrantFiled: November 18, 1996Date of Patent: September 22, 1998Assignee: Aerojet-General CorporationInventor: Karl Klager
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Patent number: 5771679Abstract: Solid rocket motor propellants which burn at at least one stable burn rate over at least one corresponding pressure range (i.e the burn rate v. pressure curve contains at least one area of low pressure exponent with respect to a normal curve) are described. The propellant compositions comprise a binder, from about 65% to about 90% by weight ammonium perchlorate, the ammonium perchlorate being of at least two distinct particle sizes; from about 0.3% to about 5.0% by weight refractory oxide selected from the group consisting of TiO.sub.2, Al.sub.2 O.sub.3, SiO.sub.2, SnO.sub.2, and ZrO.sub.2 ; and from about 5 to about 25% by weight metal, such as aluminum.Type: GrantFiled: December 5, 1996Date of Patent: June 30, 1998Assignee: Thiokol CorporationInventors: Robert H. Taylor, Jr., Carol J. Hinshaw
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Patent number: 5765361Abstract: A low-cost rocket or thruster has a low-cost propellant injector, in which fluid fuel and oxidizer are injected into a combustion chamber. The walls of the combustion chamber are protected from the high temperatures of the combustion by a grain of solid propellant, the surface of which tends to melt andor vaporize in the presence of combustion temperatures, and thereby protects the walls of the chamber. The low-cost propellant injector may not mix the fluid fuel and oxidizer effectively, so that pockets of noncombusted gas may occur within the chamber. The ratio of fluid fuel and oxidizer is selected to be slightly oxidizer-rich, so that any pockets of unburned gas tend to be oxygen-rich. When the pockets come into contact with the solid fuel, the excess oxygen combusts with the gaseous solid fuel, and when the mixture is near stoichiometric, the fluid fuel combusts.Type: GrantFiled: August 23, 1996Date of Patent: June 16, 1998Inventors: Herbert Stephen Jones, Harry Phillip Williams
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Patent number: 5762746Abstract: A composition consisting essentially of a polyphosphazene binder having the following repeating units: ##STR1## wherein n is from about 20 to about 50,000, A is selected from --O-- and --NH--, and R.sup.1 and R.sup.2 are independently selected from alkyl having from one to about 20 carbon atoms, aryl having from 6 to about 14 carbon atoms, alkaryl having from 7 to about 30 carbon atoms, any of the preceding moieties substituted with halogen, hydroxyl, alkoxy, aryloxy, or nitro groups, or any of the preceding moieties linked by ether or amine linkages. Combined with an organic fiber filler, this material provides an erosion resistant insulation composition for temporarily protecting the interior of a rocket motor combustion chamber from thermal damage while the rocket is firing.Type: GrantFiled: August 16, 1989Date of Patent: June 9, 1998Assignee: Thiokol CorporationInventors: James A. Hartwell, Dale E. Hutchens, Kenneth E. Junior, James D. Byrd
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Patent number: 5735118Abstract: Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the complex. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas generating compositions and to permit efficient combustion of the binder. Such gas generating compositions are adaptable for use in gas generating devices such as automobile air bags.Type: GrantFiled: August 16, 1996Date of Patent: April 7, 1998Assignee: Thiokol CorporationInventors: Jerald C. Hinshaw, Daniel W. Doll, Reed J. Blau, Gary K. Lund
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Patent number: 5727368Abstract: A method, device and composition for achieving ignition and sustained combustion using a solid consumable catalytic bed (CCB) is described. The CCB accomplishes this by decomposition of an injected fluid. Initially this reaction is catalytic or hypergolic in nature, eventually becoming entirely thermal as the CCB is consumed in the reaction generated. The CCB may be placed in a hybrid motor system such that the decomposed injected fluid will undergo combustion with the solid grain. When the injected fluid is high concentration hydrogen peroxide the catalytic materials of construction for the CCB are selected from the metallic hydride family, the manganese oxide family and the cuprocyanide family.Type: GrantFiled: March 28, 1996Date of Patent: March 17, 1998Inventors: Eric J. Wernimont, Scott E. Meyer, Mark C. Ventura
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Patent number: 5711146Abstract: A method for decomposing hydrogen peroxide which comprises contacting the hydrogen peroxide with a catalyst having a surface consisting of a mixture of ruthenium with at least one metal of the group consisting of iridium and platinum in which the ruthenium is about 20 to about 70 atom percent of said metals.Type: GrantFiled: December 4, 1964Date of Patent: January 27, 1998Assignee: Shell Oil CompanyInventors: Warren E. Armstrong, Alfred J. L. Toombs
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Patent number: 5592812Abstract: Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a cationic metal template, sufficient oxidizing anion to balance the charge of the complex, and a neutral ligand containing hydrogen and nitrogen. The complexes are formulated such that when the complex combusts nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. Such complexes are adaptable for use in gas generating devices such as automobile air bags.Type: GrantFiled: February 9, 1996Date of Patent: January 14, 1997Assignee: Thiokol CorporationInventors: Jerald C. Hinshaw, Daniel W. Doll, Reed J. Blau, Gary K. Lund
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Patent number: 5582001Abstract: The combustion of a hybrid engine is improved by continuously injecting into a precombustion chamber a hypergolic fluid such as triethyl aluminum which exothermically reacts with and vaporizes the oxidizer such as liquid oxygen. The prevaporized oxidizer evenly combusts the solid propellant grain to develop thrust.Type: GrantFiled: August 24, 1989Date of Patent: December 10, 1996Inventors: Michael D. Bradford, Roy J. Kniffen, Jr., Bevin C. McKinney
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Patent number: 5579634Abstract: Solid rocket motor propellant formulations are provided which are capable of burning at at least two selected burn rates. The burn rate is controlled by controlling the pressure at which the propellant burns. For example, it is possible to mechanically modify the container, such as a rocket motor casing, in which the propellant is held in order to modify the pressure under which the propellant burns. Alternatively, the propellant may be configured or molded such that the pressure changes at a chosen time due to the process of burning the propellant. The propellant is capable of burning at a relatively constant burn rate at a chosen pressure. Once the pressure changes which chosen limits, the burn rate of the propellant is rapidly modified to another relatively constant burn rate. The solid rocket motor propellant is formulated with the addition of from about 0.5% to about 4.0% TiO.sub.2. The specific operating pressures and burn rates can be selected by modifying the amount of TiO.sub.Type: GrantFiled: April 1, 1994Date of Patent: December 3, 1996Assignee: Thiokol CorporationInventor: Robert H. Taylor, Jr.