Abstract: The present invention includes a method for hydrogen clathrate hydrate synthesis. First, ice and hydrogen gas are supplied to a containment volume at a first temperature and a first pressure. Next, the containment volume is pressurized with hydrogen gas to a second higher pressure, where hydrogen clathrate hydrates are formed in the process.

Abstract: The methods and apparatus for transporting compressed gas includes a gas storage system having a plurality of pipes connected by a manifold whereby the gas storage system is designed to operate in the range of the optimum compressibility factor for a given composition of gas. The pipe for the gas storage system is preferably large diameter pipe made of a high strength material whereby a low temperature is selected which can be withstood by the material of the pipe. Knowing the compressibility factor of the gas, the temperature, and the diameter of the pipe, the wall thickness of the pipe is calculated for the pressure range of the gas at the selected temperature. The gas storage system may either be modular or be part of the structure of a vehicle for transporting the gas. The gas storage system further includes enclosing the pipes in an enclosure having a nitrogen atmosphere. A displacement fluid may be used to offload the gas from the gas storage system.

Abstract: This invention relates to the storage under pressure in a container and subsequent transport of the filled pressurized container of particular natural gas or natural gas-like mixtures that contain methane or natural gas plus an additive, and which mixtures have been refrigerated to less than ambient temperature. (This invention also relates to a similar mixture which has been created by the removal of methane or a lean gas from a richer natural gas mixture.

Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.

Abstract: A method of dispensing a liquid material from a source container which includes a blend of fluids of a first composition that normally fractionate upon boiling. A material of a second composition (different than that of the first composition) and capable of maintaining the first composition of the material remaining in the source container is added to the source container during the transfer of liquid from the source container. This addition of a material of a second composition to the supply container during the transfer can minimize and/or even eliminate fractionation of the liquid in the source tank.

Abstract: An apparatus for dispensing an odorant to a hydrogen gas includes at least one container, each container having an interior volume. At least one odorant material is disposed in the interior volume of a first container, the odorant material having at least one detectable odor. At least one hydrogen storage material is disposed in the interior volume of the first container or the interior volume of a second container.

Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus, a cryosorptive storage apparatus, and a fuel recycle loop. Methods and devices that allow for an energy efficient release of hydrogen from the cryosorptive apparatus are described. At the outset of a fuel release, the cryosorptive hydrogen storage apparatus contains cold, pressurized hydrogen. Release of hydrogen from the storage apparatus is a process that consumes heat, thereby drawing down both the temperature and pressure. Heat can be provided to the cryosorptive storage apparatus by various direct approaches, or through the influx of warm, recycled hydrogen.

Abstract: The present invention relates to methods and systems for densifying liquids, specifically the densification of cryogenic propellants. A preferred system of the present invention subcools and densifies liquid propellants by utilizing a countercurrent gas or liquid flow. The countercurrent flow preferably utilizes a gas having a lower boiling point than the propellants. A packed tower may then be used, at or above atmospheric pressure, to introduce the countercurrent flow to the propellant. This methodology avoids the costs and problems associated with subatmospheric operation. A preferred embodiment is directed toward the densification of liquid oxygen, with a similar embodiment directed toward the simultaneous densification of liquid oxygen and liquid hydrogen. Systems and methods of the present invention may also be used to densify other liquids in similar fashion.

Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.

Abstract: A system to produce a densified fluid, and more particularly a densified propellant to be used in a launch vehicle. The system includes a vessel containing a first fluid and an injection nozzle to inject a cooling fluid into the vessel. The first fluid in the vessel has a freezing temperature greater than the boiling point of the second fluid that is injected into it. The second fluid is injected into the first fluid and evaporates therefrom to cool the first fluid. An anti-icing chamber is placed around the injection nozzle and a third fluid is provided to the anti-icing chamber to form an interface which does not allow the first fluid to contact the injection nozzle. In this way, the second fluid can be substantially continuously provided through the injection nozzle to the first fluid to cool the first fluid. A heat exchanger can then be provided in the vessel to cool an additional material.

Abstract: A system to produce a densified fluid, and more particularly a densified propellant to be used in a launch vehicle. The system includes a vessel containing a first fluid and an injection nozzle to inject a cooling fluid into the vessel. The first fluid in the vessel has a freezing temperature greater than the boiling point of the second fluid that is injected into it. The second fluid is injected into the first fluid and evaporates therefrom to cool the first fluid. An anti-icing chamber is placed around the injection nozzle and a third fluid is provided to the anti-icing chamber to form an interface which does not allow the first fluid to contact the injection nozzle. In this way, the second fluid can be substantially continuously provided through the injection nozzle to the first fluid to cool the first fluid. A heat exchanger can then be provided in the vessel to cool an additional Material.

Abstract: The invention relates to a method for storing liquefied zeotropic gas mixtures. To ensure a composition of the liquid phase which meets specifications, the change of the gas phase is determined by means of a differential pressure transducer by comparing the pressure with a calibration mixture. The mixture composition of the liquid phase is regulated by subsequently metering in the mixture components which have the higher partial pressure.

Abstract: This invention relates to the storage under pressure in a container and subsequent transport of the filled pressurized container of particular natural gas or natural gas-like mixtures that contain methane or natural gas plus an additive, and which mixtures have been refrigerated to less than ambient temperature. (This invention also relates to a similar mixture which has been created by the removal of methane or a lean gas from a richer natural gas mixture.

Abstract: A hydrogen storage and supply apparatus is described. The apparatus has a container that includes a cold enclosure. A porous material capable of occluding hydrogen pervades the cold enclosure. The porous material contains a plurality of light elements including Be, B, C, N, O, F, Mg, P, S, Li, Na, Al, Si and Cl. The cold enclosure can have a temperature in a range between about 30K and 270K and can withstand pressures up to about 50 bara. The container can have a layered wall structure with at least two walls, and there can be a cavity between the walls, which can provide thermal insulation. A hydrogen-consuming system is described in which the hydrogen storage and supply apparatus is used to provide hydrogen to a hydrogen-fueled device. A hydrogen production and distribution system, which used the hydrogen storage and supply apparatuses is described. Methods of storing, supplying and using hydrogen are also described.

Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.

Abstract: A method for hydrogen storage includes providing water and hydrogen gas to a containment volume, reducing the temperature of the water and hydrogen gas to form a hydrogen clathrate at a first cryogenic temperature and a first pressure and maintaining the hydrogen clathrate at second cryogenic temperature within a temperature range of up to 250 K to effect hydrogen storage. The low-pressure hydrogen hydrate includes H2O molecules, H2 molecules and a unit cell including polyhedron cages of hydrogen-bonded frameworks of the H2O molecules built around the H2 molecules.

Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus, a cryosorptive storage apparatus, and a fuel recycle loop. Methods and devices that allow for an energy efficient release of hydrogen from the cryosorptive apparatus are described. At the outset of a fuel release, the cryosorptive hydrogen storage apparatus contains cold, pressurized hydrogen. Release of hydrogen from the storage apparatus is a process that consumes heat, thereby drawing down both the temperature and pressure. Heat can be provided to the cryosorptive storage apparatus by various direct approaches, or through the influx of warm, recycled hydrogen.

Abstract: A portable life support system includes a primary oxygen supply in thermal communication with a recirculated ventilation flow from a user. The primary oxygen supply has a solid adsorbent bed made of a molecular sieve that adsorbs oxygen at cryogenic temperatures and desorbs oxygen when heated. The primary oxygen supply freezes carbon dioxide and moisture in the recirculated ventilation flow. A wire mesh is adjacent to the primary oxygen supply to contain frozen carbon dioxide and moisture. A first ice chest is downstream of the primary oxygen supply to condition the temperature and humidity of the recirculated ventilation flow. A liquid cooled garment associated with the suit is in thermal communication with the first ice chest.

Abstract: A hydrogen containing nanostructure is provided, where the hydrogen is adsorbed to the nanostructure by physisorption. The nanostructure includes light elements, selected from the second and third rows of the periodic table. The nanostructure is formed as a layered network of light elements coupled with covalent sp2 bonds. The chemical composition of the nanostructure can be such that the desorption temperature of hydrogen is greater than the liquefaction temperature of nitrogen, 77 K. Further, a hydrogen storage system is provided, including a container and a nanostructured storage material within the container, wherein the nanostructured storage material includes light elements, and the nanostructured storage material is capable of adsorbing hydrogen by physisorption. The hydrogen storage system can include a liquid nitrogen based cooling system, capable of cooling the nanostructured storage material below the desorption temperature of hydrogen.

Abstract: A hydrogen storage and transportation system is composed of hydrogen storage alloy, a storage tank, a control valve unit and a heat exchange system, wherein the hydrogen storage alloy stores hydrogen in a solid state, the storage tank is loaded with hydrogen storage alloy, the control valve unit is a passage to control hydrogen flow, and the heat exchange system regulates the pressure and flow rate for the hydrogen storage alloy to absorb and release hydrogen. The system enables hydrogen storage in low pressure and high density. Thus, the system also facilitates hydrogen transportation with dual performance in both safety and efficiency. The system will establish a foundation for future hydrogen energy industry.

Abstract: A hydrogen storage and supply apparatus is described. The apparatus has a container that includes a cold enclosure. A porous material capable of occluding hydrogen pervades the cold enclosure. The porous material contains a plurality of light elements including Be, B, C, N, O, F, Mg, P, S, Li, Na, Al, Si and Cl. The cold enclosure can have a temperature in a range between about 30K and 270K and can withstand pressures up to about 50 bara. The container can have a layered wall structure with at least two walls, and there can be a cavity between the walls, which can provide thermal insulation. A hydrogen-consuming system is described in which the hydrogen storage and supply apparatus is used to provide hydrogen to a hydrogen-fueled device. A hydrogen production and distribution system, which used the hydrogen storage and supply apparatuses is described. Methods of storing, supplying and using hydrogen are also described.

Abstract: A vessel for retaining cryogens in the form of a flexible liner for compliably retaining a cryogen and designed for controlled release of vapors generated by the cryogen. The improved flexible liner is biodegradable, with the incorporation of the biodegradable component within the resin being accomplished without adversely affecting the properties of the film at cryogenic temperatures. A preferred biodegradable film consists of a polyester comprising butane 1,4-diol and adipic acid to which a controlled quantity of terephthalic acid has been added.

Abstract: A method is provided, in which directly generated and/or indirectly formed and storable heat energy is stored in a mobile container-like latent-heat storage unit capable of being warehoused and of being delivered, the latent-heat storage unit being transported by means of a transport unit to at least one heat-energy reception unit and being arranged there in suitable form on or in the heat-energy reception unit. The possibility is thus afforded, for the first time, of transporting and utilizing heat energy over relatively long distances flexibly and on demand, but also extremely profitably.

Abstract: The present invention relates to methods and systems for densifying liquids, specifically the densification of cryogenic propellants. A preferred system of the present invention subcools and densifies liquid propellants by utilizing a countercurrent gas or liquid flow. The countercurrent flow preferably utilizes a gas having a lower boiling point than the propellants. A packed tower may then be used, at or above atmospheric pressure, to introduce the countercurrent flow to the propellant. This methodology avoids the costs and problems associated with subatmospheric operation. A preferred embodiment is directed toward the densification of liquid oxygen, with a similar embodiment directed toward the simultaneous densification of liquid oxygen and liquid hydrogen. Systems and methods of the present invention may also be used to densify other liquids in similar fashion.

Abstract: A hydrogen containing nanostructure is provided, where the hydrogen is adsorbed to the nanostructure by physisorption. The nanostructure includes light elements, selected from the second and third rows of the periodic table. The nanostructure is formed as a layered network of light elements coupled with covalent sp2 bonds. The chemical composition of the nanostructure can be such that the desorption temperature of hydrogen is greater than the liquefaction temperature of nitrogen, 77 K. Further, a hydrogen storage system is provided, including a container and a nanostructured storage material within the container, wherein the nanostructured storage material includes light elements, and the nanostructured storage material is capable of adsorbing hydrogen by physisorption. The hydrogen storage system can include a liquid nitrogen based cooling system, capable of cooling the nanostructured storage material below the desorption temperature of hydrogen.

Abstract: An apparatus for measuring electromagnetic characteristics includes a sample rod with a sample fixed to a lower part thereof, a helium 3 refrigerator, in which the sample rod is inserted, having a main pipe that forms around the sample rod a space that is cooled by helium 3, a device for supplying helium 3 to the helium 3 refrigerator, an inner tube portion, into which the main pipe is inserted, that supports at an upper part thereof the refrigerator, an outer tube that cools an outer periphery of the inner tube with helium, a liquid helium container that supplies liquid helium to the outer tube, and a device for measuring the electromagnetic characteristics of the sample.

Abstract: A system stores densely dissolved methane-base gas and supplies gas of a predetermined composition. A container (10) stores methane-base gas dissolved in hydrocarbon solvent and supplies it to means for adjusting composition, through which an object of regulated contents is obtained. Preferably, the means for adjusting composition is means for maintaining the tank in a supercritical state, or piping (48) for extracting substances at a predetermined ratio from the gas phase (12) and liquid phase (16) in the container.

Abstract: A system stores densely dissolved methane-base gas and supplies gas of a predetermined composition. A container (10) stores methane-base gas dissolved in hydrocarbon solvent and supplies it to means for adjusting composition, through which an object of regulated contents is obtained. Preferably, the means for adjusting composition is means for maintaining the tank in a supercritical state, or piping (48) for extracting substances at a predetermined ratio from the gas phase (12) and liquid phase (16) in the container.

Abstract: A method for hydrogen storage includes providing water and hydrogen gas to a containment volume, reducing the temperature of the water and hydrogen gas to form a hydrogen clathrate at a first cryogenic temperature and a first pressure and maintaining the hydrogen clathrate at second cryogenic temperature within a temperature range of up to 250 K to effect hydrogen storage. The low-pressure hydrogen hydrate includes H2O molecules, H2 molecules and a unit cell including polyhedron cages of hydrogen-bonded frameworks of the H2O molecules built around the H2 molecules.

Abstract: A complete infrastructure system for the generation, storage, transportation, and delivery of hydrogen which makes a hydrogen ecosystem possible. The infrastructure system utilizes high capacity, low cost, light weight thermal hydrogen storage alloy materials having fast kinetics. Also, a novel hydrogen storage bed design which includes a support/heat-transfer component which is made from a highly porous, high thermal conductivity, solid material such as a high thermal conductivity graphitic foam. Finally a material including at least one particle having atomically engineered local chemical and electronic environments, characterized in that the local environments providing bulk nucleation.

Abstract: A dewar for SQUID is provided. In the dewar for SQUID, an amount of leak gas discharged from absorbent arranged in the upper portion higher than the liquid surface level of liquid helium is small even if the liquid surface level of the liquid helium is lowered.

Abstract: A densification and storage system for fluids is provided by multitudes of closely spaced parallel planes of adsorptive material (88) that is contained within a substantially impervious barrier layer (2). In normal pressure-containing embodiments, reinforcement (4) is wrapped upon the impervious barrier layer (2) to increase the burst strength of the assembly that results. In higher pressure containing embodiments, material (88) provides reinforcement of barrier layer (2).

Abstract: The gas storage method comprises a step of keeping a gas to be stored and an adsorbent in a vessel at a low temperature below the liquefaction temperature of the gas to be stored so that the gas to be stored is adsorbed onto the adsorbent in a liquefied state, a step of introducing into the vessel kept at the low temperature a gaseous or liquid medium with a freezing temperature that is higher than the above-mentioned liquefaction temperature of the gas to be stored, for freezing of the medium, so that the gas to be stored which has been adsorbed onto the adsorbent in a liquefied state is encapsulated by the medium which has been frozen, and a step of keeping the vessel at a temperature higher than the liquefaction temperature and below the freezing temperature.

Abstract: A system achieving a high density of transported natural gas by compressing it to high pressures typically above 5 MPa to transport the gas in a modified composition that permits a very low compressibility factor at near ambient temperature either above or below. This reduces greatly the size of the cooling systems that are required. In some cases cooling of the compressed gas may be achieved in a simple heat exchanger cooled by air or water. The transport of the gas takes place in self propelled ships or non-self propelled barges fitted with a cargo containment system capable of storing the cargo at high pressures, typically above 5 MPa and usually not above 25 MPa. The transport vessel may carry a store of higher molecular weight gases (c2 through c7) that when mixed with the incoming cargo results in a molecular weight of the mixture of at least 22 and possibly as high as 28 or higher.

Abstract: The gas storage method comprises a step of keeping a gas to be stored and an adsorbent in a vessel at a low temperature below the liquefaction temperature of the gas to be stored so that the gas to be stored is adsorbed onto the adsorbent in a liquefied state, a step of introducing into the vessel kept at the low temperature a gaseous or liquid medium with a freezing temperature that is higher than the above-mentioned liquefaction temperature of the gas to be stored, for freezing of the medium, so that the gas to be stored which has been adsorbed onto the adsorbent in a liquefied state is encapsulated by the medium which has been frozen, and a step of keeping the vessel at a temperature higher than the liquefaction temperature and below the freezing temperature.

Abstract: A specimen chamber for storing materials in a dewar vessel that uses liquid cryogen is made of an open-celled porous thermoplastic material that is cryogenically compatible, such as an aerated polypropylene foam. The specimen chamber allows liquid cryogen to pass through it into a plastic foam and allows liquid cryogen in a vapor phase liquid state to pass from the plastic foam into it. The thermoplastic material of the specimen chamber acts as a filter to prevent particles or fragments of plastic foam from entering into the specimen chamber and also acts as a wicking device for rapid transfer of the liquid cryogen to the plastic foam.

Abstract: A containment system for samples of dangerous goods stored at cryogenic temperatures includes a bag made of a cryogenically compatible polymer film and a porous structural cartridge made of a polypropylene polymer compound for holding a plurality of sample receptacles separate from one another to comply with the standards of UN Class 6.2 certification. The porous structural cartridge has a cartridge base with a plurality of sample receptacle apertures for holding the plurality of sample receptacles. A cartridge cover mates with the cartridge base to enclose the plurality of sample receptacle apertures. Additional cartridge bases can be included as part of the porous structural cartridge. Each cartridge has sufficient absorbing capacity to absorb the entire contents of all of the sample receptacles held within its sample receptacle apertures.

Abstract: A gas storage and dispensing system comprising a vessel for holding a gas at a desired pressure. The vessel has a gas pressure regulator in its interior volume, to maintain pressure of dispensed gas at a desired pressure determined by the set point of the regulator. A second gas pressure regulator may be joined in series gas flow communication with the first gas pressure regulator, with the second gas pressure regulator being in initial contact with gas that is dispensed prior to its flow through the first gas pressure regulator, and with the set point pressure of the second gas pressure regulator being at least twice the set point pressure of the first gas pressure regulator.

Abstract: A method of storing a gas comprises absorbing a gas into or onto an absorbent medium, in one example by cryosorbing the gas. The cryosorbed gas is then encapsulated.

Abstract: A method and apparatus for economically storing and transporting coal mine methane gas is presented. The apparatus utilizes converted propane tankers. Standard propane tankers are filled with activated carbon or commercial carbons with a high volumetric methane adsorption capacity. The methane gas is compressed by a smaller compressor at the well and loaded into the converted tanker. At least three converted tankers are utilized in this method, one being loaded at the well, one discharging its methane gas at the end-user, and one being transported in between the well and the end-user. The truck used to transport the converted tankers has a bi-fuel system adding to the economy of the method and apparatus. Utilizing this apparatus and method of storage and transportation will reduce greenhouse emissions from the mine and from the power plants, and will provide the owner and operator with numerous tax credits and clean air incentives.

Abstract: A porous material inserted into a fluid-containing vessel reduces turbulence, heat transfer, and mass transfer in the fluid. The material may be used in a cryostat to reduce turbulence in a boiling cryogenic fluid. The cryostat may be used in an energy dispersive x-ray analysis unit to cool an x-ray detector.

Abstract: The present invention is a system and method for freeze granulation of a medium such as a biopharmeceutical product. The medium is put into a chamber and mixed using a pair of counter rotating agitators. The agitators have angled blades or paddles on them in order to induce motion in the medium parallel to the axis of the agitator shafts. A set of liquid nitrogen and liquid carbon dioxide nozzles are attached to the chamber. The liquid nitrogen nozzles spray a mist of liquid nitrogen into the medium. The liquid carbon dioxide nozzles spray carbon dioxide snow into the chamber. The liquid nitrogen and the carbon dioxide can be sprayed into the chamber at the same time or alternately.