External Refrigeration Circuit Patents (Class 62/623)
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Patent number: 11951435Abstract: A vapor separation system including a cooler having an inlet configured to receive an air-oil-water mixture, and an outlet configured to discharge separated oil and water in two different phases of matter. A first sensor is at the outlet of the cooler. A controller is communicatively coupled to the cooler, wherein the controller is configured to receive temperature feedback from the first sensor, and increase or reduce the amount of cooling, with the cooler and based on the temperature feedback, the oil-water mixture to a separation temperature configured to liquefy at least a portion of the oil in the air-oil-water mixture, while maintaining at least a portion of the water in the air-oil-water mixture in a vaporized state.Type: GrantFiled: October 19, 2022Date of Patent: April 9, 2024Assignee: GE INFRASTRUCTURE TECHNOLOGY LLCInventors: Victor Alfonso Gonzalez Tellez, Tho V. Nguyen, Haitham J. Khamissi, Oswaldo Alberto Sanchez Rubio, Douglas A. Jones
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Patent number: 11692771Abstract: A process for obtaining a product gas and product LNG having pressure P1 close to the atmospheric pressure from lean LNG, includes: a) branching the lean LNG to obtain a first flow and a second flow; b) cooling the second flow by using a refrigerant; c) branching a liquid flow derived from the cooled second flow to obtain refrigerant LNG and remaining LNG; d) subjecting the remaining LNG to pressure reduction and gas-liquid separation to obtain a gas phase flow and a liquid phase flow (product LNG) having pressure P1; e) subjecting the refrigerant LNG to pressure reduction; f) using a flow from the step e as the refrigerant; g) joining, before or after the step f, the gas phase flow having pressure P1 to a flow from the step e; h) liquefying a flow resulting from the steps f and g by pressure increase and cooling (through heat exchange with the first flow); i) increasing the first flow in pressure before the step h; j) obtaining the product gas by regasifying the first flow after the steps h and i; and k) joiType: GrantFiled: August 12, 2020Date of Patent: July 4, 2023Assignee: TOYO ENGINEERING CORPORATIONInventors: Taisei Yamamoto, Yasuyuki Yamamori
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Patent number: 11668522Abstract: A system and method for integrated heavy hydrocarbon removal in a liquefaction system having a lean natural gas source. An economizer located between a main cryogenic heat exchanger and a reflux drum is provided to cool an overhead vapor stream against a partially condensed stream. In addition, pressure of the natural gas feed stream is maintained into a scrub column. A pressure drop is provided by a valve located between the economizer and the reflux drum on a partially condensed stream withdrawn from the cold end of the warm section of the main cryogenic heat exchanger.Type: GrantFiled: July 21, 2016Date of Patent: June 6, 2023Assignee: Air Products and Chemicals, Inc.Inventors: Fei Chen, Mark Julian Roberts, Christopher Michael Ott, Annemarie Ott Weist
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Patent number: 11493270Abstract: A dual-mode LNG liquefier arrangement that is configurable to operate in a first mode broadly characterized as a low pressure, liquid nitrogen add LNG liquefier without turbo-expansion or a second mode broadly characterized as a low pressure, liquid nitrogen add LNG liquefier with turbo-expansion.Type: GrantFiled: May 14, 2020Date of Patent: November 8, 2022Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Neil M. Prosser, Richard M. Kelly, Aditya Vaze
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Patent number: 11358916Abstract: Described is a process for producing field butane. The process includes increasing the n-butane concentration in field butane. The process may include a concentration process that includes distillation and a thermal cracking process.Type: GrantFiled: April 23, 2019Date of Patent: June 14, 2022Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Vijay Dinkar Bodas, Sultan Al-Otaibe, Guillermo Leal, Mohammed Bismillah Ansari
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Patent number: 11353261Abstract: Light gases such as helium are extracted from a carbon dioxide-containing feed stream by distillation. Costly dehydration steps are avoided by pumping the liquid bottoms stream leaving the distillation column without vaporization so as to ensure that any water present in the feed remains in solution with the bulk stream leaving the process. This prevents any liquid phase water causing corrosion or solid ice or hydrates forming to plug the flow.Type: GrantFiled: October 31, 2019Date of Patent: June 7, 2022Assignee: Air Products and Chemicals, Inc.Inventors: Paul Higginbotham, John Eugene Palamara, Cory E. Sanderson, John H. Petrik
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Patent number: 11221176Abstract: A natural gas liquefaction method and system having integrated nitrogen removal. Recycled LNG gas is cooled in a separate and parallel circuit from the natural gas stream in the main heat exchanger. Cooled recycled gas and natural gas streams are directed to a nitrogen rectifier column after the warm bundle. The recycle stream is introduced to the rectifier column above the natural gas stream and at least one separation stage is located in the rectifier column between the recycle stream inlet and the natural gas inlet. The bottom stream from the rectifier column is directed to a cold bundle of the main heat exchanger where it is subcooled.Type: GrantFiled: August 14, 2018Date of Patent: January 11, 2022Assignee: Air Products and Chemicals, Inc.Inventors: Mark Julian Roberts, Fei Chen, Christopher Michael Ott, Annemarie Ott Weist
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Patent number: 10947465Abstract: A process for hydrocracking a hydrocarbon feed is provided. The process comprises hydrocracking the hydrocarbon feed to produce a first hydrocracking product stream, separating the first hydrocracking product stream to form a gas stream and a liquid stream, hydrocracking the liquid stream to produce a second hydrocracking product stream, separating the second hydrocracking product stream to form a first light stream and a first heavy stream comprising benzene, toluene, xylene, C9+ hydrocarbon, or a combination comprising at least one of the foregoing, purifying the gas stream to form a purified gas stream, and separating the purified gas stream to form at least two of a hydrogen stream, C1 stream, C2 stream, C3 stream, C4 stream, C5+ stream, or a combination comprising at least one of the foregoing.Type: GrantFiled: August 10, 2018Date of Patent: March 16, 2021Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Kenneth Francis Lawson, Andrea del Pilar NiƱo-Garcia
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Patent number: 10852060Abstract: A process comprising separating a hydrocarbon feed stream into a natural gas-rich stream and a liquefied petroleum gas (LPG)-rich stream using process equipment comprising only one multi-stage separation column, wherein the natural gas-rich stream has an energy content of less than or equal to about 1,300 British thermal units per cubic foot (Btu/ft3), and wherein the LPG-rich stream has a vapor pressure less than or equal to about 350 pounds per square inch gauge (psig). A process comprising separating a hydrocarbon feed stream into a top effluent stream and a LPG-rich stream, and subsequently expanding the top effluent stream to produce a natural gas-rich stream. An apparatus comprising a multi-stage separation column configured to separate a hydrocarbon feed stream into a top effluent stream and a LPG-rich stream, and an expander configured to expand the top effluent stream and produce a natural gas-rich stream.Type: GrantFiled: November 14, 2011Date of Patent: December 1, 2020Assignee: Pilot Energy Solutions, LLCInventor: Eric Prim
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Patent number: 10767922Abstract: A method and apparatus for liquefying a natural gas feed stream and removing nitrogen therefrom to produce a nitrogen-depleted LNG product, in which a natural gas feed stream is fed into the warm end of a main heat exchanger, cooled and at least partially liquefied, withdrawn from an intermediate location of the main heat exchanger and separated to form a nitrogen-enriched natural gas vapor stream and a nitrogen-depleted natural gas liquid stream, the liquid and vapor streams being reintroduced into an intermediate location of the main heat exchanger and further cooled in parallel to form a first LNG stream and a first at least partially liquefied nitrogen-enriched natural gas stream, respectively.Type: GrantFiled: June 19, 2017Date of Patent: September 8, 2020Assignee: Air Products and Chemicals, Inc.Inventors: Fei Chen, Yang Liu, Gowri Krishnamurthy, Christopher Michael Ott, Mark Julian Roberts
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Patent number: 10766835Abstract: A separation system for separating a feed stream comprising propylene and propane and a method for separating such feed stream. The separation system includes a distillation column for producing a light stream comprising propylene and a heavy stream comprising propane; a reboiler for reboiling a part of the first heavy stream to produce a boiled heavy stream; a condenser for cooling the light stream to produce a condensed light stream; and an absorption refrigerator for receiving water and providing chilled water, for receiving hot water from a waste heat source and providing a cooled hot water and for receiving cooling water and providing a heated cooling water. The absorption refrigerator is arranged such that the cooling of the water and the hot water occurs by the cooling water. The condenser is arranged such that the cooling of the light stream occurs by the chilled water from the absorption refrigerator.Type: GrantFiled: August 21, 2017Date of Patent: September 8, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventor: Joris Van Willigenburg
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Patent number: 10605522Abstract: Embodiments relate generally to systems and methods for pre-cooling a natural gas stream to a liquefaction plant. A system may comprise a compressor configured to receive a first natural gas stream at a first pressure and produce a second natural gas stream at a second pressure; an exchanger, wherein the exchanger is configured to receive the second natural gas stream as the second pressure and cool the second natural gas stream to produce a cooled natural gas stream; and an expander, wherein the expander is configured to receive the cooled natural gas stream and expand the cooled natural gas stream from the second pressure to a third pressure.Type: GrantFiled: September 1, 2017Date of Patent: March 31, 2020Assignee: Fluor Technologies CorporationInventors: John Mak, Jacob Thomas, Dhirav Patel, Steven Borsos
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Patent number: 10443930Abstract: Processes and systems are provided for removing nitrogen from a hydrocarbon-containing gas to thereby recover a liquid natural gas (LNG) stream. In particular, the processes and systems described herein can be used to efficiently separate methane from nitrogen, which is an undesirable byproduct found in many hydrocarbon-containing gases used to produce LNG. The processes and systems described herein can utilize various refrigerant systems to separate and produce the LNG.Type: GrantFiled: June 30, 2014Date of Patent: October 15, 2019Assignee: Black & Veatch Holding CompanyInventor: Hao Jiang
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Patent number: 10323495Abstract: Disclosed techniques include a method of obtaining an enhanced oil recovery fluid from a hydrocarbon reservoir, comprising producing a hydrocarbon stream from the hydrocarbon reservoir, separating an associated gas stream from the hydrocarbon stream, and condensing at least a portion of the associated gas stream to obtain an enriched hydrocarbon fluid suitable for injecting into a liquid layer of the hydrocarbon reservoir to enhance recovery of hydrocarbons from the hydrocarbon reservoir.Type: GrantFiled: March 9, 2017Date of Patent: June 18, 2019Assignee: ExxonMobil Upstream Research CompanyInventors: Jaime A. Valencia, David W. Maher, Robert D. Denton, Gary F. Teletzke, Michael W. Lin
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Patent number: 10267559Abstract: A system for liquefying a gas includes a liquefaction heat exchanger having a feed gas inlet adapted to receive a feed gas and a liquefied gas outlet through which the liquefied gas exits after the gas is liquefied in the liquefying passage of the heat exchanger by heat exchange with a primary refrigeration passage. A mixed refrigerant compressor system is configured to provide refrigerant to the primary refrigeration passage. An expander separator is in communication with the liquefied gas outlet of the liquefaction heat exchanger, and a cold gas line is in fluid communication with the expander separator. A cold recovery heat exchanger receives cold vapor from the cold gas line and liquid refrigerant from the mixed refrigerant compressor system so that the refrigerant is cooled using the cold vapor.Type: GrantFiled: September 12, 2017Date of Patent: April 23, 2019Assignee: Chart Energy & Chemicals, Inc.Inventors: Douglas A. Ducote, Jr., Timothy P. Gushanas, Mark R. Glanville
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Patent number: 10240863Abstract: The method is carried out for continuously producing a liquefied methane gas (LMG) from a pressurized mixed methane gas feed stream. It is particularly well adapted for use in relatively small LMG distributed production plant, for instance those ranging from 400 to 15,000 MT per year, and/or when the mixed methane gas feed stream has a wide range of nitrogen-content proportions, including nitrogen being substantially absent. The proposed concept can also be very useful in the design of medium-scale and/or large-size plants, including ones where the nitrogen content always remains above a certain threshold. The methods and arrangements proposed herein can mitigate losses of methane gas when venting nitrogen, for instance in the atmosphere.Type: GrantFiled: December 22, 2016Date of Patent: March 26, 2019Assignee: RTJ TECHNOLOGIES INC.Inventors: Charles Tremblay, Alain Roy, Simon Jasmin
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Patent number: 10113127Abstract: A mixed single refrigerant process for separating a nitrogen gas stream from a natural gas stream containing nitrogen to produce a nitrogen gas stream from a liquefied natural gas stream wherein the separated nitrogen gas stream is used as a refrigerant for the natural gas stream and wherein the mixed refrigerant provides cooling for the process.Type: GrantFiled: April 16, 2010Date of Patent: October 30, 2018Assignee: BLACK & VEATCH HOLDING COMPANYInventor: Brian C. Price
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Patent number: 9958200Abstract: A method is provided for separating off acid gases, in particular CO2 and H2S, from a hydrocarbon-rich fraction, in particular natural gas. The hydrocarbon-rich fraction is cooled and partially condensed. The resultant CO2-enriched liquid fraction is separated by rectification into a CO2-rich liquid fraction and a CO2-depleted gas fraction. The hydrocarbon-rich fraction is cooled close to the temperature of the CO2 triple point by means of a closed multistage refrigeration circuit. The refrigerant is a CO2 fraction of greater than 99.5% by volume. The rectification column is operated at a pressure between 40 and 65 bar. The reboiler of the rectification column is heated by means of a condensing refrigerant substream of the refrigeration circuit that is at a suitable pressure level.Type: GrantFiled: July 9, 2014Date of Patent: May 1, 2018Assignee: LINDE AKTIENGESELLSCHAFTInventors: Heinz Bauer, Claudia Gollwitzer
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Patent number: 9945604Abstract: A method for liquefying a natural gas feed stream and removing nitrogen therefrom, the method comprising passing a natural gas feed stream through a main heat exchanger to produce a first LNG stream, and separating a liquefied or partially liquefied natural gas stream in a distillation column to form nitrogen-rich vapor product, wherein a closed loop refrigeration system provides refrigeration to the main heat exchanger and to a condenser heat exchanger that provides reflux to the distillation column.Type: GrantFiled: April 24, 2014Date of Patent: April 17, 2018Assignee: Air Products and Chemicals, Inc.Inventors: Christopher Michael Ott, Gowri Krishnamurthy, Fei Chen, Yang Liu, Mark Julian Roberts
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Patent number: 9920986Abstract: Variable N2 content in feed gas ranging from 3 mol % to 50 mol % can be rejected from the process using a feed exchanger that is fluidly coupled with a cold separator and a single fractionation column to produce a nitrogen vent stream and streams that are suitable to be further processed for NGL recovery and LNG production.Type: GrantFiled: October 4, 2016Date of Patent: March 20, 2018Assignee: Fluor Technologies CorporationInventor: John Mak
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Patent number: 9829245Abstract: Provided is a natural gas liquefaction system including a natural gas storage unit, a liquefied natural gas storage unit, body, a pumping unit, a sub-cooling unit, and a first distributing and conveying unit.Type: GrantFiled: December 7, 2012Date of Patent: November 28, 2017Assignee: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Daejun Chang, Pal G Bergan
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Patent number: 9816754Abstract: A method and apparatus for liquefying a natural gas feed stream and removing nitrogen therefrom to produce a nitrogen-depleted LNG product, in which a natural gas feed stream is passed through main heat exchanger to produce a first LNG stream, which is separated to form a nitrogen-depleted LNG product and a recycle stream composed of nitrogen-enriched natural gas vapor, and in which the recycle stream is passed through main heat exchanger to produce a first LNG stream, separately from and in parallel with the natural gas feed stream, to produce a first at least partially liquefied nitrogen-enriched natural gas stream that is separated to provide a nitrogen-rich vapor product.Type: GrantFiled: April 24, 2014Date of Patent: November 14, 2017Assignee: Air Products and Chemicals, Inc.Inventors: Fei Chen, Yang Liu, Gowri Krishnamurthy, Christopher Michael Ott, Mark Julian Roberts
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Patent number: 9593883Abstract: Liquid carbon dioxide separated from sour gas is expanded by throttling decompression and is gas-liquid separated at a low temperature so as to be supplied for shipping or the improvement of petroleum recovery. Methane generated from a stranded gas well is allowed to pass as a coolant through liquid carbon dioxide separated and discharged from sour gas generated from the stranded gas well so as to cool liquid carbon dioxide. Disclosed is a module for treating carbon dioxide, and a treatment method thereof for supplying liquid carbon dioxide at a proper temperature and state conditions when there is a need for liquid carbon dioxide of very low temperature for the storage or collection of carbon dioxide, the improvement of petroleum recovery, or the like by cooling carbon dioxide using a material separated from sour gas of a stranded gas well as a coolant.Type: GrantFiled: August 22, 2012Date of Patent: March 14, 2017Assignee: DAEWOO SHIPBUILDING & MARINE ENGINEERING CO., LTD.Inventors: Byeong Yong Yoo, Sung Bae Kim, Il Guk Woo, Yeong Tae Oh, Hee Seung Na
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Patent number: 9487458Abstract: Variable N2 content in feed gas ranging from 3 mole % to 50 mole % can be rejected from the process using a feed exchanger that is fluidly coupled with a cold separator and a single fractionation column to produce a nitrogen vent stream and streams that are suitable to be further processed for NGL recovery and LNG production.Type: GrantFiled: February 28, 2014Date of Patent: November 8, 2016Assignee: Fluor CorporationInventor: John Mak
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Patent number: 9335091Abstract: Methods and systems for removing nitrogen during liquefaction of natural are provided. Methods of removing nitrogen include warming a predominantly methane stream in a methane cold box to provide a warmed predominantly methane stream; conducting at least a portion of the warmed predominantly methane stream from the methane cold box to a nitrogen removal unit comprising at least a first nitrogen removal column and a last nitrogen removal column, wherein the first nitrogen removal column is located upstream of the last nitrogen removal column; passing the warmed predominantly methane stream through the last nitrogen removal column to provide a refluxed warmed predominantly methane stream; and routing at least a portion of the refluxed warmed predominantly methane stream to the last nitrogen removal column.Type: GrantFiled: July 25, 2013Date of Patent: May 10, 2016Assignee: ConocoPhillips CompanyInventors: Wesley Roy Qualls, Qi Ma, Megan Victoria Evans, Karl Lee Herzog, Jame Yao, Mohan Chahal, Matt Calvin Gentry, Attilio Jose Praderio, Marc Thomas Bellomy, Satish Gandhi, Mike Wilkes, Will James
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Patent number: 9316434Abstract: This process includes the cooling of an introduction stream (72) inside an upstream heat exchanger (28). It includes the introduction of the cooled introduction stream (76) into a fractionating column (50) and the tapping at the bottom portion of the column (50) of the denitrided stream of hydrocarbons. It also includes the introduction of a stream (106) rich in nitrogen obtained from the head portion of the column (50) into a separation container (60) and the recovery of the head gaseous stream from the separation container (60) in order to form the stream (20) which is rich in helium. The liquid stream (110) is obtained from the bottom of the first separation container (60) is separated into a liquid nitrogen stream (18) and a first reflux stream (114) which is introduced as reflux into the head of the fractionating column (50).Type: GrantFiled: October 2, 2009Date of Patent: April 19, 2016Assignee: TECHNIP FRANCEInventors: Henri Paradowski, Sylvain Vovard
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Patent number: 9309172Abstract: The present invention provides a method of separating ethylene or ethane from a mixed gas containing ethylene and ethane using hydroquinone. According to the present invention, hydroquinone selectively forms a clathrate with ethylene, and thus it is possible to separate ethylene with high yield and purity through a single process.Type: GrantFiled: January 22, 2014Date of Patent: April 12, 2016Assignee: Korea Institute of Energy ResearchInventors: Seong-Pil Kang, Jong-Won Lee, Dongwook Lee, Yong Koo Kim
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Patent number: 9222724Abstract: The method provides liquefaction of a natural gas by carrying out the following stages: cooling the natural gas; feeding the cooled natural gas into a fractionating column so as to separate a methane-rich gas phase and a liquid phase rich in compounds heavier than ethane; and liquefying the methane-rich stream so as to obtain the liquid natural gas. According to the invention, the operating conditions in the fractionating column are so selected that said liquid phase comprises a molar proportion of methane ranging between 10% and 150% of the molar proportion of ethane.Type: GrantFiled: October 17, 2008Date of Patent: December 29, 2015Assignee: IFP Energies NouvellesInventors: BĆ©atrice Fischer, Gilles Ferschneider, Anne Claire Lucquin
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Patent number: 9121636Abstract: A system for removing a contaminant from a refrigerant stream employed in a closed-loop refrigeration cycle of an LNG facility. The system employs a distillation column to separate the refrigerant stream into a contaminant-rich and a contaminant-depleted stream, wherein the contaminant-depleted stream is subsequently returned to the closed-loop refrigeration cycle. The distillation column can include a reboiler and/or condenser. The reboiler and condenser can utilize one or more process streams from within the LNG facility to provide heating and/or cooling to the distillation column.Type: GrantFiled: November 16, 2006Date of Patent: September 1, 2015Assignee: ConocoPhillips CompanyInventors: Jon M. Mock, Weldon L. Ransbarger, James D. Ortego
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Patent number: 9050554Abstract: Device for compressing and drying gas includes a multistage compressor with a low pressure stage, a high pressure stage, and a pressure pipe; and an adsorption dryer with a drying zone and a regeneration zone. An intercooler is located between the low pressure stage and high pressure stage, and the device includes a heat exchanger with a main compartment with an inlet part and an outlet part for a first primary fluid. The ends of the tubes of the heat exchanger are connected to a separate inlet compartment and outlet compartment for each series of tubes. A first series of tubes forms a cooling circuit of the intercooler in order to heat up gas from the high pressure stage for the regeneration of the adsorption dryer.Type: GrantFiled: May 11, 2011Date of Patent: June 9, 2015Assignee: ATLAS COPCO AIRPOWERInventors: Stijn Jozef Rita Johanna Janssens, Uwe Pahner, Christophe Briers
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Patent number: 9045697Abstract: Hydrocarbon distillation columns with heat pumps and methods of operating them are described. The overhead stream is compressed to increase temperature so that it can be used both to heat the reboiler and to superheat the overhead stream before it enters the heat pump compressor.Type: GrantFiled: March 5, 2012Date of Patent: June 2, 2015Assignee: UOP LLCInventors: Clayton C. Sadler, Xin X. Zhu, Tokhanh N. Ngo, David J. Shecterle
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Patent number: 8667812Abstract: A process and an apparatus are disclosed for removing carbon dioxide from a hydrocarbon gas stream. The gas stream is cooled, expanded to intermediate pressure, and supplied to a fractionation tower at a top column feed position. The tower overhead vapor stream is compressed to higher pressure and cooled to partially condense it, forming a condensed stream. The condensed stream is expanded to intermediate pressure, used to subcool a portion of the tower bottom liquid product, then supplied to the tower at a mid-column feed position. The subcooled portion of the tower bottom liquid product is expanded to lower pressure and used to cool the compressed overhead vapor stream. The quantities and temperatures of the feeds to the fractionation tower are effective to maintain the overhead temperature of the fractionation tower at a temperature whereby the major portion of the carbon dioxide is recovered in the tower bottom liquid product.Type: GrantFiled: May 27, 2011Date of Patent: March 11, 2014Assignee: Ordoff Engineers, Ltd.Inventors: Kyle T. Cuellar, John D. Wilkinson, Hank M. Hudson
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Patent number: 8555673Abstract: The invention relates to a method and apparatus for separating a mixture containing carbon monoxide, nitrogen and hydrogen by cryogenic distillation in a separation system which includes a denitrification column and at least another column. The method can include separating the mixture in order to obtain a fluid enriched with carbon monoxide and containing nitrogen, separating the fluid in the denitrification column, pressurizing the carbon monoxide flow from the column in a compressor up to a high pressure, collecting a fraction of carbon monoxide flow to be used as a product, expanding an amount of the high-pressure carbon monoxide flow in a valve prior to supplying it to the denitrification column, and varying the flow expanded in the valve according to re-boiling needs of the denitrification column.Type: GrantFiled: December 12, 2007Date of Patent: October 15, 2013Assignee: L'Air Liquide, SociĆ©tĆ© pour l'Ćtude et l'Ćxploitation des ProcĆ©dĆ©s Georges ClaudeInventors: Arthur Darde, Antoine Hernandez
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Patent number: 8528361Abstract: A method for recovering C2 and higher weight hydrocarbons, or alternatively C3 and higher weight hydrocarbons, from low pressure gas, wherein the method avoids the need to significantly compress contaminated low pressure gas in most cases, and is robust in response to pressure and temperature variations in the low pressure gas feed.Type: GrantFiled: October 7, 2010Date of Patent: September 10, 2013Assignee: Technip USAInventors: Rajeev Nanda, Rahul Singh
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Patent number: 8413463Abstract: The present invention relates to an improved process for recovery of natural gas liquids from a natural gas feed stream. The process runs at a constant pressure with no intentional reduction in pressure. An open loop mixed refrigerant is used to provide process cooling and to provide a reflux stream for the distillation column used to recover the natural gas liquids. The processes may be used to recover C3+ hydrocarbons from natural gas, or to recover C2+ hydrocarbons from natural gas.Type: GrantFiled: June 11, 2012Date of Patent: April 9, 2013Assignee: Lummus Technology, Inc.Inventor: Michael Malsam
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Patent number: 8316665Abstract: Contemplated plants thermally integrate operation of a refinery component, and most preferably of a hydrocarbon splitter with LNG regasification to provide refrigeration duty and with a power cycle to provide the reboiler duty of the component. It should be noted that such configurations advantageously allow operation of the splitter at a reduced temperature and at reduced pressure, thereby increasing separation efficiency, while the power output is boosted using air intake chilling. Most notably, such process advantages are achieved by satisfying the heating duty of LNG regasification.Type: GrantFiled: March 21, 2006Date of Patent: November 27, 2012Assignee: Fluor Technologies CorporationInventor: John Mak
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Patent number: 8209997Abstract: The present invention relates to an improved process for recovery of natural gas liquids from a natural gas feed stream. The process runs at a constant pressure with no intentional reduction in pressure. An open loop mixed refrigerant is used to provide process cooling and to provide a reflux stream for the distillation column used to recover the natural gas liquids. The processes may be used to recover C3+ hydrocarbons from natural gas, or to recover C2+ hydrocarbons from natural gas.Type: GrantFiled: May 16, 2008Date of Patent: July 3, 2012Assignee: Lummus Technology, Inc.Inventor: Michael Malsam
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Publication number: 20120085128Abstract: A method for recovering C2 and higher weight hydrocarbons, or alternatively C3 and higher weight hydrocarbons, from low pressure gas, wherein the method avoids the need to significantly compress contaminated low pressure gas in most cases, and is robust in response to pressure and temperature variations in the low pressure gas feed.Type: ApplicationFiled: October 7, 2010Publication date: April 12, 2012Inventors: Rajeev Nanda, Rahul Singh
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Publication number: 20120085127Abstract: A method for recovering C2 and higher weight hydrocarbons, or alternatively C3 and higher weight hydrocarbons, from low pressure gas, wherein the method avoids the need to significantly compress contaminated low pressure gas in most cases, and is robust in response to pressure and temperature variations in the low pressure gas feed.Type: ApplicationFiled: October 7, 2010Publication date: April 12, 2012Inventors: Rajeev Nanda, Rahul Singh
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Patent number: 7856848Abstract: The present invention related to a flexible hydrocarbon gas separation process that could dehydrate the water-saturated hydrocarbon gas mixture and recover thereof the required higher hydrocarbons (NGL) therein with a controllable ethane recovery rate (ranging from >95% to <2%) while keeping high recovery rate of all other heavier components. The flexible process comprises the following steps: deep-cooling and dehydrating the raw gas and get the NGL condensate; flowing the deep-dehydrated gas into the flexible absorber to get the rich oil with desirable ethane content; completely demethanizing and partially deethanizing as desired the rich oil and the NGL condensate to get purified rich oil and purified NGL condensate, respectively; separating the NGL vapor from the purified rich oil; cooling and compressing the NGL vapor; mixing the NGL vapor with the purified NGL condensate; and liquefying the mixture to get the final NGL product.Type: GrantFiled: March 5, 2007Date of Patent: December 28, 2010Inventor: Yingzhong Lu
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Publication number: 20100175425Abstract: A method for cooling natural gas with a refrigerant, one non-limiting embodiment which includes: (A) compressing and cooling the refrigerant to a first pressure to form a compressed refrigerant; (B) splitting the compressed refrigerant into a first stream and a second stream both at the first pressure; (C) cooling the first stream to form a cooled first stream; (D) expanding the cooled first stream to a first expansion pressure to form an expanded first stream; (E) compressing the second stream to a second pressure higher than the first pressure, forming a higher pressure second stream; (F) cooling the higher pressure second stream to form a cooled second stream; (G) expanding the cooled second stream to a second expansion pressure to form an expanded second stream; and, (H) Cooling the natural gas with the expanded first stream and expanded second stream, forming a cooled natural gas stream.Type: ApplicationFiled: January 14, 2009Publication date: July 15, 2010Inventor: SUSAN T. WALTHER
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Patent number: 7713497Abstract: A natural gas liquid plant includes a separator (103) that receives a cooled low pressure feed gas (4), wherein the separator (103) is coupled to an absorber (108) and a demethanizer (110). Refrigeration duty of the absorber (108) and demethanizer (110) are provided at least in part by expansion of a liquid portion of the cooled low pressure feed gas (4) and an expansion of a liquid absorber bottom product (19), wherein ethane recovery is at least 85 mol % and propane recovery is at least 99 mol %. Contemplated configurations are especially advantageous as upgrades to existing plants with low pressure feed gas where high ethane recovery is desirable.Type: GrantFiled: August 15, 2002Date of Patent: May 11, 2010Assignee: Fluor Technologies CorporationInventor: John Mak
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Publication number: 20100107684Abstract: The invention relates to a process for liquefying a gas stream rich in methane, said process comprising: (a) providing said gas stream; (b) withdrawing a portion of said gas stream for use as a refrigerant; (c) compressing said refrigerant; (d) cooling said compressed refrigerant with an ambient temperature cooling fluid; (e) subjecting the cooled, compressed refrigerant to supplemental cooling; (f) expanding the refrigerant of (e) to further cool said refrigerant, thereby producing an expanded, supplementally cooled refrigerant; (g) passing said expanded, supplementally cooled refrigerant to a heat exchange area; and, (h) passing said gas stream of (a) through said heat exchange area to cool at least part of said gas stream by indirect heat exchange with said expanded, supplementally cooled refrigerant, thereby forming a cooled gas stream. In further embodiments for improved efficiencies, additional supplemental cooling may be provided after one or more other compression steps.Type: ApplicationFiled: March 4, 2008Publication date: May 6, 2010Inventor: Moses Minta
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Publication number: 20100037655Abstract: A method for recovering hydrogen from a gas stream is presented. This method includes introducing a feed gas stream comprising hydrogen and methane to a first cold box, thereby producing a first hydrogen-enriched stream, and a first methane-enriched stream; then introducing the first hydrogen-enriched stream to a first feed compressor, thereby producing a compressed first hydrogen-enriched stream. The method includes introducing the compressed first hydrogen-enriched stream to a second cold box, thereby producing a second hydrogen-enriched stream, and a second methane-enriched stream; then introducing the second hydrogen-enriched stream to a second feed compressor, thereby producing a compressed second hydrogen-enriched stream. The method includes introducing the compressed second hydrogen-enriched stream to a third cold box, thereby producing a third hydrogen-enriched stream, and a third methane-enriched stream.Type: ApplicationFiled: December 9, 2008Publication date: February 18, 2010Applicant: Air Liquide Process and Construction Inc.Inventor: Bhadra S. Grover
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Publication number: 20100000254Abstract: Provided is a method of producing gas hydrate at a low cost. An acid gas 3 is removed from a natural gas 1, and after dehydration 5 of accompanying water, part of heavy components which do not produce gas hydrate 10 are separated and removed under a relatively high temperature. Moreover, the rest of the heavy components are taken out in a gas hydrate production step 9 together with an excessive portion of light components not contributing to production of the gas hydrate 10, as a fuel gas 11 which is used as a cooling source or a power source for a cooling system in the gas hydrate production step 9.Type: ApplicationFiled: March 13, 2007Publication date: January 7, 2010Inventors: Masataka Hiraide, Kae Serizawa, Kikuo Nakamura, Nakaoka Makoto
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Publication number: 20090301131Abstract: A method of treating a hydrocarbon stream such as natural gas from a feed stream (10) comprising at least the steps of: a) passing the feed stream (10) through a distillation column (12) to provide a gaseous stream (20) and a C2+ liquid stream (30); b) compressing at least part of the gaseous stream (20) through one or more feed compressors (14, 16) to provide a compressed stream (40); and c) commonly driving (28) at least one of the feed compressors with one or more separate refrigerant compressors for one or more separate refrigerant circuits, by mechanically interconnecting said compressors.Type: ApplicationFiled: May 16, 2007Publication date: December 10, 2009Applicant: SHELL OIL COMPANYInventors: Hillegonda Bakker, Joannes Ignatius Geijsel, Mark Antonius Kevenaar
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Patent number: 7628035Abstract: In this method, the LNG stream is cooled using a refrigerating fluid in a first heat-exchanger. The refrigerating fluid is subjected to a second semi-open refrigeration cycle which is independent of the first cycle. The method comprises a step for introducing the stream of sub-cooled LNG into a distillation column and a step for recovering a stream of gas at the top of the column. The second refrigeration cycle comprises a step for forming a stream of refrigerating fluid from a portion of the top stream of gas, a step for compressing the stream of refrigerating fluid to a high pressure, then a step for expanding a portion of the stream of compressed refrigerating fluid in order to form a substantially liquid sub-cooling stream. The substantially liquid stream is evaporated in the first heat-exchanger.Type: GrantFiled: October 9, 2006Date of Patent: December 8, 2009Assignee: Technip FranceInventor: Henri Paradowski
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Publication number: 20090282864Abstract: The present invention relates to an improved process for recovery of natural gas liquids from a natural gas feed stream. The process runs at a constant pressure with no intentional reduction in pressure. An open loop mixed refrigerant is used to provide process cooling and to provide a reflux stream for the distillation column used to recover the natural gas liquids. The processes may be used to recover C3+ hydrocarbons from natural gas, or to recover C2+ hydrocarbons from natural gas.Type: ApplicationFiled: May 16, 2008Publication date: November 19, 2009Inventor: Michael Malsam
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Publication number: 20090277217Abstract: An LNG facility employing an enhanced nitrogen removal system that concentrates the amount of nitrogen in the feed stream to a nitrogen removal unit (NRU) to thereby increase the separation efficiency of the NRU. In one embodiment, the nitrogen removal system comprises a multistage separation vessel operable to separate nitrogen from a cooled natural gas stream. At least a portion of the resulting nitrogen-containing stream exiting the multistage separation vessel can be used as a refrigerant, processed to a nitrogen removal unit, and/or utilized as fuel gas for the LNG facility.Type: ApplicationFiled: May 8, 2008Publication date: November 12, 2009Applicant: CONOCOPHILLIPS COMPANYInventors: Weldon L. Ransbarger, J. Dale Ortego, JR.
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Patent number: 7610775Abstract: The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.Type: GrantFiled: July 8, 2005Date of Patent: November 3, 2009Assignee: Velocys, Inc.Inventors: Anna Lee Tonkovich, Wayne W. Simmons, Laura J. Silva, Dongming Qiu, Steven T. Perry, Thomas Yuschak, Thomas P. Hickey, Ravi Arora, Amanda Smith, Robert Dwayne Litt, Paul Neagle