Expansion Patents (Class 62/634)
  • Patent number: 11662141
    Abstract: Implementations described and claimed herein provide systems and methods for processing liquefied natural gas (LNG). In one implementation, a solvent is injected into a feed of natural gas at a solvent injection point. A mixed feed is produced from a dispersal of the solvent into the feed of natural gas. The mixed feed contains heavy components. A chilled feed is produced by chilling the mixed feed. The chilled feed includes a vapor and a condensed liquid. The condensed liquid contains a fouling portion of the heavy components condensed by the solvent during chilling. The liquid containing the fouling portion of the heavy components is separated from the vapor. The vapor is directed into a feed chiller heat exchanger following separation of the liquid containing the fouling portion of the heavy components from the vapor, such that the vapor being directed into feed chiller heat exchanger is free of freezing components.
    Type: Grant
    Filed: April 29, 2020
    Date of Patent: May 30, 2023
    Assignee: ConocoPhillips Company
    Inventors: Michael J. Calderon, Dale L. Embry, Paul R. Davies, Attilio J. Praderio
  • Patent number: 11604025
    Abstract: Implementations described and claimed herein provide systems and methods for processing liquefied natural gas (LNG). In one implementation, a dry feed gas is received. The dry feed gas is chilled with clean vapor from a heavies removal column to form a chilled feed gas. The chilled feed gas is partially condensed into a vapor phase and a liquid phase. The liquid phase retains freezing components. The freezing components are extracted using a reflux stream in the heavies removal column. The freezing components are removed as a condensate. The vapor phase is compressed into a clean feed gas. The clean feed gas is free of the freezing components for downstream liquefaction.
    Type: Grant
    Filed: October 16, 2020
    Date of Patent: March 14, 2023
    Assignee: ConocoPhillips Company
    Inventors: Jinghua Chan, Qi Ma, Dale L. Embry, Attilio J. Praderio
  • Patent number: 10816264
    Abstract: A process for purification of a current of hydrogen synthesis gas (100), particularly in the front-end of an ammonia plant, wherein said gas contains hydrogen and minor amounts of carbon monoxide, carbon dioxide, water and impurities, said process including steps of methanation (13) of said current (100), converting residual amounts of carbon monoxide and carbon dioxide to methane and water, dehydration (14) of the gas to remove water, and then a cryogenic purification (15) such as liquid nitrogen wash, to remove methane and Argon; a corresponding plant and method for revamping an ammonia plant are also disclosed.
    Type: Grant
    Filed: June 25, 2014
    Date of Patent: October 27, 2020
    Assignee: Casale SA
    Inventors: Ermanno Filippi, Raffaele Ostuni, Damiano Marzari Chiesa
  • Patent number: 10258960
    Abstract: A reforming device (10) according to the present invention has a compressor (11), a first heat exchanger (12), a desulfurization device (13), a reformer (14), a raw material gas branching line (L11) that extracts a compressed natural gas (21) from a downstream side of the desulfurization device (13) with respect to the flow direction of the natural gas (21) and supplies the natural gas (21) to the reformer (14), and a flue gas discharging line (L12) that discharges a flue gas (22) generated in the reformer (14), wherein the first heat exchanger (12) is provided in the flue gas discharging line (L12), and the flue gas (22) is used as a heating medium of the compressed natural gas (21).
    Type: Grant
    Filed: December 13, 2016
    Date of Patent: April 16, 2019
    Assignee: MITSUBISHI HEAVY INDUSTRIES ENGINEERING, LTD.
    Inventors: Mikiya Sakurai, Naoya Okuzumi, Ryota Shimura, Shuichi Miyamoto, Yoshio Seiki, Hiroyuki Osora
  • Patent number: 10012434
    Abstract: In a process for the production of carbon dioxide and hydrogen from a gas flow comprising at least hydrogen, at least one sulfur-comprising component and carbon dioxide originating from a Claus unit fed with a gas comprising at least 50 mol % of oxygen, the gas flow is compressed and dried in order to produce a compressed and dried gas flow and the compressed and dried gas flow is separated at a subambient temperature in order to produce at least a fluid enriched in carbon dioxide with respect to the compressed and dried gas flow and at least a fluid enriched in hydrogen with respect to the compressed and dried gas flow.
    Type: Grant
    Filed: February 11, 2014
    Date of Patent: July 3, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Nicolas Chambron, Richard Dubettier-Grenier, Sylvain Gerard
  • Patent number: 9823014
    Abstract: The disclosure relates to a method and apparatus for cooling, preferably liquefying a boil off gas (BOG) stream from a liquefied cargo in a floating transportation vessel, said liquefied cargo having a boiling point of greater than ?110° C.
    Type: Grant
    Filed: April 3, 2012
    Date of Patent: November 21, 2017
    Assignee: Babcock IP Management (Number One) Limited
    Inventor: Alan Roderick Duckett
  • Patent number: 9605896
    Abstract: The disclosure includes a process for treating a natural gas containing carbon dioxide wherein the natural gas is separated by a cryogenic process in order to provide, on the one hand, a stream of liquid carbon dioxide, containing hydrocarbons, and, on the other hand, purified natural gas; at least one part of the natural gas is cooled in a first heat exchanger and then in a second heat exchanger before the cryogenic process and/or before a reflux to the cryogenic process; at least one part of the stream of liquid carbon dioxide is recovered in order to provide a stream of recycled carbon dioxide; the stream of recycled carbon dioxide is divided into a first portion and a second portion; the first portion is expanded and then heated in the first heat exchanger, in order to provide a first stream of heated carbon dioxide; the second portion is cooled, then at least one part of the second portion is expanded and then heated in the second heat exchanger, in order to provide a second stream of heated carbon dioxi
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: March 28, 2017
    Assignee: TOTAL S.A.
    Inventor: Xavier Renaud
  • Patent number: 7713497
    Abstract: A natural gas liquid plant includes a separator (103) that receives a cooled low pressure feed gas (4), wherein the separator (103) is coupled to an absorber (108) and a demethanizer (110). Refrigeration duty of the absorber (108) and demethanizer (110) are provided at least in part by expansion of a liquid portion of the cooled low pressure feed gas (4) and an expansion of a liquid absorber bottom product (19), wherein ethane recovery is at least 85 mol % and propane recovery is at least 99 mol %. Contemplated configurations are especially advantageous as upgrades to existing plants with low pressure feed gas where high ethane recovery is desirable.
    Type: Grant
    Filed: August 15, 2002
    Date of Patent: May 11, 2010
    Assignee: Fluor Technologies Corporation
    Inventor: John Mak
  • Publication number: 20090282865
    Abstract: A process for the recovery of ethane, ethylene, propane, propylene, and heavier hydrocarbons from a liquefied natural gas (LNG) stream and a hydrocarbon gas stream is disclosed. The LNG feed stream is divided into two portions. The first portion is supplied to a fractionation column at a first upper mid-column feed point. The second portion is directed in heat exchange relation with a first portion of a warmer distillation stream rising from the fractionation stages of the column, whereby the LNG feed stream is partially heated and the distillation stream is totally condensed. The condensed distillation stream is divided into a “lean” LNG stream and a reflux stream, whereupon the reflux stream is supplied to the column at a top column feed position. The second portion of the LNG feed stream is heated further to partially or totally vaporize it and thereafter supplied to the column at a first lower mid-column feed position. The gas stream is divided into two portions.
    Type: Application
    Filed: April 14, 2009
    Publication date: November 19, 2009
    Applicant: ORTLOFF ENGINEERS, LTD.
    Inventors: Tony L. Martinez, John D. Wilkinson, Hank M. Hudson, Kyle T. Cuellar
  • Patent number: 7530236
    Abstract: An apparatus and process for removing natural gas liquids from an liquid natural gas (LNG) stream, specifically recovering at least 90% of ethane from the LNG, utilizing the low-level heat available in an LNG terminal.
    Type: Grant
    Filed: March 1, 2006
    Date of Patent: May 12, 2009
    Inventor: Rajeev Nanda
  • Publication number: 20080314079
    Abstract: A process is provided for denitrogenation of a crude LNG stream. A crude LNG stream comprising between about 1% and 10% nitrogen, and the remainder methane and heavier hydrocarbons, is expanded in a means for expansion, and cooled. Resultant crude LNG stream is introduced into nitrogen rejection column, wherein nitrogen content of LNG is reduced. A nitrogen-enriched vapor stream is withdrawn from top of the column, and a nitrogen-diminished liquid stream is withdrawn from bottom of the column. The nitrogen-diminished bottoms LNG stream is pumped to higher pressure and then divided into two streams. The second stream is reduced in pressure and then passed through reboiler heat exchanger, thus cooling the crude LNG stream. Partially vaporized second stream is reinjected into column at a level above the level of withdrawal of nitrogen-diminished bottoms LNG stream and below the level of introduction of crude LNG feed stream to provide column boilup.
    Type: Application
    Filed: June 19, 2007
    Publication date: December 25, 2008
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventor: Adam Adrian Brostow
  • Publication number: 20080307827
    Abstract: A method and system of refining natural gas that improves the quality of liquefied natural gas and enables separation and recovery of hydrocarbons other than methane. The method of refining natural gas containing methane; any other hydrocarbon selected from the group consisting of ethane, ethylene, propane, propylene, n-butane, isobutane, 1-butene, n-pentane, and isopentane; carbon dioxide; and hydrogen sulfide, includes adjusting a pressure and temperature of the natural gas so that the methane is in the gas phase, the other hydrocarbon in the liquid phase, and the carbon dioxide and the hydrogen sulfide in the solid phase, respectively; separating the natural gas, of which the pressure and temperature has been adjusted, into a gas containing the methane and a suspension liquid; and separating the separated suspension liquid into a liquid containing the other hydrocarbon and a solid containing the carbon dioxide and the hydrogen sulfide.
    Type: Application
    Filed: June 10, 2008
    Publication date: December 18, 2008
    Inventors: Yuuko HINO, Takashi Asano, Mamoru Kamoshida
  • Patent number: 7424808
    Abstract: A plant includes an absorber (105) that receives a feed gas (10) at a pressure of at least 400 psig and comprising at least 5 mol % carbon dioxide, wherein the absorber (105) is operated at an isothermal or decreasing top-to-bottom thermal gradient, and wherein the absorber (105) employs a physical solvent to at least partially remove an acid gas from the feed gas (10). Such configuration advantageously provide cooling (108) by expansion of the rich solvent (21) generated in the absorber (105), wherein both a semi-rich solvent (13) generated and recycled to the absorber (105) and the feed gas (10) are cooled by expansion of the rich solvent (21).
    Type: Grant
    Filed: September 17, 2002
    Date of Patent: September 16, 2008
    Assignee: Fluor Technologies Corporation
    Inventor: John Mak
  • Patent number: 6793712
    Abstract: A pretreatment system for natural gas liquefaction employing heat integration for more efficient and effective natural gas temperature control. The pretreatment system expands the natural gas prior to acid gas removal. After acid gas removal, the natural gas is cooled by indirect heat exchange with the expanded natural gas located upstream of the acid gas removal system.
    Type: Grant
    Filed: November 1, 2002
    Date of Patent: September 21, 2004
    Assignee: ConocoPhillips Company
    Inventor: Wesley R. Qualls
  • Patent number: 5678423
    Abstract: A method for the recovery of volatile organic components (VOC) released when loading liquid hydrocarbons into a storage or cargo tank, is described. The VOCs issuing from the tank are compressed, and injected into a sidestream taken from the main hydrocarbon stream, which is cooled and used as the absorbing medium, and is conducted to a VOC recovery unit comprising at least a bi-phase rotary separator turbine (BRST). In the BRST the VOC-containing gas is substantially separated into a VOC component and inert gas. The inert gas is vented to the atmosphere. The VOC component or VOC-enriched liquid stream is then returned to the main cargo stream or a cargo tank. Any methane contained in the volatile gases issuing from the cargo tank, instead of being vented to the atmosphere, is recovered or a catalytic process is used to convert methane to carbon dioxide and water for discharge to the atmosphere. The system is particularly intended for the offshore loading of oil into tankers.
    Type: Grant
    Filed: May 4, 1995
    Date of Patent: October 21, 1997
    Assignee: Kvaerner Process System A.S.
    Inventors: Simon Davies, Niels Henrik Hasting, Lance Hays
  • Patent number: 5596884
    Abstract: The cryogenic treatment of landfill gas removes troublesome compounds that cause severe corrosion of combustion engines in which the gas is used as fuel. It involves compressing the gas to an elevated pressure and isenthalpically expanding the gas to chill the gas to a temperature below -20 .degree. F. The compressed gas is first cooled to eliminate moisture as condensate. Methanol is injected into the gas so that it can be deeply chilled without forming ice with residual moisture in the gas. An aqueous methanol condensate containing troublesome compounds forms in, and is removed from, the deeply chilled gas before it is expanded to provide refrigeration for chilling the gas. By adding water to the aqueous methanol, the troublesome compounds lose solubility in diluted methanol and form a supernatant layer that can be separated for disposal. The diluted methanol can be recycled.
    Type: Grant
    Filed: December 26, 1995
    Date of Patent: January 28, 1997
    Assignee: Kryos Energy Inc.
    Inventors: Stephen J. Markbreiter, Irving Weiss