Solidification Patents (Class 62/637)
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Patent number: 11946355Abstract: A method to recover and process hydrocarbons from a gas flare system to produce natural gas liquids (NGL), cold compressed natural gas (CCNG), compressed natural gas (CNG) and liquid natural gas (LNG). The method process provides the energy required to recover and process the hydrocarbon gas stream through compression and expansion of the various streams.Type: GrantFiled: November 27, 2017Date of Patent: April 2, 2024Assignees: 1304338 Alberta Ltd., 1304342 Alberta Ltd.Inventors: Jose Lourenco, MacKenzie Millar
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Patent number: 11035611Abstract: The disclosure provides a method for separating components of a gas. A feed gas stream is cooled in a first vessel. The feed gas stream includes methane, water, carbon dioxide, and Natural Gas Liquids. The feed gas stream is cooled in a first vessel. A portion of the water condenses to form a primary liquid stream, resulting in a first depleted gas stream, which is cooled in a second vessel. A portion of the NGLs condense to form a secondary liquid stream, resulting in a second depleted gas stream, which is cooled in a condensing exchanger. A first portion of the methane condenses to form a liquid methane stream, resulting in a third depleted gas stream, which is cooled in a third vessel. A portion of the carbon dioxide condenses, desublimates, or condenses and desublimates as a final product stream, also resulting in a fourth depleted gas stream.Type: GrantFiled: July 13, 2018Date of Patent: June 15, 2021Assignee: Sustainable Energy Solutions, Inc.Inventors: Larry Baxter, Chris Hoeger, Jacom Chamberlain, Kyler Stitt
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Patent number: 10995984Abstract: A method is disclosed for separating components of a gas. A feed gas stream is cooled in the first vessel. The feed gas stream comprises methane, carbon dioxide, and a secondary component. A first portion of the secondary component condenses, desublimates, or a combination thereof to form a primary stream, resulting in a first depleted gas stream. The first depleted gas stream is cooled in a condensing exchanger such that a first portion of the methane condenses as a first liquid methane stream, resulting in a second depleted gas stream. The second depleted gas stream is cooled in the second vessel such that a first portion of the carbon dioxide desublimates to form a solid product stream, resulting in a third depleted gas stream.Type: GrantFiled: July 13, 2018Date of Patent: May 4, 2021Assignee: Sustainable Energy Solutions, Inc.Inventors: Larry Baxter, Chris Hoeger, Jacom Chamberlain, Kyler Stitt
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Patent number: 10882001Abstract: A process for removing a foulant from a gas stream. The gas stream is cooled in a series of heat exchangers, causing a portion of the foulant to desublimate and become entrained in a cryogenic liquid. This foulant slurry stream is pressurized, cooled, and separated into a pressurized foulant solid stream and the cryogenic liquid stream. The pressurized foulant solid stream is melted to produce a liquid foulant stream. Heat exchange processes, both internal and external, are provided that close the heat balance of the process. In this manner, the foulant is removed from the gas stream.Type: GrantFiled: March 6, 2017Date of Patent: January 5, 2021Assignee: Hall Labs LLCInventors: Larry Baxter, Eric Mansfield, Christopher Hoeger
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Patent number: 10871323Abstract: The present invention provides a method of liquefying a contaminated hydrocarbon-containing gas stream: (a) providing a CO2 contaminated hydrocarbon-containing gas stream (20); (b) cooling the contaminated hydrocarbon-containing gas stream to obtain a partially liquefied stream (70); (c) separating the partially liquefied stream obtaining a liquid stream (90); (d) cooling the liquid stream (90) in a direct contact heat exchanger (200) obtaining a multiphase stream (201) containing at least a liquid phase and a solid CO2 phase; (e) separating the multiphase stream in a solid-liquid separator (202) obtaining a CO2 depleted liquid stream (141); (f) passing the CO2 depleted liquid stream (141) to a further cooling, pressure reduction and separation stage to generate a further CO2 enriched slurry stream (206); (g) passing at least part of the further CO2 enriched slurry stream (206) to the direct contact heat exchanger (200) to provide cooling duty to and mix with the liquid stream (90).Type: GrantFiled: December 1, 2016Date of Patent: December 22, 2020Assignee: SHELL OIL COMPANYInventors: Thijs Groenendijk, Raimo Edwin Gregor Poorte, Nirupa Raghavan, Michiel Gijsbert Van Aken
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Patent number: 10422561Abstract: The present invention relates to a recuperative trapping stage (3) for a refrigerator or refrigerator system. The recuperative trapping stage (3) comprises at least one first portion and at least one second portion configured for conveying fluids, wherein the first portion is in fluid communication with the second portion and wherein at least one part of the second portion is arranged within the first portion. Further the present invention relates to a refrigerator with at least one recuperative trapping stage (3) according to the present invention and with at least one cooler (1), the cooler (1) having at least one cold stage, wherein at least a part or section of the first portion of the at least one recuperative trapping stage (3) is thermally coupled, or at least configured to be thermally coupleable, to the at least one cold stage. Finally the present invention relates to a method of cleaning at least one recuperative trapping stage (3) in a refrigerator according to the present invention.Type: GrantFiled: July 8, 2015Date of Patent: September 24, 2019Assignee: BLUEFORS CRYOGENICS OY LTDInventor: Rob Blaauwgeers
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Patent number: 9683777Abstract: Embodiments described herein provide a method and systems for separating carbon dioxide from heavy hydrocarbons. The method includes cooling a first liquid stream including carbon dioxide and heavy hydrocarbons within an oscillatory crystallization unit to generate carbon dioxide solids and a second liquid stream including the heavy hydrocarbons. The method also includes separating the carbon dioxide solids from the second liquid stream via a solid-liquid separation system.Type: GrantFiled: September 30, 2013Date of Patent: June 20, 2017Assignee: ExxonMobil Upstream Research CompanyInventor: Srinivas N. Moorkanikkara
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Patent number: 9633774Abstract: A method for making a magnetic assembly comprises the following steps: twisting a first to eighth magnetic wires to form a bundle of wires having a first end and an opposite second end; providing a magnetic core; winding the bundle of magnetic wires around the magnetic core; sorting the first end and the second end of the bundle of wires to form individual first ends and individual second ends of the first to eighth wires; picking out the second ends of the first wire and the second wire, and the first ends of the third wire and the fourth wire to form a center tap of a primary coil of a transformer; and picking out the second ends of the fifth wire and the sixth wire, and the first ends of the seventh wire and the eighth wire to form a center tap of a secondary coil of the transformer.Type: GrantFiled: October 26, 2014Date of Patent: April 25, 2017Assignee: HON HAI PRECISION INDUSTRY CO., LTD.Inventors: Yong-Chun Xu, Jie Zhang
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Patent number: 9250012Abstract: Condensable vapors such as carbon dioxide are separated from light gases in a process stream. The systems and methods employ a particle bed cooled by an in-bed heat exchanger to desublimate the condensable vapors from the process stream. The condensable vapors are condensed on the bed particles while the light gases from the process stream, which are not condensed, form a separated light-gas stream. The separated light-gas stream can be used in a recuperative heat exchanger to cool the process stream.Type: GrantFiled: March 11, 2014Date of Patent: February 2, 2016Assignee: SUSTAINABLE ENERGY SOLUTIONS, LLCInventor: Larry L. Baxter
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Patent number: 8899074Abstract: A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO2 from a liquid NG process stream and processing the CO2 to provide a CO2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.Type: GrantFiled: October 22, 2009Date of Patent: December 2, 2014Assignee: Battelle Energy Alliance, LLCInventors: Bruce M. Wilding, Terry D. Turner
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Patent number: 8624594Abstract: The present invention relates to a polarized xenon gas manufacturing supply device that is provided with a polarization cell 6 that produces a polarized xenon gas by polarizing a mixture of xenon gas and a diluent gas that consists primarily of a high-boiling-point gas that has a boiling point higher than that of the xenon gas, and a condenser (9) that cools the mixed gas discharged from the polarization cell (6) and condenses and separates the high-boiling-point gas by using the difference in boiling points between the xenon gas and the high-boiling-point gas, wherein the supply device is constructed so as to re-vaporize the condensed liquid of the high-boiling-point gas produced by the condenser (9) and introduce it to the polarization cell (6). This polarized xenon gas manufacturing supply device makes it possible to continuously manufacture and supply highly polarized and highly concentrated xenon gas.Type: GrantFiled: July 29, 2009Date of Patent: January 7, 2014Assignee: Osaka UniversityInventors: Hideaki Fujiwara, Hirohiko Imai, Satoshi Iguchi, Hironobu Yoshimura, Atsuomi Kimura
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Patent number: 8585802Abstract: An energy-efficient method of recovering carbon dioxide (CO2) in a high-pressure liquid state from a high-pressure gas stream. The method includes cooling, condensing, and/or separating CO2 from a high-pressure gas stream in two or more separation zones and further purifying the resulting sub-critical pressure liquid CO2 streams in a third purification zone to thereby provide purified CO2. The purified liquid CO2 may be pumped to above the critical pressure for further utilization and/or sequestration for industrial or environmental purposes.Type: GrantFiled: July 7, 2011Date of Patent: November 19, 2013Inventor: Arnold Keller
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Patent number: 8475572Abstract: The invention relates to a method of removing carbon dioxide from a fluid stream by a fluid separation assembly. The fluid separation assembly has a cyclonic fluid separator with a tubular throat portion arranged between a converging fluid inlet section and a diverging fluid outlet section and a swirl creating device. The separation vessel has a tubular section positioned on and in connection with a collecting tank. In the method, a fluid stream with carbon dioxide is provided. Subsequently, a swirling motion is imparted to the fluid stream so as to induce outward movement. The swirling fluid stream is then expanded such that components of carbon dioxide in a meta-stable state within the fluid stream are formed. Subsequently, the outward fluid stream with the components of carbon dioxide is extracted from the cyclonic fluid separator and provided as a mixture to the separation vessel.Type: GrantFiled: December 28, 2007Date of Patent: July 2, 2013Assignee: Twister B.V.Inventors: Bart Prast, Jakob Arie Cornelis Langerak, Marco Betting, Cornelis Antonie Tjeenk Willink
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Publication number: 20130000350Abstract: An apparatus for the removal of hydrocarbons from a body of water comprising a temperature reduction device comprising a heat exchange in thermal communication with a flow of a liquefied cryogen, the temperature reduction device being adapted to receive a hydrocarbon/water mixture, position a first surface of the at least partially phase separated mixture in thermal communication with the heat exchanger, and reduce the temperature of the at least partially phase separated mixture to a temperature sufficient to cause the hydrocarbon phase to at least partially congeal or at least partially solidify.Type: ApplicationFiled: June 30, 2011Publication date: January 3, 2013Applicant: Air Liquide Industrial U.S. LPInventors: David C. Braithwaite, Brandon Sumners, Eric P. Klein, Stephen Bilger, Ronald C. Idol
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Patent number: 8312738Abstract: The present invention relates to methods and apparatuses for the operation of a distillation tower containing a controlled freezing zone and at least one distillation section. The process and tower design are utilized for the additional recovery of hydrocarbons from an acid gas. In this process, a separation process is utilized in which a multi-component feedstream is introduced into an apparatus that operates under solids forming conditions for at least one of the feedstream components. The freezable component, although typically CO2, H2S, or another acid gas, can be any component that has the potential for forming solids in the separation system. A dividing wall is added to at least a portion of the lower distillation section of the apparatus to effect the separation of at least some fraction of the hydrocarbons in that portion of the tower.Type: GrantFiled: November 20, 2007Date of Patent: November 20, 2012Assignee: ExxonMobil Upstream Research CompanyInventors: Vikram Singh, Edward J. Grave, Paul Scott Northrop, Narasimhan Sundaram
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Publication number: 20120186296Abstract: A process and apparatus for liquefying a gas stream comprising hydrocarbons and sour species is provided in which the sour species are removed in liquefied form as the sweetened gas stream is progressively cooled to liquefaction temperatures. The process involves cooling the gas stream in a manner to produce a cooled gas stream comprising gaseous hydrocarbons and residual sour species. The cooled gas stream is then treated with a cold solvent to deplete the cooled gas stream of residual sour species. The resulting cooled sweetened gas stream is then further cooled to produce liquid hydrocarbons.Type: ApplicationFiled: June 11, 2010Publication date: July 26, 2012Inventors: Nimalan Gnanendran, Martin Wilkes
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Publication number: 20120006054Abstract: An energy-efficient method of recovering carbon dioxide (CO2) in a high-pressure liquid state from a high-pressure gas stream. The method includes cooling, condensing, and/or separating CO2 from a high-pressure gas stream in two or more separation zones and further purifying the resulting sub-critical pressure liquid CO2 streams in a third purification zone to thereby provide purified CO2. The purified liquid CO2 may be pumped to above the critical pressure for further utilization and/or sequestration for industrial or environmental purposes.Type: ApplicationFiled: July 7, 2011Publication date: January 12, 2012Inventor: Arnold Keller
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Publication number: 20110167869Abstract: A transformer has a toroidal core with an opening therein and a plurality of wires to define a central winding section, a plurality of outer twisted wire sections and a plurality of wire proximity sections positioned between each outer twisted wire section and the central winding section. The central winding section includes a plurality of wires wrapped around the toroidal core and coupling a conductor of a primary side of a transformer and a conductor of a secondary side of a transformer. Each outer twisted wire section includes at least a pair of wires twisted together in a predetermined twisted pattern that are electrically connected to but spaced from the central winding section. The wire proximity section is configured to maintain physical proximity between the conductor of the primary side of the transformer and the conductor of the secondary side of the transformer.Type: ApplicationFiled: October 16, 2009Publication date: July 14, 2011Inventors: Henricus Abraham Geers, Helmar Van Santen
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Publication number: 20110107791Abstract: An apparatus for recovery of solids from a vapor, the apparatus including: a vessel comprising a cylindrical portion on top of an angled portion; a vapor inlet located in the cylindrical portion for introducing a solid-vapor mixture tangentially to the cylindrical portion; at least one inlet nozzle disposed in a top of the vessel for spraying a hydrocarbon fluid into the vessel; an indirect heat exchange device disposed concentrically within the cylindrical portion, thereby providing an annulus for vapor and hydrocarbon flow; a heat exchange device disposed at an exterior of the angled portion; an outlet located at a bottom of the angled portion to recover the vapor having a reduced solids content and a solid-hydrocarbon mixture. Also disclosed are processes to clean an oil vapor using such an apparatus.Type: ApplicationFiled: July 14, 2009Publication date: May 12, 2011Applicant: M-I LLCInventor: Richard Bingham
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Patent number: 7644594Abstract: A method and apparatus are disclosed for recovering and separating anesthetic gas components from waste anesthetic gases to be purged from a healthcare facility. With minimal reliance on the utility infrastructure and supplies of a healthcare facility, the method and apparatus needs only electrical or mechanical power, a source of waste anesthetic gases, and an atmospheric vent in order to operate. A heat exchanger/condenser, which uses a dedicated heat transfer fluid as a refrigerant, is employed to condense anesthetic gas components from the waste anesthetic gases as either liquid condensates or solid frosts. The warmed heat transfer fluid is cooled in a separate refrigeration unit and recycled back to the heat exchanger/condenser. A preferred embodiment of the invention is a self-contained, packaged unit which can be easily accommodated in a physician's office, small animal clinic, dental office or other healthcare facility requiring effective waste anesthetic gas management.Type: GrantFiled: May 11, 2006Date of Patent: January 12, 2010Assignee: Anesthetic Gas Reclamation, L.L.C.Inventors: James M. Berry, Steve Morris
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Patent number: 7596965Abstract: A method and system for the fractionation and removal of nitrous oxide and other volatile halocarbon gas components from waste anesthetic gases using liquid oxygen are disclosed. Liquid oxygen is warmed for use in a healthcare facility by cooling and condensing waste anesthetic gases. A cold trap/fractionator is provided wherein selective components of the waste anesthetic gas are collected as a frost on the coils of the cold trap/fractionator by desublimation/deposition and/or condensation/solidification. In a periodic batch process, the collected frost is first thawed and the melted liquids or gases are then collected at various increasing temperatures, thereby separating the nitrous oxide and other halocarbon gas components by their varying melting points. The thawed anesthetic components are collected in separate tanks based on their melting points. Warmed by the waste anesthetic gases in the cold trap/fractionator, the oxygen is supplied to the healthcare facility for its normal uses.Type: GrantFiled: May 11, 2006Date of Patent: October 6, 2009Assignee: Anesthetic Gas Reclamation, LLCInventors: James M. Berry, Steve Morris
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Patent number: 7445664Abstract: The invention relates to a desublimator for producing particulate, solid aluminum chloride from aluminum chloride vapor, which is formed by a vessel which is closed on all sides and has vertical walls and a feed point for the aluminum chloride vapor and an offtake point for the solid aluminum chloride, wherein the walls of the vessel are formed by flat metal sheets which are welded into a rigid frame so that they can be set into vibration by being struck with a tapper.Type: GrantFiled: September 13, 2005Date of Patent: November 4, 2008Assignee: BASF AktiengesellschaftInventors: Dieter Schläfer, Hans-Ulrich Schlimper
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Patent number: 7152431Abstract: A process for removing contaminants from a natural gas feed stream including water and sour species is provided, which process comprises the steps of cooling the natural gas feed stream in a first vessel (12) to a first operating temperature at which hydrates are formed and removing from the first vessel (12) a stream of dehydrated gas (34); and cooling the dehydrated gas in a second vessel (14) to a second operating temperature at which solids of the sour species are formed or at which the sour species dissolve in a liquid and removing from the second vessel (14) a stream of dehydrated sweetened gas (62).Type: GrantFiled: February 5, 2004Date of Patent: December 26, 2006Assignee: Shell Oil CompanyInventors: Robert Amin, Casper Krijno Groothuis
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Patent number: 6735977Abstract: An apparatus and a method for providing a magnetic holding field about a chamber for accumulating frozen 129Xe. The apparatus includes a magnetic field source and a yoke for supporting the magnetic field source about the chamber. The magnetic field source provides a magnetic holding field having a field strength of greater than 2 kiloGauss. The apparatus may further include yoke for coupling the magnetic holding field through a portion of the chamber.Type: GrantFiled: August 19, 2002Date of Patent: May 18, 2004Assignee: Medi-Physics, Inc.Inventors: Nicholas N. Kuzma, Ian Nelson
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Patent number: 6666047Abstract: The invention relates to a polarizer for noble gases comprising a glass sample cell and a pressure chanter in which the sample cell is located. High pressure and accompanying broadband or narrow-band lasers can be similarly provided in an optimal manner. To this end, the polarizer is operated at pressures of 30 bar and higher.Type: GrantFiled: March 27, 2002Date of Patent: December 23, 2003Assignee: Forschungszentrum Julich GmbHInventors: Nadim Joni Shah, Stephan Appelt, Timur Unlu, Horst Halling, Karl Zilles
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Patent number: 6637240Abstract: A process for producing a nitrogen-enriched vapor product from a supply of a nitrogen-rich liquid uses a purifying device and a distillation column having a distillation zone. The process includes the steps of: feeding at least a portion of the supply of the nitrogen-rich liquid to the distillation zone at a first location; feeding a stream of a gas containing nitrogen and at least one contaminant to the purifying device, wherein the gas is cooled by a cryogenic liquid whereby at least a portion of the at least one contaminant condenses, solidifies, or dissolves; eventually feeding at least a portion of the cool gas from the purifying device to the distillation zone at a second location below the first location; withdrawing a stream of the nitrogen-enriched vapor product from the distillation zone; and withdrawing a stream of an oxygen-enriched liquid from the distillation zone.Type: GrantFiled: November 8, 2002Date of Patent: October 28, 2003Assignee: Air Products and Chemicals, Inc.Inventors: John Louis Griffiths, Adam Adrian Brostow, Declan Patrick O'Connor, Swaminathan Sunder, Patrick Alan Houghton
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Publication number: 20030108485Abstract: Modular expandable hyperpolarizers include a central control module and at least one optical pumping module that can be expandable to a plurality of optical pumping modules that can be separately operated depending on the capacity demands at the production site (hospital, clinic and the like). Methods for producing blended polarized gas products include introducing a pre-packaged pre-mixed amount of a polarizer-ready blend of unpolarized gas. Methods for producing the polarized gas can be carried out at the point of use site and the production run according to patient load. Other methods consider the patient load and automatically schedule the hyperpolarizer to yield the desired polarized gas doses to support the patient and/or MRI/NMR equipment schedule.Type: ApplicationFiled: October 22, 2002Publication date: June 12, 2003Inventor: Kenneth Bolam
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Patent number: 6513345Abstract: A nozzle of converging-diverging shape for creating mist flow at supersonic velocity comprising: a throat having a characteristic diameter D*; an inlet having a characteristic diameter D1, positioned a distance L1 upstream of the nozzle throat; and an outlet having a characteristic diameter D2, positioned a distance L2 downstream of the nozzle throat, wherein the ratio of L2/(D2−D*) is larger than 4, but smaller than 250; an inertia separator based thereon, and a method for supersonic separation of one or more components of a predominantly gaseous stream.Type: GrantFiled: June 28, 2001Date of Patent: February 4, 2003Assignee: Shell Oil CompanyInventors: Marco Betting, Theodoor Van Holten, Cornelis Antonie Tjeenk Willink, Johannes Miguel Henri Maria Van Veen
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Patent number: 6490883Abstract: Volatile compounds (“VCs”), especially volatile organic compounds (“VOCs”), are cryogenically removed from a process gas stream (pW) by cooling the gas stream in a condenser to condense the VC to form both liquid VC and VC ice and providing a treated process gas essentially freed of the VC but containing entrained VC ice particles, which are subsequently removed by passing the treated process gas through a filter downstream of the condenser to remove at least particles of a size greater than 50 &mgr;m. The condensation can be conducted in an indirect heat exchanger or by direct contact of the process gas with a liquid cryogen such as liquid nitrogen. It is preferred that the filter removes VC ice particles greater than 1 &mgr;m.Type: GrantFiled: June 12, 2001Date of Patent: December 10, 2002Assignee: Air Products and Chemicals, Inc.Inventors: Jean-Philippe Trembley, John Louis Griffiths
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Patent number: 6487877Abstract: A process for producing a nitrogen-enriched vapor product from a supply of a nitrogen-rich liquid uses a purifying device and a distillation column having a distillation zone. The process includes the steps of: feeding at least a portion of the supply of the nitrogen-rich liquid to the distillation zone at a first location; feeding a stream of a gas containing nitrogen and at least one contaminant to the purifying device, wherein the gas is cooled by a cryogenic liquid whereby at least a portion of the at least one contaminant condenses, solidifies, or dissolves; eventually feeding at least a portion of the cool gas from the purifying device to the distillation zone at a second location below the first location; withdrawing a stream of the nitrogen-enriched vapor product from the distillation zone; and withdrawing a stream of an oxygen-enriched liquid from the distillation zone.Type: GrantFiled: May 1, 2002Date of Patent: December 3, 2002Assignee: Air Products and Chemicals, Inc.Inventors: John Louis Griffiths, Adam Adrian Brostow, Declan Patrick O'Connor, Swaninathan Sunder, Patrick Alan Houghton
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Publication number: 20020174678Abstract: An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO2) clean-up cycle.Type: ApplicationFiled: February 27, 2002Publication date: November 28, 2002Inventors: Bruce M. Wilding, Dennis N. Bingham, Michael G. McKellar, Terry D. Turner, Kevin T. Raterman, Gary L. Palmer, Kerry M. Klingler, John J. Vranicar
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Patent number: 6486666Abstract: The invention relates to a method for determining the degree of polarization (P) of a nuclear spin polarized gas, in particular 3He, 129Xe, in which the nuclear spin polarized gas is placed in a container, comprising determining the magnetic field Bd of the pola gas by measuring the magnetic dipole field emerging therefrom and then determining from Bd the degree of polarization of the gas.Type: GrantFiled: May 18, 2000Date of Patent: November 26, 2002Assignee: Hellspin Polarisierte Gase GmbHInventors: Tino Grossmann, Werner Heil, Daniela Rohe, Reinhard Surkau, Elke Aidam, Michael Ebert, Ernst-Wilhelm Otten
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Patent number: 6484532Abstract: Hyperpolarizers which produce hyperpolarized noble gases include one or more on-board NMR monitoring coils configured to monitor the polarization level of the hyperpolarized gas at various production points in the polarized gas production cycle. A dual symmetry NMR coil is positioned adjacent the optical pumping cell and is in fluid communication with a secondary reservoir in fluid communication with the polarized gas dispensing or exit flow path. This can measure the post-thaw polarization of the gas “on-board” the polarizer. Alternately or additionally, a NMR monitoring coil is assembled to the exit port portion of the optical pumping cell to give a more reliable indication of the polarization level of the gas as it flows out of the gas optical pumping cell. Another NMR monitoring coil can be positioned in a cryogenic bath adjacent a quantity of frozen polarized 129Xe to determine the polarization level of the frozen gas.Type: GrantFiled: August 23, 2001Date of Patent: November 26, 2002Assignee: Medi-Physics, Inc.Inventor: Bastiaan Driehuys
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Patent number: 6430960Abstract: Hyperpolarizers which produce hyperpolarized noble gases include one or more on-board NMR monitoring coils configured to monitor the polarization level of the hyperpolarized gas at various production points in the polarized gas production cycle. A dual symmetry NMR coil is positioned adjacent the optical pumping cell and is in fluid communication with a secondary reservoir in fluid communication with the polarized gas dispensing or exit flow path. This can measure the post-thaw polarization of the gas “on-board” the polarizer. Alternately or additionally, a NMR monitoring coil is assembled to the exit port portion of the optical pumping cell to give a more reliable indication of the polarization level of the gas as it flows out of the gas optical pumping cell. Another NMR monitoring coil can be positioned in a cryogenic bath adjacent a quantity of frozen polarized 129Xe to determine the polarization level of the frozen gas.Type: GrantFiled: August 23, 2001Date of Patent: August 13, 2002Assignee: Medi-Physics, Inc.Inventor: Bastiaan Driehuys
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Publication number: 20020066287Abstract: Hyperpolarizers which produce hyperpolarized noble gases include one or more on-board NMR monitoring coils configured to monitor the polarization level of the hyperpolarized gas at various production points in the polarized gas production cycle. A dual symmetry NMR coil is positioned adjacent the optical pumping cell and is in fluid communication with a secondary reservoir in fluid communication with the polarized gas dispensing or exit flow path. This can measure the post-thaw polarization of the gas “on-board” the polarizer. Alternately or additionally, a NMR monitoring coil is assembled to the exit port portion of the optical pumping cell to give a more reliable indication of the polarization level of the gas as it flows out of the gas optical pumping cell. Another NMR monitoring coil can be positioned in a cryogenic bath adjacent a quantity of frozen polarized 129Xe to determine the polarization level of the frozen gas.Type: ApplicationFiled: August 23, 2001Publication date: June 6, 2002Inventor: Bastiaan Driehuys
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Patent number: 6374635Abstract: The present invention aims to provide a process and an apparatus for recovering a PFC gas, which can readily bring cooling traps to a cryogenic temperature with a low-capacity refrigerator and can recover a high-purity PFC gas by applying deep freeze separation without the need for a multistage fractionator.Type: GrantFiled: August 17, 2000Date of Patent: April 23, 2002Assignee: Ebara CorporationInventors: Junichi Hayakawa, Tetsuo Komai, Yoichi Mori
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Publication number: 20020029586Abstract: Hyperpolarizers which produce hyperpolarized noble gases include one or more on-board NMR monitoring coils configured to monitor the polarization level of the hyperpolarized gas at various production points in the polarized gas production cycle. A dual symmetry NMR coil is positioned adjacent the optical pumping cell and is in fluid communication with a secondary reservoir in fluid communication with the polarized gas dispensing or exit flow path. This can measure the post-thaw polarization of the gas “on-board” the polarizer. Alternately or additionally, a NMR monitoring coil is assembled to the exit port portion of tie optical pumping cell to give a more reliable indication of the polarization level of the gas as it flows out of the gas optical pumping cell. Another NMR monitoring coil can be positioned in a cryogenic bath adjacent a quantity of frozen polarized 129Xe to determine the polarization level of the frozen gas.Type: ApplicationFiled: August 23, 2001Publication date: March 14, 2002Inventor: Bastiaan Driehuys
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Publication number: 20020000096Abstract: Volatile compounds (“VCs”), especially volatile organic compounds (“VOCs”), are cryogenically removed from a process gas stream (PW) by cooling the gas stream in a condenser to condense the VC to form both liquid VC and VC ice and providing a treated process gas essentially freed of the VC but containing entrained VC ice particles, which are subsequently removed by passing the treated process gas through a filter downstream of the condenser to remove at least particles of a size greater than 50 &mgr;m. The condensation can be conducted in an indirect heat exchanger or by direct contact of the process gas with a liquid cryogen such as liquid nitrogen. It is preferred that the filter removes VC ice particles greater than 1 &mgr;m.Type: ApplicationFiled: June 12, 2001Publication date: January 3, 2002Inventors: Jean-Philippe Trembley, John Louis Griffiths
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Patent number: 6318092Abstract: Methods of hyperpolarizing a noble gas by spin-exchange optical pumping use an alkali metal hybrid comprising a primary alkali metal and an auxiliary alkali metal to effectuate spin transfer interaction among the primary alkali metal, the auxiliary alkali metal, and the noble gas.Type: GrantFiled: February 15, 2000Date of Patent: November 20, 2001Assignee: The Trustees of Princeton UniversityInventors: William Happer, Gordon D. Cates, Jr., Mikhail V. Romalis, Christopher J. Erickson
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Patent number: 6305190Abstract: Methods of collecting, thawing, and extending the useful polarized life of frozen polarized gases include heating a portion of the flow path and/or directly liquefying the frozen gas during thawing. A polarized noble gas product with an extended polarized life product is also included. Associated apparatus such as an accumulator and heating jacket for collecting, storing, and transporting polarized noble gases include a secondary flow channel which provides heat to a portion of the collection path during accumulation and during thawing.Type: GrantFiled: November 14, 2000Date of Patent: October 23, 2001Assignee: Medi-Physics, Inc.Inventors: Bastiaan Driehuys, David Zollinger, Daniel Deaton, K. C. Hasson, Alan Langhorn
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Patent number: 6301928Abstract: The present invention provides a method for preventing the decrease of the efficiency of heat transfer, caused by frost formation, in a precooler of an air breathing engine. In the precooler, the heat exchanger tube is provided. Into the heat exchanger tube, liquid hydrogen serving as a coolant is supplied. The main air flow is sent to the precooler via the intake duct, and the main air flow which is cooled down there, is then sent to a compressor of the air breathing engine. Via the nozzle provided in the middle of the intake duct, ethanol is mixed into the main air flow. Ethanol is carried into the precooler, and condenses together with the water vapor on the surface of the heat exchanger tube. A frost layer thus formed has less cavities and low thermal resistance as compared to that formed when the water vapor condenses solely. Therefore, the decrease of the performance of the heat exchanger, which is caused by the frost formation, can be prevented.Type: GrantFiled: July 1, 1999Date of Patent: October 16, 2001Assignee: The Director-General of the Institute of Space and Astronautical ScienceInventors: Nobuhiro Tanatsugu, Kenya Harada
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Patent number: 6295834Abstract: Hyperpolarizers which produce hyperpolarized noble gases include one or more on-board NMR monitoring coils configured to monitor the polarization level of the hyperpolarized gas at various production points in the polarized gas production cycle. A dual symmetry NMR coil is positioned adjacent the optical pumping cell and is in fluid communication with a secondary reservoir in fluid communication with the polarized gas dispensing or exit flow path. This can measure the post-thaw polarization of the gas “on-board” the polarizer. Alternately or additionally, a NMR monitoring coil is assembled to the exit port portion of the optical pumping cell to give a more reliable indication of the polarization level of the gas as it flows out of the gas optical pumping cell. Another NMR monitoring coil can be positioned in a cryogenic bath adjacent a quantity of frozen polarized 129Xe to determine the polarization level of the frozen gas.Type: GrantFiled: June 30, 1999Date of Patent: October 2, 2001Assignee: Medi-Physics, Inc.Inventor: Bastiaan Driehuys
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Patent number: 6276169Abstract: Liquid CO2 is expanded in specially designed primary and secondary nozzles to produce frozen solid CO2. The impurities initially contained in the liquid CO2 are trapped inside of the frozen CO2, which is collected in a clean container. The container is emptied on top of a high purity surface. The impurities are concentrated on the surface, since these impurities are non-volatile and do not escape with the CO2 gas formed as the frozen CO2 is heated by the ambient temperature to its sublimation point. After all of the frozen CO2 has sublimed, the surface can be analysed by standard analysis methods to determine quantity and composition of the impurities. The determination and quantification of non-volatile impurities, such as organic oils and greases, in the CO2 supply that feeds, for example, cleaning systems utilizing CO2, is thus made possible.Type: GrantFiled: October 4, 1999Date of Patent: August 21, 2001Assignee: Eco-Snow Systems, Inc.Inventors: Charles W. Bowers, Wilfried Krone-Schmidt
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Patent number: 6158242Abstract: The present invention relates to an apparatus and a method for efficiently and cost-effectively removing moisture from pressurized gas stream to any required low level. The invention adopts an irregular matrix of finned pipes to remove the moisture as liquid and solid deposits. Clogging is completely eliminated in the freezer and heat recuperator of this apparatus. The dew-point of the dried gas may be reduced to under -100.degree. F. The method and the apparatus provided by the present invention are universally applicable to the dehydration of all kind of gases, and, hence, can replace all the three major dehydration methods and dehydrators currently in the market, i.e., the solid desiccant absorption, the liquid desiccant absorption, and the refrigeration dehydration. No BTEX pollutant is emitted to the atmosphere when applied to natural gas dehydration.Type: GrantFiled: October 20, 1999Date of Patent: December 12, 2000Inventor: Yingzhong Lu
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Patent number: 6134914Abstract: A process is disclosed for separating a component from a gaseous mixture, in particular for separating xenon from the breathing gas exhaled by an anaesthetized patient. The disclosed process has the following steps: the gaseous mixture is brought into contact with a cooling surface at a temperature below the melting point of the components to be separated, the proportion of the gaseous mixture which is not condensed on the cooling surface in a solid state is carried away, and the component condensed on the cooling surface is heated above the melting point of the component to be separated. Also disclosed are a device for carrying out this process, a corresponding process for recovering anaesthetic gas and an associated anaesthetic equipment.Type: GrantFiled: November 15, 1999Date of Patent: October 24, 2000Assignee: Messer Griesheim GmbHInventors: Manfred Eschwey, Reiner Hamm, Peter Neu, Renate Schmidt, Georg Schroeder
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Patent number: 6134913Abstract: The invention comprises a new and unique 3He gas polarization process. In dition, it provides for an improved diaphragm pump configuration. This arrangement allows the 3He gas and 3He-4He gas mixture to be polarized and compressed to a pressure in the range of one bar and placed into a glass storage cell without significant loss of polarization.Type: GrantFiled: October 15, 1998Date of Patent: October 24, 2000Assignee: The United States of America, as represented by the Secretary of CommerceInventor: Thomas R. Gentile
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Patent number: 6125654Abstract: The production and usage of hyperpolarized .sup.129 Xenon which comprises providing solid xenon with either an internal (dissolved) or external (imbedded) nuclear spin relaxant, loading and positioning the solid xenon in a low temperature refrigerator operating in the range of 5 mK to 30 mK with a surrounding magnetic field of between about 10 and 20 Tesla enabling high xenon spin polarizations between about 10% and 50% to be obtained in a time of about 1-3 days owing to the properties of the relaxant, separating the xenon from the relaxant or otherwise rendering the relaxant inoperable after polarizing and thereby switching off further relaxation and insuring preservation of the polarization of the xenon in solid, liquid or gaseous form for storage or external use for long times, ranging from weeks to the order of minutes, depending on the usage conditions.Type: GrantFiled: October 16, 1998Date of Patent: October 3, 2000Assignee: Syracuse UniversityInventor: Arnold Honig
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Patent number: 6085743Abstract: A system, and corresponding method, that interfaces with a gas polarization system to deliver a polarized noble gas to a subject for inhalation. Large volumes of polarized noble gas are obtained by repeated production/freezing cycles of a spin-exchange system. A storage cylinder is provided for storing a polarized noble gas. A gas delivery line is coupled to the storage cylinder and selectively delivers the polarized noble gas to the storage cylinder, and from the storage cylinder to the subject. A vacuum means is in communication with the gas delivery line for evacuating the storage cylinder in the gas delivery line prior to the noble gas being delivered thereto.Type: GrantFiled: May 30, 1997Date of Patent: July 11, 2000Assignee: The Regent of the University of MichiganInventors: Matthew S. Rosen, Scott D. Swanson, Kevin P. Coulter, Robert C. Welsh, Timothy Chupp
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Patent number: 6082133Abstract: An apparatus for separating CO.sub.2 from a mixture of gases includes CO.sub.2 and a second gas, the apparatus includes an active heat exchanger and a regenerating heat exchanger. The active heat exchanger includes a heat exchange surface in contact with the mixture of gases. The mixture of gases is present in the active heat exchanger at a predetermined pressure which is chosen such that CO.sub.2 freezes on the heat exchange surface when the surface is cooled by a refrigerant having a temperature below that at which CO.sub.2 freezes at the predetermined pressure. The regenerating heat exchanger includes a heat exchange surface in contact with the refrigerant and also in contact with a layer of frozen CO.sub.2. The refrigerant enters the regenerating heat exchanger at a temperature above that at which the CO.sub.2 in the frozen layer of CO.sub.2 sublimates. The sublimation of the solid CO.sub.Type: GrantFiled: February 5, 1999Date of Patent: July 4, 2000Assignee: Cryo Fuel Systems, IncInventors: Michael A. Barclay, Thomas C. Brook, John A. Barclay, Raymond R. Tison
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Patent number: RE37402Abstract: The present invention relates to an accessory structure for vehicle air-conditioner for improving the compartment atmosphere by cleaning the evaporator as heat exchanger and others or feeding aromatic or other functional solvent in a vehicle air-conditioner for taking in external air or internal air from an air-conditioning air intake route, and more particularly to an accessory structure for vehicle air-conditioner capable of improving the compartment atmosphere, by connecting a solvent feed route to solvent flow injection means provided at the upstream side of the heat exchanger in the air-conditioning air intake route, providing the base end of the solvent feed route with receiving means separated from the solvent source, fixing the receiving means in a specific place in the compartment, and putting in an accommodating space such as glove box, while separating the solvent source such as filled container from the receiving means, thereby preventing the solvent source from being ruptured or damaged, and moreType: GrantFiled: August 16, 1999Date of Patent: October 9, 2001Inventor: Yasumasa Akazawa