Spaced Initial Charging Patents (Class 62/646)
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Patent number: 12123646Abstract: A system and method for liquefaction of natural gas using two distinct refrigeration circuits having compositionally different working fluids and operating at different temperature levels is provided. The turbomachinery associated with the liquefaction system are driven by a single three-pinion or four-pinion integral gear machine with customized pairing arrangements. The system and method of natural gas liquefaction further includes the conditioning of a lower pressure natural gas containing feed stream to produce a purified, compressed natural gas stream at a pressure equal to or above the critical pressure of natural gas and substantially free of heavy hydrocarbons to be liquefied.Type: GrantFiled: April 8, 2022Date of Patent: October 22, 2024Assignee: Praxair Technology, Inc.Inventor: Henry Edward Howard
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Patent number: 12098883Abstract: An air gas separation plant comprising, in the direction of circulation of the air stream: a compression means that makes it possible to compress the air stream to a pressure P1 of between 1.15 bar abs and 2 bar abs, an adsorption unit of TSA type, and a cryogenic distillation unit, with the adsorption unit comprising at least two adsorbers A and B each having a parallelepipedal casing arranged horizontally and comprising: an air stream inlet and an air stream outlet, a fixed bed adsorbent mass, likewise of parallelepipedal shape, the faces of which are parallel to the faces of the casing; and a set of volumes allowing the air stream to pass through the adsorbent mass horizontally, over the entire cross-section and throughout the entire thickness thereof.Type: GrantFiled: February 12, 2020Date of Patent: September 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Benoit Davidian
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Patent number: 12061045Abstract: In a process for starting up an air separation unit, which is at a temperature of above 0° C., the air separation unit comprising a main air compressor for compressing the feed air, a booster driven by a turbine and a venting conduit connected downstream of the booster and upstream of the main heat exchanger wherein in order to start up the air separation unit, once the turbine is operating at said given speed, the venting conduit is opened to send at least part of the air compressed in the booster from the booster outlet to the atmosphere.Type: GrantFiled: December 19, 2018Date of Patent: August 13, 2024Assignee: L'Air Liquide, Societe Anonyme Pour I'Etude et I'Exploitation des Procedes Georges ClaudeInventors: Eric Day, Fei Gao, Huali Xie
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Patent number: 12055345Abstract: An air separation unit and associated method for separating air by cryogenic distillation using a distillation column system including a higher pressure column, a lower pressure column, an intermediate pressure kettle column, and an argon column arrangement is provided. The disclosed air separation unit and method is particularly suited for production of an argon product as well as several nitrogen products wherein a portion of the nitrogen overhead intermediate pressure kettle column is taken as an intermediate or elevated pressure nitrogen product. The present air separation unit and associated method employs a once-through kettle column reboiler, a once-through kettle column condenser while the argon condenser condenses an argon-rich vapor stream against a pumped oxygen stream from the bottom of the lower pressure column.Type: GrantFiled: July 28, 2022Date of Patent: August 6, 2024Assignee: Praxair Technology, Inc.Inventors: Neil M. Prosser, James R. Handley
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Patent number: 12044362Abstract: The filling station (1) for means of transport (4) comprises: a supply (2) of a methane pipeline transporting gaseous methane; a liquefaction assembly (A) connected in a fluid-operated manner to the supply (2) and adapted to liquefy the gaseous methane conveyed by the methane pipeline to obtain liquid methane; at least one dispenser (3) of the liquid methane, which is connected in a fluid-operated manner to the liquefaction assembly (A) and is connectable in a removable manner to a means of transport (4) to supply the means of transport (4) with the liquid methane.Type: GrantFiled: October 3, 2019Date of Patent: July 23, 2024Assignee: GRAF Industries S.p.A.Inventors: Mario Mormile, Marco Antonino Palella, Andrea Vaccari
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Patent number: 12025372Abstract: A method for separating air by cryogenic distillation in a system of columns comprising a first column and a second column operating at a lower pressure than the first column, comprising the steps of compressing all of the feed air in a first compressor to a first output pressure of at least 1 bar greater than the pressure of the first column, sending a first portion of the air under the first output pressure to the second compressor, and compressing the air to a second output pressure, cooling and condensing at least a portion of the air under the second output pressure in a heat exchanger, withdrawal of a liquid from a column of the system of columns, pressurising the liquid and evaporating the liquid by heat exchange in the heat exchanger, and pressure reduction of a portion of the compressed air to a second output pressure, at least partially evaporating said air in the heat exchanger, optionally additional heating of said air in the heat exchanger, and sending at least a portion of this air to the secondType: GrantFiled: May 18, 2018Date of Patent: July 2, 2024Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Jean-Pierre Tranier
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Patent number: 11976880Abstract: A method for low temperature separation of air using an air separating installation having a distillation column system which has a first, a second, a third and a fourth separating unit. Compressed and cooled air is fed into the first separating unit. An oxygen-enriched, nitrogen-depleted, argon-containing first sump liquid and a nitrogen-enriched, oxygen-depleted first head gas are formed by means of the first separating unit. An oxygen-rich second sump liquid and an argon-enriched second head gas are formed by means of the second separating unit. A liquid return to the second separating unit is provided by means of the third separating unit. A fourth sump liquid and a fourth head gas are formed by means of the fourth separating unit, and the fourth sump liquid is at least partially returned to the second separating unit.Type: GrantFiled: August 20, 2019Date of Patent: May 7, 2024Assignee: Linde GmbHInventor: Stefan Lochner
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Patent number: 11933538Abstract: A moderate pressure nitrogen and argon producing cryogenic air separation unit is provided that includes a three distillation column system and turbine air stream bypass arrangement or circuit. The turbine air stream bypass arrangement or circuit is configured to improve argon and nitrogen recoveries in select operating modes by optionally diverting a portion of the turbine air stream to a nitrogen waste stream circuit drawn from the lower pressure column of the cryogenic air separation unit such that the diverted portion of the turbine air stream bypasses the distillation column system.Type: GrantFiled: April 14, 2021Date of Patent: March 19, 2024Assignee: Praxair Technology, Inc.Inventors: Brian R. Kromer, Neil M. Prosser
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Patent number: 11933541Abstract: A system and method for producing two or more nitrogen product streams and a crude argon stream from a nitrogen and argon producing air separation unit is provided. The disclosed embodiments of the cryogenic-based nitrogen and argon producing air separation units and associated air separation cycles include the means for directing a first portion of a boil-off stream from an argon condenser of the air separation unit to a waste expansion refrigeration circuit and concurrently recycling a second portion of the boil-off stream from the argon condenser to the main air compression system of the air separation unit to be mixed or blended with the incoming feed air. Optionally, a third portion of the boil-off stream from the argon condenser may be further compressed in a cold compressor and returned to the lower pressure column.Type: GrantFiled: August 11, 2021Date of Patent: March 19, 2024Assignee: Praxair Technology, Inc.Inventor: Zhengrong Xu
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Patent number: 11890044Abstract: The instant disclosure relates to electrophysiology catheters for tissue ablation. In particular, the instant disclosure relates to a cryogenic ablation balloon with safety features that facilitate identification of a leak into an interstitial space between inner and outer balloons as part of the ablation balloon catheter assembly, and prevents egress of cryogenic fluid out of the ablation balloon.Type: GrantFiled: December 5, 2017Date of Patent: February 6, 2024Assignee: ST. JUDE MEDICAL, CARDIOLOGY DIVISION, INC.Inventors: Troy T. Tegg, Salo Arias, Derek Sutermeister
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Patent number: 11828532Abstract: A method and apparatus for transferring a first liquid removed from an outlet of a first distillation column to an inlet of a second distillation column is provided. The second distillation column operates at a higher pressure than the first distillation column, and the inlet of the second distillation column is at higher elevation as compared to the outlet of the first distillation column. The method advantageously transfers the first liquid from the outlet to the inlet by mixing with a sufficient amount of a lower density second liquid that results in a mixed liquid having a reduced density as compared to the first liquid.Type: GrantFiled: December 31, 2020Date of Patent: November 28, 2023Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Eric Day
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Patent number: 11602713Abstract: A method for cryogenic separation of air uses an air separation plant, wherein, in a mass transfer column, a liquid first fluid and a gaseous second fluid are subjected to mass transfer with one another. A gaseous third fluid is removed from the column and is at least partly discharged from the air separation plant. A liquid fourth fluid is removed from the column and is at least partly fed into a low-pressure column. The first fluid is formed using at least a part of an oxygen-rich liquid removed from the low-pressure column. The second fluid is formed using an oxygen-enriched liquid removed from a high-pressure column. The oxygen-enriched liquid removed from the high-pressure column and bottom liquid of the mass transfer column are mixed and partly evaporated in a condenser-evaporator. A liquid fifth fluid is removed from the mass transfer column between a feed point for the first fluid and a feed point for the oxygen-enriched liquid, and is at least partly fed into the low-pressure column.Type: GrantFiled: April 18, 2019Date of Patent: March 14, 2023Assignee: Linde AktiengesellschaftInventor: Dimitri Golubev
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Patent number: 11578916Abstract: A method and a device for producing an air product based on cryogenic rectification; after being cooled by a main heat exchanger, raw material air and nitrogen compressed by means of a compressor are sent to a rectification system for low temperature separation. In the rectification system, products such as oxygen and nitrogen are obtained by means of low temperature separation, and oxygen-enriched liquid air is obtained at or near the bottom of a rectification tower. The oxygen-enriched liquid air or liquid-state air in the rectification system is sent out after being raised to a target pressure by means of a low temperature liquid air pump; air products of various pressures can be produced by means of selecting low temperature liquid air pumps with different lifts or by connecting in series different amounts of low temperature liquid air pumps.Type: GrantFiled: December 29, 2017Date of Patent: February 14, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georqes ClaudeInventors: Bowei Zhao, Alain Briglia, Fengjie Xue
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Patent number: 11566841Abstract: A method for producing liquid nitrogen using a residual gas stream derived from a flue gas of a power plant is provided. The residual gas stream is purified in a front-end purification unit to remove freezable components and then the purified stream is compressed. Following compression, the stream can be divided into a first portion and a second portion, wherein the first portion is cooled and sent to a distillation column, wherein oxygen and argon are separated, thereby leaving an essentially pure gaseous nitrogen stream. The gaseous nitrogen stream can then be liquefied using refrigeration provided by expanding the second portion of the purified stream. In a preferred embodiment, the second portion is expanded in two turbines, and the gaseous nitrogen is compressed in a cold nitrogen booster, which is powered by one of the two turbines. In an additional embodiment, after warming, the expanded second portion of the purified stream can be used to regenerate the front-end purification unit.Type: GrantFiled: November 27, 2019Date of Patent: January 31, 2023Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Michael A Turney
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Patent number: 11549747Abstract: A cryogenic air separation apparatus comprises: a heat exchanger, a first rectification column, a first condenser, a second rectification column, a third rectification column, a second condenser, a high-purity oxygen rectification column, a third condenser, a nitrogen compressor, and a compressed recycled gas line L52 for introducing product nitrogen gas compressed by the first nitrogen compressor into a warm end (heat source) of an ultra-high-purity oxygen vaporizer as a compressed recycled gas.Type: GrantFiled: April 3, 2020Date of Patent: January 10, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Geordes ClaudeInventors: Kenji Hirose, Shinji Tomita
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Patent number: 11549433Abstract: The present invention relates to systems and methods for controlling a power production plant and optionally providing a one or more product streams for an end use thereof. Control of a power production plant specifically can include executing one or more functions effective for adjusting a heat profile of a heat exchange unit (HEU) operating with a plurality of streams passing therethrough. This can include implementing a control function that alters a flow of one or more of the plurality of streams by adding flow to or withdrawing flow one or more of the plurality of streams at an intermediate temperature range within the HEU at a point that is positioned between a first end and a second end of the HEU.Type: GrantFiled: October 22, 2020Date of Patent: January 10, 2023Assignee: 8 Rivers Capital, LLCInventors: Brock Alan Forrest, Xijia Lu, Jeremy Eron Fetvedt, Navid Rafati
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Patent number: 11512897Abstract: A process for recovering at least one fluid (e.g. argon gas and/or nitrogen gas, etc.) from a feed gas (e.g. air) can include utilization of a compression system, primary heat exchanger unit, plant processing units to separate and recover at least one desired fluid (e.g. nitrogen gas, argon gas, etc.). In some embodiments, the process can be configured so that fluid flows output from a low pressure column and/or high pressure column of the plant can provide a condensation duty or refrigeration duty that is utilized to process certain fluid flows for recovery of argon and/or nitrogen gases. Some embodiments can be configured to provide an improved recovery of argon and/or nitrogen as well as an improvement in operational efficiency by reducing an amount of power (e.g. electrical power) needed to recover the nitrogen and/or argon.Type: GrantFiled: January 14, 2021Date of Patent: November 29, 2022Assignee: Air Products and Chemicals, Inc.Inventors: D. Michael Herron, Alan D. Berger
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Patent number: 11504692Abstract: A packing device for mass and heat transfer with a subject fluid includes a housing having opposing ends, and subject fluid openings at each opposing end defining a subject fluid flow path for at least one subject fluid flowing through the packing device. A plurality of mass and heat transfer plates each include an interior heat exchange fluid channel disposed between interior heat transfer surfaces of the mass and heat transfer plates. A heat exchange fluid inlet and fluid outlet can supply and remove heat exchange fluid to the heat exchange fluid channels of the mass and heat transfer plates. The mass and heat transfer plates can be oriented to define there between fluid flow channels for the subject fluid. A method and system for mass and heat transfer with a subject fluid, and a method and system for the removal of CO2 from a gas stream are disclosed.Type: GrantFiled: June 4, 2020Date of Patent: November 22, 2022Assignee: UT-BATTELLE, LLCInventors: Canhai Lai, Lonnie J. Love, James E. Parks, II, Xin Sun, Constantinos Tsouris, Michael Matuszewski
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Patent number: 11353262Abstract: A portion of feed air is expanded and cooled in front of a main heat exchanger, and is used as cold for precooling the remaining unexpanded feed air inside the main heat exchanger. A portion of the feed air precooled inside the main heat exchanger is removed to outside the main heat exchanger, expanded and cooled, and used as cold to cool the remaining unexpanded precooled feed air inside the main heat exchanger.Type: GrantFiled: March 20, 2019Date of Patent: June 7, 2022Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Kenji Hirose
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Patent number: 11262125Abstract: A system and method for flexible production of argon from a cryogenic air separation unit is provided. The cryogenic air separation unit is capable of operating in a ‘no-argon’ or ‘low-argon’ mode when argon demand is low or non-existent and then switching to operating in a ‘high-argon’ mode when argon is needed. The recovery of the argon products from the air separation unit is adjusted by varying the percentages of dirty shelf nitrogen and clean shelf nitrogen in the reflux stream directed to the lower pressure column. The cryogenic air separation unit and associated method also provides an efficient argon production/rejection process that minimizes the power consumption when the cryogenic air separation unit is operating in a ‘no-argon’ or ‘low-argon’ mode yet maintains the capability to produce higher volumes of argon products at full design capacity to meet argon product demands.Type: GrantFiled: January 2, 2018Date of Patent: March 1, 2022Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Neil M. Prosser, Yang Luo, Richard D. Lenz, Kevin J. Saboda
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Patent number: 11118734Abstract: A cold-box system includes a bulk gas tank, and a plurality of cold-box compartments operationally associated with the bulk gas tank. A cold-box apparatus includes a plurality of cold-box compartments operationally associated with a bulk gas tank. In one embodiment the cold-box compartments may be spaced apart from the tank aboard a waterborne platform. The system and apparatus provide redundancy regarding power aboard ship for the bulk gas tank.Type: GrantFiled: October 25, 2018Date of Patent: September 14, 2021Assignee: MAN Energy Solutions SEInventor: Christer Carlander-Reuterfelt
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Patent number: 11090624Abstract: A reactor system comprising a first reactor assembly, a first pressure transition assembly, a second reactor assembly and a second pressure transition assembly.Type: GrantFiled: July 31, 2018Date of Patent: August 17, 2021Assignee: OHIO STATE INNOVATION FOUNDATIONInventors: Liang-Shih Fan, Dawei Wang, Mandar Kathe
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Patent number: 10995983Abstract: A method and the apparatus for obtaining a compressed gas product by means of cryogenic separation of air in a distillation column system which has a high-pressure column and a low-pressure column. All of the feed air is compressed in a main air compressor to a first pressure which is at least 4 bar higher than the operating pressure of the high-pressure column. A first partial flow of the feed air compressed in the main air compressor is cooled to an intermediate temperature in a main heat exchanger and is expanded so as to perform work in a first air turbine. At least a first part of the first partial flow expanded so as to perform work is introduced into the distillation column system.Type: GrantFiled: July 1, 2015Date of Patent: May 4, 2021Assignee: LINDE AKTIENGESELLSCHAFTInventor: Dimitri Goloubev
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Patent number: 10866024Abstract: Method for separating air by cryogenic distillation, wherein at least part of the air to be distilled is boosted in an air booster, compressed air is allowed to expand in at least one expansion turbine and, if the pressure drop between two points of the booster passes under a threshold and/or a flow of the booster passes under a minimum flow of the booster, part of the air boosted in the booster is allowed to expand without having been cooled between the booster and the expansion turbine and the boosted expanded air is sent upstream or downstream of the at least one turbine, without having been cooled in the heat exchanger, after having been boosted.Type: GrantFiled: August 3, 2018Date of Patent: December 15, 2020Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Cavagne Patrice, Nicolas Chamontin, Benedicte Dos Santos, Laurent Richaume
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Patent number: 10794370Abstract: A hydraulic propulsion system converts heat or thermal energy into hydraulic energy, and such hydraulic energy into mechanical work. The hydraulic propulsion system includes a thermal unit, a hydraulic cylinder with pistons and springs mounted therein, one or more hydraulic motors, one or more hydraulic accumulators, and one or more electrical energy generators, as well as a plurality of flow control valves to control the flow of hydraulic fluid between the various components. The hydraulic propulsion system may be enhanced by a sonic transmission unit including a sonic wave generator.Type: GrantFiled: March 15, 2019Date of Patent: October 6, 2020Assignee: A & A International, LLCInventors: Horia Abaitancei, Cornel Mihai, Stefan Ioana
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Patent number: 10794630Abstract: Method for separating air by cryogenic distillation, wherein air is compressed in a compressor and is subsequently sent to a heat exchanger, with the air cooled in the exchanger being sent to a check valve downstream of the heat exchanger and subsequently to a turbine, the valve being positioned so that air from a short-circuiting duct cannot return to the exchanger from the compressor.Type: GrantFiled: August 3, 2018Date of Patent: October 6, 2020Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Patrice Cavagne, Benedicte Dos Santos, Yann-Pierrick Lemaire
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Patent number: 10712088Abstract: A method of temperature balancing for thermal integration of an air separation unit (ASU) with an oxycombustion power generation system, including compressing air through a plurality of compression stages, and routing a first stage compressed air stream through a first heat exchanger in heat exchange communication with a subsequent stage compressed air stream to lower the first stage compressed air stream temperature and increase the temperature of a subsequent stage compressed air stream.Type: GrantFiled: May 4, 2018Date of Patent: July 14, 2020Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Pierre-Philippe Guerif, Alain Guillard, Vincent Follaca
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Patent number: 10605523Abstract: A process comprises a first set of distillation columns and a second set of distillation columns, a low-pressure column of the first set being connected to a column operating at higher pressure of the second set by means of a gas arriving from the top of the column operating at a higher pressure and/or by means of a fluid arriving from the low-pressure column.Type: GrantFiled: November 7, 2014Date of Patent: March 31, 2020Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Benoit Davidian, Richard Dubettier-Grenier
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Patent number: 10591209Abstract: An air separation plant for obtaining product containing argon by low temperature separation of compressed, cooled feed air. The air separation plant comprises a high-pressure column, a multi-part low-pressure column having a base segment and a head segment and a multi-part crude argon column having a base segment and a head segment. An oxygen-enriched flow is obtained from part of the feed air in the high pressure column, an argon-enriched flow is obtained from part of the oxygen-enriched flow in the low-pressure column, and an argon-rich flow is obtained from part of the argon-enriched flow in the crude argon column. Liquid flow is transferred from a lower region of the head segment of the low-pressure column and from a lower region of the base segment of the crude argon column into an upper region of the base segment of the low-pressure column.Type: GrantFiled: March 5, 2014Date of Patent: March 17, 2020Assignee: LINDE AKTIENGESELLSCHAFTInventor: Stefan Lochner
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Patent number: 10480853Abstract: A method and plant for the cryogenic separation of air, the plant having an air compressor, a heat exchanger and a distillation column system having a low-pressure column at a first pressure and a high-pressure column at a second pressure. Feed air is compressed in the air compressor to a third pressure at least 2 bar above the second pressure A first fraction of compressed feed air is cooled in the heat exchanger and expanded in a first expansion turbine. A second fraction is cooled in the heat exchanger and expanded in a second expansion turbine A third fraction is compressed to a fourth pressure, cooled in the heat exchanger and then expanded. The third fraction is compressed to the fourth pressure in sequence in a recompressor, a hot first turbine booster and a second turbine booster. A dense fluid expander is used to expand the third fraction.Type: GrantFiled: July 28, 2015Date of Patent: November 19, 2019Assignee: LINDE AKTIENGESELLSCHAFTInventors: Tobias Lautenschlager, Dimitri Golubev
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Patent number: 10458702Abstract: A method and device used to variably obtain a compressed-gas product by means low-temperature separation of air in a distillation column system. In a first operating mode, a first amount of first compressed-gas product is obtained, and, in a second operating mode, a second, smaller amount is obtained. In the first operating mode, a first amount of air is compressed in the main air compressor, and in the second operating mode, a second, larger amount is compressed in the main air compressor.Type: GrantFiled: June 25, 2015Date of Patent: October 29, 2019Assignee: LINDE AKTINGESELLSCHAFTInventor: Dimitri Golubev
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Patent number: 10443931Abstract: The method and the device arc used for the cryogenic decomposition of air in a distillation column system for separating nitrogen and oxygen, said system having a first high-pressure column (23), a low-pressure column (25, 26), and three condenser-evaporators, namely a high-pressure column head condenser (27), a low-pressure column bottom evaporator (28), and an auxiliary condenser (29; 228).Type: GrantFiled: September 20, 2012Date of Patent: October 15, 2019Assignee: LINDE AKTIENGESELLSCHAFTInventors: Georg Demski, Alexander Alekseev, Thomas Rathbone, Dimitri Goloubev, Ayhan Yayli
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Patent number: 10436507Abstract: Process and apparatus for producing pressurized gaseous nitrogen by cryogenic separation of air. The distillation column system includes a high pressure column, a medium pressure column, a main condenser and top condenser both being condenser-evaporators. Compressed and purified feed air is cooled in a heat exchanger and introduced to the distillation system. A gaseous nitrogen stream from the high pressure column is condensed in the main condenser. Bottom liquid of the medium pressure column is evaporated and gaseous nitrogen from the medium pressure column is condensed in the top condenser. Liquid nitrogen from the medium pressure column is pressurized and introduced to the high pressure column. A second gaseous nitrogen stream from the high pressure column is recovered as pressurized gaseous nitrogen product. A portion of the compressed and purified feed air is work-expanded and then warmed in the main heat exchanger.Type: GrantFiled: January 5, 2017Date of Patent: October 8, 2019Assignee: LINDE AKTIENGESELLSCHAFTInventor: Robert Michael Igra
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Patent number: 10401083Abstract: The plant is used for producing oxygen by cryogenic air separation. The plant has a high-pressure column, a low-pressure column and a main condenser. An argon-elimination column is in fluid connection with an intermediate point of the low-pressure column and is connected to an argon-elimination column head condenser. An auxiliary column has a sump region, into which gas is introduced from the argon-elimination column head condenser. The head of the auxiliary column is connected to a return flow liquid line, in order to introduce a liquid stream from the high-pressure column or the head condenser. The liquid stream has an oxygen content which is at least equal to that of air. At least one part of the crude liquid oxygen from the sump of the high-pressure column is fed to the auxiliary column at a first intermediate point.Type: GrantFiled: March 10, 2016Date of Patent: September 3, 2019Assignee: LINDE AKTIENGESELLSCHAFTInventors: Stefan Lochner, Thomas Nohlen, Lars Kirchner, Dimitri Golubev
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Patent number: 10359231Abstract: A method for controlling production of high pressure gaseous oxygen in a cryogenic air separation unit that uses a high pressure gaseous oxygen bypass together with adjustments to the split of the incoming compressed and purified air between the boiler air circuit and the turbine air circuit such that the volumetric ratio of the boiler air stream to the turbine air stream is reduced to between about 0.15:1 and 0.35:1.Type: GrantFiled: April 12, 2017Date of Patent: July 23, 2019Assignee: PRAXAIR TECHNOLOGY, INC.Inventor: Nick J. Degenstein
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Patent number: 10293386Abstract: A method of thermally servicing a solvent-refining column comprises: running a closed-loop water-steam system past a top and bottom of a first column, the first column containing at least a solvent and impurities; boiling pressurized water in the closed-loop water-steam system to steam using first heat from the top of the first column; compressing the steam in the closed-loop water-steam system to a higher temperature; and providing second heat to the first column by condensing the steam at the bottom of the first column after compression.Type: GrantFiled: November 21, 2017Date of Patent: May 21, 2019Assignee: Tesla, Inc.Inventor: Ryan Melsert
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Patent number: 10295253Abstract: The invention relates to a method for separating air by cryogenic distillation in a set of columns including a first column operating at a first pressure, a second column operating at a second pressure which is lower than the first pressure, and a third column operating at a third pressure, which is lower than the second pressure, wherein the third column includes first and second evaporator-condensers, and nitrogen from a cold compressor is sent to one of the evaporator-condensers.Type: GrantFiled: October 14, 2014Date of Patent: May 21, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Benoit Davidian
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Patent number: 10273155Abstract: A process and a related equipment for making ammonia make-up synthesis gas are disclosed, where: a hydrocarbon feedstock is reformed obtaining a raw ammonia make-up syngas stream; said raw syngas is purified in a cryogenic purification section refrigerated by a nitrogen-rich stream produced in an air separation unit; the nitrogen-rich stream at output of said cryogenic section is further used for adjusting the hydrogen/nitrogen ratio of the purified make-up syngas; an oxygen-rich stream is also produced in said air separation unit and is fed to the reforming section.Type: GrantFiled: May 22, 2017Date of Patent: April 30, 2019Assignee: Casale SAInventors: Ermanno Filippi, Geoffrey Frederick Skinner
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Patent number: 10247471Abstract: An argon reflux condensation system and method in which a plurality of once-through condensers are connected to an argon column of an air separation plant to condense argon-rich vapor streams for production of reflux to the argon column. Condensation of the argon-rich vapor streams is brought about through indirect heat exchange with crude liquid oxygen streams that partially vaporize and are introduced into a lower pressure column of the plant for further refinement. The flow rate of the crude liquid oxygen streams are sensed and controlled at locations in the air separation plant where the crude liquid oxygen is in a liquid state and in proportion to the size of the once-through heat exchangers. Prior to flowing into the once-through condensers, the partially vaporized crude oxygen stream enters a phase separator which separates the crude oxygen vapor from the crude liquid oxygen.Type: GrantFiled: July 11, 2018Date of Patent: April 2, 2019Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: James R. Handley, Brian S. Powell, Henry E. Howard, Vijayaraghavan S. Chakravarthy, Maulik R. Shelat, Steven R. Falta
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Patent number: 10222120Abstract: The invention relates to a method and device for generating two purified partial air streams under different pressures. A total air stream (1) is compressed to a first total air pressure. The compressed total air stream (5) is cooled with cooling water under the first total air pressure by way of heat exchange (4, 6). The heat exchange with cooling water for cooling the total air stream (5) is carried out as a direct heat exchange in a first direct contact cooler (6), at least in part. The cooled total air stream (9) is divided into a first partial air stream (10) and a second partial air stream (11). The first partial air stream (10) is purified in a first purification device (18) under the first total air pressure, generating the first purified partial air stream (19). The second partial air stream (11) is re-compressed to a higher pressure (12), which is higher than the first total air pressure.Type: GrantFiled: September 20, 2012Date of Patent: March 5, 2019Assignee: LINDE AKTIENGESELLSCHAFTInventors: Alexander Alekseev, Dimitri Goloubev
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Patent number: 10215489Abstract: A method and a device used to variably obtain a compressed-gas product by means of the low-temperature separation of air in a distillation column system. In a first operating mode, a first amount of first compressed-gas product is obtained, and, in a second operating mode, a second, smaller amount is obtained. In the first operating mode, a first amount of high-pressure column nitrogen is compressed in a nitrogen compressor and in the second operating mode, a second, larger amount is compressed in the nitrogen compressor.Type: GrantFiled: June 25, 2015Date of Patent: February 26, 2019Assignee: LINDE AKTIENGESELLSCHAFTInventor: Dimitri Golubev
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Patent number: 10209004Abstract: A method for obtaining an air product from an air separation plant having a distillation column system and a tank system. The tank system includes a first tank and a second tank. Cryogenic liquid is withdrawn from the distillation column system, stored in the tank system, and used as the air product. The cryogenic liquid is supplied to the first tank and withdrawn from the second tank during a first period, and is supplied to the second tank and withdrawn from the first tank during a second period. The tank system has a third tank to which cryogenic liquid withdrawn from the first tank and the second tank is transferred unheated. The air product is withdrawn from the third tank in liquid state, vaporized and discharged. Alternatively, the cryogenic liquid can be withdrawn from the third tank and stored in the liquid state in a fourth tank.Type: GrantFiled: January 4, 2017Date of Patent: February 19, 2019Assignee: LINDE AKTIENGESELLSCHAFTInventors: Stefan Lochner, Ralph Spöri, Christian Zimmermann
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Patent number: 10101084Abstract: An apparatus for the production of low pressure gaseous oxygen includes a heat exchanger and a system of columns comprised of an auxiliary column, a higher pressure column and a lower pressure column. The LP column and the HP column are thermally integrated via a top reboiler/condenser disposed on top of the HP column. The system of columns is configured to separate a cooled air stream into oxygen and nitrogen. The auxiliary column comprises a distillation section and a first and second reboiler. One of the reboilers is driven by the cooled air stream and the other reboiler is driven by a pressurized nitrogen stream. The first and second reboilers boil their fluids at the same pressure as the auxiliary column.Type: GrantFiled: July 31, 2015Date of Patent: October 16, 2018Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Paul Musicus
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Patent number: 10018414Abstract: A method for the production of low pressure gaseous oxygen includes providing a system of distillation columns and a heat exchanger, wherein the system of columns comprises a lower pressure column, a higher pressure column, an auxiliary column, the auxiliary column having a distillation section, a first reboiler, and a second reboiler, wherein the LP column and the HP column are thermally integrated via a top reboiler/condenser disposed on top of the HP column. A cooled air stream is rectified within the system of columns such that the auxiliary column produces a cold oxygen fluid that is then warmed in the heat exchanger to produce a low pressure oxygen product. The cooled air stream provides reboiling duty for the first reboiler prior to rectification within the system of columns, and a compressed nitrogen stream received from a cold end of the heat exchanger provides reboiling duty for the second reboiler.Type: GrantFiled: July 31, 2015Date of Patent: July 10, 2018Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Paul Musicus
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Patent number: 10012435Abstract: In a method for producing a first pressurized gas and a second gas on a one-off basis by cryogenic distillation of air, according to a first step, no fluid heats up or cools down in a second heat exchanger, and according to a second step, a flow of pressurized liquid from the double column heats up and vaporizes in the second exchanger to form a gas required on a one-off basis, a flow of air at the second pressure cools in the second exchanger.Type: GrantFiled: August 28, 2013Date of Patent: July 3, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Marie Cognard, Richard Dubettier-Grenier, Sylvain Gerard
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Patent number: 9995530Abstract: A cryogenic method for capturing carbon dioxide in the gaseous emissions produced from the fossil-energy combustion of solid, liquid, or gaseous fossil fuels in a power generation installation employing an OxyFuel mode of combustion.Type: GrantFiled: February 24, 2016Date of Patent: June 12, 2018Inventors: Charles Bliss, Mason Charles Moseley
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Patent number: 9989306Abstract: The method and device according to the invention provide for recovery of high-pressure oxygen and high-pressure nitrogen by low-temperature separation of air in a distillation-column system. This system comprises a high-pressure column, a low-pressure column, and a main condenser. A first air feed stream is cooled at a first subcritical pressure in a main heat exchanger to approximately dew point and introduced at least partially into the high-pressure column. A second air feed stream is brought to a second, supercritical, pressure, cooled, depressurized, and introduced at least partially into the distillation-column system. A first partial stream of the second air feed stream is cooled in the main heat exchanger, and a second partial stream is cooled in a high-pressure heat-exchanger system. The first and second partial streams are then merged and work-expanded in a liquid turbine.Type: GrantFiled: February 20, 2014Date of Patent: June 5, 2018Assignee: LINDE AKTIENGESELLSCHAFTInventor: Tobias Lautenschlager
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Patent number: 9976803Abstract: Process for producing gaseous oxygen by cryogenic distillation of air, wherein a portion of the feed air flow is brought to a pressure P1, by means of a first compressor, the suction temperature T0 of which is between 0 and 50° C., the gas at the pressure P1 is cooled, in order to generate an air stream at the pressure P1 and the temperature T1 between 5 and 45° C., a portion of the air compressed in the first compressor undergoes an additional compression step starting from the temperature T1 and pressure P1 to a pressure P2 greater than P1, then is cooled, to the temperature T2 where T2 and T1 differ by less than 10° C.Type: GrantFiled: September 9, 2014Date of Patent: May 22, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATTION DES PROCEDES GEORGES CLAUDEInventors: Alexis Asse, Ingrid Berthaume, Alain Briglia, Richard Dubettier-Grenier, Patrick Le Bot, Jean-Marc Peyron
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Patent number: 9964354Abstract: A method is provided for production of gaseous oxygen at high pressures by splitting a main air feed into at least three separate streams, with the first stream being fed to a heat exchanger and then a column system for rectification; the second stream being further compressed in a warm booster, partially cooled in the heat exchanger, expanded in a turbine coupled to the warm booster and then fed to the column system; the third stream being expanded in a warm expander before being introduced to the heat exchanger and introduced to the column system. In certain embodiments, substantially all of the main air feed is eventually introduced to the column system for rectification, resulting in reduced sizing of a main air compressor and improved product recoveries.Type: GrantFiled: January 19, 2016Date of Patent: May 8, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventor: Paul Musicus
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Patent number: 9964353Abstract: A system and method serve generate oxygen by low-temperature air separation in a distillation column system having a high-pressure column and a low-pressure column, a main condenser which is constructed as a condenser-evaporator, and an auxiliary column. A gaseous oxygen-containing fraction is introduced into the auxiliary column. A nitrogen-containing liquid stream from the high-pressure column, the main condenser or the low-pressure column is applied as reflux to the top of the auxiliary column. An argon-rich stream from an intermediate site of the low-pressure column is introduced into an argon removal column that has an argon removal column top condenser. The low-pressure column is arranged beside the high-pressure column, the main condenser is arranged over the high-pressure column, the auxiliary column is arranged over the main condenser, the argon removal column is arranged over the auxiliary column and the argon removal column top condenser is arranged over the argon removal column.Type: GrantFiled: March 3, 2016Date of Patent: May 8, 2018Assignee: Linde AktiengesellschaftInventors: Tobias Lautenschlager, Stefan Lochner