Abstract: A rare earth metal oxysulfide represented by a general formula R2O2S (R denotes one kind or two or more kinds of rare earth elements to be selected from a group of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, as wells as Y) is formed into spherical granules. The mean particle size of the granules is 0.05–1 mm and their relative density is 96% or over. The granules are used as a regenerative material at the liquid helium temperature.

Abstract: A system for producing high and ultra high purity nitrogen comprising a first column for the production of nitrogen and a second column having a top condenser wherein boil off from the second column top condenser is turboexpanded to generate refrigeration for the system.

Abstract: A system for producing high purity nitrogen comprising a higher pressure first column having a top condenser and a lower pressure second column wherein boil off from the first column top condenser is turboexpanded to generate refrigeration for the system.

Abstract: The invention relates to a method and a device for separating a gas component in a gas mixture by freezing. The gas component to be separated has the lower vapor pressure when compared with the other gas components in the gas mixture. A working temperature is chosen at which the gas components to be separated freezes out almost completely. The partial pressure of the other gas components at working temperature is kept lower than the vapor temperature of the other gas components at working temperature. Once the components to be separated have been frozen out, the other gases are evacuated. The device comprises at least two cooling tanks. Means are provided to alternately feed the gas mixture to the cooling tanks so that a predetermined partial pressure arises in each tank.

Abstract: This apparatus (3A, 3B) is for heat exchange between at least one first fluid available at a temperature at about ambient and at least one second fluid available at a cryogenic temperature below −20° C. It comprises structure alternately to circulate the first fluid through heat exchange material in an overall centripetal manner relative to a general central axis (X-X) of the apparatus (3), from a radially external inlet (17) of the apparatus, and structure to circulate the second fluid through the heat exchange material in an overall centrifugal manner relative to said central axis, from a radially internal inlet (18) of the apparatus. Use in cooling regenerators and exchangers, and if desired for simultaneous purification, of atmospheric air to be distilled.

Abstract: In a process for separating air in a plant comprising at least two columns (1, 3), some of the air (100) at an intermediate pressure is cooled in at least one passage of a heat-exchange system which is or are regenerated by a gas from the plant (17, 21) which may contain at least 50% oxygen. The rest of the air at the medium pressure (200) is either purified outside the heat-exchange system or sent to a passage which is purified in the same way.

Abstract: Super clean air suitable for use in a tunnel-type wafer transport system, etc., is produced efficiently with the specific energy consumption reduced and the yield improved by making good use of part of cooling energy and gas produced in a low temperature separation type nitrogen producing apparatus. Material air 1a collected from the atmosphere is pretreated in a room temperature adsorption tower 7, this pretreated air is adsorption treated at -60.degree. C. in a first low temperature adsorption tower 9, and the treated air 1c is further adsorption treated at -150.degree. C. in a second low temperature adsorption tower 10, thereby producing super clean air 1e containing not higher than 1 ppb of the chemical components other than nitrogen, oxygen and noble gases and having a dew point of not higher than -100.degree. C.

Abstract: An apparatus for separating CO.sub.2 from a mixture of gases includes CO.sub.2 and a second gas, the apparatus includes an active heat exchanger and a regenerating heat exchanger. The active heat exchanger includes a heat exchange surface in contact with the mixture of gases. The mixture of gases is present in the active heat exchanger at a predetermined pressure which is chosen such that CO.sub.2 freezes on the heat exchange surface when the surface is cooled by a refrigerant having a temperature below that at which CO.sub.2 freezes at the predetermined pressure. The regenerating heat exchanger includes a heat exchange surface in contact with the refrigerant and also in contact with a layer of frozen CO.sub.2. The refrigerant enters the regenerating heat exchanger at a temperature above that at which the CO.sub.2 in the frozen layer of CO.sub.2 sublimates. The sublimation of the solid CO.sub.

Abstract: Air is supplied to an air separation apparatus via a heat exchanger in which the entering air is cooled against an air gas separated in the separation apparatus. The air is first compressed in an adiabatic compressor. The air gas separated in the separation apparatus is humidified after it leaves the separation apparatus but before it reaches the heat exchanger.

Abstract: A process for further purification of nitrogen gas, thereby producing ultra-high purity nitrogen which is substantially free of hydrogen, oxygen and carbon monoxide, wherein the nitrogen gas is contacted with a metal-containing adsorbent at a temperature of 150 K. or less.

Abstract: A method for gas mixture demethanization is suitable for decreasing the loss of the target product (ethylene) and power requirements for gas mixture demethanization process.

Abstract: A method is provided for separation of air by cryogenic rectification comprising compressing feed air, passing the compressed feed air through a prepurifier wherein the air is substantially cleaned of impurities, thereafter cooling the cleaned air in a cooled regenerator and then introducing it into a cryogenic air separation facility wherein it is separated into nitrogen-rich and oxygen-rich components.

Abstract: An apparatus and method for recovering one or more components from the vapor feed in which the component is recovered from the vapor feed at a lower pressure within a lower pressure cold trap. Thereafter, a higher pressure cold trap is connected to the lower pressure cold trap and the component revaporizes in the lower pressure cold trap and resolidifies in the higher pressure cold trap. The higher pressure cold trap is then isolated and the component is allowed to thaw to build up a vapor pressure such that the component can be delivered for recovery at a high pressure. Two or more components having higher and lower boiling points can be recovered by low pressure cold traps set in series. Low pressure cold traps can be provided to operate in an out of phase relationship so that components are frozen on one set of lower pressure cold traps while being vaporized from the other set of cold traps.

Abstract: Air is supplied to an air separation apparatus via a heat exchanger in which the entering air is cooled against an air gas separated in the separation apparatus. The air is first compressed in an adiabatic compressor. The air gas separated in the separation apparatus is humidified after it leaves the separation apparatus but before it reaches the heat exchanger.

Abstract: A cryogenic rectification system for producing nitrogen, especially at low production flowrates, wherein incoming feed air is cooled by a regenerator without need for cold end imbalance and wherein exogenous cryogenic liquid is added to the rectification column.