Abstract: Azeotrope-like compositions are disclosed. The azeotrope-like compositions are mixtures of E-1-chloro-2,3,3,3-tetrafluoropropene with E-1,1,1,4,4,4-hexafluoro-2-butene or E-1,1,1,4,4,5,5,5-octafluoro-2-pentene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as dielectrics.

Abstract: A method and apparatus for the separation and recovery of SF6 from a gas mixture consisting essentially of SF6, CF4, and N2. The method and apparatus involve membrane separation to separate N2 from SF6 and CF4, and liquefaction to separate SF6 from CF4.

Abstract: The process recovers NF3 from a multicomponent fluid containing NF3, one or more components less volatile than NF3, and one or more components more volatile than NF3. The process uses a first distillation column and a second distillation column, each distillation column having a top and a bottom. The process includes the following steps: feeding the multicomponent fluid to the first distillation column at a first feed location below the top of the first distillation column; feeding a cryogenic liquid to the first or second distillation column adjacent the top of the first or second distillation column; withdrawing a mixture containing NF3 from the first distillation column; feeding the mixture to the second distillation column at a second feed location; separating NF3 from the mixture in the second distillation column; and removing a stream of NF3 from the second distillation column.

Abstract: This invention is directed to a method, and a system therefor, for recovering PFC using condensation by passing a PFC-containing feed stream into a condenser, preferably reflux condenser, to effect liquefaction into a PFC-containing condensate and a carrier gas stream, and passing the PFC-containing product into a mass transfer unit to fractionate the PFC-containing condensate into a high volatility PFC stream and a PFC product.

Abstract: A process for separating pentafluoroethane and 1,1,1-trifluoroethane, which comprises extraction distilling a mixed fluid comprising pentafluoroethane and 1,1,1-trifluoroethane in the presence of at least one extracting agent selected from the group consisting of esters and ketones each having a standard boiling point of from -10.degree. C. to 100.degree. C. Also disclosed is a process for separating pentafluoroethane, 1,1,1-trifluoroethane and chloropentafluoroethane, which comprises extraction distilling a mixed fluid comprising pentafluoroethane, 1,1,1-trifluoroethane and chloropentafluoroethane in the presence of at least one extracting agent selected from the group consisting of esters and ketones each having a standard boiling point of from -10.degree. C. to 100.degree. C.

Abstract: An ultra-high purity nitrogen trifluoride production method comprises: pressurizing a nitrogen trifluoride feed gas, eliminating moisture and carbon dioxide from the feed gas, and cooling down the same feed gas; causing the cooled feed gas to pass through adsorption columns, and introducing it into a medium-pressure rectification column by way of a reboiler in the medium-pressure rectification column, where it is rectified in the medium-pressure rectification column; introducing the resulting gas obtained by this rectification into a middle stage of a low-pressure rectification column, where it is rectified; and taking out ultra-high purity nitrogen trifluoride obtained by virtue of this rectification from the lower part of the low-pressure rectification column.

Abstract: A cryogenic system for the recovery of fluorine compounds from a carrier gas stream such as an effluent stream from a semiconductor facility comprising three cryogenic rectification columns and a mass transfer contacting device.

Abstract: The present invention relates to a system for separating a mixture containing at least two components, each component having a different volatility. The separation is achieved through the use of a fractional distillation column and upper and lower storage vessels in conjunction with a chilling unit for forming a liquid phase of the mixture and a generator for forming a gas phase of the mixture.

Abstract: A method and apparatus for preparing high purity hydrogen bromide, wherein a starting hydrogen bromide which contains impurities having low boiling points is supplied to an intermediate space. While the gas phase of the starting hydrogen bromide is allowed to ascend through an upper rectifying section, it is brought into contact with a first reflux solution flowing in the reverse direction. The uncondensed gas stored in an upper space is cooled and partly condensed. The condensed liquid is allowed to flow down through an upper rectifying section as the first reflux solution. The liquid-phase of the starting hydrogen bromide is mixed with the first reflux solution in the intermediate space and serves as a second reflux solution. The liquid stored in a lower space is heated and partly evaporated. The liquid stored in the lower space is supplied outside as high purity hydrogen bromide. The uncondensed gas stored in the upper space is discharged outside.

Abstract: A process for recovering a given component from a first gas stream in which the given component is intermittently present by PSA or TSA using an adsorbent which more strongly adsorbs the given component by introducing into the first gas stream, prior to PSA or TSA treatment, a second gas stream that is enriched in the given component. The second gas stream may be introduced into the first gas stream only during periods when the concentration of given component in the first gas stream is below its maximum concentration or it may be continuously introduced into the first gas stream at a level which is greater than the maximum concentration of given component originally present in the first gas stream.

Abstract: A cryogenic system for the recovery of fluorine compounds from a carrier gas stream such as an effluent stream from a semiconductor facility comprising combining the carrier gas feed stream with additive liquid to keep fluorine compounds from solidifying and to reduce the vapor pressure of the fluorine compounds, followed by separation and recovery using a cryogenic rectification column system.

Abstract: A process and apparatus for the recovery and purification of a contaminated refrigerant withdrawn from a refrigeration or refrigerant recovery system which employs a compressor and an adsorbent selective for the adsorption of halogenated hydrocarbons. The adsorbent is selected from the group consisting of silicalite, faujasites, steamed and rare earth exchanged zeolite Y, mordenite, ZSM-5 and mixtures thereof, and more particularly the group consisting of a low cerium rare earth exchanged zeolite Y-84, a low cerium rare earth exchanged zeolite LZ-210, Breck Structure Six, ECR-32, and mixtures thereof. A significant increase in the capacity of these adsorbents over conventional adsorbents combined with the use of novel process steps to recover, purify and return a purified refrigerant to the refrigeration system result in significant cost savings at reduced risk of release of halogenated hydrocarbons to the environment.