Means For Treating Or Maintaining Molten Metal Patents (Class 65/182.3)
  • Patent number: 11760678
    Abstract: Methods for reducing the oxygen concentration in an enclosure including a platinum-containing vessel through which molten glass is flowing are disclosed. The methods include injecting hydrogen gas into an oxygen-containing atmosphere flowing between the enclosure and a reaction chamber. The atmosphere is heated with a heating element in the reaction chamber, whereupon oxygen in the oxygen-containing atmosphere reacts with the hydrogen. In other embodiments, the hydrogen gas and oxygen-containing atmosphere can be exposed to a catalyst comprising platinum positioned in the reaction chamber.
    Type: Grant
    Filed: April 15, 2019
    Date of Patent: September 19, 2023
    Assignee: Corning Incorporated
    Inventors: Michael James Buchholz, Megan Aurora DeLamielleure, George Kristian Schwenke
  • Patent number: 11542188
    Abstract: A glass furnace for continuous operation, including a melting tank for containing a glass melt, and at least one magnetic actuator configured to generate a time-varying magnetic field suitable for moving a stirring body immersed in the glass melt.
    Type: Grant
    Filed: February 21, 2020
    Date of Patent: January 3, 2023
    Assignee: ABB Schweiz AG
    Inventors: Ener Salinas, Xiaojing Zhang, Hongliang Yang, Göran Eriksson, Ulf Sand
  • Patent number: 11390552
    Abstract: A novel apparatus and method for producing flat glass by floating molten glass on liquid tin, significantly improving the efficiency of heating the tin and reducing or eliminating the need to anneal by eliminating the stress introduced by pulling the glass across the tin bath. The apparatus directly heats and melts the tin by exposure to high-intensity infrared energy through surfaces of the tin-containing tub, said tub made from a material that is transmissive at selected infrared wavelengths.
    Type: Grant
    Filed: November 12, 2021
    Date of Patent: July 19, 2022
    Inventor: James W. Masten, Jr.
  • Patent number: 10384973
    Abstract: A drawing method for glass is described. The method provides glass components that have a strongly increased ratio of width to thickness when compared to the preform, which makes the manufacturing of flat glass components more economical. The method purposefully controls the temperature distribution within the preform.
    Type: Grant
    Filed: June 3, 2014
    Date of Patent: August 20, 2019
    Assignee: SCHOTT AG
    Inventors: Frank Buellesfeld, Ralf Biertuempfel
  • Patent number: 10280105
    Abstract: A float glass chamber and related methods include a hot section having an atmosphere in at least the lower plenum with less than 3 percent hydrogen based on volume and a cold section having a different volume percent hydrogen.
    Type: Grant
    Filed: June 8, 2007
    Date of Patent: May 7, 2019
    Inventors: Charlene S. Smith, George A. Pecoraro
  • Patent number: 10227251
    Abstract: A drawing method for glass is described. The method provides glass components that have a strongly increased ratio of width to thickness when compared to the preform, which makes the manufacturing of flat glass components more economical. The method purposefully controls the temperature distribution within the preform.
    Type: Grant
    Filed: June 3, 2014
    Date of Patent: March 12, 2019
    Assignee: SCHOTT AG
    Inventors: Frank Buellesfeld, Ralf Biertuempfel
  • Patent number: 9718719
    Abstract: Disclosed is a float bath which allows easy temperature control according to an internal position, and a glass manufacturing apparatus and glass manufacturing method including the float bath. The float bath includes a plurality of heaters provided at an upper portion of the float bath to supply heat into the float bath, and a shield provided between predetermined heaters among the plurality of heaters to block heat transfer therebetween.
    Type: Grant
    Filed: February 25, 2014
    Date of Patent: August 1, 2017
    Assignee: LG CHEM, LTD.
    Inventors: Kyoung-Hoon Min, Ye-Hoon Im, Su-Chan Park, Sang-Oeb Na, Won-Jae Moon
  • Patent number: 9352995
    Abstract: Provided is an apparatus for producing a sheet glass, including: a forming device that forms a glass ribbon by allowing molten glass continuously supplied onto molten metal in a bath to flow on the molten metal; a rotary roll disposed in an outer vicinity of the bath and configured to draw the glass ribbon obliquely upward from the molten metal; and a supporting device supporting the rotary roll from below.
    Type: Grant
    Filed: August 6, 2014
    Date of Patent: May 31, 2016
    Assignee: ASAHI GLASS COMPANY, LIMITED
    Inventor: Motoichi Iga
  • Patent number: 9010152
    Abstract: Ion transport membranes are integrated with a glass melting furnace and a float glass bath. Only feeds of air, steam and hydrocarbon are necessary for producing hot oxygen for the melting furnace and a mixture of nitrogen, carbon dioxide, and hydrogen for the float glass bath.
    Type: Grant
    Filed: December 31, 2012
    Date of Patent: April 21, 2015
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Wei Huang, Youssef Joumani, Remi Pierre Tsiava, Bhadra S. Grover
  • Patent number: 8656739
    Abstract: The present invention provides a method for manufacturing a float glass by floating the glass on a molten tin that is contained in a molten tin bath, which includes the steps of a) discharging a portion of the molten tin in the molten tin bath to the outside of the molten tin bath; b) removing oxygen dissolved in the molten tin that is discharged from the molten tin bath by injecting an oxygen stripping gas that contains hydrogen into the molten tin; and c) returning the molten tin from which oxygen is removed to the molten tin bath, and an apparatus for manufacturing the same.
    Type: Grant
    Filed: October 1, 2009
    Date of Patent: February 25, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Sang-Oeb Na, Kil-Ho Kim, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Won-Jae Moon
  • Patent number: 8616022
    Abstract: An apparatus for manufacturing a float glass includes a bottom block in which molten metal is stored and floats, a loop block which covers the bottom block and has at least one hole formed therethrough, a heater installed through the hole, and a fragment intercepting member for preventing fragments generated at the loop block from falling onto the bottom block through the hole.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: December 31, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Woo-Hyun Kim, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
  • Patent number: 8448469
    Abstract: The present invention provides a method for manufacturing a float glass by floating the glass on a molten tin that is contained in a molten tin bath, which includes the steps of a) discharging a portion of the molten tin in the molten tin bath to the outside of the molten tin bath; b) removing oxygen dissolved in the molten tin that is discharged from the molten tin bath by injecting an oxygen stripping gas that contains hydrogen into the molten tin; and c) returning the molten tin from which oxygen is removed to the molten tin bath, and an apparatus for manufacturing the same.
    Type: Grant
    Filed: January 24, 2012
    Date of Patent: May 28, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Sang-Oeb Na, Kil-Ho Kim, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Won-Jae Moon
  • Patent number: 8297078
    Abstract: A float bath for manufacturing a float glass includes a brick assembly composed of a plurality of bricks to store a molten metal so that a float glass is capable of moving forward while floating on the molten metal, a bottom casing for forming an outer side of the brick assembly, and an air blower installed away from the bottom casing to supply a cooling air toward the bottom casing. The air blower is disposed so that the cooling air is injected toward gaps between the bricks.
    Type: Grant
    Filed: August 10, 2011
    Date of Patent: October 30, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Won-Jae Moon, Yang-Han Kim, Sang-Oeb Na, Jeong-Deok Kim, Heui-Joon Park, Jin Han, Woo-Hyun Kim, Dong-Shin Shin, Jae-Han Jun
  • Patent number: 8276403
    Abstract: A method for removing oxygen from molten tin in the float bath chamber of a float glass manufacturing process is provided. The method includes providing a chamber having within it molten metal and a gaseous atmosphere above the molten metal, providing at least one reducing gas container proximate the interface between the molten metal and the gaseous atmosphere, providing a source of a reducing gas, and directing the reducing gas to the at least one container. In the at least one container, the reducing gas reacts with the oxygen in the molten metal. The method may include removing a vapor/particulate stream from the float bath chamber. The method may also include removing the vapor and/or the particulate from the stream. An apparatus for removing oxygen from the molten tin is also provided.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: October 2, 2012
    Assignee: Pilkington Group Limited
    Inventor: Douglas M. Nelson
  • Patent number: 8266925
    Abstract: An apparatus for manufacturing a float glass, including a float bath for storing a molten metal on which a molten glass flows, wherein the molten metal flows in the float bath, comprises an discharge opening formed through a wall of a downstream end of the float bath at the center of the wall to discharge a molten metal crashing against the wall and dross floating on the molten metal; and a pair of side channels formed inside of the wall and communicated with the discharge opening and both sides of the float bath.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: September 18, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Sang-Oeb Na, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Won-Jae Moon, Kil-Ho Kim, Heui-Joon Park, Chang-Hee Lee
  • Patent number: 8201419
    Abstract: An apparatus for manufacturing a float glass, including a float bath for strong a molten metal on which a molten glass flows, wherein the molten metal flows in the float bath, comprises a plurality of discharge slits formed through a wall of a downstream end of the float bath to discharge a molten metal crashing against the wall and dross floating on the molten metal; a flow-back channel formed in a widthwise direction of the float bath and communicated with the discharge slits; and a dross collecting member for collecting the dross flowing through the flow-back channel.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: June 19, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Won-Jae Moon, Sang-Oeb Na, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Kil-Ho Kim, Heui-Joon Park, Chang-Hee Lee
  • Patent number: 8201420
    Abstract: An apparatus for manufacturing a float glass, including a float bath for storing a molten metal on which a molten glass flows, wherein the molten metal flows in the float bath, comprises a discharge slot having substantially the same size as width of the molten glass to discharge a molten metal crashing against a wall of a downstream end of the float bath and dross floating on the molten metal, and formed through the wall substantially parallel to a traveling direction of the molten glass; connecting channels for communicating the discharge slot with both sides of the float bath; and dross collecting members for collecting the dross.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: June 19, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Won-Jae Moon, Sang-Oeb Na, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Kil-Ho Kim, Heui-Joon Park, Chang-Hee Lee
  • Publication number: 20120118017
    Abstract: The present invention provides a method for manufacturing a float glass by floating the glass on a molten tin that is contained in a molten tin bath, which includes the steps of a) discharging a portion of the molten tin in the molten tin bath to the outside of the molten tin bath; b) removing oxygen dissolved in the molten tin that is discharged from the molten tin bath by injecting an oxygen stripping gas that contains hydrogen into the molten tin; and c) returning the molten tin from which oxygen is removed to the molten tin bath, and an apparatus for manufacturing the same.
    Type: Application
    Filed: January 24, 2012
    Publication date: May 17, 2012
    Inventors: Sang-Oeb NA, Kil-Ho KIM, Yang-Han KIM, Hyung-Young OH, Young-Sik KIM, Won-Jae MOON
  • Publication number: 20120040818
    Abstract: A float bath for manufacturing a float glass includes a brick assembly composed of a plurality of bricks storing a molten metal so that a float glass is capable of moving forward while floating on the molten metal, a bottom casing for forming an outer side of the brick assembly, and an air blower installed away from the bottom casing to supply a cooling air toward the bottom casing. The air blower includes a plurality of nozzles having a diameter of about 30 mm and arranged with a pitch of about 250 mm to about 300 mm in order to cool the bottom casing to a predetermined temperature.
    Type: Application
    Filed: August 11, 2011
    Publication date: February 16, 2012
    Inventors: Won-Jae MOON, Yang-Han Kim, Sang-Oeb Na, Jeong-Deok Kim, Heui-Joon Park, Jin Han, Woo-Hyun Kim, Dong-Shin Shin, Jae-Han Jun
  • Publication number: 20120040817
    Abstract: A float bath for manufacturing a float glass includes a brick assembly composed of a plurality of bricks to store a molten metal so that a float glass is capable of moving forward while floating on the molten metal, a bottom casing for forming an outer side of the brick assembly, and an air blower installed away from the bottom casing to supply a cooling air toward the bottom casing. The air blower is disposed so that the cooling air is injected toward gaps between the bricks.
    Type: Application
    Filed: August 10, 2011
    Publication date: February 16, 2012
    Inventors: Won-Jae MOON, Yang-Han Kim, Sang-Oeb Na, Jeong-Deok Kim, Heui-Joon Park, Jin Han, Woo-Hyun Kim, Dong-Shin Shin, Jae-Han Jun
  • Publication number: 20120000248
    Abstract: A method for removing oxygen from molten tin in the float bath chamber of a float glass manufacturing process is provided. The method includes providing a chamber having within it molten metal and a gaseous atmosphere above the molten metal, providing at least one reducing gas container proximate the interface between the molten metal and the gaseous atmosphere, providing a source of a reducing gas, and directing the reducing gas to the at least one container. In the at least one container, the reducing gas reacts with the oxygen in the molten metal. The method may include removing a vapor/particulate stream from the float bath chamber. The method may also include removing the vapor and/or the particulate from the stream. An apparatus for removing oxygen from the molten tin is also provided.
    Type: Application
    Filed: March 25, 2010
    Publication date: January 5, 2012
    Applicant: PILKINGTON GROUP LIMITED
    Inventor: Douglas M. Nelson
  • Publication number: 20110301014
    Abstract: An apparatus for manufacturing a float glass includes a float bath in which a molten glass moves on a surface of a floatable molten metal to form a glass ribbon, a casing deformation preventing member for allowing an inert gas to flow around an end casing at an outlet of the float bath to prevent the end casing from deforming, a dross box disposed adjacent to a downstream end of the float bath and having lift-out rollers for drawing the glass ribbon, an introduction member for introducing an inert gas into the dross box, and a recycling path for supplying an inert gas, which discharges from the casing deformation preventing member, to the introducing member.
    Type: Application
    Filed: June 2, 2011
    Publication date: December 8, 2011
    Inventors: Woo-Hyun KIM, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
  • Publication number: 20110294647
    Abstract: An apparatus for manufacturing a float glass includes a bottom block in which molten metal is stored and floats, a loop block which covers the bottom block and has at least one hole formed therethrough, a heater installed through the hole, and a fragment intercepting member for preventing fragments generated at the loop block from falling onto the bottom block through the hole.
    Type: Application
    Filed: May 31, 2011
    Publication date: December 1, 2011
    Inventors: Woo-Hyun Kim, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
  • Publication number: 20110294645
    Abstract: An apparatus for manufacturing a float glass includes a bottom block in which molten metal is stored to float, a loop block which covers the bottom block, and a shield for preventing a vapor, which is generated from the molten metal at both sides of the bottom block, from advancing toward the molten glass or for keeping a circumstance above the molten glass.
    Type: Application
    Filed: May 31, 2011
    Publication date: December 1, 2011
    Inventors: Woo-Hyun KIM, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
  • Patent number: 8020409
    Abstract: An apparatus 10 for producing a plate glass, comprising a bath 14 for float-forming for reserving a molten metal 16 for forming a band-shaped plate glass having a predetermined thickness by feeding a molten glass ribbon 20 in a predetermined direction on the molten metal 16, and a pair of partition walls 46 provided substantially above left and right edges 22 of the molten glass ribbon 20 and substantially along the edges 22 to partition a space above a bath surface of the molten metal into an upper space A above a region covered with the molten glass ribbon 20 and upper spaces B above regions not covered with the molten glass ribbon 20; wherein the partition walls 46 each has a vertically dividable structure dividable into an upper partition wall 46A and a lower partition wall 46B, and the lower partition wall 46B is constituted by strip-shaped lower strip members 58 provided continuously to each other in a lateral direction, and the strip members 58 are configured to be removable or openable from the upper
    Type: Grant
    Filed: December 1, 2009
    Date of Patent: September 20, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Nobuyuki Ban, Toru Kamihori, Atsushi Inoue, Motoichi Iga
  • Publication number: 20110203322
    Abstract: The present invention provides a method for manufacturing a float glass by floating the glass on a molten tin that is contained in a molten tin bath, which includes the steps of a) discharging a portion of the molten tin in the molten tin bath to the outside of the molten tin bath; b) removing oxygen dissolved in the molten tin that is discharged from the molten tin bath by injecting an oxygen stripping gas that contains hydrogen into the molten tin; and c) returning the molten tin from which oxygen is removed to the molten tin bath, and an apparatus for manufacturing the same.
    Type: Application
    Filed: October 1, 2009
    Publication date: August 25, 2011
    Inventors: Sang-Oeb Na, Kil-Ho Kim, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Won-Jae Moon
  • Publication number: 20100223957
    Abstract: Disclosed is a float bath system for manufacturing a float glass, comprising a block assembly having a plurality of blocks connected to each other and configured to store a molten metal therein; a steel casing surrounding the block assembly; an air blower capable of supplying air to the steel casing; and a cooling water spray member capable of spraying a cooling water onto the steel casing. And, a cooling method of said float bath system is disclosed.
    Type: Application
    Filed: March 1, 2010
    Publication date: September 9, 2010
    Inventors: Won-Jae Moon, Sang-Oeb Na, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Kil-Ho Kim, Heui-Joon Park, Chang-Hee Lee
  • Patent number: 7644597
    Abstract: An apparatus 10 for producing a plate glass, comprising a bath 14 for float-forming for reserving a molten metal 16 for forming a band-shaped plate glass having a predetermined thickness by feeding a molten glass ribbon 20 in a predetermined direction on the molten metal 16, and a pair of partition walls 46 provided substantially above left and right edges 22 of the molten glass ribbon 20 and substantially along the edges 22 to partition a space above a bath surface of the molten metal into an upper space A above a region covered with the molten glass ribbon 20 and upper spaces B above regions not covered with the molten glass ribbon 20; wherein the partition walls 46 each has a vertically dividable structure dividable into an upper partition wall 46A and a lower partition wall 46B, and the lower partition wall 46B is constituted by strip-shaped lower strip members 58 provided continuously to each other in a lateral direction, and the strip members 58 are configured to be removable or openable from the upper
    Type: Grant
    Filed: October 6, 2006
    Date of Patent: January 12, 2010
    Assignee: Asahi Glass Company, Limited
    Inventors: Nobuyuki Ban, Toru Kamihori, Atsushi Inoue, Motoichi Iga
  • Publication number: 20090260399
    Abstract: The float glass apparatus has a glass melt producing unit including a melting tank and a refining tank for the glass melt, a float tank including a metallic basin and metal bath contained in the basin, conducting devices for conducting the glass melt from the glass melt producing unit to the metal bath and auxiliary devices as needed. In order to minimize bubble defects and extend service life of apparatus parts made from platinum or a platinum alloy, the apparatus includes a device for minimizing direct current flowing between the glass melt producing unit and the float tank, which includes an auxiliary electrode connected with ground and located in the glass melt producing unit in electrical contact with the glass melt and a direct electrical connection between the metallic basin of the float tank and ground.
    Type: Application
    Filed: June 9, 2009
    Publication date: October 22, 2009
    Inventors: Thomas Pfeiffer, Gernot Roeth, Olaf Claussen, Knut Jakobi, Andreas Roters, Klaus-Dieter Duch, Ottmar Schuessler
  • Publication number: 20080223079
    Abstract: The purpose of the present invention is to provide an apparatus for producing a float glass capable of controlling a temperature rise in the bottom casing to prevent the bottom casing from being corroded by reaction with the molten metal released therefrom. The bottom casing of a flat glass producing apparatus is comprised of a plurality of non-magnetic casing pieces that are electrically insulated from each other by means of a non-woven fabric of silica glass having non-affinity for tin whereby in comparison with a flat glass producing apparatus having the bottom casing of a united structure, an induced current can be controlled thereby prohibiting a temperature rise in the bottom casing. With such structure, tin penetrating in joint portions of the bottom bricks can be prevented from melting and the corrosion of the bottom casing by reaction with the released molten tin can be prevented.
    Type: Application
    Filed: May 21, 2008
    Publication date: September 18, 2008
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Toru KAMIHORI, Motoichi Iga, Tetsushi Takiguchi
  • Publication number: 20080022721
    Abstract: This invention relates to a method of making glass. In certain example embodiments, a major surface(s) of the glass is treated with aluminum chloride (e.g., AlCl3) at or just prior to the annealing lehr. The aluminum chloride treatment at or just prior to the annealing lehr, in either a float or patterned line glass making process, is advantageous in that it allows the treatment to be performed at a desirable glass temperature and permits exhaust functions in or proximate the annealing lehr to remove byproducts of the treatment in an efficient manner.
    Type: Application
    Filed: July 25, 2006
    Publication date: January 31, 2008
    Inventors: Bernd Disteldorf, Anthony V. Longobardo, Keith McCrystal
  • Publication number: 20040261458
    Abstract: The present invention relates to a float bath comprising a transport assembly and/or an adaptor for producing glass by a float-forming process.
    Type: Application
    Filed: June 27, 2003
    Publication date: December 30, 2004
    Inventor: James M. Uhlik
  • Publication number: 20040107732
    Abstract: A float glass chamber and related methods comprising a hot section having an atmosphere in at least the lower plenum comprises less than 3 percent hydrogen based on volume and a cold section, wherein the boundary line between the hot section and the cold section is where the temperature of the glass falls below a threshold temperature
    Type: Application
    Filed: September 26, 2003
    Publication date: June 10, 2004
    Inventors: Charlene S. Smith, George A. Pecoraro
  • Patent number: 6467309
    Abstract: A heat-resistant pipe is arranged so as to traverse below a glass ribbon in a float bath of molten tin, and bubbles emanate from the heat-resistant pipe, thereby making the bottom surface (which is in contact with the tin) uneven. Alternatively, the bottom surface is made uneven with a roller for lifting the glass ribbon out of the float bath into an annealing furnace. In addition to these operations for making the glass surface uneven, a film can be applied to the top face of the glass ribbon (i.e. the surface that is not in contact with the tin) by CVD, supplying a mixed gas of raw material from coaters. Thus, the invention makes it possible to manufacture a glass sheet having an uneven surface efficiently, using a technique for processing the surface of a glass sheet that is suitable for a production line for float glass.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: October 22, 2002
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Akihiro Hishinuma, Toshiaki Hashimoto