Means For Treating Or Maintaining Molten Metal Patents (Class 65/182.3)
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Patent number: 12071370Abstract: The present invention relates to a glass substrate including a pair of main surfaces and an end surface, and having a surface layer diffusion Sn atom concentration of 2.0×1018 atomic/cm3 or more and 1.4×1019 atomic/cm3 or less in at least one of the main surfaces, the surface layer diffusion Sn atom concentration being obtained by subtracting an Sn atom concentration of an inside of the glass substrate from an Sn atom concentration of a surface layer of the glass substrate, in which the Sn atom concentration of a surface layer of the glass substrate is defined as an Sn atom concentration at a depth of 0.1 to 0.3 ?m from the main surface and the Sn atom concentration of an inside of the glass substrate is defined as an Sn atom concentration at a depth of 9.0 to 9.2 ?m from the main surface.Type: GrantFiled: January 28, 2021Date of Patent: August 27, 2024Assignee: AGC Inc.Inventors: Hirofumi Tokunaga, Daisuke Kobayashi, Kazutaka Ono, Atsuyoshi Takenaka, Yoshitaka Maeyanagi
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Patent number: 11760678Abstract: Methods for reducing the oxygen concentration in an enclosure including a platinum-containing vessel through which molten glass is flowing are disclosed. The methods include injecting hydrogen gas into an oxygen-containing atmosphere flowing between the enclosure and a reaction chamber. The atmosphere is heated with a heating element in the reaction chamber, whereupon oxygen in the oxygen-containing atmosphere reacts with the hydrogen. In other embodiments, the hydrogen gas and oxygen-containing atmosphere can be exposed to a catalyst comprising platinum positioned in the reaction chamber.Type: GrantFiled: April 15, 2019Date of Patent: September 19, 2023Assignee: Corning IncorporatedInventors: Michael James Buchholz, Megan Aurora DeLamielleure, George Kristian Schwenke
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Patent number: 11542188Abstract: A glass furnace for continuous operation, including a melting tank for containing a glass melt, and at least one magnetic actuator configured to generate a time-varying magnetic field suitable for moving a stirring body immersed in the glass melt.Type: GrantFiled: February 21, 2020Date of Patent: January 3, 2023Assignee: ABB Schweiz AGInventors: Ener Salinas, Xiaojing Zhang, Hongliang Yang, Göran Eriksson, Ulf Sand
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Patent number: 11390552Abstract: A novel apparatus and method for producing flat glass by floating molten glass on liquid tin, significantly improving the efficiency of heating the tin and reducing or eliminating the need to anneal by eliminating the stress introduced by pulling the glass across the tin bath. The apparatus directly heats and melts the tin by exposure to high-intensity infrared energy through surfaces of the tin-containing tub, said tub made from a material that is transmissive at selected infrared wavelengths.Type: GrantFiled: November 12, 2021Date of Patent: July 19, 2022Inventor: James W. Masten, Jr.
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Patent number: 10384973Abstract: A drawing method for glass is described. The method provides glass components that have a strongly increased ratio of width to thickness when compared to the preform, which makes the manufacturing of flat glass components more economical. The method purposefully controls the temperature distribution within the preform.Type: GrantFiled: June 3, 2014Date of Patent: August 20, 2019Assignee: SCHOTT AGInventors: Frank Buellesfeld, Ralf Biertuempfel
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Patent number: 10280105Abstract: A float glass chamber and related methods include a hot section having an atmosphere in at least the lower plenum with less than 3 percent hydrogen based on volume and a cold section having a different volume percent hydrogen.Type: GrantFiled: June 8, 2007Date of Patent: May 7, 2019Inventors: Charlene S. Smith, George A. Pecoraro
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Patent number: 10227251Abstract: A drawing method for glass is described. The method provides glass components that have a strongly increased ratio of width to thickness when compared to the preform, which makes the manufacturing of flat glass components more economical. The method purposefully controls the temperature distribution within the preform.Type: GrantFiled: June 3, 2014Date of Patent: March 12, 2019Assignee: SCHOTT AGInventors: Frank Buellesfeld, Ralf Biertuempfel
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Patent number: 9718719Abstract: Disclosed is a float bath which allows easy temperature control according to an internal position, and a glass manufacturing apparatus and glass manufacturing method including the float bath. The float bath includes a plurality of heaters provided at an upper portion of the float bath to supply heat into the float bath, and a shield provided between predetermined heaters among the plurality of heaters to block heat transfer therebetween.Type: GrantFiled: February 25, 2014Date of Patent: August 1, 2017Assignee: LG CHEM, LTD.Inventors: Kyoung-Hoon Min, Ye-Hoon Im, Su-Chan Park, Sang-Oeb Na, Won-Jae Moon
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Patent number: 9352995Abstract: Provided is an apparatus for producing a sheet glass, including: a forming device that forms a glass ribbon by allowing molten glass continuously supplied onto molten metal in a bath to flow on the molten metal; a rotary roll disposed in an outer vicinity of the bath and configured to draw the glass ribbon obliquely upward from the molten metal; and a supporting device supporting the rotary roll from below.Type: GrantFiled: August 6, 2014Date of Patent: May 31, 2016Assignee: ASAHI GLASS COMPANY, LIMITEDInventor: Motoichi Iga
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Patent number: 9010152Abstract: Ion transport membranes are integrated with a glass melting furnace and a float glass bath. Only feeds of air, steam and hydrocarbon are necessary for producing hot oxygen for the melting furnace and a mixture of nitrogen, carbon dioxide, and hydrogen for the float glass bath.Type: GrantFiled: December 31, 2012Date of Patent: April 21, 2015Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Wei Huang, Youssef Joumani, Remi Pierre Tsiava, Bhadra S. Grover
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Patent number: 8656739Abstract: The present invention provides a method for manufacturing a float glass by floating the glass on a molten tin that is contained in a molten tin bath, which includes the steps of a) discharging a portion of the molten tin in the molten tin bath to the outside of the molten tin bath; b) removing oxygen dissolved in the molten tin that is discharged from the molten tin bath by injecting an oxygen stripping gas that contains hydrogen into the molten tin; and c) returning the molten tin from which oxygen is removed to the molten tin bath, and an apparatus for manufacturing the same.Type: GrantFiled: October 1, 2009Date of Patent: February 25, 2014Assignee: LG Chem, Ltd.Inventors: Sang-Oeb Na, Kil-Ho Kim, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Won-Jae Moon
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Patent number: 8616022Abstract: An apparatus for manufacturing a float glass includes a bottom block in which molten metal is stored and floats, a loop block which covers the bottom block and has at least one hole formed therethrough, a heater installed through the hole, and a fragment intercepting member for preventing fragments generated at the loop block from falling onto the bottom block through the hole.Type: GrantFiled: May 31, 2011Date of Patent: December 31, 2013Assignee: LG Chem, Ltd.Inventors: Woo-Hyun Kim, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
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Patent number: 8448469Abstract: The present invention provides a method for manufacturing a float glass by floating the glass on a molten tin that is contained in a molten tin bath, which includes the steps of a) discharging a portion of the molten tin in the molten tin bath to the outside of the molten tin bath; b) removing oxygen dissolved in the molten tin that is discharged from the molten tin bath by injecting an oxygen stripping gas that contains hydrogen into the molten tin; and c) returning the molten tin from which oxygen is removed to the molten tin bath, and an apparatus for manufacturing the same.Type: GrantFiled: January 24, 2012Date of Patent: May 28, 2013Assignee: LG Chem, Ltd.Inventors: Sang-Oeb Na, Kil-Ho Kim, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Won-Jae Moon
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Patent number: 8297078Abstract: A float bath for manufacturing a float glass includes a brick assembly composed of a plurality of bricks to store a molten metal so that a float glass is capable of moving forward while floating on the molten metal, a bottom casing for forming an outer side of the brick assembly, and an air blower installed away from the bottom casing to supply a cooling air toward the bottom casing. The air blower is disposed so that the cooling air is injected toward gaps between the bricks.Type: GrantFiled: August 10, 2011Date of Patent: October 30, 2012Assignee: LG Chem, Ltd.Inventors: Won-Jae Moon, Yang-Han Kim, Sang-Oeb Na, Jeong-Deok Kim, Heui-Joon Park, Jin Han, Woo-Hyun Kim, Dong-Shin Shin, Jae-Han Jun
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Patent number: 8276403Abstract: A method for removing oxygen from molten tin in the float bath chamber of a float glass manufacturing process is provided. The method includes providing a chamber having within it molten metal and a gaseous atmosphere above the molten metal, providing at least one reducing gas container proximate the interface between the molten metal and the gaseous atmosphere, providing a source of a reducing gas, and directing the reducing gas to the at least one container. In the at least one container, the reducing gas reacts with the oxygen in the molten metal. The method may include removing a vapor/particulate stream from the float bath chamber. The method may also include removing the vapor and/or the particulate from the stream. An apparatus for removing oxygen from the molten tin is also provided.Type: GrantFiled: March 25, 2010Date of Patent: October 2, 2012Assignee: Pilkington Group LimitedInventor: Douglas M. Nelson
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Patent number: 8266925Abstract: An apparatus for manufacturing a float glass, including a float bath for storing a molten metal on which a molten glass flows, wherein the molten metal flows in the float bath, comprises an discharge opening formed through a wall of a downstream end of the float bath at the center of the wall to discharge a molten metal crashing against the wall and dross floating on the molten metal; and a pair of side channels formed inside of the wall and communicated with the discharge opening and both sides of the float bath.Type: GrantFiled: February 12, 2010Date of Patent: September 18, 2012Assignee: LG Chem, Ltd.Inventors: Sang-Oeb Na, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Won-Jae Moon, Kil-Ho Kim, Heui-Joon Park, Chang-Hee Lee
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Patent number: 8201420Abstract: An apparatus for manufacturing a float glass, including a float bath for storing a molten metal on which a molten glass flows, wherein the molten metal flows in the float bath, comprises a discharge slot having substantially the same size as width of the molten glass to discharge a molten metal crashing against a wall of a downstream end of the float bath and dross floating on the molten metal, and formed through the wall substantially parallel to a traveling direction of the molten glass; connecting channels for communicating the discharge slot with both sides of the float bath; and dross collecting members for collecting the dross.Type: GrantFiled: February 12, 2010Date of Patent: June 19, 2012Assignee: LG Chem, Ltd.Inventors: Won-Jae Moon, Sang-Oeb Na, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Kil-Ho Kim, Heui-Joon Park, Chang-Hee Lee
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Patent number: 8201419Abstract: An apparatus for manufacturing a float glass, including a float bath for strong a molten metal on which a molten glass flows, wherein the molten metal flows in the float bath, comprises a plurality of discharge slits formed through a wall of a downstream end of the float bath to discharge a molten metal crashing against the wall and dross floating on the molten metal; a flow-back channel formed in a widthwise direction of the float bath and communicated with the discharge slits; and a dross collecting member for collecting the dross flowing through the flow-back channel.Type: GrantFiled: February 12, 2010Date of Patent: June 19, 2012Assignee: LG Chem, Ltd.Inventors: Won-Jae Moon, Sang-Oeb Na, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Kil-Ho Kim, Heui-Joon Park, Chang-Hee Lee
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Publication number: 20120118017Abstract: The present invention provides a method for manufacturing a float glass by floating the glass on a molten tin that is contained in a molten tin bath, which includes the steps of a) discharging a portion of the molten tin in the molten tin bath to the outside of the molten tin bath; b) removing oxygen dissolved in the molten tin that is discharged from the molten tin bath by injecting an oxygen stripping gas that contains hydrogen into the molten tin; and c) returning the molten tin from which oxygen is removed to the molten tin bath, and an apparatus for manufacturing the same.Type: ApplicationFiled: January 24, 2012Publication date: May 17, 2012Inventors: Sang-Oeb NA, Kil-Ho KIM, Yang-Han KIM, Hyung-Young OH, Young-Sik KIM, Won-Jae MOON
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Publication number: 20120040818Abstract: A float bath for manufacturing a float glass includes a brick assembly composed of a plurality of bricks storing a molten metal so that a float glass is capable of moving forward while floating on the molten metal, a bottom casing for forming an outer side of the brick assembly, and an air blower installed away from the bottom casing to supply a cooling air toward the bottom casing. The air blower includes a plurality of nozzles having a diameter of about 30 mm and arranged with a pitch of about 250 mm to about 300 mm in order to cool the bottom casing to a predetermined temperature.Type: ApplicationFiled: August 11, 2011Publication date: February 16, 2012Inventors: Won-Jae MOON, Yang-Han Kim, Sang-Oeb Na, Jeong-Deok Kim, Heui-Joon Park, Jin Han, Woo-Hyun Kim, Dong-Shin Shin, Jae-Han Jun
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Publication number: 20120040817Abstract: A float bath for manufacturing a float glass includes a brick assembly composed of a plurality of bricks to store a molten metal so that a float glass is capable of moving forward while floating on the molten metal, a bottom casing for forming an outer side of the brick assembly, and an air blower installed away from the bottom casing to supply a cooling air toward the bottom casing. The air blower is disposed so that the cooling air is injected toward gaps between the bricks.Type: ApplicationFiled: August 10, 2011Publication date: February 16, 2012Inventors: Won-Jae MOON, Yang-Han Kim, Sang-Oeb Na, Jeong-Deok Kim, Heui-Joon Park, Jin Han, Woo-Hyun Kim, Dong-Shin Shin, Jae-Han Jun
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Publication number: 20120000248Abstract: A method for removing oxygen from molten tin in the float bath chamber of a float glass manufacturing process is provided. The method includes providing a chamber having within it molten metal and a gaseous atmosphere above the molten metal, providing at least one reducing gas container proximate the interface between the molten metal and the gaseous atmosphere, providing a source of a reducing gas, and directing the reducing gas to the at least one container. In the at least one container, the reducing gas reacts with the oxygen in the molten metal. The method may include removing a vapor/particulate stream from the float bath chamber. The method may also include removing the vapor and/or the particulate from the stream. An apparatus for removing oxygen from the molten tin is also provided.Type: ApplicationFiled: March 25, 2010Publication date: January 5, 2012Applicant: PILKINGTON GROUP LIMITEDInventor: Douglas M. Nelson
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Publication number: 20110301014Abstract: An apparatus for manufacturing a float glass includes a float bath in which a molten glass moves on a surface of a floatable molten metal to form a glass ribbon, a casing deformation preventing member for allowing an inert gas to flow around an end casing at an outlet of the float bath to prevent the end casing from deforming, a dross box disposed adjacent to a downstream end of the float bath and having lift-out rollers for drawing the glass ribbon, an introduction member for introducing an inert gas into the dross box, and a recycling path for supplying an inert gas, which discharges from the casing deformation preventing member, to the introducing member.Type: ApplicationFiled: June 2, 2011Publication date: December 8, 2011Inventors: Woo-Hyun KIM, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
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Publication number: 20110294645Abstract: An apparatus for manufacturing a float glass includes a bottom block in which molten metal is stored to float, a loop block which covers the bottom block, and a shield for preventing a vapor, which is generated from the molten metal at both sides of the bottom block, from advancing toward the molten glass or for keeping a circumstance above the molten glass.Type: ApplicationFiled: May 31, 2011Publication date: December 1, 2011Inventors: Woo-Hyun KIM, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
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Publication number: 20110294647Abstract: An apparatus for manufacturing a float glass includes a bottom block in which molten metal is stored and floats, a loop block which covers the bottom block and has at least one hole formed therethrough, a heater installed through the hole, and a fragment intercepting member for preventing fragments generated at the loop block from falling onto the bottom block through the hole.Type: ApplicationFiled: May 31, 2011Publication date: December 1, 2011Inventors: Woo-Hyun Kim, Sang-Oeb Na, Won-Jae Moon, Jeong-Deok Kim, Kil-Ho Kim, Heui-Joon Park, Jin Han, Dong-Shin Shin
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Patent number: 8020409Abstract: An apparatus 10 for producing a plate glass, comprising a bath 14 for float-forming for reserving a molten metal 16 for forming a band-shaped plate glass having a predetermined thickness by feeding a molten glass ribbon 20 in a predetermined direction on the molten metal 16, and a pair of partition walls 46 provided substantially above left and right edges 22 of the molten glass ribbon 20 and substantially along the edges 22 to partition a space above a bath surface of the molten metal into an upper space A above a region covered with the molten glass ribbon 20 and upper spaces B above regions not covered with the molten glass ribbon 20; wherein the partition walls 46 each has a vertically dividable structure dividable into an upper partition wall 46A and a lower partition wall 46B, and the lower partition wall 46B is constituted by strip-shaped lower strip members 58 provided continuously to each other in a lateral direction, and the strip members 58 are configured to be removable or openable from the upperType: GrantFiled: December 1, 2009Date of Patent: September 20, 2011Assignee: Asahi Glass Company, LimitedInventors: Nobuyuki Ban, Toru Kamihori, Atsushi Inoue, Motoichi Iga
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Publication number: 20110203322Abstract: The present invention provides a method for manufacturing a float glass by floating the glass on a molten tin that is contained in a molten tin bath, which includes the steps of a) discharging a portion of the molten tin in the molten tin bath to the outside of the molten tin bath; b) removing oxygen dissolved in the molten tin that is discharged from the molten tin bath by injecting an oxygen stripping gas that contains hydrogen into the molten tin; and c) returning the molten tin from which oxygen is removed to the molten tin bath, and an apparatus for manufacturing the same.Type: ApplicationFiled: October 1, 2009Publication date: August 25, 2011Inventors: Sang-Oeb Na, Kil-Ho Kim, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Won-Jae Moon
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Publication number: 20100223957Abstract: Disclosed is a float bath system for manufacturing a float glass, comprising a block assembly having a plurality of blocks connected to each other and configured to store a molten metal therein; a steel casing surrounding the block assembly; an air blower capable of supplying air to the steel casing; and a cooling water spray member capable of spraying a cooling water onto the steel casing. And, a cooling method of said float bath system is disclosed.Type: ApplicationFiled: March 1, 2010Publication date: September 9, 2010Inventors: Won-Jae Moon, Sang-Oeb Na, Yang-Han Kim, Hyung-Young Oh, Young-Sik Kim, Kil-Ho Kim, Heui-Joon Park, Chang-Hee Lee
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Patent number: 7644597Abstract: An apparatus 10 for producing a plate glass, comprising a bath 14 for float-forming for reserving a molten metal 16 for forming a band-shaped plate glass having a predetermined thickness by feeding a molten glass ribbon 20 in a predetermined direction on the molten metal 16, and a pair of partition walls 46 provided substantially above left and right edges 22 of the molten glass ribbon 20 and substantially along the edges 22 to partition a space above a bath surface of the molten metal into an upper space A above a region covered with the molten glass ribbon 20 and upper spaces B above regions not covered with the molten glass ribbon 20; wherein the partition walls 46 each has a vertically dividable structure dividable into an upper partition wall 46A and a lower partition wall 46B, and the lower partition wall 46B is constituted by strip-shaped lower strip members 58 provided continuously to each other in a lateral direction, and the strip members 58 are configured to be removable or openable from the upperType: GrantFiled: October 6, 2006Date of Patent: January 12, 2010Assignee: Asahi Glass Company, LimitedInventors: Nobuyuki Ban, Toru Kamihori, Atsushi Inoue, Motoichi Iga
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Publication number: 20090260399Abstract: The float glass apparatus has a glass melt producing unit including a melting tank and a refining tank for the glass melt, a float tank including a metallic basin and metal bath contained in the basin, conducting devices for conducting the glass melt from the glass melt producing unit to the metal bath and auxiliary devices as needed. In order to minimize bubble defects and extend service life of apparatus parts made from platinum or a platinum alloy, the apparatus includes a device for minimizing direct current flowing between the glass melt producing unit and the float tank, which includes an auxiliary electrode connected with ground and located in the glass melt producing unit in electrical contact with the glass melt and a direct electrical connection between the metallic basin of the float tank and ground.Type: ApplicationFiled: June 9, 2009Publication date: October 22, 2009Inventors: Thomas Pfeiffer, Gernot Roeth, Olaf Claussen, Knut Jakobi, Andreas Roters, Klaus-Dieter Duch, Ottmar Schuessler
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Publication number: 20080223079Abstract: The purpose of the present invention is to provide an apparatus for producing a float glass capable of controlling a temperature rise in the bottom casing to prevent the bottom casing from being corroded by reaction with the molten metal released therefrom. The bottom casing of a flat glass producing apparatus is comprised of a plurality of non-magnetic casing pieces that are electrically insulated from each other by means of a non-woven fabric of silica glass having non-affinity for tin whereby in comparison with a flat glass producing apparatus having the bottom casing of a united structure, an induced current can be controlled thereby prohibiting a temperature rise in the bottom casing. With such structure, tin penetrating in joint portions of the bottom bricks can be prevented from melting and the corrosion of the bottom casing by reaction with the released molten tin can be prevented.Type: ApplicationFiled: May 21, 2008Publication date: September 18, 2008Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Toru KAMIHORI, Motoichi Iga, Tetsushi Takiguchi
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Publication number: 20080022721Abstract: This invention relates to a method of making glass. In certain example embodiments, a major surface(s) of the glass is treated with aluminum chloride (e.g., AlCl3) at or just prior to the annealing lehr. The aluminum chloride treatment at or just prior to the annealing lehr, in either a float or patterned line glass making process, is advantageous in that it allows the treatment to be performed at a desirable glass temperature and permits exhaust functions in or proximate the annealing lehr to remove byproducts of the treatment in an efficient manner.Type: ApplicationFiled: July 25, 2006Publication date: January 31, 2008Inventors: Bernd Disteldorf, Anthony V. Longobardo, Keith McCrystal
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Publication number: 20040261458Abstract: The present invention relates to a float bath comprising a transport assembly and/or an adaptor for producing glass by a float-forming process.Type: ApplicationFiled: June 27, 2003Publication date: December 30, 2004Inventor: James M. Uhlik
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Publication number: 20040107732Abstract: A float glass chamber and related methods comprising a hot section having an atmosphere in at least the lower plenum comprises less than 3 percent hydrogen based on volume and a cold section, wherein the boundary line between the hot section and the cold section is where the temperature of the glass falls below a threshold temperatureType: ApplicationFiled: September 26, 2003Publication date: June 10, 2004Inventors: Charlene S. Smith, George A. Pecoraro
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Patent number: 6467309Abstract: A heat-resistant pipe is arranged so as to traverse below a glass ribbon in a float bath of molten tin, and bubbles emanate from the heat-resistant pipe, thereby making the bottom surface (which is in contact with the tin) uneven. Alternatively, the bottom surface is made uneven with a roller for lifting the glass ribbon out of the float bath into an annealing furnace. In addition to these operations for making the glass surface uneven, a film can be applied to the top face of the glass ribbon (i.e. the surface that is not in contact with the tin) by CVD, supplying a mixed gas of raw material from coaters. Thus, the invention makes it possible to manufacture a glass sheet having an uneven surface efficiently, using a technique for processing the surface of a glass sheet that is suitable for a production line for float glass.Type: GrantFiled: May 31, 2000Date of Patent: October 22, 2002Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Akihiro Hishinuma, Toshiaki Hashimoto