Spheroidizing Or Rounding Of Solid Glass Particles Patents (Class 65/21.3)
  • Patent number: 11485681
    Abstract: Described are cementitious reagent materials produced from globally abundant inorganic feedstocks. Also described are methods for the manufacture of such cementitious reagent materials and forming the reagent materials as microspheroidal glassy particles. Also described are apparatuses, systems and methods for the thermochemical production of glassy cementitious reagents with spheroidal morphology. The apparatuses, systems and methods makes use of an in-flight melting/quenching technology such that solid particles are flown in suspension, melted in suspension, and then quenched in suspension. The cementitious reagents can be used in concrete to substantially reduce the CO2 emission associated with cement production.
    Type: Grant
    Filed: December 18, 2020
    Date of Patent: November 1, 2022
    Assignee: TERRA CO2 TECHNOLOGY HOLDINGS, INC.
    Inventor: Donald John Lake
  • Patent number: 11326773
    Abstract: A waste heat recovery boiler in producing glass beads includes an equipment base arranged at the lower part of the waste heat recovery boiler. The upper part of the equipment base is connected with a cylindrical combustion production chamber, the lower part of the combustion production chamber is provided with a raw material inlet with single-layer or staggered layers. A finished product outlet is arranged at the lower end inside the combustion diffusion chamber, a membrane wall is arranged outside the combustion diffusion chamber, a steam-water lead-out straight tube system is symmetrically arranged at the upper end of the combustion diffusion chamber, a top annular water collecting tank is connected between the steam-water lead-out straight tube system and a steam-water lead-out tube system, and the steam-water lead-out tube system is connected with an upper drum.
    Type: Grant
    Filed: September 18, 2018
    Date of Patent: May 10, 2022
    Inventor: Shang-Yong Huang
  • Patent number: 11017975
    Abstract: An apparatus for coupling to an input connection of an electron gun, the input connection having a heater terminal and a cathode terminal, includes: a connector having a first end and a second end; wherein the first end of the connector is configured to attach to a cable; wherein the second end of the connector is configured to connect to the input connection of the electron gun; and wherein the connector comprises an opening configured to receive the heater terminal of the input connection of the electron gun.
    Type: Grant
    Filed: December 20, 2019
    Date of Patent: May 25, 2021
    Assignee: Varian Medical Systems, Inc.
    Inventors: Mark E. Trail, Rudolf H. Potter
  • Patent number: 10546711
    Abstract: An apparatus for coupling to an input connection of an electron gun, the input connection having a heater terminal and a cathode terminal, includes: a connector having a first end and a second end; wherein the first end of the connector is configured to attach to a cable; wherein the second end of the connector is configured to connect to the input connection of the electron gun; and wherein the connector comprises an opening configured to receive the heater terminal of the input connection of the electron gun.
    Type: Grant
    Filed: July 23, 2019
    Date of Patent: January 28, 2020
    Assignee: Varian Medical Systems, Inc.
    Inventors: Mark E. Trail, Rudolf H. Potter
  • Publication number: 20150107301
    Abstract: The production of a quartz glass grit comprises the granulation of pyrogenetically produced silicic acid, and the formation of a SiO2 granulate and the vitrification of the SiO2 granulate using a treatment gas, which contains at least 30% by volume of helium and/or hydrogen. Said process is time consuming and cost intensive.
    Type: Application
    Filed: April 17, 2013
    Publication date: April 23, 2015
    Inventors: Walter Lehmann, Achim Hofmann, Thomas Kayser, Martin Arndt
  • Publication number: 20140212626
    Abstract: A process for making inorganic, metal oxide spheres that includes exposing solidified, molded microparticles that include a glass precursor composition to a temperature sufficient to transform the molded microparticles into molten glass and cooling the molten glass to form inorganic, metal oxide spheres.
    Type: Application
    Filed: March 28, 2014
    Publication date: July 31, 2014
    Applicant: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: David C. Kramlich, John L. Vandenberg, Matthew H. Frey, Scott R. Culler, Kathleen M. Schakel-Carlson
  • Patent number: 8701441
    Abstract: A process for making inorganic, metal oxide spheres that includes exposing solidified, molded microparticles that include a glass precursor composition to a temperature sufficient to transform the molded microparticles into molten glass and cooling the molten glass to form inorganic, metal oxide spheres.
    Type: Grant
    Filed: August 21, 2006
    Date of Patent: April 22, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: David C. Kramlich, John L. Vandenberg, Matthew H. Frey, Scott R. Culler, Kathleen M. Schakel-Carlson
  • Patent number: 8545733
    Abstract: Disclosed is a process for the manufacture of glass-crystalline particles comprising a glass component and a crystalline component comprising the steps of: a) providing a precursor solution comprising a solvent, a glass component composition, and a crystalline component composition; b) forming an aerosol comprising finely divided droplets of the precursor solution, wherein the droplet concentration which is below the concentration where collisions and subsequent coalescence of the droplets results in a 10% reduction in droplet concentration; c) heating the aerosol wherein, upon heating, glass-crystalline particles are formed, wherein the glass-crystalline particles comprise a glass component and a crystalline component, and wherein the crystalline component comprises one or more metal oxides; and d) isolating the glass-crystalline particles.
    Type: Grant
    Filed: September 27, 2010
    Date of Patent: October 1, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Eric Lee Brantley, John T. Chaplinsky, Howard David Glicksman, James J. Krajewski, Brian J. Laughlin, Kurt Richard Mikeska, Lawrence V. Triboletti
  • Publication number: 20130244857
    Abstract: The present invention relates to a dielectric ceramic composition for multilayer ceramic capacitor (MLCC), including a first component of 91 to 98 wt % and a second component of 2 to 9 wt %, wherein the first component includes a main component BaTiO3 of 94 to 98 wt %, a first subcomponent of 0.5 to 2 wt % including a glass powder having a mesh structure, and a second subcomponent of 1 to 4 wt % including at least one of MgO, Cr2O3 and Mn3O4, and the second component includes (Ba1-y-xCaySrx)(ZryTi1-y)O3, and x satisfies 0.2?x?0.8 and y satisfies 0.03?y?0.15.
    Type: Application
    Filed: March 12, 2013
    Publication date: September 19, 2013
    Applicant: SAMHWA CAPACITOR CO., LTD.
    Inventors: Young Joo OH, Jung Rag YOON, Byong Chul WOO
  • Publication number: 20130125586
    Abstract: A process for producing proppants from waste mineralogical material. The process can include providing the waste mineralogical material in a form such as particles, fines, dust, powders, and the like, and forming a plurality of “green” pellets from the waste mineralogical material. Thereafter, the plurality of green pellets are fed into a provided flame drop tower that has a combustion flame, a hot zone, and a collection basin located downstream from the hot zone. The plurality of green pellets pass through the hot zone, are melted and subsequently solidified in the shape of a sphere downstream from the hot zone to form vitrified glass spheres. In some instances, the vitrified glass spheres are subjected to a devitrification step.
    Type: Application
    Filed: January 17, 2013
    Publication date: May 23, 2013
    Applicant: THE PENN STATE RESEARCH FOUNDATION
    Inventor: THE PENN STATE RESEARCH FOUNDATION
  • Publication number: 20120175558
    Abstract: The invention relates to a process for preparing porous glass particles suitable for use as precursor materials for production of an opto-ceramic element. The process comprises: providing particles of a soluble glass composition comprising at least one soluble component, at least one component having low solubility in an aqueous solution, and at least one lasing dopant which also has a low solubility in the aqueous solution; and immersing the particles in an aqueous solution having low solubility for said at least one component and said at least one lasing dopant, to thereby dissolve substantially all of the soluble portions of the glass particles.
    Type: Application
    Filed: July 25, 2007
    Publication date: July 12, 2012
    Inventors: Samuel David Conzone, Carol Click
  • Patent number: 8117867
    Abstract: A process for producing spherical inorganic particles which have high flowability, can be incorporated in a high proportion, and are useful as a filler for composite substrates such as printed wiring boards and encapsulating materials. Also provided is a process for producing spherical inorganic particles which have high flowability and can be incorporated in a high proportion and which are useful as a filler for encapsulating materials and give an encapsulating material having high electrical insulating properties. One of the processes for producing spherical inorganic particles comprises: (a1) pulverizing a silicate-containing inorganic material to form a pulverization product; (b1) heating the pulverization product in an atomized state to form the pulverization product into spherical particles; (c1) spraying water over the spherical particles to cool them while maintaining the atomized state of the spherical particles; and (d1) collecting the spherical particles.
    Type: Grant
    Filed: August 9, 2006
    Date of Patent: February 21, 2012
    Assignee: Nitto Boseki Co., Ltd.
    Inventors: Shigeo Yamaguchi, Takeo Inoue
  • Publication number: 20110233486
    Abstract: Disclosed is a process for the manufacture of glass-crystalline particles comprising a glass component and a crystalline component comprising the steps of: a) providing a precursor solution comprising a solvent, a glass component composition, and a crystalline component composition; b) forming an aerosol comprising finely divided droplets of the precursor solution, wherein the droplet concentration which is below the concentration where collisions and subsequent coalescence of the droplets results in a 10% reduction in droplet concentration; c) heating the aerosol wherein, upon heating, glass-crystalline particles are formed, wherein the glass-crystalline particles comprise a glass component and a crystalline component, and wherein the crystalline component comprises one or more metal oxides; and d) isolating the glass-crystalline particles.
    Type: Application
    Filed: September 27, 2010
    Publication date: September 29, 2011
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Eric Lee Brantley, John T. Chaplinsky, Howard David Glicksman, James J. Krajewski, Brian J. Laughlin, Kurt Richard Mikeska, Lawrence V. Triboletti
  • Patent number: 7927670
    Abstract: The invention concerns silica microspheres (M) having an outer diameter between 50 and 125 ?m, preferably between 60 and 90 ?m, a wall thickness not less than 1 ?m, preferably between 1 and 3 ?m and a density between 0.3 and 0.7/cm3, a manufacturing method by injecting silica microsphere precursors (MS, PR1, PR1?, PR2?) into an inductive plasma (P), assembly methods and possible uses of silica microspheres.
    Type: Grant
    Filed: September 19, 2005
    Date of Patent: April 19, 2011
    Inventor: Sylvain Rakotoarison
  • Patent number: 7884055
    Abstract: A method and apparatus for manufacturing ceramic microspheres from industrial slag. The microspheres have a particle size of about 38 microns to about 150 microns. The microspheres are used to create a cement slurry having a density of at least about 11 lbs/g. The resultant cement slurry may then be used to treat subterranean wells.
    Type: Grant
    Filed: December 4, 2008
    Date of Patent: February 8, 2011
    Assignee: Intevep, S.A.
    Inventors: George Quercia, Yibran Perera, Aiskely Blanco, Fedymar Pereira
  • Patent number: 7858148
    Abstract: Artificial turf for use with an artificial turf system, which may also include a base layer and a support layer. The artificial turf comprising a backing supporting pile tufts of between ¼? to 4? in length, in position on its upper surface. The backing may comprise a porous synthetic foam or backing sheet. A filler of particles shaped to have no sharp edges and of substantially equal size are interspersed over the backing and about the tufts up to at least half thick length. The artificial turf substantially retains its resiliency, porosity and equal density throughout.
    Type: Grant
    Filed: March 5, 2007
    Date of Patent: December 28, 2010
    Assignee: USGreentech, L.L.C.
    Inventor: Randolph S. Reddick
  • Patent number: 7787984
    Abstract: A sphering apparatus includes a sphering furnace on a body of which a plurality of adhesion preventing air-introducing holes is formed and at a lower position of which a carrier air-introducing hole and a carrier air-withdrawing hole are formed; an air blower introducing both an adhesion preventing air and a carrier air; a first pipe one end of which is connected to a discharging part of the air blower and the other end of which is biforked, one biforked end being connected to the carrier air-introducing hole and the other biforked end being connected to a manifold bundling the plurality of adhesion preventing air-introducing holes; a first damper provided in any one of two pipes in the biforked part of the first pipe; a cyclone connected to the carrier air-withdrawing hole through a second pipe; and a bag filter connected to the cyclone through a third pipe.
    Type: Grant
    Filed: September 22, 2005
    Date of Patent: August 31, 2010
    Assignee: Taiyo Nippon Sanso Corporation
    Inventors: Yoshiyuki Hagiwara, Shinichi Miyake
  • Patent number: 7631518
    Abstract: Methods for producing glass powders are provided. The methods include generating an aerosol stream comprising droplets that include a liquid and a glass precursor. Glass particles are formed in the aerosol stream having a small average particle size. The powders can also have a small particle size, narrow size distribution, a high density and a spherical morphology. The invention also includes devices and products formed from the glass powders.
    Type: Grant
    Filed: December 3, 2004
    Date of Patent: December 15, 2009
    Assignee: Cabot Corporation
    Inventors: Toivo T. Kodas, Mark J. Hampden-Smith, James Caruso, Quint H. Powell, Audunn Ludviksson
  • Publication number: 20090249833
    Abstract: A process for producing spherical inorganic particles which have high flowability, can be incorporated in a high proportion, and are useful as a filler for composite substrates such as printed wiring boards and encapsulating materials. Also provided is a process for producing spherical inorganic particles which have high flowability and can be incorporated in a high proportion and which are useful as a filler for encapsulating materials and give an encapsulating material having high electrical insulating properties. One of the processes for producing spherical inorganic particles comprises: (a1) pulverizing a silicate-containing inorganic material to form a pulverization product; (b1) heating the pulverization product in an atomized state to form the pulverization product into spherical particles; (c1) spraying water over the spherical particles to cool them while maintaining the atomized state of the spherical particles; and (d1) collecting the spherical particles.
    Type: Application
    Filed: August 9, 2006
    Publication date: October 8, 2009
    Applicant: Nitto Boseki Co., Ltd.
    Inventors: Shigeo Yamaguchi, Takeo Inoue
  • Patent number: 7328594
    Abstract: A process for stably and efficiently producing quality glass articles such as preforms at high yields, and a process for producing an optical device from the preform obtained by the above process. In the process for producing a glass article, molten glass gobs having a predetermined weight each are poured, or molten glass drops having a predetermined weight each are dropped through a nozzle, into a boiling liquid having a boiling point lower than the class transition temperature of the glass constituting said glass article or a liquid which is temperature-adjusted beforehand so as to be caused to boil by the amount of heat of the glass, to form glass articles.
    Type: Grant
    Filed: December 12, 2002
    Date of Patent: February 12, 2008
    Assignee: Hoya Corporation
    Inventors: Akira Murakami, Katsumi Utsugi, Yoshinori Iguchi, Masahiro Yoshida, Yoshikane Shinkuma, Atsushi Watabe
  • Patent number: 7297646
    Abstract: Ceramics comprising (i) at least one of Nb2O5 or Ta2O5 and (ii) at least two of (a) Al2O3, (b) REO, or (c) at least one of ZrO2 or HfO2. Embodiments of ceramics according to the present invention can be made, formed as, or converted into optical waveguides, glass beads, articles (e.g., plates), fibers, particles (e.g., abrasive particles), and thin coatings.
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: November 20, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Anatoly Z. Rosenflanz, Craig R. Schardt
  • Patent number: 7240518
    Abstract: The apparatus for producing glass beads of the present invention comprises a melting pot 2 for heating and melting glass, a nozzle 2A for dripping molten glass 4 in the melting pot 2, which is disposed at the bottom of the melting pot 2, and a liquid glass droplet receiver 11 filled with cooling solution 150 for cooling the liquid glass droplet 10 dripped from the nozzle 2A, which is disposed under the nozzle 2A, wherein the cooling solution 150 is made from a material that forms a bubble layer around the liquid glass droplet 10 as the cooling solution 150 is vaporized due to the heat of the liquid glass droplet 10 during a period when the liquid glass droplet 10 is cooled down to a temperature lower than the glass transfer temperature in the cooling solution 150.
    Type: Grant
    Filed: December 25, 2002
    Date of Patent: July 10, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Masahiro Hiraka, Shigeo Furukawa, Mitsuhiro Fujita
  • Patent number: 7093463
    Abstract: A method for producing powders that consist of substantially spherical particles from a material such as glass, ceramics or plastic that produces a highly viscous melt that solidifies at a glass transition temperature Tg or at a solidification temperature Ts. The inventive method comprises the following steps: (a) producing a melt of a viscosity ? in the range of from 0.1 to 100 Ns/m2; (b) atomizing the melt using a first gas, the first gas having a temperature TA?Tg or ?0.5Ts at the outlet of the nozzle and (c) cooling off the particles produced by atomization in a cooling section downstream of the nozzle using a coolant, the temperature of the coolant being smaller than Ts or Tg.
    Type: Grant
    Filed: October 9, 2000
    Date of Patent: August 22, 2006
    Assignee: Applikations-und Technikzentrum fur Energieverfahrens-Umwelt-und Stromungstechnik (ATZ-EVUS)
    Inventors: Gerhard Wolf, Andreas Emmel
  • Patent number: 7059153
    Abstract: A powder of solid and spherical glass particles is easily manufactured by subjecting a mixed solution of a raw material oxide powder comprising a glass network-forming element, and an aqueous solution of a water-soluble compound comprising a glass-forming element other than the element of the raw material oxide powder to spray-thermal decomposition, wherein the spray-thermal decomposition temperature is set to be in a specific range according to the amount of the raw material oxide powder in the total of the amount of the raw material oxide powder and the oxide-converted amount of the water-soluble compound, as well as the average particle size of the glass powder to be manufactured.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: June 13, 2006
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Koji Hattori, Shinsei Okabe, Toshiyuki Miyoshi
  • Publication number: 20040261454
    Abstract: Disclosed are a process for producing a glass shaped material having high quality and high mass accuracy and a process for producing an optical element, which includes the preparation of a glass shaped material having high quality and high mass accuracy, the heating of said glass shaped material and the precision-press-molding thereof.
    Type: Application
    Filed: June 23, 2004
    Publication date: December 30, 2004
    Applicant: Hoya Corporation
    Inventors: Masahiro Yoshida, Yoshikane Shinkuma, Xuelu Zou
  • Publication number: 20040259713
    Abstract: The present invention relates to microspheres (i.e., beads) that comprise titania and bismuth oxide. The glass microspheres further comprise zirconia. The invention also relates to retroreflective articles, and in particular pavement markings, comprising such microspheres.
    Type: Application
    Filed: June 11, 2003
    Publication date: December 23, 2004
    Applicant: 3M Innovative Properties Company
    Inventor: Matthew H. Frey
  • Patent number: 6758062
    Abstract: The present invention intends to provide a manufacturing method for a plasma display panel, so as to overcome problems associated with a withstanding voltage of a dielectric glass layer. Glass particles have angular shapes after grinding with a grinder, but as the surface of them has been melted, they are converted into spheroids. Those glass particles can get wet evenly, so that a binder evenly adheres to the surface of a glass particle when a glass paste including the glass particles is applied to the surface of a substrate. In this case, there is a scarce possibility for a gas, generated by baking the binder, to remain in the form of bubbles in a formed dielectric glass layer. There are fewer bubbles remaining in a completed dielectric glass layer than in a dielectric glass layer than in a glass layer made from angular glass particles.
    Type: Grant
    Filed: August 1, 2001
    Date of Patent: July 6, 2004
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Taku Watanabe, Masaki Aoki, Shigeo Suzuki
  • Patent number: 6742364
    Abstract: A method of manufacturing a micro molten glass droplet, has the steps of, colliding a molten glass droplet with a micro through hole formed in a plate-shaped member; and pushing out at least part of the glass droplet to a reverse surface of the micro through hole as a micro droplet, thereby forming a glass droplet with a diameter of not more than 5 mm.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: June 1, 2004
    Assignee: Minolta Co., Ltd.
    Inventor: Shinichi Nishikawa
  • Publication number: 20020139144
    Abstract: The present invention intends to provide a manufacturing method for a plasma display panel, so as to overcome problems associated with a withstanding voltage of a dielectric glass layer,
    Type: Application
    Filed: August 1, 2001
    Publication date: October 3, 2002
    Inventors: Taku Watanabe, Masaki Aoki, Shigeo Suzuki
  • Publication number: 20020121108
    Abstract: A retrofit technology for air-fuel fired, vertical glass furnace for oxygen firing or boosting to provide additional heat to the process to increase furnace production capacity. The additional firing using oxygen is strategically controlled to enable enhanced radiation from oxygen flame for the spheroidizing process without negative effects on the overall process. With proper implementation, an increased production from 50% to 200%, depending on the size of the spheres, can be achieved while maintaining acceptable product quality. Processes in accordance with the present invention can be performed using one of a number of methods of oxygen boosting.
    Type: Application
    Filed: October 19, 2001
    Publication date: September 5, 2002
    Inventors: Eric Streicher, John Foss, Mahendra L. Joshi, Harley A. Borders
  • Publication number: 20020053223
    Abstract: A method of manufacturing a micro molten glass droplet, has the steps of, colliding a molten glass droplet with a micro through hole formed in a plate-shaped member; and pushing out at least part of the glass droplet to a reverse surface of the micro through hole as a micro droplet, thereby forming a glass droplet with a diameter of not more than 5 mm.
    Type: Application
    Filed: August 17, 2001
    Publication date: May 9, 2002
    Inventor: Shinichi Nishikawa
  • Patent number: 6358531
    Abstract: A method is provided for preparing shells, concentric shells or porous, homogenous gels from alkali borate glass particles at low temperatures (i.e. room temperature or less than above 100° C.). The alkali borate glass particles contain one or more cations such as aluminum which react with an aqueous solution containing an anion such as hydroxide to form an aqueous insoluble material having a solubility limit of less than about 0.01 wt. percent. The resulting shells or gels may be used in many different applications such as a filler in resins, as filters, precursors for nano-sized powders, as thin surface films or catalyst support media. The resulting shells or gels may also have a chemotherapeutic drug added thereto, following which the resulting product is administered to a mammal and the insoluble material is dissolved form the product in vivo through administration of chelating agent.
    Type: Grant
    Filed: February 1, 1999
    Date of Patent: March 19, 2002
    Assignee: The Curators of the University of Missouri
    Inventors: Delbert E. Day, Samuel D. Conzone
  • Publication number: 20020007650
    Abstract: A powder of solid and spherical glass particles is easily manufactured by subjecting a mixed solution of a raw material oxide powder comprising a glass network-forming element, and an aqueous solution of a water-soluble compound comprising a glass-forming element other than the element of the raw material oxide powder to spray-thermal decomposition, wherein the spray-thermal decomposition temperature is set to be in a specific range according to the amount of the raw material oxide powder in the total of the amount of the raw material oxide powder and the oxide-converted amount of the water-soluble compound, as well as the average particle size of the glass powder to be manufactured.
    Type: Application
    Filed: May 30, 2001
    Publication date: January 24, 2002
    Applicant: Murata Manufacturing Co., Ltd.
    Inventors: Koji Hattori, Shinsei Okabe, Toshiyuki Miyoshi