Abstract: In one embodiment, a chalcogenide glass optical fiber is produced by forming a billet including a chalcogenide glass mass and a polymer mass in a stacked configuration, heating the billet to a temperature below the melting point of the chalcogenide glass, extruding the billet in the ambient environment to form a preform rod having a chalcogenide glass core and a polymer jacket, and drawing the preform rod.

Abstract: An IR supercontinuum source for generating supercontinuum in the MIR or possibly LWIR spectral bands comprises a supercontinuum fiber formed from a heavy metal oxide host glass having low optical loss and high non-linearity over the spectral band that is stable, strong and chemically durable. The supercontinuum fiber is suitably a depressed inner clad fiber configured to support only single transverse spatial mode propagation of the pump signal and supercontinuum. The source suitably includes a tapered depressed inner clad fiber to couple the pump signal into the supercontinuum fiber. The source may be configured as an “all-fiber” source.

Abstract: The invention provides techniques for drawing fibers that include conducting, semiconducting, and insulating materials in intimate contact and prescribed geometries. The resulting fiber exhibits engineered electrical and optical functionalities along extended fiber lengths. The invention provides corresponding processes for producing such fibers, including assembling a fiber preform of a plurality of distinct materials, e.g., of conducting, semiconducting, and insulating materials, and drawing the preform into a fiber.

Abstract: An IR supercontinuum source for generating supercontinuum in the MIR or possibly LWIR spectral bands comprises a supercontinuum fiber formed from a heavy metal oxide host glass having low optical loss and high non-linearity over the spectral band that is stable, strong and chemically durable. The supercontinuum fiber is suitably a depressed inner clad fiber configured to support only single transverse spatial mode propagation of the pump signal and supercontinuum. The source suitably includes a tapered depressed inner clad fiber to couple the pump signal into the supercontinuum fiber. The source may be configured as an “all-fiber” source.

Abstract: A tellurium oxide glass that is stable, strong and chemically durable exhibits low optical loss from the UV band well into the MIR band. Unwanted absorption mechanisms in the MIR band are removed or reduced so that the glass formulation exhibits optical performance as close as possible to the theoretical limit of a tellurium oxide glass. The glass formulation only includes glass constituents that provide the intermediate, modifiers and any halides (for OH— reduction) whose inherent absorption wavelength is longer than that of Tellurium (IV) oxide. The glass formulation is substantially free of Sodium Oxide and any other passive glass constituent including hydroxyl whose inherent absorption wavelength is shorter than that of Tellurium (IV) oxide. The glass formulation preferably includes only a small residual amount of halide.

Abstract: The present invention is generally directed to a method of making chalcogenide glasses including holding the melt in a vertical furnace to promote homogenization and mixing; slow cooling the melt at less than 10° C. per minute; and sequentially quenching the melt from the top down in a controlled manner. Additionally, the present invention provides for the materials produced by such method. The present invention is also directed to a process for removing oxygen and hydrogen impurities from chalcogenide glass components using dynamic distillation.

Abstract: The present invention is generally directed to a method of making a hollow-core photonic band gap preform from a specialty glass by pressing a specialty glass through a die to form a tube wherein the outer transverse shape of the tube is a hexagon, triangle, quadrilateral, or other polygon; stretching the tube to form a micro-tube with approximately the same outer transverse shape as the tube; stacking a plurality of micro-tubes into a bundle minimizing voids between adjacent micro-tubes and forming a central longitudinal void wherein the plurality of micro-tubes within the bundle comprise an inner structured region of the preform and the central void of the bundle comprises a hollow core in the preform; and inserting the bundle into a jacket tube. Also disclosed are the hollow-core photonic band gap preform and fiber formed by this method.

Abstract: A thermally stable chalcogenide glass, a process for making the same, and an optical fiber drawn therefrom are provided. A chalcogenide glass having the composition Ge(5?y)As(32?x)Se(59+x)Te(4+y) (0?y?1 and 0?x?2) is substantially free from crystallization when it is heated past the glass transition temperature Tg or drawn into optical fibers. A process for making the thermally stable chalcogenide glass includes purifying the components to remove oxides and scattering centers, batching the components in a preprocessed distillation ampoule, gettering oxygen impurities from the mixture, and heating the components to form a glass melt. An optical fiber formed from the chalcogenide glass is substantially free from crystallization and exhibits low signal loss in the near-infrared region, particularly at wavelengths of about 1.55 ?m.

Abstract: The present invention is generally directed to a device comprising multiple specialty glass optical fibers that combines several different mid-infrared optical signals from multiple optical fibers into one signal in a single optical fiber. In addition, the present invention provides for a method of making the device.

Abstract: A thermally stable chalcogenide glass, a process for making the same, and an optical fiber drawn therefrom are provided. A chalcogenide glass having the composition Ge(5?y)As(32?x)Se(59+x)Te(4+y) (0?y?1 and 0?x?2) is substantially free from crystallization when it is heated past the glass transition temperature Tg or drawn into optical fibers. A process for making the thermally stable chalcogenide glass includes purifying the components to remove oxides and scattering centers, batching the components in a preprocessed distillation ampoule, gettering oxygen impurities from the mixture, and heating the components to form a glass melt. An optical fiber formed from the chalcogenide glass is substantially free from crystallization and exhibits low signal loss in the near-infrared region, particularly at wavelengths of about 1.55 ?m.

Abstract: The present invention is generally directed to a method of making chalcogenide glasses including holding the melt in a vertical furnace to promote homogenization and mixing; slow cooling the melt at less than 10° C. per minute; and sequentially quenching the melt from the top down in a controlled manner. Additionally, the present invention provides for the materials produced by such method. The present invention is also directed to a process for removing oxygen and hydrogen impurities from chalcogenide glass components using dynamic distillation.

Abstract: This invention pertains to a chalcogenide glass of low optical loss that can be on the order of 30 dB/km or lower, and to a process for preparing the chalcogenide glass.

Abstract: The present invention provides an apparatus for dispensing a beverage, the beverage comprising a liquid-beverage portion and a frozen-beverage portion. The apparatus comprises means for dispensing into a receptacle the liquid beverage portion, means (102) for freezing a portion of beverage so as to provide the frozen beverage portion and means (104, 104? for dispensing the frozen-beverage portion into the receptacle. The present apparatus also provides a method for dispensing a frozen beverage portion by providing one or more cooling chambers (102) cooled by cooling means, supplying at least one of the cooling chambers with a portion of beverage, freezing the portion of beverage to provide at least one beverage frozen-beverage portion and ejecting one frozen beverage portion from its cooling chamber.

Abstract: This invention pertains to a chalcogenide glass of low optical loss that can be on the order of 30 dB/km or lower, and to a process for preparing the chalcogenide glass.

Abstract: A process includes the steps of disposing a solid core glass rod at a point removed from hot temperature that can cause crystallization in the core glass rod, disposing a solid clad glass rod at a point removed from the core glass rod; softening to the flowing condition the solid clad glass rod, transferring the softened clad glass to a lower point, the softened clad glass having a central void therethrough, heating the softened clad glass above its crystallization temperature, cooling the softened clad glass to a draw temperature, transferring the solid core glass rod into the central void in the softened glad glass, softening to the flowing condition the solid core glass rod with the heat from the softened and cooled clad glass, and drawing the core/clad, glass fiber by allowing the clad and core glasses to flow in the form of a fiber.

Abstract: Dynamically controlling the reaction temperature at the tip of a soot preform by controlling the flow of hydrogen gas to the core torch provides a wide latitude of control over the temperature range necessary to produce uniform composition of the preform.

Abstract: In general, in one aspect, the invention features an article including a high-power, low-loss fiber waveguide that includes alternating layers of different dielectric materials surrounding a core extending along a waveguide axis, the different dielectric materials including a polymer and a glass.

Abstract: The present invention provides new compounds for use in proton exchange membranes which are able to operate in a wide variety of temperature ranges, including in the intermediate temperature range of about 100° C. to 700° C., and new and improved methods of making these compounds. The present invention also provides new and improved methods for making chalcogenide compounds, including, but not limited to, non-protonated sulfide, selenide and telluride compounds. In one embodiment, the proton conductivity of the compounds is between about 10−8 S/cm and 10−1 S/cm within a temperature range of between about −50 and 500° C.

Abstract: A method for molding a chalcogenide glass lens includes providing a mold. A preformed lens of chalcogenide glass is placed within the mold. The lens has a top surface and a bottom surface. An amount of chalcogenide glass is deposited within the mold and on the top surface of the preformed lens. The mold is heated, such that the chalcogenide glass on the top surface of the preformed lens softens, melts, and bonds to the top surface of the preformed lens. A lens surface is formed in the melted chalcogenide glass to form a molded lens which is bonded to the top surface of the preformed lens. The molded lens and preformed lens assembly is then removed from the mold.

Abstract: This invention pertains to apparatus and process for making core/clad glass fibers. The apparatus includes a central tube or receptacle connected at the top to a pressure controller and terminating in a reduced section; a side tube or receptacle positioned at about the level of the upper portion of the central tube; an outer tube or receptacle disposed around the bottom portion of the central tube terminating in a smaller section which is concentric with and spaced directly below the section of the central tube; a side arm connecting the side tube and the outer tube; and furnaces around the side, outer, and the reduced sections of the central arid the outer tubes.

Abstract: A method of making chalcogenide glass which utilizes liquid encapsulation to prevent the evaporation loss of low boiling point or high vapor pressure glass components while the glass melt is being processed.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: A starting material for producing optical fibers contains metal halides. The refractive index of the optical fiber formed from the starting marterial is predeterminable by adjusting a composite of the molten bath. The starting material is produced by mixing halogenated gases into a gas mixture with the desired partial pressure ratio, causing a chemical reaction at a first temperature of the gas mixture with at least metal to form a reaction product, the first temperature being higher than the melting temperature of the reaction product and cooling the reaction product to a second temperature that is below the melting temperature.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: An apparatus and process for fabricating tubing used in the making of chalcogenide fibers. The apparatus features a three-sectioned melt/spin ampoule that allows for fabricating the chalcogenide tubing without introducing impurities and contaminants, in a self-contained apparatus.

Abstract: A method and apparatus is disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: A method for the manufacture of optical components, at least one three-dimensional optical waveguide structure being produced in a light-sensitive substrate by locally subjecting the substrate to an exposure so that a difference in refractive index between the substrate and the at least one optical waveguide structure is created. Provision is made for an exposure to occur at least twice, at different angles of incidence for the light perpendicular to a light wave propagation direction of the optical waveguide structure; the substrate surrounding what will later be the optical waveguide structure thereby experiences a diminution in refractive index, the optical waveguide structure being defined using a mask.

Abstract: A glass 1 is irradiated with a focused pulsed laser beam 2 having a peak power density of 10.sup.5 W/cm.sup.2 or more and a repetition rate of 10 KHz or more. The glass 1 irradiated with the laser beam 2 changes its refractive index at the focal point 4. During the laser beam irradiation, the glass 1 is continuously moved with respect to the focal point of the pulsed laser beam 2 or continuously scanned with the focused laser beam 2, so as to form the refractive index changed region (i.e. an optical waveguide 5) with a predetermined pattern. The glass 1 in which the optical waveguide 5 will be formed may be any kind of glass having high transparency.

Abstract: A method for manufacturing a glass preform from a metal sulfide chalcogenide glass to which a large amount of light emitting substances can be added includes steps of etching a surface made of the chalcogenide glass or oxychalcogenide glass of disc shape core and clad forming glass starting materials by an etchant including an acid and a compound reacting with a hydrogen chalcogenide, and forming the core forming glass starting material and the clad forming glass starting material into a united body serving as a glass preform. In a method for manufacturing a single-mode glass fiber using a preform method by drawing the glass preform whose outer round surface is made of a chalcogenide glass or oxychalcogenide glass, the outer round surface of the glass preform is etched using an etchant including an acid and a compound reacting with a hydrogen chalcogenide and then drawn into the glass fiber.

Abstract: A glass is irradiated with a focused pulsed laser beam having a peak power density of 10.sup.5 W/cm.sup.2 or more and a repetition rate of 10 KHz or more. The glass irradiated with the laser beam changes its refractive index at the focal point. During the laser beam irradiation, the glass is continuously moved with respect to the focal point of the pulsed laser beam or continuously scanned with the focused laser beam, so as to form the refractive index changed region (i.e. an optical waveguide) with a predetermined pattern. The glass in which the optical waveguide is formed may be any kind of glass having high transparency.

Abstract: A process for producing a preform for a chalcogenide glass fiber which comprises inserting a cladding tube having contained therein a chalcogenide glass rod for core into a quartz tube having at its bottom a nozzle having an aperture smaller than the outer diameter of the cladding tube, locally heating the bottom of the quartz tube and pulling the cladding tube having contained the glass rod for core and a process for producing a chalcogenide glass fiber by heating and drawing the preform thus obtained, by which processes the devitrification of glass and the generation of bubbles in the core glass or at the core glass-cladding glass interface can be prevented and the adhesion between the core glass and the cladding glass can be improved. In particular, when the glass material for core does not contain Ge, a chalcogenide glass fiber having such a core-cladding structure that the transmission loss of the glass fiber when infrared light pass through the fiber is small and the mechanical strength is high.

Abstract: An infrared fiber optic coupler and a method for making an infrared fiber optic coupler are disclosed.

Abstract: A method for manufacturing a glass fiber includes a process of drawing a starting glass material partially or entirely made of chalcogenide glass or oxychalcogenide glass, such as preform rod, rod-in-tube, or jacketing tube, into a glass fiber in an atmosphere containing sulfur. The concentration of the sulfur in the atmosphere is set at sulfur's vapor pressure or greater around the glass surface at a maximum temperature of the glass fiber while the glass fiber is drawn, thereby fabricating the glass fiber without forming substantially any crystallization on the glass surface.

Abstract: A vertically disposed apparatus used to make core-clad optical fibers inces an inner elongated cylinder removably closed at the top and provided at the bottom with an inner exit port of a smaller diameter than the inner cylinder and an outer cylinder, disposed around the inner cylinder, removably closed at the top and provided at the bottom with an outer exit port of a smaller diameter than the outer cylinder. The inner exit port is of a smaller diameter than the outer exit port and is disposed directly above the outer exit port. The apparatus also includes a heater for heating the inner and outer cylinders and acces to the inner and the outer cylinders for individually pressurizing inner and outer cylinders.

Abstract: A selenide glass with improved mechanical and optical properties such as ended transmission in the infrared region of radiation having wavelengths beyond 15 microns; Tg in the region of 363.degree.-394.degree. C.; and thermal stability of 85.degree.-145.degree. C. based on the difference between T.sub.g and T.sub.x, comprising, on mol basis, 20-70% germanium selenide, 0.5-25% gallium selenide, indium selenide or mixtures thereof; and 5-50% of at least one alkaline earth in selenide form is described. A process for improving mechanical and optical properties of a selenide glass based on germanium selenide comprises the steps of mixing glass components, including a modifier in elemental or selenide form; melting the glass components to form a molten mixture; cooling the molten glass mixture to a solid state; annealing the solid glass; and cooling the annealed glass to about room temperature is also described.

Abstract: Hydrogen and/or carbon impurities are removed from chalcogenide or chalcoide glasses by the addition of a halide, such as TeCl.sub.4, to the batch composition. During melting of the batch composition, the metal halide reacts with the hydrogen and/or carbon impurities to form a hydrogen halide and/or carbon tetrahalide gas and a metal which becomes incorporated into the chalcogen-based glass. Useful halides include halides of sulfur, selenium, tellurium, polonium, or halides of a metal (such as aluminum, magnesium, zirconium, or a mixture thereof) that forms a stable oxide. Mixed metal halides may also be used. The glass melt is then distilled, outgassed, homogenized, fined, and annealed. An apparatus specially designed for making a fiber preform by the above process is also described. An annealed preform made by this method may be drawn into a low-loss fiber in the 2 .mu.m to 12 .mu.m range.

Abstract: A method of fabricating optical preforms that yield optical fibers having minimal scattering centers by substantially eliminating bubbles and crystallites that form during preform fabrication. The method utilizes glasses having low viscosity in their liquid state to eliminate large bubbles that contain ambient gasses. Small bubbles that have sizes comparable to the wavelength of light are eliminated by simultaneously vacuum-pumping and slow-cooling the liquid glass used to fabricate the preform before pouring the glass into the preform cast mold. Finally, bubbles due to the formation of vacuums in the preform are eliminated by applying a temperature gradient across the cast mold to induce a steep vertical gradient in viscosity in the liquid glass when the liquid glass is poured in the mold.

Abstract: Core/clad glass optical fiber preforms free of bubbles and soot at the coclad interface are fabricated by inserting a glass core rod into a cladding glass tube sized so that space remains between them, sealing the top and bottom of the tube onto the core rod to form a sealed space between them which is relatively soot free and under a vacuum and then hot isostatically pressing the sealed composite to collapse the tube onto the rod and also collapse bubbles in the glass. Soot formation is avoided or minimized by purging the space with inert gas while the bottom of the tube is collapsed onto the rod and by sealing the top under a dynamic vacuum and at the lowest possible temperature to avoid soot formation without cracking the glass. The space is vacuum outgassed before the second seal is made. Chalcogenide fiber drawn from a preform made in this fashion exhibits very low transmission losses.

Abstract: A method of making a polyimide coated heavy metal fluorinated fiber includes the steps of drawing an optical fiber through a low-temperature curing polyimide solution to form a polyimide coating which cures in a range of about 200.degree. and 390.degree. C. A low curing temperature enables a low temperature profile to be used for curing the coating. The low-temperature curing conditions provide a maximum fiber exposure temperature above the glass transition temperature of the fiber but minimize crystallization of the fiber during curing. The method is also applicable to chalcogenide fibers which carry optical signals in the infrared region.

Abstract: A method and apparatus are provided for forming a glass preform which can be directly drawn into a single or multi-mode optical fiber. Single or multi-mode fibers drawn from the preforms described herein have high quality core-clad interfaces since the core and cladding materials are not exposed to crystallization temperatures upon the addition of the core material to cladding material.

Abstract: A method and apparatus are provided for drawing a self-aligned core fiber free of surface contamination and inserting the core fiber into a cladding material to make an optical fiber preform. Single or multi-mode optical fibers having high quality core-clad interfaces can be directly drawn from the preforms described herein.

Abstract: The disclosed method of making a mixed glass optical fiber exemplarily comprises providing a high-silica tube, and causing molten non-high silica glass to flow into the bore of the tube by application of a pressure differential. In order to prevent cracking, the tube desirably has an outer diameter/inner diameter ratio of at least 5, preferably about 10 or even more, and an inner diameter of at most 1 min. In a preferred embodiment, a conventional SiO.sub.2 tube is partially collapsed to an inner diameter less than 1 mm, a quantity of a non-high-silica glass is placed in a neck of the partially collapsed tube and heated such that molten glass communicates with the reduced-diameter portion of the bore and can be drawn into the reduced-diameter portion by means of a vacuum. The resulting mixed glass body is then further stretched to result in a core rod of core diameter at most 0.3 min. After overcladding the core rod with SiO.sub.2, fiber is drawn from the thus produced preform. A thus produced fiber with SiO.

Abstract: A method and apparatus are provided for drawing a self-aligned core fiber free of surface contamination and inserting the core fiber into a cladding material to make an optical fiber preform. Single or multi-mode optical fibers having high quality core-clad interfaces can be directly drawn from the preforms described herein.

Abstract: A method of making a polyimide coated heavy metal fluorinated fiber includes the steps of drawing an optical fiber through a low-temperature curing polyimide solution to form a polyimide coating which cures in a range of about 200.degree. and 390.degree. C. A low curing temperature enables a low temperature profile to be used for curing the coating. The low-temperature curing conditions provide a maximum fiber exposure temperature above the glass transition temperature of the fiber but minimize crystallization of the fiber during curing. The method is also applicable to chalcogenide fibers which carry optical signals in the infrared region.

Abstract: A method and apparatus are provided for forming a glass preform which can be directly drawn into a single or multi-mode optical fiber. Single or multi-mode fibers drawn from the preforms described herein have high quality core-clad interfaces since the core and cladding materials are not exposed to crystallization temperatures upon the addition of the core material to cladding material.

Abstract: Halide glass articles, e.g. rods, tubes and preforms for making fluoride glass fibres, are prepared by melting and/or casting the articles under a low pressure, e.g. 0.01 to 500 mbars and, during the low pressure regime, a gas flow rate of between 0.01 to 100 liters/min (measured at NTP) is maintained. It has been found that subjecting the melts to a low pressure reduces the attenuation of the fibre which eventually results from the melts.