Abstract: The present invention relates to a method of making a soot particle and apparatus for making such soot particle. Preferably the method of making the soot particle is substantially free of the step of combusting a fuel and substantially free of the step of forming a plasma. Preferably, the apparatus is devoid of a heating element associated with both combustion and formation of a plasma. A preferred technique for at least one heating step for forming the doped soot particle is induction heating.

Abstract: The present invention provides an optical element including a silver halide-containing glass material having a concentration of less than 0.001 wt % cerium; and a refractive index pattern formed in the silver halide-containing glass material, the refractive index pattern including regions of high refractive index and regions of low refractive index, the difference between the refractive indices of the high refractive index regions and the low refractive index regions being at least 4×10−5 at a wavelength of 633 nm. The present invention also provides methods for making optical elements from siliver halide-containing glass materials.

Abstract: The present invention discloses a process for making rare earth (RE) doped optical fibre by using RE oxide coated silica nanoparticles as the precursor materia, more particularly the method of the present invention involves preparation of stable dispersions (sol) of RE oxide coated silica nanoparticles at ambient temperature and applying a thin coating on the inner surface of silica glass tube following dip coating technique or any other conventional methods, of the said silica sol containing suitable dopants selected from Ge, Al, P, etc.

Abstract: The present invention relates to a method of making a soot particle and apparatus for making such soot particle. Preferably the method of making the soot particle is substantially free of the step of combusting a fuel and substantially free of the step of forming a plasma. Preferably, the apparatus is devoid of a heating element associated with both combustion and formation of a plasma. A preferred technique for at least one heating step for forming the soot particle is induction heating.

Abstract: Disclosed is an optical fiber article for receiving pump radiation of a first wavelength for amplifying or generating radiation of a second wavelength. The optical fiber article includes a core for propagating light of the second wavelength. The core has a first index of refraction and includes a rare earth material. A cladding surrounds the core and has a second index of refraction that is less than the first index of refraction. The outer circumference of the cladding can include a plurality of sections, where the plurality of sections includes at least one substantially straight section and one inwardly curved section. The optical fiber article can also include at least one outer layer surrounding the cladding, where the index of refraction of the outer layer is less than the second refractive index. Methods for producing the optical fiber article are also disclosed, as well as methods for providing a preform for drawing such an optical fiber article.

Abstract: The present invention provides a simple method for fabricating fiber-optic glass preforms having complex refractive index configurations and/or dopant distributions in a radial direction with a high degree of accuracy and precision. The method teaches bundling together a plurality of glass rods of specific physical, chemical, or optical properties and wherein the rod bundle is fused in a manner that maintains the cross-sectional composition and refractive-index profiles established by the position of the rods.

Abstract: The present invention provides an improved process for making rare earth doped preforms and fibers by a combination of MCVD technique and solution doping method, said method comprising developing matched or depressed clad structure inside a silica glass substrate tube followed by deposition of unsintered particulate layer containing GeO2 and P2O5 for formation of the core and solution doping by soaking the porous soot layer into an alcoholic/aqueous solution of RE-salts containing co-dopants like AlCl3/Al(NO3)3 in definite proportion, controlling the porosity of the soot, dipping period, strength of the solution and the proportion of the codopants to achieve the desired RE ion concentration in the core and minimize the core clad boundary defects and followed by drying, oxidation, dehydration and sintering of the RE containing porous deposit and collapsing at a high temperature to produce the preform and overcladding with silica tubes of suitable dimensions and fiber drawing to produce fibers.

Abstract: An inorganic body containing rare earth and/or transition metal ions that has been irradiated with a pulsed laser beam in the manner such that a focal point of the pulsed laser beam is adjusted to an inner part of the inorganic body is disclosed. The inorganic body may be a glass or crystal containing one or more of oxide, halide and chalcogenide. The rare earth ion may be one or more of Ce, Nd, Pr, Sm, Eu, Tb, Dy, Tm, Tb. The transition metal ion may be one or more of Ti, Mn, Cr, V, Fe, Cu, Mo and Ru. When the focal point is relatively shifted with respect to the inorganic body, an ionic valence-changed domain is formed with a predetermined pattern at the inner part of the inorganic body. The pulsed laser beam preferably has a pulse width under a picosecond. The ionic valence change occurs at the focal point and its vicinity, but the rare earth or transition metal ion keeps its original valence at all other parts, so as to form a reformed domain with a predetermined pattern in the inorganic body.

Abstract: The present invention provides a simple method for fabricating fiber-optic glass preforms having complex refractive index configurations and/or dopant distributions in a radial direction with a high degree of accuracy and precision. The method teaches bundling together a plurality of glass rods of specific physical, chemical, or optical properties and wherein the rod bundle is fused in a manner that maintains the cross-sectional composition and refractive-index profiles established by the position of the rods.

Abstract: A method for manufacturing a photomask material includes delivering a powder containing silicon dioxide into a plasma to produce silica particles and depositing the silica particles on a deposition surface to form glass.

Abstract: A method for making a glass ceramic, optoelectronic material such as a clad optical fiber or other component for use in an optoelectronic device. The method comprises preparing a glass composition batch to yield a precursor glass for a nanocrystalline glass-ceramic that is doped with at least one kind of optically active ion, such as a transition metal or lanthanide element; melting the batch; forming a glass cane; surrounding the cane with a chemically inert cladding material shaped in the form of a tube; drawing a glass fiber from the combined precursor-glass “cane-in-tube” at a temperature slightly above the liquidus of the precursor glass composition, and heat treating at least a portion of the drawn clad glass fiber under conditions to develop nanocrystals within the core composition and thereby forming a glass ceramic.

Abstract: A device and method is disclosed for manufacturing optical fiber preforms utilizing microwave plasma assisted chemical vapor deposition. Precursor gas is introduced to the face of a vertically mounted dielectric rod, and a plasma is struck by means of simultaneous excitation of an E01 type wave and an H type wave with rotating linear polarization. The silica rod is positioned so that its face is at the bottom of the tube. Precursor gas is delivered from a position below the face of the silica rod, and microwave energy, which travels through the rod to the rod face, is delivered from a source positioned above the rod. With this configuration, a uniformly dense plasma localized on the face of the rod can simultaneously deposit both a pure or doped core and a doped cladding. It is also useful for creating waveguides, preform cores for use as substrates in creating optical fiber preforms, capillaries and ceramic rods.

Abstract: A preform for a low loss fiber optic cable and method and apparatus for fabricating such a preform is provided. The method includes providing AlCl3 and CVD precursors and locally doping CaCl3. Alkali and/or alkaline earth fluxing agents can be introduced. The alkali and/or alkaline earths are doped along with the aluminum into the silica glass core.

Abstract: A method for producing an optical fiber preform is disclosed. The fiber core is solution-doped with a high dopant concentration of an index modifier, preferably aluminum. High aluminum concentrations can be achieved without incorporating phosphorus in the core.

Abstract: The present invention provides a method of fabricating rare earth doped preforms and optical fibres by a combination of modified chemical vapour deposition (MCVD) process and solution doping technique said MCVD process is used to develop matched or depressed clad structure inside a silica glass substrate tube followed by deposition of porous silica soot layer containing GeO2, P2O5 or such refractive index modifiers by the backward deposition method for formation of the core and presintering the deposited particulate layer by backward pass with flow of GeCl4 and/or corresponding dopant halides, soaking the porous soot layer into an alcoholic/aqueous solution of RE-salts containing codopants such as AlCl3 in definite proportion, drying, oxidation, dehydration and sintering of the RE containing porous deposit and by collapsing at a high temperature to produce the preform followed by drawing the fibres by known technique to produce fibres with suitable core-clad dimensions and geometry.

Abstract: The reproducibility of preforms made by solution doping is significantly improved by adding an internal heat source, such as N2O, as a processing gas during the soot deposition process. The addition of the internal heat source gas results in forming a surface soot layer which exhibits a relatively uniform and consistent morphology. The improvement in the soot surface morphology results in improving the uniformity of the amount of solution dopant retained in the soot layer from preform to preform.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: A method for manufacturing an optical fiber, the method including the steps of: providing a substrate tube; depositing high purity silica-based cladding layers on the inside of the tube; depositing a germanium-free core comprising a glass including silica, and oxides of Al, La, Er, and Tm; collapsing the substrate tube to form a preform; and drawing the preform to yield an optical fiber.

Abstract: The present invention discloses a method of fabricating rare earth-doped preforms for optical fibers. A silica soot is deposited as a layer with high porosity on an inner surface of a silica-based tube by a modified chemical vapor deposition (MCVD) process at a temperature high enough to produce the silica soot but low enough to avoid sintering of the soot into the silica-based tube. The silica-based tube is then immersed in a solution including a rare earth element and a codopant element for impregnation. The excess solution is drained and the silica-based tube is dried in a stream of chlorine and inert gas at an elevated temperature. Then, the rare earth element and the codopant element are oxidized under an oxygen partial pressure at a temperature high enough to overcome kinetic limitations against oxidation.

Abstract: A material for use in optical amplifiers is described. The material includes an oxide glass substrate material, a rare earth dopant and a silver dopant. The silver dopant enhances photoluminescence of the rare earth dopants in the oxide glass. The silver can be introduced into the glass using an ion exchange process or by ion implantation. Oxide glass doped with erbium ions and silver ions provides a broad excitation band for photoluminescence of Er3+ in the visible and near ultraviolet. An amplifier material according to the present invention can be formed by ion implanting a rare earth ion, for example erbium, and doping with silver by an ion exchange method. Alternatively, the silver can be implanted into the material as well. The resulting silver dopant may be dispersed throughout the oxide glass primarily as ions as a result of the fabrication method.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: The present invention is directed to a fluorinated rare earth doped glass composition and method for making a glass-ceramic optical article therefrom, e.g. optical fiber waveguides, fiber lasers and active fiber amplifiers, having application in the 1300 nm and 1550 nm telecommunications windows. The inventive compositions include Pr3+ and/or Dy3+ in a concentration range of between 300-2,000 ppmw and Ag+ in a concentration range of between 500-2000 ppmw; or Er3+ in a concentration range of between 500-5,000 ppmw and Ag+ in a concentration range of between 0-2,000 ppmw. The monovalent silver ion provides an ionic charge balanced glass-ceramic crystal. These compositions exhibit reduced or absent rare earth ion clustering and fluorescence quenching effects in the presence of high concentrations of rare earth ion dopants.

Abstract: A method for manufacturing an optical article including the steps of providing a substrate tube; forming one or more cladding layers inside the substrate tube, the one or more cladding layers including an innermost cladding layer; forming a concentric fluorine reservoir adjacent to the innermost cladding layer; and forming a core adjacent to the fluorine reservoir and concentric with the one or more outer cladding layers. The fluorine concentration in the fluorine reservoir is higher than the fluorine concentration in either the core or the innermost cladding layer.

Abstract: The present invention discloses a method of fabricating rare earth-doped preforms for optical fibers. A silica soot is deposited as a layer with high porosity on an inner surface of a silica-based tube by a modified chemical vapor deposition (MCVD) process at a temperature high enough to produce the silica soot but low enough to avoid sintering of the soot into the silica-based tube. The silica-based tube is then immersed in a solution including a rare earth element and a codopant element for impregnation. The excess solution is drained and the silica-based tube is dried in a stream of chlorine and inert gas at an elevated temperature. Then, the rare earth element and the codopant element are oxidized under an oxygen partial pressure at a temperature high enough to overcome kinetic limitations against oxidation.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: Applicants have discovered that glass optical waveguides subject to hydrogen-induced loss increases can be passivated by treating the glass with deuterium. The deuterium-treated glass not only exhibits a lower rate of loss increase when later exposed to environments containing H2, but also retains high transmission of light in the 1.55 and 1.31 micrometer wavelength regions immediately after the deuterium heat treatment. The method applies to Er-doped fiber, transmission fiber and planar waveguides. Under some circumstances, hydrogen can be substituted for deuterium.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: The present invention discloses novel methods for fabricating optical fiber glass preforms which may contain alumina, germania, erbium, or other rare earth metals as dopants. Doping with a higher concentration of alumina enhances the solubility of the erbium, or other rare earth, dopant within the glass and the resultant optical properties of the fiber. However, the addition of an alumina dopant can cause processing difficulties due to the formation of inclusions, such as gas bubble, seeds or crystallite formation, within the glass preform or glass cane. The present invention overcomes these processing difficulties and produces glass preforms or canes that are inclusion-free.

Abstract: A hybrid method of and apparatus for producing a structure capable of being drawn into an optical fiber. The method includes the steps of conducting vapor-phase reactants into an interior region of a glass tube, conducting aerosol form reactants into the interior of the glass tube. The tube is exposed to a heat, thereby causing a reaction among the vapor-phase and aerosol reactants. The reaction yields a product, in a solid form, within the tube. The apparatus includes a reaction tube, a vapor-phase reactant conduit, an aerosol-form conduit, and a heat source. The vapor-phase and aerosol-form reactant conduits facilitate introduction of vapor-phase and aerosol-form reactants into the reaction tube. The aerosol-form reactants are introduced proximate to a reaction zone created by the heat source. The aerosol-form reactants conduit and heat source travel the axial length of the reaction tube.

Abstract: The present invention discloses novel methods for fabricating glass articles, particularly optical fiber glass preforms, which may contain alumina, yttrium, lanthanum, erbium, or other rare earth metals as dopants. The glass articles made in accordance with the present invention exhibit radially uniform dopant profiles relative to conventional dopant methods. In addition, the overall concentration of the dopant is increased relative to analogous dopant methods.

Abstract: The present invention provides an improved process for making rare earth doped preforms and fibers by a combination of MCVD technique and solution doping method, said method comprising developing matched or depressed clad structure inside a silica glass substrate tube followed by deposition of unsintered particulate layer containing GeO2 and P2O5 for formation of the core and solution doping by soaking the porous soot layer into an alcoholic/aqueous solution of RE-salts containing co-dopants like AlCl3/Al(NO3)3 in definite proportion, controlling the porosity of the soot, dipping period, strength of the solution and the proportion of the codopants to achieve the desired RE ion concentration in the core and minimize the core clad boundary defects and followed by drying, oxidation, dehydration and sintering of the RE containing porous deposit and collapsing at a high temperature to produce the preform and overdladding with silica tubes of suitable dimensions and fiber drawing to produce fibers.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: An optical amplifying fiber including a clad, a first core provided inside the clad and containing Ge, a second core provided inside the first core and containing Er and Al, and a third core provided inside the second core and containing Ge. The second core has a refractive index higher than that of the clad, and the first and third cores have refractive indexes each of which is higher than that of the second core. Since the third core having the high refractive index is provided at a central portion, it is possible to make smaller a mode field diameter and hence to improve a conversion efficiency of pumping light into signal light. Further, since the second core contains Al as an amplification band width increasing element, it is possible to sufficiently ensure a wide amplification band width.

Abstract: A method and apparatus are disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: A method that provides a new way to embed rare earth fluorides into silicate (or germania-doped silica) glasses by means of solution chemistry. Embedding rare earth fluorides into a silicate (or germania-doped silica) glass comprises the following steps. First, form a porous silicate core preform. Second, submerge the preform into an aqueous solution of rare earth ions. Third, remove the preform from the solution and wash the outside surfaces of the preform. Fourth, submerge the preform into an aqueous solution of a fluorinating agent to precipitate rare earth trifluorides from the solution and deposit in the pores or on the wall of the preform. This is followed by drying.

Abstract: An optical article having a rare earth doped, fluorinated aluminosilicate glass core composition consisting essentially, in mole %, of: SiO2 0-90 GeO2 0-90 Na2O 0-25 Li2O 0-10 K2O 0-25 Rb2O 0-25 Cs2O 0-25 Al2O3 5-40 Ga2O3 5-40 RE2(1)O3 0-40 RE2(2)O3 0-1  Er2O3 0.

Abstract: A method that provides a new way to embed rare earth fluorides into silicate (or germania-doped silica) glasses by means of solution chemistry. Embedding rare earth fluorides into a silicate (or germania-doped silica) glass comprises the following steps. First, form a porous silicate core preform. Second, submerge the preform into an aqueous solution of rare earth ions. Third, remove the preform from the solution and wash the outside surfaces of the preform. Fourth, submerge the preform into an aqueous solution of a fluorinating agent to precipitate rare earth trifluorides from the solution and deposit in the pores or on the wall of the preform. This is followed by drying.

Abstract: A sintered dense glass, alumina-doped optical fiber preform is stretched and is then heated to a temperature of 1490-1495° C. to remove bubbles without causing crystallization. Thereafter, the stretched glass body is either drawn directly into an optical fiber or overclad and then drawn into a fiber.

Abstract: Homogeneous assays for determining quantitatively the extent of a specific binding reaction can be carried out effectively on very dilute solutions using measurements of fluorescence if a fluorescence measurement scheme that is capable of rejecting short-lived background fluorescence is employed and if the fluorescent group being measured has the following properties: a. the group being measured must be a rare earth metal chelate complex combination; b. the chelate must be water-soluble; c. the complex combination must also be stable in extremely dilute aqueous solutions, that is, the measured chelate must have at least one ligand having a metal-to-ligand binding constant of at least about 1013M−1 or greater and it must have a fluorescent emission that is long-lived compared to the longest decay lifetime of ambient substances and have a half life of from 0.01 to 50 msec.

Abstract: A method and apparatus is disclosed for the manufacture of an optical fiber preform having incorporated therein a comparatively high concentration of rare earth dopant material, and which thus can be drawn and processed into an optical fiber having low numerical aperture, low core attenuation, and high pumping power absorption. The high concentrations of rare earth dopant material are accomplished through either the “hybrid vapor processing” (HVP) method or a “hybrid liquid processing” (HLP) method, each capable of being practiced in combination or independently of one another. The HVP method involves the vaporization of a rare earth halogen by the exposure thereof to a sufficiently elevated temperature, independently, or contemporaneously with the transport of the resultant rare earth halogen laden vapor, into a glass forming oxidation reaction zone on a flowing stream of essentially an unreactive inert gas, such as helium.

Abstract: A method of and an apparatus for erbium-doped optical fibers usable as an optical amplifier allowing optical signals to be directly amplified by themselves, which method and apparatus are capable of reducing manufacturing time while increasing productivity.

Abstract: A method of making a fiber having a single mode absorptive core whose position relative to the cross sectional plane of the inner multimode cladding varies along the length of the fiber. A groove or grooves are made in the outer cladding of the preform. When fiber is drawn from the grooved preform, the position of the core does not follow the centerline of the fiber; the position within the fiber varies in accordance with the grooves.

Abstract: A method of fabricating an optical fiber doped with a rare earth component using a volatile complex, which flattens the light frequency response under a stimulated emission of radiation principle using a modified chemical vapor deposition method. Silicon tetrachloride (SiCl.sub.4) and oxygen are injected into a quartz reaction tube under a heating process, so that a cladding layer is repeatedly deposited. Then, a volatile organic metal chelate, silicon tetrachloride and oxygen are injected into the quartz reaction tube, and then heated and water-cooled to form a porous layer. At the same time, a rare earth element is deposited on the porous layer, to thereby form a core layer. Thereafter, via a high heating process, a preform is completed. Then, an optical fiber is obtained from the preform via a drawing-out process. Here, hydroxide ions (OH.sup.

Abstract: A cladding-pumped fiber structure, suitable for use as a laser, provides for efficient clad-to-core energy transfer. The outside interface of the pump-clad is constructed from a rod-shaped preform by local melt-displacement using an open flame.

Abstract: A selenide glass with improved mechanical and optical properties such as ended transmission in the infrared region of radiation having wavelengths beyond 15 microns; Tg in the region of 363.degree.-394.degree. C.; and thermal stability of 85.degree.-145.degree. C. based on the difference between T.sub.g and T.sub.x, comprising, on mol basis, 20-70% germanium selenide, 0.5-25% gallium selenide, indium selenide or mixtures thereof; and 5-50% of at least one alkaline earth in selenide form is described. A process for improving mechanical and optical properties of a selenide glass based on germanium selenide comprises the steps of mixing glass components, including a modifier in elemental or selenide form; melting the glass components to form a molten mixture; cooling the molten glass mixture to a solid state; annealing the solid glass; and cooling the annealed glass to about room temperature is also described.

Abstract: A single mode optical fiber suitable for use in an amplified fiber optic system which includes an inner glass core doped with a rare earth element and an outer transparent glass cladding. The fiber exhibits a plurality of mode coupling sites formed at regular intervals along the length of the fiber which provides for a reduced DOP. The sites are formed by a twist at regular intervals along the fiber length by applying a torque to the fiber. The method of forming the fiber is also disclosed.

Abstract: A first process of the invention comprises forming two constricted portions (28) at a quartz reaction tube (4), charging a solution of a compound of a rare earth element as a solution into the section between the constricted portions (28) for doping. By this, the doping concentration becomes uniform along the length of an optical fiber preform (30) with defects being rarely produced. This process does not involve any complicated operation. A second process of the invention comprises impregnating a solution in the form of a mist in a soot-like core glass (26) by which it becomes possible to control the doping concentration in high accuracy. A third process of the invention comprises impregnating a solution while controlling the concentration in response to a quantity of a transmitted laser beam through a soot-like core glass (26), by which the doping concentration is ensured independently of the density of the soot-like core glass.

Abstract: A single mode optical fiber suitable for use in an amplified fiber optic system which includes an inner glass core doped with a rare earth element and an outer transparent glass cladding. The fiber exhibits a plurality of mode coupling sites formed at regular intervals along the length of the fiber which provides for a reduced DOP. The sites are formed by a twist at regular intervals along the fiber length by applying a torque to the fiber. The method of forming the fiber is also disclosed.

Abstract: The present invention is directed to the preparation of two groups of transparent glass-ceramics exhibiting high optical clarity and containing essentially only one crystal phase. The first group consists essentially, in cation percent, of______________________________________ SiO.sub.2 20-35 PbF.sub.2 19-23 AlO.sub.1.5 10-20 YF.sub.3 3-7, CdF.sub.2 19-34 ______________________________________and the second group consists essentially, in cation percent, of ______________________________________ SiO.sub.2 20-35 PbF.sub.2 15-25 AlO.sub.1.5 10-20 YF.sub.3 3-7 CdF.sub.2 21-31 ZnF.sub.2 3-7. ______________________________________These glass-ceramics may be used to fabricate optical waveguide fibers. Also when doped with certain rare earth elements, notably Pr, Er, and Dy, the glass-ceramic materials may be used to fabricate optical amplifiers and lasers.