Ion Exchange Utilized Patents (Class 65/400)
  • Patent number: 11968794
    Abstract: Glass-based articles are disclosed having a thickness in a range of from about 0.2 mm to about 4.0 mm, a first compressive stress layer extending from a first surface of the glass-based article to a first depth of compression that is in a range of from about 5% to about 20% of the thickness, a second compressive stress layer extending from a second surface of the glass-based article to a second depth of compression that is in a range of from about 5% to about 20% of the thickness, wherein the second surface is opposite the first surface, and a central region extending from the first depth of compression to the second depth of compression and having a maximum tensile stress in a range of from about 0.5 MPa to about 20 MPa. Electronic devices comprising the glass-based articles and methods of making glass-based articles are also disclosed.
    Type: Grant
    Filed: December 5, 2022
    Date of Patent: April 23, 2024
    Assignee: CORNING INCORPORATED
    Inventors: Kameron Isaiah Chambliss, Benedict Osobomen Egboiyi, Kevin Barry Reiman, Vitor Marino Schneider
  • Patent number: 11912615
    Abstract: Glass-based articles comprise stress profiles providing improved fracture resistance. The glass-based articles herein provide high fracture resistance after multiple drops.
    Type: Grant
    Filed: March 6, 2023
    Date of Patent: February 27, 2024
    Assignee: CORNING INCORPORATED
    Inventors: Timothy Michael Gross, Xiaoju Guo, Jason Thomas Harris, Peter Joseph Lezzi, Alexandra Lai Ching Kao Andrews Mitchell, Pascale Oram, Kevin Barry Reiman, Rostislav Vatchev Roussev, Ljerka Ukrainczyk
  • Patent number: 11905202
    Abstract: A method of modifying a glass substrate comprises: generating surface features with peaks and valleys on a first surface of a glass substrate, the surface features providing a roughness average (Ra) within the range of 10 nm to 2000 nm; generating a region of the glass substrate that is under compressive stress, the region extending from the first surface to a depth of compression; and removing a portion of the region under compressive stress from the first surface into the depth of compression to define a new first surface still having surface features with peaks and valleys providing a roughness average (Ra) within the range of 10 nm to 2000 nm. Removing the portion of the region under compressive stress from the first surface into the depth of the compression to define a new first surface can comprise contacting the first surface with a light etchant.
    Type: Grant
    Filed: May 15, 2020
    Date of Patent: February 20, 2024
    Assignee: Corning Incorporated
    Inventors: Yuhui Jin, Taylor Marie Wilkinson
  • Patent number: 10927029
    Abstract: An apparatus for producing composite glass tube with a plurality of glass layers includes a plurality of cylindrical containers of increasing inner dimensions concentrically arranged and stationary. Each cylindrical container includes a side wall, bottom wall, and a delivery ring. Adjacent cylindrical containers define an annular chamber, a flow control region, and an annular flow channel therebetween. The apparatus includes at least one flow control valve positioned in the flow control region and translatable relative to the adjacent cylindrical containers. Translation of the flow control valves relative to the cylindrical containers is operable to change an impedance to flow of molten glass through the flow control region, thereby modifying an overall flow rate or circumferential distribution of molten glass from the cylindrical containers. Systems and methods for producing composite glass tube using the apparatus are also disclosed.
    Type: Grant
    Filed: November 27, 2018
    Date of Patent: February 23, 2021
    Assignee: CORNING INCORPORATED
    Inventors: Dale Madard Fisher, Jr., David Posada-Pineda
  • Patent number: 8561429
    Abstract: A strengthened glass that does not exhibit frangible behavior when subjected to impact or contact forces, and a method of strengthening a glass. The glass may be strengthened by subjecting it to multiple, successive, ion exchange treatments. The multiple ion exchange treatments provide a local compressive stress maximum at a depth of the strengthened layer and a second local maximum at or near (e.g., within 10 ?m) the surface of the glass.
    Type: Grant
    Filed: July 10, 2009
    Date of Patent: October 22, 2013
    Assignee: Corning Incorporated
    Inventors: Douglas Clippinger Allan, Adam James Ellison, Sinue Gomez
  • Patent number: 8312743
    Abstract: A method for forming buried ion-exchanged waveguides involves a two-step process. In a first step a waveguide is formed at the surface of a substrate using an ion-exchange technique. After formation of the waveguide, a field-assisted annealing is carried out to move the waveguide away from the surface of the substrate so that it is buried in the substrate. Exemplary field-assisted annealing is carried out at a temperature close to the ion-exchange temperature ±10° C. to optimize results.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: November 20, 2012
    Assignee: City University of Hong Kong
    Inventors: Edwin Yue Bun Pun, Ke Liu
  • Patent number: 7882709
    Abstract: Provided are a glass substrate for an information recording medium, which has both high strength and high flatness and can be manufactured at low cost, a method for manufacturing such glass substrate and an information recording medium using such glass substrate. The glass substrate for the information recording medium satisfies inequalities of 0.1?(W1?W3)/W2?5, where, W1 is an ion concentration at the center portion in the thickness direction of the glass substrate in a chemically reinforced region at the outer circumference end surface and the inner circumference end surface of the glass substrate and is the maximum value of K+ ion concentration, W2 is a Na+ ion concentration at a position where the K+ ion concentration is maximum, and W3 is a K+ ion concentration in a glass substrate region not chemically reinforced.
    Type: Grant
    Filed: November 5, 2007
    Date of Patent: February 8, 2011
    Assignee: Konica Minolta Opto, Inc.
    Inventors: Hideki Kawai, Kenichi Sasaki, Hiroaki Sawada
  • Patent number: 7858546
    Abstract: The present invention provides a mother glass composition for gradient-index lens, from which a lead-free Li-based gradient-index lens that is excellent in weather resistance, in particular weather resistance in the presence of water, can be manufactured. The mother glass composition includes the following components, indicated by mol %: 40?SiO2?65; 1?TiO2?10; 0.1?MgO?22; 0.15?ZnO?15; 2?Li2O?18; 2?Na2O?20; 0?B2O3?20; 0?Al2O3?10; 0?K2O?3; 0?Cs2?O?3; 0?Y2O3?5; 0?ZrO2?2; 0?Nb2O5?5; 0?In2O3?5; 0?La2O3?5; and 0?Ta2O5?5. The mother glass composition further includes at least two oxides selected from CaO, SrO, and BaO each in a range of 0.1 mol % to 15 mol %. The total of MgO+ZnO is greater than or equal to 2 mol %. The molar ratio of ZnO/(MgO+ZnO) is in a range of 0.07 to 0.93. The total of Li2O+Na2O is in a range of 6 mol % to 38 mol %. The total of Y2O3+ZrO2+Nb2O5+In2O3+La2O3+Ta2O5 is in a range of 0 mol % to 11 mol %.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: December 28, 2010
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Taro Miyauchi, Tatsufumi Shiba
  • Publication number: 20100251775
    Abstract: A treatment method for an optical fibre including the steps of exposing the fibre to an atmosphere containing deuterium at a given temperature, concentration and pressure, measuring the attenuation in the fibre as a function of time at least one wavelength, during the exposure of the fibre to an atmosphere containing deuterium, identifying an attenuation maximum after an exposure duration, and stopping the exposure of the fibre to the atmosphere containing deuterium when said duration has elapsed.
    Type: Application
    Filed: March 22, 2010
    Publication date: October 7, 2010
    Applicant: DRAKA COMTEQ B.V.
    Inventors: Elise Regnier, Frans Gooijer, Stephanus Gerardus Fransiscus Geerings, Ekaterina Burov, Aurelien Bergonzo, Alain Pastouret
  • Publication number: 20100154479
    Abstract: Disclosed is a method and device for manufacturing an optical preform. The method includes supplying dopant-containing glass-forming gases to the interior of a hollow glass substrate tube. Furthermore, the supply flow of dopant-containing glass-forming gases includes a main gas flow and one or more secondary gas flows. The secondary gas flows are divided into subflows, which are supplied to the interior of the hollow glass substrate tube together with the main gas flow. The method further includes effecting deposition of glass layers on the interior surface of the hollow glass substrate tube.
    Type: Application
    Filed: December 19, 2009
    Publication date: June 24, 2010
    Applicant: DRAKA COMTEQ B.V.
    Inventors: Igor Milicevic, Mattheus Jacobus Nicolaas van Stralen, Johannes Antoon Hartsuiker, Roland Gerhardres Jacobus Maria Heuvelmans
  • Patent number: 7382541
    Abstract: A gradient-index rod lens is provided that is excellent in yield. The gradient-index rod lens has a core/clad structure and is obtained by providing a mother glass rod, which includes a core glass mother composition and a clad glass mother composition, with a refractive index distribution through ion exchange. The clad and the core each contains an alkali metal oxide but are substantially free from lead. The clad and the core each contains an alkali metal oxide and has a basic composition including components other than the alkali metal oxide, but they are different from each other in the basic composition. The clad glass mother composition has a higher thermal expansion coefficient and glass-transition temperature than those of the core glass mother composition. The difference of the thermal expansion coefficient between the clad glass mother composition and the core glass mother composition is larger than 2×10?7/° C. but smaller than 20×10?7/° C.
    Type: Grant
    Filed: October 4, 2005
    Date of Patent: June 3, 2008
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Teruhide Inoue, Kunihiro Nomiyama, Koichi Sakaguchi
  • Patent number: 7221835
    Abstract: Methods of fabricating extra-mural absorption elements adapted for incorporation in an image-conducting optical fiber array include fabricating various constituent components to be included in an optical fiber bundle from one or more reducible-ion-containing glasses. Various components fabricated from a reducible-ion-containing glass are selectively exposed to a reducing atmosphere such that they are reduction-blackened prior to at least one heating and drawing step relative to the bundle into which they are to be fusedly incorporated. Such “pre-blackened” components function as extra-mural absorption media throughout the length of an image-conducting optical fiber array and alternatively include fiber claddings and substitutional and interstitial extra-mural absorption elements.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: May 22, 2007
    Assignee: Schott Corporation
    Inventors: Michael Weisser, Paige Higby, Richard Strack, Kevin Tabor, James Triba, Gary DiGregorio
  • Patent number: 7149395
    Abstract: The present invention provides a light-enhancing component and a fabrication method thereof by using the focused-ion-beam. In the present invention, the surface plasmon polariton structure is coated on the surface of the optical fiber so as to form the light-enhancing component. When the light passes through the optical fiber, the luminous flux transmitted through the aperture on the surface plasmon polariton is enhanced, and the light beam smaller than the diffraction limitation can be transmitted to the far-field, i.e. the nano-optic sword is formed. The light-enhancing component of the present invention can be used for the optical data storage, the optical microscopy, the biomedical detections and the lithography to perform the extra optical resolutions beyond the diffraction limitation.
    Type: Grant
    Filed: August 9, 2005
    Date of Patent: December 12, 2006
    Assignees: Instrument Technology Research Center, National Applied Research Laboratories
    Inventors: Jyh-Shin Chen, Tong-Long Fu, Shao-Chang Cheng, Yu-Hsuan Lin, Yi-Chiuen Hu, Hui-Hsiung Lin, Hsiao-Yu Chou
  • Patent number: 6769274
    Abstract: The present invention relates to a method of manufacturing a waveguide using an ion exchange process. The present invention controls the refractive index and the thickness of a surface layer on a glass substrate using an ion exchange process, forms the waveguide pattern on the surface layer by means of photolithography and etching process and coats with materials having the refractive index same to or lower than that of the glass substrate to form a cladding layer. Accordingly, the present invention can manufacture a planar waveguide, which is excellent in dimension control and reproducibility and has a sharp step wall.
    Type: Grant
    Filed: December 26, 2001
    Date of Patent: August 3, 2004
    Assignee: Electronics and Telecommunications Research Institute
    Inventors: Doo Hee Cho, Joon Tae Ahn, Min Yong Jeon, Kyong Hon Kim
  • Patent number: 6470712
    Abstract: A laser processing method for removing glass by melting, evaporation or ablation from sheet-like glass substrate for forming microscopic concavities and convexities. Diffraction grating and planar microlens array obtained thereby.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: October 29, 2002
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Tadashi Koyama, Keiji Tsunetomo, Masahiro Oikawa, Kenjiro Hamanaka
  • Patent number: 6393180
    Abstract: A method of forming a grating in waveguide uses an ion exchange process to provide a waveguide region within and clad by a surrounding substrate and through an ion exchange process diffusing into the substrate an ion, such as such as Ag+, that is photosensitive and that provides a refractive index difference from adjacent non-diffused regions of the substrate. After the diffusion process, the step of exposing at least some of the waveguide region to light having a suitable intensity and duration to provide a permanent index change within regions of the waveguide region to form a grating is performed.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: May 21, 2002
    Assignee: JDS Fitel Inc.
    Inventors: Mark Farries, Barrie Keyworth, Jan Ingenhoff, Norbert Fabricius
  • Publication number: 20020017115
    Abstract: A method that provides a new way to embed rare earth fluorides into silicate (or germania-doped silica) glasses by means of solution chemistry. Embedding rare earth fluorides into a silicate (or germania-doped silica) glass comprises the following steps. First, form a porous silicate core preform. Second, submerge the preform into an aqueous solution of rare earth ions. Third, remove the preform from the solution and wash the outside surfaces of the preform. Fourth, submerge the preform into an aqueous solution of a fluorinating agent to precipitate rare earth trifluorides from the solution and deposit in the pores or on the wall of the preform. This is followed by drying.
    Type: Application
    Filed: July 26, 2001
    Publication date: February 14, 2002
    Inventor: Huailiang Wei
  • Patent number: 6289699
    Abstract: A wavelength selective optical fiber coupler having various applications in the field of optical communications is disclosed. The coupler is composed of dissimilar waveguides in close proximity. A light induced, permanent index of refraction grating is recorded in the coupler waist The grating filters and transfers energy within a particular range of wavelengths from a first waveguide to a second waveguide. Transversely asymmetric gratings provide an efficient means of energy transfer. The coupler can be used to combine or multiplex a plurality of lasers operating at slightly different wavelengths into a single fiber. Other embodiments such as a dispersion compensator and gain flattening filter are disclosed.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: September 18, 2001
    Assignee: Arroyo Optics, Inc.
    Inventors: Anthony S. Kewitsch, George A. Rakuljic, Amnon Yariv
  • Patent number: 6128926
    Abstract: A non-phase separable glass material for fabricating a GRIN lens comprises 5-20 mole % boron oxide and ratio R of network modifiers in mole % to the network former boron oxide in mole % is in the range of about 1-1.5. The melted preform of such glass material is extruded through an opening to form a glass rod where the extrusion process eliminates bubbles that may be present in the preform. Neodymium oxide may be added in the frit material for forming the preform to reduce friction forces in the extrusion process and reduces the stress in the glass rod. Centerless grinding may be performed to control the diameter and roughness of the surface of the rod to control the diffusion parameters during the subsequent ion-exchange.
    Type: Grant
    Filed: March 15, 1999
    Date of Patent: October 10, 2000
    Assignee: Dicon Fiberoptics, Inc.
    Inventors: Udayan Senapati, Ho-Shang Lee
  • Patent number: 6067388
    Abstract: The invention is directed to a method for making integrated optical components having strip waveguides (11 to 15; 21 to 2M) and a layer waveguide 53. A mask 4 having a lattice structure 3i functions to generate the layer waveguide 53 via ion exchange. The method of the invention is suitable for making couplers having free spaces with low attenuation and is especially suitable for arrayed waveguide grating multiplexers. The invention also is directed to an integrated optical component made pursuant to the method of the invention.
    Type: Grant
    Filed: July 14, 1999
    Date of Patent: May 23, 2000
    Assignee: IOT Integrierte Optik GmbH
    Inventors: Norbert Fabricius, Wolfgang Foss, Martin Wolff, Uwe Hollenbach, Uwe Seiberth