Abstract: An optical device may include at least one optical fiber, and a phase change material (PCM) layer on the at least one optical fiber. The PCM layer may include GexSey, where x is in a range of 20-40, and y is in a range of 60-80.

Abstract: An article of manufacture for warming human extremities via graduated thermal insulation with a blanket comprised of concentrations of and transitions to and from concentrations of various types of woven thread fabric or non-woven fabric, having various properties of thermal insulation.

Abstract: A graphite crucible for silicon single crystal manufacturing by the Czochralski method, having a long life cycle, contains at least one gas venting hole provided in a corner portion of the crucible. Gas generated by reaction between the graphite crucible and a quartz crucible is released to the outside through the gas venting hole, and formation of SiC on the surface of the graphite crucible and deformation of the quartz crucible caused by the pressure of the generated gas are prevented.

Abstract: Provided is an optical fiber drawing apparatus and optical fiber drawing method using the same. The apparatus may include a crucible accommodating core and clad sources and having a bottom hole through which the core and clad sources pass, and a plug disposed under the crucible, the plug passing through the bottom hole. The plug may include a bottom plug disposed under the crucible to close the bottom hole, and a first upper plug disposed on the bottom plug to pass through the bottom hole.

Abstract: A process includes the steps of disposing a solid core glass rod at a point removed from hot temperature that can cause crystallization in the core glass rod, disposing a solid clad glass rod at a point removed from the core glass rod; softening to the flowing condition the solid clad glass rod, transferring the softened clad glass to a lower point, the softened clad glass having a central void therethrough, heating the softened clad glass above its crystallization temperature, cooling the softened clad glass to a draw temperature, transferring the solid core glass rod into the central void in the softened glad glass, softening to the flowing condition the solid core glass rod with the heat from the softened and cooled clad glass, and drawing the core/clad, glass fiber by allowing the clad and core glasses to flow in the form of a fiber.

Abstract: A crucible for melting a silica for fusion of said silica into a desired shape. The crucible having a main body with inner and outer surfaces comprised of a refractory material. In addition, at least a portion of the inner surface includes a barrier layer comprised of a material selected from rhenium, osmium, iridium, and mixtures thereof. An inlet tube to the crucible being provided to supply an oxidizing gas to a melt zone.

Abstract: The double crucible for a glass drawing method has a heatable outer crucible (1) and an inner crucible (2) surrounded by the outer crucible (1), which is heatable separately from the outer crucible (1). Both crucibles (1,2) have an outlet nozzle (1a, 2a) for the glass to be drawn. To make glass fibers from heavy metal oxide glass (HMO-glass) with higher quality and comparatively simple crucible features, the outlet nozzle (1a) of the outer crucible (1) extends a certain distance beyond the outlet nozzle (2a) of the inner crucible (2). Surfaces of the outlet nozzles coming in contact with the glass melt are polished and are provided on a material, which has a reducing action on heavy metal glass in the melt in all cases. These surfaces also have sufficient mechanical strength for and chemical inertness to heavy metal oxide glass.

Abstract: This invention pertains to apparatus and process for making core/clad glass fibers. The apparatus includes a central tube or receptacle connected at the top to a pressure controller and terminating in a reduced section; a side tube or receptacle positioned at about the level of the upper portion of the central tube; an outer tube or receptacle disposed around the bottom portion of the central tube terminating in a smaller section which is concentric with and spaced directly below the section of the central tube; a side arm connecting the side tube and the outer tube; and furnaces around the side, outer, and the reduced sections of the central arid the outer tubes.

Abstract: A starting material for producing optical fibers contains metal halides. The refractive index of the optical fiber formed from the starting material is predeterminable by adjusting a partial pressure ratio of a halogen-containing gas mixture. The starting material is produced by mixing halogenated gases into a gas mixture with the desired partial pressure ratio, causing a chemical reaction at a first temperature of the gas mixture with at least metal to form a reaction product, the first temperature being higher than the melting temperature of the reaction product and cooling the reaction product to a second temperature that is below the melting temperature.

Abstract: A method for making gradient refractive index optical components includes mixing a molten basic material (11) with a refractive index modifying material (21) in continuously changing proportions. The mixture is changed into a plurality of semi-molten fibers (41), and the fibers are rolled to form a continuous plate (51). The plate has a continuously changing refractive index along a lengthwise direction thereof. The plate is wound around a spindle (57) to obtain a wound preformed rod (58). The preformed rod is integrally fused by local heating, and drawn to form a draw (61) having a predetermined diameter. The draw is cut into pieces. Each piece can then be made into an optical component having a continuously changing refractive index in a radial direction. The method allows precise control of all steps, and such control is achieved with relative ease throughout.

Abstract: The disclosed invention includes a method of making an optical fiber drawn from a multiple crucible. The method includes moving a first crucible of the multiple crucible relative to a second crucible of the multiple crucible. The invention also includes minimizing core and cladding diffusion. A tip of the first crucible is disposed axially above a tip of the second crucible by a preselected distance. The invention further includes the ability to alter a diameter of the core of the fiber. A differential pressure is applied to the first crucible. A positive differential pressure is applied to increase the core diameter. A negative differential pressure is applied to decrease the core diameter. Furthermore, the invention includes drawing the fiber under non-isothermal conditions; there is a thermal gradient of at least 10° C./m between the two tips.

Abstract: The invention relates to a method of making an optical fiber and an optical fiber made in accordance with the inventive method. The method includes the step of drawing an optical fiber from a multiple crucible apparatus, wherein one of the crucibles of the apparatus has a non-symmetrical orifice. The inventive fiber has at least a core and cladding. At least one section of the inventive fiber includes an orientation element.

Abstract: This invention pertains to apparatus and process for making core/clad glass fibers. The apparatus includes a central tube or receptacle connected at the top to a pressure controller and terminating in a reduced section; a side tube or receptacle positioned at about the level of the upper portion of the central tube; an outer tube or receptacle disposed around the bottom portion of the central tube terminating in a smaller section which is concentric with and spaced directly below the section of the central tube; a side arm connecting the side tube and the outer tube; and furnaces around the side, outer, and the reduced sections of the central and the outer tubes.

Abstract: The present invention is directed to a fluorinated rare earth doped glass composition and method for making a glass-ceramic optical article therefrom, e.g. optical fiber waveguides, fiber lasers and active fiber amplifiers, having application in the 1300 nm and 1550 nm telecommunications windows. The inventive compositions include Pr3+ and/or Dy3+ in a concentration range of between 300-2,000 ppmw and Ag+ in a concentration range of between 500-2000 ppmw; or Er3+ in a concentration range of between 500-5,000 ppmw and Ag+ in a concentration range of between 0-2,000 ppmw. The monovalent silver ion provides an ionic charge balanced glass-ceramic crystal. These compositions exhibit reduced or absent rare earth ion clustering and fluorescence quenching effects in the presence of high concentrations of rare earth ion dopants.

Abstract: A method of fabricating an optical fiber incorporating a volatile constituent, involving: (a) providing a preform comprising a cladding glass having an axial aperture and a core glass arranged in the axial aperture, wherein the working temperature of the core glass lies below the working temperature of the cladding glass; and (b) drawing the preform into an optical fiber at a drawing temperature that lies between the working temperatures of the core and cladding glasses and above the softening temperature of the cladding glass, wherein the core glass prior to drawing includes a dioxide or higher oxide compound of the volatile constituent having a Gibbs free energy of disassociation into a monoxide compound of the volatile constituent that is negative at the drawing temperature, whereby the dioxide or higher oxide compound tends to disassociate into the monoxide compound during drawing. The volatile constituent may be Sn or Pb. The method may also be adapted for incorporating P as the volatile constituent.

Abstract: The disclosed invention is a rotationally symmetrical resistance furnace heating element. The heating element has at least two ends. A respective cooling element is disposed in communication with each end. The heating element includes at least first and second high current density sections. The high current density sections are axially separated by at least one low current density section. The high current density sections have a smaller diameter than the low current density section. The invention also includes a multiple crucible method of drawing an optical fiber from the draw furnace described above. The method includes the step of heating an entire body of raw materials in a hot zone in the furnace.

Abstract: A double crucible fiber fabrication system employing a rod to control flow of the core material to produce a core of desired diameter. The rod fits closely within the inner crucible and moves at a speed necessary to produce a core material flow rate which will produce a desired core diameter. Control of the rod speed produces good control of core diameter for a wide variety of different core materials. It is also possible to control the rod speed in order to compensate for capillary effects and leakage of core material. Furthermore, control of the rod speed allows fabrication of a fiber having a core diameter which varies as desired throughout a single fiber.

Abstract: Glass compositions for a core/cladding type distributed-index optical element produced by a thermal-interdiffusion process using a double crucible is provided. The glass compositions comprises a glass composition for core containing 18 mol %<Li.sub.2 O.ltoreq.30 mol %, 0 mol %.ltoreq.Na.sub.2 O.ltoreq.12 mol %, 0 mol %.ltoreq.PbO.ltoreq.5 mol %, 8 mol %.ltoreq.MgO.ltoreq.18 mol %, 0.5 mol %.ltoreq.BaO.ltoreq.5 mol %, 1 mol %.ltoreq.TiO.sub.2 .ltoreq.10 mol %, and 40 mol %.ltoreq.SiO.sub.2 .ltoreq.65 mol % as major components, where 18 mol %<(Li.sub.2 O+Na.sub.2 O).ltoreq.30 mol %, 50 mol %.ltoreq.(SiO.sub.2 +TiO.sub.2).ltoreq.66 mol %, and 8 mol %.ltoreq.(MgO+PbO).ltoreq.22 mol %; and comprises a glass composition for cladding containing 18 mol %<R.sub.2 O.ltoreq.30 mol %(R.sub.2 O.dbd.Na.sub.2 O+K.sub.2 O), 0 mol %.ltoreq.PbO.ltoreq.5 mol %, 8 mol % .ltoreq.MgO.ltoreq.18 mol %, 0.5 mol %.ltoreq.BaO.ltoreq.5 mol %, 1 mol %.ltoreq.TiO.sub.2 .ltoreq.10 mol %, and 40 mol %.ltoreq.SiO.sub.2 .ltoreq.

Abstract: A vertically disposed apparatus used to make core-clad optical fibers inces an inner elongated cylinder removably closed at the top and provided at the bottom with an inner exit port of a smaller diameter than the inner cylinder and an outer cylinder, disposed around the inner cylinder, removably closed at the top and provided at the bottom with an outer exit port of a smaller diameter than the outer cylinder. The inner exit port is of a smaller diameter than the outer exit port and is disposed directly above the outer exit port. The apparatus also includes a heater for heating the inner and outer cylinders and acces to the inner and the outer cylinders for individually pressurizing inner and outer cylinders.

Abstract: A core/clad glass optical fiber is made by melting a core glass rod and a adding glass rod in separate crucibles which are not intersecting with respect to each other and the respective core and cladding glass melts passed out of contact with each other to a glass melt contacting zone proximate a fiber drawing orifice in which the cladding glass surrounds the core glass and a core/clad glass fiber is drawn. This process enables the clad glass fiber to be drawn directly from core and cladding glass rods without the need for a preform or forming a melt from glass chards or chunks, thereby reducing the cost of producing the fiber and also producing a glass clad optical fiber of high purity and excellent concentricity. Chalcogenide glass fibers having a concentricity of 100% have been made.

Abstract: A hollow high temperature ceramic superconducting fiber (10, 100), a process for making the hollow fibers and an apparatus for carrying out the process are provided. The apparatus functions to simultaneously draw a molten superconducting material (16) and a molten glass material (18) into a hollow preform (25) which is heat treated to form a hollow superconducting fiber (10, 100) which is flexible and has a high electrical current carrying capacity. The glass cladding layer (14, 14') surrounds the hollow superconducting core (12).

Abstract: A glass delivery system including a first forehearth having an orifice, a second forehearth having an orifice, a bottom pan assembly adapted to be positioned underneath the orifice of the first forehearth, and a glass delivery tube having an upper end adapted to be positioned underneath the orifice of the second forehearth and a lower end adapted to deliver glass to the bottom pan assembly. The orifice is adapted to combine the glass from the two forehearths and, deliver cased glass to provide an interior glass from said first forehearth and an external layer of glass from said second forehearth. Provision is made for moving the glass delivery tube horizontally, vertically and in azimuth relative to the second forehearth and for moving the bottom assembly relative to the first forehearth.

Abstract: The present invention is directed to the preparation of two groups of transparent glass-ceramics exhibiting high optical clarity and containing essentially only one crystal phase. The first group consists essentially, in cation percent, of______________________________________ SiO.sub.2 20-35 PbF.sub.2 19-23 AlO.sub.1.5 10-20 YF.sub.3 3-7, CdF.sub.2 19-34 ______________________________________and the second group consists essentially, in cation percent, of ______________________________________ SiO.sub.2 20-35 PbF.sub.2 15-25 AlO.sub.1.5 10-20 YF.sub.3 3-7 CdF.sub.2 21-31 ZnF.sub.2 3-7. ______________________________________These glass-ceramics may be used to fabricate optical waveguide fibers. Also when doped with certain rare earth elements, notably Pr, Er, and Dy, the glass-ceramic materials may be used to fabricate optical amplifiers and lasers.