Producing Or Treating Iron(fe) Or Iron Alloy Patents (Class 75/10.22)
  • Patent number: 10704121
    Abstract: A method of reducing metal oxides in a plasma arc torch comprising a cathode and an anode. The method comprises collecting a set of metallic oxide ore and filtering the set of ore based on a particle size. The method further comprises preprocessing the filtered ore with the application of a heat gradient or an electric current. The preprocessed ore is mixed with a composition of reduction gases. The mixture is injected into the plasma arc torch to form a post-plasma mixture. The method further comprises collecting the post-plasma mixture and analyzing the post-plasma mixture. The method also comprises separating the post-plasma mixture into a set of slag and a set of liquid.
    Type: Grant
    Filed: August 22, 2019
    Date of Patent: July 7, 2020
    Assignee: Capital One Services, LLC
    Inventors: David Wurmfeld, Kevin Osborn
  • Patent number: 10539043
    Abstract: A method of generating syngas as a primary product from renewable feedstock, fossil fuels, or hazardous waste with the use of a cupola. The cupola operates on inductive heat alone, chemically assisted heat, or plasma assisted heat. Cupola operation is augmented by employing carbon or graphite rods to carry electrical current into the metal bath that is influenced by the inductive element. The method includes the steps of providing a cupola for containing a metal bath; and operating an inductive element to react with the metal bath. A combination of fossil fuel, a hazardous waste, and a hazardous material is supplied to the cupola. A plasma torch operates on the metal bath directly, indirectly, or in a downdraft arrangement. Steam, air, oxygen enriched air, or oxygen are supplied to the metal bath. A pregassifier increases efficiency and a duct fired burner is added to a simple cycle turbine with fossil fuel augmentation.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: January 21, 2020
    Assignee: Plasma Tech Holdings, LLC
    Inventor: James Charles Juranitch
  • Patent number: 9212058
    Abstract: A method of producing hydrogen from hydro-carbon feed material is disclosed. A cylindrical plasma reaction region having a temperature greater than 800 C is created in a cylindrical reaction chamber by a cylindrical plasma array. The feed material is introduced into the plasma, where it undergoes plasma pyrolysis and is separated into hydrogen gas and solid carbon. The hydrogen gas is further purified using a hydrogen sieve that allows hydrogen through but retards larger molecules. The hydrogen gas is then feed into a fuel cell where it mixes with oxygen to provide electrical power. The plasma array may have one or more angled plasma arcs such that the plasma reaction region rotates as a vortex. There may also be two or more cylindrical plasma arrays arranged parallel to each other and to the cylindrical reaction chamber such that the feed material is fed through them.
    Type: Grant
    Filed: April 19, 2009
    Date of Patent: December 15, 2015
    Inventor: Christopher Lawrence de Graffenried, Sr.
  • Publication number: 20150040722
    Abstract: An iron production furnace equipment (1) has a melting reactor (2) into which iron oxide-containing raw material (4) and slag formers (5) are added. A melter arrangement (22) melts the iron oxide-containing raw material and transforms the melted raw material into liquid slag (6) A smelting reduction reactor (3) is connected to the melting reactor by a slag transfer arrangement (10). The smelting reduction reactor comprises a heater arrangement (30) for heating the slag. Means (32) for supplying a reductant (7) for reducing the iron oxide in the slag into a liquid iron melt (8) and for producing a combustible gas mixture (11) comprising at least one of CO and H2. A gas connection (12) is connected between the smelting reduction reactor and the melter arrangement. The melter arrangement in turn comprises a combuster (28) combusting the gas mixture. The combustion heat is used for purpose of melting.
    Type: Application
    Filed: February 7, 2013
    Publication date: February 12, 2015
    Inventors: Sven Santén, Matej Imris
  • Patent number: 8920532
    Abstract: The present invention describes an inoculation process for inoculating a nucleating additive to a cast iron alloy in a pouring distributor by means of using a transferred arc plasma torch, with an anode partially immersed in the cast iron alloy and a cathode located on the surface of said alloy, the anode or the cathode or both comprising graphite, preferably synthetic crystalline graphite, which supplies said nucleating additive to the iron alloy. The invention thus describes an inoculation device useful for carrying out the inoculation process.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: December 30, 2014
    Assignee: Fundacion Tecnalia Research & Innovation
    Inventors: Luis Cobos Jimenez, Francisco Rodríguez Vázquez, Jose Luis Oncala Avilés, Pedro Carnicer Alfonso
  • Publication number: 20140230605
    Abstract: A method of processing a metallic material includes introducing an electrically conductive metallic material comprising at least one of a metal and a metallic alloy into a furnace chamber maintained at a low pressure relative to atmospheric pressure. A first electron field having a first area of coverage is generated using at least a first ion plasma electron emitter, and the material within the furnace chamber is subjected to the first electron field to heat the material to a temperature above a melting temperature of the material. A second electron field having a second area of coverage smaller than the first area of coverage is generated using a second ion plasma electron emitter. At least one of any solid condensate within the furnace chamber, any solidified portions of the electrically conductive metallic material, and regions of a solidifying ingot to the second electron field, is subjected to the second electron field, using a steering system.
    Type: Application
    Filed: April 24, 2014
    Publication date: August 21, 2014
    Applicant: ATI PROPERTIES, INC.
    Inventor: Robin M. Forbes Jones
  • Patent number: 8764875
    Abstract: Combined microwave heating and plasma/electric arc heating is utilized in several processes and apparatus which involve co-production of pig iron and high quality syngas, biomass to liquid fuel production, coal to liquid fuel production, co-gasification of biomass and coal, municipal solid waste treatment, waste-to-energy (agriculture waste, ASR and PEF), EAF dust and BOF sludge treatment to recover zinc and iron, hazardous bottom ash vitrification, and bromine, chlorine and sulfur removal/recycling.
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: July 1, 2014
    Inventors: Xiaodi Huang, Jiann-Yang Hwang
  • Patent number: 8728195
    Abstract: Direct reduced iron (DRI) is obtained from iron ore by reduction using microwave assisted low temperature hydrogen plasma. The process includes steps of: (a) loading iron ore onto a sample holder (b) placing the sample holder inside a chamber followed by evacuating the chamber; (c) introducing hydrogen gas in the chamber at flow rate ranging between 100-500 standard cubic centimeters (sccm) followed by heating the sample holder and the iron ore at a temperature ranging between 300-800° C., a pressure ranging between 20-100 torr and a microwave power ranging between 500-1500 W to obtain direct reduced iron; and (d) cooling the direct reduced iron obtained in step (c) by flowing hydrogen at flow rate of about 300 sccm.
    Type: Grant
    Filed: August 13, 2012
    Date of Patent: May 20, 2014
    Assignee: Council of Scientific & Industrial Research
    Inventors: Bhagyadhar Bhoi, Barada Kanta Mishra, Raja Kishore Paramguru, Siddharth Kumar Pradhan, Partha Sarathi Mukherjee, Sambita Sahoo, Snigdha Priyadarshini, Priyanka Rajput, Subir Kumar Das
  • Patent number: 8610024
    Abstract: An exemplary embodiment providing one or more improvements includes a device and method for producing a lunar agglutinate simulant in which batch material is supported and moved through a plasma arc at a rate which partially reacts the batch material.
    Type: Grant
    Filed: February 5, 2008
    Date of Patent: December 17, 2013
    Assignees: Zybek Advanced Products, Inc., U.S. Geological Survey
    Inventors: Michael Weinstein, Stephen A. Wilson
  • Publication number: 20130047782
    Abstract: A green process for the preparation of direct reduced iron (DRI) from iron ore by reduction using microwave assisted low temperature hydrogen plasma, wherein the said process includes the steps of: loading of iron ore onto the sample holder followed by evacuating of the chamber; introducing the hydrogen gas in the chamber at flow rate ranging between 100-500 sccm followed by heating the holder and sample at temperature ranging between 300-800° C. and pressure ranging between 20-100 torr and at microwave power ranging between 500-1500 W to obtain direct reduced iron; and cooling the direct reduced iron as obtained in step (b) at temperature ranging between 300-800° C. by flowing hydrogen at flow rate of about 300 sccm.
    Type: Application
    Filed: August 13, 2012
    Publication date: February 28, 2013
    Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: BHAGYADHAR BHOI, Barada Kanta Mishra, Raja Kishore Paramguru, Siddharth Kumar Pradhan, Partha Sarathi Mukherjee, Sambita Sahoo, Snigdha Priyadarshini, Priyanka Rajput, Subir Kumar Das
  • Patent number: 8357223
    Abstract: This invention relates to a waste treatment furnace and method comprising: Generating a molten metal bed, which moves in a forward direction, such as to define a closed circuit in a cyclical and continuous manner, the surface of said bed comprising at least one essentially-slag-free segment. Loading waste onto the aforementioned essentially-slag-free segment, the waste being dragged by the molten metal bed such that it floats in the mentioned forward direction. Retaining the waste on the surface of the molten metal bed as it moves in the mentioned forward direction. Treating the waste under the effect of the constant and continuous heat exchange generated by the movement of the molten metal bed beneath the waste retained thereon.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: January 22, 2013
    Assignee: Fundacion Tecnalia Research and Innovation
    Inventor: Luis Cobos Jimenez
  • Publication number: 20120279349
    Abstract: The present invention describes an inoculation process for inoculating a nucleating additive to a cast iron alloy in a pouring distributor by means of using a transferred arc plasma torch, with an anode partially immersed in the cast iron alloy and a cathode located on the surface of said alloy, the anode or the cathode or both comprising graphite, preferably synthetic crystalline graphite, which supplies said nucleating additive to the iron alloy. The invention thus describes an inoculation device useful for carrying out the inoculation process.
    Type: Application
    Filed: November 25, 2009
    Publication date: November 8, 2012
    Inventors: Luis Cobos Jimenez, Francisco Rodríguez Vázquez, Jose Luis Oncala Avilés, Pedro Carnicer Alfonso
  • Patent number: 8137432
    Abstract: A method for smelting steel scrap in a furnace, including: blowing a working gas into the furnace via a flow channel to supply melting energy; guiding the working gas through at least one electrodeless plasma torch; producing a plasma by at least one inductive heating coil, which encloses the flow channel coaxially and forms a heating zone; and guiding a cooling gas through a radially outside region of the flow channel.
    Type: Grant
    Filed: June 8, 2007
    Date of Patent: March 20, 2012
    Assignee: Siemens Aktiengesellschaft
    Inventor: Thomas Matschullat
  • Publication number: 20120031232
    Abstract: Combined microwave heating and plasma/electric arc heating is utilized in several processes and apparatus which involve co-production of pig iron and high quality syngas, biomass to liquid fuel production, coal to liquid fuel production, co-gasification of biomass and coal, municipal solid waste treatment, waste-to-energy (agriculture waste, ASR and PEF), EAF dust and BOF sludge treatment to recover zinc and iron, hazardous bottom ash vitrification, and bromine, chlorine and sulfur removal/recycling.
    Type: Application
    Filed: August 3, 2011
    Publication date: February 9, 2012
    Inventors: Xiaodi Huang, Jiann-Yang Hwang
  • Patent number: 8029594
    Abstract: A method for introducing dust into a molten bath of a pyrometallurgical installation is described. According to the method, a carrier gas containing dust particles is guided through a heating zone of an electrode less plasma torch, the gas being converted to a plasma by inductive heating prior to being blown into a region of the installation which receives the molten bath.
    Type: Grant
    Filed: June 4, 2007
    Date of Patent: October 4, 2011
    Assignee: Siemens Aktiengesellschaft
    Inventors: Werner Hartmann, Günter Lins, Thomas Matschullat
  • Publication number: 20110167959
    Abstract: A method for introducing dust into a molten bath of a pyrometallurgical installation is described. According to the method, a carrier gas containing dust particles is guided through a heating zone of an electrode less plasma torch, the gas being converted to a plasma by inductive heating prior to being blown into a region of the installation which receives the molten bath.
    Type: Application
    Filed: June 4, 2007
    Publication date: July 14, 2011
    Inventors: Werner Hartmann, Günter Lins, Thomas Matschullat
  • Patent number: 7905941
    Abstract: This invention relates to a single-step pyrometallurgical process for the recovery of non-ferrous metals from zinc bearing residues, in particular from by-products of the zinc and lead industry such as goethite and jarosite. A process for the recovery of metals from industrial Zn residues containing Zn, Fe and S is defined, wherein Zn is fumed, Fe is slagged, and S is oxidized to SO2, characterized in that the Zn fuming, the Fe slagging, and the S oxidation are performed in a single step process, by smelting the residues in a furnace comprising at least one submerged plasma torch generating an oxidizing gas mixture, and by feeding a solid reducing agent to the melt. The process achieves the oxidation of S and the slagging of Fe, while simultaneously achieving the reduction and the fuming of metals such as Zn.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: March 15, 2011
    Assignee: Umicore
    Inventors: Maurits Van Camp, Peter Verguts
  • Patent number: 7888284
    Abstract: An absorbent includes a ferromagnetic nucleus with a one-layer or two-layer shell or devoid thereof and the nucleus is embodied in the form of a plate with a planar size that ranges from 500-5000 ?m and the thickness is equal to 0.1-1000 ?m. The method for producing the inventive magnetically-operated absorbent includes evaporating and/or melting a magnetic material powder in a low-temperature plasma, quenching and condensing the thus obtained vaporized and/or melt-particle product in a gas flux, and transferring the product precipitated in the form of crystals or micro slugs of corresponding metals, correspondingly to a stabilizer-containing dispersion medium and holding in the medium until a gas release is over. Then the crystals or micro slugs are processed by flattening, for example pressing so that the plates of a specified thickness are obtained.
    Type: Grant
    Filed: July 1, 2009
    Date of Patent: February 15, 2011
    Assignees: Evgeny Pavlovich Germanov, Mikhail Vladimirovich Kutushov
    Inventor: Mikhail Vladimirovich Kutushov
  • Patent number: 7815708
    Abstract: The invention relates to a process for the separation and recovery of non-ferrous metals from zinc-bearing residues, in particular from residues produced by the zinc manufacturing industry. The process comprises the steps of: —subjecting the residue to a flash or agitated bath fuming step, thereby producing an Fe bearing slag and Zn- and Pb-bearing fumes; and —extracting the Zn- and Pb-bearing fumes and valorising Zn and Pb; characterised in that CaO, SiO2 and MgO are added as a flux before or during the fuming step so as to obtain a final slag composition with: formula (I) all concentrations being expressed in wt %. The invention also relates to a single-chamber reactor for Zn-fuming equipped with one or more submerged plasma torches as heat and gas sources. [ Fe ] [ SiO 2 ] + [ CaO ] [ SiO 2 ] + [ MgO ] 3 > 3.5 ; 0.1 < [ CaO ] [ SiO 2 ] < 1.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: October 19, 2010
    Assignee: Umicore
    Inventors: Maurits Van Camp, Jonathan Aerts, Benedict Janssens, Sven Santen
  • Patent number: 6855183
    Abstract: The invention is a method for producing stainless steel using a generator, heating the vessel that is part of the generator, loading waste comprising steel into the heated vessel, melting the loaded waste to a molten state using a non-transferred torch to cut and melt the waste and then using a transferred torch to maintain a molten metal pool, adding additional steel to raise the molten metal pool to a minimum depth, raising the temperature to 2000 degrees Centigrade, acquiring EPA approval, loading waste into the vessel at a defined rate, maintaining the molten metal pool further melting any non-melted waste into a molten status with the transferred torch, determining BTU content and gas flow, injecting steam into the vessel, flowing gas from the vessel through scrubbers into storage containers and removing the stainless steel from the molten metal pool.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: February 15, 2005
    Inventor: Joseph Frank Pierce, Jr.
  • Patent number: 6689192
    Abstract: Method for producing metallic nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating non-oxidizing plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone to metal vapor. The metal vapor is directed away from the hot zone and to the plasma afterglow where it cools and condenses to form solid metallic nanoparticles.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: February 10, 2004
    Assignee: The Regents of the University of California
    Inventors: Jonathan Phillips, William L. Perry, William J. Kroenke
  • Publication number: 20030206822
    Abstract: High purity iron with a very few content of impurities such as copper, a method of manufacturing thereof, and high purity iron targets are provided. The iron containing impurities such as copper is dissolved in a hydrochloric acid solution, and the concentration of the hydrochloric acid of the aqueous solution of iron chloride is adjusted to 0.1 kmol/m3 to 6 kmol/m3. Then, iron is added in the aqueous solution of iron chloride, and an inert gas is injected into the solution with agitating, in order to convert the trivalent iron ions and divalent copper ions contained in the aqueous solution of iron chloride respectively to divalent iron ions and monovalent copper ions. Then, the aqueous solution of iron chloride is fed into a column filled up with the anion exchange resins. The divalent iron ions are not absorbed on the anion exchange resins although the monovalent copper ions are absorbed on the anion exchange resins. Therefore, copper can be separated from the aqueous solution of iron chloride.
    Type: Application
    Filed: May 28, 2003
    Publication date: November 6, 2003
    Inventors: Masahito Uchikoshi, Norio Yokoyama, Tamas Kekesi, Minoru Isshiki
  • Publication number: 20020117022
    Abstract: High purity iron with a very few content of impurities such as copper, a method of manufacturing thereof, and high purity iron targets are provided. The iron containing impurities such as copper is dissolved in a hydrochloric acid solution, and the concentration of the hydrochloric acid of the aqueous solution of iron chloride is adjusted to 0.1 kmol/m3 to 6 kmol/m3. Then, iron is added in the aqueous solution of iron chloride, and an inert gas is injected into the solution with agitating, in order to convert the trivalent iron ions and divalent copper ions contained in the aqueous solution of iron chloride respectively to divalent iron ions and monovalent copper ions. Then, the aqueous solution of iron chloride is fed into a column filled up with the anion exchange resins. The divalent iron ions are not absorbed on the anion exchange resins although the monovalent copper ions are absorbed on the anion exchange resins. Therefore, copper can be separated from the aqueous solution of iron chloride.
    Type: Application
    Filed: September 28, 2001
    Publication date: August 29, 2002
    Inventors: Masahito Uchikoshi, Norio Yokoyama, Tamas Kekesi, Minoru Isshiki
  • Patent number: 6391081
    Abstract: A metal purification method and a metal refinement method in which metals of high purity can be easily refined and recovered without increasing the size of the purification and refining devices or complicating the operation. To this end, metals containing impurities are molten in a plasma arc containing active hydrogen to remove the impurities. If the metals contain ceramics inclusions, the metals are molten in a plasma arc containing active hydrogen and the ceramics inclusions are caused to float over the molten metal by exploiting the difference of density between the molten metal and the ceramics inclusions. The floating ceramics inclusions are decomposed and removed. For application to refining, the metal oxides are molten in a plasma arc containing active hydrogen so as to be reduced to metals.
    Type: Grant
    Filed: March 23, 2000
    Date of Patent: May 21, 2002
    Assignee: Sony Corporation
    Inventors: Masahito Uchikoshi, Norio Yokoyama, Minoru Isshiki, Kouji Mimura
  • Patent number: 6306195
    Abstract: The present invention relates to an improved process for the preparation of high grade synthetic rutile from ilmenite with pig iron as a by-product. The process comprises subjecting ilmenite to reduction with coal, cooling and removing unreacted coal to obtain a product having 80-95% metallization, smelting the metallized ilmenite mixed with less than 10% carbon (w/w) in a transferred arc plasma using arc current, under flow of inert gas for a fixed time. The metal is then separated as pig iron and TiO2 as slag, the slag ground followed by oxidation at high temperature in the presence of an oxidizing gas, the oxidized product being leached with dilute HCl followed by filtration, washing and drying to obtain synthetic rutile.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: October 23, 2001
    Assignee: Council of Scientific and Industiral Research
    Inventors: Pawvathu Narayanan Nair Mohan Das, Karval Harikrishna Bhat, Melay Eriyat Kochu Janaki, Sreedharan Sasibhushanan, Parthasarathi Mukherjee, Bishnu Charan Rabindha Mohanty, Hem Shanker Ray
  • Patent number: 6221124
    Abstract: The invention concerns a method of treating electric arc furnace (EAF) dust. In the method the dust is preheated and decontaminated under conditions which oxidize the magnetite content of the dust to hematite. Thereafter the preheated and decontaminated dust is introduced into a fluidized bed reactor in which hematite is reduced, by means of a hot reducing gas generated by reforming natural gas in a non-catalytic plasma-arc heating process, to yield an iron-rich material suitable for recycling to the EAF, and a high grade zinc oxide product.
    Type: Grant
    Filed: November 16, 1998
    Date of Patent: April 24, 2001
    Assignee: L & C Steinmuller (Africa) (Proprietary) Limited
    Inventor: Peter William Ennis Blom