Reducing Or Smelting Slag Or Dross As Starting Material Patents (Class 75/10.35)
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Patent number: 12215395Abstract: Disclosed are processes for recycling chromium oxide and producing chromium-alloy steel. Chromium oxide is reduced to metallic chromium and metallic chromium is mixed with steel to form chromium-alloy steel.Type: GrantFiled: March 17, 2020Date of Patent: February 4, 2025Assignee: SAUDI IRON AND STEEL COMPANY (HADEED)Inventors: Mansour Nasser Alharbi, Sami Muteib Almutairi, Malleswara Rao Tadiboyina
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Patent number: 10435769Abstract: A method for refining sulfidic copper concentrate includes feeding sulfidic copper concentrate and oxygen-bearing reaction gas and slag forming material into a reaction shaft of a suspension smelting furnace, collecting slag and blister copper in a settler of the suspension smelting furnace to form a blister layer containing blister copper and a slag layer, and discharging slag and blister copper separately from the settler of the suspension smelting furnace, so that slag is fed into an electric furnace. The method further includes feeding a part of the sulfidic copper concentrate into the electric furnace.Type: GrantFiled: January 15, 2019Date of Patent: October 8, 2019Assignee: OUTOTEC (FINLAND) OYInventor: Akusti Jaatinen
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Patent number: 9625871Abstract: A toner container includes a second lever. A toner supply portion includes a second actuating portion that, during a process in which the toner container is attached to the toner supply portion, switches the second lever from a third position to a fourth position. The waste toner collecting portion includes a third actuating portion and a stopper member. The third actuating portion, during the toner container attachment process, acts on the second lever disposed at the third position and prohibits an attachment of the toner container, and acts on the second lever disposed at the fourth position and permits an attachment of the toner container. The stopper member is prohibits an attachment of the toner container in a state of having been attached to a first attachment position, and permits the attachment in a state of having been attached to a second attachment position.Type: GrantFiled: June 23, 2016Date of Patent: April 18, 2017Assignee: KYOCERA Document Solutions Inc.Inventor: Masaki Sato
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Patent number: 9512497Abstract: Disclosed herein is a method of reducing slag, including the steps of: examining the components of slag to be reduced, and setting a target composition ratio after reduction; determining the mixing ratio and input amount of a complex reducing agent of a plurality of reducing agents in accordance with the set target composition ratio to determine the complex reducing agent; and supplying the complex reducing agent into molten slag to reduce the slag. The method is advantageous in that the reduction efficiency of slag can be maximized, various kinds of reducing agents can be efficiently used, and the recovery amount of valuable metals can be increased, thus reducing cost.Type: GrantFiled: July 29, 2014Date of Patent: December 6, 2016Assignees: Hyundai Steel Company, Inha-Industry Partnership InstituteInventors: Joon-Seong Ki, Dong-Kyung Shin, Byung-Don You, Seong-Woong Joo, Seong-Hun Hong, Jin-Ill Hwang
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Publication number: 20150135896Abstract: The method of reduction processing of steel-making slag, includes: a hot steel-making slag inflow process of continuously or intermittently charging, from a slag supplying container, hot steel-making slag to a molten slag layer on a molten iron contained in an electric furnace while adjusting an amount of inflow with the slag supplying container; a reducing agent supplying process of supplying a reducing agent to the molten slag layer; an electrifying and heating process of heating the molten iron and the molten slag layer through application of electric power; and a reduction process of continuing reduction processing of the hot steel-making slag in a non-oxidizing atmosphere while intermittently discharging either one or both of the molten iron or molten slag of the molten slag layer.Type: ApplicationFiled: June 27, 2013Publication date: May 21, 2015Inventors: Toshiya Harada, Takashi Arai, Hiroshi Hirata
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Publication number: 20150122082Abstract: The invention relates to a method for processing slags of non-ferrous metallurgy, containing iron and valuable metals, to produce clean slag that is free of detrimental substances and valuable metals and suitable as it is for use as a raw material or construction material. Slag is reduced in a reduction furnace (18) with the help of reducing agents (19) so far that at least 5% of the iron of the slag is reduced into metal. At the same time, some of the valuable metals, such as zinc, lead, arsenic and cadmium, vaporize. The contents of the reduction furnace (18) are continuously mixed to prevent separation of a metallic phase from the slag. The generated slag-metal mixture (21) is tapped off from the reduction furnace (18), cooled, crushed and ground to a finer size. Finally, a metal fraction (26) is separated from a clean slag (25).Type: ApplicationFiled: April 15, 2013Publication date: May 7, 2015Inventors: Maija-Leena Metsarinta, Jussi Liipo, Pekka Kurki, Madeleine Scheidema
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Patent number: 8771396Abstract: A method for producing blister copper directly from copper concentrate is provided, comprising: a) adding copper concentrate, copper matte, slagging material, oxygen enriched air, endothermic material to an upper segment of the reaction furnace; b) adding reducing agent to the lower segment space of the reaction furnace; c) directing the produced hot coke and liquid slag into an electric furnace, and adding copper concentrate into the electric furnace to generate an electric furnace slag and copper matte; d) the copper matte being granulated and finely ground, then re-fed into the reaction furnace.Type: GrantFiled: November 14, 2012Date of Patent: July 8, 2014Assignee: Xiangguang Copper Co., Ltd.Inventors: Songlin Zhou, Weidong Liu, Zheling Ge
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Publication number: 20130269481Abstract: The present invention provides a method for producing blister copper directly from copper concentrate, comprising: a) adding copper concentrate, copper matte, slagging material, oxygen enriched air, endothermic material to a upper segment of the reaction furnace; b) adding reducing agent to the lower segment space of the reaction furnace; c) directing the produced hot coke and liquid slag into an electric furnace, and adding copper concentrate into the electric furnace to generate an electric furnace slag and copper matte; d) the copper matte being granulated and finely ground, then re-fed into the reaction furnace. The addition of reducing agent in the lower segment will not increase the heat load of the reaction furnace since the reducing agent does not burn.Type: ApplicationFiled: November 14, 2012Publication date: October 17, 2013Applicant: Xiangguang Copper Co., Ltd.Inventors: Songlin Zhou, Weidong Liu, Zheling Ge
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Publication number: 20130186236Abstract: A process and an apparatus are disclosed for improved recovery of metal from hot and cold dross, wherein a dross-treating furnace is provided with a filling material with capacity to store heat. This filling material is preheated to a desired temperature by injection of an oxidizing gas to burn non-recoverable metal remaining in the filling material after tapping of the recoverable metal contained in the dross and discharging of the treatment residue. When dross is treated in such furnace, the heat emanating by conduction from the filling material is sufficient to melt and separate the recoverable metal contained in the dross, without addition of an external heat source, such as fuel or gas burners, plasma torches or electric arcs and without use of any salt fluxes. Furthermore, the recovered metal being in the molten state can be fed to the molten metal holding furnace without cooling the melt.Type: ApplicationFiled: October 18, 2012Publication date: July 25, 2013Applicant: PYROGENESIS CANADA INC.Inventor: Pyrogenesis Canada Inc.
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Patent number: 8298317Abstract: A steelmaking process is disclosed. The process includes producing molten steel and molten steelmaking slag in a steelmaking process, the steelmaking slag including iron units and flux units, and thereafter producing molten iron in a molten bath based direct smelting process using a substantial portion of the steelmaking slag as part of the feed material requirements for the direct smelting process. A direct smelting process is also disclosed. The process includes pre-treating ferrous material including steelmaking slag and thereafter direct smelting molten iron using the pretreated ferrous material as part of the feed material for the process.Type: GrantFiled: April 7, 2011Date of Patent: October 30, 2012Assignee: Technological Resources Pty. LimitedInventors: Rodney James Dry, Robin John Batterham
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Patent number: 8157884Abstract: The invention concerns a method for the continuous or discontinuous extraction of a metal or several metals from a slag that contains the metal or a compound of the metal, in which the liquefied metal-containing slag is heated in a primary or secondary smelting unit (1). To provide an improved method for extracting metals, especially copper, from slags, the invention provides that the metal-containing slag is heated in a primary or secondary smelting unit (1) designed as an alternating-current electric furnace, and the molten material is then fed from the primary or secondary smelting unit (1) into a furnace (2) designed as a direct-current electric furnace, in which the metal to be extracted is subjected to an electrolytic separation, where a reducing agent in the form of calcium silicide (CaSi), calcium carbide (CaC2), ferrosilicon (FeO), aluminum (Al), and/or reducing gases is added and/or injected into the primary or secondary smelting unit (1).Type: GrantFiled: October 25, 2007Date of Patent: April 17, 2012Assignee: SMS Siemag AktiengesellschaftInventors: Rolf Degel, Jürgen Kunze
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Patent number: 8133295Abstract: A method for producing lead involves feeding lead concentrate, flux and solid fuel passing to a feed preparation unit. The prepared, mixed feed is then passed to a lead smelting furnace, such as an ISASMELT furnace or other top entry, submerged lance furnace. Air or oxygen, is injected into the molten charge in the ISASMELT furnace via the submerged lance. The feed mixture is converted into lead bullion and a lead-containing slag. The slag removed from the furnace is formed into lumps having a desirable size range. The slag lumps, together with coke and flux are fed into a blast furnace. In the blast furnace, the slag is converted into lead bullion and discard slag. The lead bullion removed may be subsequently fed to a lead refinery for further treatment.Type: GrantFiled: April 4, 2008Date of Patent: March 13, 2012Assignees: Yunnan Metallurgical Group, Xstrata Technology Pty LtdInventors: Philip Scott Arthur, William John Errington
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Publication number: 20110203413Abstract: A process for the treatment of loads or residues of non-ferrous metals and their alloys includes the steps of loading of scraps or dross to be processed and heating the load and melting the metal. The process additionally includes revolving the heated load, tapping the molten metal and emptying a cavity of the furnace. Heating of the load or residues to a temperature above the melting temperature of the metal or non-ferrous alloy to be recovered is carried out by means of a free burning convective arc which is independent from the supply of external gas to the process, and which may dispense with the use of melting salts.Type: ApplicationFiled: May 5, 2011Publication date: August 25, 2011Applicants: Fundacao de Amparo a Pesquisa do Estado de Sao Paulo - Fapesp, Instituto de Pesquisa Tecnologicas do Est. S. Paulo S/A - IPTInventors: Antônio Carlos da CRUZ, Oskar Wessel BENDER
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Patent number: 7955409Abstract: A method of smelting copper includes: a generating step of generating blister and slag from copper matte by charging the copper matte into a smelting furnace and oxidizing the copper matte; a first refining step of refining another blister from the slag by reduction in an electrical furnace; and a charging step of charging the slag into one of the smelting furnace or another smelting furnace for treating copper concentrate and generating matte as repeating flux if copper grade of slag generated in the first refining step is higher than 0.8 weight %.Type: GrantFiled: July 14, 2009Date of Patent: June 7, 2011Assignee: Pan Pacific Copper Co., Ltd.Inventors: Kenta Nakakado, Makoto Hamamoto, Seiichi Watanabe
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Patent number: 7935172Abstract: A steelmaking process is disclosed. The process includes producing molten steel and molten steelmaking slag in a steelmaking process, the steelmaking slag including iron units and flux units, and thereafter producing molten iron in a molten bath based direct smelting process using a substantial portion of the steelmaking slag as part of the feed material requirements for the direct smelting process. A direct smelting process is also disclosed. The process includes pre-treating ferrous material including steelmaking slag and thereafter direct smelting molten iron using the pretreated ferrous material as part of the feed material for the process.Type: GrantFiled: January 31, 2005Date of Patent: May 3, 2011Assignee: Technological Resources Pty LimitedInventors: Rodney James Dry, Robin John Batterham
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Patent number: 7918917Abstract: A method of smelting copper includes: a generating step of generating blister and calcium ferrite slag from copper matte by charging the copper matte into a smelting furnace and oxidizing the copper matte; and a refining step of refining another blister from the calcium ferrite slag in an electrical furnace under a temperature condition of 1250 degrees C. to 1350 degrees C. and under a reductive atmosphere condition of oxygen partial pressure logPO2??9.3.Type: GrantFiled: July 14, 2009Date of Patent: April 5, 2011Assignee: Pan Pacific Copper Co., Ltd.Inventors: Kenta Nakakado, Makoto Hamamoto, Seiichi Watanabe
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Publication number: 20100089202Abstract: During the production of stainless steel, a slag is formed during the melting of the solid material in the electric arc furnace, the slag having a high degree of metal oxides, particularly chromium oxide. The chromium concentration often reaches values of more than 30%. Currently, such slags cannot be reduced to a desired degree due to their composition. In order to minimize the resulting high loss of recyclable material, the invention provides to charge the electric arc furnace with pellets, or briquettes (8), which are made of a defined mixture of an iron carrier as the ballast material, carbon, or carbon and silicon, as the reducing agent, and a binder, wherein they react beneath the slag layer (7) in the steel melt (6) with the metal oxides of the slag (7), particularly with the chromium oxide present, in a floating, chemical, and reducing manner. The reaction gases (12) produced in the process, which are mainly made of carbon monoxide, advantageously support a foaming of the slag (7).Type: ApplicationFiled: January 10, 2008Publication date: April 15, 2010Applicant: SMS SIEMAG AKTIENGESELLSCHAFTInventors: Johann Reichel, Lutz Rose
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Publication number: 20090249919Abstract: The invention concerns a method for the continuous or discontinuous extraction of a metal or several metals from a slag that contains the metal or a compound of the metal, in which the liquefied metal-containing slag is heated in a primary or secondary smelting unit (1). To provide an improved method for extracting metals, especially copper, from slags, the invention provides that the metal-containing slag is heated in a primary or secondary smelting unit (1) designed as an alternating-current electric furnace, and the molten material is then fed from the primary or secondary smelting unit (1) into a furnace (2) designed as a direct-current electric furnace, in which the metal to be extracted is subjected to an electrolytic separation, where a reducing agent in the form of calcium silicide (CaSi), calcium carbide (CaC2), ferrosilicon (FeO), aluminum (Al), and/or reducing gases is added and/or injected into the primary or secondary smelting unit (1).Type: ApplicationFiled: October 25, 2007Publication date: October 8, 2009Inventors: Rolf Degel, Jürgen Kunze
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Patent number: 7597736Abstract: In a process for utilizing slag containing oxidic iron particles, adding a reducing agent and reducing oxidic iron particles of the slag are charging the slag into a reactor vessel onto a residual iron metal containing dissolved carbon, slowly and continuously over an extended period of time, electric heating the slag and the iron melt over an extended period of time, injecting a carbon-containing reducing agent with inert gas over an extended period of time by a lance into a region close to the boundary surface between the slag and the iron melt or directly into the iron melt, dissolving the carbon of the reducing agent in the iron melt and reducing oxidic iron particles of the slag with metallic iron and CO being formed, over an extended period of time, forming a foamed slag by the resulting CO over an extended period of time, introducing an oxygen-containing gas or oxygen into the foamed slag and postcombustion of CO to CO2 over an extended period of time, bottom flushing the reactor vessel with inert gasType: GrantFiled: November 16, 2005Date of Patent: October 6, 2009Assignee: Siemens Vai Metals Technologies GmbH & CoInventors: Alexander Fleischanderl, Udo Gennari
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Publication number: 20090211398Abstract: The invention is directed to a process for extracting a metal from a slag containing said metal, wherein the liquefied metal-containing slag is heated in at least one electric arc furnace (1, 2). In order provide an improved method for recovering especially copper from slags, the invention provides that the metal-containing slag is heated in a first furnace (1) constructed as an AC electric furnace or a DC electric furnace, and the melt is introduced from the first furnace (1) into a second furnace (2) which is constructed as a DC electric furnace. Further, the invention is directed to an arrangement for extracting a metal from a slag containing said metal.Type: ApplicationFiled: June 8, 2006Publication date: August 27, 2009Applicant: SMS DEMAG AGInventors: Juergen Kunze, Rolf Degel, Dieter Borgwardt, Andrzej Warczok, Gabriel Angel Riveros Urzua
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Publication number: 20080250900Abstract: A method for producing lead involves feeding lead concentrate, flux and solid fuel passing to a feed preparation unit. The prepared, mixed feed is then passed to a lead smelting furnace, such as an ISASMELT furnace or other top entry, submerged lance furnace. Air or oxygen, is injected into the molten charge in the ISASMELT furnace via the submerged lance. The feed mixture is converted into lead bullion and a lead-containing slag. The slag removed from the furnace is formed into lumps having a desirable size range. The slag lumps, together with coke and flux are fed into a blast furnace. In the blast furnace, the slag is converted into lead bullion and discard slag. The lead bullion removed may be subsequently fed to a lead refinery for further treatment.Type: ApplicationFiled: April 4, 2008Publication date: October 16, 2008Inventors: Philip Scott Arthur, William John Errington
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Publication number: 20080250899Abstract: The invention provides a method of processing a starting material in the form of a metal oxide-containing raw metallurgical slag to obtain a processed slag product. The method includes admixing the raw slag with a reductant to obtain a reaction mixture and heating the reaction mixture to cause the reductant to reduce the metal oxide in the slag, to obtain molten metal, in particular containing f erromanganese, and molten processed slag, in particular having a manganese content of at most 10% by mass. The method further includes separating the molten processed slag from the molten metal and causing or allowing the molten processed slag to solidify, thereby to obtain a solid processed slag product. This processed slag product may be, as desired, a filler for use in brick-making or for use in formulating a ready-mix concrete, an extender for extending a cement or for producing a blended cement, or an aggregate for use in the construction or building industry.Type: ApplicationFiled: August 28, 2006Publication date: October 16, 2008Inventor: Anton Mecchi
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Patent number: 7435281Abstract: A pyrometallurgic process for the treatment of post-steelwork residues, comprises the following phases: preparing a furnace (1) of the electric type, suitable for the introduction of the residues; preparing the residues, for example in a hopper with the possibility of mixing with additives and reaction elements; introducing the residues, together with suitable additives and chemical reagents, into the furnace (1); introducing directly into the slag, by means of lances (4), additives, flushing and reaction elements to correct the composition of the slag (7); reacting the residues with the slag (7) to obtain: a) separation of the liquid metallic phases which are added to the metal bath (6) to form a sellable liquid metal; b) separation of the metallic volatile elements in vapour phase which, when transferred to the free zone of the furnace (1) recombine with the oxygen for the formation of oxides and consequently of powder.Type: GrantFiled: February 10, 2005Date of Patent: October 14, 2008Assignee: Techint Compagnia Tecnica Internazionale S.p.A.Inventors: Marcello Pozzi, Carlo Raggio, Loredana Di Sante
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Publication number: 20080156144Abstract: The present invention relates to a method for reducing to metallic chromium the chromium oxide material found in slag formed in an electric arc furnace during the process of making stainless steel in that furnace. The chromium oxide content of the slag can be effectively reduced to a relatively low concentration by maintaining the slag in a liquid phase while at the same time blowing into the furnace via a carrier gas certain amounts of powdered aluminum dross. In particular, powdered aluminum dross can be blown into the furnace in amounts ranging from about 10 to 20 kg of dross per ton of molten steel in the furnace. Alternatively, powdered aluminum dross can be blown into the furnace in a thrown-in amount which satisfies the equation: 0.5?[Thrown-In Al dross (ton)×100]/[Slag in Furnace (ton)×Cr2O3 (wt %)]?1.0. Via such a method used during the stainless steel making process, the recovery of valuable chromium and the rate of chromium oxide reduction can be increased.Type: ApplicationFiled: December 26, 2007Publication date: July 3, 2008Applicant: POSCOInventors: Sang-Yuel JUNG, Yong Hwan KIM, Sun-Min BYUN, Sang-Beom LEE, Hyun-Chul CHUN
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Patent number: 7172640Abstract: In a method and a device for melting down metal-containing material, preferably fine-particulate metal-containing material, such as sponge iron, in a metallurgical melting furnace (1), wherein, in an interior space (11) of the melting furnace (1), a metal melt (5) and a slag layer (6) floating on top of the metal melt (5) are maintained, the metal-containing material is added by means of a supply means dipping into the slag layer (6) and energy is added in the form of electric arcs (14), the metal-containing material is charged directly into the central region (Z) of the melting furnace (1) by means of at least one charging tube (8) exclusively serving for conveying material via the charging tube outlet (9) of the same, the electric arcs (14) are directed obliquely towards the metal melt (5) against the central region (Z) of the melting furnace (1) and the metal-containing material is melted in the slag layer (6) and a mixed process slag-metal melt is maintained in the region of the charging tube outlet (9).Type: GrantFiled: October 22, 2001Date of Patent: February 6, 2007Assignee: Voest-Alpine Industrieanlagenbau GmbHInventors: Harald Berger, Peter Mittag, Bernhard Aigner
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Patent number: 6761749Abstract: The invention relates to a method of producing blister copper pyrometallurgically in a suspension reactor directly from its sulfidic concentrate. According to the method the copper sulfide concentrate is fed into a suspension reactor, into which cooled and finely ground copper matte is also fed in order to bind the heat released from the concentrate.Type: GrantFiled: September 30, 2002Date of Patent: July 13, 2004Assignee: Outokumpu OyjInventors: Jaakko Poijärvi, Tarmo Mäntymäki
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Publication number: 20040099091Abstract: The invention relates to a method for producing stainless steels, in particular steels containing chromium and chromium-nickel. The method is carried out in a melting device containing a metallurgical vessel, or in a melting device (1) containing at least two vessels (2, 3) for supplying a steel-casting installation, an electric arc furnace process (1) and an air-refining process taking place alternately in the two vessels (2, 3). To improve the efficiency of a method of this type, the aim of the invention is to carry out a reversible treatment of unreduced converter slag in the electric-arc furnace mode. To achieve this, in the first treatment stage, the slag (19) with a high chromium content is melted together with the added charge, the slag is then reduced during the melting process with the silicon and carbon under favourable thermodynamic conditions of the arc, once the slag has reached a minimum temperature of 1,490° C. and the slag is subsequently removed.Type: ApplicationFiled: July 21, 2003Publication date: May 27, 2004Inventors: Karl Reiner Gotzinger, Stefan Lembe, Johann Reichel, Bernt Rollinger
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Patent number: 6679931Abstract: A method for recovering metallic chromium from slags which contain chromium oxide from converter processes, such as AOD, MRP, AOD-L, MRP-L, CLU, ASM, Conarc stainless steel or vacuum processes, such as VOD, SS-VOD, RH, RH with lanze, includes drawing off the slag which is produced at the end of a blowing or treatment operation in a converter or a vacuum installation in unreduced form. The slag is charged into an electric furnace, which is also charged with a standard charge of scrap and, if appropriate, dust residues. Carbon and, if appropriate, silicon are additionally added to the electric furnace.Type: GrantFiled: April 9, 2002Date of Patent: January 20, 2004Assignee: SMS Demag AGInventors: Karl Götzinger, Jan Reichel
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Patent number: 6506225Abstract: In a steelmaking process in which, in order to desulfurize iron melts (4) using a strongly basic slag in a desulfurization vessel (7), the desulfurization slag (8) is brought to a temperature of from 1400-1800° C.Type: GrantFiled: November 28, 2000Date of Patent: January 14, 2003Assignee: Voest-Alpine Industrieanlagenbau GmbHInventor: Hermann Pirker
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Publication number: 20020083794Abstract: In a method and a device for melting down metal-containing material, preferably fine-particulate metal-containing material, such as sponge iron, in a metallurgical melting furnace (1), wherein, in an interior space (11) of the melting furnace (1), a metal melt (5) and a slag layer (6) floating on top of the metal melt (5) are maintained, the metal-containing material is added by means of a supply means dipping into the slag layer (6) and energy is added in the form of electric arcs (14), the metal-containing material is charged directly into the central region (Z) of the melting furnace (1) by means of at least one charging tube (8) exclusively serving for conveying material via the charging tube outlet (9) of the same, the electric arcs (14) are directed obliquely towards the metal melt (5) against the central region (Z) of the melting furnace (1) and the metal-containing material is melted in the slag layer (6) and a mixed process slag-metal melt is maintained in the region of the charging tube outlet (9).Type: ApplicationFiled: October 22, 2001Publication date: July 4, 2002Inventors: Harald Berger, Peter Mittag, Bernhard Aigner
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Patent number: 6409793Abstract: A method for processing steel slags and optionally iron carriers such as, e.g., electric furnace slags, converter slags, dusts derived from steel production, mill scale or secondary metallurgical residues, in which the molten steel slags or iron carriers are supplemented with chromium ores or chromium-containing and/or nickel-containing dusts in order to adjust a slag basicity of 1.2 to 1.6, whereby the bath temperature is maintained at above 1600° C., in particular between 1650° C. and 1800° C., and a carbon-containing iron bath is provided or formed. In addition to environmentally safe slags, a high-grade ferrochromium alloy may be recovered, thus enhancing the economy of the method.Type: GrantFiled: December 22, 2000Date of Patent: June 25, 2002Assignee: “Holderbank” Financiere Glarus AGInventor: Alfred Edlinger