Abstract: Disclosed is an incomplete extraction method for recycling batteries, which may include: introducing a pretreatment gas into a device loaded with a waste battery powder, and bringing a gas outlet into communication with absorption liquid A and absorption liquid B in order; raising the temperature and introducing the pretreatment gas; reducing the temperature and introducing a reaction gas; raising the temperature, introducing the reaction gas, and then introducing the pretreatment gas; and reducing the temperature, and turning off the pretreatment gas; adding an extractant to absorption liquid A, mixing the mixture, taking organic phase A, adding a stripping agent, and taking aqueous phase A; and adjusting the pH to acidity, then adding an extractant, taking organic phase B, adding a stripping agent to obtain a stock solution enriched in Li, Mn, Ni and Co.

Abstract: The invention relates to a method for producing a ferroalloy containing nickel. From a fine-grained raw material containing iron and chromium and a fine-grained raw material containing nickel, a mixture is formed with binding agent, the mixture is agglomerated so that first formed objects of desired size are obtained. The objects formed are heat treated in order to strengthen the objects so that the heat treated objects withstand conveyance and loading into a smelter furnace. Further, the objects are smelted under reducing circumstances in order to achieve ferrochromenickel, a ferroalloy of a desired composition containing at least iron, chromium and nickel.

Abstract: An improved method for treating manganese-containing materials, such as nodules recovered by undersea mining, including reacting the materials with ammonia, and leaching with a mineral acid, and to methods for recovering valuable constituents from such nodules, especially manganese, cobalt, nickel, iron, copper, titanium, vanadium, cerium, and molybdenum. A method for the production of nitrate products is also disclosed.

Abstract: The invention relates to a method for producing a ferroalloy containing nickel. From a fine-grained raw material containing iron and chromium and a fine-grained raw material containing nickel, a mixture is formed with binding agent, the mixture is agglomerated so that first formed objects of desired size are obtained. The objects formed are heat treated in order to strengthen the objects so that the heat treated objects withstand conveyance and loading into a smelter furnace. Further, the objects are smelted under reducing circumstances in order to achieve ferrochromenickel, a ferroalloy of a desired composition containing at least iron, chromium and nickel.

Abstract: Various embodiments provide a process roasting a metal bearing material under oxidizing conditions to produce an oxidized metal bearing material, roasting the oxidized metal bearing material under reducing conditions to produce a roasted metal bearing material, and leaching the roasted metal bearing material in a basic medium to yield a pregnant leach solution.

Abstract: A method of ironmaking using full-oxygen hydrogen-rich gas which includes hot transferring and hot charging the high-temperature coke, sinter and pellet into the ironmaking furnace through transferring and charging device, and injecting oxygen and hydrogen-rich combustible gas at a predetermined temperature into the ironmaking furnace through the oxygen tuyere and the gas tuyere disposed at the ironmaking furnace, respectively. It also provides an apparatus for ironmaking using full-oxygen hydrogen-rich gas which includes a raw material system, a furnace roof gas system, a coke oven gas injecting system, a dust injecting system, a slag dry-granulation and residual heat recovering system and an oxygen system. Additionally an apparatus and method for hot transferring and hot charging of ironmaking raw material is disclosed.

Abstract: A process and apparatus for refining iron from high-phosphorus content iron ores. The process involves mixing a high-phosphorus iron oxide ore and an alkaline solution of pH between about 12.5 and 13.5, screening the mixture by gravity to separate an alkaline-high-phosphorus solution from a low-phosphorus iron ore; and treating the low-phosphorus iron ore with lime and a natural gas.

Abstract: A process for the selective recovery of Mo, V, Ni, Co and Al from spent hydroprocessing catalysts includes the steps of treating the spent catalysts to recovery metals, support as well as chemicals. The process steps include deoiling, decoking, washing, dissolving, complexing agent treatment, acid treatment and solvent extraction. This process uses limited steps than conventional processes by the use of ultrasonic agitation for metal extraction and the presence of a chelating agent particularly Ethylene Diamine Tetra-Acetic Acid (EDTA). The process also discloses the compete recovery of the extracting agent EDTA with high purity for reuse.

Abstract: A method of reduction treatment of metal oxides characterized by using as a material a powder containing metal oxides and containing alkali metals and halogen elements and further, in accordance with need, carbon, mixing said material with water to produce a slurry, then dehydrating this and charging the dehydrated material, mixed with another material in accordance with need, into a rotary hearth type reduction furnace for reduction.

Abstract: A method of reduction treatment of metal oxides characterized by using as a material a powder containing metal oxides and containing alkali metals and halogen elements and further, in accordance with need, carbon, mixing said material with water to produce a slurry, then dehydrating this and charging the dehydrated material, mixed with another material in accordance with need, into a rotary hearth type reduction furnace for reduction.

Abstract: An improved method for processing of nickel-bearing ores, laterite ores, saprolite and limonite ores, oxidic and sulfide ores, metallurgical wastes, and other metal-bearing materials, to recover the valuable minerals contained therein, comprising comminuting ore to a desired size; leaching the ore at about 70 C to 130 C for about 30 minutes to 4 hours with nitric acid, raising the temperature of the solution to form a liquid/solid residue in which nickel, cobalt and magnesium values are in solution, and iron, manganese, and aluminum are solid residues in oxide form; conducting a liquid-solid separation and removing the solids; and recovering the nickel, cobalt, and manganese from the liquid-metal concentrate. The leachate is recovered and the nitric acid from the leachate is recycled.

Abstract: An ore containing crystal water (bond water) is heated to dehydrate the crystal water in the form of water vapor, thereby rendering the ore porous to generate a porous ore. Next, the porous ore is forced into contact with a dry-distilled gas (organic gas) obtained by dry-distillation of an organic substance such as wood and the like or an organic liquid such as tar and the like. An organic compound such as tar and the like contained in the dry-distilled gas or organic liquid adheres to the surface of the porous ore. Next, the porous ore adhered with an organic compound is heated at 500° C. or higher, to generate an ore in which a part of an oxide of an element such as iron and the like contained is reduced by carbon in the organic compound.

Abstract: A metallic article is produced by furnishing one or more nonmetallic precursor compound comprising the metallic base nickel, cobalt, iron, iron-nickel, or iron-nickel-cobalt, and at least one alloying element. The nonmetallic precursor compound(s) are chemically reduced to produce an initial metallic particle without melting the initial metallic particle. The initial metallic particle is thereafter melted and solidified to produce the metallic article. The melted-and-solidified metal may be used in the as-cast form, or it may be converted to billet and further worked to the final form.

Abstract: A process for producing a ferronickel product from a mixed nickel iron hydroxide product, said process including the steps of: providing a mixed nickel iron hydroxide product; pelletising the mixed nickel iron hydroxide product to produce nickel iron hydroxide pellets; calcining the nickel iron hydroxide pellets to produce mixed nickel iron oxide pellets; and reducing the nickel iron oxide pellets with one or more reducing gases at high temperatures to produce ferronickel pellets.

Abstract: The present invention relates to the recovery of base metals, in particular but not exclusively copper, via integrated hydrometallurgical and pyrometallurgical processing of base-metal sulphides, in particular but not exclusively iron-containing base-metal sulphides.

Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.

Abstract: A method for recovering catalytic metals from fluids containing catalytic metal colloids. Fluid compositions such as rinse solutions or dragout baths containing catalytic metal colloids are passed through a filter that entraps catalytic metal colloids on the filter. The catalytic metal colloids have a high affinity for the filter in contrast to other components of the fluids. The other components of the fluids pass through the filter while the catalytic colloids concentrate on the filter. The filter containing the catalytic metal colloids is burned, and the catalytic metal is retrieved. The method is economically efficient and environmentally friendly.

Abstract: A method for recovering catalytic metals from fluid compositions containing catalytic metal colloids. Fluid compositions such as aqueous rinse solutions or dragout baths containing catalytic metal colloids are passed through a porous metal filter that entraps the catalytic metal colloids. The catalytic metal colloids have a high affinity for the porous metal filter in contrast to other components of the fluids. The other components of the fluids pass through the porous metal filter while the catalytic metal colloids concentrate on the porous metal filter. The catalytic metal colloids that are captured on the porous metal filter are removed from the filter by backwashing the filter with a gas and/or a liquid. The backwashing forces the catalytic metal colloids off of the porous metal filter and through a solids discharge valve and into a solids collection container. The method is economically efficient with high catalytic metal recovery and is environmentally friendly.

Abstract: A method for cooling hot reduced iron briquettes at low cost without degrading the strength is provided. The method includes a primary cooling step of cooling the hot reduced iron briquettes by steam at a cooling rate of 4.0° C./s or less, a secondary cooling step of cooling the reduced iron briquettes by steam and sprayed water at a cooling rate of 4.0° C./s or less, and a final cooling step of cooling the reduced iron briquettes by sprayed water at a cooling rate of 3.5° C./s or more to a temperature in a final product temperature range. The steam generated by evaporation of sprayed water during the final cooling step is used in the primary and/or secondary cooling step.

Abstract: A method for treating steel works dust in order to recuperate elements capable of being upgraded. The method comprises attrition in water followed by hydraulic grading of the resulting load. The method is characterized in that is further comprises: a washing step to separate the water soluble saline fractions of the insoluble oxides; hot treatment to eliminate metals in the form of free oxides such as zinc and lead; treatment by heating at a temperature ranging between 240 and 800° C.; treatment with sulphuric acid having a concentration between 5 and 8%.

Abstract: A smelting process wherein very pure iron or various iron family metals are economically obtained from ores which contain iron family metals by hydrometallurgy. The process involves: (a) grinding an ore containing iron family metals to pulverize the ore into fines of 25 mesh undersize; (b) immersing the pulverized ore into at least one inorganic acid having a concentration of 1N to 8N to elute the iron family metals into the inorganic acid to carry out a leaching; (c) filtering the resultant mixture of residue and inorganic acid containing eluted iron family metals to obtain a filtrate and a gangue; (d) adding an alkali to the filtrate obtained in step (c), whereby a hydroxide of the iron family metal is precipitated; (e) filtering the resultant suspension which contains the hydroxide to collect the hydroxide of iron family metals; and (f) heating the collected hydroxide or a dried hydroxide thereof in a reducing atmosphere at a temperature of 400 to 500° C.

Abstract: The invention relates to a method for recovering non-ferrous metals, particularly nickel, cobalt, copper, zinc, manganese and magnesium, from materials containing said metals by converting said non-ferrous metals into sulphates by means of melt and melt coating sulphation, i.e. by a thermal treatment under oxidizing conditions within a temperature range of 400 to 800° C., during which a reaction mixture is formed containing at least one said non-ferrous metal, iron(III)sulphate and alkali metal sulphate, and appropriate reaction conditions are selected to substantially prevent iron(III)sulphate from thermally decomposing to hematite, and finally, said non-ferrous metals are recovered as metallic compounds. In the method of the invention, a process is formed around the melt and melt coating sulphation, which comprises nine steps.

Abstract: Besides a synthesis gas, a metallurgical raw material is to be produced from an oil containing heavy metals. To do this, the oil is partially oxidized and the heavy metal-containing soot is separated and burnt and the heavy metals thus occurring as ash can be taken to further processing, e.g. washing from the synthesis gas produced, using an aqueous washing solution.

Abstract: The present invention relates to cobalt metal agglomerates consisting of peanut-shaped primary particles with average particle sizes in the range from 0.5 to 2 .mu.m, to a process for the production thereof and to the use thereof.

Abstract: The present invention relates to cobalt metal agglomerates consisting of peanut-shaped primary particles, to a process for the production thereof and to the use thereof.

Abstract: The present invention relates to a process for preparing cobalt metals by reducing cobalt oxides with ammonia or nitrogen/hydrogen gas mixtures. In accordance with the present invention, a cobalt metal is economically prepared by reacting a cobalt oxide with a nitrogen reductant at a temperature of 300 to 550.degree. C. for 3 to 7 hours, where the nitrogen reductant is injected into a reactor containing the cobalt oxide at a flow rate of 300 to 700 cc/min, preferably 500 cc/min per 1 g of cobalt oxide, while continuously elevating the temperature of the reactor at a rate of 3 to 7.degree. C./min, most preferably 5.degree. C./min.

Abstract: A method for producing direct reduced iron or/and pig iron from an industrial waste materials stream such as EAF and blast furnace dust generally comprising the steps of separating the materials contained in the waste materials stream by magnetic separation or flotation, briquetting the iron-containing materials separated during the separation process with carbon, and providing the briquettes to a reduction furnace or/and to a small scale blast furnace or cupola furnace to produce direct reduced iron or/and pig iron, respectively. The exhaust streams from the process are further treated to recover chemical values and to allow the recycle of the exhaust streams to the main process.

Abstract: The present invention relates to a method for upgrading silicon-containing solid residues obtained after leaching of copper from copper-containing residues from direct synthesis of organochlorosilanes. Solid residue, optionally together with an oxidation agent, is supplied to a smelting furnace where the residues are melted and form a molten metallic phase substantially containing silicon and a calcium silicate slag and tapping of the molten metallic phase and an inert slag from the smelting furnace.

Abstract: An integrated process for the treatment of spent catalysts containing mainly molybdenum, vanadium, nickel, cobalt and, alumina to produce ammonium metavanadate, vanadium pentoxide, molybdic trioxide, fused alumina and a high grade nickel/cobalt alloy essentially free of aluminum.

Abstract: A process for producing a high purity cobalt is provided comprising the following steps. An aqueous solution of cobalt chloride having a hydrochloric acid concentration of 7 to 12N is provided. The solution includes either or both of Fe and Ni as impurities. The solution is contacted with an anion exchange resin so that cobalt is adsorbed on the resin. Cobalt is eluted from the resin with hydrochloric acid at a concentration of 1 to 6N. The solution containing the eluted cobalt is dried or otherwise concentrated to produce a purified aqueous solution of cobalt chloride having a pH of 0 to 6. Organic materials are preferably removed from the purified solution by active carbon treatment. Electrolytic refining is conducted with the purified aqueous solution as an electrolyte to obtain electrodeposited cobalt. A high purity cobalt sputtering target can be obtained wherein Na content is 0.05 ppm or less; K content is 0.

Abstract: A method for the production of an iron-based feedstock suitable for use as the feedstock for steel mills, from industrial waste streams containing iron, by combining an iron poor material such as exhaust fumes from metals production processes with the waste streams, treating the combined waste stream with an ammonium chloride leaching solution, separating the undissolved precipitates comprising iron compounds from the leachant solution, and further treating the undissolved precipitants by elevated temperature roasting, resulting in the iron-based feedstocks.

Abstract: A method by which numerous gas generators from unused air-bags can be scrapped in an environmentally acceptable manner. The method consists ofa) heating the gas generator to actuate the generator to produce combustion gases and an actuated generator having water soluble contaminants thereon;b) washing the actuated generator with a water composition to remove the contaminants from the actuated generator to produce a washed generator and a contaminated water composition containing the contaminants;c) dividing the washed generator to produce divided generator parts;d) chemically treating the contaminated water composition to produce a purified water composition; ande) classifying the divided generator parts into classified generator parts.Optionally, the dividing step can occur before the washing step, or before and after the washing step. The classified generator parts and purified water can be disposed of in an environmentally acceptable manner.

Abstract: A method for the production of an enriched iron product, specifically direct reduced iron and iron oxide suitable for use as the feedstock for steel mills, from industrial waste streams containing iron, by combining an iron oxide rich material such as mill scale and/or used batteries with the waste streams, treating the combined waste stream with an ammonium chloride leaching solution, separating the undissolved precipitates comprising iron compounds from the leachant solution, and further treating the undissolved precipitants by elevated temperature roasting, resulting in the iron feedstocks.

Abstract: A method is provided for recovering nickel from high magnesium-containing lateritic ores which also contain iron. The ores which are referred to as saprolitic ores are subjected to leaching with a mineral acid from the group consisting of HCl, H.sub.2 SO.sub.4 and HNO.sub.3, HCl being preferred.Following leaching with HCl, for example, the pregnant solution obtained is separated from undissolved solids and the nickel preferably recovered by contacting the solution with a resin selective to nickel absorption. The raffinate remaining which contains iron and magnesium chlorides may be subjected to pyro-hydrolysis to produce their respective oxides and free HCl for recycle into the leaching system. The nickel is extracted from the resin using a stripping solution of said acid, and the nickel thereafter extracted from the nickel-loaded stripping solution.

Abstract: For purification of liquids used for cooling and/or lubrication interspersed with metallic and/or other materials contaminations, especially for separation of rolling scale and of substances containing oil or grease from the industrial process water in open or exposed cooling circulation cycles in the smelting industry, especially in rolling mills, it is proposed to separate the coarse rolling scale by gravity sedimentation from the contaminated process water, to subsequently remove the mid-size and fine rolling scale particles from the process water prepurified in this manner by magnetic separation, to divide by flotation the thus finished clarified or purified process water into fractions containing oil concentrate, water and the finest rolling scale particles carrying little oil, the purified process water is to be used as a cooling agent, the entire rolling scale separated out of the process water is smelted in the form of sinter and the concentrate containing oil is either rejected or subjected to a wast

Abstract: The invention relates to a method for fully beneficating nickel sulfide concentrates or other corresponding mixtures, unsuitable for smelting, by combining the use of both pyrometallurgical and hydrometallurgical processes, so that there are formed two separate concentrates, the first of which is suited to pyrometallurgical and the second to hydrometallurgical treatment. In the concentrate going to pyrometallurgical processing, the valuable metal content increases as a consequence of the treatment, and the Fe/MgO ratio of this concentrate is at least 2.6.

Abstract: Steelworks dusts or sludge is mixed into sewage preferably in the presence of a flocculating agent to provide a rapid separation of a clear effluent and a sludge which is dewatered and dried to form a solid material adapted to entrap harmful materials in the sewage such as heavy metals, pathogens and organic chemicals. The solid material is supplied to a smelt reduction furnace from which molten iron is recovered and a hot gas discharge is provided from which recovery of zinc and other materials may be achieved, other waste material being removed as a slag.

Abstract: The present invention relates to methods of recycling metal containing electrical components to recover one or more metal values therefrom by comminuting the used metal containing electrical component, preferably in an inert environment, separating water soluble and insoluble materials and recovering metal or metal compounds from at least one of these materials.

Abstract: A method for the extraction of valuable minerals and precious metals from oil sands ore bodies or other related ore bodies that is synergistically unique in the arrangement of processes for production of valuable minerals and precious metals in an economically and environmentally acceptable manner. The oil sands ores from oil sands ore bodies and other related ores from other related ore bodies including overburden and interburden mineral ores are crushed, the hydrocarbons, if any exists in worthwhile quantities, are recovered and the resulting coarse sands, other related ores and fines streams are processed in a definite sequence using known processes to recover the valuable minerals and precious metals values. All reactants and reagents, including water, are recycled in the method and tailings ponds are not required. Heat recovery is used extensively to cogenerate almost all of the process steam and process electrical requirements for the method.

Abstract: The process is described for treating the sludge formed in a phosphate conversion bath, and in particular, in zinc phosphate conversion baths to convert the sludge into useful chemical materials thereby eliminating the need for disposal to landfill. The process comprises the steps of(A) recovering the solid by-products from the used phosphating solution;(B) treating the solid by-products with an aqueous base at a pH of greater than 10 to form a first aqueous phase and a metal-containing precipitate;(C) recovering the metal-containing precipitate from the first aqueous phase as a first product of the process;(D) acidifying the first aqueous phase obtained in (C) to a from about 7 to about 10 to form a second aqueous phase and an insoluble metal-containing precipitate;(E) recovering the solid metal-containing precipitate from the second aqueous phase as a second product of the process; and(F) recovering the second aqueous phase as a third product of the invention.

Abstract: A method of processing an aqueous feed liquid to precipitate at least one metal (e.g., copper, nickel or a combination thereof) in a form to make the metal subsequently removable from the feed liquid by filtration, comprises the initial step of mixing (i) an aqueous feed liquid containing a soluble salt of the metal to be removed, (ii) oxalic acid in excess of that required to react with metal, and (iii) a pH-adjusting liquid in a quantity sufficient to lower the pH of the feed liquid to a point between that at which the feed liquid becomes slightly supersaturated with respect to the oxalate of the metal and that at which precipitation of the metal oxalate is initiated. The mixture is then allowed to stand (either at room temperature or heated to elevated temperatures) for a period of time sufficient to form metal oxalate, and finally the formed metal oxalate is separated from the feed liquid to leave an aqueous liquid suitable for discharge to a sewer line.