With Concurrent Production Of Titanium Dioxide Patents (Class 75/435)
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Patent number: 10570041Abstract: Method for treating iron-contaminated water using a treatment approach identified herein as the Activated Iron Solids (AIS) Process. The AIS process is capable of oxidizing and removing iron as iron oxides from iron-contaminated waters producing a clean effluent. The AIS process is performed in a single or multiple tank system in which high concentrations of AIS are suspended through mechanical mixing to maintain a catalytic surface chemistry environment that increases iron removal thousands times faster than would naturally occur and hundreds times faster than existing arts (e.g., aerobic pond passive treatment). The AIS process can utilize inexpensive alkaline material (such as, pulverized limestone) where initial mine drainage alkalinity (mg/L as CaCO3) to ferrous iron (mg/L) ratio is less than approximately 1.7.Type: GrantFiled: August 19, 2013Date of Patent: February 25, 2020Inventor: Jonathan M. Dietz
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Patent number: 10543491Abstract: The invention discloses a multi-stage suspension magnetizing roasting-magnetic separation system and method for refractory iron ore, which belongs to the field of mineral processing technology. This system comprises multistage suspension preheater, multistage suspension oxidizer, multistage suspension redactor, on-line grade analyzer, ore-like splitter, magnetic separator, dust remover, roots blower and other components and connection modes. The refractory iron ore treated by the present method can be produced to homogeneous magnetite or maghemite accurately, and through magnetic separation, on-line grade analyzer detection and ore-like splitter, the concentrate powder which reach the set grade can be obtained, and the unqualified ore powder enters the next stage of oxidation-reduction-magnetic separation-split treatment.Type: GrantFiled: May 29, 2018Date of Patent: January 28, 2020Assignee: Northeastern UniversityInventors: Yuexin Han, Yanjun Li, Shuai Yuan, Peng Gao, Yongsheng Sun, Wenbo Li
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Patent number: 8834600Abstract: The present invention relates to a zero-waste process for extraction of alumina from different types of bauxite ores and red mud residues and of titanium dioxide from ilmenite. Iron oxide is first reduced to metallic iron above the melting point of C-saturated cast iron alloy which yields a high-C iron alloy and an Al and Ti metal oxide rich slag which is then treated with alkali carbonate to form alkali aluminates and titanates. The alkali aluminates are separated by water leaching from which the hydroxide of alumina is precipitated by bubbling C02. The residue from water leaching is treated with sulphuric acid and Ti02 is precipitated via a hydrolysis route. The process recovers most of the metal values and generates only small quantities of silicious residues at pH 4-5 which can be used for soil conditioning.Type: GrantFiled: June 11, 2004Date of Patent: September 16, 2014Assignee: The University of LeedsInventors: Animesh Jha, Pailo Antony Malpan, Vilas Dattatray Tathavadkar
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Patent number: 8545593Abstract: A method for producing liquid ferroalloy by direct processing of manganese and chromium bearing iron compounds, by the steps: of mixing carbonaceous reductant, fluxing agent, and a binder with materials such as iron sands, metallic oxides, manganese-iron ore concentrates and/or chromium-iron ore concentrates and silica sands, to form a mixture; forming agglomerates from the mixture; feeding the agglomerates to a melting furnace with other materials; melting the feed materials at a temperature of from 1500 to 1760° C. and forming a slag and hot metal; removing the slag; tapping the hot metal as liquid ferroalloy, and utilizing the off-gases from the melting furnace as combustion fuel to drive a turbine and to generate electricity.Type: GrantFiled: October 24, 2011Date of Patent: October 1, 2013Assignee: Cardero Resource CorporationInventor: Glenn E. Hoffman
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Patent number: 8372179Abstract: The present invention is one or more processes for producing separable iron and titanium oxides from an ore comprising titanium oxide and iron oxide, comprising: (a) forming agglomerates comprising carbon-based material and the ore, the quantity of carbon of the agglomerates being at least sufficient for forming a ferrous oxide-containing molten slag, at an elevated temperature; (b) introducing the agglomerates onto a bed of carbon-based material in a moving hearth furnace, wherein the carbon-based materials used for both the agglomerates and the bed have a low sulfur content; (c) heating the agglomerates in the moving hearth furnace to a temperature sufficient for liquefying the agglomerates to produce a liquid comprising ferrous oxide-containing slag; (d) metallizing the ferrous oxide of the slag by reaction of the ferrous oxide and the carbon of the carbon bed at a furnace temperature sufficient for maintaining the slag in a liquid state; (e) solidifying the slag after metallization of the ferrous oxide toType: GrantFiled: October 14, 2008Date of Patent: February 12, 2013Assignee: E I du Pont de Nemours and CompanyInventors: John James Barnes, Stephen Erwin Lyke, Dat Nguyen, Joseph M. Shekiro, Jr., Guangliang Liu
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Patent number: 7780756Abstract: The disclosure is directed to a process for producing separable iron and titanium oxides from an ore containing titanium oxide and ferric oxide, comprising: (a) forming agglomerates comprising carbon-based materials and the ore, the quantity of carbon of the agglomerates being sufficient for, at an elevated temperature, reducing ferric oxide to ferrous oxide and forming a ferrous oxide-rich molten slag, (b) introducing the agglomerates onto a carbon bed of a moving hearth furnace; (c) heating the agglomerates in the moving hearth furnace to a temperature sufficient for reducing and melting the agglomerates to produce a ferrous oxide-rich molten slag; (d) metallizing the ferrous oxide of the molten slag by reaction of the ferrous oxide and the carbon of the carbon bed at a furnace temperature sufficient for maintaining the slag in a molten state; and (e) solidifying the slag after metallization of the ferrous oxide to form a matrix of titanium oxide-rich slag having a plurality of metallic iron granules distriType: GrantFiled: April 27, 2009Date of Patent: August 24, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: John James Barnes, Stephen Erwin Lyke, Dat Nguyen, Akira Uragami, Isao Kobayashi, Mitsutaka Hino, Thomas Peter Battle, Joseph M. Shekiro, Jr.
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Publication number: 20100126310Abstract: A method for producing pig iron by direct processing of ferrotitania sands, by the steps of: (a) mixing carbonaceous reductant, a fluxing agent, and a binder with titanium-containing materials selected from iron sands, metallic oxides, and/or iron ore concentrates, to form a mixture; (b) forming agglomerates from the mixture (c) introducing the agglomerates to a melting furnace; (d) melting the agglomerates at a temperature of from 1500 to 1760 C and forming hot metal with a slag thereon; (e) removing the slag; (f) tapping the hot metal; and (g) recovering the titanium and vanadium values.Type: ApplicationFiled: August 12, 2008Publication date: May 27, 2010Inventor: Glenn E. Hoffman
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Patent number: 7341658Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.Type: GrantFiled: April 17, 2003Date of Patent: March 11, 2008Assignee: Tatanium Corporation Inc.Inventor: Robert G. Reeves
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Publication number: 20070251352Abstract: The present invention is a bacteria and nutrient delivery composition containing bran. The subject composition is preferably made in the form of a tablet that is structurally stable without being excessively hard. The tablets preferably have a configuration that reduces the likelihood of premature shearing in tableting presses or jamming in feeder devices for biomass generators. Methods of manufacturing the bacterial delivery composition in a structurally stable form that maintains bacterial viability are also provided.Type: ApplicationFiled: October 17, 2006Publication date: November 1, 2007Inventors: Judith G. Pruitt, Robert Clarence Pearce, John Ray Roheim
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Patent number: 6685761Abstract: The invention is a method and apparatus for producing beneficiated titanium oxides using a modified rotary hearth furnace, that is a finisher-hearth-melter (FHM) furnace. In the method the refractory surface of the hearth is coated with carbonaceous hearth conditioners and refractory compounds, where onto said hearth is charged with pre-reduced agglomerates. The pre-reduced agglomerates is leveled, then heated until molten, and then reacted with the carbon and reducing gas burner gases until any residual iron oxide is converted to iron having a low sulfur content. Fluid slag and molted iron forms melted agglomerates. The fluid slag is rich in titanium. The melted agglomerates are cooled, and then the melted agglomerates and the hearth conditioners, including the refractory compounds, are discharged onto a screen, which separate the melted agglomerates from the hearth conditioner.Type: GrantFiled: March 19, 2003Date of Patent: February 3, 2004Assignee: Midrex International B.V. Rotterdam, Zurich BranchInventors: Glenn E. Hoffman, Ronald D. Gray
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Patent number: 6306195Abstract: The present invention relates to an improved process for the preparation of high grade synthetic rutile from ilmenite with pig iron as a by-product. The process comprises subjecting ilmenite to reduction with coal, cooling and removing unreacted coal to obtain a product having 80-95% metallization, smelting the metallized ilmenite mixed with less than 10% carbon (w/w) in a transferred arc plasma using arc current, under flow of inert gas for a fixed time. The metal is then separated as pig iron and TiO2 as slag, the slag ground followed by oxidation at high temperature in the presence of an oxidizing gas, the oxidized product being leached with dilute HCl followed by filtration, washing and drying to obtain synthetic rutile.Type: GrantFiled: March 24, 2000Date of Patent: October 23, 2001Assignee: Council of Scientific and Industiral ResearchInventors: Pawvathu Narayanan Nair Mohan Das, Karval Harikrishna Bhat, Melay Eriyat Kochu Janaki, Sreedharan Sasibhushanan, Parthasarathi Mukherjee, Bishnu Charan Rabindha Mohanty, Hem Shanker Ray
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Patent number: 6030430Abstract: Described herein is an Improved Converter System designed to help reduce air, land and water pollution by completely converting materials that presently cause pollution into clean burning fuels and a host of other products beneficial to mankind. The primary conversion unit in the system is a zone controlled multipurpose slagging-ash oxygen jet blast converter. All incoming materials are passed through this process computer aided talented offspring of its two ancient prototypes the blast furnace and slagging-ash gas producers and the zone controlled blast furnaces described in U.S. Pat. Nos. 4,381,938, 4,495,054, 3,928,023 and 3,814,404. It employs two sets of tuyeres located in the bosh to input endothermic reacting gases, vapors and dusts through tuyere sets T1 and T2. A 100% oxygen jet blast is also input through tuyere set T2.Type: GrantFiled: July 24, 1998Date of Patent: February 29, 2000Assignees: Material Conversions, Inc., Improved Converters Inc.Inventors: H. Bruce Claflin, John Jasbinsek
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Patent number: 5997606Abstract: A process for producing titanium slag which is low in radioactivity wherein molten titanium slag, produced by smelting ilmenite in the presence of a reductant in a DC electric arc furnace, is separated from molten iron, boron in an amount which is less than 2.5% equivalent B.sub.2 O.sub.3 of the slag is blended with the molten slag which thereafter is allowed to cool to form a glassy phase which contains the bulk of the radioactive elements of the slag before being crushed to particles below about 1 mm, whereafter the radioactive elements are leached to leave a titanium slag product which is low in radioactivity.Type: GrantFiled: August 6, 1998Date of Patent: December 7, 1999Assignee: Billiton SA LimitedInventors: Jacobus Cornelius Gideon Kotze Van Der Colf, Johannes Nell, Frances Stander
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Patent number: 5900040Abstract: A method and apparatus of introducing one or more reagents into a rotary and/or elongate kiln in which titaniferous material is being treated eg upgraded wherein the reagent(s) is introduced (I) at a plurality of locations along the length of the kiln and/or (II) at or adjacent to a discharge end of the kiln. The reagents may comprise one or more of chlorine-containing compounds, sulphur, sulphur-containing compounds, magnesium compounds, manganese compounds, fluxes and glass-forming reagents, including a borate salt or mineral. The reagent may be mixed with the discharge end coal or introduced separately.Type: GrantFiled: September 10, 1996Date of Patent: May 4, 1999Assignee: RGC Mineral Sands LimitedInventors: Harold Robert Harris, Ian Edward Grey
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Patent number: 5885324Abstract: Synthetic Rutile is prepared from raw ilmenite ore by a method comprising activating ilmenite and subjecting it to a multi-stage countercurrent leaching process in hot hydrochloric acid.Type: GrantFiled: August 30, 1996Date of Patent: March 23, 1999Assignee: Tiomin Resources, Inc.Inventors: Graham F.. Balderson, Charles A. MacDonald
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Patent number: 5853452Abstract: Hot metal is circulated by an R-H unit in a closed loop path through first and second hearths and chambers. Titaniferous material containing iron oxide is introduced into the first hearth and the iron oxide therein is reduced in a heating zone in the first hearth to iron to produce titania slag having a reduced iron content which is removed in chamber before the hot metal passes via an underflow weir into chamber at which coal is added and a proportion of hot metal is removed. The addition of coal is such that more than 2% by weight of carbon dissolves in the hot metal in the second hearth. Coal ash slag is removed at chamber, while the hot metal containing the dissolved carbon is recirculated to the first hearth.Type: GrantFiled: February 19, 1997Date of Patent: December 29, 1998Assignee: The University of BirminghamInventor: Noel A. Warner
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Patent number: 5730774Abstract: A process for removing impurities from a titaniferous material that has been subjected to thermal reduction and which includes a titaniferous phase of general formula M.sub.3 O.sub.5. The thermally reduced titaniferous material is subjected to a secondary heat treatment to covert the M.sub.3 O.sub.5 phase to a more readily leachable M.sub.2 O.sub.3 phase. This material is then cooled and leached in an aqueous acid solution containing hydrochloric acid or sulfuric acid, and the leachate is separated from the titaniferous material to form a purified titaniferous material.Type: GrantFiled: April 1, 1996Date of Patent: March 24, 1998Assignee: Technological Resources PTY Ltd.Inventors: Michael John Hollitt, Ross Alexander McClelland
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Patent number: 5679131Abstract: A method for producing titanium dioxide from an iron-containing titanium ore concentrate includes heating the ore concentrate in the presence of a reducing agent to provide a sintered reaction product including a titanium salt of the alkali metal and metallic iron. The titanium salt of the alkali metal is decomposed by addition of water to provide titanium dioxide. For ilmenite (FeTiO.sub.3), preferred alkali metal salts include carbonates, and formates of sodium and potassium. The titanium metal salt so formed is sodium or potassium meta titanate (K.sub.2 TiO.sub.3 or Na.sub.2 TiO.sub.3) depending on the alkali metal used. Suitable reducing agents include hydrogen, methane, carbon monoxide, or solid carbon. Metallic iron may be magnetically separated from ground reaction product or from a slurry formed by addition of water to the reaction product, the slurry including the titanium dioxide.Type: GrantFiled: March 13, 1996Date of Patent: October 21, 1997Assignee: Photran CorporationInventor: Ivan M. Obushenko
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Patent number: 5601630Abstract: A process for removal of iron from reduced titanium ores involves hydrometallurgical treatment with an aqueous solution through which an oxidising gas including oxygen and/or ozone is passed to oxidise metallised iron present within said reduced titanium ore.Type: GrantFiled: February 22, 1994Date of Patent: February 11, 1997Assignee: The Commonweath Industrial Gases LimitedInventor: Walter Hoecker
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Patent number: 5387276Abstract: A method of removal of valuable minerals of oil sand tailings including continuous operation of mixing said tailings with acid, curing the agglomeration and leaching of the cured agglomeration for removal of valuable minerals.Type: GrantFiled: December 10, 1993Date of Patent: February 7, 1995Assignee: Solv-Ex CorporationInventor: John S. Rendall
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Patent number: 5124008Abstract: A method for the extraction of valuable minerals and precious metals from oil sands ore bodies or other related ore bodies that is synergistically unique in the arrangement of processes for production of valuable minerals and precious metals in an economically and environmentally acceptable manner. The oil sands ores from oil sands ore bodies and other related ores from other related ore bodies including overburden and interburden mineral ores are crushed, the hydrocarbons, if any exists in worthwhile quantities, are recovered and the resulting coarse sands, other related ores and fines streams are processed in a definite sequence using known processes to recover the valuable minerals and precious metals values. All reactants and reagents, including water, are recycled in the method and tailings ponds are not required. Heat recovery is used extensively to cogenerate almost all of the process steam and process electrical requirements for the method.Type: GrantFiled: June 22, 1990Date of Patent: June 23, 1992Assignee: Solv-Ex CorporationInventors: John S. Rendall, Valentine W. Vaughn, Jr.
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Patent number: 5063032Abstract: Synthetic rutile is prepared from titaniferous slags containing alkaline-earth metal impurities, such as magnesium oxide, by a method comprising contacting the slag with chlorine at a temperature of at least about 800.degree. C., and then leaching the chlorine-treated slag with hydrochloric acid at a temperature of at least about 140.degree. C.Type: GrantFiled: March 27, 1990Date of Patent: November 5, 1991Assignee: QIT-Fer et Titane, Inc.Inventor: Michel Gueguin