With Concurrent Production Of Iron(fe) And Other Desired Nonmetallic Product (e.g., Energy, Fertilizer, Etc.) Patents (Class 75/958)
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Patent number: 11479830Abstract: A method for treating converter slag for the purpose of recirculating iron, wherein a converter slag is brought into contact with oxygen in such a way that by means of turbulence, the slag is mixed, the iron and iron oxide components that are present are oxidized, and the slag is then allowed to stand in the vessel or a vessel until a segregation into a solidifying, silicate and phosphorus-rich first fraction and an underlying liquid iron oxide-rich second fraction has taken place, with the converter slag that is used being mixed with a partial flow from the iron oxide-rich second fraction in such a way that the total FeO content of the slag that is to be treated with oxygen is over 35% by weight, thus enabling the segregation into two fractions.Type: GrantFiled: August 24, 2018Date of Patent: October 25, 2022Assignee: voestalpine Stahl GmbHInventor: Herbert Schmid
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Patent number: 8551213Abstract: A system of coal gasification and direct ironmaking attains both heat recovery in a coal-based direct ironmaking process and a reduction in equipment investment in a coal gasification process. A waste heat boiler in the system recovers heat of gas exhausted from a coal gasification furnace. A heater in exhaust gas lines of a heat reduction furnace in the coal-based direct ironmaking process superheats the steam generated by and exhausted from the waste heat boiler. A superheated steam line supplies the steam superheated by the heater as an oxidant to the coal gasification furnace.Type: GrantFiled: September 25, 2009Date of Patent: October 8, 2013Assignee: Kobe Steel, Ltd.Inventors: Masataka Tateishi, Masahiro Motoyuki
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Patent number: 8545593Abstract: A method for producing liquid ferroalloy by direct processing of manganese and chromium bearing iron compounds, by the steps: of mixing carbonaceous reductant, fluxing agent, and a binder with materials such as iron sands, metallic oxides, manganese-iron ore concentrates and/or chromium-iron ore concentrates and silica sands, to form a mixture; forming agglomerates from the mixture; feeding the agglomerates to a melting furnace with other materials; melting the feed materials at a temperature of from 1500 to 1760° C. and forming a slag and hot metal; removing the slag; tapping the hot metal as liquid ferroalloy, and utilizing the off-gases from the melting furnace as combustion fuel to drive a turbine and to generate electricity.Type: GrantFiled: October 24, 2011Date of Patent: October 1, 2013Assignee: Cardero Resource CorporationInventor: Glenn E. Hoffman
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Patent number: 8506672Abstract: A system of coal gasification and direct ironmaking attains both heat recovery in a coal-based direct ironmaking process and a reduction in equipment investment in a coal gasification process. A waste heat boiler in the system recovers heat of gas exhausted from a coal gasification furnace. A heater in exhaust gas lines of a heat reduction furnace in the coal-based direct ironmaking process superheats the steam generated by and exhausted from the waste heat boiler. A superheated steam line supplies the steam superheated by the heater as an oxidant to the coal gasification furnace.Type: GrantFiled: September 25, 2009Date of Patent: August 13, 2013Assignee: Kobe Steel, Ltd.Inventors: Masataka Tateishi, Masahiro Motoyuki
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Patent number: 7341658Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.Type: GrantFiled: April 17, 2003Date of Patent: March 11, 2008Assignee: Tatanium Corporation Inc.Inventor: Robert G. Reeves
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Patent number: 6692549Abstract: The present invention generally relates to processes and apparatuses for the integration of a blast furnace and an air separation plant to increase blast furnace production. The present invention recovers energy from the air separation through the expansion of a product stream.Type: GrantFiled: December 19, 2001Date of Patent: February 17, 2004Assignee: Air Liquide Process and Construction, Inc.Inventors: Bao Ha, Jean-Renaud Brugerolle
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Publication number: 20030192405Abstract: The invention relates to a steelmaking thermal energy recovery system. The steelmaking thermal energy recovery system comprises a steelmaking waste flue gas, a calcinable material, and a kiln. The steelmaking waste flue gas provides at least a portion of the thermal energy to the kiln for calcination of the calcinable material.Type: ApplicationFiled: April 15, 2002Publication date: October 16, 2003Inventor: Willard K. McClintock
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Patent number: 6592646Abstract: In a method of producing direct reduced iron with use of a coal-derived gas, coal is heated to lower the moisture thereof, and the moisture-lowered coal is gasified in a coal gasification furnace to produce a coal-derived gas containing a reducing gas. The reducing gas is then utilized to reduce iron ore in an iron ore reducing furnace. With use of an exhaust gas from the iron ore reducing furnace, the coal is heated in the step of heating coal.Type: GrantFiled: October 3, 2001Date of Patent: July 15, 2003Assignees: Kabushiki Kaisha Kobe Seiko Sho, Babcock-Hitachi Kabushiki KaishaInventors: Takuo Shigehisa, Jinichi Tomuro, Eiichiro Makino
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Patent number: 6572674Abstract: Steel work gases (blast-furnace gases, coke-oven gases, converter gases, etc.) are burnt with an exhaust gas from a gas turbine, optionally with a supply of natural gas and of air, in a postcombustion section between the outlet of the gas turbine and the inlet of a recovery boiler, the steam from which is utilized especially for producing electrical energy.Type: GrantFiled: February 7, 2000Date of Patent: June 3, 2003Assignee: L'Air Liquide - Société Anonyme á Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Pascal Avart, Jérôme Girard, Geneviève Mure, Emmanuel Pousset
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Patent number: 6475264Abstract: A process for direct smelting a metalliferous feed material is disclosed. The process includes the steps of partially reducing metalliferous feed material and substantially devolatilising coal in a pre-reduction vessel and producing a partially reduced metalliferous feed material and char. The process also includes direct smelting the partially reduced metalliferous feed material to molten metal in a direct smelting vessel using the char as a source of energy and as a reductant and post-combusting reaction gas produced in the direct smelting process with pre-heated air or oxygen-enriched air to a post-combustion level of greater than 70% to generate heat required for the direct smelting reactions and to maintain the metal in a molten state.Type: GrantFiled: March 21, 2000Date of Patent: November 5, 2002Assignee: Technological Resources Pty LtdInventor: Rodney James Dry
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Patent number: 6379422Abstract: A process for direct smelting metalliferous feed material is disclosed. Iron oxides are partially reduced in a solid state in a pre-reduction vessel. The partially reduced iron oxides are smelted to molten iron in a direct smelting vessel which contains a molten bath of iron and slag and is supplied with a solid carbonaceous material as a source of reductant and energy and with an oxygen-containing gas for post-combusting carbon monoxide and hydrogen generated in the vessel. The direct smelting step generates an off-gas that contains sulphur and the off-gas is released from the direct smelting vessel. Part only of the off-gas released from the direct smelting vessel is used in the pre-reduction step to pre-reduce iron oxides in the pre-reduction vessel. Part only of the off-gas is used in the pre-reduction step in order to control the amount of sulphur that is returned with the partially reduced iron oxides to the direct smelting vessel.Type: GrantFiled: August 4, 2000Date of Patent: April 30, 2002Assignee: Technological Resources Pty. Ltd.Inventor: Rodney James Dry
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Patent number: 6361757Abstract: This invention provides a catalyst for producing hydrogen gas from a mixed gas comprising dimethyl ether and water vapor or carbon dioxide gas, which comprises copper, iron, cobalt, palladium, iridium, platinum, rhodium, or nickel as an active component, and a method of producing synthesis gas or hydrogen gas in a high yield at a low temperature. By using the catalyst, a fuel cell, electricity generation, reduction of iron ore and the like can be carried out.Type: GrantFiled: June 4, 1999Date of Patent: March 26, 2002Assignee: NKK CorporationInventors: Tsutomu Shikada, Yotaro Ohno, Norio Inoue, Masatsugu Mizuguchi, Keiji Tomura, Takeshi Furukawa, Takuya Kadowaki, Sadayoshi Iwabuchi, Takashi Ogawa, Masami Ono, Kaoru Fujimoto
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Patent number: 6306195Abstract: The present invention relates to an improved process for the preparation of high grade synthetic rutile from ilmenite with pig iron as a by-product. The process comprises subjecting ilmenite to reduction with coal, cooling and removing unreacted coal to obtain a product having 80-95% metallization, smelting the metallized ilmenite mixed with less than 10% carbon (w/w) in a transferred arc plasma using arc current, under flow of inert gas for a fixed time. The metal is then separated as pig iron and TiO2 as slag, the slag ground followed by oxidation at high temperature in the presence of an oxidizing gas, the oxidized product being leached with dilute HCl followed by filtration, washing and drying to obtain synthetic rutile.Type: GrantFiled: March 24, 2000Date of Patent: October 23, 2001Assignee: Council of Scientific and Industiral ResearchInventors: Pawvathu Narayanan Nair Mohan Das, Karval Harikrishna Bhat, Melay Eriyat Kochu Janaki, Sreedharan Sasibhushanan, Parthasarathi Mukherjee, Bishnu Charan Rabindha Mohanty, Hem Shanker Ray
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Patent number: 6251160Abstract: In a process for dechroming, and/or depleting the MgO content of, steel slags, oxygen is introduced into the liquid steel slag to an extent sufficient for converting iron quantitatively to iron oxide and at least 5% by weight of the iron oxide contained in the slag to iron-III-oxide. The oxidized slag obtained solidifies and is disintegrated, whereupon the paramagnetic portions formed are magnetically isolated and separated from the dechromed slag.Type: GrantFiled: April 23, 1999Date of Patent: June 26, 2001Assignee: “Holderbank” Financiere Glarus AGInventor: Alfred Edlinger
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Patent number: 6152984Abstract: A system for producing directly reduced iron integrated with a turbine power generator and preferably a cryogenic air separation plant wherein off-gas from the direct reduction drives the turbine and preferably oxygen from the air separation plant is used to generate synthesis gas for the direct reduction and nitrogen from the air separation plant dampens NOx generation and augments power generation in the turbine.Type: GrantFiled: September 10, 1998Date of Patent: November 28, 2000Assignee: Praxair Technology, Inc.Inventor: Raymond Francis Drnevich
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Patent number: 6068677Abstract: The method for processing waste or waste fractions, such as, for example, household refuse, car shredder light fractions or the like, provides for pyrolysis, gasification and/or combustion, whereupon the residues are melted under reducing conditions. The reduced portions are then are subjected to a stepwise oxidation, with chromium being quantitatively separated in a first oxidation stage. After this, a calcium ferrite slag is formed by further oxidation, whereupon the remaining metal bath is further processed in order to recover nonferrous heavy metals.Type: GrantFiled: August 5, 1997Date of Patent: May 30, 2000Assignee: "Holderbank" Financiere Glarus AGInventor: Alfred Edlinger
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Patent number: 6053961Abstract: Method and apparatus for smelting iron ore in which iron ore is preheated and partly reduced within a first reaction zone and then further reduced in a second reaction zone. The first reaction zone can be a shaft reduction furnace and the second reaction zone can be a melter gasifier. An auxiliary third reaction zone partially oxidizes a carbonaceous material to produce char for the third reaction zone. A reducing gas produced by partial oxidation of the char is used to effect the partial reduction conducted within the first reaction zone. Volatile substances contained within a heating gas produced by the partial oxidation within the auxiliary third reaction zone is further oxidized and used to preheat the iron ore within the first reaction zone.Type: GrantFiled: March 17, 1998Date of Patent: April 25, 2000Assignee: The BOC Group, Inc.Inventor: Donald Prentice Satchell, Jr.
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Patent number: 6051048Abstract: A first, solid, carbon-containing fuel is gasified and iron is melted in a gasifier-melter. A first flow of resulting fuel gas is employed to form the iron in a vertical shaft furnace by direct reduction of iron ore. A second flow of resulting fuel gas is mixed with fuel gas produced by separately gasifying a second carbon-containing fuel in a second gasifier, in which no iron is melted and which supplies essentially no carbonaceous solid fuel to the first gasification stage. This mixing helps to dampen fluctuations in the flow rate of the second flow of the resulting fuel gas.Type: GrantFiled: June 17, 1998Date of Patent: April 18, 2000Assignee: The BOC Group plcInventor: Brian Anthony Keenan
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Patent number: 6033456Abstract: The present invention relates to an integrated process and apparatus for supplying at least a portion of, or substantially all, or all of the reducing gas feedstock to a reduction reactor, such as a reactor for the direct reduction of iron, wherein the reducing gas contacts a feed material at a mean operating gas pressure and effects reduction of the feed material to provide a reduced product. The integrated process includes the production of a hydrogen-rich gas by the partial oxidation of a hydrocarbonaceous feedstock to produce a hydrogen-rich gas, which can also be referred to as a synthesis gas or syngas. The synthesis gas is at a pressure substantially greater than the mean operating gas pressure in the reduction reactor. The synthesis gas is expanded to lower its pressure to substantially the mean operating gas pressure in the DRI reduction reactor to thereby form the reducing gas feedstock at the pressure conditions used for the DRI reaction.Type: GrantFiled: February 6, 1998Date of Patent: March 7, 2000Assignee: Texaco Inc.Inventor: Frederick C. Jahnke
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Patent number: 6030430Abstract: Described herein is an Improved Converter System designed to help reduce air, land and water pollution by completely converting materials that presently cause pollution into clean burning fuels and a host of other products beneficial to mankind. The primary conversion unit in the system is a zone controlled multipurpose slagging-ash oxygen jet blast converter. All incoming materials are passed through this process computer aided talented offspring of its two ancient prototypes the blast furnace and slagging-ash gas producers and the zone controlled blast furnaces described in U.S. Pat. Nos. 4,381,938, 4,495,054, 3,928,023 and 3,814,404. It employs two sets of tuyeres located in the bosh to input endothermic reacting gases, vapors and dusts through tuyere sets T1 and T2. A 100% oxygen jet blast is also input through tuyere set T2.Type: GrantFiled: July 24, 1998Date of Patent: February 29, 2000Assignees: Material Conversions, Inc., Improved Converters Inc.Inventors: H. Bruce Claflin, John Jasbinsek
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Patent number: 5653182Abstract: Method for neutralizing waste, such as powder from luminescent tubes and similarly, residue from incineration of household waste, optionally comprising environmentally hazardous components, such as Hg, Cd, Zn, Co or Ba. The waste is fed into a melting furnace in conjunction with an SiO.sub.Type: GrantFiled: December 28, 1995Date of Patent: August 5, 1997Assignee: HAS Holding ASInventor: Arvid Inge Sorvik
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Patent number: 5643354Abstract: A direct ironmaking process in which coal and oxygen are used directly for reducing ore and smelting the resulting sponge iron wherein a high-temperature ion transport membrane process recovers oxygen for use in the ironmaking process. Heat for oxygen recovery is provided by combustion of medium-BTU fuel gas generated by the ironmaking process and/or by heat exchange with hot gas provided by the ironmaking process. The ironmaking and oxygen recovery processes can be integrated with a combined cycle power generation system to provide an efficient method for the production of iron, oxygen, and electric power.Type: GrantFiled: April 6, 1995Date of Patent: July 1, 1997Assignee: Air Products and Chemicals, Inc.Inventors: Rakesh Agrawal, Michael Shi-Kuan Chen, Arthur Ramsden Smith, Robert Michael Thorogood, Thomas Joseph Ward
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Patent number: 5630862Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising petroleum coke and the sulfur and heavy metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier having an upper fuel charging end, a reduction gas discharging end, a lower molten metal and slag collection end, and means providing an entry for charging ferrous material into the melter gasifier; introducing a carbonaceous fuel including petroleum coke into the melter gasifier at the upper fuel charging end; blowing oxygen-containing gas into the petroleum coke to form at least a first fluidized bed of coke particles from the petroleum coke; introducing ferrous material into the melter gasifier through the entry means, reacting petroleum coke, oxygen and particulate ferrous material to combust the major portion of the petroleum coke to produce reduction gas and molten iron or steel preproducts containing heavy metals freedType: GrantFiled: June 15, 1995Date of Patent: May 20, 1997Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 5613997Abstract: Method and apparatus for performing a metallurgical process in which a carbonaceous material is converted to a reducing gas and a metal is melted in a main reactor, particulate coal is partially oxidized in a secondary reactor to form a particulate char and a calorific gas under conditions which minimize the formation of carbon monoxide, and at least part of the char and some of the calorific gas are introduced into the main reactor.Type: GrantFiled: September 18, 1995Date of Patent: March 25, 1997Assignee: The BOC Group plcInventor: Donald P. Satchell, Jr.
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Patent number: 5529599Abstract: A method for the co-production of fuel and iron from coal and from iron ore respectively, which is comprised of heating the coal in the absence of oxygen to make a raw coal gas and a residual coke, and of increasing the content of free hydrogen in the coal gas through the cracking against a desulfurizing hot reagent, of the hydrocarbons contained in the gas in order to yield a hydrogen rich, desulfurized, hot reducing synthetic gas. This synthetic gas which is highly reactive, is fed through a bed of iron ore in order to directly reduce the ore to metallized iron. The off-gas exiting from the bed of ore is divided into three parts:-a first part is mixed with the raw coal gas, and is recycled for further use; a second part is used to provide the thermal energy required for the heating of the coal to make the raw gas and the coke; and a third part which is purged to maintain the process in balance, is utilized for other thermal needs.Type: GrantFiled: November 8, 1995Date of Patent: June 25, 1996Inventor: Albert Calderon
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Patent number: 5496392Abstract: The present invention relates to a process for the production of metal alloys, metal oxides and slag-based products, such as mineral wool, from industrial waste materials. More specifically, the present invention relates to a process for recycling industrial waste materials into valuable commercial products, including, pure metals, metal alloys, metal oxides, and a molten slag comprising non-reducible metal oxides which thereafter can be converted to vitreous fiber and shot. Industrial waste materials suitable for use in the present invention include metal-containing waste products, particularly inorganic hazardous waste materials. The present process accomplishes total recycling in such a manner that the entire industrial waste material is consumed and converted to useful products.Type: GrantFiled: March 29, 1994Date of Patent: March 5, 1996Assignee: EnviroscienceInventors: Bobby H. Sims, Carl T. Philipp
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Patent number: 5464464Abstract: A method for reducing particulate iron oxide and/or other iron units to molten iron utilizing gaseous hydrogen as reductant in a reducing furnace, in which the ore freely falls during the melting and reduction process. Reacted top gas is purified and recirculated through the reduction furnace, establishing a counter-flow relationship to the particulate iron oxide, thereby heating and reducing the oxide. The heat for reduction is generated by combusting a fraction of the hydrogen reductant with oxygen. Heat may also be supplied via the use of electric arc heating. Oxygen may be partially or wholly replaced with water in order to maintain reaction oxidizer ratios while reducing heat supplied to the reaction.Type: GrantFiled: June 10, 1994Date of Patent: November 7, 1995Assignee: Borealis Technical Incorporated LimitedInventor: Jonathan Edelson
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Patent number: 5431710Abstract: A fine particle mixture of iron concentrate and pulverized flux is introduced into the upper portion of the vertical prereduction section of a sealed unitary vessel. Heated gas partially reduces the iron concentrate particles to form wustite which falls to the lower portion where it is melted to form fluid slag. The slag passes into the horizontal section of the vessel which is divided by a barrier into a reduction portion and an oxidation portion. In the reduction portion, pulverized coal and oxygen are introduced and iron oxide in the slag is reduced to iron. The entrained iron droplets in the slag are permitted to sediment in a quiescent zone where the slag is removed. The molten iron may be recovered or converted into steel by flowing through passages in the lower portion of the barrier into the oxidation portion where oxygen is introduced to remove C, Si, P and other impurities and to convert iron into steel or semi-steel. The final product and slag are separately removed from the oxidation portion.Type: GrantFiled: April 14, 1993Date of Patent: July 11, 1995Inventor: Li W. Ebenfelt
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Patent number: 5397376Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising petroleum coke and the sulfur and heavy metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier having an upper fuel charging end, a reduction gas discharging end, a lower molten metal and slag collection end, and means providing an entry for charging ferrous material into the melter gasifier; introducing petroleum coke into the melter gasifier at the upper fuel charging end; blowing oxygen-containing gas into the petroleum coke to form at least a first fluidized bed of coke particles from the petroleum coke; introducing ferrous material into the melter gasifier through the entry means, reacting petroleum coke, oxygen and particulate ferrous material to combust the major portion of the petroleum coke to produce reduction gas and molten iron or steel preproducts containing heavy metals freed from combustion of the petroleType: GrantFiled: June 30, 1993Date of Patent: March 14, 1995Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 5380352Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising rubber tires and the sulfur and metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier. The metals freed from combustion of the rubber tires is contained in the molten iron and sulfur freed from combustion of the rubber tires is contained in the slag.Type: GrantFiled: May 18, 1993Date of Patent: January 10, 1995Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 5364447Abstract: A smelting process for blending hazardous and non-hazardous inorganic industrial wastes with carbon or aluminum reducing agents to simultaneously recover metal alloys (reducible metals), metal oxides (volatile reducible metals), carbon dioxide and man-made vitreous fiber (non reducible metals). Wastes including hazardous wastes of U.S. EPA Series D, F, P, K, and U are pulverized and blended with liquids such as water or waste water to produce a homogeneous mass. The mass is formed into briquettes and melted in a cupola or plasma arc furnace in the presence of carbon or aluminum to reduce metals. Other types of furnaces such as an electric arc furnace may be used to avoid the steps of forming and curing briquettes. Reduction is carried out at temperatures between 1660 and 3100 degrees Fahrenheit. Calcium flux from calcium-stabilized wastes enhances mineral wool quality, lowers the sulfur content of metals and raises pH to facilitate metal reduction. Reducible metals are reduced and drawn off into molds.Type: GrantFiled: March 29, 1993Date of Patent: November 15, 1994Assignee: Enviroscience, Inc.Inventors: Carl T. Philipp, Bobby H. Sims
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Patent number: 5354356Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising petroleum coke and the sulfur and heavy metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier having an upper fuel charging end, a reduction gas discharging end, a lower molten metal and slag collection end, and means providing an entry for charging ferrous material into the melter gasifier; introducing petroleum coke into the melter gasifier at the upper fuel charging end; blowing oxygen-containing gas into the petroleum coke to form at least a first fluidized bed of coke particles from the petroleum coke; introducing ferrous material into the melter gasifier through the entry means, reacting petroleum coke, oxygen and particulate ferrous material to combust the major portion of the petroleum coke to produce reduction gas and molten iron or steel preproducts containing heavy metals freed from combustion of the petroleType: GrantFiled: December 17, 1992Date of Patent: October 11, 1994Assignee: Bechtel Group Inc.Inventor: Richard B. Greenwalt
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Patent number: 5338336Abstract: The present invention provides a method for processing environmentally undesirable materials including petroleum coke and the sulfur and heavy metals contained therein and agglomerated waste dust from an electric arc furnace and the zinc, cadmium, lead and iron oxides contained therein and of providing fuel and a charging material for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier. Metallized arc furnace waste dust material from a reduction furnace is introduced into the melter gasifier. The petroleum coke, oxygen and metallized waste dust material are reacted to produce reduction gas and molten iron from the iron oxides in the waste dust material. The molten iron contains the metals freed from combustion of the petroleum coke. The reduction gas is removed from the melter gasifier for use in the reduction furnace to produce an top off gas containing vapors of zinc, cadmium and lead.Type: GrantFiled: June 30, 1993Date of Patent: August 16, 1994Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 5322544Abstract: This invention relates to the melting of scrap metal containing steel in an electric arc furnace using whole scrap rubber tires as an additional source of heat. Also, scrap rubber may be pylarized to form combustibles which are fed into the electric arc furnace for combustion.Type: GrantFiled: February 8, 1993Date of Patent: June 21, 1994Assignee: Nucor CorporationInventor: Franklin L. Stebbing
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Patent number: 5320676Abstract: The invention relates to a method of making iron or steel preproducts and reduction gas with a low slag forming process utilizing petroleum coke as a fuel in a melter gasifier.Type: GrantFiled: July 29, 1993Date of Patent: June 14, 1994Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 5317862Abstract: In a process integration, particularly with a blast furnace, nitrogen under pressure is moisturized by the addition to it of hot, pressurized water. The moisturized nitrogen is expanded and power thereby generated. The nitrogen is not mixed with combustion gases. Improved heat balance and work recovery are achieved.Type: GrantFiled: April 6, 1993Date of Patent: June 7, 1994Assignee: The BOC Group, plcInventor: Thomas Rathbone
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Patent number: 5295351Abstract: In a process integration, particularly with a blast furnace, low grade fuel gas produced by the furnace is compressed and moisturized. The moisturized fuel is burnt using a major part of a compressed air stream to support its combustion. The resulting combustion gases are then expanded with the generation of power. The minor part of the air is separated into oxygen and nitrogen. Oxygen is used in the blast furnace.Type: GrantFiled: April 6, 1993Date of Patent: March 22, 1994Assignee: The BOC Group, plcInventor: Thomas Rathbone
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Patent number: 5268019Abstract: Air is taken from the air compressor of a gas turbine including in addition to the compressor a combustion chamber and an expansion turbine. The gas turbine drives an alternator. The air taken from the compressor is cooled in heat exchanger to remove heat of compression therefrom. The air is separated in an air separation plant into oxygen and nitrogen. A stream of oxygen is withdrawn from the plant and used in a blast furnace in which iron is made. The off-gas from the blast furnace is a low grade gaseous fuel. It is compressed in compressor which has interstage cooling to remove at least some of the heat of compression. The compressed fuel gas is passed through the heat exchanger countercurrently to the air stream. The resulting pre-heated fuel gas flows into the combustion chamber of the gas turbine and is burned therein to generate gaseous combustion products that are expanded in the turbine. A nitrogen stream is withdrawn in the air separation plant.Type: GrantFiled: March 10, 1992Date of Patent: December 7, 1993Assignee: The BOC Group plcInventor: Thomas Rathbone
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Patent number: 5259864Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising petroleum coke and the sulfur and heavy metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier having an upper fuel charging end, a reduction gas discharging end, a lower molten metal and slag collection end, and means providing an entry for charging ferrous material into the melter gasifier; introducing petroleum coke into the melter gasifier at the upper fuel charging end; blowing oxygen-containing gas into the petroleum coke to form at least a first fluidized bed of coke particles from the petroleum coke; introducing ferrous material into the melter gasifier through the entry means, reacting petroleum coke, oxygen and particulate ferrous material to combust the major portion of the petroleum coke to produce reduction gas and molten iron or steel preproducts containing heavy metals freed from combustion of the petroleType: GrantFiled: October 6, 1992Date of Patent: November 9, 1993Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 5259865Abstract: The invention relates to a method of making iron or steel preproducts and reduction in gas a substantially slag free process utilizing petroleum coke as a fuel in a melter gasifier.Type: GrantFiled: April 30, 1993Date of Patent: November 9, 1993Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 5258054Abstract: A fine particle mixture of iron concentrate and pulverized flux is introduced into the upper portion of the vertical prereduction section of a sealed unitary vessel. Heated gas partially reduces the iron concentrate particles to form wustite which falls to the lower portion where it is melted to form fluid slag. The slag passes into the horizontal section of the vessel which is divided by a barrier into a reduction portion and an oxidation portion. In the reduction portion, pulverized coal and oxygen are introduced and the FeO in the slag is reduced to iron. The entrained iron droplets in the slag are permitted to sediment in a quiescent zone where the slag is removed. The molten iron flows through passages in the lower portion of the barrier into the oxidation portion where oxygen is introduced to remove C, Si, P and other impurities. The final product and waste are separately removed from the oxidation portion. Exhaust gases exit a vertical stack where heat is recaptured and dust particles removed.Type: GrantFiled: November 6, 1991Date of Patent: November 2, 1993Inventor: Li W. Ebenfelt
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Patent number: 5198190Abstract: A method of recycling hazardous and non-hazardous industrial wastes to reclaim valuable metals, metal alloys, and metal oxides, and to produce mineral wool. Wastes including hazardous wastes of USEPA Series D, F, P, K, and U are pulverized and blended with liquids such as water or wastewater to produce a homogeneous mass. Calcium from calcium-stabilized wastes is used to enhance the quality of the mineral wool, lower the sulfur content, remove phosphorous, and raise pH to facilitate metal reduction. The mass is formed into briquettes and melted in a cupola or shaft furnace in the presence of carbon or aluminum to reduce metals. Other types of furnaces such as an electric arc furnace may be used to avoid the steps of forming and curing briquettes. Reduction is carried out at temperatures between 1660 and 3100 degrees Fahrenheit. Reducible metals are reduced and drawn off into molds. Substantial purity is obtained in the recovered reducible metals.Type: GrantFiled: December 21, 1990Date of Patent: March 30, 1993Assignee: Enviroscience, Inc.Inventors: Carl T. Philipp, Bobby H. Sims
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Patent number: 5186740Abstract: This method of preheating scrap iron mixed with plastic, rubber and resinous, ie organic, materials and intended for electric furnaces, in particular electric arc furnaces, is characterized by transforming the plastic, rubbery or resinous and like materials of organic nature present in the scrap iron, to advantageously eliminate them by a path able to produce thermal energy usable for preheating the scrap to be melted, said path consisting of pyrolysis in an environment fed both with the scrap to be melted and with said organic materials, the whole being previously shredded.Type: GrantFiled: September 13, 1990Date of Patent: February 16, 1993Assignee: Blufin S.r.l.Inventor: Roberto Sancinelli
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Patent number: 5124008Abstract: A method for the extraction of valuable minerals and precious metals from oil sands ore bodies or other related ore bodies that is synergistically unique in the arrangement of processes for production of valuable minerals and precious metals in an economically and environmentally acceptable manner. The oil sands ores from oil sands ore bodies and other related ores from other related ore bodies including overburden and interburden mineral ores are crushed, the hydrocarbons, if any exists in worthwhile quantities, are recovered and the resulting coarse sands, other related ores and fines streams are processed in a definite sequence using known processes to recover the valuable minerals and precious metals values. All reactants and reagents, including water, are recycled in the method and tailings ponds are not required. Heat recovery is used extensively to cogenerate almost all of the process steam and process electrical requirements for the method.Type: GrantFiled: June 22, 1990Date of Patent: June 23, 1992Assignee: Solv-Ex CorporationInventors: John S. Rendall, Valentine W. Vaughn, Jr.
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Patent number: 5076837Abstract: A method and apparatus for recovering work from a nitrogen stream, wherein the nitrogen is preheated via heat exchange with hot fluid from a chemical process, which process utilizes the oxygen product of the air separation. Preferably at least a part of the expanded nitrogen is utilized to preheat at least one fluid reactant of the chemical process. The chemical process may be gasification or direct reduction of iron oxide, as well as the conversion of natural gas into synthesis gas.Type: GrantFiled: October 16, 1989Date of Patent: December 31, 1991Assignee: The BOC Group plcInventors: Thomas Rathbone, John T. Lavin
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Patent number: 5066326Abstract: Process and apparatus for the rapid efficient melting of solid ferrous metal scrap without direct exposure to water vapor, carbon dioxide, oxygen or oxygen-containing gases, using natural gas and/or other caloric gaseous fuels. The apparatus includes a furnace having a refractory base, means for introducing ferrous metal such as solid steel scrap to the well area, means for providing a slag layer over the solid steel scrap, and gas burner means for emitting one or more forced gas flames for superheating the slag layer to a liquid which covers the scrap and for agitating and circulating the molten slag to form a highly-efficient heat-transfer medium for melting and refining the steel scrap while it is insulated against contact with gases, particularly water vapor, carbon dioxide, oxygen or oxygen-containing gases. The process may operate continuously and can recover heat for scrap preheating, turbine power and other efficient uses.Type: GrantFiled: May 7, 1990Date of Patent: November 19, 1991Assignee: Gas Research InstituteInventors: Jagdish A. Agarwal, Richard Gannon, Victor Goldfarb, David Stickler, Jaime Woodroffe
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Patent number: 5066325Abstract: A process and arrangement are provided for the efficient generation of energy from coal, while at the same time providing for a relatively inexpensive step in processing of iron or steel, and the extraction of valuable materials such as oils from coal. An advantage to the process is that relatively low quality coals can be utilized, since the coal is pretreated before any burning operation. Generally, the process involves three interacting stages. In the First Stage, a coal liquefaction/pyrolysis procedure is utilized to drive off volatiles, and form a very low volatile char. The volatiles can be collected and utilized as a valuable oil product, such as for diesel fuel or the like. The char material is preferably pelletized and utilized as a reductant, in a Second Stage of iron reduction and melting.Type: GrantFiled: February 24, 1989Date of Patent: November 19, 1991Assignee: Northern States Power CompanyInventor: John M. Lehto
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Patent number: 5055131Abstract: A process and arrangement are provided for the efficient generation of energy from coal, while at the same time providing for a relatively inexpensive step in processing of iron or steel, and the extraction of valuable materials such as oils from coal. An advantage to the process is that relatively low quality coals can be utilized, since the coal is pretreated before any burning operation. Generally, the process involves three interacting stages. In the First Stage, a coal liquefaction/pyrolysis procedure is utilized to drive off volatiles, and form a very low volatile char. The volatiles can be collected and utilized as a valuable oil product, such as for diesel fuel or the like. The char material is preferably pelletized and utilized as a reductant, in a Second Stage of iron reduction and melting.Type: GrantFiled: October 16, 1989Date of Patent: October 8, 1991Assignee: Northern States Power CompanyInventor: John M. Lehto
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Patent number: 5045112Abstract: A process and arrangement are provided for the efficient generation of energy from coal, while at the same time providing for a relatively inexpensive step in processing of iron or steel, and the extraction of valuable materials such as oils from coal. An advantage to the process is that relatively low quality coals can be utilized, since the coal is pretreated before any burning operation. Generally, the process involves three interacting stages. In the First Stage, a coal liquefaction/pyrolysis procedure is utilized to drive off volatiles, and form a very low volatile char. The volatiles can be collected and utilized as a valuable oil product, such as for diesel fuel or the like. The char material is preferably pelletized and utilized as a reductant, in a Second Stage of iron reduction and melting.Type: GrantFiled: August 22, 1988Date of Patent: September 3, 1991Assignee: Northern States Power CompanyInventor: John M. Lehto
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Patent number: 4957546Abstract: The present invention relates to a new steelmaking process and apparatus which operates on an intermittent basis where several cycles composed of reducing and oxidizing periods are performed to create sufficient energy for melting of solid metallic charge, i.e., sponge iron, scrap, iron ore. During the reducing period, oxygen and carbonaceous material are injected through the vessel bottom thus attaining both carburization of a steam of the melt and generation of CO+H.sub.2 rich gas, and when the dissolved carbon of the melt is in the range of 3%-4%, conditions are then changed to the oxidizing period where solid metallic charge is added initially while oxygen injection is maintained, and until the solid charge has been melted, thus generating a stream of CO+CO.sub.2 gas rich in CO. In addition, other fluids and solids participate in the process, i.e., nitrogen, hydrocarbons, fluxes, and are used according to the appropriate period of the process.Type: GrantFiled: May 10, 1989Date of Patent: September 18, 1990Assignee: Instituto Mexicano de Investigaciones SiderurgicasInventor: Arturo Lazcano-Navarro