Color Stripping Or Subduing Patents (Class 8/102)
  • Patent number: 3986825
    Abstract: A hair treating composition containing, in addition to a hair coloring agent, a water soluble secondary or tertiary amine polymer or a polymer of diallylamine or a quaternary polymer of diallyldialkylammonium salts which improves the surface characteristics of hair.
    Type: Grant
    Filed: May 14, 1975
    Date of Patent: October 19, 1976
    Assignee: The Gillette Company
    Inventor: Phillip E. Sokol
  • Patent number: 3984402
    Abstract: Indoaniline having the formula ##SPC1##Wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, lower alkyl or halogen with 1 - 2 of these substituents being other than hydrogen; R.sub.5, R.sub.6 and R.sub.7 each independently represent a member selected from the group consisting of hydrogen, lower alkyl and lower alkoxy; R.sub.8 and R.sub.9 each independently represent a member selected from the group consisting of hydrogen, lower alkyl and lower alkyl substituted with a member selected from the group consisting of amino, hydroxy, carbamoyl, piperidinyl and acylamino, R.sub.8 and R.sub.5 or R.sub.9 and R.sub.
    Type: Grant
    Filed: December 24, 1974
    Date of Patent: October 5, 1976
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
  • Patent number: 3984443
    Abstract: Indamine having the formula ##SPC1##Wherein R and R' each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms, lower alkoxy having 1-4 carbon atoms, amino, acylamino wherein the acyl moiety has 1 to 4 carbon atoms and hydroxy, with the proviso that one, but not both of R and R' is said amino, acylamino or hydroxy; R.sub.1 and R.sub.2 each independently represent a member selected from the group consisting of lower alkyl having 1-4 carbon atoms and lower alkyl having 1-4 carbon atoms and substituted with a member selected from the group consisting of hydroxy, acylamino wherein the acyl moiety has 1 to 4 carbon atoms, carbamyl, piperidino, benzoylamino and alkylsulfonamido wherein the alkyl moiety has 1 to 4 carbon atoms; R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.
    Type: Grant
    Filed: February 25, 1975
    Date of Patent: October 5, 1976
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Andre Bugaut, Francoise Estradier
  • Patent number: 3981677
    Abstract: Hair dyeing compositions are disclosed which contain an N-substituted o-phenylenediamine, the N-substituent being an alkyl, alkoxyalkyl, hydroxyalkyl, alkylaminoalkyl, dialkylaminoalkyl, phenyl or substituted phenyl. These give reddish shades by purely oxidative means, and the shades are fast to wet treatments and are long-wearing. Also disclosed are methods of dyeing hair with these compositions, as well as certain novel compounds suitable for the purpose, e.g., N-(alkoxyalkyl)-o-phenylenediamines.
    Type: Grant
    Filed: January 2, 1974
    Date of Patent: September 21, 1976
    Assignee: Clairol Incorporated
    Inventors: Alexander Halasz, Frederick Brody, deceased, by Richard Newman, executor
  • Patent number: 3981676
    Abstract: A dye for coloring hair is one of an indamine, indoaniline, indophenol, diaminobenzoquinone or mixtures thereof which is lyophilized from a solution of the dye in an organic solvent or in an aqueous solution of the organic solvent by freezing the solution at a temperature of -200.degree. to -60.degree.C, and then subliming the frozen solution under a vacuum at a temperature lower than the melting point of the frozen solution. The thus lyophilized dye can be desorped to eliminate, if necessary, residual moisture. The lyophilized dye can be solubilized in an aqueous solution to produce a hair dye composition and can be present therein in amounts of about 0.0005-4 percent by weight of said composition.
    Type: Grant
    Filed: June 25, 1973
    Date of Patent: September 21, 1976
    Assignee: L'Oreal
    Inventors: Giuliana Ghilardi, Pierre Bore, Jean-Francois Grollier
  • Patent number: 3981678
    Abstract: A process for producing a dye in powder form involves reacting an oxidation agent with an oxidation base in an aqueous alkaline medium, preferably an ammoniacal medium, having a pH ranging from 8 to 13, in the presence of an organic solvent for the dye being produced, at a temperature and during a period of time allowing at least a partial oxidation, preferably between 15.degree.-30.degree.C for a period of about 5 minutes to 30 hours and lyophilizing the resulting reaction product. The resulting dye can be used to color keratinic fibers, especially human hair.
    Type: Grant
    Filed: June 25, 1973
    Date of Patent: September 21, 1976
    Assignee: L'Oreal
    Inventors: Giuliana Ghilardi, Pierre Bore, Jean-Francois Grollier
  • Patent number: 3977826
    Abstract: Terpenes and their derivatives provide improved stability to aqueous solutions containing hydrogen peroxide as well as to aerosol co-dispensing hair coloring systems containing oxidation dye compositions.
    Type: Grant
    Filed: February 21, 1975
    Date of Patent: August 31, 1976
    Assignee: Clairol Incorporated
    Inventor: Sigmund Iscowitz
  • Patent number: 3977825
    Abstract: Indoaniline of the formula ##SPC1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 represent alkyl; R.sub.4, R.sub.5 and R.sub.6 each independently represent hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino and R.sub.5 can also represent amino, alkylamino, hydroxy alkylamino or carbamylalkylamino, the alkyl and alkoxy groups above being able to contain 1 to 6 carbon atoms and the acyl group from 2 to 7 carbon atoms with the condition that R.sub.5 does not represent hydrogen, chlorine, methyl or methoxy and when R.sub.5 represents acetylamino, R.sub.6 does not represent hydrogen; it being understood that the above compounds can be present in the tautomeric form of that represented by formula (I). The indoaniline is usefully employed in dye compositions for keratinic fibers, especially living human hair.
    Type: Grant
    Filed: June 24, 1974
    Date of Patent: August 31, 1976
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
  • Patent number: 3975515
    Abstract: Process for reducing the alkali concentration in alkaline reactive cosmetic preparations which comprises the step of adding to such a preparation, shortly before its use, at least one alkali-cleavable organic compound having ester and/or halogen groups in its molecule and which is capable on cleavage to form an acid. The invention also includes the agents suitable for carrying out the aforesaid process.
    Type: Grant
    Filed: September 30, 1974
    Date of Patent: August 17, 1976
    Assignee: Wella AG
    Inventors: Theodor Wajaroff, Eugen Konrad
  • Patent number: 3973900
    Abstract: Hair dyeing compositions containing a dye which has the formula ##SPC1##Wherein R.sub.1 and R.sub.2 are each hydrogen or hydroxy ethyl alone or in conjunction with an oxidation and/or direct dyeing dye. The hair dyeing compositions can also include the conventional additives such as water soluble surface active agents, thickening agents, complex formers, antioxidants, softeners, perfumes, and the like.
    Type: Grant
    Filed: September 9, 1974
    Date of Patent: August 10, 1976
    Assignee: Wella AG
    Inventors: Hans Husemeyer, Eugene Konrad
  • Patent number: 3972937
    Abstract: Hair dye and hair-setting lotion compositions contain a diphenylamine of the formula ##SPC1##Wherein Z represents amino, acylamino or hydroxy, R.sub.1, R.sub.2 and R.sub.3 represent hydrogen or lower alkyl, R.sub.4 represents hydrogen, lower alkyl or together with R.sub.1 and the nitrogen atom to which R.sub.4 is attached form a dihydro-oxazine or pyrroline heterocycle and R.sub.5 represents hydrogen, lower alkyl or together with R.sub.2 and the nitrogen atom to which R.sub.5 is attached form a dihydro-oxazine or pyrroline heterocycle and the acid salts of said diphenylamine.
    Type: Grant
    Filed: August 21, 1974
    Date of Patent: August 3, 1976
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
  • Patent number: 3970423
    Abstract: Oxidative hair dye composition containing as "para component" compounds of the formula: ##SPC1##Or their acid addition salts, in which:R.sub.1 is alkyl or hydroxyalkyl;R.sub.2 is hydrogen or hydroxyalkyl;R.sub.3 is hydrogen, alkyl, alkoxy or halogen; andR.sub.4 occupies any one of the remaining positions on the benzene radical and is hydrogen, alkyl, alkoxy or halogen; providing that R.sub.2 is hydrogen when R.sub.3 is alkyl, alkoxy or halogen and providing that at least two of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 are other than hydrogen.
    Type: Grant
    Filed: February 6, 1975
    Date of Patent: July 20, 1976
    Assignee: Clairol Incorporated
    Inventors: Frederick Brody, Stanley Pohl
  • Patent number: 3966398
    Abstract: A hair dyeing composition containing a non-ionic surfactant having the formula ##EQU1## WHEREIN R is selected from the group consisting of aliphatic, cycloaliphatic and arylaliphatic radicals and mixtures thereof having 7-21 carbon atoms, n is greater than 1 and equal to or less than 10, is disclosed.
    Type: Grant
    Filed: March 24, 1975
    Date of Patent: June 29, 1976
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Henri Sebag
  • Patent number: 3961634
    Abstract: Process and composition for bleaching hair containing oxidizing agents which liberate active oxygen, and which contain keratose so as to reduce damage to the hair.
    Type: Grant
    Filed: July 23, 1974
    Date of Patent: June 8, 1976
    Assignee: Henkel & Cie G.m.b.H.
    Inventor: Peter Busch
  • Patent number: 3961879
    Abstract: A dye composition for keratinic fibers comprising in combinationA. at least one oxidation base comprising a paraphenylenediamine, present in the form of a free base, or in the form of an acid addition salt thereof andB. at least one coupler of the formula: ##SPC1##wherein Y represents a member selected from the group consisting of --NHCOCH.sub.3 and --NHCONH.sub.2 ; and X represents a member selected from the group consisting of fluorine, chlorine, and bromine, or the acid addition salt of the compound of formula (I).
    Type: Grant
    Filed: June 24, 1974
    Date of Patent: June 8, 1976
    Assignee: L'Oreal
    Inventors: Andree Bugaut, Monique Laudon
  • Patent number: 3960476
    Abstract: A process for producing a dye in powder form involves reacting an oxidation agent with an oxidation base in an aqueous alkaline preferably ammoniacal medium having a pH ranging from 8 to 13 at a temperature and during a period of time allowing at least a partial oxidation, preferably between 15.degree.-30.degree.C for a period of about 5 minutes to 30 hours and lyophilizing or spray-drying the resulting reaction product. The resulting dye can be used to color keratinic fibers, especially human hair.
    Type: Grant
    Filed: April 15, 1974
    Date of Patent: June 1, 1976
    Inventors: Giuliana Ghilardi, Pierre Bore, Jean-Francois Grollier
  • Patent number: 3957424
    Abstract: An enzyme-based oxidative process for coloring hair wherein the hair is exposed to a solution having a pH of about 4 to about 10 and containing hydrogen peroxide, soybean peroxidase enzyme and one or more oxidation dye precursors.
    Type: Grant
    Filed: September 13, 1974
    Date of Patent: May 18, 1976
    Assignee: The Procter & Gamble Company
    Inventors: Eugene Zeffren, John Francis Sullivan
  • Patent number: 3954393
    Abstract: A composition for dyeing hair comprising the product formed by contacting bismuth citrate, triethanolamine and sulfur in the presence of water. The product is stable in solution; in use the product is applied to human hair, as on the scalp, and thereupon effects a darkening of the hair.
    Type: Grant
    Filed: August 29, 1973
    Date of Patent: May 4, 1976
    Assignee: Combe, Inc.
    Inventor: Herbert Lapidus
  • Patent number: 3950532
    Abstract: A composition and method for treating the hair and skin characterized by a greasy, unaesthetic appearance to reduce or essentially eliminate this greasy appearance which includes topically applying to a human having hair or skin so characterized a cosmetic composition containing as an active ingredient a cis or trans 3,4-thiolannediol, its cis or trans S-oxide derivatives or its cis or trans S-dioxide derivatives.
    Type: Grant
    Filed: May 10, 1972
    Date of Patent: April 13, 1976
    Assignee: L'Oreal
    Inventors: Claude Bouillon, Michel Colin
  • Patent number: 3950127
    Abstract: A hair dye composition comprising a fluid direct-dye hair dye vehicle suitable for application to human hair containing a tinctorially effective amount of a hair dye of formula: ##SPC1##In which:A. R is an electron donor functional group;B. y is a whole number from 0 to 1 inclusive; andC. x is a whole number from 1 to 2 inclusive.Also describes a method of dyeing hair using these compositions and further describes certain novel nitrodiphenylamine dyes.
    Type: Grant
    Filed: December 26, 1972
    Date of Patent: April 13, 1976
    Assignee: Clairol Incorporated
    Inventors: Alexander Halasz, David Cohen
  • Patent number: 3948596
    Abstract: A dye composition for keratinic fibers comprising in combination:A. at least one oxidation base selected from the group consisting of an aromatic or heterocyclic compound carrying either two amino groups or one amine group and one hydroxy group, fixed in para position relative to each other on the aromatic or heterocyclic nucleus of said compound, said oxidation base being in the form of a free base or in the form of an acid addition salt thereof; andB. at least one coupler of the formula: ##SPC1##Wherein X represents a member selected from the group consisting of F, Cl or Br.
    Type: Grant
    Filed: June 24, 1974
    Date of Patent: April 6, 1976
    Assignee: Societe Anonyme dite: L'Oreal
    Inventors: Gregoire Kalopissis, Andree Bugaut
  • Patent number: 3933886
    Abstract: A hair dye preparation contains diamino-nitrobenzene compounds as a direct hair dye or contains diamino-nitrobenzene compounds as coupling components in combination with developing components for oxidation dyestuffs. A process for dyeing human hair comprises applying one of these preparations to the hair.
    Type: Grant
    Filed: May 16, 1974
    Date of Patent: January 20, 1976
    Assignee: Henkel & Cie GmbH
    Inventor: Ferdi Saygin
  • Patent number: 3931912
    Abstract: A pressurized package containing a conventional pressure propellant is divided into two compartments arranged for mixing of their contents simultaneously with dispensing, one compartment containing a peroxide solution and the other containing a hair treating composition including certain selected compounds in quantity sufficient to prevent development of unsafe pressure should the peroxide decompose within the package.
    Type: Grant
    Filed: October 7, 1974
    Date of Patent: January 13, 1976
    Assignee: The Gillette Company
    Inventor: Du Yung Hsiung