Color Stripping Or Subduing Patents (Class 8/102)
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Patent number: 3986825Abstract: A hair treating composition containing, in addition to a hair coloring agent, a water soluble secondary or tertiary amine polymer or a polymer of diallylamine or a quaternary polymer of diallyldialkylammonium salts which improves the surface characteristics of hair.Type: GrantFiled: May 14, 1975Date of Patent: October 19, 1976Assignee: The Gillette CompanyInventor: Phillip E. Sokol
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Patent number: 3984402Abstract: Indoaniline having the formula ##SPC1##Wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, lower alkyl or halogen with 1 - 2 of these substituents being other than hydrogen; R.sub.5, R.sub.6 and R.sub.7 each independently represent a member selected from the group consisting of hydrogen, lower alkyl and lower alkoxy; R.sub.8 and R.sub.9 each independently represent a member selected from the group consisting of hydrogen, lower alkyl and lower alkyl substituted with a member selected from the group consisting of amino, hydroxy, carbamoyl, piperidinyl and acylamino, R.sub.8 and R.sub.5 or R.sub.9 and R.sub.Type: GrantFiled: December 24, 1974Date of Patent: October 5, 1976Assignee: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
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Patent number: 3984443Abstract: Indamine having the formula ##SPC1##Wherein R and R' each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms, lower alkoxy having 1-4 carbon atoms, amino, acylamino wherein the acyl moiety has 1 to 4 carbon atoms and hydroxy, with the proviso that one, but not both of R and R' is said amino, acylamino or hydroxy; R.sub.1 and R.sub.2 each independently represent a member selected from the group consisting of lower alkyl having 1-4 carbon atoms and lower alkyl having 1-4 carbon atoms and substituted with a member selected from the group consisting of hydroxy, acylamino wherein the acyl moiety has 1 to 4 carbon atoms, carbamyl, piperidino, benzoylamino and alkylsulfonamido wherein the alkyl moiety has 1 to 4 carbon atoms; R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.Type: GrantFiled: February 25, 1975Date of Patent: October 5, 1976Assignee: L'OrealInventors: Gregoire Kalopissis, Andre Bugaut, Francoise Estradier
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Patent number: 3981677Abstract: Hair dyeing compositions are disclosed which contain an N-substituted o-phenylenediamine, the N-substituent being an alkyl, alkoxyalkyl, hydroxyalkyl, alkylaminoalkyl, dialkylaminoalkyl, phenyl or substituted phenyl. These give reddish shades by purely oxidative means, and the shades are fast to wet treatments and are long-wearing. Also disclosed are methods of dyeing hair with these compositions, as well as certain novel compounds suitable for the purpose, e.g., N-(alkoxyalkyl)-o-phenylenediamines.Type: GrantFiled: January 2, 1974Date of Patent: September 21, 1976Assignee: Clairol IncorporatedInventors: Alexander Halasz, Frederick Brody, deceased, by Richard Newman, executor
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Patent number: 3981676Abstract: A dye for coloring hair is one of an indamine, indoaniline, indophenol, diaminobenzoquinone or mixtures thereof which is lyophilized from a solution of the dye in an organic solvent or in an aqueous solution of the organic solvent by freezing the solution at a temperature of -200.degree. to -60.degree.C, and then subliming the frozen solution under a vacuum at a temperature lower than the melting point of the frozen solution. The thus lyophilized dye can be desorped to eliminate, if necessary, residual moisture. The lyophilized dye can be solubilized in an aqueous solution to produce a hair dye composition and can be present therein in amounts of about 0.0005-4 percent by weight of said composition.Type: GrantFiled: June 25, 1973Date of Patent: September 21, 1976Assignee: L'OrealInventors: Giuliana Ghilardi, Pierre Bore, Jean-Francois Grollier
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Patent number: 3981678Abstract: A process for producing a dye in powder form involves reacting an oxidation agent with an oxidation base in an aqueous alkaline medium, preferably an ammoniacal medium, having a pH ranging from 8 to 13, in the presence of an organic solvent for the dye being produced, at a temperature and during a period of time allowing at least a partial oxidation, preferably between 15.degree.-30.degree.C for a period of about 5 minutes to 30 hours and lyophilizing the resulting reaction product. The resulting dye can be used to color keratinic fibers, especially human hair.Type: GrantFiled: June 25, 1973Date of Patent: September 21, 1976Assignee: L'OrealInventors: Giuliana Ghilardi, Pierre Bore, Jean-Francois Grollier
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Patent number: 3977826Abstract: Terpenes and their derivatives provide improved stability to aqueous solutions containing hydrogen peroxide as well as to aerosol co-dispensing hair coloring systems containing oxidation dye compositions.Type: GrantFiled: February 21, 1975Date of Patent: August 31, 1976Assignee: Clairol IncorporatedInventor: Sigmund Iscowitz
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Patent number: 3977825Abstract: Indoaniline of the formula ##SPC1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 represent alkyl; R.sub.4, R.sub.5 and R.sub.6 each independently represent hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino and R.sub.5 can also represent amino, alkylamino, hydroxy alkylamino or carbamylalkylamino, the alkyl and alkoxy groups above being able to contain 1 to 6 carbon atoms and the acyl group from 2 to 7 carbon atoms with the condition that R.sub.5 does not represent hydrogen, chlorine, methyl or methoxy and when R.sub.5 represents acetylamino, R.sub.6 does not represent hydrogen; it being understood that the above compounds can be present in the tautomeric form of that represented by formula (I). The indoaniline is usefully employed in dye compositions for keratinic fibers, especially living human hair.Type: GrantFiled: June 24, 1974Date of Patent: August 31, 1976Assignee: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
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Patent number: 3975515Abstract: Process for reducing the alkali concentration in alkaline reactive cosmetic preparations which comprises the step of adding to such a preparation, shortly before its use, at least one alkali-cleavable organic compound having ester and/or halogen groups in its molecule and which is capable on cleavage to form an acid. The invention also includes the agents suitable for carrying out the aforesaid process.Type: GrantFiled: September 30, 1974Date of Patent: August 17, 1976Assignee: Wella AGInventors: Theodor Wajaroff, Eugen Konrad
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Patent number: 3973900Abstract: Hair dyeing compositions containing a dye which has the formula ##SPC1##Wherein R.sub.1 and R.sub.2 are each hydrogen or hydroxy ethyl alone or in conjunction with an oxidation and/or direct dyeing dye. The hair dyeing compositions can also include the conventional additives such as water soluble surface active agents, thickening agents, complex formers, antioxidants, softeners, perfumes, and the like.Type: GrantFiled: September 9, 1974Date of Patent: August 10, 1976Assignee: Wella AGInventors: Hans Husemeyer, Eugene Konrad
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Patent number: 3972937Abstract: Hair dye and hair-setting lotion compositions contain a diphenylamine of the formula ##SPC1##Wherein Z represents amino, acylamino or hydroxy, R.sub.1, R.sub.2 and R.sub.3 represent hydrogen or lower alkyl, R.sub.4 represents hydrogen, lower alkyl or together with R.sub.1 and the nitrogen atom to which R.sub.4 is attached form a dihydro-oxazine or pyrroline heterocycle and R.sub.5 represents hydrogen, lower alkyl or together with R.sub.2 and the nitrogen atom to which R.sub.5 is attached form a dihydro-oxazine or pyrroline heterocycle and the acid salts of said diphenylamine.Type: GrantFiled: August 21, 1974Date of Patent: August 3, 1976Assignee: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
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Patent number: 3970423Abstract: Oxidative hair dye composition containing as "para component" compounds of the formula: ##SPC1##Or their acid addition salts, in which:R.sub.1 is alkyl or hydroxyalkyl;R.sub.2 is hydrogen or hydroxyalkyl;R.sub.3 is hydrogen, alkyl, alkoxy or halogen; andR.sub.4 occupies any one of the remaining positions on the benzene radical and is hydrogen, alkyl, alkoxy or halogen; providing that R.sub.2 is hydrogen when R.sub.3 is alkyl, alkoxy or halogen and providing that at least two of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 are other than hydrogen.Type: GrantFiled: February 6, 1975Date of Patent: July 20, 1976Assignee: Clairol IncorporatedInventors: Frederick Brody, Stanley Pohl
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Patent number: 3966398Abstract: A hair dyeing composition containing a non-ionic surfactant having the formula ##EQU1## WHEREIN R is selected from the group consisting of aliphatic, cycloaliphatic and arylaliphatic radicals and mixtures thereof having 7-21 carbon atoms, n is greater than 1 and equal to or less than 10, is disclosed.Type: GrantFiled: March 24, 1975Date of Patent: June 29, 1976Assignee: L'OrealInventors: Guy Vanlerberghe, Henri Sebag
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Patent number: 3961634Abstract: Process and composition for bleaching hair containing oxidizing agents which liberate active oxygen, and which contain keratose so as to reduce damage to the hair.Type: GrantFiled: July 23, 1974Date of Patent: June 8, 1976Assignee: Henkel & Cie G.m.b.H.Inventor: Peter Busch
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Patent number: 3961879Abstract: A dye composition for keratinic fibers comprising in combinationA. at least one oxidation base comprising a paraphenylenediamine, present in the form of a free base, or in the form of an acid addition salt thereof andB. at least one coupler of the formula: ##SPC1##wherein Y represents a member selected from the group consisting of --NHCOCH.sub.3 and --NHCONH.sub.2 ; and X represents a member selected from the group consisting of fluorine, chlorine, and bromine, or the acid addition salt of the compound of formula (I).Type: GrantFiled: June 24, 1974Date of Patent: June 8, 1976Assignee: L'OrealInventors: Andree Bugaut, Monique Laudon
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Patent number: 3960476Abstract: A process for producing a dye in powder form involves reacting an oxidation agent with an oxidation base in an aqueous alkaline preferably ammoniacal medium having a pH ranging from 8 to 13 at a temperature and during a period of time allowing at least a partial oxidation, preferably between 15.degree.-30.degree.C for a period of about 5 minutes to 30 hours and lyophilizing or spray-drying the resulting reaction product. The resulting dye can be used to color keratinic fibers, especially human hair.Type: GrantFiled: April 15, 1974Date of Patent: June 1, 1976Inventors: Giuliana Ghilardi, Pierre Bore, Jean-Francois Grollier
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Patent number: 3957424Abstract: An enzyme-based oxidative process for coloring hair wherein the hair is exposed to a solution having a pH of about 4 to about 10 and containing hydrogen peroxide, soybean peroxidase enzyme and one or more oxidation dye precursors.Type: GrantFiled: September 13, 1974Date of Patent: May 18, 1976Assignee: The Procter & Gamble CompanyInventors: Eugene Zeffren, John Francis Sullivan
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Patent number: 3954393Abstract: A composition for dyeing hair comprising the product formed by contacting bismuth citrate, triethanolamine and sulfur in the presence of water. The product is stable in solution; in use the product is applied to human hair, as on the scalp, and thereupon effects a darkening of the hair.Type: GrantFiled: August 29, 1973Date of Patent: May 4, 1976Assignee: Combe, Inc.Inventor: Herbert Lapidus
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Patent number: 3950532Abstract: A composition and method for treating the hair and skin characterized by a greasy, unaesthetic appearance to reduce or essentially eliminate this greasy appearance which includes topically applying to a human having hair or skin so characterized a cosmetic composition containing as an active ingredient a cis or trans 3,4-thiolannediol, its cis or trans S-oxide derivatives or its cis or trans S-dioxide derivatives.Type: GrantFiled: May 10, 1972Date of Patent: April 13, 1976Assignee: L'OrealInventors: Claude Bouillon, Michel Colin
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Patent number: 3950127Abstract: A hair dye composition comprising a fluid direct-dye hair dye vehicle suitable for application to human hair containing a tinctorially effective amount of a hair dye of formula: ##SPC1##In which:A. R is an electron donor functional group;B. y is a whole number from 0 to 1 inclusive; andC. x is a whole number from 1 to 2 inclusive.Also describes a method of dyeing hair using these compositions and further describes certain novel nitrodiphenylamine dyes.Type: GrantFiled: December 26, 1972Date of Patent: April 13, 1976Assignee: Clairol IncorporatedInventors: Alexander Halasz, David Cohen
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Patent number: 3948596Abstract: A dye composition for keratinic fibers comprising in combination:A. at least one oxidation base selected from the group consisting of an aromatic or heterocyclic compound carrying either two amino groups or one amine group and one hydroxy group, fixed in para position relative to each other on the aromatic or heterocyclic nucleus of said compound, said oxidation base being in the form of a free base or in the form of an acid addition salt thereof; andB. at least one coupler of the formula: ##SPC1##Wherein X represents a member selected from the group consisting of F, Cl or Br.Type: GrantFiled: June 24, 1974Date of Patent: April 6, 1976Assignee: Societe Anonyme dite: L'OrealInventors: Gregoire Kalopissis, Andree Bugaut
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Patent number: 3933886Abstract: A hair dye preparation contains diamino-nitrobenzene compounds as a direct hair dye or contains diamino-nitrobenzene compounds as coupling components in combination with developing components for oxidation dyestuffs. A process for dyeing human hair comprises applying one of these preparations to the hair.Type: GrantFiled: May 16, 1974Date of Patent: January 20, 1976Assignee: Henkel & Cie GmbHInventor: Ferdi Saygin
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Patent number: 3931912Abstract: A pressurized package containing a conventional pressure propellant is divided into two compartments arranged for mixing of their contents simultaneously with dispensing, one compartment containing a peroxide solution and the other containing a hair treating composition including certain selected compounds in quantity sufficient to prevent development of unsafe pressure should the peroxide decompose within the package.Type: GrantFiled: October 7, 1974Date of Patent: January 13, 1976Assignee: The Gillette CompanyInventor: Du Yung Hsiung