Azo Dye Component Ground Patents (Class 8/451)
  • Patent number: 8551191
    Abstract: Dicationic azo dyes of the formula (I), which are suitable for coloring keratin fibers, in particular human hair, and are in part themselves still not described in the prior art are provided. In colorations, particularly brilliant and luminous red shades are obtained. Agents for dyeing and optionally simultaneously lightening keratin fibers and methods for dyeing and optionally simultaneously lightening keratinic fibers also are provided.
    Type: Grant
    Filed: March 4, 2013
    Date of Patent: October 8, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Wibke Gross, Helmut Giesa, Astrid Kroos
  • Patent number: 8506652
    Abstract: The present invention is directed to a disperse dye of formula (1) Wherein, X, Y and Z are, independently, hydrogen, halogen, cyano, nitro or SO2F; Wherein at least one of X, Y and Z is SO2F. R1 is hydrogen, methyl, hydroxyl or NHR4; R2 is hydrogen, chloro or methoxy; R3 is hydrogen, (C1-C4)-alkyl or —CH2(CH2)nCOOCH2CN; R5 is hydrogen, (C1-C4)-alkyl or —CH2(CH2)mCOOCH2CN; R4 is —COCH3, —CO C2H5, —SO2CH3 or SO2C2H5; n and m are independently 0,1 or 2, with the proviso: —When, Y and Z both are Cl, R1 is other than methyl. When, R2 is Hydrogen and R3, R4 both are alkyl, R1 is selected from NHSO2CH3 or NHSO2C2H5. Disperse dyes of Formula (I) have excellent washing fastness and light fastness on polyester fiber and polyester blends.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: August 13, 2013
    Assignee: Colourtex Industries Limited
    Inventors: Pankaj Desai, Kiyoshi Himeno, Nikhil Desai, Jay Patel
  • Patent number: 7833958
    Abstract: A laundry treatment composition which comprises a surfactant and from 0.0001 to 0.1 wt % of a combination of dyes which together have a visual effect on the human eye as a single dye having a peak absorption wavelength on cotton of from 540 nm to 650 nm, preferably from 570 mn to 630 mn, the combination comprising a photostable dye which is substantive to cotton.
    Type: Grant
    Filed: July 1, 2009
    Date of Patent: November 16, 2010
    Assignee: Conopco, Inc.
    Inventors: Danielle Santinho Barbizan, Stephen Norman Batchelor, Lisanne Beatriz Grigolon, Andrea Dias Sorze, Andrew Thomas Steel
  • Patent number: 7829517
    Abstract: The present invention relates to a solid laundry detergent composition comprising non-ionic detersive surfactant and reactive dye.
    Type: Grant
    Filed: March 30, 2009
    Date of Patent: November 9, 2010
    Assignee: The Procter & Gamble Company
    Inventor: Alan Thomas Brooker
  • Patent number: 7582122
    Abstract: Disclosed herein is a mixed cationic direct dye comprising at least one anthraquinone chromophore and at least one cationic chromophore chosen from cationic azo chromophores and cationic hydrazone chromophores, wherein the at least one anthraquinone chromophore is bound to the at least one cationic chromophore by means of at least one linkage. Also disclosed herein is a dyeing composition comprising at least one mixed cationic direct dye. Further disclosed herein is a method of dyeing of keratin fibers, for example, keratin fibers, comprising applying said dyeing composition to the keratin fibers. Still further disclosed herein is a multi-compartment kit comprising at least one compartment comprising at least one dye composition and at least one second compartment comprising at least one oxidizing agent.
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: September 1, 2009
    Assignee: L'Oreal S.A.
    Inventors: Nicolas Daubresse, Andrew Greaves
  • Patent number: 7569531
    Abstract: A laundry treatment composition which comprises a surfactant and from 0.0001 to 0.1 wt % of a combination of dyes which together have a visual effect on the human eye as a single dye having a peak absorption wavelength on cotton of from 540 nm to 650 nm, preferably from 570 mn to 630 mn, the combination comprising a photostable dye which is substantive to cotton.
    Type: Grant
    Filed: June 4, 2004
    Date of Patent: August 4, 2009
    Assignee: Conopco Inc.
    Inventors: Danielle Santinho Barbizan, Stephen Norman Batchelor, Lisanne Beatriz Grigolon, Andrea Dias Sorze, Andrew Thomas Steel
  • Patent number: 7407516
    Abstract: The present disclosure relates to a novel dyeing composition for dyeing human keratinous fibers, such as hair, comprising at least one dicationic diazo dye of formula (I): [W1—N?N—W2—W3—(W4—W5)p-]2-L ??Formula (I) as well as the process for dyeing hair using same. Certain compounds of formula (I) are also disclosed herein.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: August 5, 2008
    Assignee: L'Oreal, S.A.
    Inventor: Laurent Vidal
  • Patent number: 7399320
    Abstract: The invention concerns the use as direct dyeing agent of at least one tetra-azapentamethine compound, a dyeing composition comprising at least such a compound, as well as a method for dyeing keratinous fibers, in particular human keratinous fibers and more particularly hair, which consists in applying at least one composition comprising such a compound. The composition also concerns tetra-azapentamethine compounds of formula (I). The invention further concerns a method for bleaching such compounds, as well as bleaching keratinous fibers previously dyed therewith.
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: July 15, 2008
    Assignee: L'Oreal
    Inventors: Herve Burgaud, Herve David, Rui Pereira, Beatrice Belcour-Castro
  • Patent number: 7294153
    Abstract: Keratinic fibers are colored by a two-component composition for coloring keratinous fibers comprising a first preparation (A) comprising at least one oxidation dye precursor and a second preparation (B) comprising at least one care component, wherein the two preparations are packaged separately from one another in the compartments of a two-compartment tube. The compartment openings in the tube are oriented in such a way that the contents of each of the chambers is emitted simultaneously into a common space.
    Type: Grant
    Filed: June 19, 2006
    Date of Patent: November 13, 2007
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Astrid Kleen, Mustafa Akram, Stefan Hoepfner, Hartmut Manneck
  • Patent number: 7261743
    Abstract: The present disclosure relates to the process of dyeing human keratinous fibers, such as the hair, with at least one specific direct dye in cosmetic compositions. Also disclosed herein are the direct dyeing and lightening compositions comprising said compounds, and the corresponding dyeing kits.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: August 28, 2007
    Assignee: L'Oreal
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7255718
    Abstract: The present invention relates to a composition for coloring keratin fibers and a method of use thereof. The coloring composition contains at least one phosphate-based tenside of a particular formula, at least one conditioning component, and at least one dye and/or dye precursor.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: August 14, 2007
    Assignee: Hans Schwarzkopf GmbH & Co. KG
    Inventors: Mustafa Akram, Wolfgang Wolff, Sandra Rohweder
  • Patent number: 7247173
    Abstract: Keratinic fibers are dyed with a two-component agent for tinting and/or dyeing keratinic fibers comprising a first preparation (A) comprising at least one direct-absorbing dye and/or at least one precursor of a nature-analogous dye, and a second preparation (B) containing at least one conditioning substance, wherein the two preparations are packaged separately from one another in the chambers of a two-chamber tube. The chamber openings in the tube are oriented in such a way that the contents of each of the chambers are emitted simultaneously into a common space.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: July 24, 2007
    Assignee: Henkel Kommandit Gesellschaft auf Aktien
    Inventors: Astrid Kleen, Mustafa Akram, Susanne Bietz, Stefan Hoepfner, Hartmut Manneck, Maureen Rippe
  • Patent number: 7232467
    Abstract: A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: June 19, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jean-Marie Adam, Taher Yousaf, Beate Fröhling, Victor Paul Eliu
  • Patent number: 7229479
    Abstract: A method of coloring porous material, especially human hair, is described, which method comprises applying to the material being colored, in any desired order successively, or simultaneously, a) at least one capped diazonium compound and b) at least one cationic water-soluble aromatic coupling component, under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: June 12, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Beate Fröhling, Victor Paul Eliu
  • Patent number: 7217299
    Abstract: The present invention relates to a dye composition comprising, as direct dye, at least one dye of the azo-pyridinio-pyridone family and at least one synthetic dye different from the first dye. The invention also relates to a process for dyeing keratin fibers, e.g., human keratin fibers such as the hair, and to a multi-compartment device for implementing it.
    Type: Grant
    Filed: January 7, 2005
    Date of Patent: May 15, 2007
    Assignee: L'Oreal S.A.
    Inventors: Sylvain Kravtchenko, Alain Lagrange, Frédéric Guerin
  • Patent number: 7198651
    Abstract: The present invention relates to a method to achieve a reversible change of the colour of hair dyed with an azo dye wherein the change of the colour can be effected by, for example, the salonist or the consumer in a simple manner. The colour of the hair thus dyed may be changed simply by treating the dyed hair with an acid treatment composition at any time after the first dyeing treatment. If desired by the consumer, the colour may be returned to substantially the original post dye colour by treating the hair further with an alkaline treatment composition.
    Type: Grant
    Filed: November 26, 2004
    Date of Patent: April 3, 2007
    Assignees: Kao Corporation, Fuji Photo Film Co., Ltd.
    Inventors: Dominic Pratt, Masayoshi Nojiri, Toshio Kawagishi
  • Patent number: 7189266
    Abstract: The present disclosure relates to a composition for dyeing human keratin fibers, such as the hair, comprising, in a medium suitable for dyeing, at least one direct dye and at least on dicationic compound. Also disclosed herein is a process for dyeing and lightening human keratin fibers, such as the hair, with the compositions disclosed, as well as a the corresponding dyeing kits.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: March 13, 2007
    Assignee: L'Oreal, S.A.
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7172631
    Abstract: The present disclosure relates to a dyeing composition for human keratinous fibers, such as the hair, comprising, in a suitable dyeing medium, at least one oxidation dye, and at least one dicationic compound. The disclosure further relates to the dyeing methods and dyeing kit using the dye composition.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: February 6, 2007
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7108726
    Abstract: The invention concerns a direct dyeing composition for keratinous fibres, in particular for human keratinous fibres and more particularly hair, comprising, in a medium suitable for dyeing, at least a direct colouring agent, and furthermore at least a cationic associative polyurethane. The invention also concerns dyeing methods and devices using said composition.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: September 19, 2006
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Roland De La Mettrie
  • Patent number: 7101406
    Abstract: The subject of the present application is a dyeing composition for dyeing keratinous fibers, in particular human keratinous fibres such as hair, comprising, in an appropriate dyeing medium, at least one cationic tertiary para-phenylenediamine containing a pyrrolidine ring, and at least one cationic direct dye comprising at least one heterocyclic group. The subject of the invention is also the dyeing method using this composition and the corresponding devices.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: September 5, 2006
    Assignee: L'Oreal
    Inventors: Jean Cotteret, Alain Lagrange
  • Patent number: 7083655
    Abstract: The present invention is directed to a hair dyeing composition comprising at least one azo dye of the following general formula (1): A—N=N—B??(1) where A=monovalent, optionally substituted heterocyclic group binding via the carbon atom to the azo group, that does not contain carboxy (—CO2H) or sulfo groups (SO3H) or quaternary ammonium groups and B=heterocyclic, aromatic or alkyl group containing a dissociative proton and, which is free of carboxy (—CO2H) or sulfo groups (—SO3H) or quaternary ammonium groups. Additionally, the present invention describes a method of dyeing human or animal hair by using such a dye and the use of this direct azo dye for dyeing human or animal hair. The use of this direct azo dye can impart the hair with an extremely vivid colour and has a less colour fade over the time.
    Type: Grant
    Filed: May 28, 2003
    Date of Patent: August 1, 2006
    Assignees: Kao Corporation, Fuji Photo Film Co., Ltd.
    Inventors: Dominic Pratt, Toshio Kawagishi
  • Patent number: 7077873
    Abstract: A subject-matter of the disclosure is a novel composition for the dyeing of human keratinous fibres, for example, the hair, comprising a monocationic monoazo dye of formula (I) W1-N?N—W2-NW3-W4-W5, the dyeing processes employing it, the use of the dyes of formula (I) as direct dyes and the novel compounds of formula (I).
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: July 18, 2006
    Assignee: L'Oréal, SA
    Inventors: Hervé David, Nathalie Berteuil, Laurent Vidal
  • Patent number: 7056346
    Abstract: The present invention relates to a composition comprising, in a cosmetically acceptable support suitable for dyeing the hair, at least one direct dye and at least one crosslinked polymer containing acrylic residue units of the structure in which R1 denotes H, CH3 or C2H5, and C10–C30 alkyl acrylate residue units, wherein the composition is a direct dyeing composition for the hair, and wherein said at least one direct dye is an anthraquinone or azo dye which is acidic or cationic.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: June 6, 2006
    Assignee: L'Oreal S.A.
    Inventor: Mireille Maubru
  • Patent number: 7056355
    Abstract: The present invention is directed to a hair dyeing composition containing a dissociative azo dye of the following general formula (1) A-N?N—B??(1) wherein “A” represents a phenyl or naphthyl group which may be substitued; “B” represents an atomic group containing a dissociative proton, with the proviso “A” and “B” are free of sulfo, carboxyl and quaternary ammonium groups. Additionally, the present invention describes a method of dyeing human or animal hair by using such a dye and the use of this direct azo dye for dyeing human or animal hair. The use of this direct azo dye can impart the hair with an extremely vivid color and has less color fading over time.
    Type: Grant
    Filed: September 15, 2003
    Date of Patent: June 6, 2006
    Assignees: Kao Corporation, Fuji Photo Film Co., Ltd.
    Inventors: Dominic Pratt, Toshio Kawagishi
  • Patent number: 7022143
    Abstract: The invention concerns a novel dyeing composition for dyeing keratinous fibers, in particular human hair, comprising a cationic azo-dye of formula (I): W1—N?N—W2—W3, as well as the dyeing method using said composition and the novel compounds of formula (I).
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: April 4, 2006
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 7001436
    Abstract: The invention concerns a dyeing composition for keratinous fibres, in particular human keratinous fibres and more particularly hair, comprising a dicationic diazo dye of formula (I), as well as the dyeing composition using same. The invention also concerns the novel compounds of formula (I).
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: February 21, 2006
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Hervé David
  • Patent number: 6916344
    Abstract: The invention relates to a direct dyeing composition for keratinic fibers, especially human keratinic fibers such as hair, containing at least one direct dye and a thickening polymer with an ether plastic skeleton, in a medium which is suitable for dyeing. The invention also relates to dyeing methods and devices for using the invention composition.
    Type: Grant
    Filed: November 10, 2000
    Date of Patent: July 12, 2005
    Assignee: L'Oreal S.A.
    Inventors: Delphine Allard, Frédéric Legrand
  • Patent number: 6902586
    Abstract: The present invention relates to the use for dyeing keratin fibers, in particular human keratin fibers such as the hair, of a dye precursor bearing at least one phosphate substituent of formula —O—PO(OH)2, in the presence of at least one acid or alkaline phosphatase.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: June 7, 2005
    Assignee: L'Oreal
    Inventors: Rui Pereira, Richard Martin
  • Patent number: 6893471
    Abstract: The invention concerns a dyeing composition for dyeing keratinous fibers, in particular human keratinous fibers and more particularly hair, comprising a dicationic diazo dye of formula W1—N?N—W2—N?N—W3 as well as the dyeing method using same and the novel compounds of formula (I).
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: May 17, 2005
    Assignee: L'Oreal S.A.
    Inventor: Laurent Vidal
  • Patent number: 6884267
    Abstract: The invention concerns a novel dyeing composition for dyeing keratinous fibers, in particular human hair, comprising a cationic azo-dye of formula (I): W1—N?N—W2—W3, as well as the dyeing method using said composition and the novel compounds of formula (I).
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: April 26, 2005
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 6884266
    Abstract: The invention concerns a novel dyeing composition for dyeing keratinous fibers, in particular human hair, comprising a cationic azo dye of formula (I): W1—N?N—W2—NW3W4, and the dyeing method using said composition and the novel compounds of formula (I).
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: April 26, 2005
    Assignee: L'Oreal
    Inventors: Laurent Vidal, Madeleine Leduc
  • Patent number: 6884265
    Abstract: The invention concerns a novel dyeing composition for dyeing keratinous fibers, in particular human hair, comprising a dicationic diazo dye of formula (I): W1—W2—N?N—W3—L—W4—N?N—W5—W6, as well as the dyeing method using said composition and the novel compounds of formula (I).
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: April 26, 2005
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Madeleine Leduc
  • Patent number: 6881230
    Abstract: The invention concerns a novel dyeing composition for dyeing keratinous fibers, in particular human hair, comprising a cationic azo-dye of formula (I): W1-N?N-W2-W3, as well as the dyeing method using said composition and the novel compounds of formula (I).
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: April 19, 2005
    Assignee: L'Oreal S.A.
    Inventor: Laurent Vidal
  • Patent number: 6824570
    Abstract: A dye composition for dyeing human keratin fibers, such as hair, comprising at least one monocationic monoazo dye of formula (I) W1—W2—N═N—W3, a dyeing process using the composition and certain novel compounds of formula (I).
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: November 30, 2004
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 6773463
    Abstract: The present invention relates to a fiber-dyeing agent (A) prepared by mixing two components (A1) and (A2), said agent being characterized in that component (A1) contains at least one compound of formula (I) wherein X denotes a halogen atom, a methoxy group or an ethoxy group; Y denotes an oxygen atom, a sulfur atom or a selenium atom; R1 and R2 are equal or different and independently of each other denote hydrogen, a halogen atom, a (C1-C4)-alkyl group, a halogen-substituted (C1-C4)-alkyl group, a (C1-C4)-alkoxy group, a nitro group, an acetamido group or an NRaRb group, wherein the Ra and Rb groups are equal or different and independently of each other denote hydrogen, a (C1-C4)-alkyl group, an optionally substituted aromatic carbon ring or a (C1-C4)-alkanecarbonyl group, or Ra and Rb together with the nitrogen atom form a heterocyclic (C3-C6) group, and component (A2) contains at least one compound from the group consisting of amines, aminonitrobenzenes and phenols; to a method for dyeing
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: August 10, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Cécile Pasquier, Véronique Charrière, Hans-Jürgen Braun
  • Patent number: 6749645
    Abstract: The object of the present invention is the use of 4-nitro-2,1,3-benzoxadiazole derivatives of general formula (I) as dye in colorants for keratin fibers such as, for example, wool, silk, furs or hair and particularly human hair In formula (I) X denotes oxygen, sulfur or NRa, Ra standing for hydrogen, a (C1-C4)-alkyl group, a monohydroxy-(C1-C4)-alkyl group, a polyhydroxy-(C2-C4)-alkyl group or a mono-(C1 C4)-alkoxy-(C1-C4)-alkyl group, R1 and R2 can be equal or different and independently of each other denote hydrogen, a halogen atom, a (C1-C4)-alkyl group, a halogen-substituted (C1-C4)-alkyl group, a (C1-C4)-alkoxy group, a nitro group or an NRbRc group, the Rb and Rc groups being equal or different and independently of each other denoting hydrogen, a (C1-C4)-alkyl group, an optionally substituted aromatic carbon ring or a (C1-C4)-alkanecarbonyl group, or Rb and Rc together with the nitrogen atom forming a heterocyclic (C3-C6) group, and Q denotes hydrogen, an aliphatic group, an aromati
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: June 15, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Cécile Pasquier, Véronique Charrière, Hans-Juergen Braun
  • Publication number: 20040055097
    Abstract: The present invention relates to an azo dye of formula (1), wherein R1 is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, thiadiazole, indazole, benzatriazole, pyrazole, anthraquinone, naphtholic acid imide, chromone, phthalimide or diphenylene oxide series, R2 is an unsubstitued or substitued aryl radical or an unsubstituted or substituted aralkyl radical and R3 is an unsubstituted or substituted aryl radical or an unsubstituted or substituted aralkyl radical, with the proviso that one of the substituents R2 and R3 is an unsubstituted or substituted aryl radical and the other is an unsubstituted or substituted aralkyl radical, 2-hydroxy-2-phenylethyl being expected as a substituted aralkyl radical, to mixtures comprising at least two structually different azo dyes of formula (1) and to the use of those azo dyes and dye mixtures in the dyeing or printing of semi-synthetic or synthetic hydrophobic fibre materials.
    Type: Application
    Filed: July 23, 2003
    Publication date: March 25, 2004
    Inventors: Yvonne Pichler, Urs Lauk
  • Patent number: 6689173
    Abstract: Provided is a hair dye composition containing a direct dye (1). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye even after storage. wherein, R1 to R4 each represents a (substituted) C1-6 alkyl group, (substituted) alkenyl group or (substituted) aryl group or R3 and R4, when taken together with the adjacent C, form a 5 to 12 membered ring, R5 represents H, (substituted) C1-6 alkyl group, (substituted) alkenyl group, (substituted) aryl group or acyl group, X1 and X2 each represents H or halogen atom, Y1 and Y2 each represents H, (substituted) C1-6 alkyl group, (substituted) alkenyl group, (substituted) C1-6 alkoxy group or halogen atom, Z1 and Z2 each represents H, (substituted) C1-6 alkyl group, (substituted) alkenyl group, (substituted) C1-6 alkoxy group, nitro group or halogen atom, and A− represents an anion.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: February 10, 2004
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga, Shintaro Totoki, Yoshinori Saito
  • Patent number: 6623531
    Abstract: The invention relates to a hair dye composition having markedly high dyeing power, less color fade over time, and undergoes a small change in the color tone of the dye even after storage.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: September 23, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga
  • Patent number: 6616708
    Abstract: Provided is a hair dye composition containing a direct dye (1), (2) or (3). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye even after storage. wherein, R1 represents a (substituted) aryl group, R2, R4 to R6, R8 and R9 each represents H, a (substituted) C1-6 alkyl group or a (substituted) aryl group, R3 and R7 each represents a (substituted) aryl group, R10 to R12 each represents a (substituted) C1-6 alkyl or (substituted) aryl group, rings A to G each represents a benzene ring which may be substituted by a (substituted) amino group, (substituted) C1-6 alkyl group, C1-6 alkoxy group or halogen atom or may further be cyclocondensed with a benzene ring, and X− represents an anion.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: September 9, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga
  • Publication number: 20030145396
    Abstract: Dye mixtures including one or more azo dyes of the general formula (1) and one or more azo dyes of the general formula (2) 1
    Type: Application
    Filed: September 30, 2002
    Publication date: August 7, 2003
    Inventors: Joachim Steckelberg, Werner Russ
  • Patent number: 5908775
    Abstract: The invention provides a method of textile printing using microorganisms with less limitation to dyes with less damage on base materials, and with less blurring of color borders. The method is capable of producing a complex, fine pattern; capable of realizing colored discharge printing with brilliant colors; and capable of readily producing an ombre pattern. The invention also provides a microorganism for decolorization of azo-system dye and use in the textile printing method. In accordance with the invention, textile printing is carried out by coating a solution or paste (which may contain a dye) containing a bacterial strain Bacillus OY1-2 of genus Bacillus (Deposit Number: FERM 13118), in a desirable pattern on the cloth dyed with an azo dye (which may include a non-azo dye), subsequently proliferating or acting the bacterial strain while keeping the strain in a wet state, and to entirely or partially metabolize the azo dye to eliminate or decrease the coloring of the azo dye for textile printing.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: June 1, 1999
    Assignees: Okasa Prefecture, Yushiro Chemical Industry Co., Ltd.
    Inventors: Wataru Sugiura, Keiko Nagai, Tadashi Yokoyama
  • Patent number: 5872002
    Abstract: The invention provides a method of textile printing using microorganisms with less limitation to dyes with less damage on base materials, and with less blurring of color borders. The method is capable of producing a complex, fine pattern; capable of realizing colored discharge printing with brilliant colors; and capable of readily producing an ombre pattern. The invention also provides a microorganism for decolorization of azo-system dye and use in the textile printing method.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: February 16, 1999
    Assignee: Yushiro Chemical Industry Co., Ltd.
    Inventors: Wataru Sugiura, Keiko Nagai, Tadashi Yokoyama
  • Patent number: 5869322
    Abstract: The invention provides a method of textile printing using microorganisms with less limitation to dyes, with less damage on base materials, and with less blurring of color borders. The method is capable of producing a complex, fine pattern; capable of realizing colored discharge printing with brilliant colors; and capable of readily producing an ombre pattern. The invention also provides a microorganism for decolorization of azo-system dye and use in the textile printing method.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: February 9, 1999
    Assignee: Yushiro Chemical Industry Co., Ltd.
    Inventors: Wataru Sugiura, Keiko Nagai, Tadashi Yokoyama
  • Patent number: 4859207
    Abstract: A process for dyeing textile planar fabrics made from natural or synthetic polyamides with anionic dyes by(a) locally applying a resist agent by itself or in conjunction with an anionic dye of fluorescent whitening agent,(b) subjecting the textiles to a heat treatment, and(c) carrying out ground dyeing with a dye liquor that contains a further anionic dye,which process comprises using, as resist agent, a melamine compound of formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently phenyl or naphthyl, each of which may be substituted by halogen, hydroxy, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, Z is an acid water-solubilizing group, and m is 1 to 6.
    Type: Grant
    Filed: July 19, 1988
    Date of Patent: August 22, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Thys Bouwknegt, Heinz Abel
  • Patent number: 4571246
    Abstract: An improved process for production of discharge resist prints on textile material which contain hydrophobic fibers wherein at least one disperse dyestuff dischargeable to white discharge-resistant disperse dyestuff is applied, in the form of a dye liquor or printing paste, to the textile material and a discharge resist printing paste is printed on the material in the desired pattern, and the material is subsequently subjected to heat treatment at 100.degree. to 230.degree. C., wherein the improvement comprises the discharge resist printing paste containing, as the discharging agent, at least one salt of hydrogen sulphide, polysulphanes, compounds have a thiolate group of the formula --S.sup..crclbar. or a tautomerizable thio-group of the formula .dbd.S, and mixtures thereof.
    Type: Grant
    Filed: September 17, 1984
    Date of Patent: February 18, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Theo Stahl, Konrad Mix, Kurt Roth
  • Patent number: 4386935
    Abstract: An improved process for producing discharge reserve prints on textile materials comprising water-repellent fibers or mixed water-repellent and cellulose fibers wherein a disperse dyestuff which is dischargeable to white is applied to the textile material in the form of a dye liquor or dye printing paste, at least partially drying the textile material, applying a discharge reserve printing paste to the material by printing on the material in the desired pattern and subsequently heating the printed material at temperatures from 100.degree. to 230.degree. C., with the improvement comprising (a) the discharge reserve printing paste containing, as the discharging agent, an alkaline material which produces a pH value of at least 8 in 5% strength aqueous solution and (b) the disperse dyestuff which is dischargeable to white is a disperse dyestuff of the formula ##STR1## as more fully defined herein.
    Type: Grant
    Filed: September 28, 1981
    Date of Patent: June 7, 1983
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Klaus Kuhlein, Theo Stahl, Horst Tappe, Kurt Roth
  • Patent number: 4313731
    Abstract: Mono-azo compounds and mono-azo dyes represented by the following general formula and a dyeing process for polyester fibers using the mono-azo dyes: ##STR1## wherein R.sup.1 and R.sup.2 individually represent hydrogen atom, substituted or non-substituted alkyl group, alkenyl group and cyclohexyl group, R.sup.3 represents hydrogen atom, chlorine atom, bromine atom, alkyl group, substituted or non-substituted alkoxy group or alkenyl group and R.sup.4 represents hydrogen atom, chlorine atom, bromine atom, alkyl group, alkoxy group, hydroxy group, acylamino group, alkoxycarbonylamino group, aralkyloxycarbonylamino group or alkylaminocarbonylamino group.
    Type: Grant
    Filed: September 12, 1980
    Date of Patent: February 2, 1982
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Seiichi Imahori, Kiyoshi Himeno, Maeda, Shuichi
  • Patent number: 4268600
    Abstract: A photochemical color-printing process for textile articles wherein a photosensitive triazene and azo dye coupling agent are applied to surface of textile article, the coated textile is exposed to light with a negative image, unreacted chemical products are removed by washing and rinsing the coated textile article after imaging, and then the coated textile article is dried.
    Type: Grant
    Filed: December 1, 1978
    Date of Patent: May 19, 1981
    Assignee: Issec and Tissages de Soieries Rennis
    Inventors: Jean J. Robillard, Claude R. Riou
  • Patent number: 4265629
    Abstract: In the process for production of resist effects on textile materials of mixed fibers of polyester and cellulose comprising impregnating the materials with a dye liquor containing disperse dyestuffs and reactive dyestuffs which react with the resisting agents, drying or partially drying the padded materials and subsequently printing a resist paste on the material, and heat-treating the materials the improvement comprises the dischargeable disperse dyestuffs being of a class of dyestuffs of which an exemplary species is ##STR1## one of the tautomeric forms of a class of dyestuffs of which an exemplary species is ##STR2## or disperse dyestuffs which are free from groups conferring solubility in water and which contain at least two carboxylic acid ester moieties.
    Type: Grant
    Filed: December 19, 1979
    Date of Patent: May 5, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventors: Joachim Ribka, Horst Tappe, Kurt Roth, Hans-Jurgen Weyer