Basic Dye, Including Diphenylmethane, Triphenylmethane, Xanthene, Fluorene, Methine, Acridine, Oxazine, Phenazine, Flavylium, Naphthoperinone, Quinophthalone, Quaternary Ammonium Group, Etc., Containing Patents (Class 8/462)
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Patent number: 8613778Abstract: The present invention is related to an oxidative colouring composition for keratin fibres especially human hair. The present invention is a composition comprising at least one hair dye and at least one magnesium salt. Furthermore, it is the use of at least one magnesium salt in a composition comprising at least one hair dye for preventing warming up and increase of its volume upon mixing with an aqueous composition comprising at least one oxidizing agent. Present invention is at the same time on the process for colouring keratin fibres with the use of the compositions.Type: GrantFiled: December 23, 2011Date of Patent: December 24, 2013Assignee: KAO Germany GmbHInventors: Jonathan Wood, Sabine Schäfer
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Patent number: 8066782Abstract: The invention relates to the dyeing of keratin fibres using azomethine direct dyes or precursors of azomethine dyes obtained from 2-alkylresorcinols. The invention relates to a dye composition comprising at least one azomethine direct dye or pre-cursor of an azomethine direct dye, to a process for dyeing keratin fibres, using the said composition, and to their uses in the dyeing of keratin fibres. This composition allows a particularly stable and fast coloration to be obtained.Type: GrantFiled: December 9, 2008Date of Patent: November 29, 2011Assignee: L'Oreal S.A.Inventors: Madeleine Leduc, Eric Metais, Stéphane Sabelle, Christophe Rondot
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Patent number: 8025704Abstract: Agent having at least one non-ionic component having an HLB of 8.0 or less are disclosed, as well as the combination of a blue and red substantive dye wherein the weight ratio of the blue dyes as opposed to the red dyes is 1 or greater. Further disclosed are agents for dyeing human hair blond having at least one oxidizing agent preparation and optionally a bleaching force reinforcing preparation. The agents make it possible to avoid undesired color shifts towards yellow or red nuances during blond hair dyeing.Type: GrantFiled: February 8, 2011Date of Patent: September 27, 2011Assignee: Henkel AG & Co. KGaAInventor: Hartmut Manneck
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Patent number: 7935154Abstract: Provided is a process for lightening or dyeing keratin fibers, including human keratin fibers such as the hair, in the presence of an oxidizing agent, wherein the following are applied to the keratin fibers: (a) an anhydrous cosmetic composition (A) comprising at least one fatty substance and at least one surfactant, (b) a cosmetic composition (B) comprising at least one organic amine with a pKb of less than 12 at 25° C. and at least one mineral base, and (c) a composition (C) comprising at least one oxidizing agent; when the process described herein is a process for dyeing keratin fibers, composition (B) further comprises at least one dye. Also provided is a multi-compartment device comprising a first compartment having the anhydrous cosmetic composition, a second compartment having at least one organic amine with a pKb of less than 12 at 25° C., and also at least one mineral base and optionally at least one dye, and a third compartment having an oxidizing composition.Type: GrantFiled: December 18, 2009Date of Patent: May 3, 2011Assignee: L'Oreal S.A.Inventors: Leïla Hercouet, Alain Lagrange
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Patent number: 7931696Abstract: Disclosed are dyes of formula wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine, perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; and Q is defined herein.Type: GrantFiled: January 22, 2008Date of Patent: April 26, 2011Assignee: BASF SE LudwigshafenInventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7922777Abstract: The present disclosure relates to a process for lightening human keratin fibers using at least one anhydrous composition (A) comprising at least one fatty substance, at least one surfactant, monoethanolamine and at least one basic amino acid, and at least one composition (B) comprising at least one oxidizing agent. The disclosure relates to a multi-compartment device comprising the abovementioned compositions (A) and (B).Type: GrantFiled: December 18, 2009Date of Patent: April 12, 2011Assignee: L'Oréal S.A.Inventors: Leïla Hercouet, Alain Lagrange, Frédéric Simonet
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Patent number: 7918902Abstract: The present disclosure relates to a process for lightening or dyeing keratin fibers, for example, human keratin fibers such as the hair, comprising applying to the keratin fibers: (a) an anhydrous cosmetic composition (A) comprising at least one fatty substance and at least one surfactant; (b) a cosmetic composition (B) comprising at least one ammonium salt; and (c) a composition (C) comprising at least one oxidizing agent; when the process is a process for dyeing keratin fibers, said cosmetic composition (B) further comprises at least one oxidation dye and/or at least one direct dye. The present disclosure also relates to a multi-compartment device comprising the disclosed compositions for lightening or dyeing keratin fibers.Type: GrantFiled: December 18, 2009Date of Patent: April 5, 2011Assignee: L'Oreal S.A.Inventors: Leïla Hercouet, Alain Lagrange
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Patent number: 7909888Abstract: Provided is a process for dyeing or lightening human keratin fibers, comprising applying to the keratin fibers: a) at least one anhydrous composition (A) comprising at least one fatty substance and at least one surfactant; b) at least one composition (B) comprising monoethanolamine and at least one basic amino acid; and c) at least one composition (C) comprising at least one oxidizing agent; provided that when the process is a dyeing process, the at least one anhydrous composition (A) is free from organic amines and the at least one composition (B) comprises at least one oxidation dye and/or at least one direct dye fiber.Type: GrantFiled: December 18, 2009Date of Patent: March 22, 2011Assignee: L'OrealInventors: Leïla Hercouet, Alain Lagrange, Marie Giafferi
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Patent number: 7909887Abstract: A novel process for dyeing human keratin fibers in the presence of an oxidizing agent, comprising applying to the fibers at least one anhydrous composition (A) comprising at least one fatty substance, at least one organic amine having a pKb less than 12 at 25° C., and at least one surfactant, at least one composition (B) comprising at least one oxidizing agent, and at least one composition (C) comprising at least one dye chosen from oxidation dyes and direct dyes; a multi-compartment device or kit, wherein at least one first compartment comprises the at least one anhydrous cosmetic composition (A), at least one second compartment comprises at least one composition (B), and at least one third compartment comprises at least one composition (C); and a ready-to-use composition for dyeing human keratin fibers, comprising at least 35% by weight of at least one fatty substance, at least one organic amine having a pKb less than 12 at 25° C.Type: GrantFiled: December 19, 2008Date of Patent: March 22, 2011Assignee: L'Oreal S.A.Inventor: Leïla Hercouet
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Patent number: 7901465Abstract: An oil-in-water type one-part hair dye composition containing components (A), (B), (C) and (D); (A) a direct dye; (B) a hydrocarbon oil; (C) a polyoxyalkylene-modified dimethylpolysiloxane with an HLB of 7 or higher; and (D) an aromatic alcohol; wherein the content ratio by mass of the component (B) to the component (C), (B)/(C) is 0.05 to 10.Type: GrantFiled: August 31, 2007Date of Patent: March 8, 2011Assignee: Kao CorporationInventors: Noboru Chiba, Hiroko Okabe
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Patent number: 7901464Abstract: A process for dyeing human keratin fibers in the presence of at least one oxidizing agent, comprising applying to the fibers at least one anhydrous composition (A) comprising at least one fatty substance and at least one surfactant, at least one composition (B) comprising at least one oxidizing agent, and at least one composition (C) comprising at least one dye chosen from direct and oxidation dyes, and at least one organic amine having a pKb at 25° C. of less than 12. The present disclosure also relates to a multi-compartment device containing, in separate compartments, the compositions (A), (B), and (C); and a method of making a ready-to-use composition. The present disclosure also relates to an anhydrous composition comprising at least one fatty substance, at least one surfactant, at least one dye, and at least one organic amine.Type: GrantFiled: December 19, 2008Date of Patent: March 8, 2011Assignee: L'Oreal S.A.Inventors: Leïla Hercouet, Marie Giafferi, Alain Lagrange
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Patent number: 7896931Abstract: The present invention relates to a hair dye composition containing a dissociative azo dye which has high dyeing power, is capable of imparting a vivid color to the hair firmly, has excellent fastness to light, shampooing, sweat, friction, and heat, and fades less with the passage of time because the dye is stable against an alkali agent or an oxidizing agent and does not decompose during hair dyeing; and a hair dyeing method using the hair dye composition.Type: GrantFiled: June 27, 2008Date of Patent: March 1, 2011Assignees: Kao Corporation, FUJIFILM CorporationInventors: Masakazu Yamaguchi, Osamu Takiguchi, Masaaki Tsukase, Yasuhiro Ishiwata
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Patent number: 7771490Abstract: Disclosed are thiol dyes of formula (I), wherein R1, R2, R3, R4 and R5 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); A is a residue of an organic dye; and Y1 is the direct bond; C1C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene). The compounds are used to dye hair with or without reducing agents. Furthermore, the present invention relates to compositions comprising thiol dyes of formula (I) and to process for the preparation of theses compounds.Type: GrantFiled: August 21, 2006Date of Patent: August 10, 2010Assignee: Ciba CorporationInventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7731762Abstract: A dye composition is provided and includes a non-aqueous dye and an ionic liquid. A dyeing method is provided and includes a process of applying the dye composition to an object, and a process of removing fluidity of the dye composition.Type: GrantFiled: March 8, 2006Date of Patent: June 8, 2010Assignee: Fujifilm CorporationInventor: Yoshio Inagaki
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Patent number: 7722680Abstract: The subject of the present invention is the use, for dyeing in particular human keratin materials, of a direct dye, in particular an azo dye, by dry thermal transfer. Its subject is furthermore a method for dyeing keratin materials, n which at least one direct dye, in particular one azo dye, contained in a dry composition, is applied to or close to the keratin materials, and a source of heat is applied, causing the thermal transfer of the direct dye(s) at the surface and/or inside the keratin materials. It relates furthermore to the dry composition and a method for preparing it.Type: GrantFiled: February 11, 2006Date of Patent: May 25, 2010Assignee: L'Oreal S.A.Inventors: Grégory Plos, Luc Gourlaouen, Jean-Dominique Bazin De Bezons
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Patent number: 7704284Abstract: Disclosed are compounds of formula (1a), wherein R1 is N+R8R9; R8 and/or R9 independently from each other are hydrogen; C1-C12alkyl; or phenyl-C1-C4-alkyl; or R8 and/or R9 are a bivalent C3-C6alkylene radical which is linked to the carbon atoms C1 or C2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R2 is NR10R11; or OR10; R10 and R11, independently from each other are hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; or R10 and/or R11 are a bivalent C3-C6alkylene radical which is linked to the carbon atoms C3 or C4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16-membered carbocyclic ring; or R10 and R11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R3, R4, R5, R6 and R7 independently form each other are hydrogen; C1-C12alkyl; halogen; NR12R13; or a radical of formula (1a); R12 and R13 independently from each other are hydrogen; C1-C12alkyl; phenyl-C1-C4alkyl; or a radical of formula (1a2); VType: GrantFiled: September 25, 2006Date of Patent: April 27, 2010Assignee: Ciba CorporationInventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7655052Abstract: Disclosed herein is the use, in the coloring of keratinous fibers, for example human keratinous fibers, such as the hair, of a composition comprising at least one compound chosen from the compounds of formula (I) comprising a cyclic group G including a ring H capable of opening, the dyes corresponding to the compounds of formula (I) wherein the ring H is open and the addition salts thereof: and a method for treating keratinous fibers employing this composition.Type: GrantFiled: March 20, 2008Date of Patent: February 2, 2010Assignee: L'Oreal S.A.Inventors: Alain Lagrange, Frédéric Guerin
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Patent number: 7645304Abstract: The subject of the present invention is the use, for dyeing in particular human keratin materials, of a specific direct azomethine dye, by dry thermal transfer. Its subject is furthermore a method for dyeing keratin materials, in which at least one direct azomethine dye contained in a dry composition, is applied to or close to the keratin materials, and a source of heat is applied, causing the thermal transfer of the direct dye(s) at the surface and/or inside the keratin materials. It relates furthermore to the dry composition and a method for preparing it.Type: GrantFiled: February 28, 2006Date of Patent: January 12, 2010Assignee: L'Oreal S.A.Inventors: Grégory Plos, Luc Gourlaouen, Jean-Dominique Bazin De Bezons
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Patent number: 7641703Abstract: Disclosed herein is the use, in the coloring of keratinous fibers, such as human keratinous fibers, such as the hair, of a composition comprising at least one compound chosen from the compounds of formula (I) comprising a cyclic group G including a ring H capable of opening, the dyes corresponding to the compounds of formula (I) wherein the ring H is open, and the addition salts thereof: and a method for treating keratinous fibers employing this composition.Type: GrantFiled: March 20, 2008Date of Patent: January 5, 2010Assignee: L'Oreal S.A.Inventors: Frédéric Guerin, Alain Lagrange
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Patent number: 7338535Abstract: Disclosed herein is a rapid dyeing process for human keratin fibers, such as hair, comprising applying to the keratin fibers at least one dye composition comprising, in a medium suitable for dyeing, at least one direct dye chosen from arylmethane dyes, cationic azo dyes, methine dyes, azomethine dyes and azine dyes; maintaining the composition in contact with the keratin fibers for a leave-in time of less than 5 minutes; and rinsing the treated keratin fibers; wherein the resulting coloration has, according to the CIELAB notation, an L* value of less than 40 and/or a C* value of greater than 20, such as greater than 25, when the composition is applied to natural hair containing 90% white hairs at a temperature of 27° C.±5° C. for a period of 4 minutes, for a bath ratio of 10. Further disclosed herein is a process for stripping the keratin fibers colored with the direct dye, comprising applying an oxidizing or reducing treatment in a time period of less than 5 minutes.Type: GrantFiled: October 21, 2003Date of Patent: March 4, 2008Assignee: L'Oreal S.A.Inventors: Grégory Plos, Frédéric Guerin
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Patent number: 7294152Abstract: The present disclosure relates to a specific direct dye compound that is a fluorindine derivative, and dyeing compositions comprising at least one derivative of the compound and at least one polymer. A process for dyeing keratin fibers with the defined compositions is also disclosed.Type: GrantFiled: January 7, 2005Date of Patent: November 13, 2007Assignee: L'Oreal S.A.Inventor: Alain Lagrange
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Patent number: 7156884Abstract: Pro-dyes of direct dyes having an enzymatically-labile functionality, e.g. glutaramide derivatives of direct dyes of formula (I) or their physiologically acceptable salts, are described, as well as compositions for dyeing keratinous fibers containing these pro-dyes, as well as compositions for dyeing keratinous fibers containing a combination of at least one pro-dye and at least one enzyme capable of cleaving the glutaramide functionality in the pro-dye. A method for dyeing keratinous fibers with the aforementioned dyeing compositions is also described.Type: GrantFiled: February 20, 2003Date of Patent: January 2, 2007Assignee: Wella AGInventors: David Rozzell, Juergen Allwohn, Laurent Chassot, Cècile Pasquier, Guido Sauter, Vèronique Buclin-Charrière
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Patent number: 6908491Abstract: A method for color-revitalizing a color tone of hair that involves applying a color-revitalizing composition to hair previously dyed with an oxidative hair dye composition. The color-revitalizing composition, which has a color determined by the color of the oxidative hair dye composition and contains at least one direct dye, revitalizes the color tone originally obtained by after dyeing with the oxidative hair dye composition.Type: GrantFiled: October 23, 2001Date of Patent: June 21, 2005Assignee: The Andrew Jergens CompanyInventors: Vince Fischer, Masahiko Sakai, Satoshi Onitsuka, Hajime Miyabe, Hiroshi Ikeda, David Ferguson
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Patent number: 6878169Abstract: Provided is a hair dye composition containing a direct dye (1): [wherein, R1, R2, R3, R4, R5 and R6 each represents a C1-6 alkyl group; R7 and R8 each represents a hydroxy group, a C1-6 alkyl group, a C1-6 alkoxy group, an amino group or alkylamino groups; R9 represents a hydrogen atom or a C1-6 alkyl group; and X? represents an anion]. This hair dye composition undergoes a small change in color tone even after storage because it contains the direct dye (1) which has high stability against any one of an alkali agent, oxidizing agent and reducing agent, and at the same time, has markedly high hair dyeing power and exhibits excellent light resistance, washing resistance, perspiration resistance, friction resistance and heat resistance.Type: GrantFiled: December 16, 2002Date of Patent: April 12, 2005Assignee: Kao CorporationInventor: Kenichi Matsunaga
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Patent number: 6814762Abstract: Provided is a hair dye composition containing a direct dye (1) or (2): [wherein, R1, R2, R3, R4, R5 and R6 each represents a C1-6 alkyl group; R7 and R8 each represents a hydrogen atom, a hydroxy group, a C1-6 alkyl group, a C1-6 alkoxy group, an amino group or alkylamino group; R9 represents a hydrogen atom or a C1-6 alkyl group; and X− represents an anion]. This hair dye composition undergoes a small change in color tone even after storage because it contains the direct dye (1) or (2) which has high stability against any one of an alkali agent, oxidizing agent and reducing agent, and at the same time, has markedly high hair dyeing power and exhibits excellent light resistance, washing resistance, perspiration resistance, friction resistance and heat resistance.Type: GrantFiled: December 16, 2002Date of Patent: November 9, 2004Assignee: Kao CorporationInventor: Kenichi Matsunaga
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Patent number: 6773463Abstract: The present invention relates to a fiber-dyeing agent (A) prepared by mixing two components (A1) and (A2), said agent being characterized in that component (A1) contains at least one compound of formula (I) wherein X denotes a halogen atom, a methoxy group or an ethoxy group; Y denotes an oxygen atom, a sulfur atom or a selenium atom; R1 and R2 are equal or different and independently of each other denote hydrogen, a halogen atom, a (C1-C4)-alkyl group, a halogen-substituted (C1-C4)-alkyl group, a (C1-C4)-alkoxy group, a nitro group, an acetamido group or an NRaRb group, wherein the Ra and Rb groups are equal or different and independently of each other denote hydrogen, a (C1-C4)-alkyl group, an optionally substituted aromatic carbon ring or a (C1-C4)-alkanecarbonyl group, or Ra and Rb together with the nitrogen atom form a heterocyclic (C3-C6) group, and component (A2) contains at least one compound from the group consisting of amines, aminonitrobenzenes and phenols; to a method for dyeingType: GrantFiled: April 5, 2002Date of Patent: August 10, 2004Assignee: Wella AktiengesellschaftInventors: Cécile Pasquier, Véronique Charrière, Hans-Jürgen Braun
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Patent number: 6749645Abstract: The object of the present invention is the use of 4-nitro-2,1,3-benzoxadiazole derivatives of general formula (I) as dye in colorants for keratin fibers such as, for example, wool, silk, furs or hair and particularly human hair In formula (I) X denotes oxygen, sulfur or NRa, Ra standing for hydrogen, a (C1-C4)-alkyl group, a monohydroxy-(C1-C4)-alkyl group, a polyhydroxy-(C2-C4)-alkyl group or a mono-(C1 C4)-alkoxy-(C1-C4)-alkyl group, R1 and R2 can be equal or different and independently of each other denote hydrogen, a halogen atom, a (C1-C4)-alkyl group, a halogen-substituted (C1-C4)-alkyl group, a (C1-C4)-alkoxy group, a nitro group or an NRbRc group, the Rb and Rc groups being equal or different and independently of each other denoting hydrogen, a (C1-C4)-alkyl group, an optionally substituted aromatic carbon ring or a (C1-C4)-alkanecarbonyl group, or Rb and Rc together with the nitrogen atom forming a heterocyclic (C3-C6) group, and Q denotes hydrogen, an aliphatic group, an aromatiType: GrantFiled: March 26, 2002Date of Patent: June 15, 2004Assignee: Wella AktiengesellschaftInventors: Cécile Pasquier, Véronique Charrière, Hans-Juergen Braun
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Patent number: 6746492Abstract: A semipermanent hair dye composition comprising (A) a direct dye, (B) a hydrocarbon oil and (C) polyoxyalkylene-modified dimethyl polysiloxane. The semipermanent hair dye composition can uniformly dye hair without coloring the scalp and skin and gives the hair an excellent feel after hair coloring.Type: GrantFiled: December 20, 2001Date of Patent: June 8, 2004Assignee: Kao CorporationInventors: Tetsuya Kawai, Takashi Itou
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Patent number: 6669739Abstract: The object of the present invention is a preparation for coloring fibers, which is prepared before use by mixing an acidic component (A1), containing at least one enamine of Formula (I)/(Ia) with a component (A2), containing a Schiff's base of Formula (II) as well as a method for temporarily coloring fibers, for which the coloration, obtained with the aforementioned coloring agent, can be removed once again at any time by a sulfite-containing decolorizing agent.Type: GrantFiled: December 21, 2001Date of Patent: December 30, 2003Assignee: Wella AktiengesellschaftInventors: Guido Sauter, Hans-Juergen Braun, Nadia Reichlin
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Patent number: 4384869Abstract: A method of bleaching of certain triarylmethane dyes in aqueous systems with low concentration of hypochlorite ion, activated by the presence of bromide ion and ammonium ions. The method is particularly useful in providing a disappearing color signal in the automatic cleaning and sanitizing of toilet bowls with low concentrations of hypochlorite. Compositions and articles for implementing the practice of the method in the automatic cleaning and sanitizing of toilet bowls are also disclosed.Type: GrantFiled: December 23, 1981Date of Patent: May 24, 1983Assignee: The Procter & Gamble CompanyInventor: Louis F. Wong