Coating Or Sizing With Dyeing Process Or Product Patents (Class 8/495)
  • Publication number: 20030204918
    Abstract: A method of changing an existing color on a fabric material involves desizing the fabric material, washing the fabric material with an enzyme, and applying one or more chemical reagents to the fabric material to cause the existing color on the fabric material to change into a different color. Subsequently, a chemical reagent is either sprinkled, or sprayed and sprinkled, onto the fabric. The fabric is then washed with a softening agent.
    Type: Application
    Filed: May 6, 2002
    Publication date: November 6, 2003
    Inventor: Ying-Hsiang Huang
  • Patent number: 6623532
    Abstract: The present invention provides a method of applying ink containing dyes to fabric composed of synthetic and cellulose fibers using an ink-jet system to print the fabric with high color shade depth and brilliancy and ink-jet printed goods obtained by the ink-jet printing method. The fabric composed of cellulose and synthetic fibers is treated with an acidic aqueous dispersion containing cellulose reactive compound, water-soluble polymer and non-water-soluble inactive organic compound with a melting point of 40° C.-150° C. and the fabric is dried before its ink-jet printing with reactive and disperse dyes.
    Type: Grant
    Filed: September 5, 2001
    Date of Patent: September 23, 2003
    Assignee: Seiren Co., Ltd.
    Inventors: Shungaku Nakamura, Ayumi Yamazaki
  • Publication number: 20030121630
    Abstract: Lignin-containing papers are rendered light stable when they contain TiO2 in combination with an amine hindered radical scavenger.
    Type: Application
    Filed: October 8, 2002
    Publication date: July 3, 2003
    Inventors: Zhirun Yuan, John A Schmidt, Peter F McGarry, Cyril Heitner
  • Patent number: 6544299
    Abstract: Colorfastness of cationic dyeable nylon fibers dyed with acid and/or premetalized acid dyes is enhanced and potential water bleed problems can also be overcome by treating the dyed fibers with an acrylic water bleed fixative in conjunction with a traditional cotton water bleed fixative. In a typical procedure, the acrylic fixative is applied first, followed by the nylon fixative or the cotton fixative.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: April 8, 2003
    Assignee: Burlington Industries, Inc.
    Inventor: Michael E. Bell
  • Patent number: 6494924
    Abstract: The dyes have an average particle size within the range from 5 nm to 1 &mgr;m and a variance of less than 50%. They are especially useful for ink-jet ink preparations.
    Type: Grant
    Filed: October 3, 2000
    Date of Patent: December 17, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Auweter, Heribert Bohn, Robert Heger, Dieter Horn, Bernd Siegel, Karl Siemensmeyer
  • Patent number: 6488893
    Abstract: A combination of a semi-soluble methacrylic polymer and a sulfonated naphthalene condensation product, optionally with a semi-soluble or insoluble ethyl methacrylate polymer of high molecular weight, provides improved resistance to staining by acid colorants of fibrous polyamide substrate.
    Type: Grant
    Filed: October 1, 1999
    Date of Patent: December 3, 2002
    Assignee: Trichromatic Carpet Inc.
    Inventors: Yassin M. Elgarhy, Karim Elgarhy
  • Publication number: 20020137415
    Abstract: Semi-bleached to bleached sulfonated aromatic condensation resin alone or in combination with a semi-soluble methacrylic polymer of high molecular weight provides improved resistance to staining by acid colorants in a fibrous polyamide or wool substrate.
    Type: Application
    Filed: March 19, 2002
    Publication date: September 26, 2002
    Inventor: Yassin M. Elgarhy
  • Patent number: 6369023
    Abstract: The use of polyether hydroxycarboxylate copolymers in textile manufacturing and treating processes. The polyether hydroxycarboxylate copolymer has the structure wherein M+ is a cation wherein M is independently selected from the group consisting of hydrogen, ammonia, alkali metals, alkaline earth metals, zinc, copper, organic amines, amino acids, and amino saccharides; R1 is the residue of an ethylenically unsaturated comonomer having at least one functional group which is selected from the group consisting of carboxylic acid, sulfonic acid and phosphonic acid; R2 and R3 are independently selected from the group consisting of hydrogen, and a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms; n is from about 2 to about 100; X1 and X2 are independently 0 or 1; a is from 0 to 100 mole percent; and b is from 100 to 0 mole percent, provided that (a+b) is 100 mole percent.
    Type: Grant
    Filed: January 5, 1999
    Date of Patent: April 9, 2002
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Klein A. Rodrigues, Allen M. Carrier, Michael C. Hazlewood
  • Patent number: 6368361
    Abstract: Tea polyphenol obtained by the extraction from tea has an antibacterial effect. In methods for producing an antibacterial fiber by fixing the tea polyphenol to fiber, the object of the present invention is to provide a process for manufacturing an antibacterial fiber capable of exerting an excellent antibacterial performance without the use of metal chelates potentially causing metal allergy and environmental problems. In order to achieve the above object, the present invention manufactures an antibacterial fiber by a process comprising the steps of contacting fiber with or immersing fiber in an aqueous solution in which a cationic surfactant with a quaternary ammonium salt group, a water-soluble protein, and an alkaline compound are dissolved; and separating said fiber from the aqueous solution, to immerse the fiber in another aqueous solution containing tea polyphenol.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: April 9, 2002
    Assignee: Ito En, Ltd.
    Inventors: Fumihisa Yayabe, Yasuhiko Ikegawa, Shuichi Takahashi, Yukiko Nonaka, Saburo Sugimoto, Kazuhiko Hayashi, Yuji Higashibata
  • Patent number: 6352563
    Abstract: A printed cloth in which a dye is deposited in dots on the cloth to form a desired printed pattern. Said dot deposition is formed in a length of 0.05 to 0.3 mm to the longitudinal direction of the fiber in single fiber unit of the yarn constituting said cloth. A fine printed pattern is deposited clearly in good reproducibility. The printed pattern can be formed by using the dyes of the three primary colors or of the three primary colors and black color. It is preferred that Dyes I , II and III having a perceived chromaticity index (a) and (b) defined in the color range [CIE 1976 (L, a, b) space] on the cloth within the following range are used as said dyes of three primary colors and DyeIV is used as said black dye.
    Type: Grant
    Filed: February 22, 2000
    Date of Patent: March 5, 2002
    Assignee: Kanebo, Ltd.
    Inventors: Kazuo Kusaki, Toshikazu Fuse, Tohru Morita, Toshihiko Ishihara, Kazuyoshi Morimoto, Kazuo Iwata, Michiyo Nishimura
  • Patent number: 6337313
    Abstract: A method to prevent the backstaining of denim during a stonewashing process comprising treating the denim with a solution or dispersion of a hydrophobically modified polymer having a hydrophilic backbone and at least one hydrophobic moiety, wherein said hydrophilic backbone is prepared from at least one monomer selected from the group consisting of ethylenically unsaturated hydrophilic monomer selected from the group consisting of unsaturated C1-C6 acid, amide, ether, alcohol, aldehyde, anhydride, ketone and ester; polymerizable hydrophilic cyclic monomer; non-ethylenically unsaturated polymerizable hydrophilic monomer which is selected from the group consisting of glycerol and other polyhydric alcohols; and combinations thereof, wherein said hydrophilic backbone is optionally substituted with one or more amino, amine, amide, sulfonate, sulfate, phosphonate, hydroxy, carboxyl or oxide groups; wherein said hydrophobic moiety is prepared from at least one hydrophobic monomer or a chain transfer agent, said hydr
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: January 8, 2002
    Assignee: National Starch and Chemical Investment Company
    Inventor: Klein A. Rodrigues
  • Publication number: 20010054209
    Abstract: A method for dyeing cellulosic materials with reactive dye by pretreating the fabric with a polycationic polymeric agent which is desirably also polynucleophilic is disclosed. The agent can be a polyquaternary amine material especially a poly(DADMAC) or polyvinylpyridine, particularly one including nucleophilic sites such as primary amino groups, e.g. polyallylamine/DADMAC copolymers and polyvinylpyridines quaternisied with w-aminoalkyl groups. The dyes can react with the nucleophilic centres so dyebath exhaustion can be driven by dye fixation rather than substantivity to the substrate. The need to use of salts to drive substantivity can be obviated and post dyeing washing to remove unreacted/hydrolysed dye is much simplified. Material dyed by the method has the good wash fastness properties of materials dyed using reactive dyes. A wide variety of cellulosic substrates can be dyed including lyocell fibre materials and blend/union materials with polyamides.
    Type: Application
    Filed: August 23, 1999
    Publication date: December 27, 2001
    Inventors: GEOFFREY WILLIAM COLLINS, STEPHEN MARTIN BURKINSHAW, ROY GORDON
  • Patent number: 6332293
    Abstract: A launderable dust control mat having antimicrobial properties is provided. The mat includes a pile fiber upper surface and a rubber backing surface. Metal based antimicrobial agent, are disposed within both the fiber forming the upper surface and the rubber forming the backing surface thereby providing antimicrobial character to the mat as a whole.
    Type: Grant
    Filed: February 24, 1998
    Date of Patent: December 25, 2001
    Assignee: Milliken & Company
    Inventors: Robert C. Kerr, James N. Rockwell
  • Patent number: 6221112
    Abstract: A polyester film can be dyed by coating the film with a layer of a dye mixture which is a suspension of at least one disperse dyestuff in a solution of a thickener in water and which has a viscosity of no more than 500 centipoise, preferably 5-50 centipoise, at ambient temperature, followed by heating to cause the dyestuff to migrate from the layer into the film. The coating process is preferably reverse gravure printing. The process can be used to prepare films which contain one or more dyestuffs in one surface region of the film and one or more different dyestuffs, for example an ultraviolet absorber, in the other surface region of the film. The dyed films show good resistance to fading when exposed to light and are useful for example as automobile window films.
    Type: Grant
    Filed: November 2, 1998
    Date of Patent: April 24, 2001
    Assignee: CP Films, Inc.
    Inventor: William Douglas Snider
  • Patent number: 6156072
    Abstract: This invention relates to a method of manufacturing a fabric for ink jet printing and to an ink jet printing method for imparting to the fabric a clear and sharp image free from ink oozing in ink jet printing. Specifically, it relates to a method of manufacturing a fabric for ink jet printing which is characterized in that an aqueous treatment solution having a water-insoluble solvent dispersed or emulsified in an aqueous polymer solution is imparted to the fabric and dried; and to an ink jet printing method characterized in that the ink jet printing is made with the ink jet printing fabric used and that after developing, the pretreatment agent is removed by washing the fabric.
    Type: Grant
    Filed: August 1, 1994
    Date of Patent: December 5, 2000
    Assignee: Toray Industries, Inc.
    Inventors: Hiromi Usui, Yutaka Masuda, Nobuyoshi Handa
  • Patent number: 6136044
    Abstract: Micro-particles of transition metals or their compounds can be generated as an integral part of a fiber by first attaching a nucleating agent to the fiber, and then adding a solution of metal ions. The ions are reduced by the nucleating agent in the fiber, and micro-particles are generated in or on the fiber. Because of the strong color signal resulting from a low concentration of metal micro-particles, the method is cost effective even when using gold or titanium ions. Various colors were generated by changing the size and spacing of the micro-particles, the metal or metal complex used, and the characteristics of the fiber. The dyed fibers displayed colors ranging from pink, red, purple, yellow, orange, peach, brown, gold, silver, grey, green, and black. These colors resisted bleaching by either chemicals or light.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: October 24, 2000
    Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical College
    Inventor: William J. Todd
  • Patent number: 6129879
    Abstract: Process for treating a textile product comprising propylene polymer fibers comprises heating the textile product with the fibers in a substantially relaxed state at at least one temperature that is below the melting point of the propylene polymer but no more than about 20.degree. C. below such melting point. In one embodiment, the propylene polymer fibers subjected to such heating are characterized by a particular crystalline microstructure as determined by small angle X-ray diffraction. In another embodiment, the propylene polymer fibers subjected to such heating are melt spun, oriented fibers heated at at least one lower temperature.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: October 10, 2000
    Assignee: BP Amoco Corporation
    Inventors: Bruce Howard Bersted, Richard Tutt Norris, Jr., Leonid Slutsker, Ty Jackson Stokes
  • Patent number: 6123741
    Abstract: The invention relates to a process for dyeing a thread with indigo, characterized in that it comprises the following steps:a. prewashing a thread F by passing it through a prewash arrangement (1) comprising two or more tanks (2) containing a prewash solution (10, 15);b. then dyeing the thread by passing it through a dyeing arrangement (30) comprising a series of tanks (35) each containing a solution of reduced indigo, and when passing from one tank (35) to another, the thread is subjected to oxidation by exposure to the air transforming the reduced indigo into indigo, which then dyes the thread by impregnation, the oxidation by exposure to the air being achieved in such a way that when passing from the first tank (35) to the eighth in succession, if the value x is given to the oxidation between the first and second tanks, the result will be:After the 8th tank the oxidation value=8x;c. washing and initial drying the thread by passing it through a washing and initial drying arrangement (40).d.
    Type: Grant
    Filed: June 16, 1999
    Date of Patent: September 26, 2000
    Inventors: Francois Girbaud, Marie-Therese Bachellerie
  • Patent number: 6110231
    Abstract: A method of applying a surface coating to an intermediate textile product to enhance the performance of the textile product in a downstream manufacturing process. The method includes the steps of preparing an application composition having a process-enhancing material, an acid-decomposable emulsifier and an acid; emulsifying the application composition in a water bath to improve the surface activity of the process-enhancing material; exposing the intermediate textile product to the water bath containing the application composition; and decomposing the emulsifier into non-surface active substances simultaneously with the step of applying the application composition to the intermediate textile product to thereby permit the process-enhancing material to exhaust onto the textile product.
    Type: Grant
    Filed: June 1, 1998
    Date of Patent: August 29, 2000
    Assignee: Boehme Filatex, Inc.
    Inventor: Thomas W. Cooke
  • Patent number: 6090166
    Abstract: The invention relates to a process for dyeing a textile fabric with indigo by using indoxyl which comprises the following stages:a. pre-washing a thread F by passing it thorough a pre-wash system (1) composed of two or more vats (2) containing a pre-wash solution (10,15);b.
    Type: Grant
    Filed: July 8, 1999
    Date of Patent: July 18, 2000
    Inventors: Fran.cedilla.ois Girbaud, Marie-Therese Bachellerie
  • Patent number: 6080687
    Abstract: The present invention is directed to a method for dyeing anionic textile materials such as cellulosic materials with a cationic pigment dispersion. The method comprises padding the textile material with a cationic pigment dispersion comprising a pigment and a cationic dispersant and padding the textile material with a film-forming polymer. The padding steps can occur simultaneously with both the cationic pigment dispersion and the film-forming polymer in the same bath or in consecutive padding steps with the cationic pigment dispersion applied before the film-forming polymer or vice versa. The padded materials are dried and cured to produce the pigment-dyed materials.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: June 27, 2000
    Assignee: Zydex Industries
    Inventor: Ranka Ajay Ishwarlal
  • Patent number: 6074705
    Abstract: An applicator for temporarily masking stains on clothing includes a canister having an chamber for containing fluid, a water based, stain masking solution disposed within the chamber of the canister, and a brush or a spray head applying the stain masking solution from the chamber of the canister on a stain requiring masking. The stain masking solution covers the stain so that the stain is substantially concealed. The canister has an elongate annular wall having an open end at one end thereof, and an end wall closing the other end of the annular wall. Preferably, the stain masking solution consists of: resin--approximately 10.0 percent by weight; isopropanol--approximately 15.0 percent by weight; water--approximately 55.0 percent by weight; titanium dioxide--approximately 15.0 percent by weight; and ammonia--approximately 5.0 percent by weight.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: June 13, 2000
    Inventor: David N. DeBaene
  • Patent number: 6051036
    Abstract: A printed cloth in which a dye is deposited in dots on the cloth to form a desired printed pattern. Said dot deposition is formed in a length of 0.05 to 0.3 mm to the longitudinal direction of the fiber in single fiber unit of the yarn constituting said cloth. A fine printed pattern is deposited clearly in good reproducibility. The printed pattern can be formed by using the dyes of the three primary colors or of the three primary colors and black color. It is preferred that Dyes I, II and III having a perceived chromaticity index (a) and (b) defined in the color range [CIE 1976 (L, a, b) space] on the cloth within the following range are used as said dyes of three primary colors and DyeIV is used as said black dye.______________________________________ I Yellow: (a) -20.about.0 (b) 50.about.90 II Red: (a) 50.about.70 (b) 0.about.20 III Blue: (a) -50.about.-1 (b) -50.about.-20 IV Black: (a) -6.about.6 (b) -6.about.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: April 18, 2000
    Assignee: Kanebo, Ltd.
    Inventors: Kazuo Kusaki, Toshikazu Fuse, Tohru Morita, Toshihiko Ishihara, Kazuyoshi Morimoto, Kazuo Iwata, Michiyo Nishimura
  • Patent number: 6042616
    Abstract: A method for finishing a cellulose fiber-containing textile fabric comprises treating a cellulose fiber-containing textile fabric with liquid ammonia, applying a resin finishing agent to said fabric, subjecting subsequently to either or both of a hot calendering treatment and a heat treatment, and finally treating the resultant fabric with hot water. The resultant fabric keeps its shape stability including a crease or shrink resistance when washed, without involving any problem on residual formaldehyde.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: March 28, 2000
    Assignee: Nisshinbo Industries, Inc.
    Inventors: Yuichi Yanai, Masayoshi Oba, Kazuhiko Ichimura, Yasushi Takagi, Kazuhiko Harada
  • Patent number: 6040014
    Abstract: A fabric treatment composition comprises a fatty acid and a silicone elastomer, wherein the composition is used as a pretreatment for the fabric prior to application of ink thereto to facilitate retention and resolution of the ink on the fabric. The composition may also comprise a polyethylene glycol stearate and a fatty acid condensation product. The invention also describes a method of treating a fabric prior to printing thereon with an ink, the method comprising locating the fabric on a frame or base, applying a treatment composition comprising a polyethylene glycol stearate and a silicone elastomer to the fabric, and drying the fabric immediately thereafter. The invention further is for a method of preparing a fabric treatment composition.
    Type: Grant
    Filed: October 21, 1998
    Date of Patent: March 21, 2000
    Inventors: Avedik Izmirlian, Attilio del Verme
  • Patent number: 6033443
    Abstract: This invention relates to a process for treating Lyocell cellulose fibers, which comprises treating the Lyocell cellulose fiber with at least one compound of formula ##STR1## wherein X is --NR-- or --S--, A is an aliphatic radical containing 1 to 18 carbon atoms which is free of sulfo groups, or --X--A is hydroxy, and R is hydrogen or, independently of A, has the meaning of A.
    Type: Grant
    Filed: September 15, 1998
    Date of Patent: March 7, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Peter Aeschlimann
  • Patent number: 6022380
    Abstract: A process for manufacturing colored hair is disclosed. This process comprises the steps of applying a color sizing agent to hair material, semi-drying the color sizing agent applied to the hair material, winding a vapor feeding member comprised of a net member and a moisture-containing member around an area of the hair material where the color sizing agent is applied, winding an evaporation adjusting member for adjusting the quantity of evaporation of the moisture around the vapor feeding member from outside thereof, and permeating and fixing the color sizing agent to the applied area of the hair material by heating the vapor feeding member, thereby, hair at least partly applied with a desired color or color shade is obtained. A colored hair obtained by the above process is also disclosed.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: February 8, 2000
    Assignee: Aderans Co., Ltd.
    Inventor: Toshihiko Satoh
  • Patent number: 6010542
    Abstract: A method of dyeing a substrate in carbon dioxide comprises the steps of (a) providing a dye composition comprising carbon dioxide, a dye, and a surfactant, the surfactant included in an amount sufficient to solubilize, emulsify or disperse the dye in the carbon dioxide; and then (b) dyeing said substrate with said dye composition.
    Type: Grant
    Filed: August 28, 1998
    Date of Patent: January 4, 2000
    Assignee: Micell Technologies, Inc.
    Inventors: James P. DeYoung, James B. McClain, Joseph M. DeSimone, Timothy J. Romack
  • Patent number: 6001137
    Abstract: Waterfast ink jet printing onto textiles is performed by treating the textiles with a polymer or copolymer of epihalohydrin prior to the ink jet printing process. A softener such as a tetraalkylammonium salt may also be used, as may be a cationic binder.
    Type: Grant
    Filed: March 11, 1998
    Date of Patent: December 14, 1999
    Assignee: Encad, Inc.
    Inventors: Dheya Alfekri, Gary Staley, Bob Chin, Brian Hardin, Cincin Siswanto
  • Patent number: 5976196
    Abstract: An improved method for fixing color of a dyed textile by coating a dyed textile with a mixture of (i) an aminopolyamide-epichlorohydrin resin and (ii) a glyoxylated acrylamide-dimethyl diallyl ammonium chloride resin.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: November 2, 1999
    Assignee: Callaway Corporation
    Inventors: Anthony B Cooper, Richard T. Underwood, Geoffrey A. Monteith, Michael D. Wright
  • Patent number: 5951719
    Abstract: An improved method for fixing color of a dyed textile fabric by coating a dyed textile with an acrylamide polymer which has been reacted with glyoxal at a mole ratio of glyoxal to polymer of at least 0.8:1. Preferably the dyed textile fabric has been pre-coated with an anionic polymer.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: September 14, 1999
    Assignee: Callaway Corporation
    Inventors: Anthony Cooper, Richard T. Underwood, Geoffrey Monteith, Michael Wright
  • Patent number: 5925149
    Abstract: When nylon fibers are dyed with a first anionic dye and then treated with a stainblocker, they can be woven into a fabric with untreated nylon fibers and then subjected to a second dyeing process using a second anionic dye of a different color than the color of the first anionic dye, without risk of dye bleed or dye blending during the second dyeing operation.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: July 20, 1999
    Assignee: Simco Holding Corporation
    Inventors: Joseph A. Pacifici, Daniel G. Sims
  • Patent number: 5922088
    Abstract: A process for fixing dyes impregnated in fine-dimensional synthetic textile substrates in an environmentally safe manner. The process comprises contacting the dyed synthetic substrates with a phenol- and formaldehyde-free dye-fixative composition comprising:(a) polymethacrylic acid,(b) copolymers of methacrylic acid consisting essentially of methacrylic acid and an ethylenically unsaturated comonomer selected from the group consisting of 2-acrylamido-2-methyl-propanesulfonic acid, sodium vinyl sulfonate, sodium styrene sulfonate, alkyl acrylate,(c) sulfamic acid, and(d) combinations of (a), (b) and (c).
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: July 13, 1999
    Assignee: Henkel Corporation
    Inventors: Howard Cole, Brian Francois, David I. Devore
  • Patent number: 5912409
    Abstract: Stain-resistant, lightfast nylon carpet is prepared by dyeing cationic-dyeable nylon fibers by applying a print paste containing an acid dye or a premetallized acid dye at a pH of from about 2.0 to about 6-5 and fixing the dye to the fibers, forming the printed nylon fibers into a carpet, applying a print paste containing an acid dye or premetallized acid dye and dyeing the nylon fibers contacted with the print pastes and thereafter heating the dyeladen fibers to fix the dye into the fibers. Stain-resistant lightfast nylon yarns are prepared by printing cationic-dyeable yarn with a premetallized acid dye at a pH of about 4.0 to less than about 6.5 then fixing the dye to the yarn.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: June 15, 1999
    Assignee: Burlington Industries, Inc.
    Inventor: William G. Jenkins
  • Patent number: 5882356
    Abstract: The fibrillation tendency of solvent-spun cellulose fiber is reduced by treating the previously dried fiber with a chemical reagent containing at least two functional groups which are reactive with cellulose and which are electrophilic carbon--carbon double bonds, particularly vinyl sulfone groups, or precursors thereof or electrophilic three-membered heterocyclic rings or precursors thereof. The chemical reagent is preferably colorless and is preferably applied to the fiber from aqueous solution. The fiber may be contained in a woven or knotted fabric.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: March 16, 1999
    Assignee: Courtaulds Fibres (Holdings) Limited
    Inventor: Christopher David Potter
  • Patent number: 5855623
    Abstract: Methods are provided for treating polyester, polyamide, acrylic, aramid or cellulosic substrates to improve the uniformity of dyeing and to improve the hydrophilic, soil-release, odor-, mildew-, bacterial- and fungal- resistant properties of these substrates.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: January 5, 1999
    Assignee: Intera Technologies, Inc.
    Inventors: Larry L. English, Ted A. Mallen
  • Patent number: 5837371
    Abstract: A process for lubricating acrylic fibers before dyeing in which packages of acrylic yarn formed by winding acrylic yarn about a dye tube are treated immersed in an aqueous lubricating bath containing a polyethylene, a low melting paraffin wax emulsion; and a high melting paraffin wax emulsion, followed by raising the temperature of the bath, to sequentially coat the fibers of the yarn with the polyethylene, the low melting paraffin wax emulsion, and the high melting paraffin wax emulsion. The yarn packages are then separated from the lubricating bath, and immersed in a dye bath to dye the yarn. In commercial application, the lubrication and subsequent dyeing is conducted in the chamber of a dye machine.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: November 17, 1998
    Assignee: Amital Spinning Corporation
    Inventor: Dominick J. Rivas
  • Patent number: 5756407
    Abstract: A treated fibrous polyamide substrate having durable resistance to staining by acid colorants comprising a fibrous polyamide substrate having applied thereto an aqueous solution of a sulfonated, phosphated resol resin; which aqueous solution may include a methacrylic polymer or copolymer and a fluorochemical; and the method of treating said substrate with the solution to render it durable to staining by acid colorants.
    Type: Grant
    Filed: October 9, 1996
    Date of Patent: May 26, 1998
    Assignee: Trichromatic Carpet Inc.
    Inventors: Yassin M. Elgarhy, Barry R. Knowlton
  • Patent number: 5736468
    Abstract: A treated fibrous polyamide substrate having durable resistance to staining by acid colorants comprising a fibrous polyamide substrate having applied thereto an aqueous solution of a sulfonated, phosphated resol resin and a methacrylic polymer or copolymer of high number average molecular weight, and preferably high weight average molecular weight and optionally, fluorochemical; and the method of treating said substrate with the solution to render it durable to staining by acid colorants.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: April 7, 1998
    Assignee: Trichromatic Carpet Inc.
    Inventor: Yassin M. Elgarhy
  • Patent number: 5653772
    Abstract: A method of fixing cellulose fibers dyed with a reactive dye, which comprises a homopolymer containing a vinylamine structural unit, a copolymer containing from 5 to 90% by weight of a vinylamine structural unit and from 5 to 90% by weight of a diallylamine structural unit, a copolymer containing from 5 to 90% by weight of a vinylamine structural unit, from 5 to 90% by weight of structural unit of a vinyl compound copolymerizable with the vinylamine, or copolymer containing from 5 to 90% by weight of a vinylamine structural unit, from 5 to 90% weight of a diallylamine structural unit and from 5 to 90% by weight of a structural unit of a vinyl compound copolymerizable with vinylamine and diallylamine, and/or a salt of the homopolymer or copolymers.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: August 5, 1997
    Assignee: Nicca Chemical Co., Ltd.
    Inventors: Yasuharu Mori, Nobuhiko Ueno, Kouji Midori, Juji Uchida, Masayuki Maeno
  • Patent number: 5632781
    Abstract: The present invention provides a cationic polycondensate dye fixing agent prepared by reacting (a) a mono- or polyfunctional amine having at least one reactive --NH or --NH.sub.2 group, or a salt thereof, with (b) a polycondensate-forming cyano compound at a temperature of at least about 260.degree. C.The present invention also provides a process of improving the fastness of dyed materials using the cationic polycondensate dye fixing agent of the present invention.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: May 27, 1997
    Assignees: NICCA U.S.A., Inc., NICCA Chemical Co., Ltd
    Inventors: Shinichi Morinaga, Kouji Midori
  • Patent number: 5626952
    Abstract: A process for sizing spun yarns by adding urea in an amount of about 10 to 50% by weight of the weight of a polyacrylamide polymer, wherein the polymer and urea are applied in an amount sufficient to impart a high order of abrasion resistance to the yarn.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: May 6, 1997
    Assignee: Callaway Corporation
    Inventors: Michael L. McAbee, Warren S. Perkins, Donald H. Shomake
  • Patent number: 5607482
    Abstract: The present invention relates to a method for textile printing with aqueous dispersions in which an organic fixing agent is crosslinked with a blocked polyisocyanate having (i) an average molecular weight of about 800 to about 25,000, (ii) a content of blocked isocyanate groups, calculated as free NCO and based on non-blocked polyisocyanate, corresponding to an NCO content of about 5 to about 20% by weight, (iii) an ionic group content of about 1 to about 75 milliequivalents per 100 g of blocked polyisocyanate, and (iv) a content of polyalkylene oxide units of about 1 to about 20% by weight, based on blocked polyisocyanate, said blocked polyisocyanate being obtained by the reaction of(a) organic polyisocyanates,(b) isocyanate-reactive compounds containing (potential) ionic groups,(c) polyalkylene ether alcohols,(d) NCO blocking agents, and(e) optionally, isocyanate-reactive compounds that are different from components (b), (c), and (d).
    Type: Grant
    Filed: September 8, 1995
    Date of Patent: March 4, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Reiff, Herbert Wigger, Matthias Gehling, Karl-Heinz Passon
  • Patent number: 5601746
    Abstract: Aqueous dispersions (D) of a wax (W) dispersed in the aqueous phase by means of a dispersant (B), wherein in (D)the wax (W) is(A) an oxidized hydrocarbon wax or a mixture of oxidized hydrocarbon waxesor a mixture or (A) and at least one non-oxidized hydrocarbon wax (P), the acid number of which is.gtoreq.5,and the dispersant (B) isa non-ionogenic, anionic, cationic or amphoteric surfactant or a mixture of two or more of these surfactants, which displays an HLB.gtoreq.7,and the dispersion (D) optionally contains at least one protective colloid (C), at least one agent (E) for pH-adjustment, at least one antifreeze agent (F) and/or at least one preserving agent (D), but is substantially free of other waxes than (A) and (P) and of other surfactants than (B) and (C),are eminently suitable as wet lubricants that are very stable to temperature modifications and to high electrolyte concentrations, especially as occurring in pretreatment and in dyeing of cellulosic substrates.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: February 11, 1997
    Assignee: Sandoz Ltd.
    Inventors: Bernard Danner, Francis Palacin
  • Patent number: 5571290
    Abstract: Stain-resistant nylon, especially cationic-dyeable carpet nylon, is prepared by dyeing and/or printing cationic-dyeable nylon fibers with acid or premetallized dye. Lightfastness and depth of shade of an apparent value equal to acid dyeable nylons is obtained with superior stain resistance equal to commercially available solution dyed nylon carpeting.
    Type: Grant
    Filed: September 25, 1995
    Date of Patent: November 5, 1996
    Assignee: Burlington Industries, Inc.
    Inventor: William G. Jenkins
  • Patent number: 5565265
    Abstract: A liquid and stain resistant, antimicrobial fabric is provided that can withstand the high temperatures required for transfer printing. A coating composition comprising a copolymer composition, an antimicrobial agent and a fluorochemical composition is applied to fabric such as polyester, to produce the coated fabric. The liquid and stain resistant antimicrobial, printed fabric retains its natural texture, is durable and easy to handle.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: October 15, 1996
    Assignees: Craig A. Rubin, Randy B. Rubin
    Inventors: Craig A. Rubin, Randy B. Rubin, Kyle Bullock
  • Patent number: 5560751
    Abstract: A method for dyeing an optical component such as a lens or filter. A coating of dyeing solution is formed on a surface of a lens and the lens is subjected to a nonuniform heating treatment in dependence on the position within the surface to obtain the desired color density gradient of the lens. In accordance with the positions within such surface, a nonuniform integrated heating amount distribution provides the desired color density gradient with excellent reproducibility.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 1, 1996
    Assignee: Nikon Corporation
    Inventor: Seiichirou Hoshiyama
  • Patent number: 5507839
    Abstract: A dye is fixed to a solid material by using a diene or dienophile as the dye, incorporating a dienophile or diene into the solid material, effecting Diels-Alder reaction between the diene and the dienophile or between the dye and the solid material for binding the dye to the solid material. The dyed solid material has an increased dye concentration and prevents dye diffusion with the lapse of time.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: April 16, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Mitsugu Tanaka
  • Patent number: 5482764
    Abstract: A method to improve the bleach resistance of a textile fiber is provided by having the steps of:(a) applying a solution or dispersion of a compound of the formula: ##STR1## where R.sup.1 and R.sup.2 are independently selected from the group consisting of H, CO.sub.2 R.sub.4, SO.sub.3 H, PO.sub.3 H, CON(R.sup.4).sub.2, OH, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, and halo, where R.sup.4 is H or C.sub.1 -C.sub.4 alkyl;R.sup.3 is selected from the group consisting of H, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkenyl, C.sub.1 -C.sub.4 alkylenephenyl, phenyl and COR.sup.5, where R.sup.5 is C.sub.1 -C.sub.4 alkyl, phenyl or benzyl, any of which may be substituted with up to two groups from R.sub.2 ; and salts of such compounds; in a solvent selected from the group consisting of water and C.sub.1 -C.sub.4 alcohol; and(b) drying said textile fiber to evaporate said solvent and deposit a non-volatile coating of said phenolic compound on a surface of said fiber.
    Type: Grant
    Filed: February 2, 1994
    Date of Patent: January 9, 1996
    Assignee: Milliken Research Corporation
    Inventors: Daniel T. McBride, Carey N. Barry, Jr.
  • Patent number: 5464452
    Abstract: A process for fixing dyes impregnated in fine-dimensional synthetic textile substrates in an environmentally safe manner. The process comprises contacting the dyed synthetic substrates with a phenol- and formaldehyde-free dye-fixative composition comprising: (a) polymethacrylic acid, (b) copolymers of methacrylic acid consisting essentially of methacrylic acid and an ethylenically unsaturated comonomer selected from the group consisting of 2-acrylamido-2-methyl-propanesulfonic acid, sodium vinyl sulfonate, sodium styrene sulfonate, alkyl acrylate, and combinations thereof, (c) combinations of (a) and (b), and (d) water.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: November 7, 1995
    Assignee: Henkel Corporation
    Inventors: Arthur H. Cole, Susan C. Glenn, Grannis S. Johnson