Abstract: A polyurethane composition comprising a polyurethane and at least one dye selected from the group consisting of metal complex dyes, vat dyes, sulfur dyes and acid dyes. The polyurethane is synthesized by the reaction of a polymeric diol containing a polyoxyethylene chain as a minor proportion, an alicyclic diisocyanate, an alicyclic diamine and hydrazine in particular proportions. This polyurethane composition is little susceptible to deterioration by light and is suitable for use as a component of artificial leather or as a coating material for fabrics.
Type:
Grant
Filed:
April 3, 1981
Date of Patent:
January 4, 1983
Assignee:
Kuraray Company, Limited
Inventors:
Koji Hirai, Kenji Shirano, Kazuo Hara, Takayuki Okamura
Abstract: A colorant preparation containing(A) a colorant which is sparingly soluble or insoluble in water,(B) a plasticizer based on an ester and(C) a reaction product of a fatty acid ester of a polyhydric alcohol and ethylene oxide, a process for the production of this preparation and its use for pigmenting plastics.
Type:
Grant
Filed:
January 28, 1981
Date of Patent:
June 1, 1982
Assignee:
Bayer Aktiengesellschaft
Inventors:
Michael Kressner, Joachim Kolbe, Fritz Bremer, Georg Pape, Karlheinz Wolf, Ferdinand Kummeler
Abstract: Anthraquinone-azomethine compounds of the formula ##STR1## or of the tautomeric formula ##STR2## in which A denotes an anthraquinone radical which is free from sulphonic acid groups and is optionally further substituted and which preferably consists of at most 5 fused rings,R.sub.1 denotes hydrogen, optionally substituted aryl, preferably ##STR3## hetero-aryl, cycloalkyl or C.sub.1 -C.sub.12 -alkyl, it being possible for the alkyl chain to be interrupted by oxygen or sulphur and/or to be substituted by hydroxyl groups or N(R.sub.3).sub.2 groups, --N(R.sub.3).sub.2 or ##STR4## R.sub.2 denotes a substituent, R.sub.3 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, cycloalkyl oroptionally substituted aryl,m denotes 1, 2, 3 or 4 andn denotes 0, 1, 2, 3, 4 or 5, processes for their preparation and processes for pigmenting organic macromolecular substances using the new anthraquinone-azomethine compounds.
Type:
Grant
Filed:
July 21, 1980
Date of Patent:
April 6, 1982
Assignee:
Bayer Aktiengesellschaft
Inventors:
Rutger Neeff, Meinhard Rolf, Walter Muller
Abstract: Anthraquinone derivatives which, in one of their tautomeric structures, correspond to the formula ##STR1## in which A denotes an anthraquinone radical which is free from sulphonic acid groups, is optionally further substituted and preferably consists of at most 5 fused rings,m denotes a number from 1 to 4, preferably 1 or 2,R denotes a substituent andn denotes 0, 1, 2, 3 or 4,processes for their preparation, their use for pigmenting organic macromolecular substances, and the material pigmented in this manner.
Type:
Grant
Filed:
April 14, 1980
Date of Patent:
April 6, 1982
Assignee:
Bayer Aktiengesellschaft
Inventors:
Rutger Neeff, Meinhard Rolf, Walter Muller
Abstract: Anthraquinone-azomethine compounds of the formula ##STR1## or of the tautomeric formula ##STR2## or of the tautomeric formula ##STR3## in which A denotes an anthraquinone radical which is free from sulphonic acid groups and optionally further substituted and which preferably consists of at most 5 fused rings,R.sub.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, hydroxy-C.sub.1 -C.sub.4 -alkyl, optionally substituted phenyl, carboxyl, carboxylic acid, C.sub.1 -C.sub.4 -alkyl ester or hydroxyl,R.sub.2 denotes hydrogen, halogen, nitro, cyano, optionally substituted carbamoyl or optionally substituted sulphamoyl, sulphonic acid C.sub.1 -C.sub.4 -alkyl ester, sulphonic acid aryl ester, C.sub.1 -C.sub.4 - alkylcarbonyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, optionally substituted benzoyl, alkyl or optionally substituted phenyl sulphone, or a hetero-aromatic radical, for example a radical of the formula ##STR4## or of the formula ##STR5## or of the formula ##STR6## R.sub.
Type:
Grant
Filed:
July 21, 1980
Date of Patent:
March 9, 1982
Assignee:
Bayer Aktiengesellschaft
Inventors:
Rutger Neeff, Meinhard Rolf, Walter Muller
Abstract: A process of integrating a photochromic substance, especially a spiropyran or a metal dithizonate, into a transparent substrate of polymerized organic material such as poly [ethylene glycol di-allyl di-carbonate] by thermal transfer, comprising applying the photochromic substance alone or with a solvent and/or thickening agent to the surface of a transparent organic substrate such as a lens disc, and heating until the photochromic substance is sublimed and then diffused and anchored in the organic material of the lens, preferably just beneath the surface to which it is applied. Preferably, the photochromic substance is initially carried on a temporarily support for application.
Type:
Grant
Filed:
January 10, 1979
Date of Patent:
September 1, 1981
Assignee:
Essilor International "Cie Generale d'Optique"
Abstract: Anthraquinone derivatives which in one of their tautomeric structures correspond to the formula ##STR1## in which A denotes an anthraquinone radical which is free from sulphonic acid groups, is optionally further substituted and preferably consists of at most 5 fused rings,m is a number from 1-4 and preferably 1 or 2,R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 -alkyl group andR.sub.2 is a cyano group or a radical of the formula ##STR2## or a radical of the formula ##STR3## in which formulae R.sub.3 is hydrogen, a straight-chain or branched alkyl group of a cycloalkyl radical,R.sub.4 is a substituent,n is 0, 1, 2, 3 or 4 andp is 0, 1, 2, 3, 4 or 5,processes for their preparation and their use for pigmenting organic macromolecular substances.
Type:
Grant
Filed:
July 19, 1979
Date of Patent:
August 18, 1981
Assignee:
Bayer Aktiengesellschaft
Inventors:
Rutger Neeff, Meinhard Rolf, Walter Muller
Abstract: A method of marking an ophthalmic lens of organic material and the lens so marked. A marking substance containing an optical brightener which is a derivative of benzoxazolyls stilbenes, or benzotriazoles is mixed with a suitable binder and solvent and applied to a surface of the lens to be marked by thermal transfer from a transfer support. The marking substance is shaped to the desired configuration either when applied to the transfer support or by a mask defining the mark or indicia to be applied. Heat is applied to the marking substance and the lens which sublimes the optical brightener which then penetrates into the organic material of the lens to be anchored therein. The resultant indicia or mark provides a permanent marking of the lens and is only visible in ultra-violet light.
Type:
Grant
Filed:
October 13, 1978
Date of Patent:
March 24, 1981
Assignee:
Essilor International "Cie Generale d'Optique
Abstract: A process for dyeing textile substrates comprising a mixture of elastomeric and non-elastomeric fibres, in which in a first step the elastomeric fibre portion is dyed by a cold dwell process and then in a second the non-elastomeric fibre portion is dyed by a conventional exhaust or continuous process.