Polyester Fiber And Cellulose Fiber Patents (Class 8/532)
  • Patent number: 5038415
    Abstract: A disperse dye composition comprising (a) a pyridone monoazo compound of the formula (I), ##STR1## wherein X.sup.1 and X.sup.2 are each hydrogen, halogen, alkyl, alkoxy or others, and R.sup.1 is alkyl, alkenyl, cycloalkyl, phenyl or anilino, and (b) a pyridone monoazo compound of the formula (II). ##STR2## wherein X.sup.3 and X.sup.4 are each hydrogen, halogen, alkyl, alkoxy or others, and R.sup.2 is alkyl, alkenyl, cycloalkyl, phenyl or anilino, optionally together with (c) a quinophthalone compound of the formula (III), ##STR3## wherein Y is hydrogen or bromine, and the ring A is unsubstituted or substituted benzene or naphthalene ring, which is useful as a yellow dye component for dyeing or printing hydrophobic fiber materials with superior dye bath stability and level dyeing property.
    Type: Grant
    Filed: January 9, 1990
    Date of Patent: August 13, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasuyoshi Ueda, Junichi Sekihachi, Takashi Omura, Hideo Hattori, Kiyoharu Nakatsuka
  • Patent number: 5019133
    Abstract: A method for dyeing polyester-containing fibers by using a disperse dye, wherein said dyeing is conducted under an alkaline condition in an aqueous medium in the presence of at least one amino acid member selected from the group consisting of an amino acid, an amino acid derivative having at least one hydrogen atom of its amino group replaced with an organic group, and an alkali metal salt of such an amino acid or amino acid derivative, in the dyeing bath, and a dyeing assistant useful for the method.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: May 28, 1991
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Kiyoshi Himeno, Kazuhisa Konishi
  • Patent number: 5015261
    Abstract: A process for the pre-treatment of natural and regenerated cellulosic fibres and blends thereof with synthetic fibres for the purpose of subsequent transfer printing comprises applying to said fibres a composition comprising a mixture of hexamethoxymethyl melamine and a C.sub.4-8 glycol in the presence of water, and drying said fibres at a temperature below 180.degree. C.The above compositions per se, with or without water and polyvinyl chloride or polyvinylidene chloride polymer or copolymer emulsions or dispersions, are also claimed.
    Type: Grant
    Filed: June 16, 1987
    Date of Patent: May 14, 1991
    Assignee: BASF Australia, Ltd.
    Inventors: Henry Donenfeld, Eduard Lemanis
  • Patent number: 5013328
    Abstract: A substrate to which a dyestuff or optical brightener has been applied is aftertreated with a cationic or protonatable polymeric Product P selected from:(A) a polymeric reaction product, Product A, of a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups with cyanamide, dicyanamide, guanidine or bisguanidine in which up to 50 mole percent of the cyanamide, dicyanamide, guanidine or bisguanidine may be replaced by a dicarboxylic acid or a mono- or di-ester thereof, with the splitting off ammonia, optionally in the presence of a catalyst; Product A containing at least one free hydrogen atom linked to a nitrogen atom; or(B) the polymeric reaction product, Product B, of Product A with(a) epichlorohydrin or a precursor thereof; or(b) an N-methylol derivative of a urea, melamine, guanamine, triazinone, urone, carbamate or acid amine optionally in the presence of a catalyst for crosslinking N-methylol compounds; or(c) a water-soluble homo- or co-polymer, Pr
    Type: Grant
    Filed: November 15, 1989
    Date of Patent: May 7, 1991
    Assignee: Sandoz Ltd.
    Inventors: Oskar Annen, Bernhard Schlick
  • Patent number: 5002587
    Abstract: Copolymers which are obtainable from(1) 20 to 50% by weight of an N-substituted or N-unsubstituted acrylamide or methacrylamide and(2) 50 to 80% by weight of an N-vinyl-substituted amide or of a vinyl ester, derived in each case from a saturated aliphatic monocarboxylic acid,the sum of (1) and (2) adding up to 100%.These novel copolymers are suitable as dyeing assistants, particularly as padding assistants or liquor binders in the dyeing of cellulose fibre materials.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: March 26, 1991
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans-Ulrich Berendt
  • Patent number: 5000756
    Abstract: The invention relates to a process for dyeing cellulosic fibre materials with reactive dyes by the pad dyeing process in the process of an assistant, which process comprises the use of a mixture containing(a) at least one reactive dye of formula ##STR1## wherein Pc, W, k, R.sub.1, R.sub.2, B and R are as defined in claim 1, and(b) at least one colorless compound which contains at least one --SO.sub.2 --Z group, wherein Z is as defined in claim 1.
    Type: Grant
    Filed: December 1, 1989
    Date of Patent: March 19, 1991
    Assignee: Ciba-Geigy Corporation
    Inventor: Peter Aeschlimann
  • Patent number: 4994089
    Abstract: The carrier mixture contains N-alkylphthalimides and compounds of the general formula ##STR1## in which R is C.sub.1 -C.sub.7 -alkyl; phenyl, benzyl or phenylethyl, which can be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.3 -alkylcarbonyloxy, hydroxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl,m is 0 or 1,n is 0 or 1, m and n not being 0 at the same time.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: February 19, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Frank Bartkowiak, Hans Schulze, Wolf-Dieter Schroer, Gunther Boehmke, Karlhans Jakobs, Willi Schossler
  • Patent number: 4992078
    Abstract: Improved sulfur dye dispersions are obtained by subjecting an aqueous suspension of oxidized sulfur dye particles to membrane separation. The oxidized sulfur dye is obtained by controlled aeration whereby the content of sulfides, polysulfur and inorganic salts is significantly decreased.
    Type: Grant
    Filed: February 23, 1989
    Date of Patent: February 12, 1991
    Assignee: Sandoz Ltd.
    Inventor: Laszlo A. Meszaros
  • Patent number: 4985041
    Abstract: Compositions for use as dye assistants are formed from a non-phenolic aromatic swelling agent for the fiber to be dyed mixed with just enough dispersant to cause a non-foaming emulsion upon dilution of the dye assistant in water, but not enough dispersant to interfere with the swelling process of the fiber by the dye assistant. Thus, the swelling agent is mixed with the minimum amount of surfactant required for the production of an emulsion and dispersion of the dye with little or no foaming in the dye bath. Formulations can also be prepared having higher levels of water which are non-flammable.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: January 15, 1991
    Inventor: Ralph Matalon
  • Patent number: 4985044
    Abstract: Since anthraquinonoid disperse dyes of the dark blue and navy region give only a low color strength on synthetic fibers, there was an urgent need for their coloristically advantageous substitution by high performance blue azo dyes which are suitable for being used in the carrier dyeing process.According to the invention, the systematic development of multi-component mixtures based on selected blue azo dyes from the dicyano azo series makes it possible to avoid most of the disadvantages mentioned.
    Type: Grant
    Filed: June 7, 1989
    Date of Patent: January 15, 1991
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Reinhard Kuhn, Ulrich Buhler
  • Patent number: 4960435
    Abstract: A crystalline form of the dye represented by the following formula (1): ##STR1## characterized by an X-ray diffraction pattern having a strong peak at the angle of diffraction (2.theta.) of 23.2.degree. and relatively strong peaks respectively at the angles of diffraction (2.theta.) of 8.3.degree., 12.3.degree., 20.8.degree., 21.9.degree., 25.0.degree., 27.1.degree., 29.2.degree. and 30.8.degree. according to X-ray powder diffractometry through the use of a Cu-K.alpha. line and a process for preparing the same by heat-treating a heat-instable crystalline form of the dye represented by the formula (1) in water, water containing a water-soluble organic solvent, or water containing an anionic or nonionic surfactant at a temperature of 40.degree. C. or above.It withstands dyeing at high temperature, e.g. 130.degree. C. or higher, to provide dyed fibers having excellent fastness properties.
    Type: Grant
    Filed: December 5, 1989
    Date of Patent: October 2, 1990
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Mituaki Tunoda, Nobuharu Suzuki
  • Patent number: 4960434
    Abstract: A dye composition suitable for the coloration of synthetic textile materials, especially linear polyester, by conventional disperse dyeing and printing processes comprising a mixture of a dye of the formula: ##STR1## and a dye of the formula: ##STR2## wherein X and X' are each independently selected from Br, Cl and I;Q and Q' are independently C.sub.1-4 -alkyl;T is C.sub.1-4 -alkyl;R.sup.1 and R.sup.2 are each independently C.sub.1-4 -alkyl or C.sub.2-4 -alkenyl; andT.sup.1 and T.sup.2 are each independently C.sub.1-4 -alkyl or C.sub.2-4 -alkenyl.
    Type: Grant
    Filed: June 7, 1989
    Date of Patent: October 2, 1990
    Assignee: Imperial Chemical Industries plc
    Inventors: David Brierley, Alan T. Leaver
  • Patent number: 4913705
    Abstract: A mixed fabric of hydroxy group-containing fibers and cyano and/or carboxy group-containing fibers, the hydroxy group-containing fibers having been dyed with a reactive dye, is aftertreated with a product of reacting a mono- or polyfunctional amine having one or more primary, secondary and/or tertiary amino groups with cyanamide, dicyandiamide guanidine or bis-guanidine, said product containing at least one reactive hydrogen atom linked to a nitrogen atom, and is then dyed with a basic dye.
    Type: Grant
    Filed: September 2, 1988
    Date of Patent: April 3, 1990
    Assignee: Sandoz Ltd.
    Inventors: Bernhard Schlick, Claudio Artico
  • Patent number: 4906248
    Abstract: Cellulose fibers can be effectively dyed with an assistant composition comprising (a) a polymer or copolymer of maleic acid, acrylic acid, methacylic acid or a salt thereof and (b) a sulfonate of a monocyclic or polycyclic aromatic compound or a condensate thereof with an aliphatic aldehyde.
    Type: Grant
    Filed: March 24, 1988
    Date of Patent: March 6, 1990
    Assignee: Kao Corporation
    Inventors: Naoki Kyochika, Shigeru Nagao
  • Patent number: 4902300
    Abstract: Synthetic/cellulosic blend textile fabrics are simultaneously dyed and the synthetic component simultaneously treated to impart flame resistance in a single step with good color yield. Additional fabric finishing may be used to impart flame resistance to the cellulosic component of the fabric.
    Type: Grant
    Filed: May 19, 1988
    Date of Patent: February 20, 1990
    Assignee: Burlington Industries, Inc.
    Inventors: James R. Johnson, Randolph L. Finley
  • Patent number: 4889923
    Abstract: Azo compounds corresponding to the general formula (1) ##STR1## in which m represents the number 1 or 2, the cyano groups being attached to D in the ortho-position relative to the azo group,n denotes the number 1 or 2,Y is the vinyl group or a .beta.-sulfatoethyl group,D denotes a radical of a diazo component of the benzene or naphthalene series which is optionally additionally substituted, but is otherwise free from anionic groups, andK denotes a radical of a coupling component which is optionally additionally substituted, but is otherwise free from anionic groups.The compounds have valuable fiber-reactive dyestuff properties and are suitable for dyeing both hydrophilic and hydrophobic materials, in particular fiber materials, such as, for example, cellulose, wool, synthetic polyamide and polyester.
    Type: Grant
    Filed: December 16, 1987
    Date of Patent: December 26, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Peter Mischke, Hans J. Schladetsch
  • Patent number: 4886518
    Abstract: A process for dyeing cellulose fibres or cellulose-containing blend fibres with vat dyes, sulfur dyes, leuco vat ester dyes or azoic dyes by the pad dyeing process without incurring ending, in which an aqueous dyeing liquor is used which, aside from the dye, contains a colorless compound of the formula ##STR1## or of the formula ##STR2## where Q is ##STR3## or .dbd.N--, Y is hydrogen, halogen, cyano, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkylsulfonyl,V and W, independently of each other, are each R.sub.2 --X.sub.2 --, R.sub.3 --X.sub.3 --, hydroxyl C.sub.1 --C.sub.5 alkoxy or an unsubstituted or C.sub.1 --C.sub.5 alkyl-- or C.sub.5 --C.sub.6 cycloalkyl-monosubstituted or --disubstituted amino group, the alkyl radical being unsubstituted or substituted by hydroxyl, cyano, sulfo or sulfato,R.sub.1, R.sub.2 and R.sub.3, independently of one another, are each an aromatic or heteroaromatic radical,X.sub.1, X.sub.2 and X.sub.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: December 12, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean-Marie Sire
  • Patent number: 4881942
    Abstract: A process for the coloration of a union of polyester and cellulosic textile materials which comprises applying thereto a liquor or paste containing a disperse dye and a dye containing a cellulose reactive group having a quaternary nitrogen substituent, or the precursors of such a dye, and thereafter heating the textile material at such a temperature and for such a period as to fix the dye on the textile material, characterized in that the pH of the liquor or paste is from 5.8 to 8.0.
    Type: Grant
    Filed: July 7, 1988
    Date of Patent: November 21, 1989
    Assignee: Imperial Chemical Industries PLC
    Inventor: Herbert G. Connor
  • Patent number: 4881941
    Abstract: A textile substrate is dyed by immersing it in a gathered configuration into an oil medium containing a dissolved or dispersed dye for a sufficient time to allow the oil medium to come into contact with part but not all of the surface of the substrate and the thus-treated substrate is then preferably immersed in an aqueous medium having another dye dissolved or dispersed therein.
    Type: Grant
    Filed: July 12, 1988
    Date of Patent: November 21, 1989
    Assignee: Sandoz Ltd.
    Inventor: Michael W. Dixon
  • Patent number: 4872882
    Abstract: Dyeing formulations in solid or liquid form, containing one or more red disperse dyes of the general formula (1) ##STR1## where R.sub.1 denotes an alkyl group of 1 to 4 carbon atoms, and one or more red disperse dyes of the general formula (2) ##STR2## where R.sub.2 and R.sub.3 denote independently of each other the group --CH.sub.2 --CH.sub.2 --CH.sub.2 --COOCH.sub.3 or --CH.sub.2 --CH.sub.2 --CH.sub.2 --COOC.sub.2 H.sub.5 and R.sub.
    Type: Grant
    Filed: September 1, 1988
    Date of Patent: October 10, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Reinhard Kuhn
  • Patent number: 4872883
    Abstract: The mixture of monoazo dyestuffs which contains one or more dyestuffs of the formula I ##STR1## and one or more dyestuffs of the formula II ##STR2## wherein R.sup.1 and R.sup.2 independently of one another denote linear or branched alkyl with 1 to 6 carbon atoms and R denotes linear or branched alkyl with 1 to 3 carbon atoms, is outstandingly suitable for dyeing and printing hydrophobic materials a deep blue color.
    Type: Grant
    Filed: January 27, 1988
    Date of Patent: October 10, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Buhler, Klaus Hofmann, Manfred Hahnke
  • Patent number: 4863483
    Abstract: A process is provided for direct coloring of textile fibres comprising appropriately pre-treating said fibres, preparing a solution of a cross-linking agent being a solution of a water insoluble technical hexamethoxymethyl melamine in a C.sub.4-8 glycol, adding said solution of the cross-linking agent to a dye liquor or printing paste containing a colorant (excluding cationic dyestuffs) in the presence of an acid donor, applying the resultant mixture to said fibres and drying and curing said fibres.Also provided is a dye liquor or print paste comprising a colorant (excluding cationic dyestuffs), an acid donor and a cross-linking agent being a solution of a water insoluble technical hexamethoxymethyl melamine in a C.sub.4-8 glycol.
    Type: Grant
    Filed: September 10, 1987
    Date of Patent: September 5, 1989
    Assignee: BASF Australia Ltd.
    Inventors: Henry Donenfeld, Eduard Lemanis
  • Patent number: 4861344
    Abstract: Water-soluble azo compounds having useful fiber-reactive dye properties conforming to the general formula ##STR1## in which: A is phenylene which may be substituted or unsubstituted, or is a radical of the formula ##STR2## in which W is a direct bond or a radical of the formula --CH.dbd.CH-- or --NH--CO--NH-- and R* denotes hydrogen, nitro, sulfo, carboxy, methyl, ethyl, methoxy or ethoxy;n is the number zero or 1;B is a radical of the formula ##STR3## where R is equal to carboxy or carbamoyl; M is hydrogen or an alkali metal; andK is one of five radicals described in the specification, each of which contains a fiber-reactive group.These azo compounds produce fast dyeings on carboxamido- and/or hydroxy-containing materials, in particular cellulose fibers. On cellulose, fast dyeings are also obtained in a weakly acid to neutral medium, for example together with disperse dyes for dyeing a polyester fiber portion.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: August 29, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ludwig Schlafer, Hartmut Springer, Reinhard Hahnle
  • Patent number: 4861342
    Abstract: Dyeing or finishing process characterized in that textile materials are impregnated in a padding machine with aqueous dyeing or finishing baths which contain, besides graft polymers, which may be obtained from a product of addition of an alkylene oxide to an at least trivalent aliphatic alcohol containing from 3 to 10 carbon atoms and methacrylamide or acrylamide, and in that the fixing of the dyes or of the finish is then performed continuously by a treatment with microwaves for 5 to 30 seconds.The process permits an excess water input on all the textile materials and a rapid fixing by the microwaves.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: August 29, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Paul Danel
  • Patent number: 4844710
    Abstract: Aqueous textile assistants of high storage stability and hard water resistance comprising at least (a) a partial phosphoric ester, (b) a nonionic surfactant, (c) an anionic surfactant and (d) an alkali metal hydroxide. They can be used for wetting and deaerating fibre materials.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: July 4, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Christian Guth, Jorg Haase, Albert Stehlin
  • Patent number: 4842609
    Abstract: Polyester/cotton fabrics are flame retardant treated with a flame-retardant cyclic phosphonate ester and tetrakis-(hydroxymethyl)phosphonium sulfate (THPS), usually applied simultaneously, then cured. The resulting fabrics retain their flame-retardant properties after numerous machine washings and have an acceptable hand.
    Type: Grant
    Filed: July 7, 1988
    Date of Patent: June 27, 1989
    Assignee: Burlington Industries, Inc.
    Inventor: James R. Johnson
  • Patent number: 4828572
    Abstract: The invention relates to a process for dyeing or printing textile fibre materials in stable shades with reactive dyes which produce grey or black dyeings or prints, which process comprises dyeing or printing textile fibre materials with a mixture of heavy metal-containing, water-soluble reactive dyes which produce grey or black dyeings or prints, each component of which mixture, under identical dyeing, printing and fixation conditions, produces dyeings or prints with a tinge different from the tinge of the dyeings or prints produced by the other component, and carrying out subsequent fixation.
    Type: Grant
    Filed: October 13, 1987
    Date of Patent: May 9, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Wolfgang Sutterlin, Rainer Begrich
  • Patent number: 4826503
    Abstract: The invention relates to a process for aftertreating cellulosic material which has been dyed with reactive or direct dyes and subsequently treated in an acid bath. The aftertreatment with a solution of an alkali metal salt or alkaline earth metal salt enhances the wetfastness properties and the tear resistance of the cellulosic material.
    Type: Grant
    Filed: October 9, 1986
    Date of Patent: May 2, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean-Francois Landre
  • Patent number: 4812143
    Abstract: Liquid formulations of disperse dyestuffs for dyeing hydrophobic synthetic fiber materials or mixtures of synthetic fiber materials with cellulose fiber material or wool contain from 0.1 to 10% by weight of pulverulent highly disperse inorganic oxides or silicates or mixtures of both said oxides and silicates having a specific surface area (BET) of 20 to 800 m.sup.2 /g.
    Type: Grant
    Filed: December 7, 1987
    Date of Patent: March 14, 1989
    Assignee: Cassella Aktiengesellschaft
    Inventors: Klaus Hofmann, Ulrich Buhler, Erwin Dietz
  • Patent number: 4808193
    Abstract: Water-soluble compounds having fiber-reactive dye properties of the general formula ##STR1## in which A is an alkylene of 2 to 6 carbon atoms or a phenylene which can be substituted by 1 or 2 substituents, or is a radical of the formula ##STR2## in which W is a direct bond or a bridge member and the R' and R* each denote hydrogen, chlorine, methyl, methoxy, ethoxy, carboxy or sulfo;B is chlorine or fluorine;R is hydrogen, chlorine, an alkyl of 1 to 4 carbon atoms or an alkoxy of 1 to 4 carbon atoms;M is hydrogen or an alkali metal;n stands for the number zero, 1 or 2,K is a radical of the formula ##STR3## in which D is phenylene which can be substituted by chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, carboxy or sulfo, or is naphthalene with optionally 1 or 2 sulfo groups,R.sup.1 denotes hydrogen, chlorine, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms,R.sup.
    Type: Grant
    Filed: May 26, 1988
    Date of Patent: February 28, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ludwig Schlafer, Hartmut Springer, Michael Kunze
  • Patent number: 4806127
    Abstract: Water-soluble disazo compounds conforming to the general formula (1) ##STR1## and their 1:1 copper complex compounds which possess useful fiber-reactive dye properties and are capable of dyeing carboxamido- and/or hydroxy-containing materials, in particular cellulose fibers, in fast shades; wherein:D.sup.1 and D.sup.2 are each a phenylene, which may be substituted, or a naphthylene optionally substituted by sulfo; in the case of the copper complex compounds the ortho-position in D.sup.1 or D.sup.2 or in both being substituted by an oxy group complex-bonded to the copper, or D.sup.1 is a radical of the formula (2a), (2b) or (2c) ##STR2## or D.sup.2 is a radical which is the reverse of formulas (2a), (2b) or (2c), in whichR.sup.1 and R.sup.2 are each independently of the other hydrogen, nitro, sulfo, methyl, ethyl, methoxy or ethoxy;K.sup.1 is a radical of the formula (3a), (3b) or (3c) ##STR3## and K.sup.
    Type: Grant
    Filed: August 27, 1987
    Date of Patent: February 21, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ludwig Schlafer, Hartmut Springer, Reinhard Hahnle
  • Patent number: 4801303
    Abstract: Polyester-cotton blend textile substrates are dyed with a disperse dye and then with a sulfur dye from the same dyebath which is maintained at a temperature no higher than 105.degree. C. when the sulfur dye is present therein and which preferably contains glucose as the reducing agent for the sulfur dye.
    Type: Grant
    Filed: June 1, 1987
    Date of Patent: January 31, 1989
    Assignee: Sandoz Ltd.
    Inventors: Mark S. Carlough, Laszlo A. Meszaros
  • Patent number: 4767420
    Abstract: The transfer sheet or web is intended for the use in a heat transfer printing process of cotton, of cotton-polyester blend or of nitrogen containing textile fibers such as wool, silk or nylon.It comprises on its surface at least one organic impregnating agent which has a melting point between 60.degree. and 230.degree. C. and is no polymer, at least one water insoluble, non-subliming dyestuff, and the minimum amount of a binder. The dyestuff forms a pattern or image which is heat contact printed on said textile substrate without the use of carrier vapors or vacuum. The pattern to be heat transferred may also be prepared in an electrophotographic process using a new toner comprising particles of impregnating agent, binder and dyestuff.The pattern on the transfer support is transferred at a temperature between 160.degree. and 230.degree. C. during 30 to 60 seconds to said textile substrate. The printings obtained have very good light, rubbing and washing fastnesses; the handling is not impaired.
    Type: Grant
    Filed: January 23, 1987
    Date of Patent: August 30, 1988
    Assignee: Sicpa Holding S.A.
    Inventors: Wolfgang Mehl, Albert Amon
  • Patent number: 4764176
    Abstract: The invention relates to a method for preventing the brightening effect of an optical brightening agent on a textile substrate comprising applying on the textile substrate a water-soluble, cationic, optical brightener quencher either before or together with a resin precursor and submitting the treated substrate to a heat treatment. This method imparts an antibrightening effect to goods when they are washed with an optical brightener containing detergent.
    Type: Grant
    Filed: July 16, 1986
    Date of Patent: August 16, 1988
    Assignee: Sandoz Ltd.
    Inventor: Toshinobu Sakamoto
  • Patent number: 4763371
    Abstract: A method for the coloration of textile materials which comprises applying thereto by a printing or continuous dyeing technique a colored polymer containing repeat units derived from at least one organic dye containing two or more polymerizable olefinically unsaturated groups.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: August 16, 1988
    Assignee: Imperial Chemical Industries PLC
    Inventor: Brian Parton
  • Patent number: 4752299
    Abstract: A process for dyeing a mixed fibrous substrate comprising applying to the substrate at least one disperse dye and at least one metal containing direct and/or reactive dye in the presence of a complexing agent having a stability constant K value with the metal of the direct or reactive dye of from 6 to 17 inclusive.
    Type: Grant
    Filed: October 23, 1986
    Date of Patent: June 21, 1988
    Assignee: Sandoz Ltd.
    Inventors: Oskar Annen, John A. Hook
  • Patent number: 4737156
    Abstract: Cationic cellulose graft copolymers obtained by the graft polymerization of a cellulose substrate and a cationic monomer are useful as textile treatment agents, especially as dye enchancers. As pretreatment agents, they improve dye yield, dye levelness and dye fastness properties and as after-treatment agents, they improve dye fastness and crock resistance properties.
    Type: Grant
    Filed: October 27, 1986
    Date of Patent: April 12, 1988
    Assignee: National Starch and Chemical Corporation
    Inventors: Martin Tambor, Jerry L. Cope, John L. Jerome
  • Patent number: 4699625
    Abstract: Textile fabrics containing blends of synthetic fibers and cellulosic fibers are dyed in a continuous process such that the fibers of each class are substantially colored and a union dyeing is obtained. The method comprises continuously impregnating the fabric with a dyebath composition comprising a premetallized dyestuff and a reactive resin. After impregnation, the fabric is subjected to a temperature of from 280.degree. to 400.degree. F. to dry the fabric and to cure the dyebath composition on the fabric.
    Type: Grant
    Filed: February 12, 1986
    Date of Patent: October 13, 1987
    Assignee: Collins & Aikman Corporation
    Inventor: Evans M. Jenkins
  • Patent number: 4693726
    Abstract: Process for dyeing cellulose fibers or cellulose blend fibers, which comprises dyeing the fibers mentioned with water-soluble reactive dyes which contain in the dye molecule at least once the structural element of the formula ##STR1## in which Y denotes a hydroxyl, hydroxymethyl, alkoxy C.sub.1 -C.sub.4, aldehyde, carboxamide, monoalkyl C.sub.1 -C.sub.4 -carboxamide, dialkyl C.sub.1 -C.sub.4 -carboxamide, monophenyl carboxamide, cyano, alkyl C.sub.1 -C.sub.4 -oxycarbonyl or sulfo group or a halogen atom, in an aqueous medium within the pH range 4-11.
    Type: Grant
    Filed: April 3, 1986
    Date of Patent: September 15, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Fritz Meininger, Peter Mischke, Gerd Konig, Hartmut Springer
  • Patent number: 4685933
    Abstract: Concentrated aqueous solutions of dyestuffs having water-solubilizing groups which contain cyanamides of the formula ##STR1## wherein R.sub.1 =NHCN, NHCONH.sub.2 or NHCONHCH.sub.3 where n=0 andm=1 or n=1 and m=0,have a long shelf life, in particular also in the case of reactive dyestuffs.
    Type: Grant
    Filed: June 24, 1985
    Date of Patent: August 11, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Wolff, Karlheinz Wolf, Werner Marschner
  • Patent number: 4682983
    Abstract: The transfer sheet is used for dry thermal printing of water swellable celluluse fibers with dyestuffs which are insoluble in water of 60.degree. C. The dyestuffs are difficult to evaporate and cannot be used in a conventional heat transfer printing process. They are transferred at 230.degree. C. and a contact pressure of 10.sup.4 -10.sup.6 Pa from a base paper provided with a release coating, to cellulose fibers which have been swollen with water and the swollen state of which has been preserved after drying with a polyglycol. I order to increase the penetration of dyestuffs into the textile structure, it is recommended to lower the air pressure in the transfer area down to a pressure ranging from 1 to 5.times.10.sup.4 Pa.
    Type: Grant
    Filed: March 12, 1986
    Date of Patent: July 28, 1987
    Assignee: Sicpa Holding S.A.
    Inventor: Wolfgang Mehl
  • Patent number: 4678476
    Abstract: Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.
    Type: Grant
    Filed: September 26, 1986
    Date of Patent: July 7, 1987
    Assignee: Cassella Aktiengesellschaft
    Inventors: Horst Tappe, Hubert Kruse, Reinhard Kuhn, Albert Bode, Margareta Boos
  • Patent number: 4678473
    Abstract: Cellulosic fibers are converted to cellulosate by immersion in an alkali metal hydroxide and then reacted with an aqueous solution of thioarylsulfonium salts to produce modified cellulosic fibers which are substantive to acid, direct, disperse, reactive and sulfur dyes. Cellulosic/synthetic and cellulosic/wool blends can also be treated to produce a fabric blend comprising modified cellulosic components that are substantive to diverse dye classes and synthetic and wool components which are substantive to a single dye class. When using a disperse dyebath of one color the entire fabric blend is dyed one color. When adding an acid, reactive or sulfur dye of a second color to the dyebath, the synthetic or wool component is dyed one color and the cellulosic component is dyed a different color.
    Type: Grant
    Filed: September 3, 1986
    Date of Patent: July 7, 1987
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: Tyrone L. Vigo, Eugene J. Blanchard
  • Patent number: 4676803
    Abstract: The invention is directed to reactive azo dyestuffs, free from anionic groups and which contain a basic group and a halogenotriazinyl radical and are of the general formula ##STR1## in which D is the radical of an organic azo dyestuff which is free from anionic groups and is preferably free from basic groups,B is a direct bond or a bridge member to a ring C atom of D,R.sub.1 is H, alkyl, aralkyl or aryl andW is a halogenotriazinyl radical containing a basic group; the dyestuffs are useful for the dyeing and printing of fibre materials containing cellulose.
    Type: Grant
    Filed: May 14, 1986
    Date of Patent: June 30, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Robert Kuth, Klaus Wunderlich
  • Patent number: 4666454
    Abstract: A fabric comprising polyethylene terephthalate fibers which exhibits a reduced tendency to pill upon encountering surface abrasion is formed on an expeditious basis. During the polymerization of the monomers required to form the polyethylene terephthalate, a quantity of polyethylene glycol (as described) is copolymerized therewith to form a polymer which exhibits a substantial intrinsic viscosity (as described). Following the melt-extrusion of the polymer to form fibers and fabric formation, the fabric is subjected to a dye bath at an elevated temperature wherein it is dyed, and the intrinsic viscosity of the polymer is reduced (as described). The presence of units derived from polyethylene glycol within the polymer chain has been found to lead to such intrinsic viscosity reduction within the dye bath.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: May 19, 1987
    Assignee: Celanese Corporation
    Inventors: Ronald N. DeMartino, Jeffrey T. Langley, Robert D. Johnson
  • Patent number: 4664670
    Abstract: The transfer sheet or web is intended for the use in a heat transfer printing process of cotton, of cotton-polyester blend or of nitrogen containing textile fibers such as wool, silk or nylon.It comprises on its surface at least one organic impregnating agent which has a melting point between 60.degree. and 230.degree. C. and is no polymer, at least one water insoluble, non-subliming dyestuff, and the minimum amount of a binder. The dyestuff forms a pattern or image which is heat contact printed on said textile substrate without the use of carrier vapors or vacuum. The pattern to be heat transferred may also be prepared in an electrophotographic process using a new toner comprising particles of impregnating agent, binder and dyestuff.The pattern on the transfer support is transferred at a temperature between 160.degree. and 230.degree. C. during 30 to 60 seconds to said textile substrate. The printings obtained have very good light, rubbing and washing fastnesses; the handling is not impaired.
    Type: Grant
    Filed: December 14, 1984
    Date of Patent: May 12, 1987
    Assignee: Sicpa Holding SA
    Inventors: Wolfgang Mehl, Albert Amon
  • Patent number: 4661116
    Abstract: Textile fabrics formed at least partially of cationic dyeable polyester fibers are dyed in a continuous process with an aqueous dyebath comprising(a) 0 to 5 g/l of thickener;(b) cationic dyestuffs in an amount sufficient to dye the cationic dyeable polyester fibers to the desired depth of color;(c) 2 to 100 g/l of a partially sulfated adduct of ethylene oxide with an alkyl phenol or C.sub.8 to C.sub.16 fatty alcohols;(d) 2 to 60 g/l of nonionic or anionic surfactants; and(e) 5 to 50 g/l of at least one organic compound selected from the group consisting of aromatic nitrile ethers and ethoxylated chlorophenols.The fabrics are continuously dyed by padding, immersing, spraying or otherwise applying the dyestuffs, steaming the fabrics in their wet condition, and subsequently washing and drying.
    Type: Grant
    Filed: January 31, 1985
    Date of Patent: April 28, 1987
    Assignee: Collins & Aikman Corporation
    Inventors: Frederick E. Barwick, III, Kyle R. Pearce
  • Patent number: 4659333
    Abstract: The invention relates to a process for fixing azo, metal complex azo and formazan dyes on textile fabrics with hot steam to give stable shades, which process comprises fixing textile fabrics dyed or printed with said dyes in hot steam that contains at least 0.5% by volume of air.
    Type: Grant
    Filed: August 29, 1985
    Date of Patent: April 21, 1987
    Assignee: CIBA-GEIGY Corporation
    Inventor: Andres Schaub
  • Patent number: 4657558
    Abstract: Textile fabrics formed at least partially of polyester fibers are dyed with an aqueous dyebath comprising(a) 0 to 5 g/l of thickener;(b) disperse dyestuffs in an amount sufficient to dye the fibers to the desired depth of color;(c) 2 to 100 g/l of a partially sulfated adduct of ethylene oxide with an alkyl phenyl or C.sub.8 to C.sub.16 fatty alcohols;(d) 0 to 60 g/l of nonionic or anionic surfactants; and(e) 5 to 50 g/l of at least one organic compound selected from the group consisting of aromatic nitrile ethers and ethoxylated chlorophenols.The fabrics may be continuously dyed by padding, immersing, spraying or otherwise applying the dyestuffs, steaming the fabrics in their wet condition, and subsequently washing and drying.
    Type: Grant
    Filed: September 20, 1984
    Date of Patent: April 14, 1987
    Assignee: Collins & Aikman Corporation
    Inventor: Dieter Huxoll
  • Patent number: 4647285
    Abstract: The invention relates to a process for printing cellulosic fibres or cellulose-containing blend fibres with reactive dyes or dye mixtures which contain a reactive dye and subsequent fixation, which comprises printing these materials with a print paste containing at least one water-soluble reactive dye of the formulaD--(X).sub.m (1)in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, nitroaryl, dioxazine, phenazine or stilbene series, X is a fibre-reactive radical of the aliphatic, aromatic or heterocyclic series which is bonded to the radical D either directly or via a bridge member and m is 1, 2, 3, 4, 5 or 6, and salts of aliphatic carboxylic acids having 3 to 18 carbon atoms, and subsequently fixing the print; and to the print pastes used and to their use for printing textile materials.
    Type: Grant
    Filed: September 20, 1985
    Date of Patent: March 3, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Scheibli, Alex Kanzig, Andres Schaub