Polyacrylonitrile Fiber Patents (Class 8/534)
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Advancement of exhaustion, migration, adsorption and fixation of dyestuff to the cellulose materials
Patent number: 12037743Abstract: The present invention relates to a method of dyeing using a salt mixture as an electrolyte with 0.5 to 5.00 GPL of sodium chloride or sodium sulphate and alkali agents I and II to exhaust and fix a dyestuff to a cellulose material in a reactive dyeing. In the method the cellulose fiber is treated with (i) the salt mixture with sodium chloride or sodium sulphate specifically, putting the pre-treated fiber maintained at a pH between 3 and above and an (MLR) maintained between 1:20 and 1:3 at a temperature between 20° C. and above and exhausted for between 15 minutes and above, (ii) the alkali agent I with a pH between 9.5 and above at a temperature between 30° C. and above and stained for between 20 minutes and above (iii) the alkali agent II with a pH between 10.5 and above at a temperature between 30° C. and above and stained for 40 minutes and above.Type: GrantFiled: October 11, 2019Date of Patent: July 16, 2024Inventor: Prabhakaran Parthasarathy -
Patent number: 11946173Abstract: Yarns and fabrics that include modacrylic fibers are described herein. A yarn and/or fabric may include modacrylic fibers, meta-aramid fibers, anti-static fibers, and optionally para-aramid fibers. In some embodiments, the modacrylic fibers, meta-aramid fibers, and, if present, para-aramid fibers, may each be solution-dyed.Type: GrantFiled: May 20, 2020Date of Patent: April 2, 2024Assignee: Glen Raven, Inc.Inventors: Robert Charles Earhart, Mia Rauston Alberto, Christopher Brent Martin
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Patent number: 9156988Abstract: An object of the present invention is provide a disperse dye composition that has the light fastness required of synthetic fiber materials for automotive interiors that are exposed to sunlight at high temperature and high humidity, and that has good blue, red, and yellow dyeability. This object is achieved by a mixed disperse dye composition comprising a blue disperse dye composition having a specific composition ratio of five specific types of disperse dyes, and other specific yellow and/or red disperse dyes. The invention makes it possible to provide a disperse dye composition having not only high fastness of each color but light fastness with a favorable balance of the three primary colors, with the dye properties of each color equal during dyeing, and good dye color reproducibility, as well as by a dyeing method using this dye.Type: GrantFiled: June 7, 2012Date of Patent: October 13, 2015Assignee: Nippon Kayaku Kabushiki KaishaInventors: Yoshiyuki Sato, Toru Yamaguchi
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Patent number: 7824451Abstract: The present invention provides a blue dye mixture which contains the pigments represented by formulae [1], [2], [3], and [4] The present invention also relates to dye mixtures in which there are compounded therewith a yellow dye mixture and/or a red dye mixture. The invention further relates to a method of dyeing polyester-based fibers and dyed polyester-based fibers and dyed polyester-based fiber materials.Type: GrantFiled: June 29, 2004Date of Patent: November 2, 2010Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Toshio Hihara, Wataru Seto, Koichi Fujisaki, Daisuke Hosoda, Hiroshi Inoue
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Patent number: 6695889Abstract: In textile products (e.g. yarns, woven fabrics, knit fabrics) comprising highly crosslinked polyacrylic fibers (made of acrylic fibers by partially hydrolyzing a nitrile group to generate an amido group and a carboxylic acid group), fibers blended with the highly crosslinked polyacrylic fibers can be dyed in an even hue. A pre-dyeing treatment process for such textile products (e.g. yarns, woven fabrics, knit fabrics) comprising highly crosslinked polyacrylic fibers comprises a pretreatment step of immersing the textile product into an acidic solution and treating it at a high temperature and an elevated pressure. A dyeing process comprises the steps of conducting this pre-dyeing treatment process, and thereafter conventionally dyeing fibers blended with the highly crosslinked polyacrylic fibers. A pretreated and undyed textile product and a dyed textile product are obtained by the pre-dyeing treatment process and the dyeing process mentioned above, respectively.Type: GrantFiled: September 14, 2001Date of Patent: February 24, 2004Assignees: Sakaren Co., Ltd., Mizuno Corp.Inventors: Takamasa Sakamoto, Tsutomu Shiotani, Takeshi Ogino
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Patent number: 6596035Abstract: A single composition for simultaneous coloring and highlighting hair to provide hair fibers having variations in tonality and hue, comprising, 1-10% inorganic persulfate, 1-20% hydrogen peroxide, 0.001-20% of at least one primary intermediate and, optionally, at least one coupler for the formation of oxidation dyes; and 0.01-20% of one or more surfactants; as well as a one step method for simultaneously color and highlighting hair to provide hair fibers having variations in tonality and hue comprising, combining, immediately prior to use, a powder composition comprised of at least one alkali metal or alkaline earth metal persulfate, an aqueous developer composition comprised of hydrogen peroxide; and an aqueous based colorant composition comprised of at least one primary intermediate and, optionally, at least one coupler for the formation of oxidation dyes; and applying the mixture to the hair for a period of time sufficient to cause coloration and highlighting of the hair.Type: GrantFiled: April 30, 2001Date of Patent: July 22, 2003Assignee: Revlon Consumer Products CorporationInventors: Glen Alan Gutkowski, Alexander Chan, Shailendra Kumar Singh
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Patent number: 6527815Abstract: Textiles made of synthetic fibers and synthetic fiber blended fabrics are constructed in the form of a garment then dyed while avoiding setting permanent creases and permanent wrinkles in the garment. The process includes selecting a synthetic or synthetic blended fabric for the dyeing process by determining the fabric's shrinkage in the warp and fill directions, for instance no greater than 6%, constructing a garment from the fabric selected, then dyeing the constructed garment in an aqueous dyebath at a temperature in the range of 220 to 260° F. for a time sufficient to achieve a desired shade and levelness of color followed by drying and optionally pressing the dyed garment.Type: GrantFiled: September 13, 2000Date of Patent: March 4, 2003Assignee: Burlington Industries, Inc.Inventors: Katherine T. Bryant, John E. Newbern, Earl E. Bradsher, III, Terry L. Currans, G. Lewis Best, III, Ashutosh Karnik, John W. McAnulty
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Patent number: 6042616Abstract: A method for finishing a cellulose fiber-containing textile fabric comprises treating a cellulose fiber-containing textile fabric with liquid ammonia, applying a resin finishing agent to said fabric, subjecting subsequently to either or both of a hot calendering treatment and a heat treatment, and finally treating the resultant fabric with hot water. The resultant fabric keeps its shape stability including a crease or shrink resistance when washed, without involving any problem on residual formaldehyde.Type: GrantFiled: September 8, 1998Date of Patent: March 28, 2000Assignee: Nisshinbo Industries, Inc.Inventors: Yuichi Yanai, Masayoshi Oba, Kazuhiko Ichimura, Yasushi Takagi, Kazuhiko Harada
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Patent number: 5403361Abstract: A process for dyeing textile fiber materials with water-soluble dyestuffs, in particular anionic dyestuffs, and of these in particular those having a fiber-reactive group, in which the dyeing is carried out using low-electrolyte or entirely electrolyte-free and/or low-alkali or entirely alkali-free dye liquors or printing pastes and a fiber material which has been modified with a silane compound containing amino groups is used as the textile material. The fiber material is modified by applying the silane compound containing amino groups to the material in aqueous solution and subjecting the impregnated material to a heat treatment. Novel silane compounds which contain a secondary amino group and can likewise be employed for the purpose mentioned are furthermore described.Type: GrantFiled: August 12, 1993Date of Patent: April 4, 1995Assignee: Hoechst AGInventors: Andreas Schrell, Werner H. Russ, Thomas Riehm, Tilo Vaahs
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Patent number: 5286854Abstract: Basic azo dyes useful for dyeing or printing polymeric material have the formula ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkanoylamino,R.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or a radical of the formula CO-X, andX is hydroxyl, C.sub.1 -C.sub.4 -alkoxy, amino, mono- or di(C.sub.1 -C.sub.6 -alkyl)amino or a radical of the formula ##STR2## where n is 0 or 1,R.sup.3, R.sup.4 and R.sup.5 are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,R.sup.6 is hydrogen or C.sub.1 -C.sub.4 -alkyl,L is C.sub.2 -C.sub.6 -alkylene, andAn.sup..crclbar. is one equivalent of an anion,with the proviso that at least one basic or quaternary radical is present in the molecule.Type: GrantFiled: December 30, 1992Date of Patent: February 15, 1994Assignee: BASF AktiengesellschaftInventors: Erwin Hahn, Heidi Hengelsberg, Udo Mayer
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Patent number: 5223000Abstract: Mixtures of different oligomer compounds of formula (1) are suitable for use as direct dyes for dyeing and printing a wide range of materials, especially cellulose fibers, to give dyeings and prints of good all-round fastness properties: ##STR1## wherein R.sub.1 is hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or aralkyl, R independently has the meaning of R.sub.1 or is an unsubstituted or substituted heteroaryl radical or a radical of formula ##STR2## wherein R.sub.4 is unsubstituted or substituted alkyl, cycloalkyl, aryl, aralkyl or heteroaryl, A is an unsubstituted or substituted alkylene, cycloalkylene, arylene or aralkylene radical, X is --O--, --S-- or --N(R.sub.5)--, wherein R.sub.5 is hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or aralkyl, or wherein the group ##STR3## is an unsubstituted or substituted heterocyclic radical, Y is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, sulfo, carboxy, carbamoyl, N-mono- or N,N-di-C.sub.1 -C.sub.Type: GrantFiled: October 28, 1991Date of Patent: June 29, 1993Assignee: Ciba-Geigy CorporationInventor: Urs Lauk
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Patent number: 5215545Abstract: Poly(m-phenyleneisophthalamide) fabrics are printed and optionally flame retarded in a two-step process in which the dye diffusion promoting agent N-octyl-2-pyrrolidone optionally with a flame retardant is applied following by printing and print fixation.Type: GrantFiled: March 16, 1992Date of Patent: June 1, 1993Assignees: Burlington Industries, Inc., ProChroma Technologies, Inc.Inventors: Barbara J. Cates, Phillip H. Riggins, David R. Kelly
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Patent number: 5211720Abstract: Thermoplastic fabrics are flame retardant treated and optionally heatset and/or simultaneously dyed in a heated flame retardant liquid in which a disperse or acid dye may be dissolved. Flame-resistant fabrics result.Type: GrantFiled: June 20, 1988Date of Patent: May 18, 1993Assignee: Burlington Industries, Inc.Inventor: James R. Johnson
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Patent number: 5167668Abstract: In an existing isothermal dyeing process, the alkali required for dye fixation is added to the neutral dyebath under linear or progressive program control. In this process, the amount of alkali added per unit time is small at the beginning and is increased progressively and in accordance with a program. This process passes through a certain (non-controlable) initial phase until the start of dye fixation on the cellulose. As a consequence the rate of fixation passes through a maximum before gradually decreasing when the final state of the dyeing is reached. To shorten the initial phase (waiting time) of dye fixation and to slow down dye fixation during the steepest part, it has proved advantageous according to the invention to add the alkali in accordance with a parabolic program.Type: GrantFiled: November 26, 1990Date of Patent: December 1, 1992Assignee: Hoechst AktiengesellschaftInventors: Manfred Hahnke, Pablo Canora
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Patent number: 5013328Abstract: A substrate to which a dyestuff or optical brightener has been applied is aftertreated with a cationic or protonatable polymeric Product P selected from:(A) a polymeric reaction product, Product A, of a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups with cyanamide, dicyanamide, guanidine or bisguanidine in which up to 50 mole percent of the cyanamide, dicyanamide, guanidine or bisguanidine may be replaced by a dicarboxylic acid or a mono- or di-ester thereof, with the splitting off ammonia, optionally in the presence of a catalyst; Product A containing at least one free hydrogen atom linked to a nitrogen atom; or(B) the polymeric reaction product, Product B, of Product A with(a) epichlorohydrin or a precursor thereof; or(b) an N-methylol derivative of a urea, melamine, guanamine, triazinone, urone, carbamate or acid amine optionally in the presence of a catalyst for crosslinking N-methylol compounds; or(c) a water-soluble homo- or co-polymer, PrType: GrantFiled: November 15, 1989Date of Patent: May 7, 1991Assignee: Sandoz Ltd.Inventors: Oskar Annen, Bernhard Schlick
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Patent number: 4913705Abstract: A mixed fabric of hydroxy group-containing fibers and cyano and/or carboxy group-containing fibers, the hydroxy group-containing fibers having been dyed with a reactive dye, is aftertreated with a product of reacting a mono- or polyfunctional amine having one or more primary, secondary and/or tertiary amino groups with cyanamide, dicyandiamide guanidine or bis-guanidine, said product containing at least one reactive hydrogen atom linked to a nitrogen atom, and is then dyed with a basic dye.Type: GrantFiled: September 2, 1988Date of Patent: April 3, 1990Assignee: Sandoz Ltd.Inventors: Bernhard Schlick, Claudio Artico
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Patent number: 4881941Abstract: A textile substrate is dyed by immersing it in a gathered configuration into an oil medium containing a dissolved or dispersed dye for a sufficient time to allow the oil medium to come into contact with part but not all of the surface of the substrate and the thus-treated substrate is then preferably immersed in an aqueous medium having another dye dissolved or dispersed therein.Type: GrantFiled: July 12, 1988Date of Patent: November 21, 1989Assignee: Sandoz Ltd.Inventor: Michael W. Dixon
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Patent number: 4852991Abstract: The invention relates to a process for dyeing synthetic or natural polyamide fibers with anionic dyestuffs, comprising (i) bringing the polyamide fibers into contact with an aqueous dyeing liquor which contains in addition to one or more dyestuffs a cationic dyeing assistant having affinity for anionic polyamide dyestuffs, and dyeing the polyamide fibers at a temperature of from 60.degree. to 105.degree. C., and (ii) adding an anionic dyeing assistant to the dyeing liquor 15 to 60 minutes after reaching the dyeing temperature, to complete the dye exhaustion. Surface and fibre level dyeings with a good dye penetration are thus obtained.Type: GrantFiled: March 3, 1988Date of Patent: August 1, 1989Assignee: Sandoz Ltd.Inventors: Josef Frauenknecht, Dieter Schwer
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Patent number: 4844710Abstract: Aqueous textile assistants of high storage stability and hard water resistance comprising at least (a) a partial phosphoric ester, (b) a nonionic surfactant, (c) an anionic surfactant and (d) an alkali metal hydroxide. They can be used for wetting and deaerating fibre materials.Type: GrantFiled: November 30, 1987Date of Patent: July 4, 1989Assignee: Ciba-Geigy CorporationInventors: Christian Guth, Jorg Haase, Albert Stehlin
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Patent number: 4840641Abstract: Cationic diazacyanine dyestuffs of the formula ##STR1## and their mixtures with the isomeric dyestuffs of the formula ##STR2## wherein R represents methyl or ethyl andX.sup.- represents a colorless anion, are suitable for dyeing polyacrylonitrile and, in particular, polyacrylonitrile-wool mixtures.Type: GrantFiled: April 4, 1988Date of Patent: June 20, 1989Assignee: Bayer AktiengesellschaftInventor: Alfred Brack
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Patent number: 4693726Abstract: Process for dyeing cellulose fibers or cellulose blend fibers, which comprises dyeing the fibers mentioned with water-soluble reactive dyes which contain in the dye molecule at least once the structural element of the formula ##STR1## in which Y denotes a hydroxyl, hydroxymethyl, alkoxy C.sub.1 -C.sub.4, aldehyde, carboxamide, monoalkyl C.sub.1 -C.sub.4 -carboxamide, dialkyl C.sub.1 -C.sub.4 -carboxamide, monophenyl carboxamide, cyano, alkyl C.sub.1 -C.sub.4 -oxycarbonyl or sulfo group or a halogen atom, in an aqueous medium within the pH range 4-11.Type: GrantFiled: April 3, 1986Date of Patent: September 15, 1987Assignee: Hoechst AktiengesellschaftInventors: Fritz Meininger, Peter Mischke, Gerd Konig, Hartmut Springer
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Patent number: 4645510Abstract: The invention provides a process for the exhaust dyeing with a reactive dyestuff of a textile material comprising cellulosic fibres, which process comprises the step of adding to the dyebath containing the reactive dyestuff, simultaneously the salt and the alkali in specified quantities metered per unit time so as to give a substantially linear exhaustion of the dyebath.Type: GrantFiled: May 24, 1985Date of Patent: February 24, 1987Assignee: Sandoz Ltd.Inventors: Rolf Hasler, Francis Palacin
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Patent number: 4629465Abstract: The invention relates to a process for exhaust dyeing a textile fibre substrate to obtain level dyeings, which process comprises the step of adding to the dyebath the effective amount of dyestuff or electrolyte or dyestuff and electrolyte either simultaneously or one after the other in specified quantities per cycle of the dyeing machine, metered according to a mathematical function.Type: GrantFiled: October 1, 1984Date of Patent: December 16, 1986Assignee: Sandoz Ltd.Inventors: Rolf Hasler, Francis Palacin
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Patent number: 4604101Abstract: Dyeings on hydroxy group- or nitrogen-containing fibres are improved by aftertreatment, simultaneously or sequentially, with (A) a polymeric reaction product of an amine with cyanamide, dicyandiamide, quanidine or bisguanidine and (B) a quaternary polyalkylene polyamine. A synergistic effect between (A) and (B) is observed.Type: GrantFiled: February 21, 1985Date of Patent: August 5, 1986Assignee: Sandoz Ltd.Inventors: Bruno Kissling, Tibor Robinson
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Patent number: 4501589Abstract: A process for dyeing or printing sized textiles comprising applying to the sized substrate a dyeing liquor or a printing paste which contains, in addition to the dyestuffs(i) a compound or a mixture of compounds selected from compounds having solubilizing, washing, emulsifying, dispersing or dye fixation accelerating properties, and(ii) a textile size or a mixture of textile sizes.Type: GrantFiled: June 10, 1983Date of Patent: February 26, 1985Assignee: Sandoz Ltd.Inventor: Christian Oschatz
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Patent number: 4465490Abstract: A process for the continuous dyeing of fabric webs, in which the fabric web is impregnated at a temperature between 20.degree. and 95.degree. C. with an aqueous liquor which contains dissolved and/or dispersed dyestuffs and squeezed, and the dyestuffs are fixed in a steam/air mixture, which comprises fixing the dyestuff without the impregnated fabric having been dried at an intermediate stage, keeping the dry temperature of the steam/air mixture between 110.degree. and 140.degree. C., adjusting the steam content of the steam air mixture in such a way that the wet temperature of the moist fabric web is between 50.degree. and 95.degree. C., and fixing the dyestuffs for at least 20 seconds.Type: GrantFiled: February 16, 1983Date of Patent: August 14, 1984Assignee: Hoechst AktiengesellschaftInventor: Hans-Ulrich von der Eltz
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Patent number: 4427414Abstract: Described herein is a process for the coloration of short pile fabrics, the process enabling the manufacture of various colors of pile fabric from a single intermediate fabric, the intermediate fabric having a precolored, undyeable, transparent face fiber.Type: GrantFiled: April 12, 1982Date of Patent: January 24, 1984Assignee: Badische CorporationInventor: Denis G. Orton
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Patent number: 4421519Abstract: There are described novel dye mixtures of the dyes I and II or Ia and II ##STR1## wherein the symbols have the meanings defined in claim 1. These mixtures can be used in particular for dyeing and printing polyacrylonitrile materials, or mixed fabrics of polyacrylonitrile and wool, the dyeings obtained having a clear, deeply colored blue shade and especially a very good evening shade.Type: GrantFiled: June 7, 1982Date of Patent: December 20, 1983Assignee: Ciba-Geigy CorporationInventors: Peter Loew, Rudolf Zink
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Patent number: 4362530Abstract: A composition containing(A) 10 parts by weight of an anionic product obtained by addition of 5 to 20 mols of ethylene oxide to an aliphatic saturated or unsaturated alcohol of 10 to 24 carbon atoms, followed by carboxymethylation(B) 1 to 15 parts by weight of a cationic addition product of 50 to 150 mols of ethylene oxide to a fatty amino-(C.sub.2-3)alkylene-amine(C) 1 to 10 parts by weight of a non-ionic addition product of 20 to 150 mols of ethylene oxide to castor oil, or a non-ionic sequenced addition product of 20 to 150 mols of ethylene oxide and 1 to 10 mols of propylene oxide to castor oil, and(D) 1 to 20 parts by weight of a N-(.beta.-hydroxy-(C.sub.2-4)alkyl)-fatty acid amide,is a dyeing auxiliary useful for the dyeing in one bath or printing of a mixed textile substrate comprising cationic dyeable fibres and anionic or disperse dyeable fibres.Type: GrantFiled: March 19, 1981Date of Patent: December 7, 1982Assignee: Sandoz Ltd.Inventors: Rolf Gross, Rene Fricker
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Patent number: 4297103Abstract: Process for the continuous one-bath dyeing of pile fabrics made of acrylic fibres in the pile with a cotton base fabric by the pad-steam process with basic and substantive dyestuffs, characterized in that salts of alkyl sulphates of the general formulaR--O--SO.sub.3.sup..crclbar. M.sup..sym.in whichR represents a straight-chain or branched alkyl radical with 10-16 carbon atoms andM represents an alkali metal, alkaline earth metal, ammonium, alkylammonium or alkanolammonium ion,are used as auxiliaries in the dyebath.Type: GrantFiled: October 26, 1979Date of Patent: October 27, 1981Assignee: Bayer AktiengesellschaftInventors: Udo-Winfried Hendricks, Klaus Wollny
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Patent number: 4294577Abstract: The invention contemplates a flocked fabric and method wherein flock is adhered by a heat-cured flock adhesive to a substrate fabric and wherein a heat-sublimable dye is contained as a component of the adhesive and/or as preprint of the substrate fabric, the adhesive having a curing time and temperature at which such dye substantially sublimes. Various examples are given to achieve different selectively available color patterns and contrasts, as well as different selectively available surface textures in the dyed product.Type: GrantFiled: March 25, 1980Date of Patent: October 13, 1981Assignee: Pervel Industries, Inc.Inventor: Leo N. Bernard
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Patent number: 4288226Abstract: A novel process for the continuous dyeing of cellulose textile material with anionic substantive dyes is disclosed. The process consists initially in applying to the cellulose material an aqueous liquor which, in addition to the dye, contains(A) 2.5 to 15 g/l of an etherified N-methylolmelamine,(B) an acid catalyst and at least one of the components(C) an anionic surfactant,(D) a non-ionic surfactant and(E) an organic solvent which boils above 140.degree. C.The material is then dried, if desired, and subsequently subjected to a heat treatment. An increase in dye yield of 100 to 400% is obtained with this process in continuous dyeing, especially in a pad-thermofix process. The dyeings are level and have excellent wetfastness and lightfastness properties.Type: GrantFiled: September 20, 1979Date of Patent: September 8, 1981Assignee: Ciba-Geigy CorporationInventor: Heinz Abel
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Patent number: 4233028Abstract: Described is a process for the level dyeing of polyacrylonitrile materials of slow, normal and rapid absorptive capacity with an aqueous dye liquor, which process comprises using a liquor containing at least one migrating cationic dye as well as, if required, further additives; and adding to the liquor, before, during or after dyeing, at least one organic cationic migration auxiliary.This process renders possible by the use of organic migration auxiliaries the obtainment of level single-shade and, in particular, combination-shade dyeings at normal dyeing temperatures.Particularly suitable migrating cationic dyestuffs are those having a more or less delocalized positive charge, the cation weight of which dyestuffs is smaller than 310, the parachor smaller than 750 and the log P (relative lipophil property) smaller than 3.6.Particularly suitable organic migration auxiliaries are those of which the cation weight is smaller than 250, the parachor smaller than 700 and the log P smaller than 6.4.Type: GrantFiled: January 24, 1978Date of Patent: November 11, 1980Assignee: Ciba-Geigy CorporationInventors: Josef Koller, Ulrich Horn, Peter Moser, Manfred Motter, Pierre Galafassi