Fiber Derived From Saponified Cellulose Esters Or From Nitrocellulose Converted To Cellulose, Dye Composition, Process, Or Product Patents (Class 8/536)
  • Patent number: 10093790
    Abstract: The present invention relates to a three-dimensional cellulosic molded body that has an optically detectable core/shell structure, the shell having a higher density and a lower crystallinity than the core, and the core having a sponge-like structure. The invention further relates to a method for producing this molded body as well as to its use, especially in the cosmetics and pharmaceutical industries.
    Type: Grant
    Filed: November 14, 2014
    Date of Patent: October 9, 2018
    Assignee: Lenzing Aktiengesellschaft
    Inventors: Martin Häubl, Josef Innerlohinger, Christian Schirk
  • Patent number: 8170013
    Abstract: The present invention relates to a sending device able to send packets in a network comprising at least two stations, the said device comprising means for extracting image pips on the basis of a synchronization signal, initializing an image counter on the basis of the image pips, initializing a counter every “m” zero-crossings of the image counter, the counter being regulated by a clock produced by the image counter, sampling the counter every period Tsmp, where Tsmp emanates from a time base synchronized on all the stations of the said network; and sending packets containing the samples of the counter in the network.
    Type: Grant
    Filed: June 6, 2008
    Date of Patent: May 1, 2012
    Assignee: Thomson Licensing
    Inventors: Thierry Tapie, Serge Defrance, Izabela Grasland
  • Patent number: 8167958
    Abstract: The present invention relates to a process for dyeing sheetlike textile materials with a dye, which comprises a concentrated dye system being applied in a total amount of 1% to 25% by weight, based on the textile material, to the textile material in two or more sub-steps and the dye being fixed on the textile material after each and every sub-step.
    Type: Grant
    Filed: August 14, 2009
    Date of Patent: May 1, 2012
    Assignee: DyStar Colours Deutschland GmbH
    Inventors: Christian Meyer, Wolfgang Schrott, Franz Sütsch
  • Publication number: 20040205912
    Abstract: The present invention relates to novel compounds of the formulae A, D1, D2, R1 and n are as defined in the description the compounds being in an internal or external salt form, or mixtures of compounds (1) and (2), a process for their preparation and preparations containing them used for dyeing paper.
    Type: Application
    Filed: January 17, 2004
    Publication date: October 21, 2004
    Inventors: Michaeal Lennartz, Dolf Kaser, Sandra Weiss
  • Publication number: 20030182738
    Abstract: A process of dyeing a molded article is disclosed. The process entails immersing at least a portion of the article in a dyeing bath, retaining the portion in the bath for a period of time sufficient to allow an amount of dye to diffuse into the article, and removing said article from the bath. The molded article comprises a polymeric resin such as (co)polyester, (co)polycarbonates, acrylonitrile-butadiene-styrene, polyamide, polyurethane, polyalkyl(meth)-acrylate, allyldiglycol carbonate and styrene copolymers. The dyeing bath contains in addition to dye, water, a plasticizing agent and a leveling agent.
    Type: Application
    Filed: March 26, 2002
    Publication date: October 2, 2003
    Inventors: Robert A. Pyles, Rick L. Archey
  • Publication number: 20030167581
    Abstract: The invention provides dyed yarn characterized by comprising dyed polytrimethylene terephthalate fiber, having an elastic recovery of 60% or greater under 10% elongation, and having a boiling water shrinkage of no greater than 4%. The dyed yarn of the invention has excellent stretchability and dimensional stability as well as a soft feel, and is therefore suitable for use in fabrics.
    Type: Application
    Filed: November 13, 2002
    Publication date: September 11, 2003
    Inventors: Hiroshi Yamazaki, Kazuto Oue, Mitsuyuki Yamamoto
  • Publication number: 20030135939
    Abstract: Textile materials, including paper webs, treated with a polyvinylamine polymer and a second agent that interacts with the polyvinylamine polymer is disclosed. The second agent added with the polyvinylamine polymer can be, for instance, a polymeric anionic reactive compound or a polymeric aldehyde-functional compound. When incorporated into a paper web, the combination of the polyvinylamine polymer and the second agent provide improved strength properties, such as wet strength properties. In an alternative embodiment, the polyvinylamine polymer and the second polymer can be applied to a textile material for increasing the affinity of the textile material for acid dyes.
    Type: Application
    Filed: December 18, 2001
    Publication date: July 24, 2003
    Inventors: Tong Sun, Jeff Lindsay
  • Publication number: 20030005527
    Abstract: The present invention is a thickened dye composition and method of applying same to a paper web that produces colored or patterned paper having good bleed resistance. The dye composition of the invention includes a binder; a dye; a thickener selected from the group consisting of polyvinylpyrrolidone homopolymers, polyvinylpyrrolidone copolymers, and mixtures thereof; and water. The present invention also includes colored or patterned papers prepared using this dye composition.
    Type: Application
    Filed: July 3, 2001
    Publication date: January 9, 2003
    Applicant: BASF CORPORATION
    Inventors: James A. Deckers, Stephen S. Jose, Michael T. Jennings
  • Publication number: 20020189035
    Abstract: The present invention relates to novel dyed cellulosic molded bodies, in particular to fibers or films, containing a heavy-metal-containing colorant, which, according to the thermal stability test described above, reduces the rise temperature of a cellulose solution in a tertiary amine oxide by 10° C. at most, in particular by 5° C. at most. The molded bodies according to the invention may be produced in accordance with the amine-oxide process (FIG. 1).
    Type: Application
    Filed: February 8, 2002
    Publication date: December 19, 2002
    Applicant: LENZING AKTIENGESELLSCHAFT
    Inventor: Hartmut Ruf
  • Publication number: 20020069468
    Abstract: A process for dyeing a fibrous substrate which comprises the steps of: providing a fibrous substrate; providing at least one sulfur dye; providing at least one reduction stable direct dye; and applying said reduction stable direct dye and sulfur dye to said fibrous substrate in the presence of a suitable reducing agent. Further, it has been surprising to find that these reduction stable direct dyes can be processed without a sulfur dye present. This results in a process for dyeing a fibrous substrate which comprises the steps of: providing a fibrous substrate; providing a reduction stable direct dye; and applying said reduction stable direct dye to said fibrous substrate in the presence of a suitable reducing agent.
    Type: Application
    Filed: July 3, 2001
    Publication date: June 13, 2002
    Applicant: Clariant Finance (BVI) Limited
    Inventors: J. Michael Hipp, Mark S. Carlough, William T. Sherrill, Peter J.V. Stahala
  • Publication number: 20020038484
    Abstract: Disclosed are dye mixtures for shading white paper which may contain fluorescent brightener. The dye mixtures comprise a violet dye according to the formula (1) or (2) indicated in claim 1 and sufficient of a red, blue or further violet anionic azo dye that this dye mixture is capable of producing in the Cielab colour co-ordinates system a relative hue angle of 270 to 295° when the dyeing contains 0.00005 to 0.005% by weight of dye, based on the weight of the paper, with the proviso that the value 0.005% is excluded.
    Type: Application
    Filed: July 11, 2001
    Publication date: April 4, 2002
    Inventors: Adolf Kaser, Wolfgang Schlenker
  • Publication number: 20020010971
    Abstract: The aqueous dye solutions of the composition shown in claim 1 are distinguished by a good storage stability and are suitable for dyeing paper in red color shades.
    Type: Application
    Filed: April 17, 2001
    Publication date: January 31, 2002
    Inventors: Alfred Hohener, Roland Frick, Adolf Kaeser
  • Patent number: 6320031
    Abstract: Monoazo dyes of formula (3) wherein A, R1, R2, M and n are as defined in the specification, are excellent dyes for dyeing and printing of cellulose containing materials and especially for the preparation of inks for ink jet printing.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: November 20, 2001
    Assignee: Ilford Imaging Switzerland GmbH
    Inventors: Kurt Baettig, Gérald Jan
  • Patent number: 6307007
    Abstract: New water-soluble polycondensation products are obtained by reaction of polyfunctional amines with cyanamide, its derivatives or polymers in the presence of sulfamic acid. They are excellent fixing agents which improve fastness properties of dyeings with substantive dyestuffs on cellulose fiber materials, paper, board and non-wovens.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: October 23, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Jürg Heller, Alec Tindal
  • Publication number: 20010013149
    Abstract: Process for dyeing or printing paper, films of plastic or fiber material containing hydroxyl groups or containing nitrogen with reactive dyes, which comprises using at least one reactive dye of the formula (1) from the following group a) and at least one reactive dye from the following groups b), c) and d):
    Type: Application
    Filed: January 31, 2001
    Publication date: August 16, 2001
    Inventors: Peter Scheibli, Peter Aeschlimann, Urs Lehmann, Marcel Frick
  • Patent number: 5981741
    Abstract: Disclosed are aminated acetate fiber comprising acetylcellulose and one or more water-insoluble quaternary starch ether esters, said starch ether esters containing ester groups of formulae --O--CO--CH.sub.3 and/or --O--CO--C.sub.2 H.sub.5 and ether groups of the general formula I--O--CH.sub.2 --X--CH.sub.2 --N.sup.+ R.sub.3 A.sup.- (I)whereX is a direct bond or --CH(OH)-- andA.sup.- is an anion or one equivalent of an anion, andR is hydrogen, methyl and/or ethyl,and the degree of substitution of said ether group being within the range from 0.002 to 0.8, the degree of substitution of said ester group being within the range from 0.7 to 2.998 and the overall degree of substitution being within the range from 1.5 to 3, its preparation and its use and also quaternary starch ether esters present therein.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: November 9, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Andreas Schrell, Jimmy G. Welborn
  • Patent number: 5830574
    Abstract: Melamine fibers and cellulose fiber combinations are dyed with certain dyes such that the cellulose fiber is dyed by the dyes but the melamine fiber is substantially undyed. When in fabric form, a chambray appearance is given.
    Type: Grant
    Filed: April 24, 1997
    Date of Patent: November 3, 1998
    Assignee: BASF Corporation
    Inventor: Dean R. Gadoury
  • Patent number: 5476518
    Abstract: A process for treating a dyed, velvet fabric is disclosed wherein two-toned color effects between the pile and the fabric backing are achieved. The preferred fabric comprises a cellulosic (cotton or rayon) or synthetic fiber weave backing dyed preferably with a non-disperse dye, e.g. a direct dye, and pile composed of cellulose acetate fibers dyed with a disperse dye. The dyed fabric is contacted with a dilute caustic solution, e.g., sodium hydroxide, for a period of time sufficient to at least partially or totally hydrolyze the cellulose acetate of the pile fiber, which noticeably also reduces the color intensity of the pile while having little effect on the color intensity of the backing. This is followed by rinsing, neutralization and conditioning of the treated fabric.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: December 19, 1995
    Assignee: A. Wimpfheimer & Bro., Inc.
    Inventor: Nicholas Caleshu
  • Patent number: 5216139
    Abstract: Thiopheneazo dyes of the formula ##STR1## where R.sup.1 is cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, phenylazo, phenylsulfonyl, formyl or the radical ##STR2## where R.sup.7 and R.sup.8 are independently of the other cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, phenyl, halogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl, or R.sup.1 and R.sup.2 together are the radical (CH.sub.2).sub.3 --CO, which may be substituted by 1 or 2 methyl groups and whose carbonyl group is bonded to the thiophene ring in the ortho position relative to the sulfur atom,R.sup.3 is cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, cyclohexyl, phenoxy-C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, or substituted or unsubstituted thienyl,R.sup.5 is C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.7 -alkyl whose alkyl chain is interrupted by 1 or 2 oxygen atoms, or C.sub.1 -C.sub.4 -alkoxy andR.sup.6 is cyanoethyl, phenylethyl or C.sub.3 -C.sub.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: June 1, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Guenter Hansen, Gunther Lamm, Helmut Reichelt
  • Patent number: 5175265
    Abstract: Benzisothiazole-azo dyes useful for dyeing synthetic fiber materials have the formula ##STR1## where X is hydrogen, chlorine, bromine, cyano or nitro and K is a radical of the formula ##STR2## where R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.12 -alkyl, substituted or unsubstituted phenyl, C.sub.3 -C.sub.5 -alkenyl or C.sub.5 -C.sub.7 -cycloalkyl,R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.3 is hydrogen or methyl andR.sup.4 is hydrogen, cyano, carbamoyl or C.sub.1 -C.sub.4 -alkoxycarbonyl.
    Type: Grant
    Filed: March 5, 1990
    Date of Patent: December 29, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenter Hansen, Helmut Hagen, Helmut Reichelt
  • Patent number: 4935499
    Abstract: Paper is colored by a process in which a compound which, in the form of the free acid, is of the formula I ##STR1## where, in each case independently of one another, A is unsubstituted or methyl substituted C.sub.1 -C.sub.6 -alkylene or vinylene,R is each hydrogen or C.sub.1 -C.sub.4 -alkyl,X is each --CO-- or --SO.sub.2 --,K is each a cationic group andY is hydrogen, chlorine or bromine.
    Type: Grant
    Filed: September 27, 1988
    Date of Patent: June 19, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Ruske, Hans-Juergen Degen
  • Patent number: 4764585
    Abstract: Cationic fixing agents based on the reaction products of(a) a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups and(b) cyanamide, dicyandiamide, guanidine or bisguanidinegive improved results when the reaction takes place in the presence of a catalyst (K) selected from metals, metal salts and heterocyclic nitrogen-containing organic bases, particularly zinc chloride.
    Type: Grant
    Filed: September 15, 1987
    Date of Patent: August 16, 1988
    Assignee: Sandoz Ltd.
    Inventors: Jurg Heller, Bruno Kissling, Curt Muller, Tibor Robinson, Salvatore Valenti
  • Patent number: 4600776
    Abstract: Cationic enamine dyestuffs of the general formula ##STR1## in which the symbols have the meaning given in the description, are used for dyeing natural and synthetic substrates and compositions which can be dyed with cationic dyestuffs, in particular paper.
    Type: Grant
    Filed: June 11, 1984
    Date of Patent: July 15, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karlheinrich Meisel, Roderich Raue
  • Patent number: 4585864
    Abstract: Silane quinacridone dyes, composite pigments obtainable therefrom by association with an inorganic substrate, and the processes for preparing them. The dyes have the general formula: ##STR1## wherein X is an --SO.sub.2 NHR group, where R is an alkyl group, linear or branched, having from 1 to 6 carbon atoms, a cycloalkyl group, a phenyl group optionally substituted by one or more alkyl or alkoxy groups (C.sub.1 -C.sub.6), a halogen; Y and Z indicate a silane group having the formula: ##STR2## wherein R.sub.1 is an alkoxy group (C.sub.1 -C.sub.2), R.sub.2 is an alkyl group (C.sub.1 -C.sub.4) or a phenyl group; n is 3, 4 or 5; q is 0 or 1; p and m are integers, such that when q is 1, p is 2 and m is 0, 1 or 2, and when q is 0, p is 3 and m is 0, 1, 2 or 3; W indicates an --SO.sub.3 H group; a, b and c are 0 or 1, selected in such a way that the sum a+b+c is equal to 1.
    Type: Grant
    Filed: December 18, 1984
    Date of Patent: April 29, 1986
    Assignee: Montedison S.p.A.
    Inventors: Antonio Marraccini, Filippo M. Carlini, Antonio Pasquale, Michele Pontevivo
  • Patent number: 4556625
    Abstract: The present invention discloses a method of photolytically developing a colored image on a cellulosic material. In this method, the material is contacted with a nitrogen containing polymer in solution and a mono-sulfonyl azide compound in solution. The sample is thereafter exposed to a UV-containing light source for an amount of time sufficient to develop a color thereon.
    Type: Grant
    Filed: November 25, 1983
    Date of Patent: December 3, 1985
    Assignee: Armstrong World Industries, Inc.
    Inventors: Ronald S. Lenox, Anne L. Schwartz, Charles E. Hoyle
  • Patent number: 4458073
    Abstract: There are described a new class of organic dyes containing silane groups, the composite pigments obtainable therefrom by associating them with a substrate (SiO.sub.2, TiO.sub.2, Al.sub.2 O.sub.3), and the processes for preparing same.The silane organic dyes have the formula (I): ##STR1## wherein all substituents are defined later. The silane dyes (I) are utilized per se for dyeing natural fibres, such as wool, and man-made fibres, such as the polyamide, polyester, polyacrylic fibres and the like, while the composite pigments prepared from said dyes by association with an inorganic substrate are employed in paints, air enamels and stoving enamels, in the pigmentation of plastics, in the inks, in the printing of textiles etc.
    Type: Grant
    Filed: January 17, 1983
    Date of Patent: July 3, 1984
    Assignee: Montefluos S.p.A.
    Inventors: Antonio Marraccini, Marcello Pieroni, Antonio Pasquale, Luigi Balducci
  • Patent number: 4252529
    Abstract: Water-soluble copper, cobalt and chromium complex monoazo compounds of which the metal-free monoazo compound contains as diazo component an aminophenol or aminonaphthol compound subtituted by a fiber-reactive radical of the vinyl sulfone series, the aminophenol possibly being substituted by a lower alkyl, lower alkoxy, nitro, sulfonic acid group, or a chlorine or bromine atom and the naphthol possibly being substituted by a sulfo group, and as coupling component a 6-sulfonaphthol(8) which may be substituted by a sulfo group in the adjacent aromatic nucleus and must be substituted by the monoamide radical of succinic acid, glutaric acid or adipic acid.
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: February 24, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Hans H. Steuernagel