Fiber Derived From Saponified Cellulose Esters Or From Nitrocellulose Converted To Cellulose, Dye Composition, Process, Or Product Patents (Class 8/536)
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Patent number: 10093790Abstract: The present invention relates to a three-dimensional cellulosic molded body that has an optically detectable core/shell structure, the shell having a higher density and a lower crystallinity than the core, and the core having a sponge-like structure. The invention further relates to a method for producing this molded body as well as to its use, especially in the cosmetics and pharmaceutical industries.Type: GrantFiled: November 14, 2014Date of Patent: October 9, 2018Assignee: Lenzing AktiengesellschaftInventors: Martin Häubl, Josef Innerlohinger, Christian Schirk
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Patent number: 8170013Abstract: The present invention relates to a sending device able to send packets in a network comprising at least two stations, the said device comprising means for extracting image pips on the basis of a synchronization signal, initializing an image counter on the basis of the image pips, initializing a counter every “m” zero-crossings of the image counter, the counter being regulated by a clock produced by the image counter, sampling the counter every period Tsmp, where Tsmp emanates from a time base synchronized on all the stations of the said network; and sending packets containing the samples of the counter in the network.Type: GrantFiled: June 6, 2008Date of Patent: May 1, 2012Assignee: Thomson LicensingInventors: Thierry Tapie, Serge Defrance, Izabela Grasland
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Patent number: 8167958Abstract: The present invention relates to a process for dyeing sheetlike textile materials with a dye, which comprises a concentrated dye system being applied in a total amount of 1% to 25% by weight, based on the textile material, to the textile material in two or more sub-steps and the dye being fixed on the textile material after each and every sub-step.Type: GrantFiled: August 14, 2009Date of Patent: May 1, 2012Assignee: DyStar Colours Deutschland GmbHInventors: Christian Meyer, Wolfgang Schrott, Franz Sütsch
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Publication number: 20040205912Abstract: The present invention relates to novel compounds of the formulae A, D1, D2, R1 and n are as defined in the description the compounds being in an internal or external salt form, or mixtures of compounds (1) and (2), a process for their preparation and preparations containing them used for dyeing paper.Type: ApplicationFiled: January 17, 2004Publication date: October 21, 2004Inventors: Michaeal Lennartz, Dolf Kaser, Sandra Weiss
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Publication number: 20030182738Abstract: A process of dyeing a molded article is disclosed. The process entails immersing at least a portion of the article in a dyeing bath, retaining the portion in the bath for a period of time sufficient to allow an amount of dye to diffuse into the article, and removing said article from the bath. The molded article comprises a polymeric resin such as (co)polyester, (co)polycarbonates, acrylonitrile-butadiene-styrene, polyamide, polyurethane, polyalkyl(meth)-acrylate, allyldiglycol carbonate and styrene copolymers. The dyeing bath contains in addition to dye, water, a plasticizing agent and a leveling agent.Type: ApplicationFiled: March 26, 2002Publication date: October 2, 2003Inventors: Robert A. Pyles, Rick L. Archey
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Publication number: 20030167581Abstract: The invention provides dyed yarn characterized by comprising dyed polytrimethylene terephthalate fiber, having an elastic recovery of 60% or greater under 10% elongation, and having a boiling water shrinkage of no greater than 4%. The dyed yarn of the invention has excellent stretchability and dimensional stability as well as a soft feel, and is therefore suitable for use in fabrics.Type: ApplicationFiled: November 13, 2002Publication date: September 11, 2003Inventors: Hiroshi Yamazaki, Kazuto Oue, Mitsuyuki Yamamoto
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Publication number: 20030135939Abstract: Textile materials, including paper webs, treated with a polyvinylamine polymer and a second agent that interacts with the polyvinylamine polymer is disclosed. The second agent added with the polyvinylamine polymer can be, for instance, a polymeric anionic reactive compound or a polymeric aldehyde-functional compound. When incorporated into a paper web, the combination of the polyvinylamine polymer and the second agent provide improved strength properties, such as wet strength properties. In an alternative embodiment, the polyvinylamine polymer and the second polymer can be applied to a textile material for increasing the affinity of the textile material for acid dyes.Type: ApplicationFiled: December 18, 2001Publication date: July 24, 2003Inventors: Tong Sun, Jeff Lindsay
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Publication number: 20030005527Abstract: The present invention is a thickened dye composition and method of applying same to a paper web that produces colored or patterned paper having good bleed resistance. The dye composition of the invention includes a binder; a dye; a thickener selected from the group consisting of polyvinylpyrrolidone homopolymers, polyvinylpyrrolidone copolymers, and mixtures thereof; and water. The present invention also includes colored or patterned papers prepared using this dye composition.Type: ApplicationFiled: July 3, 2001Publication date: January 9, 2003Applicant: BASF CORPORATIONInventors: James A. Deckers, Stephen S. Jose, Michael T. Jennings
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Publication number: 20020189035Abstract: The present invention relates to novel dyed cellulosic molded bodies, in particular to fibers or films, containing a heavy-metal-containing colorant, which, according to the thermal stability test described above, reduces the rise temperature of a cellulose solution in a tertiary amine oxide by 10° C. at most, in particular by 5° C. at most. The molded bodies according to the invention may be produced in accordance with the amine-oxide process (FIG. 1).Type: ApplicationFiled: February 8, 2002Publication date: December 19, 2002Applicant: LENZING AKTIENGESELLSCHAFTInventor: Hartmut Ruf
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Publication number: 20020069468Abstract: A process for dyeing a fibrous substrate which comprises the steps of: providing a fibrous substrate; providing at least one sulfur dye; providing at least one reduction stable direct dye; and applying said reduction stable direct dye and sulfur dye to said fibrous substrate in the presence of a suitable reducing agent. Further, it has been surprising to find that these reduction stable direct dyes can be processed without a sulfur dye present. This results in a process for dyeing a fibrous substrate which comprises the steps of: providing a fibrous substrate; providing a reduction stable direct dye; and applying said reduction stable direct dye to said fibrous substrate in the presence of a suitable reducing agent.Type: ApplicationFiled: July 3, 2001Publication date: June 13, 2002Applicant: Clariant Finance (BVI) LimitedInventors: J. Michael Hipp, Mark S. Carlough, William T. Sherrill, Peter J.V. Stahala
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Publication number: 20020038484Abstract: Disclosed are dye mixtures for shading white paper which may contain fluorescent brightener. The dye mixtures comprise a violet dye according to the formula (1) or (2) indicated in claim 1 and sufficient of a red, blue or further violet anionic azo dye that this dye mixture is capable of producing in the Cielab colour co-ordinates system a relative hue angle of 270 to 295° when the dyeing contains 0.00005 to 0.005% by weight of dye, based on the weight of the paper, with the proviso that the value 0.005% is excluded.Type: ApplicationFiled: July 11, 2001Publication date: April 4, 2002Inventors: Adolf Kaser, Wolfgang Schlenker
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Publication number: 20020010971Abstract: The aqueous dye solutions of the composition shown in claim 1 are distinguished by a good storage stability and are suitable for dyeing paper in red color shades.Type: ApplicationFiled: April 17, 2001Publication date: January 31, 2002Inventors: Alfred Hohener, Roland Frick, Adolf Kaeser
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Patent number: 6320031Abstract: Monoazo dyes of formula (3) wherein A, R1, R2, M and n are as defined in the specification, are excellent dyes for dyeing and printing of cellulose containing materials and especially for the preparation of inks for ink jet printing.Type: GrantFiled: February 23, 2000Date of Patent: November 20, 2001Assignee: Ilford Imaging Switzerland GmbHInventors: Kurt Baettig, Gérald Jan
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Patent number: 6307007Abstract: New water-soluble polycondensation products are obtained by reaction of polyfunctional amines with cyanamide, its derivatives or polymers in the presence of sulfamic acid. They are excellent fixing agents which improve fastness properties of dyeings with substantive dyestuffs on cellulose fiber materials, paper, board and non-wovens.Type: GrantFiled: May 14, 1999Date of Patent: October 23, 2001Assignee: Clariant Finance (BVI) LimitedInventors: Jürg Heller, Alec Tindal
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Publication number: 20010013149Abstract: Process for dyeing or printing paper, films of plastic or fiber material containing hydroxyl groups or containing nitrogen with reactive dyes, which comprises using at least one reactive dye of the formula (1) from the following group a) and at least one reactive dye from the following groups b), c) and d):Type: ApplicationFiled: January 31, 2001Publication date: August 16, 2001Inventors: Peter Scheibli, Peter Aeschlimann, Urs Lehmann, Marcel Frick
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Patent number: 5981741Abstract: Disclosed are aminated acetate fiber comprising acetylcellulose and one or more water-insoluble quaternary starch ether esters, said starch ether esters containing ester groups of formulae --O--CO--CH.sub.3 and/or --O--CO--C.sub.2 H.sub.5 and ether groups of the general formula I--O--CH.sub.2 --X--CH.sub.2 --N.sup.+ R.sub.3 A.sup.- (I)whereX is a direct bond or --CH(OH)-- andA.sup.- is an anion or one equivalent of an anion, andR is hydrogen, methyl and/or ethyl,and the degree of substitution of said ether group being within the range from 0.002 to 0.8, the degree of substitution of said ester group being within the range from 0.7 to 2.998 and the overall degree of substitution being within the range from 1.5 to 3, its preparation and its use and also quaternary starch ether esters present therein.Type: GrantFiled: April 20, 1998Date of Patent: November 9, 1999Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Andreas Schrell, Jimmy G. Welborn
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Patent number: 5830574Abstract: Melamine fibers and cellulose fiber combinations are dyed with certain dyes such that the cellulose fiber is dyed by the dyes but the melamine fiber is substantially undyed. When in fabric form, a chambray appearance is given.Type: GrantFiled: April 24, 1997Date of Patent: November 3, 1998Assignee: BASF CorporationInventor: Dean R. Gadoury
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Patent number: 5476518Abstract: A process for treating a dyed, velvet fabric is disclosed wherein two-toned color effects between the pile and the fabric backing are achieved. The preferred fabric comprises a cellulosic (cotton or rayon) or synthetic fiber weave backing dyed preferably with a non-disperse dye, e.g. a direct dye, and pile composed of cellulose acetate fibers dyed with a disperse dye. The dyed fabric is contacted with a dilute caustic solution, e.g., sodium hydroxide, for a period of time sufficient to at least partially or totally hydrolyze the cellulose acetate of the pile fiber, which noticeably also reduces the color intensity of the pile while having little effect on the color intensity of the backing. This is followed by rinsing, neutralization and conditioning of the treated fabric.Type: GrantFiled: March 14, 1995Date of Patent: December 19, 1995Assignee: A. Wimpfheimer & Bro., Inc.Inventor: Nicholas Caleshu
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Patent number: 5216139Abstract: Thiopheneazo dyes of the formula ##STR1## where R.sup.1 is cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, phenylazo, phenylsulfonyl, formyl or the radical ##STR2## where R.sup.7 and R.sup.8 are independently of the other cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, phenyl, halogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxycarbonyl, or R.sup.1 and R.sup.2 together are the radical (CH.sub.2).sub.3 --CO, which may be substituted by 1 or 2 methyl groups and whose carbonyl group is bonded to the thiophene ring in the ortho position relative to the sulfur atom,R.sup.3 is cyano or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, cyclohexyl, phenoxy-C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, or substituted or unsubstituted thienyl,R.sup.5 is C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.7 -alkyl whose alkyl chain is interrupted by 1 or 2 oxygen atoms, or C.sub.1 -C.sub.4 -alkoxy andR.sup.6 is cyanoethyl, phenylethyl or C.sub.3 -C.sub.Type: GrantFiled: December 4, 1990Date of Patent: June 1, 1993Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Etzbach, Guenter Hansen, Gunther Lamm, Helmut Reichelt
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Patent number: 5175265Abstract: Benzisothiazole-azo dyes useful for dyeing synthetic fiber materials have the formula ##STR1## where X is hydrogen, chlorine, bromine, cyano or nitro and K is a radical of the formula ##STR2## where R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.12 -alkyl, substituted or unsubstituted phenyl, C.sub.3 -C.sub.5 -alkenyl or C.sub.5 -C.sub.7 -cycloalkyl,R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.3 is hydrogen or methyl andR.sup.4 is hydrogen, cyano, carbamoyl or C.sub.1 -C.sub.4 -alkoxycarbonyl.Type: GrantFiled: March 5, 1990Date of Patent: December 29, 1992Assignee: BASF AktiengesellschaftInventors: Guenter Hansen, Helmut Hagen, Helmut Reichelt
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Patent number: 4935499Abstract: Paper is colored by a process in which a compound which, in the form of the free acid, is of the formula I ##STR1## where, in each case independently of one another, A is unsubstituted or methyl substituted C.sub.1 -C.sub.6 -alkylene or vinylene,R is each hydrogen or C.sub.1 -C.sub.4 -alkyl,X is each --CO-- or --SO.sub.2 --,K is each a cationic group andY is hydrogen, chlorine or bromine.Type: GrantFiled: September 27, 1988Date of Patent: June 19, 1990Assignee: BASF AktiengesellschaftInventors: Manfred Ruske, Hans-Juergen Degen
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Patent number: 4764585Abstract: Cationic fixing agents based on the reaction products of(a) a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups and(b) cyanamide, dicyandiamide, guanidine or bisguanidinegive improved results when the reaction takes place in the presence of a catalyst (K) selected from metals, metal salts and heterocyclic nitrogen-containing organic bases, particularly zinc chloride.Type: GrantFiled: September 15, 1987Date of Patent: August 16, 1988Assignee: Sandoz Ltd.Inventors: Jurg Heller, Bruno Kissling, Curt Muller, Tibor Robinson, Salvatore Valenti
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Patent number: 4600776Abstract: Cationic enamine dyestuffs of the general formula ##STR1## in which the symbols have the meaning given in the description, are used for dyeing natural and synthetic substrates and compositions which can be dyed with cationic dyestuffs, in particular paper.Type: GrantFiled: June 11, 1984Date of Patent: July 15, 1986Assignee: Bayer AktiengesellschaftInventors: Karlheinrich Meisel, Roderich Raue
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Patent number: 4585864Abstract: Silane quinacridone dyes, composite pigments obtainable therefrom by association with an inorganic substrate, and the processes for preparing them. The dyes have the general formula: ##STR1## wherein X is an --SO.sub.2 NHR group, where R is an alkyl group, linear or branched, having from 1 to 6 carbon atoms, a cycloalkyl group, a phenyl group optionally substituted by one or more alkyl or alkoxy groups (C.sub.1 -C.sub.6), a halogen; Y and Z indicate a silane group having the formula: ##STR2## wherein R.sub.1 is an alkoxy group (C.sub.1 -C.sub.2), R.sub.2 is an alkyl group (C.sub.1 -C.sub.4) or a phenyl group; n is 3, 4 or 5; q is 0 or 1; p and m are integers, such that when q is 1, p is 2 and m is 0, 1 or 2, and when q is 0, p is 3 and m is 0, 1, 2 or 3; W indicates an --SO.sub.3 H group; a, b and c are 0 or 1, selected in such a way that the sum a+b+c is equal to 1.Type: GrantFiled: December 18, 1984Date of Patent: April 29, 1986Assignee: Montedison S.p.A.Inventors: Antonio Marraccini, Filippo M. Carlini, Antonio Pasquale, Michele Pontevivo
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Patent number: 4556625Abstract: The present invention discloses a method of photolytically developing a colored image on a cellulosic material. In this method, the material is contacted with a nitrogen containing polymer in solution and a mono-sulfonyl azide compound in solution. The sample is thereafter exposed to a UV-containing light source for an amount of time sufficient to develop a color thereon.Type: GrantFiled: November 25, 1983Date of Patent: December 3, 1985Assignee: Armstrong World Industries, Inc.Inventors: Ronald S. Lenox, Anne L. Schwartz, Charles E. Hoyle
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Patent number: 4458073Abstract: There are described a new class of organic dyes containing silane groups, the composite pigments obtainable therefrom by associating them with a substrate (SiO.sub.2, TiO.sub.2, Al.sub.2 O.sub.3), and the processes for preparing same.The silane organic dyes have the formula (I): ##STR1## wherein all substituents are defined later. The silane dyes (I) are utilized per se for dyeing natural fibres, such as wool, and man-made fibres, such as the polyamide, polyester, polyacrylic fibres and the like, while the composite pigments prepared from said dyes by association with an inorganic substrate are employed in paints, air enamels and stoving enamels, in the pigmentation of plastics, in the inks, in the printing of textiles etc.Type: GrantFiled: January 17, 1983Date of Patent: July 3, 1984Assignee: Montefluos S.p.A.Inventors: Antonio Marraccini, Marcello Pieroni, Antonio Pasquale, Luigi Balducci
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Patent number: 4252529Abstract: Water-soluble copper, cobalt and chromium complex monoazo compounds of which the metal-free monoazo compound contains as diazo component an aminophenol or aminonaphthol compound subtituted by a fiber-reactive radical of the vinyl sulfone series, the aminophenol possibly being substituted by a lower alkyl, lower alkoxy, nitro, sulfonic acid group, or a chlorine or bromine atom and the naphthol possibly being substituted by a sulfo group, and as coupling component a 6-sulfonaphthol(8) which may be substituted by a sulfo group in the adjacent aromatic nucleus and must be substituted by the monoamide radical of succinic acid, glutaric acid or adipic acid.Type: GrantFiled: April 24, 1980Date of Patent: February 24, 1981Assignee: Hoechst AktiengesellschaftInventor: Hans H. Steuernagel