Quaternary Ammonium, Pyridino, Or Dialkylaminoalkyl Patents (Class 8/540)
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Patent number: 8795391Abstract: The present invention relates to an aqueous oxidative coloring composition for keratin fibers especially human hair with improved conditioning effect, improved color fastness against washing and for achieving homogeneous even coloration. The object of the present invention is an aqueous composition for coloring keratin fibers especially human hair, based on at least one oxidative dye precursor, optionally at least one coupling agent and/at least one direct dye and furthermore comprising in a cosmetically acceptable medium at least one anionic surfactant, at least one branched fatty acid and at least one quaternary ammonium surfactant.Type: GrantFiled: April 14, 2011Date of Patent: August 5, 2014Assignee: KAO Germany GmbHInventor: Takeshi Iizaki
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Patent number: 7972389Abstract: Provided is a second part composition for hair dyeing or bleaching, which is mixed with a first part composition containing an alkali agent before use, the composition containing the following components (A) to (D): (A) an organic amine having at least one hydrophobic chain or a salt thereof; (B) an oily component which is a liquid form at 25° C. under normal pressure (1013.25 hPa); (C) an oxidizing agent; and (D) water, in which the composition has a pH of 1 to 6 at 25° C.Type: GrantFiled: December 26, 2008Date of Patent: July 5, 2011Assignee: Kao CorporationInventors: Kenichi Matsunaga, Takashi Matsuo, Hajime Miyabe
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Patent number: 7842100Abstract: Provided is a two-part oxidation hair dye composition having a first agent containing an alkali and an oxidation dye intermediate or a direct dye and a second agent containing an oxidizing agent, wherein at least one of the first and second agents contains both of components (A) an iso-fatty acid or an anteiso-fatty acid having from 19 to 30 carbon atoms, or a slat thereof, and (B) a quaternary cationic surfactant.Type: GrantFiled: May 30, 2008Date of Patent: November 30, 2010Assignee: Kao CorporationInventors: Kenichi Matsunaga, Hajime Miyabe
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Patent number: 7771492Abstract: Compositions for oxidation dyeing of keratin fibers, in particular human keratin fibers such as hair, comprising, in a dyeing medium, at least one oxidation dye, at least one thickening polymer comprising at least one fatty chain and at least one fatty alcohol chosen from monoglycerolated and polyglycerolated fatty alcohols. Processes comprising such oxidation dyeing compositions.Type: GrantFiled: February 23, 2009Date of Patent: August 10, 2010Assignee: L'Oreal S.A.Inventors: François Cottard, Christine Rondeau
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Patent number: 7402180Abstract: A composition for the oxidation dyeing of keratin fibers, such as human keratin fibers and further such as the hair, comprising, in a medium that is suitable for dyeing and that is free of glycerol and of cationic synthetic thickening polymer comprising at least one fatty chain, at least one oxidation dye, at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols, and at least one particular polyol. The invention also relates to the dyeing processes and devices using the said composition.Type: GrantFiled: July 11, 2006Date of Patent: July 22, 2008Assignee: L'Oréal S.A.Inventors: Patricia Vuarier, Jean-Marie Millequant
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Patent number: 7255718Abstract: The present invention relates to a composition for coloring keratin fibers and a method of use thereof. The coloring composition contains at least one phosphate-based tenside of a particular formula, at least one conditioning component, and at least one dye and/or dye precursor.Type: GrantFiled: March 22, 2000Date of Patent: August 14, 2007Assignee: Hans Schwarzkopf GmbH & Co. KGInventors: Mustafa Akram, Wolfgang Wolff, Sandra Rohweder
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Patent number: 7204858Abstract: The invention relates to a composition useful for the oxidation dyeing of keratin fibres, in particular of human keratin fibres and more particularly the hair, comprising, preferably in a medium that is suitable for dyeing, at least one oxidation dye, wherein it also comprises at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, and at least one quaternized cellulose comprising at least one fatty chain. The invention also relates to the dyeing devices and processes using the said composition.Type: GrantFiled: December 20, 2002Date of Patent: April 17, 2007Assignee: L'OrealInventors: Patricia Desenne, Cecile Bebot, Florence Laurent
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Patent number: 7179303Abstract: A preparation for coloring keratin fibers containing dyes and/or dye precursors, at least one silicone oil and/or silicone gum and at least one polymer which contains at least one monomer unit corresponding to formula (I): in which n is a number of 1 to 3 and Y is a physiologically compatible anion. Also disclosed is a method of applying this preparation to keratin fibers.Type: GrantFiled: October 22, 2003Date of Patent: February 20, 2007Assignee: Henkel Kommanditgesellschaft Auf Aktien (Henkel KGaA)Inventors: Wolfgang Wolff, Mustafa Akram, Shigeri Tanaka, legal representative, Hiroshi Tanaka, deceased
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Patent number: 7122062Abstract: An objective of the invention is to provide a hair dye composition having sufficient decolorizing performance and dying performance without exhibiting any irritative odor, and also having an ability of imparting the hairs with an excellent smoothness. The aspect of the invention is a hair dye composition comprising: a first agent containing an alkanolamine and an oxidation dye; and, a second agent containing an oxidant, wherein a higher alcohol and a quaternary ammonium salt cationic surfactant are contained in the first agent and/or the second agent; wherein the molar ratio of the higher alcohol to the quaternary ammonium salt cationic surfactant is in the range of 3 to 15. In the composition described above, it is preferable that substantially no ammonia is contained.Type: GrantFiled: November 28, 2003Date of Patent: October 17, 2006Assignee: Shiseido Co., Ltd.Inventors: Takahiro Yamashita, Kazuya Shibata, Tetsuya Kambe, Katsuo Hashimoto
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Patent number: 7108726Abstract: The invention concerns a direct dyeing composition for keratinous fibres, in particular for human keratinous fibres and more particularly hair, comprising, in a medium suitable for dyeing, at least a direct colouring agent, and furthermore at least a cationic associative polyurethane. The invention also concerns dyeing methods and devices using said composition.Type: GrantFiled: November 6, 2001Date of Patent: September 19, 2006Assignee: L'Oreal S.A.Inventors: François Cottard, Roland De La Mettrie
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Patent number: 7101405Abstract: The invention concerns an oxidation dyeing composition for keratinous fibers, in particular human keratinous fibers, and more particularly hair, comprising, in a medium suitable for oxidation dyeing, at least an oxidation colouring agent, and furthermore at least a cationic associative polyurethane. The invention also concerns dyeing methods and devices using said composition.Type: GrantFiled: November 6, 2001Date of Patent: September 5, 2006Assignee: L'Oreal S.A.Inventors: Franç is Cottard, Roland De La Mettrie
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Patent number: 7077869Abstract: The invention concerns a composition for bleaching or permanent waving of keratinous fibers, in particular human keratinous fibers and more particularly hair, comprising, in a medium suitable for bleaching or permanent waving, at least a reducing agent and furthermore at least a cationic associative polyurethane. The invention also concerns methods and devices for bleaching or permanent waving of keratinous fibers using said composition.Type: GrantFiled: November 6, 2001Date of Patent: July 18, 2006Assignee: L'Oreal S.A.Inventors: Frédéric Legrand, Roland De La Mettrie
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Patent number: 7066965Abstract: The invention concerns bleaching composition for keratinous fibres, in particular human keratinous fibres and more particularly hair, comprising, in a medium suitable for bleaching, at least an oxidising agent and furthermore at least a cationic associative polyurethane. The invention also concerns the bleaching method and devices using said composition.Type: GrantFiled: November 6, 2001Date of Patent: June 27, 2006Assignee: L'Oreal S.A.Inventors: Frédéric Legrand, Roland De La Mettrie
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Patent number: 6946005Abstract: Novel pyrrolidinyl-substituted para-phenylenediamine derivatives comprising a cationic radical, the dye compositions comprising them and the process for dyeing keratin fibers using these compositions, making it possible to obtain a chromatic, powerful, unselective and fast coloration of keratin fibers.Type: GrantFiled: March 27, 2003Date of Patent: September 20, 2005Assignee: L'Oreal S.A.Inventors: Stéphane Sabelle, Laure Ramos, Madeleine Leduc, Michel Philippe
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Patent number: 6770103Abstract: A method for permanently dyeing hair is provided which includes subjecting the hair to a number of treatments, having a set time interval between each two consecutive such treatments, and wherein each treatment comprises contacting the hair for a period from about 5 seconds to about 3 minutes with a recently made mixture of an alkaline and an acidic composition, followed by a rinsing step. A shampoo or conditioner base is present in the alkaline and acidic compositions.Type: GrantFiled: March 5, 2002Date of Patent: August 3, 2004Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Jitendra Patel, Gerald Patrick Newell, Margie Fowler
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Patent number: 6758867Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: oxidative dye intermediates in a shampoo base at alkaline pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; and part ai optionally has about 0.01 to about 10.0% of a structurant; part aii: an oxidative compound in a shampoo base at acidic pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; and part ai optionally has about 0.01 to about 10.0% of a structurant; with the proviso that at least one of part ai and part aii has about 0.01 to about 5.0% of a conditioning agent; and part aii optionally has about 0.01 to about 10.0% of a structurant; b.Type: GrantFiled: December 28, 2001Date of Patent: July 6, 2004Assignee: Unilever Home & Personal Care USA, Division of Conopco, Inc.Inventors: Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler
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Patent number: 6743265Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: dye intermediates in water with a gelling agent at alkaline pH part aii an oxidizing compound such as hydrogen peroxide in water at acidic pH; b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.Type: GrantFiled: March 13, 2002Date of Patent: June 1, 2004Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Jitendra Patel, Frank Jones
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Patent number: 6736860Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: dye intermediates in water and fatty alcohol at alkaline pH, part aii: an oxidizing compound such as hydrogen peroxide in water at acidic pH b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.Type: GrantFiled: March 12, 2002Date of Patent: May 18, 2004Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Jitendra Patel, Gerald Patrick Newell, Margie Fowler, Elizabeth Kim, Fe P Pascual
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Patent number: 6736861Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: i.) an alkaline composition comprising a dye intermediate in a shampoo base or in a conditioner base; and ii.) an acidic composition comprising an oxidating compound in a shampoo base or in a conditioner base; b.) rinsing said mixture from said hair with water; with the proviso that when a conditioner base is present in a.) i.) above, an independently selected conditioner base is also present in a.) ii.) above; and when a shampoo base is present in a.) i.) above, an independently selected shampoo base is also present in a.) ii.Type: GrantFiled: July 17, 2002Date of Patent: May 18, 2004Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Jitendra Patel, Gerald Patrick Newell
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Patent number: 6726729Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: oxidative dye intermediates in a shampoo base at alkaline pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; part aii: an oxidative compound in a shampoo base at acidic pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; with the proviso that at least one of part ai and part aii has about 0.01 to about 5.0% of a conditioning agent; b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.Type: GrantFiled: December 28, 2001Date of Patent: April 27, 2004Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler
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Patent number: 6692539Abstract: The invention relates to a composition useful for the oxidation dyeing of keratin fibers, in particular of human keratin fibers and more particularly the hair, containing, in a medium that is suitable for dyeing, at least one oxidation dye, at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, at least one nonionic surfactant and at least one cationic or amphoteric polymer whose cationic charge density is greater than or equal to 2 meq/gram. The invention also relates to the dyeing devices and processes using the composition.Type: GrantFiled: December 20, 2002Date of Patent: February 17, 2004Assignee: L'OrealInventors: Patricia Desenne, Cecile Bebot, Florence Laurent
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Patent number: 5981741Abstract: Disclosed are aminated acetate fiber comprising acetylcellulose and one or more water-insoluble quaternary starch ether esters, said starch ether esters containing ester groups of formulae --O--CO--CH.sub.3 and/or --O--CO--C.sub.2 H.sub.5 and ether groups of the general formula I--O--CH.sub.2 --X--CH.sub.2 --N.sup.+ R.sub.3 A.sup.- (I)whereX is a direct bond or --CH(OH)-- andA.sup.- is an anion or one equivalent of an anion, andR is hydrogen, methyl and/or ethyl,and the degree of substitution of said ether group being within the range from 0.002 to 0.8, the degree of substitution of said ester group being within the range from 0.7 to 2.998 and the overall degree of substitution being within the range from 1.5 to 3, its preparation and its use and also quaternary starch ether esters present therein.Type: GrantFiled: April 20, 1998Date of Patent: November 9, 1999Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Andreas Schrell, Jimmy G. Welborn
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Patent number: 5037448Abstract: Salts of ionic dyes with compounds which contain at least one ammonium, cycloammonium or immonium group and at least one aliphatic, cycloaliphatic or carbonyl radical-substituted aromatic group or containing a piperazine or piperidine group or a heteroaromatic group selected from those of the triazine, pyrimidine, quinazoline, quinoxaline, phthalazine or phthalimidine series or which contain at least two carboxylic acid groups, at least one amino groups and at least one carboxylic acid group or at least one sulfonic acid group and one aliphatic, cycloaliphatic, monocyclic aromatic or heteroaromatic group are useful for dyeing synthetic materials, particularly synthetic polyamides in the mass. The obtained dyeings have exceptionally good wet fastness.Type: GrantFiled: June 30, 1989Date of Patent: August 6, 1991Assignee: Sandoz Ltd.Inventor: Bansi L. Kaul
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Patent number: 4413999Abstract: The invention provides amidoxime derivatives of the general formula ##STR1## wherein R.sub.1 is an alkyl group of 1 to 8 carbon atoms, phenyl, a heterocyclic ring structure of 5 to 8 atoms containing one or more nitrogen or oxygen atoms or combinations thereof or a bicyclic condensed ring system optionally containing at least one heterocyclic ring which groups may each be optionally substituted. R.sub.2 is a mono or bicyclic heterocyclic radical containing at least two nitrogen atoms which radical is also optionally substituted. R.sub.3 and R.sub.4 are independently H, or an alkyl of 1 to 4 carbon atoms or one, but not both, is ##STR2## and the other, H, wherein R.sub.5 or R.sub.6 are alkyls of 2 to 5 carbon atoms optionally substituted by R.sub.1, or a phenyl optionally substituted by R.sub.1 or R.sub.5 or R.sub.6 is combined with R.sub.1 to jointly form cyclic imidoximes or imidedioximes.Type: GrantFiled: March 5, 1982Date of Patent: November 8, 1983Assignee: Research Products Rehovot Ltd.Inventors: Charles Linder, Gershon Aviv
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Patent number: 4411666Abstract: A process for dyeing polyolefin fiber materials, which comprises contacting a polyolefin fiber material obtained by melt-spinning a mixture of crystalline polyolefin and 0.1 to 30% by weight based on the weight of the polyolefin of a copolymer of ethylene and an aminoalkyl acrylate compound represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen atom or methyl group, R.sub.2 and R.sub.3 each represents hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and n represents an integer from 1 to 4, or a blend product of the said polyolefin fiber material and a polyamide fiber material, with a dye bath containing an anionic dye and at least one carboxylic acid selected from the group consisting of benzoic acid, salicylic acid, p-chlorobenzoic acid and 5-chlorosalicylic acid.Type: GrantFiled: February 8, 1982Date of Patent: October 25, 1983Assignee: Sumitomo Chemical Company, LimitedInventors: Shuhei Hashizume, Sadaharu Abeta, Tadayuki Ohmae, Hajime Nishibara
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Patent number: 4384870Abstract: Compounds of the formula ##STR1## in which A is the radical of a sulpho group-containing diazo component of the aniline or 1- or 2-aminonaphthalene series,K is a coupling component radical of the phenol series, having a free hydroxy group or an etherified or acylated hydroxy group,R.sub.1 is hydrogen C.sub.1-4 alkoxy, C.sub.1-4 alkyl or C.sub.1-4 haloalkyl,R.sub.2 is C.sub.1-4 alkyl, C.sub.1-6 alkyl-CO-, C.sub.1-6 alkyl-O-CO-, -CONH.sub.2, C.sub.1-6 alkyl-NH-CO-, di-(C.sub.1-6 alkyl)N-CO-, 2-, 3-, 4-, 5- or 6-hydroxy(C.sub.2-6 alkyl)-NH-CO- or (2-, 3-, 4-, 5- or 6-hydroxy(C.sub.2-6 alkyl)).sub.2 N-CO-, andR.sub.10 is hydrogen or C.sub.1-4 alkyl,and mixtures thereof, which compounds are in free acid or salt form and are useful for dyeing or printing anionic dyeable substrates such as leather, natural and synthetic polyamides, polyurethanes and polyolefins modified to contain basic groups, especially nylon.Type: GrantFiled: July 27, 1981Date of Patent: May 24, 1983Assignee: Sandoz Ltd.Inventor: Francois Benguerel
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Patent number: 4378970Abstract: Red monoazo dyestuffs frm diazotised 1-aminobenzene-2-sulphonic acid-N-methyl-N-cyclohexylamide or 1-amino-4-,-5- or -6-methyl-benzene-2-sulphonic acid-N-methyl-N-cyclohexylamide and 2-amino-8-hydroxynaphthalene-6-sulphonic acid are disclosed which are particularly distinguished by their good migration and levelling properties and excellent fastness to light. Said dyestuffs are moreover suitable for obtaining very even combination dyeings together with known blue or yellow acid dyestuffs. These dyestuffs are particularly suited for the dyeing of carpeting, upholstery fabrics and drapery materials.Type: GrantFiled: October 15, 1981Date of Patent: April 5, 1983Assignee: Ciba-Geigy AGInventors: Paul Lienhard, Fabio Beffa
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Patent number: 4358287Abstract: 1:2 Metal complexes of the formula ##STR1## in which each of X.sub.1 and X.sub.2, independently, is --COO-- or --O--,each of B.sub.1 and B.sub.2, independently, is a radical of a coupling component of the benzene or oxyquinoline series,M is a metal capable of forming a 1:2 complex and,each of ##STR2## independently, is the radical of a diazo component of the benzene series, with the proviso that at most one of such diazo component radicals contains a single sulpho group,and mixtures thereof with one or more of the corresponding symmetrical 1:2 metal complexes,which complexes and mixtures of complexes are in free acid or salt form and are useful as anionic dyes for dyeing and printing substrates such as natural and regenerated cellulose, natural and synthetic polyamides, polyurethanes and polymers modified to contain basic groups, especially leather.Type: GrantFiled: April 13, 1981Date of Patent: November 9, 1982Assignee: Sandoz Ltd.Inventors: Heinz Wicki, Claude Vogel
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Patent number: 4300899Abstract: The present invention relates to compounds of formula I.sub.x, ##STR1## in which Y.sub.1 is (C.sub.1-6) alkoxy, Z is hydrogen, alkali metal or ammonium, andn is 1 or 2and a process for treating anionic dyeable substrates therewith to reserve the same against anionic dyes.Type: GrantFiled: February 20, 1980Date of Patent: November 17, 1981Assignee: Sandoz Ltd.Inventor: Hans-Rudolf Schmid