Quaternary Ammonium, Pyridino, Or Dialkylaminoalkyl Patents (Class 8/540)
  • Patent number: 8795391
    Abstract: The present invention relates to an aqueous oxidative coloring composition for keratin fibers especially human hair with improved conditioning effect, improved color fastness against washing and for achieving homogeneous even coloration. The object of the present invention is an aqueous composition for coloring keratin fibers especially human hair, based on at least one oxidative dye precursor, optionally at least one coupling agent and/at least one direct dye and furthermore comprising in a cosmetically acceptable medium at least one anionic surfactant, at least one branched fatty acid and at least one quaternary ammonium surfactant.
    Type: Grant
    Filed: April 14, 2011
    Date of Patent: August 5, 2014
    Assignee: KAO Germany GmbH
    Inventor: Takeshi Iizaki
  • Patent number: 7972389
    Abstract: Provided is a second part composition for hair dyeing or bleaching, which is mixed with a first part composition containing an alkali agent before use, the composition containing the following components (A) to (D): (A) an organic amine having at least one hydrophobic chain or a salt thereof; (B) an oily component which is a liquid form at 25° C. under normal pressure (1013.25 hPa); (C) an oxidizing agent; and (D) water, in which the composition has a pH of 1 to 6 at 25° C.
    Type: Grant
    Filed: December 26, 2008
    Date of Patent: July 5, 2011
    Assignee: Kao Corporation
    Inventors: Kenichi Matsunaga, Takashi Matsuo, Hajime Miyabe
  • Patent number: 7842100
    Abstract: Provided is a two-part oxidation hair dye composition having a first agent containing an alkali and an oxidation dye intermediate or a direct dye and a second agent containing an oxidizing agent, wherein at least one of the first and second agents contains both of components (A) an iso-fatty acid or an anteiso-fatty acid having from 19 to 30 carbon atoms, or a slat thereof, and (B) a quaternary cationic surfactant.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: November 30, 2010
    Assignee: Kao Corporation
    Inventors: Kenichi Matsunaga, Hajime Miyabe
  • Patent number: 7771492
    Abstract: Compositions for oxidation dyeing of keratin fibers, in particular human keratin fibers such as hair, comprising, in a dyeing medium, at least one oxidation dye, at least one thickening polymer comprising at least one fatty chain and at least one fatty alcohol chosen from monoglycerolated and polyglycerolated fatty alcohols. Processes comprising such oxidation dyeing compositions.
    Type: Grant
    Filed: February 23, 2009
    Date of Patent: August 10, 2010
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Christine Rondeau
  • Patent number: 7402180
    Abstract: A composition for the oxidation dyeing of keratin fibers, such as human keratin fibers and further such as the hair, comprising, in a medium that is suitable for dyeing and that is free of glycerol and of cationic synthetic thickening polymer comprising at least one fatty chain, at least one oxidation dye, at least one fatty alcohol chosen from mono- and polyglycerolated fatty alcohols, and at least one particular polyol. The invention also relates to the dyeing processes and devices using the said composition.
    Type: Grant
    Filed: July 11, 2006
    Date of Patent: July 22, 2008
    Assignee: L'Oréal S.A.
    Inventors: Patricia Vuarier, Jean-Marie Millequant
  • Patent number: 7255718
    Abstract: The present invention relates to a composition for coloring keratin fibers and a method of use thereof. The coloring composition contains at least one phosphate-based tenside of a particular formula, at least one conditioning component, and at least one dye and/or dye precursor.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: August 14, 2007
    Assignee: Hans Schwarzkopf GmbH & Co. KG
    Inventors: Mustafa Akram, Wolfgang Wolff, Sandra Rohweder
  • Patent number: 7204858
    Abstract: The invention relates to a composition useful for the oxidation dyeing of keratin fibres, in particular of human keratin fibres and more particularly the hair, comprising, preferably in a medium that is suitable for dyeing, at least one oxidation dye, wherein it also comprises at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, and at least one quaternized cellulose comprising at least one fatty chain. The invention also relates to the dyeing devices and processes using the said composition.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: April 17, 2007
    Assignee: L'Oreal
    Inventors: Patricia Desenne, Cecile Bebot, Florence Laurent
  • Patent number: 7179303
    Abstract: A preparation for coloring keratin fibers containing dyes and/or dye precursors, at least one silicone oil and/or silicone gum and at least one polymer which contains at least one monomer unit corresponding to formula (I): in which n is a number of 1 to 3 and Y is a physiologically compatible anion. Also disclosed is a method of applying this preparation to keratin fibers.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: February 20, 2007
    Assignee: Henkel Kommanditgesellschaft Auf Aktien (Henkel KGaA)
    Inventors: Wolfgang Wolff, Mustafa Akram, Shigeri Tanaka, legal representative, Hiroshi Tanaka, deceased
  • Patent number: 7122062
    Abstract: An objective of the invention is to provide a hair dye composition having sufficient decolorizing performance and dying performance without exhibiting any irritative odor, and also having an ability of imparting the hairs with an excellent smoothness. The aspect of the invention is a hair dye composition comprising: a first agent containing an alkanolamine and an oxidation dye; and, a second agent containing an oxidant, wherein a higher alcohol and a quaternary ammonium salt cationic surfactant are contained in the first agent and/or the second agent; wherein the molar ratio of the higher alcohol to the quaternary ammonium salt cationic surfactant is in the range of 3 to 15. In the composition described above, it is preferable that substantially no ammonia is contained.
    Type: Grant
    Filed: November 28, 2003
    Date of Patent: October 17, 2006
    Assignee: Shiseido Co., Ltd.
    Inventors: Takahiro Yamashita, Kazuya Shibata, Tetsuya Kambe, Katsuo Hashimoto
  • Patent number: 7108726
    Abstract: The invention concerns a direct dyeing composition for keratinous fibres, in particular for human keratinous fibres and more particularly hair, comprising, in a medium suitable for dyeing, at least a direct colouring agent, and furthermore at least a cationic associative polyurethane. The invention also concerns dyeing methods and devices using said composition.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: September 19, 2006
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Roland De La Mettrie
  • Patent number: 7101405
    Abstract: The invention concerns an oxidation dyeing composition for keratinous fibers, in particular human keratinous fibers, and more particularly hair, comprising, in a medium suitable for oxidation dyeing, at least an oxidation colouring agent, and furthermore at least a cationic associative polyurethane. The invention also concerns dyeing methods and devices using said composition.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: September 5, 2006
    Assignee: L'Oreal S.A.
    Inventors: Franç is Cottard, Roland De La Mettrie
  • Patent number: 7077869
    Abstract: The invention concerns a composition for bleaching or permanent waving of keratinous fibers, in particular human keratinous fibers and more particularly hair, comprising, in a medium suitable for bleaching or permanent waving, at least a reducing agent and furthermore at least a cationic associative polyurethane. The invention also concerns methods and devices for bleaching or permanent waving of keratinous fibers using said composition.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: July 18, 2006
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Legrand, Roland De La Mettrie
  • Patent number: 7066965
    Abstract: The invention concerns bleaching composition for keratinous fibres, in particular human keratinous fibres and more particularly hair, comprising, in a medium suitable for bleaching, at least an oxidising agent and furthermore at least a cationic associative polyurethane. The invention also concerns the bleaching method and devices using said composition.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: June 27, 2006
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Legrand, Roland De La Mettrie
  • Patent number: 6946005
    Abstract: Novel pyrrolidinyl-substituted para-phenylenediamine derivatives comprising a cationic radical, the dye compositions comprising them and the process for dyeing keratin fibers using these compositions, making it possible to obtain a chromatic, powerful, unselective and fast coloration of keratin fibers.
    Type: Grant
    Filed: March 27, 2003
    Date of Patent: September 20, 2005
    Assignee: L'Oreal S.A.
    Inventors: Stéphane Sabelle, Laure Ramos, Madeleine Leduc, Michel Philippe
  • Patent number: 6770103
    Abstract: A method for permanently dyeing hair is provided which includes subjecting the hair to a number of treatments, having a set time interval between each two consecutive such treatments, and wherein each treatment comprises contacting the hair for a period from about 5 seconds to about 3 minutes with a recently made mixture of an alkaline and an acidic composition, followed by a rinsing step. A shampoo or conditioner base is present in the alkaline and acidic compositions.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: August 3, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell, Margie Fowler
  • Patent number: 6758867
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: oxidative dye intermediates in a shampoo base at alkaline pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; and part ai optionally has about 0.01 to about 10.0% of a structurant; part aii: an oxidative compound in a shampoo base at acidic pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; and part ai optionally has about 0.01 to about 10.0% of a structurant; with the proviso that at least one of part ai and part aii has about 0.01 to about 5.0% of a conditioning agent; and part aii optionally has about 0.01 to about 10.0% of a structurant; b.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: July 6, 2004
    Assignee: Unilever Home & Personal Care USA, Division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler
  • Patent number: 6743265
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: dye intermediates in water with a gelling agent at alkaline pH part aii an oxidizing compound such as hydrogen peroxide in water at acidic pH; b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: June 1, 2004
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Jitendra Patel, Frank Jones
  • Patent number: 6736861
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: i.) an alkaline composition comprising a dye intermediate in a shampoo base or in a conditioner base; and ii.) an acidic composition comprising an oxidating compound in a shampoo base or in a conditioner base; b.) rinsing said mixture from said hair with water; with the proviso that when a conditioner base is present in a.) i.) above, an independently selected conditioner base is also present in a.) ii.) above; and when a shampoo base is present in a.) i.) above, an independently selected shampoo base is also present in a.) ii.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: May 18, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell
  • Patent number: 6736860
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: dye intermediates in water and fatty alcohol at alkaline pH, part aii: an oxidizing compound such as hydrogen peroxide in water at acidic pH b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: May 18, 2004
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell, Margie Fowler, Elizabeth Kim, Fe P Pascual
  • Patent number: 6726729
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: part ai: oxidative dye intermediates in a shampoo base at alkaline pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; part aii: an oxidative compound in a shampoo base at acidic pH and wherein part ai optionally has about 0.01 to about 5.0% of a conditioning agent; with the proviso that at least one of part ai and part aii has about 0.01 to about 5.0% of a conditioning agent; b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: April 27, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler
  • Patent number: 6692539
    Abstract: The invention relates to a composition useful for the oxidation dyeing of keratin fibers, in particular of human keratin fibers and more particularly the hair, containing, in a medium that is suitable for dyeing, at least one oxidation dye, at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, at least one nonionic surfactant and at least one cationic or amphoteric polymer whose cationic charge density is greater than or equal to 2 meq/gram. The invention also relates to the dyeing devices and processes using the composition.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: February 17, 2004
    Assignee: L'Oreal
    Inventors: Patricia Desenne, Cecile Bebot, Florence Laurent
  • Patent number: 5981741
    Abstract: Disclosed are aminated acetate fiber comprising acetylcellulose and one or more water-insoluble quaternary starch ether esters, said starch ether esters containing ester groups of formulae --O--CO--CH.sub.3 and/or --O--CO--C.sub.2 H.sub.5 and ether groups of the general formula I--O--CH.sub.2 --X--CH.sub.2 --N.sup.+ R.sub.3 A.sup.- (I)whereX is a direct bond or --CH(OH)-- andA.sup.- is an anion or one equivalent of an anion, andR is hydrogen, methyl and/or ethyl,and the degree of substitution of said ether group being within the range from 0.002 to 0.8, the degree of substitution of said ester group being within the range from 0.7 to 2.998 and the overall degree of substitution being within the range from 1.5 to 3, its preparation and its use and also quaternary starch ether esters present therein.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: November 9, 1999
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Andreas Schrell, Jimmy G. Welborn
  • Patent number: 5037448
    Abstract: Salts of ionic dyes with compounds which contain at least one ammonium, cycloammonium or immonium group and at least one aliphatic, cycloaliphatic or carbonyl radical-substituted aromatic group or containing a piperazine or piperidine group or a heteroaromatic group selected from those of the triazine, pyrimidine, quinazoline, quinoxaline, phthalazine or phthalimidine series or which contain at least two carboxylic acid groups, at least one amino groups and at least one carboxylic acid group or at least one sulfonic acid group and one aliphatic, cycloaliphatic, monocyclic aromatic or heteroaromatic group are useful for dyeing synthetic materials, particularly synthetic polyamides in the mass. The obtained dyeings have exceptionally good wet fastness.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: August 6, 1991
    Assignee: Sandoz Ltd.
    Inventor: Bansi L. Kaul
  • Patent number: 4413999
    Abstract: The invention provides amidoxime derivatives of the general formula ##STR1## wherein R.sub.1 is an alkyl group of 1 to 8 carbon atoms, phenyl, a heterocyclic ring structure of 5 to 8 atoms containing one or more nitrogen or oxygen atoms or combinations thereof or a bicyclic condensed ring system optionally containing at least one heterocyclic ring which groups may each be optionally substituted. R.sub.2 is a mono or bicyclic heterocyclic radical containing at least two nitrogen atoms which radical is also optionally substituted. R.sub.3 and R.sub.4 are independently H, or an alkyl of 1 to 4 carbon atoms or one, but not both, is ##STR2## and the other, H, wherein R.sub.5 or R.sub.6 are alkyls of 2 to 5 carbon atoms optionally substituted by R.sub.1, or a phenyl optionally substituted by R.sub.1 or R.sub.5 or R.sub.6 is combined with R.sub.1 to jointly form cyclic imidoximes or imidedioximes.
    Type: Grant
    Filed: March 5, 1982
    Date of Patent: November 8, 1983
    Assignee: Research Products Rehovot Ltd.
    Inventors: Charles Linder, Gershon Aviv
  • Patent number: 4411666
    Abstract: A process for dyeing polyolefin fiber materials, which comprises contacting a polyolefin fiber material obtained by melt-spinning a mixture of crystalline polyolefin and 0.1 to 30% by weight based on the weight of the polyolefin of a copolymer of ethylene and an aminoalkyl acrylate compound represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen atom or methyl group, R.sub.2 and R.sub.3 each represents hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and n represents an integer from 1 to 4, or a blend product of the said polyolefin fiber material and a polyamide fiber material, with a dye bath containing an anionic dye and at least one carboxylic acid selected from the group consisting of benzoic acid, salicylic acid, p-chlorobenzoic acid and 5-chlorosalicylic acid.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: October 25, 1983
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shuhei Hashizume, Sadaharu Abeta, Tadayuki Ohmae, Hajime Nishibara
  • Patent number: 4384870
    Abstract: Compounds of the formula ##STR1## in which A is the radical of a sulpho group-containing diazo component of the aniline or 1- or 2-aminonaphthalene series,K is a coupling component radical of the phenol series, having a free hydroxy group or an etherified or acylated hydroxy group,R.sub.1 is hydrogen C.sub.1-4 alkoxy, C.sub.1-4 alkyl or C.sub.1-4 haloalkyl,R.sub.2 is C.sub.1-4 alkyl, C.sub.1-6 alkyl-CO-, C.sub.1-6 alkyl-O-CO-, -CONH.sub.2, C.sub.1-6 alkyl-NH-CO-, di-(C.sub.1-6 alkyl)N-CO-, 2-, 3-, 4-, 5- or 6-hydroxy(C.sub.2-6 alkyl)-NH-CO- or (2-, 3-, 4-, 5- or 6-hydroxy(C.sub.2-6 alkyl)).sub.2 N-CO-, andR.sub.10 is hydrogen or C.sub.1-4 alkyl,and mixtures thereof, which compounds are in free acid or salt form and are useful for dyeing or printing anionic dyeable substrates such as leather, natural and synthetic polyamides, polyurethanes and polyolefins modified to contain basic groups, especially nylon.
    Type: Grant
    Filed: July 27, 1981
    Date of Patent: May 24, 1983
    Assignee: Sandoz Ltd.
    Inventor: Francois Benguerel
  • Patent number: 4378970
    Abstract: Red monoazo dyestuffs frm diazotised 1-aminobenzene-2-sulphonic acid-N-methyl-N-cyclohexylamide or 1-amino-4-,-5- or -6-methyl-benzene-2-sulphonic acid-N-methyl-N-cyclohexylamide and 2-amino-8-hydroxynaphthalene-6-sulphonic acid are disclosed which are particularly distinguished by their good migration and levelling properties and excellent fastness to light. Said dyestuffs are moreover suitable for obtaining very even combination dyeings together with known blue or yellow acid dyestuffs. These dyestuffs are particularly suited for the dyeing of carpeting, upholstery fabrics and drapery materials.
    Type: Grant
    Filed: October 15, 1981
    Date of Patent: April 5, 1983
    Assignee: Ciba-Geigy AG
    Inventors: Paul Lienhard, Fabio Beffa
  • Patent number: 4358287
    Abstract: 1:2 Metal complexes of the formula ##STR1## in which each of X.sub.1 and X.sub.2, independently, is --COO-- or --O--,each of B.sub.1 and B.sub.2, independently, is a radical of a coupling component of the benzene or oxyquinoline series,M is a metal capable of forming a 1:2 complex and,each of ##STR2## independently, is the radical of a diazo component of the benzene series, with the proviso that at most one of such diazo component radicals contains a single sulpho group,and mixtures thereof with one or more of the corresponding symmetrical 1:2 metal complexes,which complexes and mixtures of complexes are in free acid or salt form and are useful as anionic dyes for dyeing and printing substrates such as natural and regenerated cellulose, natural and synthetic polyamides, polyurethanes and polymers modified to contain basic groups, especially leather.
    Type: Grant
    Filed: April 13, 1981
    Date of Patent: November 9, 1982
    Assignee: Sandoz Ltd.
    Inventors: Heinz Wicki, Claude Vogel
  • Patent number: 4300899
    Abstract: The present invention relates to compounds of formula I.sub.x, ##STR1## in which Y.sub.1 is (C.sub.1-6) alkoxy, Z is hydrogen, alkali metal or ammonium, andn is 1 or 2and a process for treating anionic dyeable substrates therewith to reserve the same against anionic dyes.
    Type: Grant
    Filed: February 20, 1980
    Date of Patent: November 17, 1981
    Assignee: Sandoz Ltd.
    Inventor: Hans-Rudolf Schmid