Thiosulfato Group Containing Dye Patents (Class 8/546)
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Patent number: 10550268Abstract: A reactive dye of formula wherein Z1 and Z2 are each independently of the other vinyl or a radical —CH2—CH2—Y and Y is a group removable under alkaline conditions, n is the number 1, 2, 3 or 4, m is the number 2, 3 or 4, q is the number 0 or 1, and the substituents —(SO3H)n, —SO2—Z1 and —NH—CO—(CH2)m—SO2—Z2 are bound to the benzene rings A, B and/or C, said benzene rings A, B and/or C are optionally further substituted by at least one substituent selected from the group C1-C4alkyl, C1-C4alkoxy and halogen, is suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.Type: GrantFiled: December 6, 2016Date of Patent: February 4, 2020Assignee: HUNTSMAN INTERNATIONAL LLCInventors: Hubert Jean-Luc Christnacher, Fanny Ehret, Athanassios Tzikas, Rainer Hildebrand, Michael Nicollet
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Patent number: 9371611Abstract: Provided are processes for dyeing or printing fibre materials using reactive dye mixtures. The reactive dyes mixtures have been found to be suitable for dyeing or printing hydroxyl-group containing fibre materials or nitrogen-containing fibre materials. The dyeings or prints obtained according to such processes exhibit good all around fastness properties.Type: GrantFiled: September 15, 2014Date of Patent: June 21, 2016Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen
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Patent number: 8864850Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fiber materials, while at the same time exhibiting good build-up behavior, and yield dyeings of deep shade having good fastness properties.Type: GrantFiled: January 23, 2013Date of Patent: October 21, 2014Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen
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Patent number: 7717965Abstract: Dye mixtures that comprise at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable, with good build-up behaviour, for dyeing or printing cellulose-containing fibre materials, and yield dyeings having a deep shade and good fastness properties.Type: GrantFiled: June 28, 2006Date of Patent: May 18, 2010Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Lue Christnacher, Bruno Cortese
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Patent number: 7666232Abstract: A reactive trichromatic set comprising (a) at least one of the following reactive red dye of formula (I), wherein R1, R2, R3, X, D, Z, and n are defined the same as in the specification; (b) at least one reactive yellow dye selected from the following Color Index; C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176; and (c) at least one reactive blue dye selected from the following Color Index; C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222.Type: GrantFiled: June 22, 2006Date of Patent: February 23, 2010Assignee: Everlight USA, Inc.Inventors: Wen-Jang Chen, Bao-Kun Lai, Te-Chin Sung, Cheng-Hsiang Hsu
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Patent number: 7553339Abstract: A method of dyeing or printing textile fiber materials, which comprises bringing the fiber material into contact with (a) at least one reactive dye containing at least one anionic group, (b) at least one compound which reduces the ionic character of the anionic group, and (c) at least one nucleophilic compound, yields dyeings or prints having deep hues and very good fastness properties.Type: GrantFiled: November 1, 2004Date of Patent: June 30, 2009Assignee: Huntsman International LLCInventors: Jürgen Schmiedl, Wolfgang Mundle
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Patent number: 6706077Abstract: A coloring system for hair and/or skin comprises at least three separately packaged components: a) a thio compound capable of breaking the S—S bond between cysteine residues, and an alkaline reagent; b) a material and/or extract obtainable from the mucuna plant; and c) an oxidizing agent.Type: GrantFiled: March 5, 2002Date of Patent: March 16, 2004Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Krithivasan Bhagyalakshmi, Indu Mani, Govindarajan Raman
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Publication number: 20030163879Abstract: Disclosed is a dye mixture including two or more compounds of the formula IType: ApplicationFiled: July 12, 2002Publication date: September 4, 2003Inventors: Colin Brennan, Manfred Patsch
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Patent number: 6451071Abstract: This invention relates to colorants comprising organic chromophores, in particular reactive dyes, which comprise electrophilic reactive groups, and which are also covalently bonded to fatty amine moieties through amino linking groups. Such colorants provide excellent colorability and long-term stability, both within (or on) colored substrates and upon long-term storage. Such colorants exhibit particularly good coloring and stability within hydrocarbon compositions, such as fuels, mineral oil, and the like, and wax compositions, including candles, crayons, and the like. Methods of making such colorants as well as methods of coloring hydrocarbon and wax compositions are also contemplated within this invention.Type: GrantFiled: March 28, 2000Date of Patent: September 17, 2002Assignee: Milliken & CompanyInventor: John D. Bruhnke
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Publication number: 20010027582Abstract: Reactive dyes of formula 1Type: ApplicationFiled: March 19, 2001Publication date: October 11, 2001Inventors: Athanassios Tzikas, Rolf Deitz, Bruno Cortese
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Patent number: 6287348Abstract: This invention relates to colorants comprising organic chromophores, in particular reactive dyes, which comprise electrophilic reactive groups, and which are also covalently bonded to fatty amine moieties through amino linking groups. Such colorants provide excellent colorability and long-term stability, both within (or on) colored substrates and upon long-term storage. Such colorants exhibit particularly good coloring and stability within hydrocarbon compositions, such as fuels, mineral oil, and the like, and wax compositions, including candles, crayons, and the like. Methods of making such colorants as well as methods of coloring hydrocarbon and wax compositions are also contemplated within this invention.Type: GrantFiled: December 15, 1998Date of Patent: September 11, 2001Assignee: Milliken & CompanyInventor: John D. Bruhnke
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Patent number: 6143039Abstract: The present invention provides a dye mixture comprising one or more copper complex formazan dyes conforming to the formula (1) ##STR1## and one or more copper complex formazan dyes conforming to the formula (2) ##STR2## wherein R1, R2, Y1, Y2 and M are defined as given in claim 1, methods for preparing said dye mixtures and methods for dyeing and printing hydroxy- and/or carboxamido-containing materials using said dye mixtures.Type: GrantFiled: April 12, 1999Date of Patent: November 7, 2000Assignee: Dystar Textilfarben GmbH & Co.Inventors: Ron Pedemonte, Werner Russ
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Patent number: 6106580Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series, one or more monoazo dyes composed of a sulfo-substituted 2-amino-naphthalene as coupling component and a diazo component of the aniline series containing a fiber-reactive group of the vinylsulfone series, and optionally one or two monoazo dyes with 1-amino-3,6-disulfo-8-naphthol as a coupling component to which is coupled in the ortho-position to the amino group a diazo component of the aniline series substituted by a fiber-reactive group of the vinylsulfone series. The dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.Type: GrantFiled: August 27, 1998Date of Patent: August 22, 2000Assignee: Dystar Textilfarben GmbH & Co. Deutschland KGInventor: Joachim Steckelberg
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Patent number: 6036732Abstract: The present invention is a dye mixture containing one or more disazo dyes conforming to the formula (1), one or more monoazo dyes conforming to the formula (2), and one or more dyes of the formulae (3) The invention further relates to a method for its preparation and a process for dyeing hydroxy- and/or carboxamido containing fiber material in which the inventive dye is applied to the material.Type: GrantFiled: April 30, 1999Date of Patent: March 14, 2000Assignee: Dystar Textilfarben GmbH & Co. Deuschland KGInventors: Ron Pedemonte, Stefan Meier
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Patent number: 6015439Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series and one or more monoazo dyes composed of a cyanoamido- or morpholino- or amino-substituted chlorotriazinylamino-sulfo-naphthol coupling component and a diazo component of the aniline series containing a fiber-reactive group of the vinylsulfone series, which dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.Type: GrantFiled: February 16, 1999Date of Patent: January 18, 2000Assignee: Dystar Textilefarben GmbH & Co.Inventors: Ron Pedemonte, Andreas Stroben
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Patent number: 5931974Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series, one or more monoazo dyes composed of a carboxy-substituted benzoylamino-sulfo-naphthol coupling component and a diazo component of the aniline series, containing a fiber-reactive group of the vinylsulfone series and optionally one or two monoazo dyes with 1-amino-3,6-disulfo-8-naphthol as a coupling component to which is coupled in the ortho-position to the amino group a diazo component of the aniline series substituted by a fiber-reactive group of the vinylsulfone series. The dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.Type: GrantFiled: July 28, 1998Date of Patent: August 3, 1999Assignee: Dystar Textilfarben GmbH & Co.Inventor: Ronald P. Pedemonte
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Patent number: 5882356Abstract: The fibrillation tendency of solvent-spun cellulose fiber is reduced by treating the previously dried fiber with a chemical reagent containing at least two functional groups which are reactive with cellulose and which are electrophilic carbon--carbon double bonds, particularly vinyl sulfone groups, or precursors thereof or electrophilic three-membered heterocyclic rings or precursors thereof. The chemical reagent is preferably colorless and is preferably applied to the fiber from aqueous solution. The fiber may be contained in a woven or knotted fabric.Type: GrantFiled: July 7, 1997Date of Patent: March 16, 1999Assignee: Courtaulds Fibres (Holdings) LimitedInventor: Christopher David Potter
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Patent number: 5704951Abstract: A solid or dissolved dye mixture of azo dyes having fiber-reactive groups of the vinyl sulfone series, yielding dyeings of blue color shade, comprising one or more copper formazane dyes of the general formula (1) shown and defined in claim 1, one or more disazo dyes of the general formula (2) shown and defined in claim 1, and one or two monoazo dyes of the general formula (3) shown and defined in claim 1, respectively in the description part of the patent application, which dye mixtures are suitable for dyeing hydroxy- and/or caroboxamido groups containing materials, in particular fiber materials, such as cellulose fibers, for example cotton, wool and synthetic polyamide fibers, also together with other suitable dyes in trichromatic dyeing.Type: GrantFiled: April 1, 1996Date of Patent: January 6, 1998Assignee: Hoechst AktiengesellschaftInventors: Daniele Negri, Andreas Von Der Eltz, Werner Hubert Russ, Bengt-Thomas Grobel
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Patent number: 5690698Abstract: A dye mixture of azo dyes having fiber-reactive groups of the vinylsulfone series, comprising one or more navy-blue disazo dyes with the bivalent 1-amino-8-hydroxy-3,6-disulfo-naphthylene coupling component, one or more red-dyeing mono azo dyes, containing a phenylamino-chlorotriazinylamino-disulfo-naphthol-coupling component and one or more orange-dyeing monoazo dyestuffs with an amino-sulfonaphthol-coupling component, which dye mixtures are suitable for dyeing hydroxy- and/or carboxamido-groups containing materials, in particular fiber materials, such as cellulose fibers, for example cotton, wool and synthetic polyamide fibers.Type: GrantFiled: March 6, 1996Date of Patent: November 25, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Von Der Eltz, Werner Hubert Russ, Dirk Buchwald
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Patent number: 5474580Abstract: A process for the coloration of a substrate, especially a textile, comprising the steps of:(a) applying to the substrate a mixture comprising an aqueous solvent and a water-soluble dye comprising molecules which contain a nucleophilic group and an electrophilic group; and(b) heating or basifying or heating and basifying the dye thereby causing molecules of the dye to join together.Also claimed are dyes, polymers and oligomers.Type: GrantFiled: November 29, 1993Date of Patent: December 12, 1995Assignee: Zeneca LimitedInventors: Andrew H. M. Renfrew, Andrew P. Shawcross
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Patent number: 5445654Abstract: The disclosed black dye mixtures contain 50 to 95% by weight of one or more disazo dyes of the formula (1) and 5 to 50% by weight of one or more monoazo dyes of the formula (2) ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6, identical to or different from each other, are each hydrogen, methyl, ethyl, methoxy, ethoxy, sulfo or carboxy,Y is in each instance independently of the others vinyl, .beta.-chloroethyl, .beta.thiosulfatoethyl or .beta.-sulfatoethyl, andM is hydrogen or an alkali metal.Type: GrantFiled: November 24, 1993Date of Patent: August 29, 1995Assignee: Hoechst AktiengesellschaftInventors: Kurt Hussong, Werner H. Russ, Karl Krieger
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Patent number: 5378242Abstract: A liquid alkali for use in soaping off of cotton and cotton blended fabrics. The liquid alkali is a water-based solution of an alkali metal hydroxide and an alkali metal silicate. Preferably the composition is an aqueous mixture of potassium hydroxide and sodium silicate. In the most preferred embodiment the composition includes 35 wt % potassium hydroxide at a 45 wt % concentration, 25 wt % sodium silicate at 50.degree. Baume, and the balance water. In an alternative embodiment, up to 5 wt % of a borate is added.Type: GrantFiled: December 22, 1992Date of Patent: January 3, 1995Assignee: Apollo Chemical CompanyInventors: Nick J. Christie, Samuel G. Jones
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Patent number: 4647285Abstract: The invention relates to a process for printing cellulosic fibres or cellulose-containing blend fibres with reactive dyes or dye mixtures which contain a reactive dye and subsequent fixation, which comprises printing these materials with a print paste containing at least one water-soluble reactive dye of the formulaD--(X).sub.m (1)in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, nitroaryl, dioxazine, phenazine or stilbene series, X is a fibre-reactive radical of the aliphatic, aromatic or heterocyclic series which is bonded to the radical D either directly or via a bridge member and m is 1, 2, 3, 4, 5 or 6, and salts of aliphatic carboxylic acids having 3 to 18 carbon atoms, and subsequently fixing the print; and to the print pastes used and to their use for printing textile materials.Type: GrantFiled: September 20, 1985Date of Patent: March 3, 1987Assignee: Ciba-Geigy CorporationInventors: Peter Scheibli, Alex Kanzig, Andres Schaub
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Patent number: 4268266Abstract: Padding liquors or printing pastes which contain at least one compound which is free from ionic groups and possesses one or more glycidyl radicals are used for dyeing and printing cellulose fibres or textile materials containing cellulose fibres with water-soluble reactive dyestuffs in the absence of alkalis or alkaline compounds.Type: GrantFiled: August 27, 1979Date of Patent: May 19, 1981Assignee: Bayer AktiengesellschaftInventors: Udo-Winfried Hendricks, Dietrich Hildebrand, Robert Kuth