Thiosulfato Group Containing Dye Patents (Class 8/546)
  • Patent number: 10550268
    Abstract: A reactive dye of formula wherein Z1 and Z2 are each independently of the other vinyl or a radical —CH2—CH2—Y and Y is a group removable under alkaline conditions, n is the number 1, 2, 3 or 4, m is the number 2, 3 or 4, q is the number 0 or 1, and the substituents —(SO3H)n, —SO2—Z1 and —NH—CO—(CH2)m—SO2—Z2 are bound to the benzene rings A, B and/or C, said benzene rings A, B and/or C are optionally further substituted by at least one substituent selected from the group C1-C4alkyl, C1-C4alkoxy and halogen, is suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.
    Type: Grant
    Filed: December 6, 2016
    Date of Patent: February 4, 2020
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Hubert Jean-Luc Christnacher, Fanny Ehret, Athanassios Tzikas, Rainer Hildebrand, Michael Nicollet
  • Patent number: 9371611
    Abstract: Provided are processes for dyeing or printing fibre materials using reactive dye mixtures. The reactive dyes mixtures have been found to be suitable for dyeing or printing hydroxyl-group containing fibre materials or nitrogen-containing fibre materials. The dyeings or prints obtained according to such processes exhibit good all around fastness properties.
    Type: Grant
    Filed: September 15, 2014
    Date of Patent: June 21, 2016
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen
  • Patent number: 8864850
    Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fiber materials, while at the same time exhibiting good build-up behavior, and yield dyeings of deep shade having good fastness properties.
    Type: Grant
    Filed: January 23, 2013
    Date of Patent: October 21, 2014
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen
  • Patent number: 7717965
    Abstract: Dye mixtures that comprise at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable, with good build-up behaviour, for dyeing or printing cellulose-containing fibre materials, and yield dyeings having a deep shade and good fastness properties.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: May 18, 2010
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Lue Christnacher, Bruno Cortese
  • Patent number: 7666232
    Abstract: A reactive trichromatic set comprising (a) at least one of the following reactive red dye of formula (I), wherein R1, R2, R3, X, D, Z, and n are defined the same as in the specification; (b) at least one reactive yellow dye selected from the following Color Index; C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176; and (c) at least one reactive blue dye selected from the following Color Index; C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: February 23, 2010
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Bao-Kun Lai, Te-Chin Sung, Cheng-Hsiang Hsu
  • Patent number: 7553339
    Abstract: A method of dyeing or printing textile fiber materials, which comprises bringing the fiber material into contact with (a) at least one reactive dye containing at least one anionic group, (b) at least one compound which reduces the ionic character of the anionic group, and (c) at least one nucleophilic compound, yields dyeings or prints having deep hues and very good fastness properties.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: June 30, 2009
    Assignee: Huntsman International LLC
    Inventors: Jürgen Schmiedl, Wolfgang Mundle
  • Patent number: 6706077
    Abstract: A coloring system for hair and/or skin comprises at least three separately packaged components: a) a thio compound capable of breaking the S—S bond between cysteine residues, and an alkaline reagent; b) a material and/or extract obtainable from the mucuna plant; and c) an oxidizing agent.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: March 16, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Krithivasan Bhagyalakshmi, Indu Mani, Govindarajan Raman
  • Publication number: 20030163879
    Abstract: Disclosed is a dye mixture including two or more compounds of the formula I
    Type: Application
    Filed: July 12, 2002
    Publication date: September 4, 2003
    Inventors: Colin Brennan, Manfred Patsch
  • Patent number: 6451071
    Abstract: This invention relates to colorants comprising organic chromophores, in particular reactive dyes, which comprise electrophilic reactive groups, and which are also covalently bonded to fatty amine moieties through amino linking groups. Such colorants provide excellent colorability and long-term stability, both within (or on) colored substrates and upon long-term storage. Such colorants exhibit particularly good coloring and stability within hydrocarbon compositions, such as fuels, mineral oil, and the like, and wax compositions, including candles, crayons, and the like. Methods of making such colorants as well as methods of coloring hydrocarbon and wax compositions are also contemplated within this invention.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: September 17, 2002
    Assignee: Milliken & Company
    Inventor: John D. Bruhnke
  • Publication number: 20010027582
    Abstract: Reactive dyes of formula 1
    Type: Application
    Filed: March 19, 2001
    Publication date: October 11, 2001
    Inventors: Athanassios Tzikas, Rolf Deitz, Bruno Cortese
  • Patent number: 6287348
    Abstract: This invention relates to colorants comprising organic chromophores, in particular reactive dyes, which comprise electrophilic reactive groups, and which are also covalently bonded to fatty amine moieties through amino linking groups. Such colorants provide excellent colorability and long-term stability, both within (or on) colored substrates and upon long-term storage. Such colorants exhibit particularly good coloring and stability within hydrocarbon compositions, such as fuels, mineral oil, and the like, and wax compositions, including candles, crayons, and the like. Methods of making such colorants as well as methods of coloring hydrocarbon and wax compositions are also contemplated within this invention.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: September 11, 2001
    Assignee: Milliken & Company
    Inventor: John D. Bruhnke
  • Patent number: 6143039
    Abstract: The present invention provides a dye mixture comprising one or more copper complex formazan dyes conforming to the formula (1) ##STR1## and one or more copper complex formazan dyes conforming to the formula (2) ##STR2## wherein R1, R2, Y1, Y2 and M are defined as given in claim 1, methods for preparing said dye mixtures and methods for dyeing and printing hydroxy- and/or carboxamido-containing materials using said dye mixtures.
    Type: Grant
    Filed: April 12, 1999
    Date of Patent: November 7, 2000
    Assignee: Dystar Textilfarben GmbH & Co.
    Inventors: Ron Pedemonte, Werner Russ
  • Patent number: 6106580
    Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series, one or more monoazo dyes composed of a sulfo-substituted 2-amino-naphthalene as coupling component and a diazo component of the aniline series containing a fiber-reactive group of the vinylsulfone series, and optionally one or two monoazo dyes with 1-amino-3,6-disulfo-8-naphthol as a coupling component to which is coupled in the ortho-position to the amino group a diazo component of the aniline series substituted by a fiber-reactive group of the vinylsulfone series. The dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: August 22, 2000
    Assignee: Dystar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Joachim Steckelberg
  • Patent number: 6036732
    Abstract: The present invention is a dye mixture containing one or more disazo dyes conforming to the formula (1), one or more monoazo dyes conforming to the formula (2), and one or more dyes of the formulae (3) The invention further relates to a method for its preparation and a process for dyeing hydroxy- and/or carboxamido containing fiber material in which the inventive dye is applied to the material.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: March 14, 2000
    Assignee: Dystar Textilfarben GmbH & Co. Deuschland KG
    Inventors: Ron Pedemonte, Stefan Meier
  • Patent number: 6015439
    Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series and one or more monoazo dyes composed of a cyanoamido- or morpholino- or amino-substituted chlorotriazinylamino-sulfo-naphthol coupling component and a diazo component of the aniline series containing a fiber-reactive group of the vinylsulfone series, which dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.
    Type: Grant
    Filed: February 16, 1999
    Date of Patent: January 18, 2000
    Assignee: Dystar Textilefarben GmbH & Co.
    Inventors: Ron Pedemonte, Andreas Stroben
  • Patent number: 5931974
    Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series, one or more monoazo dyes composed of a carboxy-substituted benzoylamino-sulfo-naphthol coupling component and a diazo component of the aniline series, containing a fiber-reactive group of the vinylsulfone series and optionally one or two monoazo dyes with 1-amino-3,6-disulfo-8-naphthol as a coupling component to which is coupled in the ortho-position to the amino group a diazo component of the aniline series substituted by a fiber-reactive group of the vinylsulfone series. The dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: August 3, 1999
    Assignee: Dystar Textilfarben GmbH & Co.
    Inventor: Ronald P. Pedemonte
  • Patent number: 5882356
    Abstract: The fibrillation tendency of solvent-spun cellulose fiber is reduced by treating the previously dried fiber with a chemical reagent containing at least two functional groups which are reactive with cellulose and which are electrophilic carbon--carbon double bonds, particularly vinyl sulfone groups, or precursors thereof or electrophilic three-membered heterocyclic rings or precursors thereof. The chemical reagent is preferably colorless and is preferably applied to the fiber from aqueous solution. The fiber may be contained in a woven or knotted fabric.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: March 16, 1999
    Assignee: Courtaulds Fibres (Holdings) Limited
    Inventor: Christopher David Potter
  • Patent number: 5704951
    Abstract: A solid or dissolved dye mixture of azo dyes having fiber-reactive groups of the vinyl sulfone series, yielding dyeings of blue color shade, comprising one or more copper formazane dyes of the general formula (1) shown and defined in claim 1, one or more disazo dyes of the general formula (2) shown and defined in claim 1, and one or two monoazo dyes of the general formula (3) shown and defined in claim 1, respectively in the description part of the patent application, which dye mixtures are suitable for dyeing hydroxy- and/or caroboxamido groups containing materials, in particular fiber materials, such as cellulose fibers, for example cotton, wool and synthetic polyamide fibers, also together with other suitable dyes in trichromatic dyeing.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Daniele Negri, Andreas Von Der Eltz, Werner Hubert Russ, Bengt-Thomas Grobel
  • Patent number: 5690698
    Abstract: A dye mixture of azo dyes having fiber-reactive groups of the vinylsulfone series, comprising one or more navy-blue disazo dyes with the bivalent 1-amino-8-hydroxy-3,6-disulfo-naphthylene coupling component, one or more red-dyeing mono azo dyes, containing a phenylamino-chlorotriazinylamino-disulfo-naphthol-coupling component and one or more orange-dyeing monoazo dyestuffs with an amino-sulfonaphthol-coupling component, which dye mixtures are suitable for dyeing hydroxy- and/or carboxamido-groups containing materials, in particular fiber materials, such as cellulose fibers, for example cotton, wool and synthetic polyamide fibers.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: November 25, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Von Der Eltz, Werner Hubert Russ, Dirk Buchwald
  • Patent number: 5474580
    Abstract: A process for the coloration of a substrate, especially a textile, comprising the steps of:(a) applying to the substrate a mixture comprising an aqueous solvent and a water-soluble dye comprising molecules which contain a nucleophilic group and an electrophilic group; and(b) heating or basifying or heating and basifying the dye thereby causing molecules of the dye to join together.Also claimed are dyes, polymers and oligomers.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: December 12, 1995
    Assignee: Zeneca Limited
    Inventors: Andrew H. M. Renfrew, Andrew P. Shawcross
  • Patent number: 5445654
    Abstract: The disclosed black dye mixtures contain 50 to 95% by weight of one or more disazo dyes of the formula (1) and 5 to 50% by weight of one or more monoazo dyes of the formula (2) ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6, identical to or different from each other, are each hydrogen, methyl, ethyl, methoxy, ethoxy, sulfo or carboxy,Y is in each instance independently of the others vinyl, .beta.-chloroethyl, .beta.thiosulfatoethyl or .beta.-sulfatoethyl, andM is hydrogen or an alkali metal.
    Type: Grant
    Filed: November 24, 1993
    Date of Patent: August 29, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Kurt Hussong, Werner H. Russ, Karl Krieger
  • Patent number: 5378242
    Abstract: A liquid alkali for use in soaping off of cotton and cotton blended fabrics. The liquid alkali is a water-based solution of an alkali metal hydroxide and an alkali metal silicate. Preferably the composition is an aqueous mixture of potassium hydroxide and sodium silicate. In the most preferred embodiment the composition includes 35 wt % potassium hydroxide at a 45 wt % concentration, 25 wt % sodium silicate at 50.degree. Baume, and the balance water. In an alternative embodiment, up to 5 wt % of a borate is added.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: January 3, 1995
    Assignee: Apollo Chemical Company
    Inventors: Nick J. Christie, Samuel G. Jones
  • Patent number: 4647285
    Abstract: The invention relates to a process for printing cellulosic fibres or cellulose-containing blend fibres with reactive dyes or dye mixtures which contain a reactive dye and subsequent fixation, which comprises printing these materials with a print paste containing at least one water-soluble reactive dye of the formulaD--(X).sub.m (1)in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, nitroaryl, dioxazine, phenazine or stilbene series, X is a fibre-reactive radical of the aliphatic, aromatic or heterocyclic series which is bonded to the radical D either directly or via a bridge member and m is 1, 2, 3, 4, 5 or 6, and salts of aliphatic carboxylic acids having 3 to 18 carbon atoms, and subsequently fixing the print; and to the print pastes used and to their use for printing textile materials.
    Type: Grant
    Filed: September 20, 1985
    Date of Patent: March 3, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Scheibli, Alex Kanzig, Andres Schaub
  • Patent number: 4268266
    Abstract: Padding liquors or printing pastes which contain at least one compound which is free from ionic groups and possesses one or more glycidyl radicals are used for dyeing and printing cellulose fibres or textile materials containing cellulose fibres with water-soluble reactive dyestuffs in the absence of alkalis or alkaline compounds.
    Type: Grant
    Filed: August 27, 1979
    Date of Patent: May 19, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo-Winfried Hendricks, Dietrich Hildebrand, Robert Kuth