Alkylene Sulfato, Halotriazine, Halodiazine, Haloquinoxaline, Or Halopyrimidine Dye Patents (Class 8/549)
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Patent number: 12091552Abstract: Disclosed are reactive dyes and preparation methods thereof. The reactive dye may be prepared using heterocyclic primary amine as a diazo component, 4,4?-diamino-2,2?-stilbenedisulfonic acid, s-triazine, or ethylenediamine as a bridging group, and a dimonochlortriazine group as an active group. The color-changing compound is covalently bonded into the fiber chemical structure by nucleophilic substitution reaction between monochlorotriazine and the hydroxyl group in a textile structure, and the size of the conjugated system and the range of electron delocalization of the dye are changed by a reversible isomerization reaction of the hydroxyl group adjacent to the diazo group and the diazo group under different pH regulations. Moreover, the dye has a double color changing structure, which improves the capability of the dye combined with —H/—OH. The pH value range that can cause color changes in the dye is effectively expanded to include weak alkali, weak acid or even neutral conditions.Type: GrantFiled: August 7, 2023Date of Patent: September 17, 2024Assignee: NANTONG UNIVERSITYInventors: Min Li, Wujun Ma, Jialiang Zhou, Wenlin Qu, Ting Ding, Lifen Mao, Shiyu Li
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Patent number: 12053944Abstract: A dyeing method for functional contact lenses includes the following steps: providing a dry lens body, including hydrogel with 0-90% water content, silicone hydrogel with 0-90% water content, or a combination thereof; preparing an amphoteric polymethyl ether prepolymer, combining the amphoteric polymethyl ether prepolymer with a hydrophilic monomer to form a masking ring material, and attaching the masking ring material to an inner surface of the dry lens body to form a masking ring layer; dropping a colorant onto the inner surface, making the masking ring layer surround the colorant, irradiating the colorant with an ultraviolet light and then heating and fixing the colorant to form a dyed layer on the inner surface; and placing the dry lens body in water to hydrate and removing the masking ring layer to obtain a wet lens body.Type: GrantFiled: August 29, 2022Date of Patent: August 6, 2024Assignee: VIZIONFOCUS INC.Inventors: Wen-Ching Lin, Ching-Fang Lee, Chi-Ching Chen, Hsiao-Chun Lin
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Patent number: 11834781Abstract: The disclosure provides a method of continuous dyeing with reactive dyes in wet conditions, the method including: 1) adding fabric to a mixture of a dye liquor and an alkali through a one-bath-one-step method; 2) immersing the fabric pretreated in 1) in a padding liquor with an air film horizontal pad dyeing machine; 3) preheating the fabric after being treated in 2) at a temperature of 50-90° C.; and 4) rolling and batching the fabric after being treated in 3) at a temperature of 10-70° C. for 2-72 hours.Type: GrantFiled: July 20, 2021Date of Patent: December 5, 2023Assignees: HUAFANG CO., LTD, DONGHUA UNIVERSITY, BINZHOU HUA TEXTILE ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD.Inventors: Zhiping Mao, Hongyu Sun, Chunguang Li, Rongxia Jia, Yi Zhong, Hong Xu, Limin Wang, Qi Yu, Xiaomin Liu, Qingbo Lu, Chunying Sheng, Engang Lu, Qisheng Zhao, Wei Wu, Yamin Dai, Jinbo Wang
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Patent number: 9540765Abstract: A dye mixture, comprising at least one blue dyeing dye of the formula (1), wherein Q1 represents a bivalent radical of formula (4a), (4b) or (4c), wherein X1 denotes chlorine or fluorine, R1 is hydrogen or C1-C8 alkyl, R2 is hydrogen, C1-C8alkyl, C1-C4alkoxy or sulfo, Y1 is vinyl or a radical —CH2—CH2—U and U is a leaving group removable under alkaline conditions, R3 is hydrogen or C1-C8alkyl that is unsubstituted or substituted by hydroxy, sulfo, sulfato, cyano, carboxy, C1-C4alkoxy or phenyl, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 and at least one yellow or red dyeing reactive dye is suitable especially for the dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.Type: GrantFiled: February 5, 2014Date of Patent: January 10, 2017Assignee: HUNTSMAN INTERNATIONAL LLCInventors: Alexander Mueller, Rainer Hildebrand, Sandra Da Silva Saraiva, Wolfgang Mundle, Markus Kneubuehler
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Publication number: 20150143639Abstract: Reactive dyes of formula (1), wherein Me is chromium, cobalt or iron, R1 is hydrogen or unsubstituted or substituted C1-C4alkyl, E is a bivalent radical of formula (1a), (1b) or (1c) wherein X denotes chlorine or fluorine, T is a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e), or (2f), (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, q is the number 0 or 1, G is a bivalent radical of formula (1d) or (1e) wherein (R2)s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C1-C4alkyl, C2-C4alkanoylamino, C1-C4alkylsulfonyl, carbamoyl, sulfamoyl, sulfo and -E-T, wherein E and T are as defined above, s is the number 0, 1, 2 or 3, A denotes a bivalent radical of formula (3a), (3b) or (3c), wherein R1, R2, X, T, q and s are as defType: ApplicationFiled: April 25, 2013Publication date: May 28, 2015Inventors: Alexander Mueller, Kurt Plattner, Damien Schoehn, Rainer Hildebrand
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Publication number: 20150096131Abstract: Reactive dyes of formula (1) wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, X is halogen, 3- or 4-carboxypyridin-1-yl, or 3- or 4-carbamoylpyridin-1-yl, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, and q is the number 1 or 2, are suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.Type: ApplicationFiled: May 24, 2013Publication date: April 9, 2015Inventors: Georg Roentgen, Jean-Christophe Graciet, Rainer Hildebrand, Laszlo Fekete, Marie Schmidlin, Hubert Jean-Luc Christnacher
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Patent number: 8864850Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fiber materials, while at the same time exhibiting good build-up behavior, and yield dyeings of deep shade having good fastness properties.Type: GrantFiled: January 23, 2013Date of Patent: October 21, 2014Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen
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Publication number: 20140173835Abstract: Dye mixtures comprising at least one reactive dye of the formula (1) together with at least one reactive dye of the formula (2), wherein one of the radicals A and B denotes NH2, and the other one of the radicals A and B denotes OH, D is a benzene or naphthalene radical, R1 is hydrogen, hydroxy, sulfo, C1-C4alkyl or C1-C4alkoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R2 is hydrogen, C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino or ureido, R3 is C1-C4alkyl, (R4)0-2 denotes 0 to 2 identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy or sulfo, X1 is halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y1, Y2, Y3, Y4 and Y5 are each independently of the other vinyl or a radical —CH2CH2—U and U is a group removable under alkaline conditions, h, k, l, m and n are each independently of the other the number 0, 1 or 2, and p and q are each independently of the other the number 0 or 1, are suitable for dyeing and printing cellulosic or nitrogen-contaiType: ApplicationFiled: June 19, 2012Publication date: June 26, 2014Applicant: HUNTSMAN INTERNATIONAL LLCInventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean-Luc Christnacher, Laszlo Fekete
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Publication number: 20140157530Abstract: An ink composition for ink jet textile printing contains a reactive dye and water-soluble organic solvents including solvent A and at least one solvent B. Solvent A has a solubility of 10 g or more in 100 g of water at 20° C. and has no hydroxy group. Solvent B has a hydroxy group in the molecule thereof and has an IOB value of 2.9 or more and a Z1 value expressed by the following equation (1) of 18 or less. The total content Z2 of solvent A and solvents B in the ink composition is 3.8% by mass or more. Z 1 = ? i = 1 n ? ( 100 * Ii * Xi ) ( 1 ) wherein n represents the total number of solvents B in the ink composition, Ii represents the IOB value of solvent Bi that is any one of the solvents B, and Xi represents the ratio of the mass of solvent Bi to the total mass of the ink composition.Type: ApplicationFiled: December 10, 2013Publication date: June 12, 2014Applicant: Seiko Epson CorporationInventor: Masayuki Murai
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Publication number: 20140026333Abstract: Reactive dyes of formula (1), wherein R1 and R2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, one of the radicals D1 and D2 is a radical of the formula (2), the other one of the radicals D1 and D2 is a radical of the formula (3a), or (3b), wherein (R3)n denotes n identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Z1 is a radical of the formula —SO2—Y (4a), —CONH—(CH2)p—SO2—Y (4b), —NH—CO—CH(Hal)-CH2-Hal (4c), —NH—CO—C(Hal)?CH2 (4d), or (4e), wherein X1 is halogen, T1 independently has the definition of X1, is a non-fibre-reactive substituent or is a fibre-reactive radical of the formula (5a), —NH—(CH2)2-3—SO2—Y (5b), or —NH—(CH2)2-3—O—(CH2)2-3—SO2—Y (5c), R4 is hydrogen or unsubstituted or substituted C1-C4alkyl, (R5)0-2 denotes from 0 to 2 identical or different substituents from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Hal is halogen, Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkalineType: ApplicationFiled: March 5, 2012Publication date: January 30, 2014Inventors: Georg Roentgen, Laszlo Fekete, Michael Nicollet
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Publication number: 20130283546Abstract: Dye mixtures, comprising least one yellow dye of the formula (1), at least one yellow dye of the formula (2), at least one red dye of the formula (3), at least one blue dye of the formula (4), wherein the radicals have the definitions given in the claims, are suitable especially for the trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.Type: ApplicationFiled: June 22, 2011Publication date: October 31, 2013Applicant: HUNTSMAN INTERNATIONAL LLCInventors: Athanassios Tzikas, Georg Roentgen, Jean-Francois Landre, Remo Codemo
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Publication number: 20130133142Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fibre materials, while at the same time exhibiting good build-up behaviour, and yield dyeings of deep shade having good fastness properties.Type: ApplicationFiled: January 23, 2013Publication date: May 30, 2013Applicant: HUNTSMAN INTERNATIONAL LLCInventor: HUNTSMAN INTERNATIONAL LLC
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Publication number: 20120284934Abstract: The present invention provides azo dyes of formula (1) where Hal, M and Y are each as defined in claim 1, processes for their preparation and their use.Type: ApplicationFiled: March 13, 2012Publication date: November 15, 2012Applicant: DyStar Clours Deutschland GmbHInventor: Stefan Ehrenberg
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Publication number: 20120164288Abstract: Disclosed herein are solubility changeable dye compositions, methods of preparing such compositions and methods of using them. The composition includes a dye component linked via a linker moiety to a stimulus responsive hydrophobic moiety which modulates the solubility of the dye, wherein the hydrophobic moiety is configured to be de-linked from the dye component on exposure to a stimulus and render the dye component more hydrophilic.Type: ApplicationFiled: December 22, 2010Publication date: June 28, 2012Inventor: Seth Adrian Miller
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Patent number: 8080101Abstract: The present invention relates to dye mixtures which comprise at least one dye of the formula (I), at least one dye of the formula (II) and optionally at least one dye of the formula (III) and/or optionally at least one dye of the formula (IV) in which D1 to D7, R201 to R203, R0, R* and R**, T, M, v and f are as defined in claim 1, to dyes of the formula (II), to processes for their preparation, and to their use for dyeing and printing hydroxyl- and carboxamido-containing materials.Type: GrantFiled: September 29, 2006Date of Patent: December 20, 2011Assignee: DyStar Colours Deutschland GmbHInventors: Joachim Eichhorn, Stefan Meier, Werner Hubert Russ
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Patent number: 8066809Abstract: Reactive dyes of formula wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1-C4alkyl, D is a radical of a diazo component of the formula X1 and X2 independently of one another are halogen, T is a fiber-reactive radical of the formula (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fiber materials.Type: GrantFiled: July 31, 2007Date of Patent: November 29, 2011Assignee: Huntsman International LLCInventors: Georg Roentgen, Laszlo Fekete
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Publication number: 20110283465Abstract: The present invention relates to dyes of the formula (I), in which R1 to R4, D1, f, and M are defined as indicated in claim 1, to processes for preparing them, and to their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.Type: ApplicationFiled: January 18, 2010Publication date: November 24, 2011Applicant: DYSTAR COLOURS DEUTSCHLAND GMBHInventors: Joachim Eichhorn, Andreas Schrell
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Publication number: 20110173763Abstract: The invention provides a process for aminoarylating cellulosic materials such as cotton and reconstituted fibres and a process for treating the aminoarylated cellulose with an effect chemical such as a dye, flame retardant or cross linking agent. Improved take up of the effect chemical by the modified cellulose means increased efficiency in the process and in the case of dyeing, avoids or reduces the washing off of hydrolysed dye and the resultant production of large volumes of contaminated water requiring to be treated. The cellulosic material may be present in a blend with other types of fibre for example a blend with poly(alkyleneterephthalates) or polyamides.Type: ApplicationFiled: January 26, 2009Publication date: July 21, 2011Inventors: Colin Robert Willis, Stuart Anson Brewer, John Anthony Taylor, Duncan Adrian Phillips
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Patent number: 7967903Abstract: The present invention relates to a novel ink composition and, more particularly, to an ink composition for digital textile printing, which is suitable for ink-jet printing on cellulose fiber materials. The novel ink composition of the present invention has stable pH value, fine storage stability, smoothness and ease in printing, and reduction in color deterioration.Type: GrantFiled: January 26, 2009Date of Patent: June 28, 2011Assignee: Everlight USA, Inc.Inventors: Chuan-Hsi Lee, Hsiao-San Chen
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Patent number: 7905928Abstract: Reactive dyes of the formula (1) in which Q1, X, V1, V2, B, T and R1, R2, R4 and R5 are defined in the claims and in the disclosure and wherein the reactive dyes are suitable for dyeing widely varying fiber materials, in particular cellulosic fiber materials and produce dyeings with good allround properties.Type: GrantFiled: October 7, 2008Date of Patent: March 15, 2011Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Thomas Verdugo, Georg Roentgen
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Patent number: 7887602Abstract: Reactive dyes of formula wherein the variables are defined herein.Type: GrantFiled: August 2, 2006Date of Patent: February 15, 2011Assignee: Huntsman International, LLCInventors: Hubert Jean Luc Christnacher, Athanassios Tzikas, Georg Roentgen
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Patent number: 7745385Abstract: The present invention relates to a water-soluble pouch comprising a laundry detergent composition comprising reactive dye.Type: GrantFiled: March 30, 2009Date of Patent: June 29, 2010Assignee: The Procter & Gamble CompanyInventor: Alan Thomas Brooker
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Publication number: 20100159140Abstract: Reactive dyes of formula wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1-C4alkyl, D is a radical of a diazo component of the formula X1 and X2 independently of one another are halogen, T is a fibre-reactive radical of the formula (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fibre materials.Type: ApplicationFiled: July 31, 2007Publication date: June 24, 2010Applicant: HUNTSMAN INTERNATIONAL LLCInventors: Georg Roentgen, Laszlo Fekete
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Publication number: 20100154145Abstract: Reactive dyes of formula wherein B is an aliphatic bridging member, R1 is C1-C4alkyl, halogen or an —SO2—Z radical, R2 and R3 are each independently of the other C1-C4alkoxy, R4, R5 and R6 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, p is the number 0, 1 or 2, X1 and X2 are each independently of the other halogen, and T is halogen, a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R7)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group and Hal is halogen, or T is a radical of formula wherein R1, R2, R3, R4, k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness propType: ApplicationFiled: August 2, 2006Publication date: June 24, 2010Applicant: HUNTSMAN INTERNATIONAL LLCInventors: Hubert Jean Luc Christnacher, Athanassios Tzikas, Georg Roentgen
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Publication number: 20100151134Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fibre materials, while at the same time exhibiting good build-up behaviour, and yield dyeings of deep shade having good fastness properties.Type: ApplicationFiled: February 24, 2010Publication date: June 17, 2010Applicant: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen
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Patent number: 7708786Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2—Z or —Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: June 27, 2008Date of Patent: May 4, 2010Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
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Publication number: 20100024138Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye of formula wherein the radicals indicated in the formulae are defined in accordance with the claims, are suitable for dyeing or printing cellulosic fibre materials with good build-up behaviour and yield dyeings of a deep shade having good fastness properties.Type: ApplicationFiled: September 25, 2009Publication date: February 4, 2010Applicant: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen
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Patent number: 7641724Abstract: Dye mixtures comprising at least one dye of formula (I) together with at least one dye of formula (II) wherein the radicals are as defined in the claim, are suitable for dyeing or printing cellulosic fiber materials, while having a good build-up behavior, and yield dyeings of a deep shade having good fastness properties.Type: GrantFiled: November 8, 2004Date of Patent: January 5, 2010Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen
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Patent number: 7632316Abstract: The present invention relates to dyes of the general formula (1) where M and X are each as defined in claim 1, dye mixtures comprising one or more of the dyes of the general formula (1) and also one or more further fiber-reactive dyes, processes for their preparation, their use and printing inks comprising same.Type: GrantFiled: May 24, 2006Date of Patent: December 15, 2009Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Stefan Meier, Uwe Reiher, Werner Hubert Russ, Günther Schwaiger
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Patent number: 7604669Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fiber-reactive substituent or a fiber-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substituents frType: GrantFiled: November 6, 2006Date of Patent: October 20, 2009Assignee: Huntsman International LLCInventors: Jean-Marie Sire, Athanassios Tzikas, Georg Roentgen
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Patent number: 7597722Abstract: Process for manufacturing a fabric having distinctive and sharp differentially colored patterns or designs, which process comprises the steps of: (a) producing a first and a second polyamide, said polyamides having different concentrations of amine groups; (b) producing a first and a second polyamides having different concentrations of carboxyl end-groups and sulfonate groups; (c) producing a first yarn from said first polyamide and a second yarn from said second polyamide; (d) making a fabric having first surface areas defined by said first yarn and second surface areas defined by said second yarn; and (e) chemically dyeing said fabric in a dyeing bath comprising at least one anionic (acid) dyestuff and at least one cationic (basic) dyestuff, whereby said first yarn and therefore said first surface areas are dyed predominantly by said anionic dyestuff and said second yarn and therefore said second surface areas are dyed predominantly by said cationic dyestuff.Type: GrantFiled: February 19, 2004Date of Patent: October 6, 2009Assignee: Nilet Ltd.Inventors: Michael Eroshov, Alon Weiser, Thierry Mamodaly, Ran Rotem, Boris Streltses, Ariel Yedvab, Juliana Katz, Alexander Yermolaev, Samuel Gazit
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Publication number: 20090178213Abstract: Dye mixtures that comprise at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable, with good build-up behaviour, for dyeing or printing cellulose-containing fibre materials, and yield dyeings having a deep shade and good fastness properties.Type: ApplicationFiled: June 28, 2006Publication date: July 16, 2009Applicant: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Luc Christnacher, Bruno Cortese
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Patent number: 7553339Abstract: A method of dyeing or printing textile fiber materials, which comprises bringing the fiber material into contact with (a) at least one reactive dye containing at least one anionic group, (b) at least one compound which reduces the ionic character of the anionic group, and (c) at least one nucleophilic compound, yields dyeings or prints having deep hues and very good fastness properties.Type: GrantFiled: November 1, 2004Date of Patent: June 30, 2009Assignee: Huntsman International LLCInventors: Jürgen Schmiedl, Wolfgang Mundle
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Patent number: 7524368Abstract: The present invention relates to a black dye composition, comprising: (a) at least one azo dye of the following formula (I), (b) at least one azo dye of the following formula (II) or (III), wherein R1, R2, and R3 are defined the same as the specification. The present invention also relates to a black ink composition afforded from the aforementioned black dye composition. The black ink composition of the present invention for textile digital printing exhibits the properties of excellent color depth, fixation, stability of storage, stability and accuracy of printing for long time, and improves the issue of nozzle cloggage.Type: GrantFiled: September 10, 2007Date of Patent: April 28, 2009Assignee: Everlight USA, Inc.Inventors: Chuan-Hsi Lee, Tzu-Kwei Sun, Reng-Fang Lin, Hsiao-San Chen
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Patent number: 7524953Abstract: The invention relates to novel triphendioxazine pigments of formula (I) wherein X represents hydrogen or chlorine, while R1 represents phenyl substituted by one to five radicals from the group comprising C1-C4-alkyl, halogen, C1-C4-alkoxy, acetylamino, aminocarbonyl, methylaminocarbonyl and C1-C4-alkoxycarbonyl, or phenyl annelated in the 2,3- or 3,4- with a divalent radical of the formula —NH—(CO)m—NR2—, —CR2?CH—CO—NH—, —CR2?N—CO—NH—, —CO—NH—CO—NR2—, —CO—(NH)m—CO— or —O—(CO)m—NH— so as to form a five- or six-membered ring, R2 representing hydrogen, methyl, ethyl or phenyl and m representing 1 or 2.Type: GrantFiled: January 12, 2005Date of Patent: April 28, 2009Assignee: Clariant Produkte (Deutschland) GmbHInventors: David Blum, Carsten Plueg, Tanja Reipen
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Patent number: 7497971Abstract: The present invention relates to a mixture of fluorescent whitening agents comprising 11 to 20% by weight of a compound of formula (1), and 80 to 89% by weight of a compound of formula (2), wherein R1 denotes hydrogen, C1-C6alkyl, C5-C14aryl or C6-C24aralkyl and X is a bivalent radical of formula (3), (4) or (5) compositions containing the mixture and the use of the compositions for whitening synthetic fibers, in particular, polyester.Type: GrantFiled: December 1, 2003Date of Patent: March 3, 2009Assignee: Ciba Specialty Chemicals CorporationInventors: Jean-Jacques Donzé, Marie Meyberger, Michael Milde, Volker Papendick, Josef Zelger
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Publication number: 20090041938Abstract: The present invention concerns a dye mixture comprising at least one dye of the general formula (I) and at least one further dye either of the general formula (II) or of the general formula (III) or of the general formula (IV) where the variables are each as defined in claim 1, processes for their preparation and their use.Type: ApplicationFiled: January 19, 2007Publication date: February 12, 2009Applicant: DyStar Textilfarben GmbH & Co. Deutschland KGInventor: Andreas Giehl
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Publication number: 20090025152Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.Type: ApplicationFiled: June 27, 2008Publication date: January 29, 2009Applicant: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
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Publication number: 20080295732Abstract: The present invention relates to dye mixtures which comprise at least one dye of the formula (I), at least one dye of the formula (II) and optionally at least one dye of the formula (III) and/or optionally at least one dye of the formula (IV) in which D1 to D7, R201 to R203, R0, R* and R**, T, M, v and f are as defined in claim 1, to dyes of the formula (II), to processes for their preparation, and to their use for dyeing and printing hydroxyl- and carboxamido-containing materials.Type: ApplicationFiled: September 29, 2006Publication date: December 4, 2008Applicant: DyStar Textilfarben GmbH &Co. Deutschland KGInventors: Joachim Eichhorn, Stefan Meier, Werner Hubert Russ
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Publication number: 20080282484Abstract: The present invention discloses a reactive yellow dye composition comprising component (A) and component (B). The component (A) is a reactive azo dye represented by the following formula (I) or formula (II), The component (B) is a reactive azo dye represented by the following formula (III), wherein the substituents of the formulas (I), (II) and (III) are defined the same as in the specification. Moreover, the reactive yellow dye composition of the present invention has excellent build-up, wash-off and light fastness and can be applied with dyestuffs in other colors.Type: ApplicationFiled: August 2, 2007Publication date: November 20, 2008Applicant: Everlight USA, Inc.Inventors: Bao-Kun Lai, Cheng-Hsiang Hsu, Ya-Chi Tseng, Huei-Chin Huang
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Publication number: 20080274287Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (I) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.Type: ApplicationFiled: May 27, 2008Publication date: November 6, 2008Applicant: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Stefan Meier, Werner Russ, Joachim Eichhorn
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Patent number: 7442780Abstract: New, highly multifunctional reactive dye compounds are provided. The number of leaving groups in the non-chromophoric part of the molecule added to the number of chromophore moieties is at least equal to 5, preferably in the range of from 5 to 12, more preferably from 5 to 6. The new reactive dye compounds preferably have at least two asymmetric bridges.Type: GrantFiled: May 28, 2002Date of Patent: October 28, 2008Assignee: North Carolina State UniversityInventors: Wei Dong He, Peter Jeffrey Broadbent, David Malcolm Lewis
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Publication number: 20080256726Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substiType: ApplicationFiled: November 6, 2006Publication date: October 23, 2008Inventors: Jean-Marie Sire, Athanassios Tzikas, Georg Roentgen
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Publication number: 20080257208Abstract: Mixtures of reactive dyestuffs comprising one dyestuff of the formula (II-a) and at least one of the dyestuffs formula (II-b) to (II-d) wherein M is H, an alkali metal, an ammonium ion or the equivalent of an alkaline earth metal and is preferably H, sodium or potassium; A is diisopropanolamine B is an amine of one of the general formulae B-1 to B-8 wherein R3 is Hydrogen, Methyl, Ethyl, n-Propyl, i-Propyl, Hydroxyethyl, Hydroxypropyl, -Cyanethyl, -Hydroxycerbonylethyl, processes for their preparation and their use for dyeing and printing hydroxy- and/or carboxamidocontaining fiber materials.Type: ApplicationFiled: May 11, 2005Publication date: October 23, 2008Inventors: Warren J. Ebenezer, Werner Hubert Russ
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Patent number: 7438753Abstract: The present invention relates to a diazo dyestuff compound of the following formula (I) wherein, M is H, Na, or Li. The formula (I) compound is particularly suitable for using as a component in a black dye composition for ink-jet printing ink, and inkjet printing inks with good light-fastness are obtained.Type: GrantFiled: June 15, 2006Date of Patent: October 21, 2008Assignee: Everlight USA, Inc.Inventors: Jen-Fang Lin, Tzu-Kwei Sun, Hsiao-San Chen, Wen-Chin Lin
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Publication number: 20080250575Abstract: Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y , ??(3a) —NH—CO—(CH2)m—SO2—Y , ??(3b) —CONH—(CH2)n—SO2—Y , ??(3c) —NH—CO—CH(Hal)-CH2-Hal or ??(3d) —NH—CO—C(Hal)=CH2 , ??(3e) Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.Type: ApplicationFiled: March 9, 2005Publication date: October 16, 2008Inventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Luc Christnacher
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Publication number: 20080244839Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fibre materials, while at the same time exhibiting good build-up behaviour, and yield dyeings of deep shade having good fastness properties.Type: ApplicationFiled: March 9, 2005Publication date: October 9, 2008Applicant: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen
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Publication number: 20080216256Abstract: The presently disclosed subject matter relates to heterobifunctional reactive dyes comprising nitrogen-containing heterocycles substituted by both halogen and vinyl sulfone moieties. In particular, the presently disclosed subject matter relates to reactive dye compounds comprising two or more halo-substituted, nitrogen-containing heterocycles and an asymmetric bridging group, wherein at least one of the two or more halo-substituted, nitrogen-containing heterocycles further comprises a vinyl sulfone substituent. In some embodiments, the bridging group has a structure based on cysteamine or cysteine. The heterobifunctional reactive dyes have high substrate affinity and can be applied to substrates, such as cotton fibers, under low salt conditions and with reduced dye material waste.Type: ApplicationFiled: August 21, 2007Publication date: September 11, 2008Applicant: North Carolina State UniversityInventors: Harold S. Freeman, C. Brent Smith, Malgorzata Szymczyk, Mengnan Zhao
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Mixture of Water-Soluble Fibre-Reactive Dyes, Method for the Production Thereof, and Use of the Same
Publication number: 20080196178Abstract: Dye mixtures including the dyes of the general formula (I) and dyes of the general formula (II) where R1 to R3, A, W and M are each as defined in claim 1, their preparation and their use for dyeing or printing hydroxyl- and/or carboxamido-containing material, preferably fiber material.Type: ApplicationFiled: June 20, 2006Publication date: August 21, 2008Applicant: DyStar Textilfarben GmbH & Co. Deutschland KG IInventors: Jorg Diekmann, Birgit Eden, Stefan Meier, Ludger Wilbers -
Patent number: 7414129Abstract: The present invention relates to triphendioxazine dye of the general formula I where A1 and A2, B, R1 and M are each as defined in the claims and Y1 is a group of the general formula II or III where X1 to X4 and also R2 and R3 are each as defined in the claims, processes for their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.Type: GrantFiled: December 20, 2005Date of Patent: August 19, 2008Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventor: Stefan Ehrenberg