Alkylene Sulfato, Halotriazine, Halodiazine, Haloquinoxaline, Or Halopyrimidine Dye Patents (Class 8/549)
  • Patent number: 11834781
    Abstract: The disclosure provides a method of continuous dyeing with reactive dyes in wet conditions, the method including: 1) adding fabric to a mixture of a dye liquor and an alkali through a one-bath-one-step method; 2) immersing the fabric pretreated in 1) in a padding liquor with an air film horizontal pad dyeing machine; 3) preheating the fabric after being treated in 2) at a temperature of 50-90° C.; and 4) rolling and batching the fabric after being treated in 3) at a temperature of 10-70° C. for 2-72 hours.
    Type: Grant
    Filed: July 20, 2021
    Date of Patent: December 5, 2023
    Assignees: HUAFANG CO., LTD, DONGHUA UNIVERSITY, BINZHOU HUA TEXTILE ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD.
    Inventors: Zhiping Mao, Hongyu Sun, Chunguang Li, Rongxia Jia, Yi Zhong, Hong Xu, Limin Wang, Qi Yu, Xiaomin Liu, Qingbo Lu, Chunying Sheng, Engang Lu, Qisheng Zhao, Wei Wu, Yamin Dai, Jinbo Wang
  • Patent number: 9540765
    Abstract: A dye mixture, comprising at least one blue dyeing dye of the formula (1), wherein Q1 represents a bivalent radical of formula (4a), (4b) or (4c), wherein X1 denotes chlorine or fluorine, R1 is hydrogen or C1-C8 alkyl, R2 is hydrogen, C1-C8alkyl, C1-C4alkoxy or sulfo, Y1 is vinyl or a radical —CH2—CH2—U and U is a leaving group removable under alkaline conditions, R3 is hydrogen or C1-C8alkyl that is unsubstituted or substituted by hydroxy, sulfo, sulfato, cyano, carboxy, C1-C4alkoxy or phenyl, r and s are each independently of the other the number 0 or 1, and t is the number 0, 1 or 2, and the sum of r, s and t is 2 or 3 and at least one yellow or red dyeing reactive dye is suitable especially for the dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
    Type: Grant
    Filed: February 5, 2014
    Date of Patent: January 10, 2017
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Alexander Mueller, Rainer Hildebrand, Sandra Da Silva Saraiva, Wolfgang Mundle, Markus Kneubuehler
  • Publication number: 20150143639
    Abstract: Reactive dyes of formula (1), wherein Me is chromium, cobalt or iron, R1 is hydrogen or unsubstituted or substituted C1-C4alkyl, E is a bivalent radical of formula (1a), (1b) or (1c) wherein X denotes chlorine or fluorine, T is a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e), or (2f), (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, q is the number 0 or 1, G is a bivalent radical of formula (1d) or (1e) wherein (R2)s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C1-C4alkyl, C2-C4alkanoylamino, C1-C4alkylsulfonyl, carbamoyl, sulfamoyl, sulfo and -E-T, wherein E and T are as defined above, s is the number 0, 1, 2 or 3, A denotes a bivalent radical of formula (3a), (3b) or (3c), wherein R1, R2, X, T, q and s are as def
    Type: Application
    Filed: April 25, 2013
    Publication date: May 28, 2015
    Inventors: Alexander Mueller, Kurt Plattner, Damien Schoehn, Rainer Hildebrand
  • Publication number: 20150096131
    Abstract: Reactive dyes of formula (1) wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, X is halogen, 3- or 4-carboxypyridin-1-yl, or 3- or 4-carbamoylpyridin-1-yl, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, and q is the number 1 or 2, are suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.
    Type: Application
    Filed: May 24, 2013
    Publication date: April 9, 2015
    Inventors: Georg Roentgen, Jean-Christophe Graciet, Rainer Hildebrand, Laszlo Fekete, Marie Schmidlin, Hubert Jean-Luc Christnacher
  • Patent number: 8864850
    Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fiber materials, while at the same time exhibiting good build-up behavior, and yield dyeings of deep shade having good fastness properties.
    Type: Grant
    Filed: January 23, 2013
    Date of Patent: October 21, 2014
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen
  • Publication number: 20140173835
    Abstract: Dye mixtures comprising at least one reactive dye of the formula (1) together with at least one reactive dye of the formula (2), wherein one of the radicals A and B denotes NH2, and the other one of the radicals A and B denotes OH, D is a benzene or naphthalene radical, R1 is hydrogen, hydroxy, sulfo, C1-C4alkyl or C1-C4alkoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R2 is hydrogen, C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino or ureido, R3 is C1-C4alkyl, (R4)0-2 denotes 0 to 2 identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy or sulfo, X1 is halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y1, Y2, Y3, Y4 and Y5 are each independently of the other vinyl or a radical —CH2CH2—U and U is a group removable under alkaline conditions, h, k, l, m and n are each independently of the other the number 0, 1 or 2, and p and q are each independently of the other the number 0 or 1, are suitable for dyeing and printing cellulosic or nitrogen-contai
    Type: Application
    Filed: June 19, 2012
    Publication date: June 26, 2014
    Applicant: HUNTSMAN INTERNATIONAL LLC
    Inventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean-Luc Christnacher, Laszlo Fekete
  • Publication number: 20140157530
    Abstract: An ink composition for ink jet textile printing contains a reactive dye and water-soluble organic solvents including solvent A and at least one solvent B. Solvent A has a solubility of 10 g or more in 100 g of water at 20° C. and has no hydroxy group. Solvent B has a hydroxy group in the molecule thereof and has an IOB value of 2.9 or more and a Z1 value expressed by the following equation (1) of 18 or less. The total content Z2 of solvent A and solvents B in the ink composition is 3.8% by mass or more. Z 1 = ? i = 1 n ? ( 100 * Ii * Xi ) ( 1 ) wherein n represents the total number of solvents B in the ink composition, Ii represents the IOB value of solvent Bi that is any one of the solvents B, and Xi represents the ratio of the mass of solvent Bi to the total mass of the ink composition.
    Type: Application
    Filed: December 10, 2013
    Publication date: June 12, 2014
    Applicant: Seiko Epson Corporation
    Inventor: Masayuki Murai
  • Publication number: 20140026333
    Abstract: Reactive dyes of formula (1), wherein R1 and R2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, one of the radicals D1 and D2 is a radical of the formula (2), the other one of the radicals D1 and D2 is a radical of the formula (3a), or (3b), wherein (R3)n denotes n identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Z1 is a radical of the formula —SO2—Y (4a), —CONH—(CH2)p—SO2—Y (4b), —NH—CO—CH(Hal)-CH2-Hal (4c), —NH—CO—C(Hal)?CH2 (4d), or (4e), wherein X1 is halogen, T1 independently has the definition of X1, is a non-fibre-reactive substituent or is a fibre-reactive radical of the formula (5a), —NH—(CH2)2-3—SO2—Y (5b), or —NH—(CH2)2-3—O—(CH2)2-3—SO2—Y (5c), R4 is hydrogen or unsubstituted or substituted C1-C4alkyl, (R5)0-2 denotes from 0 to 2 identical or different substituents from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Hal is halogen, Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline
    Type: Application
    Filed: March 5, 2012
    Publication date: January 30, 2014
    Inventors: Georg Roentgen, Laszlo Fekete, Michael Nicollet
  • Publication number: 20130283546
    Abstract: Dye mixtures, comprising least one yellow dye of the formula (1), at least one yellow dye of the formula (2), at least one red dye of the formula (3), at least one blue dye of the formula (4), wherein the radicals have the definitions given in the claims, are suitable especially for the trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
    Type: Application
    Filed: June 22, 2011
    Publication date: October 31, 2013
    Applicant: HUNTSMAN INTERNATIONAL LLC
    Inventors: Athanassios Tzikas, Georg Roentgen, Jean-Francois Landre, Remo Codemo
  • Publication number: 20130133142
    Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fibre materials, while at the same time exhibiting good build-up behaviour, and yield dyeings of deep shade having good fastness properties.
    Type: Application
    Filed: January 23, 2013
    Publication date: May 30, 2013
    Applicant: HUNTSMAN INTERNATIONAL LLC
    Inventor: HUNTSMAN INTERNATIONAL LLC
  • Publication number: 20120284934
    Abstract: The present invention provides azo dyes of formula (1) where Hal, M and Y are each as defined in claim 1, processes for their preparation and their use.
    Type: Application
    Filed: March 13, 2012
    Publication date: November 15, 2012
    Applicant: DyStar Clours Deutschland GmbH
    Inventor: Stefan Ehrenberg
  • Publication number: 20120164288
    Abstract: Disclosed herein are solubility changeable dye compositions, methods of preparing such compositions and methods of using them. The composition includes a dye component linked via a linker moiety to a stimulus responsive hydrophobic moiety which modulates the solubility of the dye, wherein the hydrophobic moiety is configured to be de-linked from the dye component on exposure to a stimulus and render the dye component more hydrophilic.
    Type: Application
    Filed: December 22, 2010
    Publication date: June 28, 2012
    Inventor: Seth Adrian Miller
  • Patent number: 8080101
    Abstract: The present invention relates to dye mixtures which comprise at least one dye of the formula (I), at least one dye of the formula (II) and optionally at least one dye of the formula (III) and/or optionally at least one dye of the formula (IV) in which D1 to D7, R201 to R203, R0, R* and R**, T, M, v and f are as defined in claim 1, to dyes of the formula (II), to processes for their preparation, and to their use for dyeing and printing hydroxyl- and carboxamido-containing materials.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: December 20, 2011
    Assignee: DyStar Colours Deutschland GmbH
    Inventors: Joachim Eichhorn, Stefan Meier, Werner Hubert Russ
  • Patent number: 8066809
    Abstract: Reactive dyes of formula wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1-C4alkyl, D is a radical of a diazo component of the formula X1 and X2 independently of one another are halogen, T is a fiber-reactive radical of the formula (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fiber materials.
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: November 29, 2011
    Assignee: Huntsman International LLC
    Inventors: Georg Roentgen, Laszlo Fekete
  • Publication number: 20110283465
    Abstract: The present invention relates to dyes of the formula (I), in which R1 to R4, D1, f, and M are defined as indicated in claim 1, to processes for preparing them, and to their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.
    Type: Application
    Filed: January 18, 2010
    Publication date: November 24, 2011
    Applicant: DYSTAR COLOURS DEUTSCHLAND GMBH
    Inventors: Joachim Eichhorn, Andreas Schrell
  • Publication number: 20110173763
    Abstract: The invention provides a process for aminoarylating cellulosic materials such as cotton and reconstituted fibres and a process for treating the aminoarylated cellulose with an effect chemical such as a dye, flame retardant or cross linking agent. Improved take up of the effect chemical by the modified cellulose means increased efficiency in the process and in the case of dyeing, avoids or reduces the washing off of hydrolysed dye and the resultant production of large volumes of contaminated water requiring to be treated. The cellulosic material may be present in a blend with other types of fibre for example a blend with poly(alkyleneterephthalates) or polyamides.
    Type: Application
    Filed: January 26, 2009
    Publication date: July 21, 2011
    Inventors: Colin Robert Willis, Stuart Anson Brewer, John Anthony Taylor, Duncan Adrian Phillips
  • Patent number: 7967903
    Abstract: The present invention relates to a novel ink composition and, more particularly, to an ink composition for digital textile printing, which is suitable for ink-jet printing on cellulose fiber materials. The novel ink composition of the present invention has stable pH value, fine storage stability, smoothness and ease in printing, and reduction in color deterioration.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: June 28, 2011
    Assignee: Everlight USA, Inc.
    Inventors: Chuan-Hsi Lee, Hsiao-San Chen
  • Patent number: 7905928
    Abstract: Reactive dyes of the formula (1) in which Q1, X, V1, V2, B, T and R1, R2, R4 and R5 are defined in the claims and in the disclosure and wherein the reactive dyes are suitable for dyeing widely varying fiber materials, in particular cellulosic fiber materials and produce dyeings with good allround properties.
    Type: Grant
    Filed: October 7, 2008
    Date of Patent: March 15, 2011
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Thomas Verdugo, Georg Roentgen
  • Patent number: 7887602
    Abstract: Reactive dyes of formula wherein the variables are defined herein.
    Type: Grant
    Filed: August 2, 2006
    Date of Patent: February 15, 2011
    Assignee: Huntsman International, LLC
    Inventors: Hubert Jean Luc Christnacher, Athanassios Tzikas, Georg Roentgen
  • Patent number: 7745385
    Abstract: The present invention relates to a water-soluble pouch comprising a laundry detergent composition comprising reactive dye.
    Type: Grant
    Filed: March 30, 2009
    Date of Patent: June 29, 2010
    Assignee: The Procter & Gamble Company
    Inventor: Alan Thomas Brooker
  • Publication number: 20100159140
    Abstract: Reactive dyes of formula wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1-C4alkyl, D is a radical of a diazo component of the formula X1 and X2 independently of one another are halogen, T is a fibre-reactive radical of the formula (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    Type: Application
    Filed: July 31, 2007
    Publication date: June 24, 2010
    Applicant: HUNTSMAN INTERNATIONAL LLC
    Inventors: Georg Roentgen, Laszlo Fekete
  • Publication number: 20100154145
    Abstract: Reactive dyes of formula wherein B is an aliphatic bridging member, R1 is C1-C4alkyl, halogen or an —SO2—Z radical, R2 and R3 are each independently of the other C1-C4alkoxy, R4, R5 and R6 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, p is the number 0, 1 or 2, X1 and X2 are each independently of the other halogen, and T is halogen, a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R7)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group and Hal is halogen, or T is a radical of formula wherein R1, R2, R3, R4, k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness prop
    Type: Application
    Filed: August 2, 2006
    Publication date: June 24, 2010
    Applicant: HUNTSMAN INTERNATIONAL LLC
    Inventors: Hubert Jean Luc Christnacher, Athanassios Tzikas, Georg Roentgen
  • Publication number: 20100151134
    Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fibre materials, while at the same time exhibiting good build-up behaviour, and yield dyeings of deep shade having good fastness properties.
    Type: Application
    Filed: February 24, 2010
    Publication date: June 17, 2010
    Applicant: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen
  • Patent number: 7708786
    Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2—Z or —Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: May 4, 2010
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
  • Publication number: 20100024138
    Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye of formula wherein the radicals indicated in the formulae are defined in accordance with the claims, are suitable for dyeing or printing cellulosic fibre materials with good build-up behaviour and yield dyeings of a deep shade having good fastness properties.
    Type: Application
    Filed: September 25, 2009
    Publication date: February 4, 2010
    Applicant: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen
  • Patent number: 7641724
    Abstract: Dye mixtures comprising at least one dye of formula (I) together with at least one dye of formula (II) wherein the radicals are as defined in the claim, are suitable for dyeing or printing cellulosic fiber materials, while having a good build-up behavior, and yield dyeings of a deep shade having good fastness properties.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: January 5, 2010
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen
  • Patent number: 7632316
    Abstract: The present invention relates to dyes of the general formula (1) where M and X are each as defined in claim 1, dye mixtures comprising one or more of the dyes of the general formula (1) and also one or more further fiber-reactive dyes, processes for their preparation, their use and printing inks comprising same.
    Type: Grant
    Filed: May 24, 2006
    Date of Patent: December 15, 2009
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Meier, Uwe Reiher, Werner Hubert Russ, Günther Schwaiger
  • Patent number: 7604669
    Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fiber-reactive substituent or a fiber-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substituents fr
    Type: Grant
    Filed: November 6, 2006
    Date of Patent: October 20, 2009
    Assignee: Huntsman International LLC
    Inventors: Jean-Marie Sire, Athanassios Tzikas, Georg Roentgen
  • Patent number: 7597722
    Abstract: Process for manufacturing a fabric having distinctive and sharp differentially colored patterns or designs, which process comprises the steps of: (a) producing a first and a second polyamide, said polyamides having different concentrations of amine groups; (b) producing a first and a second polyamides having different concentrations of carboxyl end-groups and sulfonate groups; (c) producing a first yarn from said first polyamide and a second yarn from said second polyamide; (d) making a fabric having first surface areas defined by said first yarn and second surface areas defined by said second yarn; and (e) chemically dyeing said fabric in a dyeing bath comprising at least one anionic (acid) dyestuff and at least one cationic (basic) dyestuff, whereby said first yarn and therefore said first surface areas are dyed predominantly by said anionic dyestuff and said second yarn and therefore said second surface areas are dyed predominantly by said cationic dyestuff.
    Type: Grant
    Filed: February 19, 2004
    Date of Patent: October 6, 2009
    Assignee: Nilet Ltd.
    Inventors: Michael Eroshov, Alon Weiser, Thierry Mamodaly, Ran Rotem, Boris Streltses, Ariel Yedvab, Juliana Katz, Alexander Yermolaev, Samuel Gazit
  • Publication number: 20090178213
    Abstract: Dye mixtures that comprise at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable, with good build-up behaviour, for dyeing or printing cellulose-containing fibre materials, and yield dyeings having a deep shade and good fastness properties.
    Type: Application
    Filed: June 28, 2006
    Publication date: July 16, 2009
    Applicant: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Luc Christnacher, Bruno Cortese
  • Patent number: 7553339
    Abstract: A method of dyeing or printing textile fiber materials, which comprises bringing the fiber material into contact with (a) at least one reactive dye containing at least one anionic group, (b) at least one compound which reduces the ionic character of the anionic group, and (c) at least one nucleophilic compound, yields dyeings or prints having deep hues and very good fastness properties.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: June 30, 2009
    Assignee: Huntsman International LLC
    Inventors: Jürgen Schmiedl, Wolfgang Mundle
  • Patent number: 7524953
    Abstract: The invention relates to novel triphendioxazine pigments of formula (I) wherein X represents hydrogen or chlorine, while R1 represents phenyl substituted by one to five radicals from the group comprising C1-C4-alkyl, halogen, C1-C4-alkoxy, acetylamino, aminocarbonyl, methylaminocarbonyl and C1-C4-alkoxycarbonyl, or phenyl annelated in the 2,3- or 3,4- with a divalent radical of the formula —NH—(CO)m—NR2—, —CR2?CH—CO—NH—, —CR2?N—CO—NH—, —CO—NH—CO—NR2—, —CO—(NH)m—CO— or —O—(CO)m—NH— so as to form a five- or six-membered ring, R2 representing hydrogen, methyl, ethyl or phenyl and m representing 1 or 2.
    Type: Grant
    Filed: January 12, 2005
    Date of Patent: April 28, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: David Blum, Carsten Plueg, Tanja Reipen
  • Patent number: 7524368
    Abstract: The present invention relates to a black dye composition, comprising: (a) at least one azo dye of the following formula (I), (b) at least one azo dye of the following formula (II) or (III), wherein R1, R2, and R3 are defined the same as the specification. The present invention also relates to a black ink composition afforded from the aforementioned black dye composition. The black ink composition of the present invention for textile digital printing exhibits the properties of excellent color depth, fixation, stability of storage, stability and accuracy of printing for long time, and improves the issue of nozzle cloggage.
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: April 28, 2009
    Assignee: Everlight USA, Inc.
    Inventors: Chuan-Hsi Lee, Tzu-Kwei Sun, Reng-Fang Lin, Hsiao-San Chen
  • Patent number: 7497971
    Abstract: The present invention relates to a mixture of fluorescent whitening agents comprising 11 to 20% by weight of a compound of formula (1), and 80 to 89% by weight of a compound of formula (2), wherein R1 denotes hydrogen, C1-C6alkyl, C5-C14aryl or C6-C24aralkyl and X is a bivalent radical of formula (3), (4) or (5) compositions containing the mixture and the use of the compositions for whitening synthetic fibers, in particular, polyester.
    Type: Grant
    Filed: December 1, 2003
    Date of Patent: March 3, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jean-Jacques Donzé, Marie Meyberger, Michael Milde, Volker Papendick, Josef Zelger
  • Publication number: 20090041938
    Abstract: The present invention concerns a dye mixture comprising at least one dye of the general formula (I) and at least one further dye either of the general formula (II) or of the general formula (III) or of the general formula (IV) where the variables are each as defined in claim 1, processes for their preparation and their use.
    Type: Application
    Filed: January 19, 2007
    Publication date: February 12, 2009
    Applicant: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Andreas Giehl
  • Publication number: 20090025152
    Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Application
    Filed: June 27, 2008
    Publication date: January 29, 2009
    Applicant: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
  • Publication number: 20080295732
    Abstract: The present invention relates to dye mixtures which comprise at least one dye of the formula (I), at least one dye of the formula (II) and optionally at least one dye of the formula (III) and/or optionally at least one dye of the formula (IV) in which D1 to D7, R201 to R203, R0, R* and R**, T, M, v and f are as defined in claim 1, to dyes of the formula (II), to processes for their preparation, and to their use for dyeing and printing hydroxyl- and carboxamido-containing materials.
    Type: Application
    Filed: September 29, 2006
    Publication date: December 4, 2008
    Applicant: DyStar Textilfarben GmbH &Co. Deutschland KG
    Inventors: Joachim Eichhorn, Stefan Meier, Werner Hubert Russ
  • Publication number: 20080282484
    Abstract: The present invention discloses a reactive yellow dye composition comprising component (A) and component (B). The component (A) is a reactive azo dye represented by the following formula (I) or formula (II), The component (B) is a reactive azo dye represented by the following formula (III), wherein the substituents of the formulas (I), (II) and (III) are defined the same as in the specification. Moreover, the reactive yellow dye composition of the present invention has excellent build-up, wash-off and light fastness and can be applied with dyestuffs in other colors.
    Type: Application
    Filed: August 2, 2007
    Publication date: November 20, 2008
    Applicant: Everlight USA, Inc.
    Inventors: Bao-Kun Lai, Cheng-Hsiang Hsu, Ya-Chi Tseng, Huei-Chin Huang
  • Publication number: 20080274287
    Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (I) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Application
    Filed: May 27, 2008
    Publication date: November 6, 2008
    Applicant: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Meier, Werner Russ, Joachim Eichhorn
  • Patent number: 7442780
    Abstract: New, highly multifunctional reactive dye compounds are provided. The number of leaving groups in the non-chromophoric part of the molecule added to the number of chromophore moieties is at least equal to 5, preferably in the range of from 5 to 12, more preferably from 5 to 6. The new reactive dye compounds preferably have at least two asymmetric bridges.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: October 28, 2008
    Assignee: North Carolina State University
    Inventors: Wei Dong He, Peter Jeffrey Broadbent, David Malcolm Lewis
  • Publication number: 20080256726
    Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substi
    Type: Application
    Filed: November 6, 2006
    Publication date: October 23, 2008
    Inventors: Jean-Marie Sire, Athanassios Tzikas, Georg Roentgen
  • Publication number: 20080257208
    Abstract: Mixtures of reactive dyestuffs comprising one dyestuff of the formula (II-a) and at least one of the dyestuffs formula (II-b) to (II-d) wherein M is H, an alkali metal, an ammonium ion or the equivalent of an alkaline earth metal and is preferably H, sodium or potassium; A is diisopropanolamine B is an amine of one of the general formulae B-1 to B-8 wherein R3 is Hydrogen, Methyl, Ethyl, n-Propyl, i-Propyl, Hydroxyethyl, Hydroxypropyl, -Cyanethyl, -Hydroxycerbonylethyl, processes for their preparation and their use for dyeing and printing hydroxy- and/or carboxamidocontaining fiber materials.
    Type: Application
    Filed: May 11, 2005
    Publication date: October 23, 2008
    Inventors: Warren J. Ebenezer, Werner Hubert Russ
  • Patent number: 7438753
    Abstract: The present invention relates to a diazo dyestuff compound of the following formula (I) wherein, M is H, Na, or Li. The formula (I) compound is particularly suitable for using as a component in a black dye composition for ink-jet printing ink, and inkjet printing inks with good light-fastness are obtained.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: October 21, 2008
    Assignee: Everlight USA, Inc.
    Inventors: Jen-Fang Lin, Tzu-Kwei Sun, Hsiao-San Chen, Wen-Chin Lin
  • Publication number: 20080250575
    Abstract: Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y , ??(3a) —NH—CO—(CH2)m—SO2—Y , ??(3b) —CONH—(CH2)n—SO2—Y , ??(3c) —NH—CO—CH(Hal)-CH2-Hal or ??(3d) —NH—CO—C(Hal)=CH2 , ??(3e) Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    Type: Application
    Filed: March 9, 2005
    Publication date: October 16, 2008
    Inventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Luc Christnacher
  • Publication number: 20080244839
    Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fibre materials, while at the same time exhibiting good build-up behaviour, and yield dyeings of deep shade having good fastness properties.
    Type: Application
    Filed: March 9, 2005
    Publication date: October 9, 2008
    Applicant: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen
  • Publication number: 20080216256
    Abstract: The presently disclosed subject matter relates to heterobifunctional reactive dyes comprising nitrogen-containing heterocycles substituted by both halogen and vinyl sulfone moieties. In particular, the presently disclosed subject matter relates to reactive dye compounds comprising two or more halo-substituted, nitrogen-containing heterocycles and an asymmetric bridging group, wherein at least one of the two or more halo-substituted, nitrogen-containing heterocycles further comprises a vinyl sulfone substituent. In some embodiments, the bridging group has a structure based on cysteamine or cysteine. The heterobifunctional reactive dyes have high substrate affinity and can be applied to substrates, such as cotton fibers, under low salt conditions and with reduced dye material waste.
    Type: Application
    Filed: August 21, 2007
    Publication date: September 11, 2008
    Applicant: North Carolina State University
    Inventors: Harold S. Freeman, C. Brent Smith, Malgorzata Szymczyk, Mengnan Zhao
  • Publication number: 20080196178
    Abstract: Dye mixtures including the dyes of the general formula (I) and dyes of the general formula (II) where R1 to R3, A, W and M are each as defined in claim 1, their preparation and their use for dyeing or printing hydroxyl- and/or carboxamido-containing material, preferably fiber material.
    Type: Application
    Filed: June 20, 2006
    Publication date: August 21, 2008
    Applicant: DyStar Textilfarben GmbH & Co. Deutschland KG I
    Inventors: Jorg Diekmann, Birgit Eden, Stefan Meier, Ludger Wilbers
  • Patent number: 7414129
    Abstract: The present invention relates to triphendioxazine dye of the general formula I where A1 and A2, B, R1 and M are each as defined in the claims and Y1 is a group of the general formula II or III where X1 to X4 and also R2 and R3 are each as defined in the claims, processes for their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: August 19, 2008
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Stefan Ehrenberg
  • Publication number: 20080189880
    Abstract: The present invention relates to dyes of the general formula (1) where M and X are each as defined in claim 1, dye mixtures comprising one or more of the dyes of the general formula (1) and also one or more further fiber-reactive dyes, processes for their preparation, their use and printing inks comprising same.
    Type: Application
    Filed: May 24, 2006
    Publication date: August 14, 2008
    Applicant: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Meier, Uwe Reiher, Werner Hubert Russ, Gunther Schwaiger
  • Patent number: 7396370
    Abstract: A method of dyeing or printing synthetic polyamide fiber materials, wherein (a) the fiber material is dyed or printed with at least one reactive dye, and (b) the dyed or printed fiber material is subjected to after-treatment with a reducing agent, the fiber material not being treated with polycondensable or polymerizable compounds for fixing the dye on the fiber, results in dyeings and printings that are distinguished by good fastness properties.
    Type: Grant
    Filed: June 3, 2003
    Date of Patent: July 8, 2008
    Assignee: Huntsman International LLC
    Inventors: Franz Grüner, Jürgen Schmiedl, Ulrich Fembacher, Ulrich Strahm