Cyanamide- Or Dicyandiamide-formaldehyde Polymer Patents (Class 8/556)
  • Patent number: 8119778
    Abstract: A reversible thermochromic system comprising a) a compound of the formula (I) or a tautomer thereof (I) wherein R1 is C1-C18alkyl, C2-C18alkenyl, C3-C12cycloalkyl, C3-C12cycloalkyl substituted by 1, 2 or 3 C1-C4alkyl; or C7-C12phenylalkyl; R2 and R3 are hydrogen or R2 and R3 together form a group —CH?CH—CH?CH—; and R4 is hydrogen, —NO2, —SO2—R1 or (4-nitrophenyl)azo; and b) a compound containing a group of the formula (II).
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: February 21, 2012
    Assignee: BASF SE
    Inventors: Walter Fischer, Abdel-Ilah Basbas, Martin Brunner, Rolf Benz, Manuele Vitali
  • Patent number: 6830593
    Abstract: There is provided a method for preventing or reducing the fading of color on fabric by means of a divalent salt. Compositions which provide care to the color of fabrics and comprising a dye fixing agent and the divalent salt are also herein provided.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: December 14, 2004
    Assignee: The Procter & Gamble Company
    Inventor: Christian Leo Marie Vermote
  • Patent number: 6596035
    Abstract: A single composition for simultaneous coloring and highlighting hair to provide hair fibers having variations in tonality and hue, comprising, 1-10% inorganic persulfate, 1-20% hydrogen peroxide, 0.001-20% of at least one primary intermediate and, optionally, at least one coupler for the formation of oxidation dyes; and 0.01-20% of one or more surfactants; as well as a one step method for simultaneously color and highlighting hair to provide hair fibers having variations in tonality and hue comprising, combining, immediately prior to use, a powder composition comprised of at least one alkali metal or alkaline earth metal persulfate, an aqueous developer composition comprised of hydrogen peroxide; and an aqueous based colorant composition comprised of at least one primary intermediate and, optionally, at least one coupler for the formation of oxidation dyes; and applying the mixture to the hair for a period of time sufficient to cause coloration and highlighting of the hair.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: July 22, 2003
    Assignee: Revlon Consumer Products Corporation
    Inventors: Glen Alan Gutkowski, Alexander Chan, Shailendra Kumar Singh
  • Patent number: 6307007
    Abstract: New water-soluble polycondensation products are obtained by reaction of polyfunctional amines with cyanamide, its derivatives or polymers in the presence of sulfamic acid. They are excellent fixing agents which improve fastness properties of dyeings with substantive dyestuffs on cellulose fiber materials, paper, board and non-wovens.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: October 23, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Jürg Heller, Alec Tindal
  • Patent number: 6200354
    Abstract: A method of dyeing cellulosic fibers or fabrics using pre-metallized acid dye by pretreating the fabric with a cationic agent having a plurality of cationic centers and optionally after treating the dyed material with a cationic polymer is disclosed. The cationic polymer is desirably a polyquaternary amine material especially a poly(DADMAC) or polyvinylpyridine. Material dyed by the method has a “washed out” appearance similar to fabrics dyed using the “Jarofast” process, but the availability of a wide range of pre-metallized dyes gives a wider color range, and the method enables a wider range of substrates to be dyed successfully, including lyocell fiber materials e.g. those sold under Courtauld's trademark “Tencel” and blend/union materials with polyamides, easier processing and superior wash and light fastness.
    Type: Grant
    Filed: August 23, 1999
    Date of Patent: March 13, 2001
    Assignee: Imperial Chemical Industries PLC
    Inventors: Geoffrey William Collins, Stephen Martin Burkinshaw, Roy Gordon
  • Patent number: 5221288
    Abstract: A dyeing method comprising a process of treating a cellulose fiber textile product with cationic compound and another process of treating the thus-treated textile product by immersing it in a dispersion containing thermochromic material and/or photochromic material.
    Type: Grant
    Filed: March 15, 1991
    Date of Patent: June 22, 1993
    Assignee: Matsui Shikiso Chemical Co., Ltd.
    Inventors: Kazumasa Kamada, Osamu Sasaki, Shouzou Suefuku, Tatsuya Maeda
  • Patent number: 4913705
    Abstract: A mixed fabric of hydroxy group-containing fibers and cyano and/or carboxy group-containing fibers, the hydroxy group-containing fibers having been dyed with a reactive dye, is aftertreated with a product of reacting a mono- or polyfunctional amine having one or more primary, secondary and/or tertiary amino groups with cyanamide, dicyandiamide guanidine or bis-guanidine, said product containing at least one reactive hydrogen atom linked to a nitrogen atom, and is then dyed with a basic dye.
    Type: Grant
    Filed: September 2, 1988
    Date of Patent: April 3, 1990
    Assignee: Sandoz Ltd.
    Inventors: Bernhard Schlick, Claudio Artico
  • Patent number: 4880434
    Abstract: Dyed and finished products of cellulose fiber materials superior in fastness properties are obtained without change in color shade by finishing dyed products with a fixing agent or/and a finishing agent capable of bonding with cellulose through a bridge formation, the dyed products being obtained by dyeing cellulose fiber materials with a dye represented by the following formula in the free acid form, ##STR1## wherein A is phenylene or naphthylene, B is alkyl, alkenyl, phenyl, naphthyl or heterocyclic group, Me is metal ion, X is --O-- or ##STR2## Y is alkoxy, phenoxy or amino, Z is sulfo or the like water-solubility-imparting group, m and n are each 0 or an integer of 1 to 3, provided that the sum is 1 to 3, D is phenylene or naphthylene, Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 L in which L is splittable group by the action of an alkali and R is hydrogen or alkyl.
    Type: Grant
    Filed: July 12, 1988
    Date of Patent: November 14, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Naoki Harada, Tetsuya Miyamoto, Kunihiko Imada, Takashi Omura
  • Patent number: 4764585
    Abstract: Cationic fixing agents based on the reaction products of(a) a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups and(b) cyanamide, dicyandiamide, guanidine or bisguanidinegive improved results when the reaction takes place in the presence of a catalyst (K) selected from metals, metal salts and heterocyclic nitrogen-containing organic bases, particularly zinc chloride.
    Type: Grant
    Filed: September 15, 1987
    Date of Patent: August 16, 1988
    Assignee: Sandoz Ltd.
    Inventors: Jurg Heller, Bruno Kissling, Curt Muller, Tibor Robinson, Salvatore Valenti
  • Patent number: 4718918
    Abstract: Polymeric compounds (A) obtained by the reaction of epihalo-hydrin with a polyalkylene polyamine are useful as textile treatment agents. As pretreatment agents they improve the color yield of the subsequent dyeing, as aftertreatment agents they improve fastness properties. Certain of the products (A) are novel.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: January 12, 1988
    Assignee: Sandoz Ltd.
    Inventors: Jurg Heller, Bruno Kissling, Tibor Robinson, Salvatore Valenti
  • Patent number: 4604101
    Abstract: Dyeings on hydroxy group- or nitrogen-containing fibres are improved by aftertreatment, simultaneously or sequentially, with (A) a polymeric reaction product of an amine with cyanamide, dicyandiamide, quanidine or bisguanidine and (B) a quaternary polyalkylene polyamine. A synergistic effect between (A) and (B) is observed.
    Type: Grant
    Filed: February 21, 1985
    Date of Patent: August 5, 1986
    Assignee: Sandoz Ltd.
    Inventors: Bruno Kissling, Tibor Robinson
  • Patent number: 4559058
    Abstract: A precondensate obtained by reacting(A) the product of reacting a mono- or polyfunctional primary or secondary amine with cyanamide, dicyandiamide, guanidine or biguanidine and(B) an epihalohydrin is obtained in the form of a stable aqueous dispersion by acidifying the reaction product, optionally in the presence of a water-soluble polymer. The product is useful as an after-treatment agent to improve the fastness of dyeings on cotton, wool or silk.
    Type: Grant
    Filed: June 28, 1984
    Date of Patent: December 17, 1985
    Assignee: Sandoz Ltd.
    Inventors: Brian Bennett, Donald K. Clough
  • Patent number: 4511707
    Abstract: The wet fastness properties of direct or reactive dyeings on cellulosic substrates are improved by aftertreatment with a precondensate of(A) the product of reacting a mono- or polyfunctional primary or secondary amine with cyanamide, dicyandiamide (DCDA), guanidine or biguanidine; or ammonia with cyanamide or DCDA; whereby up to 50 mole % of the cyanamide, DCDA, guanidine or biguanide may be replaced with a dicarboxylic acid or a mono- or di-ester thereof, said product (A) containing reactive hydrogen atoms bound to nitrogen, and either(B) an epihalohydrin or a precursor thereof, or(C) formaldehyde or a formaldehyde precursor, or(D) a dihydroxyalkyleneurea or a methyl ether thereof,followed by formaldehyde or a formaldehyde precursor optionally together with(E) an N-methylol derivative of a urea, melamine, guanamine, triazinone, urone, carbamate or acid amideand, if (A) is used with (C) or (D), or if (E) is present, together with(F) a catalyst for the cross-linking of N-methylol compounds of the type (E) abov
    Type: Grant
    Filed: January 25, 1984
    Date of Patent: April 16, 1985
    Assignee: Sandoz Ltd.
    Inventors: James R. Runyon, Salvatore Valenti
  • Patent number: 4475918
    Abstract: Aftertreatment of dyeings on cotton or nylon with (A) a polybasic compound which is the product of reacting a primary or secondary amine with cyanamide, dicyandiamide, guanidine or biguanidine and, sequentially or simultaneously (B) a precondensate formed by reacting a compound of type (A) with an N-methylol derivative gives wet fastness properties superior to those given by either (A) or (B) used alone.
    Type: Grant
    Filed: August 24, 1983
    Date of Patent: October 9, 1984
    Assignee: Sandoz Ltd.
    Inventors: Bruno Kissling, Tibor Robinson
  • Patent number: 4443223
    Abstract: The fastness of direct dyes on cellulose substrates is improved by after-treatment with the reaction product of a quaternary polyalkylene polyamine with an N-methylol resin precursor, and heat curing in the presence of a catalyst. The unfixed portion of reactive dyes substantive to cellulose may also be given improved wet and light fastness by this treatment.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: April 17, 1984
    Assignee: Sandoz Ltd.
    Inventors: Bruno Kissling, Walter Knobel, Tibor Robinson
  • Patent number: 4439208
    Abstract: The fastness properties of basic dyeings on cellulosic substrates are improved by treating the substrate with a fixing agent comprising a precondensate or mixture of(A) the reaction product of an amine with cyanamide, dicyandiamide, guanidine or biguanidine, or,(B) a quaternary polyalkylene polyamine with(C) formaldehyde and/or,(D) an N-methylol compound optionally together with(E) a catalyst, e.g. MgCl.sub.2.The fixing agents are normally applied as an aftertreatment, with a subsequent heat-curing step.
    Type: Grant
    Filed: June 22, 1982
    Date of Patent: March 27, 1984
    Assignee: Sandoz Ltd.
    Inventors: Helmut Moser, Tibor Robinson
  • Patent number: 4439203
    Abstract: The wet fastness properties of direct or reactive dyeings on cellulosic substrates are improved by aftertreatment with a precondensate of(A) the product of reacting a mono- or polyfunctional primary or secondary amine with cyanamide, dicyandiamide (DCDA), guanidine or biguanidine; or ammonia with cyanamide or DCDA; whereby up to 50 mole % of the cyanamide, DCDA, guanidine or biguanidine may be replaced with a dicarboxylic acid or a mono- or di-ester thereof, said product (A) containing reactive hydrogen atoms bound to nitrogen,and either (B) an epihalohydrin or a precursor thereofor (C) formaldehyde or a formaldehyde precursoror (D) a dihydroxyalkyleneurea or a methyl ether thereof, followed by formaldehyde or a formaldehyde precursoroptionally together with (E) an N-methylol derivative of a urea, melamine, guanamine, triazinone, urone, carbamate or acid amideand, if (A) is used with (C) or (D), or if (E) is present, together with (F) a catalyst for the cross-linking of N-methylol compounds of the type (E) ab
    Type: Grant
    Filed: May 10, 1982
    Date of Patent: March 27, 1984
    Assignee: Sandoz Ltd.
    Inventors: James R. Runyon, Salvatore Valenti
  • Patent number: 4436521
    Abstract: The invention relates to a process for the production of anti-shrink treated wool dyeings in which wool is dyed with acid milling or metal complex dyes either before, after or between the steps of an anti-shrink treatment and, after the dyeing or the anti-shrink treatment or one of the steps of the anti-shrink treatment subsequent to the dyeing, is after-treated with a liquor containing a cationic fixing agent and a levelling/retarding agent having affinity for wool dyestuffs, and to a composition usable for such a process.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: March 13, 1984
    Assignee: Sandoz Ltd.
    Inventors: Oskar Annen, Hermann Egli, Karl Zesiger
  • Patent number: 4417898
    Abstract: The invention relates to a process for continuous dyeing a cellulosic fibrous substrate with a direct or reactive dye comprising the steps of(a) applying to the substrate an aqueous dyeing liquor containing an alkanolamine, followed by(b) fixing the dyeings, and finally(c) after-treating the dyed substrate with a fixing agent,the resulting dyeings having improved wet fastnesses.
    Type: Grant
    Filed: September 8, 1982
    Date of Patent: November 29, 1983
    Inventors: Rolf Hasler, Francis Palacin