Six-membered Hetero Ring Having Two Or More Ring Hetero Atoms Of Which At Least One Is Nitrogen Patents (Class 8/565)
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Patent number: 7393367Abstract: An agent for dyeing keratin-containing fibers, especially human hair, is comprised of a cosmetic carrier, and (A) at least one compound of Formula I, wherein each of R1, R2 and R3 is independently a hydrogen atom, a halogen atom, a C1-C6 alkyl group, a C2-C6 alkenyl group, a hydroxyl group, a C1-C6 alkoxy group, a C1-C6 hydroxyalkyl group, a C2-C6 polyhydroxyalkyl group, a hydroxy C1-C6 alkyloxy group, a sulfonyl group, a carboxyl group, a C1-C6 alkoxycarbonyl group, a hydroxy C2-C6 alkyloxycarbonyl group, a sulfonic acid group, a sulfonamido group, a sulfonamide group, a C2-C6 acyl group, a formyl group, a nitro group, a carbamoyl group —C(O)—NR4R5, or a —(CH2)nNR6R7 group wherein each of R4, R5, R6 and R7 is independently a hydrogen atom, a C1-C6 alkyl group or a C2-C6 hydroxyalkyl group; and n is number from 0 to 6, wherein R1 and R2 can form a 5- or 6-membered aromatic or heteroaromatic ring; and (B) at least one CH-acidic compound.Type: GrantFiled: November 8, 2007Date of Patent: July 1, 2008Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Wibke Gross, Horst Hoffkes, Doris Oberkobusch, Helmut Muller, Carsten Brake
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Patent number: 7326259Abstract: A subject-matter of the present patent application is the use, as direct dye in dyeing compositions for keratinous fibres, in particular human keratinous fibres, such as the hair, or for the manufacture of such compositions, of a specific polycationic compound.Type: GrantFiled: June 22, 2005Date of Patent: February 5, 2008Assignee: L'Oreal S.A.Inventor: Alain Lagrange
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Patent number: 7311736Abstract: The invention concerns the use as direct dyeing agent of at least one tetra-azapentamethine compound, a dyeing composition comprising at least such a compound, as well as a method for dyeing keratinous fibers, in particular human keratinous fibers and more particularly hair, which consists in applying at least one composition comprising such a compound. The composition also concerns tetra-azapentamethine compounds of formula (I). The invention further concerns a method for bleaching such compounds, as well as bleaching keratinous fibers previously dyed therewith.Type: GrantFiled: July 4, 2003Date of Patent: December 25, 2007Assignee: L'OrealInventors: Herve Burgaud, Herve David, Rui Pereira, Beatrice Belcour-Castro
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Patent number: 7303591Abstract: A dye composition comprising at least one mixed dye comprising at least two chromophore chosen from azine and (hetero)aromatic nitro compounds, optionally associated with at least one chromophore chosen from methine and carbonyl compounds; a process for dyeing keratin fibers, for example, human keratin fibers, such as the hair, using the composition, a multi-compartment device comprising the composition; and the abovementioned mixed dyes.Type: GrantFiled: February 28, 2005Date of Patent: December 4, 2007Assignee: L'Oreal S.A.Inventors: Andrew Greaves, Hervé David, Henri Samain
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Patent number: 7300471Abstract: Disclosed herein are a dye composition comprising at least one mixed dye comprising at least one chromophore chosen from chromophores of the azo family and the tri(hetero)arylmethane family; and the mixed dyes. Further disclosed herein are a process for dyeing keratin fibers, such as human keratin fibers, using the composition, and a device comprising the composition.Type: GrantFiled: February 28, 2005Date of Patent: November 27, 2007Assignee: L'Oreal S.A.Inventors: Andrew Greaves, Hervé David, Henri Samain
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Patent number: 7294152Abstract: The present disclosure relates to a specific direct dye compound that is a fluorindine derivative, and dyeing compositions comprising at least one derivative of the compound and at least one polymer. A process for dyeing keratin fibers with the defined compositions is also disclosed.Type: GrantFiled: January 7, 2005Date of Patent: November 13, 2007Assignee: L'Oreal S.A.Inventor: Alain Lagrange
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Patent number: 7288120Abstract: The present disclosure relates to processes for synthesizing tetraazapentamethine compounds that comprise reacting at least one compound of azine type with at least one oxidizing agent. The disclosure also relates to processes for dyeing keratin fibers, for example human keratin fibers, that comprise using such synthetic processes.Type: GrantFiled: December 13, 2004Date of Patent: October 30, 2007Assignee: L'Oreal S.A.Inventors: Rui Pereira, Hervé Burgaud
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Patent number: 7288121Abstract: The present invention relates to a dye composition including at least one mixed dye containing at least one chromophore of methine or carbonyl type or their combinations. The invention furthermore relates to a process for dyeing keratin fibers, especially human keratin fibers, such as the hair, using the composition, and also to a suitable kit. The invention also relates to the abovementioned mixed dyes per se.Type: GrantFiled: February 28, 2005Date of Patent: October 30, 2007Assignee: L'Oreal S.A.Inventors: Andrew Greaves, Hervé David, Henri Samain
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Patent number: 7282068Abstract: The present disclosure relates to compounds used as direct dyes, and dyeing compositions comprising such compounds. The disclosed compounds have the formula A-L-B, wherein A and B are chosen from arylazoimidazolium coloring functional groups, and L is a linker comprising at least one cationic group C. The disclosure also relates methods of using such compositions for coloring keratin fibers, such as the hair.Type: GrantFiled: May 31, 2005Date of Patent: October 16, 2007Assignee: L'Oreal S.A.Inventors: Alain Lagrange, Hervé David, Andrew Greaves
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Patent number: 7261743Abstract: The present disclosure relates to the process of dyeing human keratinous fibers, such as the hair, with at least one specific direct dye in cosmetic compositions. Also disclosed herein are the direct dyeing and lightening compositions comprising said compounds, and the corresponding dyeing kits.Type: GrantFiled: June 7, 2002Date of Patent: August 28, 2007Assignee: L'OrealInventors: Grégory Plos, Henri Samain
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Patent number: 7241319Abstract: Disclosed herein is a dye composition for dyeing human keratin fibers, such as the hair, comprising a direct polycationic dye of formula (I) below: Col-Z-Col??(I) in which Col, which may be identical or different, is a noncationic dye chosen from azo dyes, methine dyes, azomethine dyes, phenothiazine dyes, triarylmethene dyes, xanthene dyes, phenanthridine dyes, and phthalocyanin dyes; and Z is chosen from linear and branched, saturated and unsaturated C1-C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least two cationic charges, and also to processes for dyeing human keratin fiber using said composition, to the use of the dyes of formula (I) as direct dyes, and to multi-compartment devices.Type: GrantFiled: December 23, 2003Date of Patent: July 10, 2007Assignee: L'Oreal S.A.Inventor: Alain Lagrange
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Patent number: 7232467Abstract: A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling componentType: GrantFiled: August 26, 2003Date of Patent: June 19, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: Jean-Marie Adam, Taher Yousaf, Beate Fröhling, Victor Paul Eliu
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Patent number: 7229479Abstract: A method of coloring porous material, especially human hair, is described, which method comprises applying to the material being colored, in any desired order successively, or simultaneously, a) at least one capped diazonium compound and b) at least one cationic water-soluble aromatic coupling component, under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.Type: GrantFiled: August 26, 2003Date of Patent: June 12, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: Beate Fröhling, Victor Paul Eliu
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Patent number: 7220286Abstract: The present invention relates to cationic direct dyes of formula (I) below: in which W1 represents —NR8— or —O—; X1 represents N; CR9; R1 and R2, which may be identical or different, represent a hydrocarbon chain; R3 and R4, which may be identical or different, represent a hydrogen atom, a halogen atom, a nitro group, a cyano group or a hydrocarbon chain; R5, R6, R7, R8 and R9, which may be identical or different, represent a hydrogen atom or a hydrocarbon chain; L represents a specific bridging group and X represents a cosmetically acceptable organic or mineral anion. It likewise relates to a dye composition comprising, in a medium suitable for dyeing human keratin fibers, such a dye, a process using it, and also a multicompartment device.Type: GrantFiled: January 13, 2005Date of Patent: May 22, 2007Assignee: L'Oreal SAInventor: Andrew Greaves
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Patent number: 7211118Abstract: A composition for dyeing keratin fibers, such as human keratin fibers, and further such as the hair, comprising at least one dye chosen from heteroylmethane type direct dyes, such as triheteroylmethane direct dyes and leuco precursors of such dyes, as defined herein. A method that uses the composition for dyeing keratin fibers, such as human keratin fibers, and further such as the hair, and a kit or device containing same.Type: GrantFiled: December 29, 2003Date of Patent: May 1, 2007Assignee: L'Oreal S.A.Inventors: Frédéric Guerin, Alain Lagrange
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Patent number: 7204857Abstract: The present invention relates to the use, for dyeing keratin fibres, of at least one specific compound containing active methylene and of at least one compound chosen from an aldehyde, a ketone, a quinone and a diiminoisoindoline or 3-aminoisoindolone derivative, which makes it possible to obtain, by reaction without an oxidizing agent, a coloration of the said keratin fibres.Type: GrantFiled: December 22, 1999Date of Patent: April 17, 2007Assignee: L'Oreal S.A.Inventors: Hervé Andrean, Alain Lagrange
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Patent number: 7201779Abstract: The invention relates to a dye composition comprising a direct dye consisting of different chromophores, the dye having a particular L*a*b* value. The invention also relates to the dyeing process using this composition and to the use of this composition for dyeing keratin fibers. These compositions in particular make it possible to obtain particularly fast colorations.Type: GrantFiled: June 16, 2004Date of Patent: April 10, 2007Assignee: L'Oreal S.A.Inventors: Henri Samain, Grégory Plos, Leila Hercouet, Andrew Greaves
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Patent number: 7189266Abstract: The present disclosure relates to a composition for dyeing human keratin fibers, such as the hair, comprising, in a medium suitable for dyeing, at least one direct dye and at least on dicationic compound. Also disclosed herein is a process for dyeing and lightening human keratin fibers, such as the hair, with the compositions disclosed, as well as a the corresponding dyeing kits.Type: GrantFiled: June 10, 2002Date of Patent: March 13, 2007Assignee: L'Oreal, S.A.Inventors: Grégory Plos, Henri Samain
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Patent number: 7186276Abstract: Disclosed herein is a dye composition for dyeing human keratin fibers, such as the hair, comprising a direct polycationic dye of formula (I) below: Col-Z-Col??(I) in which Col, which may be identical or different, is a monocationic dye chosen from azo dyes, methine dyes, azomethine dyes, and phenothiazine dyes; and Z is chosen from linear and branched, saturated and unsaturated C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least two cationic charges, and also to processes for dyeing human keratin fibers using said composition, to the use of the dyes of formula (I) as direct dyes, and to multi-compartment devices.Type: GrantFiled: December 23, 2003Date of Patent: March 6, 2007Assignee: L'OrealInventor: Alain Lagrange
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Patent number: 7179307Abstract: Use of an extract of the plant Myrsine africana in oxidation dyeing for dyeing keratin fibers, a novel composition comprising this plant extract, a process for the oxidation dyeing of keratin fibers using this composition, as well as the colored products obtained using the composition.Type: GrantFiled: September 23, 2005Date of Patent: February 20, 2007Assignee: L'Oreal, S.A.Inventors: Béatrice Belcour-Castro, Hervé Burgaud, Georges Hussler, Michel Seite
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Lightening dye composition comprising at least one cationic direct dye containing mixed chromophores
Patent number: 7172633Abstract: The present invention relates to a lightening dye composition comprising, in a suitable dyeing medium, an oxidizing agent, an alkaline agent in an amount such that the pH of the composition is greater than 7, and a mixed cationic dye comprising several chromophores linked together via a linker, at least two of the chromophores being different, the chromophores having an absorbance of between 400 and 800 nm. The invention makes it possible to obtain particularly fast colorations.Type: GrantFiled: June 16, 2004Date of Patent: February 6, 2007Assignee: L'Oréal S.A.Inventors: Henri Samain, Leila Hercouet -
Patent number: 7172631Abstract: The present disclosure relates to a dyeing composition for human keratinous fibers, such as the hair, comprising, in a suitable dyeing medium, at least one oxidation dye, and at least one dicationic compound. The disclosure further relates to the dyeing methods and dyeing kit using the dye composition.Type: GrantFiled: June 7, 2002Date of Patent: February 6, 2007Assignee: L'Oreal S.A.Inventors: Grégory Plos, Henri Samain
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Patent number: 7169194Abstract: A dye composition for dyeing human keratin fibers, such as hair, comprising at least one direct tricationic dye of formula (I) below: Col—Z—Col ??(I) wherein: Col, which may be identical or different, is a monocationic dye chosen from azo dyes, cyanomethine dyes and phenothiazine dyes and Z is chosen from linear and branched, saturated and unsaturated C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing a cationic charge. Also processes for dyeing human keratin fibers using the dye composition, to the use of the at least one direct tricationic dye of formula (I) as direct dyes, and to multi-compartment devices.Type: GrantFiled: December 23, 2003Date of Patent: January 30, 2007Assignee: L'Oreal S.A.Inventor: Alain Lagrange
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Patent number: 7094262Abstract: A dye composition for dyeing human keratin fibres, such as hair, comprising at least one dissymmetrical polycationic direct dye of formula (I) below: Col1-Z-Col2??(I) wherein: Col1 and Col2, which differ in structure, are chosen from tazo dyes, methine dyes, azomethine dyes, phenothiazine dyes, triarylmethane dyes, xanthene dyes, phenanthridine dyes and phthalocyanin dyes and Z is chosen from linear and branched, saturated, unsaturated and cyclic C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least one cationic charge; and also to processes for dyeing human keratin fibres using the composition, to the use of the at least one dissymmetrical polycationic direct dye of formula (I) as direct dyes, and to multi-compartment devices.Type: GrantFiled: December 23, 2003Date of Patent: August 22, 2006Assignee: L'Oreal S.A.Inventor: Alain Lagrange
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Patent number: 7090703Abstract: The disclosure relates to novel para-phenylenediamine derivatives containing a cyclic diaza group, substituted with a cationic radical, as well as to the dye compositions comprising them, and to the method of dyeing keratin fibers using these compositions. The present invention may make it possible to obtain a chromatic, strong, relatively unselective and fast coloration on keratin fibers.Type: GrantFiled: March 24, 2004Date of Patent: August 15, 2006Assignee: L'OrealInventors: Stéphane Sabelle, Alain Genet, Madeleine Leduc
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Patent number: 7077872Abstract: The object of the present patent application are agents for dyeing keratin fibers based on a developer-coupler combination and characterized in that they contain at least one 3-aminophenol derivative of formula (I) or a physiologically compatible, water-soluble salt thereof wherein R1 denotes a group of the formula ?or a group of the formula ?as well as novel 3-aminophenol derivatives.Type: GrantFiled: April 24, 2002Date of Patent: July 18, 2006Assignee: Wella AGInventors: Cècile Pasquier, Patrick Wyss, Hans-Juergen Braun
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Patent number: 7060110Abstract: The invention concerns a novel dyeing composition for dying keratinous fibers, in particular human hair, comprising a dicationic monoazo dye, and the dyeing method using said composition and the novel compounds of formulae (I) or (II).Type: GrantFiled: April 3, 2002Date of Patent: June 13, 2006Assignee: L'OrealInventors: Laurent Vidal, Hervé David
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Patent number: 6974485Abstract: Use of an extract of the plant Myrsine africana in oxidation dyeing for dyeing keratin fibres, a novel composition comprising this plant extract, a process for the oxidation dyeing of keratin fibres using this composition, as well as the coloured products obtained using the composition.Type: GrantFiled: November 14, 2002Date of Patent: December 13, 2005Assignee: L'Oreal S.A.Inventors: Béatrice Belcour-Castro, Hervé Burgaud, Georges Hussler, Michel Seite
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Patent number: 6743263Abstract: The present invention relates to a composition for coloring keratinaceous fibers and a method of using the same. The composition of the present invention contains (a) at least one pyrimidine derivative and (b) at least one compound selected from an m-phenylene derivative, an m-aminophenol derivative, a pyridine derivative, a resorcinol derivative, a methylenedioxybenzene derivative, or 3,4-diaminobenzoic acid or combinations thereof. The method of the present invention includes applying the coloring composition to keratin-containing fibers and subsequently rinsing the coloring composition from the fibers.Type: GrantFiled: October 31, 2001Date of Patent: June 1, 2004Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Horst Hoeffkes, Doris Oberkobusch, David Rose, Melanie Hitz
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Patent number: 6740128Abstract: The object of the invention is a preparation for dyeing fibers, especially hair, which is prepared before use by mixing an acidic component (A1), containing at least an enamine of formula (I) or its acid addition salt of Formula (Ia) with an alkaline component (A2), containing at least one carbonyl compound and at least one primary amine, as well as a method for temporarily dyeing fibers, by means of which the coloration, obtained with the aforementioned dyeing preparation, is removed once again at any later time by a sulfite-containing decolorizing agent.Type: GrantFiled: December 20, 2001Date of Patent: May 25, 2004Assignee: Wella AktiengesellschaftInventors: Manuela Javet, Catherine Mueller
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Patent number: 6669739Abstract: The object of the present invention is a preparation for coloring fibers, which is prepared before use by mixing an acidic component (A1), containing at least one enamine of Formula (I)/(Ia) with a component (A2), containing a Schiff's base of Formula (II) as well as a method for temporarily coloring fibers, for which the coloration, obtained with the aforementioned coloring agent, can be removed once again at any time by a sulfite-containing decolorizing agent.Type: GrantFiled: December 21, 2001Date of Patent: December 30, 2003Assignee: Wella AktiengesellschaftInventors: Guido Sauter, Hans-Juergen Braun, Nadia Reichlin
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Patent number: 6180086Abstract: The sensitivity and specificity of the optical modality can be enhanced by the use of highly absorbing dyes as contrast agents. Novel cyanine dyes that absorb and emit light in the near infrared region of electromagnetic spectrum are disclosed. These dyes are useful for imaging, diagnosis and therapy of various diseased states. Particularly, the molecules of the invention are useful for optical diagnostic imaging and therapy, in endoscopic applications for the detection of tumors and other abnormalities, for localized therapy, for photoacoustic tumor imaging, detection and therapy, and for sonofluorescence tumor imaging, detection and therapy.Type: GrantFiled: January 18, 2000Date of Patent: January 30, 2001Assignee: Mallinckrodt Inc.Inventors: Samuel Achilefu, Raghavan Rajagopalan, Richard B. Dorshow, Joseph E. Bugaj
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Patent number: 5972044Abstract: An aqueous or aqueous-alcoholic composition for dyeing natural or synthetic fibers, especially hair, contains a combination of at least one cyclic oxo-substituted enediol according to formula I: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and independently of each other represent a hydrogen atom or an alkali metal atom, or R.sub.1 and R.sub.2 together represent an alkaline earth metal atom and n=0, 1, 2 or 3; and at least one member selected from the group consisting of malonic acid dinitrile, maleic acid diaminodinitrile, 2,5-diamino-6-nitropyridine, 1,2,3,4-tetrahydro-6-nitroquinoxaline, 7-amino-3,4-dihydro-6-nitro-2H-1,4-benzoxazine and substituted nitrobenzene compounds; as well as water and at least one cosmetic ingredient including solvents other than water, surfactants, thickeners, care materials and adjuvant materials.Type: GrantFiled: March 23, 1998Date of Patent: October 26, 1999Assignee: Wella AGInventors: Hans-Juergen Braun, Pascal Andre Semadeni
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Patent number: 5873909Abstract: The application of a treating solution containing polyhydroxy compound and choline chloride to a fibrous cellulosic material is made more uniform and reproducible by including in the treating solution a colorizing amount of a fugitive tint, by which the uniformity of the application can be observed and corrected by appropriate changes to the operating variables.Type: GrantFiled: April 7, 1998Date of Patent: February 23, 1999Assignee: Ducoa, L.P.Inventors: George L. Brodmann, John S. Thackrah
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Patent number: 5868800Abstract: The invention relates to an oxidation dyeing composition for keratinous fibres, in particular for human keratinous fibres such as hair, of the type which comprises, in a medium appropriate for dyeing, at least one oxidation dye precursor and at least one coupler, and which is characterized in that it contains, as oxidation dye precursor, at least one para-phenylenediamine which is substituted in position 2 on the benzene ring, and/or at least one of its addition salts with an acid, and, as coupler, at least one specific 6-hydroxy-1,4-benzomorpholine and/or at least one of its addition salts with an acid. The invention also relates to the use of this composition for the dyeing of keratinous fibres, especially hair.Type: GrantFiled: June 10, 1997Date of Patent: February 9, 1999Assignee: L'OrealInventors: Jean Cotteret, Marie-Pascale Audousset
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Patent number: 5785717Abstract: The present invention relates to a composition for the oxidation dyeing of keratin fibers, in particular human keratin fibers such as the hair, comprising at least one diaminopyrazole derivative as oxidation base in combination with at least one suitably selected heterocyclic coupler, and to the dyeing process using this composition with an oxidizing agent.Type: GrantFiled: February 27, 1996Date of Patent: July 28, 1998Assignee: L'OrealInventors: Mireille Maubru, Marie-Pascale Audousset
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Patent number: 5769903Abstract: The present invention relates to a composition for the oxidation dyeing of keratin fibers, in particular human keratin fibers such as the hair, comprising an oxidation base in combination with at least one suitably selected indole coupler and at least one additional heterocyclic coupler which is also suitably selected, as well as to the dyeing process using this composition with an oxidizing agent.Type: GrantFiled: April 17, 1997Date of Patent: June 23, 1998Assignee: L'OrealInventors: Marie-Pascale Audousset, Jean Cotteret
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Patent number: 5762650Abstract: A composition and a process are disclosed for imparting durable antimicrobial properties to fibrous materials. The composition contains a leveling surfactant and a water-insoluble antimicrobial compound. In one embodiment, simultaneous dyeing and antimicrobial finishing of a fibrous material is achieved using an aqueous dye bath containing the aforesaid composition.Type: GrantFiled: August 23, 1996Date of Patent: June 9, 1998Assignee: Olin CorporationInventors: Murray A. Ruggiero, Phil Magan, Thomas Edgar Robitaille, Robert P. Roth, James J. Irovando
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Patent number: 5690695Abstract: The invention relates to an oxidation dyeing composition for keratinous fibres, in particular for human keratinous fibres such as hair, of the type which comprises, in a medium appropriate for dyeing, at least one oxidation dye precursor and at least one coupler, and which is characterized in that it contains, as oxidation dye precursor, at least one para-phenylenediamine which is substituted in position 2 on the benzene ring, and/or at least one of its addition salts with an acid, and, as coupler, at least one specific 6-hydroxy-1,4-benzomorpholine and/or at least one of its addition salts with an acid. The invention also relates to the use of this composition for the dyeing of keratinous fibres, especially hair.Type: GrantFiled: May 26, 1995Date of Patent: November 25, 1997Assignee: L'OrealInventors: Jean Cotteret, Marie-Pascale Audousset
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Patent number: 5626633Abstract: Dyestuffs of the formula (I) ##STR1## wherein n denotes 1 or 2,T denotes O or N--R.sub.0, whereinR.sub.0 denotes H, alkyl, aryl or acyl or, together with R.sub.2 or R.sub.3, forms a 5- to 7-membered ring,R.sub.1 if n=1, denotes aryl, hetaryl or heterocyclylidenemethyl andif n=2, denotes a direct bond or arylene andR.sub.2 and R.sub.3 are independent or cyclic radicals having the meanings given in the description,are employed for bulk dyeing of plastics, preferably thermoplastics.Type: GrantFiled: December 1, 1995Date of Patent: May 6, 1997Assignee: Bayer AktiengesellschaftInventor: Peter Roschger
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Patent number: 5613985Abstract: The present invention relates to the use of a compound of the general formula I ##STR1## wherein R.sup.1 to R.sup.4, Hal and n are defined as in claim 1, as a coupler substance for the preparation of oxidation dyestuffs, and to hair colouring compositions which comprise a compound of the general formula I.Type: GrantFiled: September 22, 1995Date of Patent: March 25, 1997Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Bauer, Mustafa Akram
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Patent number: 5601621Abstract: Fiber materials can be modified by applying heterocycloaliphatic compounds containing at least one primary, secondary or tertiary amino group or quaternary ammonium group, the hetero portion of which in the ring is a carbonic ester radical of the formula --O--CO--O-- or a carbamic acid radical of the formula --O--CO--NH--, in aqueous alkaline solution by exposing the fiber material to these compounds at a temperature of between 60.degree. and 230.degree. C. The characteristic of the modified fiber material is that it can be dyed with dye solutions of water-soluble, anionic textile dyes which are low in electrolytes or entirely free of electrolytes and/or are low in alkali or entirely free of alkali. The advantage of a dyeing process carried out in this manner, in particular for fiber-reactive dyes, is that fixation of the dyes under alkaline conditions is unnecessary.Type: GrantFiled: February 13, 1995Date of Patent: February 11, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Schrell, Werner H. Russ, Thomas Riehm
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Patent number: 5595574Abstract: Dye donor element for use according to thermal dye sublimation transfer comprising a support having thereon a dye layer comprising at least one heterocyclic hydrazono dye, wherein said dye corresponds to the general formula:A=N-N=Hetwherein A is a carbocyclic or heterocyclic coupler group or a cyclic reactive methylene system, which may carry at least one substituent, and Het is a heterocyclic nucleus, which may carry at least one substituent.Type: GrantFiled: May 23, 1995Date of Patent: January 21, 1997Assignee: Agfa-Gevaert N.V.Inventors: Wilhelmus Janssens, Luc Vanmaele
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Patent number: 5578088Abstract: Process for dyeing aminated cellulose/polyester blend fabric with fiber-reactive disperse dyestuffs Fiber materials comprising cellulose fibers or a mixture of cellulose and polyester fibers are dyed by first modifying the fiber material with one or more compounds containing amino groups and then dyeing the modified fiber material with a fiber-reactive disperse dyestuff in supercritical CO.sub.2.Type: GrantFiled: June 29, 1995Date of Patent: November 26, 1996Assignee: Hoechst AktiengesellschaftInventors: Andreas Schrell, Werner H. Russ
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Patent number: 5571289Abstract: Dye donor element for use according to thermal dye sublimation transfer comprising a support having thereon a dye layer comprising at least one heterocyclic hydrazono dye, wherein said dye corresponds to the general formula:A.dbd.N-N.dbd.Hetwherein A is a carbocyclic or heterocyclic coupler group or a cyclic reactive methylene system, which may carry at least one substituent, and Het is a heterocyclic nucleus, which may carry at least one substituent.Type: GrantFiled: May 23, 1995Date of Patent: November 5, 1996Assignee: AGFA-Gevaert N.V.Inventors: Wilhelmus Janssens, Luc Vanmaele
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Patent number: 5571291Abstract: A low-temperature dyeing additive for protein fiber products contains one or more kinds of solvents which are freely miscible with water and having a donor number within the range of 24 to 50 and an acceptor number within the range of 10 to 24 in the presence or absence of a surfactant, in an amount of 0.025 to 40 g per liter of water, has a pH of 3.5 to 9.5. If necessary, it contains tributoxyethyl phosphate in an amount of 0.025 to 4.0 g per liter of water, and/or contains one or more kinds of anions having an enthalpy of hydration (-.DELTA.H.sub.KJ.multidot.mol.sup.-1) of 200 to 290 in an amount of 0.05 to 40 g per liter of water. This low-temperature dyeing additive for protein fiber products serves to relax the higher-order structures of the protein fibers before dyeing or during dyeing, to thereby swell the fibers, thus rendering the fibers readily dyeable without detriment to the properties thereof.Type: GrantFiled: July 5, 1995Date of Patent: November 5, 1996Assignee: Tuyaku Co., Ltd.Inventor: Sachizumi Koike
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Patent number: 5542954Abstract: A process for the production of aminated cotton fibers by subjecting a raw cotton or cotton-polyester mixture to a modification with a saturated aliphatic compound of 3 to 15 carbon atoms which contains at least one primary, secondary, tertiary, or quaternary amino group and at least one hydrolyzable ester group, in which the saturated radical is straight chain, branched, or cyclic, and may be interrupted by one or more hetero groups and may be substituted by one or more hydroxyl groups. The modification occurs simultaneously with scouring, kiering, or dry mercerizing.Type: GrantFiled: January 24, 1995Date of Patent: August 6, 1996Assignee: Hoechst AktiengesellschaftInventors: Andreas Schrell, Werner H. Russ
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Patent number: 5507840Abstract: A process for the dyeing of fiber materials with water-soluble anionic dyes, in particular those having a fiber-reactive group, is described, according to which dyeing is carried out using low-electrolyte or entirely electrolyte-free and/or low-alkali or entirely alkali-free dye solutions (dye liquors, printing pastes) and in which a fiber material is used which was modified by means of a saturated straight-chain or branched aliphatic or cycloaliphatic compound which is unsubstituted or substituted by one or more hydroxy groups and contains at least one primary, secondary or tertiary amino group or quaternary ammonium group and at least one hydrolyzable ester group, it also being possible for the aliphatic radical in this compound to be interrupted by one or more hetero groups.Type: GrantFiled: March 6, 1995Date of Patent: April 16, 1996Assignee: Hoechst AktiengesellschaftInventors: Andreas Schrell, Werner H. Russ, Thomas Riehm
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Patent number: 5498267Abstract: Process and use of reactive disperse dyes for dyeing and printing aminated, textile cotton and cotton-polyester blend fabricsHydroxyl-containing materials, in particular fiber materials, such as cellulose fiber materials, which have been modified with an amino-containing compound are dyed as such or in blend with polyester fibers with the aid of a fiber-reactive disperse dye in an aqueous, low-electrolyte or completely electrolyte-free medium and in the absence of an alkaline or alkali-donating agent at a temperature of between 100.degree. and 210.degree. C. Not only the modified cellulose-containing material but also the polyester material can be dyed in one and the same dyeing process with one and the same fiber reactive disperse dye. A uniform overall dyeing not only for modified hydroxyl-containing material but also for polyester material is obtained.Type: GrantFiled: August 11, 1994Date of Patent: March 12, 1996Assignee: Hoechst AGInventors: Werner H. Russ, Andreas Schrell, Andreas von der Eltz
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Patent number: 5474578Abstract: A hair fiber having a first color is contacted with a dye having the formula I, formula II, formula III or a mixture thereof whereby the fiber has imparted to it a second color, upon subsequent contact with alkaline peroxide the visual appearance of the first color is restored to the fiber.Type: GrantFiled: October 3, 1994Date of Patent: December 12, 1995Assignee: Clairol, Inc.Inventors: Alexander C. Chan, Alice A. Mayer, Jia-Shen Wang, Gottfried Wenke, Mu-Ill Lim