Six-membered Hetero Ring Having Two Or More Ring Hetero Atoms Of Which At Least One Is Nitrogen Patents (Class 8/565)
  • Patent number: 7393367
    Abstract: An agent for dyeing keratin-containing fibers, especially human hair, is comprised of a cosmetic carrier, and (A) at least one compound of Formula I, wherein each of R1, R2 and R3 is independently a hydrogen atom, a halogen atom, a C1-C6 alkyl group, a C2-C6 alkenyl group, a hydroxyl group, a C1-C6 alkoxy group, a C1-C6 hydroxyalkyl group, a C2-C6 polyhydroxyalkyl group, a hydroxy C1-C6 alkyloxy group, a sulfonyl group, a carboxyl group, a C1-C6 alkoxycarbonyl group, a hydroxy C2-C6 alkyloxycarbonyl group, a sulfonic acid group, a sulfonamido group, a sulfonamide group, a C2-C6 acyl group, a formyl group, a nitro group, a carbamoyl group —C(O)—NR4R5, or a —(CH2)nNR6R7 group wherein each of R4, R5, R6 and R7 is independently a hydrogen atom, a C1-C6 alkyl group or a C2-C6 hydroxyalkyl group; and n is number from 0 to 6, wherein R1 and R2 can form a 5- or 6-membered aromatic or heteroaromatic ring; and (B) at least one CH-acidic compound.
    Type: Grant
    Filed: November 8, 2007
    Date of Patent: July 1, 2008
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wibke Gross, Horst Hoffkes, Doris Oberkobusch, Helmut Muller, Carsten Brake
  • Patent number: 7326259
    Abstract: A subject-matter of the present patent application is the use, as direct dye in dyeing compositions for keratinous fibres, in particular human keratinous fibres, such as the hair, or for the manufacture of such compositions, of a specific polycationic compound.
    Type: Grant
    Filed: June 22, 2005
    Date of Patent: February 5, 2008
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7311736
    Abstract: The invention concerns the use as direct dyeing agent of at least one tetra-azapentamethine compound, a dyeing composition comprising at least such a compound, as well as a method for dyeing keratinous fibers, in particular human keratinous fibers and more particularly hair, which consists in applying at least one composition comprising such a compound. The composition also concerns tetra-azapentamethine compounds of formula (I). The invention further concerns a method for bleaching such compounds, as well as bleaching keratinous fibers previously dyed therewith.
    Type: Grant
    Filed: July 4, 2003
    Date of Patent: December 25, 2007
    Assignee: L'Oreal
    Inventors: Herve Burgaud, Herve David, Rui Pereira, Beatrice Belcour-Castro
  • Patent number: 7303591
    Abstract: A dye composition comprising at least one mixed dye comprising at least two chromophore chosen from azine and (hetero)aromatic nitro compounds, optionally associated with at least one chromophore chosen from methine and carbonyl compounds; a process for dyeing keratin fibers, for example, human keratin fibers, such as the hair, using the composition, a multi-compartment device comprising the composition; and the abovementioned mixed dyes.
    Type: Grant
    Filed: February 28, 2005
    Date of Patent: December 4, 2007
    Assignee: L'Oreal S.A.
    Inventors: Andrew Greaves, Hervé David, Henri Samain
  • Patent number: 7300471
    Abstract: Disclosed herein are a dye composition comprising at least one mixed dye comprising at least one chromophore chosen from chromophores of the azo family and the tri(hetero)arylmethane family; and the mixed dyes. Further disclosed herein are a process for dyeing keratin fibers, such as human keratin fibers, using the composition, and a device comprising the composition.
    Type: Grant
    Filed: February 28, 2005
    Date of Patent: November 27, 2007
    Assignee: L'Oreal S.A.
    Inventors: Andrew Greaves, Hervé David, Henri Samain
  • Patent number: 7294152
    Abstract: The present disclosure relates to a specific direct dye compound that is a fluorindine derivative, and dyeing compositions comprising at least one derivative of the compound and at least one polymer. A process for dyeing keratin fibers with the defined compositions is also disclosed.
    Type: Grant
    Filed: January 7, 2005
    Date of Patent: November 13, 2007
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7288120
    Abstract: The present disclosure relates to processes for synthesizing tetraazapentamethine compounds that comprise reacting at least one compound of azine type with at least one oxidizing agent. The disclosure also relates to processes for dyeing keratin fibers, for example human keratin fibers, that comprise using such synthetic processes.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: October 30, 2007
    Assignee: L'Oreal S.A.
    Inventors: Rui Pereira, Hervé Burgaud
  • Patent number: 7288121
    Abstract: The present invention relates to a dye composition including at least one mixed dye containing at least one chromophore of methine or carbonyl type or their combinations. The invention furthermore relates to a process for dyeing keratin fibers, especially human keratin fibers, such as the hair, using the composition, and also to a suitable kit. The invention also relates to the abovementioned mixed dyes per se.
    Type: Grant
    Filed: February 28, 2005
    Date of Patent: October 30, 2007
    Assignee: L'Oreal S.A.
    Inventors: Andrew Greaves, Hervé David, Henri Samain
  • Patent number: 7282068
    Abstract: The present disclosure relates to compounds used as direct dyes, and dyeing compositions comprising such compounds. The disclosed compounds have the formula A-L-B, wherein A and B are chosen from arylazoimidazolium coloring functional groups, and L is a linker comprising at least one cationic group C. The disclosure also relates methods of using such compositions for coloring keratin fibers, such as the hair.
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: October 16, 2007
    Assignee: L'Oreal S.A.
    Inventors: Alain Lagrange, Hervé David, Andrew Greaves
  • Patent number: 7261743
    Abstract: The present disclosure relates to the process of dyeing human keratinous fibers, such as the hair, with at least one specific direct dye in cosmetic compositions. Also disclosed herein are the direct dyeing and lightening compositions comprising said compounds, and the corresponding dyeing kits.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: August 28, 2007
    Assignee: L'Oreal
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7241319
    Abstract: Disclosed herein is a dye composition for dyeing human keratin fibers, such as the hair, comprising a direct polycationic dye of formula (I) below: Col-Z-Col??(I) in which Col, which may be identical or different, is a noncationic dye chosen from azo dyes, methine dyes, azomethine dyes, phenothiazine dyes, triarylmethene dyes, xanthene dyes, phenanthridine dyes, and phthalocyanin dyes; and Z is chosen from linear and branched, saturated and unsaturated C1-C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least two cationic charges, and also to processes for dyeing human keratin fiber using said composition, to the use of the dyes of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: July 10, 2007
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7232467
    Abstract: A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: June 19, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jean-Marie Adam, Taher Yousaf, Beate Fröhling, Victor Paul Eliu
  • Patent number: 7229479
    Abstract: A method of coloring porous material, especially human hair, is described, which method comprises applying to the material being colored, in any desired order successively, or simultaneously, a) at least one capped diazonium compound and b) at least one cationic water-soluble aromatic coupling component, under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: June 12, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Beate Fröhling, Victor Paul Eliu
  • Patent number: 7220286
    Abstract: The present invention relates to cationic direct dyes of formula (I) below: in which W1 represents —NR8— or —O—; X1 represents N; CR9; R1 and R2, which may be identical or different, represent a hydrocarbon chain; R3 and R4, which may be identical or different, represent a hydrogen atom, a halogen atom, a nitro group, a cyano group or a hydrocarbon chain; R5, R6, R7, R8 and R9, which may be identical or different, represent a hydrogen atom or a hydrocarbon chain; L represents a specific bridging group and X represents a cosmetically acceptable organic or mineral anion. It likewise relates to a dye composition comprising, in a medium suitable for dyeing human keratin fibers, such a dye, a process using it, and also a multicompartment device.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: May 22, 2007
    Assignee: L'Oreal SA
    Inventor: Andrew Greaves
  • Patent number: 7211118
    Abstract: A composition for dyeing keratin fibers, such as human keratin fibers, and further such as the hair, comprising at least one dye chosen from heteroylmethane type direct dyes, such as triheteroylmethane direct dyes and leuco precursors of such dyes, as defined herein. A method that uses the composition for dyeing keratin fibers, such as human keratin fibers, and further such as the hair, and a kit or device containing same.
    Type: Grant
    Filed: December 29, 2003
    Date of Patent: May 1, 2007
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Guerin, Alain Lagrange
  • Patent number: 7204857
    Abstract: The present invention relates to the use, for dyeing keratin fibres, of at least one specific compound containing active methylene and of at least one compound chosen from an aldehyde, a ketone, a quinone and a diiminoisoindoline or 3-aminoisoindolone derivative, which makes it possible to obtain, by reaction without an oxidizing agent, a coloration of the said keratin fibres.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: April 17, 2007
    Assignee: L'Oreal S.A.
    Inventors: Hervé Andrean, Alain Lagrange
  • Patent number: 7201779
    Abstract: The invention relates to a dye composition comprising a direct dye consisting of different chromophores, the dye having a particular L*a*b* value. The invention also relates to the dyeing process using this composition and to the use of this composition for dyeing keratin fibers. These compositions in particular make it possible to obtain particularly fast colorations.
    Type: Grant
    Filed: June 16, 2004
    Date of Patent: April 10, 2007
    Assignee: L'Oreal S.A.
    Inventors: Henri Samain, Grégory Plos, Leila Hercouet, Andrew Greaves
  • Patent number: 7189266
    Abstract: The present disclosure relates to a composition for dyeing human keratin fibers, such as the hair, comprising, in a medium suitable for dyeing, at least one direct dye and at least on dicationic compound. Also disclosed herein is a process for dyeing and lightening human keratin fibers, such as the hair, with the compositions disclosed, as well as a the corresponding dyeing kits.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: March 13, 2007
    Assignee: L'Oreal, S.A.
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7186276
    Abstract: Disclosed herein is a dye composition for dyeing human keratin fibers, such as the hair, comprising a direct polycationic dye of formula (I) below: Col-Z-Col??(I) in which Col, which may be identical or different, is a monocationic dye chosen from azo dyes, methine dyes, azomethine dyes, and phenothiazine dyes; and Z is chosen from linear and branched, saturated and unsaturated C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least two cationic charges, and also to processes for dyeing human keratin fibers using said composition, to the use of the dyes of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: March 6, 2007
    Assignee: L'Oreal
    Inventor: Alain Lagrange
  • Patent number: 7179307
    Abstract: Use of an extract of the plant Myrsine africana in oxidation dyeing for dyeing keratin fibers, a novel composition comprising this plant extract, a process for the oxidation dyeing of keratin fibers using this composition, as well as the colored products obtained using the composition.
    Type: Grant
    Filed: September 23, 2005
    Date of Patent: February 20, 2007
    Assignee: L'Oreal, S.A.
    Inventors: Béatrice Belcour-Castro, Hervé Burgaud, Georges Hussler, Michel Seite
  • Patent number: 7172633
    Abstract: The present invention relates to a lightening dye composition comprising, in a suitable dyeing medium, an oxidizing agent, an alkaline agent in an amount such that the pH of the composition is greater than 7, and a mixed cationic dye comprising several chromophores linked together via a linker, at least two of the chromophores being different, the chromophores having an absorbance of between 400 and 800 nm. The invention makes it possible to obtain particularly fast colorations.
    Type: Grant
    Filed: June 16, 2004
    Date of Patent: February 6, 2007
    Assignee: L'Oréal S.A.
    Inventors: Henri Samain, Leila Hercouet
  • Patent number: 7172631
    Abstract: The present disclosure relates to a dyeing composition for human keratinous fibers, such as the hair, comprising, in a suitable dyeing medium, at least one oxidation dye, and at least one dicationic compound. The disclosure further relates to the dyeing methods and dyeing kit using the dye composition.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: February 6, 2007
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Henri Samain
  • Patent number: 7169194
    Abstract: A dye composition for dyeing human keratin fibers, such as hair, comprising at least one direct tricationic dye of formula (I) below: Col—Z—Col ??(I) wherein: Col, which may be identical or different, is a monocationic dye chosen from azo dyes, cyanomethine dyes and phenothiazine dyes and Z is chosen from linear and branched, saturated and unsaturated C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing a cationic charge. Also processes for dyeing human keratin fibers using the dye composition, to the use of the at least one direct tricationic dye of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: January 30, 2007
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7094262
    Abstract: A dye composition for dyeing human keratin fibres, such as hair, comprising at least one dissymmetrical polycationic direct dye of formula (I) below: Col1-Z-Col2??(I) wherein: Col1 and Col2, which differ in structure, are chosen from tazo dyes, methine dyes, azomethine dyes, phenothiazine dyes, triarylmethane dyes, xanthene dyes, phenanthridine dyes and phthalocyanin dyes and Z is chosen from linear and branched, saturated, unsaturated and cyclic C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least one cationic charge; and also to processes for dyeing human keratin fibres using the composition, to the use of the at least one dissymmetrical polycationic direct dye of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: August 22, 2006
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7090703
    Abstract: The disclosure relates to novel para-phenylenediamine derivatives containing a cyclic diaza group, substituted with a cationic radical, as well as to the dye compositions comprising them, and to the method of dyeing keratin fibers using these compositions. The present invention may make it possible to obtain a chromatic, strong, relatively unselective and fast coloration on keratin fibers.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: August 15, 2006
    Assignee: L'Oreal
    Inventors: Stéphane Sabelle, Alain Genet, Madeleine Leduc
  • Patent number: 7077872
    Abstract: The object of the present patent application are agents for dyeing keratin fibers based on a developer-coupler combination and characterized in that they contain at least one 3-aminophenol derivative of formula (I) or a physiologically compatible, water-soluble salt thereof wherein R1 denotes a group of the formula ?or a group of the formula ?as well as novel 3-aminophenol derivatives.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: July 18, 2006
    Assignee: Wella AG
    Inventors: Cècile Pasquier, Patrick Wyss, Hans-Juergen Braun
  • Patent number: 7060110
    Abstract: The invention concerns a novel dyeing composition for dying keratinous fibers, in particular human hair, comprising a dicationic monoazo dye, and the dyeing method using said composition and the novel compounds of formulae (I) or (II).
    Type: Grant
    Filed: April 3, 2002
    Date of Patent: June 13, 2006
    Assignee: L'Oreal
    Inventors: Laurent Vidal, Hervé David
  • Patent number: 6974485
    Abstract: Use of an extract of the plant Myrsine africana in oxidation dyeing for dyeing keratin fibres, a novel composition comprising this plant extract, a process for the oxidation dyeing of keratin fibres using this composition, as well as the coloured products obtained using the composition.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: December 13, 2005
    Assignee: L'Oreal S.A.
    Inventors: Béatrice Belcour-Castro, Hervé Burgaud, Georges Hussler, Michel Seite
  • Patent number: 6743263
    Abstract: The present invention relates to a composition for coloring keratinaceous fibers and a method of using the same. The composition of the present invention contains (a) at least one pyrimidine derivative and (b) at least one compound selected from an m-phenylene derivative, an m-aminophenol derivative, a pyridine derivative, a resorcinol derivative, a methylenedioxybenzene derivative, or 3,4-diaminobenzoic acid or combinations thereof. The method of the present invention includes applying the coloring composition to keratin-containing fibers and subsequently rinsing the coloring composition from the fibers.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: June 1, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst Hoeffkes, Doris Oberkobusch, David Rose, Melanie Hitz
  • Patent number: 6740128
    Abstract: The object of the invention is a preparation for dyeing fibers, especially hair, which is prepared before use by mixing an acidic component (A1), containing at least an enamine of formula (I) or its acid addition salt of Formula (Ia) with an alkaline component (A2), containing at least one carbonyl compound and at least one primary amine, as well as a method for temporarily dyeing fibers, by means of which the coloration, obtained with the aforementioned dyeing preparation, is removed once again at any later time by a sulfite-containing decolorizing agent.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: May 25, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Manuela Javet, Catherine Mueller
  • Patent number: 6669739
    Abstract: The object of the present invention is a preparation for coloring fibers, which is prepared before use by mixing an acidic component (A1), containing at least one enamine of Formula (I)/(Ia) with a component (A2), containing a Schiff's base of Formula (II) as well as a method for temporarily coloring fibers, for which the coloration, obtained with the aforementioned coloring agent, can be removed once again at any time by a sulfite-containing decolorizing agent.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: December 30, 2003
    Assignee: Wella Aktiengesellschaft
    Inventors: Guido Sauter, Hans-Juergen Braun, Nadia Reichlin
  • Patent number: 6180086
    Abstract: The sensitivity and specificity of the optical modality can be enhanced by the use of highly absorbing dyes as contrast agents. Novel cyanine dyes that absorb and emit light in the near infrared region of electromagnetic spectrum are disclosed. These dyes are useful for imaging, diagnosis and therapy of various diseased states. Particularly, the molecules of the invention are useful for optical diagnostic imaging and therapy, in endoscopic applications for the detection of tumors and other abnormalities, for localized therapy, for photoacoustic tumor imaging, detection and therapy, and for sonofluorescence tumor imaging, detection and therapy.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: January 30, 2001
    Assignee: Mallinckrodt Inc.
    Inventors: Samuel Achilefu, Raghavan Rajagopalan, Richard B. Dorshow, Joseph E. Bugaj
  • Patent number: 5972044
    Abstract: An aqueous or aqueous-alcoholic composition for dyeing natural or synthetic fibers, especially hair, contains a combination of at least one cyclic oxo-substituted enediol according to formula I: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and independently of each other represent a hydrogen atom or an alkali metal atom, or R.sub.1 and R.sub.2 together represent an alkaline earth metal atom and n=0, 1, 2 or 3; and at least one member selected from the group consisting of malonic acid dinitrile, maleic acid diaminodinitrile, 2,5-diamino-6-nitropyridine, 1,2,3,4-tetrahydro-6-nitroquinoxaline, 7-amino-3,4-dihydro-6-nitro-2H-1,4-benzoxazine and substituted nitrobenzene compounds; as well as water and at least one cosmetic ingredient including solvents other than water, surfactants, thickeners, care materials and adjuvant materials.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: October 26, 1999
    Assignee: Wella AG
    Inventors: Hans-Juergen Braun, Pascal Andre Semadeni
  • Patent number: 5873909
    Abstract: The application of a treating solution containing polyhydroxy compound and choline chloride to a fibrous cellulosic material is made more uniform and reproducible by including in the treating solution a colorizing amount of a fugitive tint, by which the uniformity of the application can be observed and corrected by appropriate changes to the operating variables.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: February 23, 1999
    Assignee: Ducoa, L.P.
    Inventors: George L. Brodmann, John S. Thackrah
  • Patent number: 5868800
    Abstract: The invention relates to an oxidation dyeing composition for keratinous fibres, in particular for human keratinous fibres such as hair, of the type which comprises, in a medium appropriate for dyeing, at least one oxidation dye precursor and at least one coupler, and which is characterized in that it contains, as oxidation dye precursor, at least one para-phenylenediamine which is substituted in position 2 on the benzene ring, and/or at least one of its addition salts with an acid, and, as coupler, at least one specific 6-hydroxy-1,4-benzomorpholine and/or at least one of its addition salts with an acid. The invention also relates to the use of this composition for the dyeing of keratinous fibres, especially hair.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: February 9, 1999
    Assignee: L'Oreal
    Inventors: Jean Cotteret, Marie-Pascale Audousset
  • Patent number: 5785717
    Abstract: The present invention relates to a composition for the oxidation dyeing of keratin fibers, in particular human keratin fibers such as the hair, comprising at least one diaminopyrazole derivative as oxidation base in combination with at least one suitably selected heterocyclic coupler, and to the dyeing process using this composition with an oxidizing agent.
    Type: Grant
    Filed: February 27, 1996
    Date of Patent: July 28, 1998
    Assignee: L'Oreal
    Inventors: Mireille Maubru, Marie-Pascale Audousset
  • Patent number: 5769903
    Abstract: The present invention relates to a composition for the oxidation dyeing of keratin fibers, in particular human keratin fibers such as the hair, comprising an oxidation base in combination with at least one suitably selected indole coupler and at least one additional heterocyclic coupler which is also suitably selected, as well as to the dyeing process using this composition with an oxidizing agent.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: June 23, 1998
    Assignee: L'Oreal
    Inventors: Marie-Pascale Audousset, Jean Cotteret
  • Patent number: 5762650
    Abstract: A composition and a process are disclosed for imparting durable antimicrobial properties to fibrous materials. The composition contains a leveling surfactant and a water-insoluble antimicrobial compound. In one embodiment, simultaneous dyeing and antimicrobial finishing of a fibrous material is achieved using an aqueous dye bath containing the aforesaid composition.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: June 9, 1998
    Assignee: Olin Corporation
    Inventors: Murray A. Ruggiero, Phil Magan, Thomas Edgar Robitaille, Robert P. Roth, James J. Irovando
  • Patent number: 5690695
    Abstract: The invention relates to an oxidation dyeing composition for keratinous fibres, in particular for human keratinous fibres such as hair, of the type which comprises, in a medium appropriate for dyeing, at least one oxidation dye precursor and at least one coupler, and which is characterized in that it contains, as oxidation dye precursor, at least one para-phenylenediamine which is substituted in position 2 on the benzene ring, and/or at least one of its addition salts with an acid, and, as coupler, at least one specific 6-hydroxy-1,4-benzomorpholine and/or at least one of its addition salts with an acid. The invention also relates to the use of this composition for the dyeing of keratinous fibres, especially hair.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: November 25, 1997
    Assignee: L'Oreal
    Inventors: Jean Cotteret, Marie-Pascale Audousset
  • Patent number: 5626633
    Abstract: Dyestuffs of the formula (I) ##STR1## wherein n denotes 1 or 2,T denotes O or N--R.sub.0, whereinR.sub.0 denotes H, alkyl, aryl or acyl or, together with R.sub.2 or R.sub.3, forms a 5- to 7-membered ring,R.sub.1 if n=1, denotes aryl, hetaryl or heterocyclylidenemethyl andif n=2, denotes a direct bond or arylene andR.sub.2 and R.sub.3 are independent or cyclic radicals having the meanings given in the description,are employed for bulk dyeing of plastics, preferably thermoplastics.
    Type: Grant
    Filed: December 1, 1995
    Date of Patent: May 6, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventor: Peter Roschger
  • Patent number: 5613985
    Abstract: The present invention relates to the use of a compound of the general formula I ##STR1## wherein R.sup.1 to R.sup.4, Hal and n are defined as in claim 1, as a coupler substance for the preparation of oxidation dyestuffs, and to hair colouring compositions which comprise a compound of the general formula I.
    Type: Grant
    Filed: September 22, 1995
    Date of Patent: March 25, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Bauer, Mustafa Akram
  • Patent number: 5601621
    Abstract: Fiber materials can be modified by applying heterocycloaliphatic compounds containing at least one primary, secondary or tertiary amino group or quaternary ammonium group, the hetero portion of which in the ring is a carbonic ester radical of the formula --O--CO--O-- or a carbamic acid radical of the formula --O--CO--NH--, in aqueous alkaline solution by exposing the fiber material to these compounds at a temperature of between 60.degree. and 230.degree. C. The characteristic of the modified fiber material is that it can be dyed with dye solutions of water-soluble, anionic textile dyes which are low in electrolytes or entirely free of electrolytes and/or are low in alkali or entirely free of alkali. The advantage of a dyeing process carried out in this manner, in particular for fiber-reactive dyes, is that fixation of the dyes under alkaline conditions is unnecessary.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: February 11, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Werner H. Russ, Thomas Riehm
  • Patent number: 5595574
    Abstract: Dye donor element for use according to thermal dye sublimation transfer comprising a support having thereon a dye layer comprising at least one heterocyclic hydrazono dye, wherein said dye corresponds to the general formula:A=N-N=Hetwherein A is a carbocyclic or heterocyclic coupler group or a cyclic reactive methylene system, which may carry at least one substituent, and Het is a heterocyclic nucleus, which may carry at least one substituent.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: January 21, 1997
    Assignee: Agfa-Gevaert N.V.
    Inventors: Wilhelmus Janssens, Luc Vanmaele
  • Patent number: 5578088
    Abstract: Process for dyeing aminated cellulose/polyester blend fabric with fiber-reactive disperse dyestuffs Fiber materials comprising cellulose fibers or a mixture of cellulose and polyester fibers are dyed by first modifying the fiber material with one or more compounds containing amino groups and then dyeing the modified fiber material with a fiber-reactive disperse dyestuff in supercritical CO.sub.2.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: November 26, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Werner H. Russ
  • Patent number: 5571289
    Abstract: Dye donor element for use according to thermal dye sublimation transfer comprising a support having thereon a dye layer comprising at least one heterocyclic hydrazono dye, wherein said dye corresponds to the general formula:A.dbd.N-N.dbd.Hetwherein A is a carbocyclic or heterocyclic coupler group or a cyclic reactive methylene system, which may carry at least one substituent, and Het is a heterocyclic nucleus, which may carry at least one substituent.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: November 5, 1996
    Assignee: AGFA-Gevaert N.V.
    Inventors: Wilhelmus Janssens, Luc Vanmaele
  • Patent number: 5571291
    Abstract: A low-temperature dyeing additive for protein fiber products contains one or more kinds of solvents which are freely miscible with water and having a donor number within the range of 24 to 50 and an acceptor number within the range of 10 to 24 in the presence or absence of a surfactant, in an amount of 0.025 to 40 g per liter of water, has a pH of 3.5 to 9.5. If necessary, it contains tributoxyethyl phosphate in an amount of 0.025 to 4.0 g per liter of water, and/or contains one or more kinds of anions having an enthalpy of hydration (-.DELTA.H.sub.KJ.multidot.mol.sup.-1) of 200 to 290 in an amount of 0.05 to 40 g per liter of water. This low-temperature dyeing additive for protein fiber products serves to relax the higher-order structures of the protein fibers before dyeing or during dyeing, to thereby swell the fibers, thus rendering the fibers readily dyeable without detriment to the properties thereof.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: November 5, 1996
    Assignee: Tuyaku Co., Ltd.
    Inventor: Sachizumi Koike
  • Patent number: 5542954
    Abstract: A process for the production of aminated cotton fibers by subjecting a raw cotton or cotton-polyester mixture to a modification with a saturated aliphatic compound of 3 to 15 carbon atoms which contains at least one primary, secondary, tertiary, or quaternary amino group and at least one hydrolyzable ester group, in which the saturated radical is straight chain, branched, or cyclic, and may be interrupted by one or more hetero groups and may be substituted by one or more hydroxyl groups. The modification occurs simultaneously with scouring, kiering, or dry mercerizing.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: August 6, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Werner H. Russ
  • Patent number: 5507840
    Abstract: A process for the dyeing of fiber materials with water-soluble anionic dyes, in particular those having a fiber-reactive group, is described, according to which dyeing is carried out using low-electrolyte or entirely electrolyte-free and/or low-alkali or entirely alkali-free dye solutions (dye liquors, printing pastes) and in which a fiber material is used which was modified by means of a saturated straight-chain or branched aliphatic or cycloaliphatic compound which is unsubstituted or substituted by one or more hydroxy groups and contains at least one primary, secondary or tertiary amino group or quaternary ammonium group and at least one hydrolyzable ester group, it also being possible for the aliphatic radical in this compound to be interrupted by one or more hetero groups.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: April 16, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Werner H. Russ, Thomas Riehm
  • Patent number: 5498267
    Abstract: Process and use of reactive disperse dyes for dyeing and printing aminated, textile cotton and cotton-polyester blend fabricsHydroxyl-containing materials, in particular fiber materials, such as cellulose fiber materials, which have been modified with an amino-containing compound are dyed as such or in blend with polyester fibers with the aid of a fiber-reactive disperse dye in an aqueous, low-electrolyte or completely electrolyte-free medium and in the absence of an alkaline or alkali-donating agent at a temperature of between 100.degree. and 210.degree. C. Not only the modified cellulose-containing material but also the polyester material can be dyed in one and the same dyeing process with one and the same fiber reactive disperse dye. A uniform overall dyeing not only for modified hydroxyl-containing material but also for polyester material is obtained.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: March 12, 1996
    Assignee: Hoechst AG
    Inventors: Werner H. Russ, Andreas Schrell, Andreas von der Eltz
  • Patent number: 5474578
    Abstract: A hair fiber having a first color is contacted with a dye having the formula I, formula II, formula III or a mixture thereof whereby the fiber has imparted to it a second color, upon subsequent contact with alkaline peroxide the visual appearance of the first color is restored to the fiber.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: December 12, 1995
    Assignee: Clairol, Inc.
    Inventors: Alexander C. Chan, Alice A. Mayer, Jia-Shen Wang, Gottfried Wenke, Mu-Ill Lim