Hetero N Ring Contains An Oxygen Atom (including Hydrogenated) Patents (Class 8/572)
  • Patent number: 8709104
    Abstract: The invention relates to specific dye-ascorbic acid derivatives and the use thereof as dyes for the coloring of matrices, such as, for example, skin, hair, nails or textiles, and a process for the preparation thereof, a process for the coloring of matrices, and a composition comprising these dye-ascorbic acid derivatives, and a process for the preparation of these compositions. On use of the specific dye-ascorbic acid derivatives according to the invention, a positive effect on the moisture content of the matrices arises.
    Type: Grant
    Filed: August 5, 2011
    Date of Patent: April 29, 2014
    Assignee: Merck Patent GmbH
    Inventors: Thomas Rudolph, Philipp Buehle
  • Patent number: 8632612
    Abstract: Disclosed herein are compositions for dyeing keratin fibers, methods of manufacture thereof and articles comprising the same.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: January 21, 2014
    Assignee: Segetis, Inc.
    Inventor: Dorie J. Yontz
  • Patent number: 8419808
    Abstract: The present invention relates to a dye compound represented by the following formula (I), or a salt thereof: wherein R1, R2, R3, R4, D1, D2, B, and n are defined the same as the specification, and also relates to a photoelectric component using the same. The dye compound of the present invention is suitable for Dye-Sensitized Solar Cell (DSSC). Hence, the photoelectric characteristics of the DSSC can be improved by using the dye compound of the present invention.
    Type: Grant
    Filed: November 2, 2011
    Date of Patent: April 16, 2013
    Assignee: Everlight USA, Inc.
    Inventors: Ming-si Wu, Wei-Cheng Tang
  • Patent number: 8361167
    Abstract: The invention provides dye mixtures for application to human hair, the dye mixtures comprising polyphenolic materials, these materials being obtained from botanical sources. Preferably, the botanical source is fruit, especially fruit selected from blackcurrants, blackberries, blueberries, bilberries, cranberries, grapes, chokeberries, Saskatoon berries, sea-buckthorn, mulberries acai, cherries, red cabbage and/or figs. Preferably, the polyphenolic materials comprise anthocyanin compounds which, most preferably, are aglycone anthocyanidins or glycosylated anthocyanins of the formula (III): wherein R1 and R2 are, independently, H, OH or OCH3, R3 is OH (aglycone anthocyanidins) or a glycosyl group (glycosylated anthocyanins), and x is a counter-ion. The invention also provides methods for the preparation of these dye mixtures and for the use of the dye mixtures in the semi-permanent coloration of human hair.
    Type: Grant
    Filed: May 14, 2010
    Date of Patent: January 29, 2013
    Assignee: University of Leeds
    Inventors: Richard Simon Blackburn, Paul Martin Rose, Christopher Mark Rayner
  • Patent number: 8268015
    Abstract: Use of a composition comprising hydrogen peroxide in a cosmetic vehicle allows gentle discoloring of permanently colored, keratinous fibers which have been colored with a specific coloring composition. The coloring composition used for coloring the fibers comprises, in a cosmetic vehicle, a combination of at least one CH-acidic compound with at least one reactive carbonyl compound. The discoloring composition contains preferably between 0% and 15% by weight of hydrogen peroxide and has the effect, in particular in a working time of 5 to 20 minutes even without the use of organic peroxo compounds and in the absence of inorganic persalts, of effective color removal with simultaneous gentle treatment of the fibers.
    Type: Grant
    Filed: June 16, 2011
    Date of Patent: September 18, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Doris Oberkobusch, Wibke Gross, Laura Stephan
  • Patent number: 8268014
    Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) ant least one dye selected from the compounds of formulae (2); (3) and (4); wherein D is the radical of a diazo component of the formula (2a); (2b); (2c); (2d); (2f); (2g) or (2h). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: September 18, 2012
    Assignee: BASF SE Ludwigshafen
    Inventor: Beate Fröhling
  • Patent number: 8257448
    Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) a least one dye selected from the compounds of formulae (2) and (3), wherein D is the radical of a diazo component of the formula (2a) and (c) a quaternary ammonium salt selected from (c1) quaternary ammonium salts of the formula (4); (c2) imidazolium salts of the formula (5) and (c3) quaternary diammonium salts of the formula (6). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: September 4, 2012
    Assignee: BASF SE
    Inventor: Beate Fröhling
  • Patent number: 7896931
    Abstract: The present invention relates to a hair dye composition containing a dissociative azo dye which has high dyeing power, is capable of imparting a vivid color to the hair firmly, has excellent fastness to light, shampooing, sweat, friction, and heat, and fades less with the passage of time because the dye is stable against an alkali agent or an oxidizing agent and does not decompose during hair dyeing; and a hair dyeing method using the hair dye composition.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: March 1, 2011
    Assignees: Kao Corporation, FUJIFILM Corporation
    Inventors: Masakazu Yamaguchi, Osamu Takiguchi, Masaaki Tsukase, Yasuhiro Ishiwata
  • Patent number: 7892294
    Abstract: Provided herein is a method for dyeing keratin fibers, comprising applying to the keratin fibers, at least one composition comprising at least one compound chosen from compounds of leuco type of formula (I), dyes of azomethine type containing a pyrazolopyridine unit of formula (II) corresponding to the compounds of formula (I), mesomeric forms, isomers and tautomers thereof, and also acid-addition salts thereof and solvates thereof:
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: February 22, 2011
    Assignee: L'oreal S.A.
    Inventors: Aziz Fadli, Stéphane Blais
  • Patent number: 7887601
    Abstract: Disclosed herein is at least one compound chosen from compounds of leuco type of formula (I), dyes of azomethine type comprising a pyrazolopyridine unit of formula (II) corresponding to the compounds of formula (I), mesomeric forms, isomeric and tautomeric forms thereof, acid-addition salts thereof and solvates thereof:
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: February 15, 2011
    Assignee: L'Oreal S.A.
    Inventors: Aziz Fadli, Stéphane Blais
  • Patent number: 7658770
    Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: February 9, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
  • Patent number: 7658771
    Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: February 9, 2010
    Assignee: The Procter & Gable Company
    Inventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
  • Patent number: 7655052
    Abstract: Disclosed herein is the use, in the coloring of keratinous fibers, for example human keratinous fibers, such as the hair, of a composition comprising at least one compound chosen from the compounds of formula (I) comprising a cyclic group G including a ring H capable of opening, the dyes corresponding to the compounds of formula (I) wherein the ring H is open and the addition salts thereof: and a method for treating keratinous fibers employing this composition.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: February 2, 2010
    Assignee: L'Oreal S.A.
    Inventors: Alain Lagrange, Frédéric Guerin
  • Patent number: 7641703
    Abstract: Disclosed herein is the use, in the coloring of keratinous fibers, such as human keratinous fibers, such as the hair, of a composition comprising at least one compound chosen from the compounds of formula (I) comprising a cyclic group G including a ring H capable of opening, the dyes corresponding to the compounds of formula (I) wherein the ring H is open, and the addition salts thereof: and a method for treating keratinous fibers employing this composition.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: January 5, 2010
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Guerin, Alain Lagrange
  • Patent number: 7544216
    Abstract: This invention relates to unsubstituted and polymeric leuco colorants for use as consumer product additives to indicate a product function by color change, to make attractive or distinctive visual effects, or to provide latent or delayed color generation. The colorants may be present in a stable, colorless state and may be transformed to an intense colored state upon exposure to certain physical or chemical changes. Alternatively, the colorants may be transformed from one color to another color upon exposure to certain physical or chemical changes. The colored form of the unsubstituted or polymeric leuco colorant may be transient, since the colorant can revert back to its colorless form or its original color after the physical or chemical activation has been removed or changed. Polymeric leuco colorants are typically comprised of at least two components: at least one leuco chromophore component and at least one polymeric component.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: June 9, 2009
    Assignee: Milliken & Company
    Inventors: Eduardo Torres, Patrick D Moore, Joe Clark
  • Patent number: 7534273
    Abstract: The present application relates to cationic pyrazolone dyes of the general formula (I), and to coloring agents for keratin fibers comprising these dyes.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: May 19, 2009
    Assignee: Wella AG
    Inventors: Markus Speckbacher, Hans-Juergen Braun
  • Patent number: 7531008
    Abstract: The present disclosure relates to the use of a direct dye as an agent for lightening keratin fibers, such as, for example, human keratin fibers, and/or as an agent for coloring the said fibers. The disclosure also relates to a composition comprising, in a cosmetically acceptable medium, at least the direct dye. The disclosure also relates to a process for treating keratin fibers, including human keratin fibers, using the abovementioned composition, and also to a device comprising it. Finally, the disclosure relates to the use of the composition according to the disclosure as a coloring agent and/or as an optical lightening agent for the fibers.
    Type: Grant
    Filed: November 30, 2006
    Date of Patent: May 12, 2009
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7527654
    Abstract: The present invention relates to a process for dyeing keratin fibers, in particular human keratin fibers such as the hair, using a dye composition comprising at least one dye of styryl or imine type in the presence of a revealing composition comprising at least one optionally substituted (hetero) aromatic compound of weak acid type. The present invention makes it possible in particular to obtain a chromatic and fast coloration of keratin fibers, which is visible even on dark hair without prior lightening. The invention also makes it possible to obtain a coloration which, under certain conditions, does not stain.
    Type: Grant
    Filed: October 12, 2007
    Date of Patent: May 5, 2009
    Assignee: L'Oreal S.A.
    Inventor: Grégory Plos
  • Patent number: 7513916
    Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: April 7, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
  • Patent number: 7513917
    Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: April 7, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
  • Patent number: 7491245
    Abstract: Compositions for the oxidative dyeing of keratin fibers, comprising a medium suitable for dyeing and one or more tricyclic fused 6-5-6 heteroaromatic keratin dyeing compounds having one heteroatom. A method for oxidative dyeing of keratin fibers, comprising applying such compositions in the presence of an oxidizing agent, for a period sufficient to develop the desired coloration.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: February 17, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Robert Wayne Glenn, Jr., Anthony McMeekin, Mu'Ill Lim, John Michael Gardlik, Stevan David Jones, Bryan Patrick Murphy
  • Patent number: 7452385
    Abstract: The agent for coloring keratin fibers, especially human hair, contains at least one common cosmetic additive; an oxidant, such as hydrogen peroxide; and at least one naphthalene derivative of formula (I): wherein A1 and A2 are different from each other and, independently of each other, each denote a partial structure of formula (II), (IIIa), (IIIb), (IV), (V), or (VI): E is O or S; Y is N or a quaternary nitrogen atom substituted with a C1-C6-alkyl group, a C2-C4-hydroxyalkyl group, or a C4-C6-polyhydroxyalkyl group. New naphthalene derivatives are also described.
    Type: Grant
    Filed: October 20, 2004
    Date of Patent: November 18, 2008
    Assignee: Wella AG
    Inventors: Markus Speckbacher, Hans-Juergen Braun
  • Patent number: 7399320
    Abstract: The invention concerns the use as direct dyeing agent of at least one tetra-azapentamethine compound, a dyeing composition comprising at least such a compound, as well as a method for dyeing keratinous fibers, in particular human keratinous fibers and more particularly hair, which consists in applying at least one composition comprising such a compound. The composition also concerns tetra-azapentamethine compounds of formula (I). The invention further concerns a method for bleaching such compounds, as well as bleaching keratinous fibers previously dyed therewith.
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: July 15, 2008
    Assignee: L'Oreal
    Inventors: Herve Burgaud, Herve David, Rui Pereira, Beatrice Belcour-Castro
  • Patent number: 7393366
    Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one zwitterionic azo dye of the general formula (I) where R1 is an alkylsulfonate radical of the formula (II),
    Type: Grant
    Filed: January 27, 2006
    Date of Patent: July 1, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Cécile Pasquier, Eric Tinguely, Otto Göttel, Hans-Jürgen Braun
  • Patent number: 7331997
    Abstract: Compositions for the oxidative dyeing of keratin fibers, comprising a medium suitable for dyeing and one or more tricyclic fused 6-5-6 heteroaromatic keratin dyeing compounds having one heteroatom. A method for oxidative dyeing of keratin fibers, comprising applying such compositions in the presence of an oxidizing agent, for a period sufficient to develop the desired coloration.
    Type: Grant
    Filed: April 6, 2005
    Date of Patent: February 19, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Robert Wayne Glenn, Jr., Anthony McMeekin, Mu'Ill Lim, John Michael Gardlik, Stevan David Jones, Bryan Patrick Murphy
  • Patent number: 7326259
    Abstract: A subject-matter of the present patent application is the use, as direct dye in dyeing compositions for keratinous fibres, in particular human keratinous fibres, such as the hair, or for the manufacture of such compositions, of a specific polycationic compound.
    Type: Grant
    Filed: June 22, 2005
    Date of Patent: February 5, 2008
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7311736
    Abstract: The invention concerns the use as direct dyeing agent of at least one tetra-azapentamethine compound, a dyeing composition comprising at least such a compound, as well as a method for dyeing keratinous fibers, in particular human keratinous fibers and more particularly hair, which consists in applying at least one composition comprising such a compound. The composition also concerns tetra-azapentamethine compounds of formula (I). The invention further concerns a method for bleaching such compounds, as well as bleaching keratinous fibers previously dyed therewith.
    Type: Grant
    Filed: July 4, 2003
    Date of Patent: December 25, 2007
    Assignee: L'Oreal
    Inventors: Herve Burgaud, Herve David, Rui Pereira, Beatrice Belcour-Castro
  • Patent number: 7300472
    Abstract: The invention relates to agents for coloring fibers containing keratin, in particular, human hair, which comprise selected cationic, CH-acidic heterocycles according to formula I in which A, R1, R2 and X? are as defined in the application, in combination with reactive carbonyl compounds, to the use of this combination in agents for coloring fibers containing keratin, for freshening up the color or nuancing fibers containing keratin which have already been colored, and to a method of coloring fibers containing keratin, in particular, human hair.
    Type: Grant
    Filed: June 19, 2006
    Date of Patent: November 27, 2007
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wibke Gross, Horst Höffkes, Doris Oberkobusch, Sandra Mausberg
  • Patent number: 7288120
    Abstract: The present disclosure relates to processes for synthesizing tetraazapentamethine compounds that comprise reacting at least one compound of azine type with at least one oxidizing agent. The disclosure also relates to processes for dyeing keratin fibers, for example human keratin fibers, that comprise using such synthetic processes.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: October 30, 2007
    Assignee: L'Oreal S.A.
    Inventors: Rui Pereira, Hervé Burgaud
  • Patent number: 7241319
    Abstract: Disclosed herein is a dye composition for dyeing human keratin fibers, such as the hair, comprising a direct polycationic dye of formula (I) below: Col-Z-Col??(I) in which Col, which may be identical or different, is a noncationic dye chosen from azo dyes, methine dyes, azomethine dyes, phenothiazine dyes, triarylmethene dyes, xanthene dyes, phenanthridine dyes, and phthalocyanin dyes; and Z is chosen from linear and branched, saturated and unsaturated C1-C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least two cationic charges, and also to processes for dyeing human keratin fiber using said composition, to the use of the dyes of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: July 10, 2007
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7220286
    Abstract: The present invention relates to cationic direct dyes of formula (I) below: in which W1 represents —NR8— or —O—; X1 represents N; CR9; R1 and R2, which may be identical or different, represent a hydrocarbon chain; R3 and R4, which may be identical or different, represent a hydrogen atom, a halogen atom, a nitro group, a cyano group or a hydrocarbon chain; R5, R6, R7, R8 and R9, which may be identical or different, represent a hydrogen atom or a hydrocarbon chain; L represents a specific bridging group and X represents a cosmetically acceptable organic or mineral anion. It likewise relates to a dye composition comprising, in a medium suitable for dyeing human keratin fibers, such a dye, a process using it, and also a multicompartment device.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: May 22, 2007
    Assignee: L'Oreal SA
    Inventor: Andrew Greaves
  • Patent number: 7204857
    Abstract: The present invention relates to the use, for dyeing keratin fibres, of at least one specific compound containing active methylene and of at least one compound chosen from an aldehyde, a ketone, a quinone and a diiminoisoindoline or 3-aminoisoindolone derivative, which makes it possible to obtain, by reaction without an oxidizing agent, a coloration of the said keratin fibres.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: April 17, 2007
    Assignee: L'Oreal S.A.
    Inventors: Hervé Andrean, Alain Lagrange
  • Patent number: 7186276
    Abstract: Disclosed herein is a dye composition for dyeing human keratin fibers, such as the hair, comprising a direct polycationic dye of formula (I) below: Col-Z-Col??(I) in which Col, which may be identical or different, is a monocationic dye chosen from azo dyes, methine dyes, azomethine dyes, and phenothiazine dyes; and Z is chosen from linear and branched, saturated and unsaturated C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least two cationic charges, and also to processes for dyeing human keratin fibers using said composition, to the use of the dyes of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: March 6, 2007
    Assignee: L'Oreal
    Inventor: Alain Lagrange
  • Patent number: 7169194
    Abstract: A dye composition for dyeing human keratin fibers, such as hair, comprising at least one direct tricationic dye of formula (I) below: Col—Z—Col ??(I) wherein: Col, which may be identical or different, is a monocationic dye chosen from azo dyes, cyanomethine dyes and phenothiazine dyes and Z is chosen from linear and branched, saturated and unsaturated C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing a cationic charge. Also processes for dyeing human keratin fibers using the dye composition, to the use of the at least one direct tricationic dye of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: January 30, 2007
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7101406
    Abstract: The subject of the present application is a dyeing composition for dyeing keratinous fibers, in particular human keratinous fibres such as hair, comprising, in an appropriate dyeing medium, at least one cationic tertiary para-phenylenediamine containing a pyrrolidine ring, and at least one cationic direct dye comprising at least one heterocyclic group. The subject of the invention is also the dyeing method using this composition and the corresponding devices.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: September 5, 2006
    Assignee: L'Oreal
    Inventors: Jean Cotteret, Alain Lagrange
  • Patent number: 7094262
    Abstract: A dye composition for dyeing human keratin fibres, such as hair, comprising at least one dissymmetrical polycationic direct dye of formula (I) below: Col1-Z-Col2??(I) wherein: Col1 and Col2, which differ in structure, are chosen from tazo dyes, methine dyes, azomethine dyes, phenothiazine dyes, triarylmethane dyes, xanthene dyes, phenanthridine dyes and phthalocyanin dyes and Z is chosen from linear and branched, saturated, unsaturated and cyclic C1–C20 hydrocarbon-based groups comprising at least one nitrogen atom and bearing at least one cationic charge; and also to processes for dyeing human keratin fibres using the composition, to the use of the at least one dissymmetrical polycationic direct dye of formula (I) as direct dyes, and to multi-compartment devices.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: August 22, 2006
    Assignee: L'Oreal S.A.
    Inventor: Alain Lagrange
  • Patent number: 7060110
    Abstract: The invention concerns a novel dyeing composition for dying keratinous fibers, in particular human hair, comprising a dicationic monoazo dye, and the dyeing method using said composition and the novel compounds of formulae (I) or (II).
    Type: Grant
    Filed: April 3, 2002
    Date of Patent: June 13, 2006
    Assignee: L'Oreal
    Inventors: Laurent Vidal, Hervé David
  • Patent number: 6997961
    Abstract: Dyeing agents for keratin fibers, containing N-heteroarylmethyl-m-phenylenediamine derivatives of general formula (I) or the salts thereof and new N-heteroarylmethyl-m-phenylenediamine derivatives.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: February 14, 2006
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6916345
    Abstract: Dye compositions for dyeing keratin fibers, comprising at least one oxidation base and at least one coupler chosen from 6-alkoxy-2,3-diaminopyridine derivatives of formula (I) as defined herein and the addition salts thereof; the use of the compositions for dyeing keratin fibers; and the dyeing processes using the compositions; as well as at least one entity chosen from novel 6-alkoxy-2,3-diaminopyridine compounds and their addition salts thereof that are useful as couplers.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: July 12, 2005
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 6908492
    Abstract: The new 7-nitro-2,1,3-benzoxadiazole compounds and 7-nitro-2,1,3-benzthiadiazole compounds of formula (I) are: Dyeing agents for keratin fibers, containing the compounds of formula (I), and methods of dyeing hair with these dyeing agents are described.
    Type: Grant
    Filed: January 7, 2004
    Date of Patent: June 21, 2005
    Assignee: Wella Aktiengesellschaft
    Inventors: Gisela Umbricht, Hans-Juergen Braun, Sylviane Oberson, Catherine Mueller
  • Patent number: 6887281
    Abstract: The new N-heteroarylmethyl-p-phenylenediamine derivatives have the general formula (I), Oxidation hair dyeing agents are described based on a combination of developing and coupling substance, which contain at least one N-heteroarylmethyl-phenylenediamine derivative of the formula (I), or a physiologically tolerated salt thereof.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: May 3, 2005
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6878169
    Abstract: Provided is a hair dye composition containing a direct dye (1): [wherein, R1, R2, R3, R4, R5 and R6 each represents a C1-6 alkyl group; R7 and R8 each represents a hydroxy group, a C1-6 alkyl group, a C1-6 alkoxy group, an amino group or alkylamino groups; R9 represents a hydrogen atom or a C1-6 alkyl group; and X? represents an anion]. This hair dye composition undergoes a small change in color tone even after storage because it contains the direct dye (1) which has high stability against any one of an alkali agent, oxidizing agent and reducing agent, and at the same time, has markedly high hair dyeing power and exhibits excellent light resistance, washing resistance, perspiration resistance, friction resistance and heat resistance.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: April 12, 2005
    Assignee: Kao Corporation
    Inventor: Kenichi Matsunaga
  • Patent number: 6824570
    Abstract: A dye composition for dyeing human keratin fibers, such as hair, comprising at least one monocationic monoazo dye of formula (I) W1—W2—N═N—W3, a dyeing process using the composition and certain novel compounds of formula (I).
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: November 30, 2004
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 6814762
    Abstract: Provided is a hair dye composition containing a direct dye (1) or (2): [wherein, R1, R2, R3, R4, R5 and R6 each represents a C1-6 alkyl group; R7 and R8 each represents a hydrogen atom, a hydroxy group, a C1-6 alkyl group, a C1-6 alkoxy group, an amino group or alkylamino group; R9 represents a hydrogen atom or a C1-6 alkyl group; and X− represents an anion]. This hair dye composition undergoes a small change in color tone even after storage because it contains the direct dye (1) or (2) which has high stability against any one of an alkali agent, oxidizing agent and reducing agent, and at the same time, has markedly high hair dyeing power and exhibits excellent light resistance, washing resistance, perspiration resistance, friction resistance and heat resistance.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: November 9, 2004
    Assignee: Kao Corporation
    Inventor: Kenichi Matsunaga
  • Patent number: 6755872
    Abstract: A coloring composition and a method of coloring keratin-containing fibers are provided. The coloring composition contains a mixture of and/or a reaction product of at least one heteroaromatic aldehyde or ketone and at least one aromatic and/or heteroaromatic nitroamine. In the method of the present invention, the heteroaromatic aldehyde or ketone and the nitroamine may be applied to keratin-containing fibers simultaneously or successively.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: June 29, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hinrich Moeller, Doris Oberkobusch, Horst Hoeffkes
  • Patent number: 6660046
    Abstract: The invention concerns novel pyrazole derivatives comprising at least a cationic group Z, Z being selected among the quaternized aliphatic chains, aliphatic chains comprising at least a saturated quaternized cycle, and aliphatic chains comprising at least an unsaturated quaternized cycle, their use as oxidation base for dyeing keratin fibres, dyeing compositions containing them, and dyeing methods using them.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: December 9, 2003
    Assignee: L'Oreal S.A.
    Inventors: Eric Terranova, Alain Lagrange
  • Patent number: 6201126
    Abstract: Compounds of the formula (I) in which A represents N or a cyanomethylene radical, B represents S, O or NH and R1, R2, R3 and x have the meaning given in the description, are highly suitable for dyeing and printing high-molecular-weight materials, in particular automotive cover fabrics.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: March 13, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventor: Manfred Lorenz
  • Patent number: 6063136
    Abstract: The present invention relates to a composition and a dyeing process for the dyeing of keratinous fibers, in particular of human hair, having,as coupler, at least one compound of formula: ##STR1## where Z.sub.a and Z.sub.b, which are different from one another, represent an oxygen or nitrogen atom,and at least one oxidation base.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: May 16, 2000
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Gerard Malle
  • Patent number: 5601621
    Abstract: Fiber materials can be modified by applying heterocycloaliphatic compounds containing at least one primary, secondary or tertiary amino group or quaternary ammonium group, the hetero portion of which in the ring is a carbonic ester radical of the formula --O--CO--O-- or a carbamic acid radical of the formula --O--CO--NH--, in aqueous alkaline solution by exposing the fiber material to these compounds at a temperature of between 60.degree. and 230.degree. C. The characteristic of the modified fiber material is that it can be dyed with dye solutions of water-soluble, anionic textile dyes which are low in electrolytes or entirely free of electrolytes and/or are low in alkali or entirely free of alkali. The advantage of a dyeing process carried out in this manner, in particular for fiber-reactive dyes, is that fixation of the dyes under alkaline conditions is unnecessary.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: February 11, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Werner H. Russ, Thomas Riehm
  • Patent number: 5578088
    Abstract: Process for dyeing aminated cellulose/polyester blend fabric with fiber-reactive disperse dyestuffs Fiber materials comprising cellulose fibers or a mixture of cellulose and polyester fibers are dyed by first modifying the fiber material with one or more compounds containing amino groups and then dyeing the modified fiber material with a fiber-reactive disperse dyestuff in supercritical CO.sub.2.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: November 26, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Andreas Schrell, Werner H. Russ