Carboxylic Acid Esters, Cyanates, Isocyanates, Or Sulfur Analogues Thereof Patents (Class 8/582)
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Patent number: 9028563Abstract: The present invention relates to a hair dye composition, and more particularly, to a foam-type hair dye composition comprising: a first agent including a dye and an alkaline agent and a second agent including an oxidant; and a nonionic viscosity increasing agent of a PEG-aliphatic acid ester or a PPG-aliphatic acid ester in one or both of the first agent and the second agent, thereby largely improving dyeing properties without dripping after the composition is coated on hair.Type: GrantFiled: November 16, 2012Date of Patent: May 12, 2015Assignee: Amorepacific CorporationInventors: Jae Jung Park, Hyo Seung Moon, Jong Hyub Kim, Wang Gi Kim, Sang Hoon Kim, Jang Won Choi
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Patent number: 8858652Abstract: The specification describes an agent for coloring keratinic fibers. The agent includes, in a cosmetically acceptable carrier, at least one oxidation dye precursor, a precursor of a nature-analogous dye, a substantive dye, or combinations thereof. The agent also includes a carrier base combination. The carrier base combination includes at least one fatty substance of formula (I), in which R and R? in each case mutually independently denote a saturated or unsaturated C6-C22 alkyl chain; at least one nonionic surfactant of formula (II),R1-O-[G]p(II) in which R1 denotes a saturated or unsaturated C6-C22 alkyl chain, G denotes a sugar residue with 5 or 6 carbon atoms and p denotes a number from 1 to 10; and at least one cationic polymer, at least one amphoteric polymer, or combinations thereof.Type: GrantFiled: March 14, 2014Date of Patent: October 14, 2014Assignee: Henkel AG & Co. KGaAInventors: Christiane Witte, Stephan Schwartz
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Publication number: 20130139328Abstract: The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.Type: ApplicationFiled: August 15, 2011Publication date: June 6, 2013Applicant: BASF SEInventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
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Patent number: 8388698Abstract: The present invention is drawn to a composition and method for dyeing keratinous substrates containing: (a) at least one polyamine compound comprising at least three amino groups; (b) at least one nonionic surfactant; (c) at least one compound chosen from an alkyl ether carboxylic acid, an alkyl ether carboxylate, a fatty acid having from about 6 to about 40 carbon atoms, and mixtures thereof; (d) at least one dye chosen from oxidation dye precursors and direct dyes. The compositions of the present invention may optionally contain at least one thickening agent, at least one alkaline agent, at least one fatty substance, at least one salt, and at least one oxidizing agent.Type: GrantFiled: October 19, 2011Date of Patent: March 5, 2013Assignee: L'OrealInventors: Sawa Hashimoto, Nghi Van Nguyen, Tan Siliu
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Publication number: 20110277249Abstract: Colored high-strength fibers of ultra-high-molecular-weight polyolefins and methods of dyeing the high-strength fibers are disclosed herein.Type: ApplicationFiled: May 14, 2010Publication date: November 17, 2011Inventors: Ferass Abuzaina, Ali Irfan
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Patent number: 7909889Abstract: The present invention provides a method of lightening and/or coloring human keratin fibers that employs: at least one substantially anhydrous or aqueous composition (A) comprising at least one fat free of carboxylic acid groups and at least one surfactant, at least one substantially anhydrous or aqueous composition (B) comprising at least one specific aminotrialkoxysilane or aminotrialkenyloxysilane compounds, and at least one aqueous composition (C) comprising at least one oxidizing agent. In addition, the present invention provides a three-compartment device appropriate for the implementation of this method.Type: GrantFiled: April 29, 2010Date of Patent: March 22, 2011Assignee: L'Oreal S.A.Inventors: Delphine Charrier, Marie-Pascale Audousset, Leila Hercouet
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Patent number: 7905927Abstract: The present disclosure provides a method of lightening and/or coloring human keratin fibers comprising applying to the keratin fibers * at least one first composition comprising at least one fat, at least one nonionic surfactant, at least one specific aminotrialkoxy silane or aminotrialkenyloxy silane compound, and applying * at least one second composition comprising at least one oxidizing agent. It also provides a multiple-compartment device in which at least one compartment comprises the above-mentioned at least one first composition and at least one other compartment comprises the at least one oxidizing composition.Type: GrantFiled: April 29, 2010Date of Patent: March 15, 2011Assignee: L'Oreal, SAInventor: Leïla Hercouet
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Patent number: 7776104Abstract: A ready-to-use oxidizing composition for treating keratin materials, such as human keratin fibers, in particular the hair, comprising, in a cosmetically acceptable medium: (a) at least one oxidizing agent, (b) at least 30% by weight of at least one water-insoluble oxygenated organic no-dyeing particular compound relative to the total weight of the said composition, and (c) at least 20% by weight of water relative to the total weight of the said composition, and to processes for bleaching, stripping, dyeing, lightening or permanently reshaping human keratin fibers and in particular the hair, and also to the use of the said composition for bleaching, stripping, dyeing, lightening and permanently reshaping human keratin fibers and in particular the hair.Type: GrantFiled: August 24, 2006Date of Patent: August 17, 2010Assignee: L'Oreal S.A.Inventors: Sylvain Kravtchenko, Claude Dubief
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Patent number: 7728067Abstract: An adjuvant composition comprising (A) a C1-C2carboxylic acid ester of a polyhydroxy compound containing from 2 to 20 hydroxyl groups and (B) an N-heterocyclic compound having a pKa, value of from 6 to 8 is storage-stable and suitable as an acid donor in the dyeing of polyamides.Type: GrantFiled: April 25, 2005Date of Patent: June 1, 2010Assignee: Huntsman International LLCInventors: Hans-Jorg Peter, Claudius Brinkmann
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Patent number: 7699897Abstract: The disclosure relates to compositions and methods of using the compositions to color hair. The composition contains at least one polyamine, at least one acid, at least one water-insoluble ingredient, at least one hair colorant, solvent and optionally at least one auxiliary ingredient. The methods for coloring involve contacting hair with the composition of the disclosure.Type: GrantFiled: September 14, 2007Date of Patent: April 20, 2010Assignee: L'OrealInventors: Nghi Van Nguyen, David W. Cannell, Sawa Hashimoto, Cynthia Espino
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Patent number: 7651533Abstract: The present disclosure relates to a dye composition comprising at least one dye, at least one nonionic surfactant, at least one anionic surfactant, at least one fatty alcohol and at least one non-ethoxylated fatty acid ester; the weight ratio of the total amount of fatty alcohols to the total amount of nonionic and anionic surfactants being greater than 0.5 and the water content comprising at least 55% by weight. The disclosure similarly relates to a process for dyeing keratin fibers, for example human keratin fibers, using such a composition, and also to a multi-compartment device comprising the dye composition in the first compartment, and an oxidizing composition in the second compartment.Type: GrantFiled: March 31, 2006Date of Patent: January 26, 2010Inventor: Frédéric Legrand
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Patent number: 7578854Abstract: The present disclosure relates to a dye composition comprising at least one dye, at least one nonionic surfactant, at least one cationic associative polymer, at least one fatty alcohol and at least one fatty acid ester, wherein the fatty alcohol/nonionic surfactant weight ratio is greater than 0.5 and water is present in the dye composition in an amount greater than or equal to 55% by weight. The disclosure also relates to a process for dyeing keratin fibers using such a composition, and also to a multi-compartment device or kit separately containing the dye composition and an oxidizing composition.Type: GrantFiled: March 31, 2006Date of Patent: August 25, 2009Assignee: L'Oreal S.A.Inventor: Frédéric Legrand
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Patent number: 7575605Abstract: Disclosed is a dye composition comprising at least one dye, at least one fatty alcohol, at least one fatty acid ester of glycerol, at least one ether and at least one nonionic and/or anionic surfactant; wherein the dye composition comprises water in an amount of at least 55% by weight, relative to the total weight of the composition. Additionally disclosed is a process for dyeing keratin fibers using such a composition, and also a multi-compartment device comprising the dye composition and an oxidizing composition.Type: GrantFiled: March 31, 2006Date of Patent: August 18, 2009Assignee: L'Oreal S.A.Inventor: Frédéric Legrand
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Publication number: 20080271260Abstract: An adjuvant composition comprising (A) a C1-C2carboxylic acid ester of a polyhydroxy compound containing from 2 to 20 hydroxyl groups and (B) an N-heterocyclic compound having a pKa, value of from 6 to 8 is storage-stable and suitable as an acid donor in the dyeing of polyamides.Type: ApplicationFiled: April 25, 2005Publication date: November 6, 2008Inventors: Hans-Jorg Peter, Claudius Brinkmann
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Patent number: 7442214Abstract: The present disclosure relates to a dye composition comprising at least one dye, at least one fatty alcohol, at least one fatty acid ester, at least one surfactant chosen from non-ionic surfactants and anionic surfactants and at least one non-ionic associative polymer, wherein water is present in the dye composition in an amount greater than or equal to 55% by weight. The present disclosure further relates to a process for dyeing keratin fibers, including human keratin fibers, using such a composition and also to a multi-compartment kit separately comprising the dye composition and an oxidizing composition.Type: GrantFiled: March 31, 2006Date of Patent: October 28, 2008Assignee: L'Oreal S.A.Inventor: Frédéric Legrand
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Patent number: 7399318Abstract: The present invention relates to a stable composition for hair dye, which comprises at least one compound selected from dihydrocitronellyl nitrile, 2,2,6-trimethylcyclohexane carboxylic acid ethyl ester, 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, 2,2,6-trimethylcyclohexyl-3-hexanol, 1-(2-methyl-2-propenyloxy)-2,2,4-trimethylpentan-3-ol, thioglycerin, dibutyl sulfide, thiogeraniol, thiocineol, 2-methyl-4-propyl-1,3-oxathian, 4-methoxy-2-methyl-2-butanethiol and the like. The stable composition for hair dye has a superior effect in masking a malodor originated from components such as ammonia formulated in hair dye composition such as composition for hair dye, and is also stable in an alkaline product and an acidic solution product.Type: GrantFiled: March 21, 2006Date of Patent: July 15, 2008Assignee: Takasago International CorporationInventors: Junko Nagano, Kazuki Sugiyama, Yasuko Matsumura, Kunihide Hoshino, Takashi Aida
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Patent number: 7297167Abstract: The invention relates to a composition useful for the oxidation dyeing of keratin fibres, in particular of human keratin fibres and more particularly the hair, containing, in a medium that is suitable for dyeing, at least one oxidation dye, wherein it also comprises at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, at least one mono- or polyglycerolated surfactant and at least one fatty alcohol (C8-C30) comprising at least one unsaturation. The invention also relates to the dyeing devices and processes using the said composition.Type: GrantFiled: December 20, 2002Date of Patent: November 20, 2007Assignee: L'OrealInventors: Patricia Desenne, Cecile Bebot, Florence Laurent
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Patent number: 7223294Abstract: The invention relates to a composition for the oxidation dyeing of keratin fibres, in particular of human keratin fibres and more particularly the hair, containing, in a medium that is suitable for dyeing, at least one oxidation dye, wherein it also contains at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, at least one associative polymer and at least one fatty alcohol (C8–C30) comprising at least one unsaturation. The invention also relates to the dyeing devices and processes using the said composition.Type: GrantFiled: December 20, 2002Date of Patent: May 29, 2007Assignee: L'OrealInventors: Patricia Desenne, Cecile Bebot, Florence Laurent
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Patent number: 7204858Abstract: The invention relates to a composition useful for the oxidation dyeing of keratin fibres, in particular of human keratin fibres and more particularly the hair, comprising, preferably in a medium that is suitable for dyeing, at least one oxidation dye, wherein it also comprises at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, and at least one quaternized cellulose comprising at least one fatty chain. The invention also relates to the dyeing devices and processes using the said composition.Type: GrantFiled: December 20, 2002Date of Patent: April 17, 2007Assignee: L'OrealInventors: Patricia Desenne, Cecile Bebot, Florence Laurent
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Patent number: 7156884Abstract: Pro-dyes of direct dyes having an enzymatically-labile functionality, e.g. glutaramide derivatives of direct dyes of formula (I) or their physiologically acceptable salts, are described, as well as compositions for dyeing keratinous fibers containing these pro-dyes, as well as compositions for dyeing keratinous fibers containing a combination of at least one pro-dye and at least one enzyme capable of cleaving the glutaramide functionality in the pro-dye. A method for dyeing keratinous fibers with the aforementioned dyeing compositions is also described.Type: GrantFiled: February 20, 2003Date of Patent: January 2, 2007Assignee: Wella AGInventors: David Rozzell, Juergen Allwohn, Laurent Chassot, Cècile Pasquier, Guido Sauter, Vèronique Buclin-Charrière
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Patent number: 7115147Abstract: The invention relates to a composition for the oxidation dyeing of keratin fibers, preferably of human keratin fibers and more particularly the hair, containing, preferably in a medium that is suitable for dyeing, at least one oxidation dye, wherein it also contains at least one polyoxyalkylenated carboxylic acid ether or a salt thereof, at least one mono- or polyglycerolated surfactant and at least one nonionic oxyalkylenated surfactant. The invention also relates to the dyeing devices and processes using the composition.Type: GrantFiled: December 20, 2002Date of Patent: October 3, 2006Assignee: L'OrealInventors: Patricia Desenne, Cecile Bebot, Florence Laurent
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Patent number: 6821302Abstract: Compositions and methods for achieving permanent hair color change which composition includes a mixture of: a) a composition A which comprises: i) at least one oxidation hair dye precursor; ii) a metal cyanate selected from the group consisting of KOCN, NaOCN, LiOCN, Ca(OCN)2, Mg(OCN)2, Zn(OCN)2 and mixtures thereof which comprises a cyanate ion at about 0.1 to about 2.5%; and iii) an alkalizing agent; b) and a composition B which comprises: i) an oxidizing compound; wherein the mixture of composition A and composition B has a pH of about 7 to about 11; are described.Type: GrantFiled: November 1, 2002Date of Patent: November 23, 2004Assignee: Unilever Home & Personal Care USA, Division of Conopco, Inc.Inventors: Van Au, Stephen Alan Madison, John Brian Bartolone
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Patent number: 6740130Abstract: Hair-colorant compositions containing (a) from 0.2 to 25% by weight of an alkoxylated carboxylic acid ester; (b) from 0.5 to 25% by weight of a fatty acid partial glyceride; and (c) from 0.1 to 15% by weight of a hair dye; wherein all percentages by weight are based on the total composition, are disclosed. Methods of reducing cloudiness in hair-colorant compositions by combining a hair dye and a mixture of an alkoxylated carboxylic acid ester and a fatty acid partial glyceride are also disclosed.Type: GrantFiled: September 5, 2002Date of Patent: May 25, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Celia Sander, Anke Eggers, Josef Koester, Werner Seipel, Hermann Hensen
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Patent number: 6623532Abstract: The present invention provides a method of applying ink containing dyes to fabric composed of synthetic and cellulose fibers using an ink-jet system to print the fabric with high color shade depth and brilliancy and ink-jet printed goods obtained by the ink-jet printing method. The fabric composed of cellulose and synthetic fibers is treated with an acidic aqueous dispersion containing cellulose reactive compound, water-soluble polymer and non-water-soluble inactive organic compound with a melting point of 40° C.-150° C. and the fabric is dried before its ink-jet printing with reactive and disperse dyes.Type: GrantFiled: September 5, 2001Date of Patent: September 23, 2003Assignee: Seiren Co., Ltd.Inventors: Shungaku Nakamura, Ayumi Yamazaki
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Patent number: 6576025Abstract: The instant invention is directed to dyed fabric blends of aramid fibers and flame resistant (FR) cellulosic fibers, which retains a substantial amount of its strength and durability after dyeing. The dyeing process comprises the steps of: providing a fabric comprising a blend of aramid fibers and cellulosic fibers, dyeing the cellulosic fibers of the fabric, and dyeing the aramid fibers of the fabric. Dyeing of the aramid fibers being preformed with low agitation, an aryl ester carrier, and, preferably, at a temperature between 100-110° C.Type: GrantFiled: February 1, 2001Date of Patent: June 10, 2003Assignee: Difco Performance Fabrics, Inc.Inventor: Francois Lapierre
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Patent number: 6443996Abstract: A decorative dye colorant for use on various types of natural stone, such as granite, marble, limestone, and soapstone. The colorant is formed by mixing a solvent soluble dye with a suitable solvent, such as a ketone or an alcohol to form a dye solution. The solvent enables the dye to penetrate easily into the pores or openings located in the surface of the stone to color the stone so as not to mar the appearance of the surface of the stone. The dye is resistant to removal or discoloration, but may be removed by extended contact of certain chemicals with the dye. To permanently prevent the removal of the dye, a sealer is applied over the dye to prevent any such materials from contacting the dye. The sealer is comprised of an aliphatic urethane mixed with the alcohol xylol that also includes ultraviolet light resistant properties to prevent the dye from fading over time.Type: GrantFiled: April 16, 1999Date of Patent: September 3, 2002Inventors: Maurice W. Mihelich, Diane M. Mihelich
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Patent number: 6258928Abstract: A process for improving characteristics such as, whiteness retention, degradation, and dyeability of a polyamide by contacting the polyamide with thiocyanate. A polyamide produced by the process has improved dyed color depth, dyed color uniformity, hue, elimination of light dyeing ends, protection of dye sites from degradation, protection from UV degradation, reduced yellowing or oxidation, and/or resistance to loss of dyeability.Type: GrantFiled: April 6, 2000Date of Patent: July 10, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Bennett Ray Baird, David Malcolm Lewis, Kamleshkumar Chunilal Patel
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Patent number: 6200355Abstract: Methods for the deep shade dyeing of melamine fiber-containing textile articles include bringing an undyed melamine fiber-containing textile article into contact with a dye bath containing a dyestuff and an acid donor at a pH of greater than about 6.0 and an elevated dyeing temperature greater than about 100° C. for a time sufficient to dye the textile article with minimal loss of melamine fibers due to acid hydrolysis. Most preferably, the textile article or articles to be dyed is placed into the dye bath at ambient temperature, and thereafter the dye bath containing the textile article or articles to be dyed is heated to the elevated dyeing temperature, for example, at a rate of between about 0.5 to about 2.0° C. per minute. Suitable dyes include non-complexed acid dyes or acid dyes complexed with a metal (e.g., iron, cobalt, copper, aluminum or any transition metal). Suitable acid donors include butyrolactones, ethylene glycol monoformates and ethylene glycol diformates.Type: GrantFiled: December 21, 1999Date of Patent: March 13, 2001Assignee: BASF CorporationInventor: Dean R. Gadoury
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Patent number: 6030419Abstract: A process is described for dyeing polyester-containing fibre materials with disperse dyes, which comprises dyeing the polyester-containing fibre materials by a high-temperature dyeing process with a liquor comprising at least one disperse dye and at least one diffusion accelerator selected from the group of the aliphatic glycol ether derivatives.Type: GrantFiled: September 29, 1998Date of Patent: February 29, 2000Assignee: Ciba Specialty Chemicals CorporationInventor: Ulrich Strahm
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Patent number: 5968207Abstract: A process for imparting long-lasting antimicrobial properties to fabrics is disclosed which entails the diffusion of triclosan esters within each individual fiber of a textile. One preferred method is performed in a standard jet dye bath which requires a high range of temperatures to effectively color fabrics. Dyeing in this manner also involves diffusing compounds within individual fibers; thus, this manner of incorporating dyestuffs and colorants within textile fabrics provides a compatible and effective vehicle for simultaneously introducing triclosan esters within such textile fibers, also. A dye bath application is not required, however, as any procedure which allows contact between a triclosan ester derivative and a fabric at a sufficient temperature and for a sufficient time to effectuate diffusion of the ester within each individual fiber of the fabric is also contemplated within this invention.Type: GrantFiled: February 20, 1998Date of Patent: October 19, 1999Assignee: Milliken & CompanyInventor: Shulong Li
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Patent number: 5961669Abstract: A process for dying materials containing natural or synthetic polyamides is disclosed. The process includes immersing the materials to be dyed in a dye bath containing an acid dye. The pH of the dye bath is initially at a level that substantially inhibits the dye from being absorbed by the polymer. In accordance with the present invention, however, an acid producing composition is added to the bath which gradually reduces the pH of the bath and allows for uniform diffusion of the dye into the polymer. The acid producing composition of the present invention is a maleate ester, which, in one embodiment, is the reaction product of maleic acid or maleic anhydride and a glycol.Type: GrantFiled: March 12, 1998Date of Patent: October 5, 1999Assignee: Sybron Chemicals, Inc.Inventors: Robert B. Login, Calvin McIntosh Wicker, Jr., Otto Bella
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Patent number: 5922088Abstract: A process for fixing dyes impregnated in fine-dimensional synthetic textile substrates in an environmentally safe manner. The process comprises contacting the dyed synthetic substrates with a phenol- and formaldehyde-free dye-fixative composition comprising:(a) polymethacrylic acid,(b) copolymers of methacrylic acid consisting essentially of methacrylic acid and an ethylenically unsaturated comonomer selected from the group consisting of 2-acrylamido-2-methyl-propanesulfonic acid, sodium vinyl sulfonate, sodium styrene sulfonate, alkyl acrylate,(c) sulfamic acid, and(d) combinations of (a), (b) and (c).Type: GrantFiled: November 19, 1997Date of Patent: July 13, 1999Assignee: Henkel CorporationInventors: Howard Cole, Brian Francois, David I. Devore
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Patent number: 5900029Abstract: Processes for coloring a fiber or textile by adding a carbon black product having an organic group attached to the carbon black. In one process at least one diazonium salt reacts with a carbon black in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon black in a protic reaction medium. Carbon black products which may be prepared according to process of the invention are described as well as uses of such carbon black products in plastic compositions, rubber compositions, paper compositions, and textile compositions.Type: GrantFiled: July 7, 1998Date of Patent: May 4, 1999Assignee: Cabot CorporationInventors: James A. Belmont, Robert M. Amici, Collin P. Galloway
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Patent number: 5855623Abstract: Methods are provided for treating polyester, polyamide, acrylic, aramid or cellulosic substrates to improve the uniformity of dyeing and to improve the hydrophilic, soil-release, odor-, mildew-, bacterial- and fungal- resistant properties of these substrates.Type: GrantFiled: September 20, 1996Date of Patent: January 5, 1999Assignee: Intera Technologies, Inc.Inventors: Larry L. English, Ted A. Mallen
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Patent number: 5810889Abstract: The present invention provides an aqueous textile treatment composition comprising:a) a non-reactive UVA compound;b) an emulsifier for the UVA compound;c) water, and, optionally,d) a polysiloxane-based product;as well as a method of treating a textile fibre material with this composition. The treated textile fibre material, in addition to having an excellent sun protection factor (SPF) value, may also exhibit improved wash permanence and other desirable properties.Type: GrantFiled: December 16, 1996Date of Patent: September 22, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Werner Kaufmann, Rolf Hilfiker, Hanspeter Gysin, Urs Hofer, Robert Truniger, Hans Peter Harri
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Patent number: 5804352Abstract: A dye solution comprising a laser recordable dye and a solvent for the dye that has (a) a solvent functional group selected from esters, ketones and ethers; and (b) the solvent functional group has as hindering groups (i) at least one t-butyl group on one side thereof or (ii) two groups on opposite sides thereof selected from the group consisting of isoamyl, t-butyl, isobutyl and isopropyl; provided that both groups cannot be isopropyl and (c) the hindering groups are adjacent to the solvent functional group.Type: GrantFiled: October 14, 1997Date of Patent: September 8, 1998Assignee: Eastman Kodak CompanyInventors: Michael Paul Cunningham, Thomas Michael Smith
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Patent number: 5762651Abstract: To prevent dusting of a solid such as a crop protection agent, a pharmaceutical or a dyestuff, there is added thereto as a dustproofing agent a compound of the formula I ##STR1## in which Z represents Z.sub.1 or Z.sub.2 whereZ.sub.1 denotes a bivalent radical of the formula ##STR2## in which W represents a direct bond or a C.sub.1 -C.sub.3 unit, andZ.sub.2 represents unsubstituted arylenedioxy, wherein the remaining variables are defined herein.Type: GrantFiled: August 6, 1996Date of Patent: June 9, 1998Assignee: Bayer AktiengesellschaftInventors: Horst Brandt, Hans Schulze, Thomas Nagel, Hans-Werner Petroll, Udo Herrmann
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Patent number: 5718732Abstract: A process of dyeing natural or synthetic polyamide fibres in an aqueous exhaustion dyebath comprising an anionic dyestuff, comprising the steps of1. immersing the fibres to be dyed in the aqueous dyebath which has a temperature of from 20.degree.-50.degree. C. and a pH of 7-11 (7-8.5 when the polyamide is wool); and2. raising the temperature to 110.degree. C. maximum and maintaining it there until exhaustion is substantially complete;there being added to the dyebath, either prior to the commencement of temperature raising or after an alkaline migration period at the boil, an ester of a C.sub.2 -C.sub.3 hydroxycarboxylic acid with a C.sub.2 -C.sub.6 glycol and up to 30% by weight of the ester of a tertiary amine which is essentially non-volatile under the process conditions.Type: GrantFiled: July 3, 1996Date of Patent: February 17, 1998Assignee: Clariant Finance (BVI) LimitedInventors: Brian Bennett, deceased, Peter Bennett, administrator
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Patent number: 5597388Abstract: Process for the dyeing or printing of organic material, in particular fiber material, which comprises applying dyes containing at least one polymerizable double bond together with at least one colorless cationic compound containing at least one polymerizable double bond and, if desired, one or more colorless nonionic compounds containing at least one polymerizable double bond, and at least one photoinitiator, and, if desired, further auxiliaries to the organic material, in particular fiber material, and then fixing them by means of UV light.Type: GrantFiled: December 2, 1994Date of Patent: January 28, 1997Assignee: Ciba-Geigy CorporationInventor: Katharina Fritzsche
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Patent number: 5575820Abstract: A process for the dyeing and printing of organic material, in particular fibre material, which comprises applying dyes containing at least one polymerisable double bond together with at lease one colourless cationic compound containing at least one polymerisable double bond and, if desired, one or more colourless nonionic compounds containing at least one polymerisable double bond and, if desired, further auxiliaries to the organic material, in particular fibre material, and then fixing them by means of ionizing radiation.Type: GrantFiled: December 2, 1994Date of Patent: November 19, 1996Assignee: Ciba-Geigy CorporationInventor: Katharina Fritzsche
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Patent number: 5534038Abstract: Disclosed are processes for tinting hydrogel materials, such as contact lenses, by dissolving a leuco sulfate ester of a vat dye in an compatible monomer solution, adding an oxidizing initiator to the monomer solution, and oxidizing and polymerizing the monomer solution and dye in the same solution. In one aspect, the oxidation and polymerization are conducted simultaneously whereas in another embodiment, the oxidation of the soluble leuco sulfate ester of a vat dye to the insoluble vat dye and polymerization are conducted sequentially in the same reaction medium.Type: GrantFiled: May 19, 1995Date of Patent: July 9, 1996Assignee: Pilkington Barnes Hind, Inc.Inventor: John M. Evans
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Patent number: 5399616Abstract: Lubricant-containing aqueous preparations of copolymers are obtainable by polymerisation of(A) 70 to 95% by weight of a monomer mixture of(a) 20 to 90% by weight of an ethylenically unsaturated carboxylic acid, in particular of a monocarboxylic acid, or of a corresponding amide,(b) 10 to 80% by weight of a sulfonated, aliphatic or aromatic monovinyl compound, and(c) 0 to 25% by weight of N-vinylpyrrolidone or of an N-vinyl-substituted amide of a saturated aliphatic monocarboxylic acid in the presence of(B) 5 to 30% by weight of a polyol whose hydroxyl groups have been esterified with a fatty acid of 8 to 26 carbon atoms, the sum totals of (A) and (B) on the one hand and (a), (b) and (c) on the other each adding up to 100%.Type: GrantFiled: April 8, 1993Date of Patent: March 21, 1995Assignee: Ciba-Geigy CorporationInventors: Martin Kuhn, Philippe Ouziel, Hans-Ulrich Berendt, deceased
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Patent number: 5376145Abstract: A method of processing a textile material consisting wholly or partly of keratinous fibres, characterised in that the material is treated with an aqueous composition containing at least one compound which possesses one or more ethylenic double bonds activated by two adjacent carbonyl groups. Preferred compounds include fumaric acid or maleic acid, optionally substituted with one or two halo and/or alkyl groups; or a salt, ester or amide of any said acid; or an N-substituted maleimide, optionally substituted with one or two halo and/or alkyl groups.Type: GrantFiled: April 13, 1990Date of Patent: December 27, 1994Assignee: Commonwealth Scientific and Industrial Research OrganizationInventors: Peter R. Brady, Peter G. Cookson, Keith W. Fincher, John R. Cook
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Patent number: 5356442Abstract: A method is described for dyeing fibrous materials made of or containing wool with anionic dyes, which comprises dyeing these materials in the presence of a wool preservative comprising at least one compound of the formulaR--CH.sub.2 --CH(OH)--CH.sub.2 --Y (I),where the variables are as defined in the claims. Rub-fast level dyeings are obtainable without deterioration in the quality of the wool.Type: GrantFiled: July 30, 1993Date of Patent: October 18, 1994Assignee: Ciba-Geigy CorporationInventors: Philippe Ouziel, Martin Kuhn
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Patent number: 5338318Abstract: A method of dyeing film of polyethylene terephthalate wherein the film is immersed in a dye bath of solvent or dispersion dyes dissolved in a carrier consisting of glycerol triacetate, the dye bath being heated so the film is raised to the glass transition temperature of the film, and the dye and carrier are absorbed into the film. The dye and carrier are removed from the surface of the film by a washing bath, and the film is then heated to remove the carrier absorbed in the film without depreciating the dyestuff or the film.Type: GrantFiled: September 28, 1992Date of Patent: August 16, 1994Assignee: Acquired Technolgy, Inc.Inventor: Emilio A. Mercado
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Patent number: 5174791Abstract: Process for dyeing and printing blended fabrics made from polyester and natural fibre materials, characterized in that the dye baths, padding liquors or printing pastes contain compounds of general formula (I). Dye preparations containing one or more compounds of general formula (I).Type: GrantFiled: August 5, 1991Date of Patent: December 29, 1992Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Klaus Hofmann, Hubert Kruse, Jurgen Kuhlwein, Willi Steckelberg
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Patent number: 5162046Abstract: A method of dyeing film of polyethylene terephthalate wherein the film is immersed in a dye bath of solvent dyes dissolved in a carrier consisting of glycerol triacetate, the dye bath being heated so the film is raised to the glass transition temperature of the film, and the dye and carrier are absorbed into the film. The dye and carrier are removed from the surface of the film by a washing bath, and the film is then heated to remove the carrier absorbed in the film without depreciating the dyestuff or the film.Type: GrantFiled: September 30, 1991Date of Patent: November 10, 1992Inventor: Emilio A. Mercado
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Patent number: 5118324Abstract: Disclosed is a method of printing a cellulose fiber material with a reactive dye or direct dye, which comprises printing the cellulose fiber material with a printing paste containing an emulsion formed by emulsifying a mixture comprising a hydrophobic substance liquid at room temperature, represented by the following general formula I: ##STR1## wherein R.sub.1 and R.sub.2 independently represent a hydrogen atom or an acyl group derived from a saturated or unsaturated monoaliphatic carboxylic acid having 2 to 22 carbon atoms, R.sub.3 and R.sub.4 independently represent a methyl group, an ethyl group or a phenyl group, and l and m represent zero or a positive integer, with the proviso that the sum of l and m is an integer of from 1 to 300 and when each of R.sub.1 and R.sub.2 is a hydrogen atom, the sum of l and m is an integer of from 6 to 300, and a hydrophobic substance solid at room temperature, represented by the following general formula II:A(OR.sub.5).sub.Type: GrantFiled: November 19, 1990Date of Patent: June 2, 1992Assignee: Nicca Chemical Co., Ltd.Inventor: Juji Uchida
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Patent number: 5074888Abstract: A composition suitable for use as dyeing or textile auxiliary and which comprises a mixture of acid esters of adducts of ethylene oxide and propylene oxide with fatty alcohols having not less than 6 carbon atoms, at least one component of which composition is an acid ester of the formula ##STR1## wherein s is 3 to 10, p is 5 to 15,R is an aliphatic radical of not less than 6 carbon atoms; one of Z.sub.1 and Z.sub.2 is methyl and the other is hydrogen, andX is the acid radical of a low molecular aliphatic dicarboxylic acid, in particular maleic acid.This composition is used in particular as low foaming wetting agent and padding auxiliary for pretreating or dyeing cellulosic fibre materials.Type: GrantFiled: March 29, 1991Date of Patent: December 24, 1991Assignee: Ciba-Geigy CorporationInventors: Rosemarie Topfl, Heinz Abel
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Patent number: 4935033Abstract: Natural polyamide fibres, in particular wool, are dyed by means of reactive dyes using the exhaust method in the presence of a dyeing assistant consisting of a combination of (a) quaternized ammonium compounds of polyglycol compounds and (b) of acidic esters or salts thereof derived from at least dibasic oxyacids and from polyglycol compounds, both the quaternary ammonium compounds and the acidic esters being derived from an aliphatic amine having 12 to 24 carbon atoms in the aliphatic moiety. The process comprises carrying out the dyeing in the additional presence of (c) a fatty alcohol/polyalkylene glycol ether of the formulaR-O-(alkylene-O.sub.m H (1)in which R is an aliphatic radical having at least 8 carbon atoms, "alkylene" is an ethylene radical or propylene radical and m is 3 to 25.Type: GrantFiled: September 21, 1988Date of Patent: June 19, 1990Assignee: Ciba-Geigy CorporationInventors: Walter Mosimann, Dieter Mausezahl