Ureas, Thioureas, Pseudoureas, Or Pseudothioureas Patents (Class 8/585)
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Patent number: 8506653Abstract: The present invention relates to an aqueous direct dye formulation, comprising (a) 5 to 25% by weight of a dye composition comprising (a1) 50-99% by weight of one or more dyes obtainable by reduction or thermal treatment of Direct Yellow 11, and (a2) 1-50% by weight of a blue, black and/or red direct dye, (all based on the dye composition); (b) up to 0.9% by weight of a saturated, cyclic or acyclic water-soluble amine comprising a primary, secondary or tertiary amino group and at least one further functional group selected from primary, secondary and tertiary amino groups, OH groups and ether groups; and (c) up to 0.9% by weight of urea; and (d) water, wherein the percentages for (a), (b), and (c) relate to the total weight of the aqueous direct dye formulation. The invention moreover relates to a process for their preparation and the use thereof for the dyeing, in particular of paper, as well as paper which has been dyed with this aqueous direct dye formulation.Type: GrantFiled: March 11, 2010Date of Patent: August 13, 2013Assignee: BASF SEInventors: Allan Francis Cunningham, Céline Hossenlopp, Heinz Schneider, Rainer Hans Traber, Horst Herrmann, Michael Jacquier
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Patent number: 8475539Abstract: The present disclosure relates to compositions for preparing textile auxiliaries, which are used in particular to enhance the dyeing affinity of textile fibers.Type: GrantFiled: May 12, 2009Date of Patent: July 2, 2013Assignee: Total Raffinage MarketingInventor: Richard Frelechoux
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Patent number: 8343238Abstract: A process for altering the appearance of hair, the process comprising the steps of (a) providing a composition for dyeing and reducing curl and/or frizziness of hair, said composition comprising, in a cosmetically acceptable carrier: (i) at least one non-hydroxide base; (ii) at least one protein denaturant different from (a)(i); (iii) at least one dye chosen from oxidative dye precursors; (iv) at least one thickening agent; (v) optionally, at least one alkoxysilane comprising at least one solubilizing functional group; and (vi) optionally, at least one fatty substance; (b) contacting the hair with the composition in (a) to form treated hair; (c) smoothing the treated hair using a combination of heat and means for physically smoothing hair to form smoothed hair; (d) optionally, shampooing the smoothed hair; and (e) rinsing the smoothed hair.Type: GrantFiled: December 30, 2011Date of Patent: January 1, 2013Inventors: Gloria Lopez, Jeremy Puco
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Publication number: 20120005845Abstract: The present invention relates to an aqueous direct dye formulation, comprising (a) 5 to 25% by weight of a dye composition comprising (a1) 50-99% by weight of one or more dyes obtainable by reduction or thermal treatment of Direct Yellow 11, and (a2) 1-50% by weight of a blue, black and/or red direct dye, (all based on the dye composition); (b) up to 0.9% by weight of a saturated, cyclic or acyclic water-soluble amine comprising a primary, secondary or tertiary amino group and at least one further functional group selected from primary, secondary and tertiary amino groups, OH groups and ether groups; and (c) up to 0.9% by weight of urea; and (d) water, wherein the percentages for (a), (b), and (c) relate to the total weight of the aqueous direct dye formulation. The invention moreover relates to a process for their preparation and the use thereof for the dyeing, in particular of paper, as well as paper which has been dyed with this aqueous direct dye formulation.Type: ApplicationFiled: March 11, 2010Publication date: January 12, 2012Applicant: BASF SEInventors: Allan Francis Cunningham, Céline Hossenlopp, Heinz Schneider, Rainer Hans Traber, Horst Herrmann, Michael Jacquier
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Patent number: 7799093Abstract: Disclosed herein is a composition comprising at least one nonionic polysiloxane/polyurea block copolymer, at least one colored or coloring entity, and at least one volatile nonsilicone organic solvent. Such a composition may make it possible to obtain a coloring which is resistant to external agents.Type: GrantFiled: October 25, 2007Date of Patent: September 21, 2010Assignee: L'Oréal S.A.Inventors: Gaëlle Brun, Sabine Vrignaud
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Publication number: 20100136335Abstract: The present invention relates to compositions and methods for treating textile fibers and, in particular, to compositions and methods for treating fibers of carpet and other floor coverings. In one aspect, the present invention provides compositions and methods that can reduce energy consumption and conserve water resources in the production of dyed fibrous substrates having desirable repellency and stain resistant properties.Type: ApplicationFiled: October 1, 2009Publication date: June 3, 2010Inventors: Ralph R. Sargent, Michael S. Williams, Michael Grigat, Billy Lee Hullender
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Patent number: 7585332Abstract: The present invention relates to compositions for dyeing keratin fibers, and in particular human keratin fibers such as the hair, comprising at least one compound of styryl or imine type containing a heterocycle and at least one thiol compound. The present invention makes it possible in particular to obtain a chromatic and fast coloration of keratin fibers, especially with respect to shampooing. Moreover, the color obtained is visible even on dark hair without necessarily using an oxidizing composition. The invention also makes it possible to obtain a coloration which, under certain conditions, does not stain.Type: GrantFiled: October 15, 2007Date of Patent: September 8, 2009Assignee: L'Oreal S.A.Inventor: Grégory Plos
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Publication number: 20080233379Abstract: The present invention is directed to endless belts and fabrics incorporating thermochromic material such as polythiophene for use as a process control aid which can be used in thermal profiling of industrial thermal process, the industrial fabrics used in such a process, the manufacture of the industrial fabrics thereof and/or the products produced or carried thereon.Type: ApplicationFiled: March 20, 2007Publication date: September 25, 2008Inventor: Joseph G. O'Connor
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Patent number: 7312012Abstract: The present invention relates to a thermal donor comprising a dye mixture and a urea light-stabilizing compound, wherein the light-stabilizing compound is represented by structure I: wherein: R1, R2 and R3 represent a hydrogen atom, alkyl group, cycloalkyl group, alkenyl group, aralkyl group, aryl group or heterocyclic group, provided that at least one of R1, R2, and/or R3 is a hydrogen atom; R4-R8 represent a hydrogen atom, hydroxyl group, alkyl group, cycloalkyl group, alkenyl group, aralkyl group, aryl group, heterocyclic group, aryloxy group, or alkoxy group; and R3 forms a heterocyclic ring with either R4 or R8, and an imaging system comprising a donor sheet having a layer containing a dye and an image receiving sheet having a dye receiving layer, wherein either the donor sheet or the image receiving sheet comprises a dye mixture and a urea light-stabilizing compound of structure I.Type: GrantFiled: December 14, 2006Date of Patent: December 25, 2007Assignee: Eastman Kodak CompanyInventors: Donald R. Diehl, Shari L. Eiff, Ramanuj Goswami, Christine J. Landry-Coltrain, Gary M. Russo
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Patent number: 7264639Abstract: This invention relates to a hair dyeing composition showing excellent dyeing ability comprising at least one direct acting hair dye and benzylurea and/or benzyl carbamate and/or N-(2-methoxybenzyl)urea. The direct acting hair dyes are preferably selected from anionic, acidic dyestuffs. In addition to benzylurea and/or benzyl carbamate and/or N-(2-methoxybenzyl)urea compositions further comprise organic solvents as penetration enhancers. Compositions according to the invention has a pH in the range from 1 to 5 and preferably comprises polymeric thickening agents, organic and/or inorganic acids and conditioning agents.Type: GrantFiled: September 6, 2006Date of Patent: September 4, 2007Assignee: KPSS-Kao Professional Salon Services GmbHInventors: Isabel Vega Carrascal, Bernd Noecker
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Patent number: 7135045Abstract: This invention relates to a hair dyeing composition showing excellent dyeing ability comprising at least one direct acting hair dye and benzylurea and/or benzyl carbamate and/or N-(2-methoxybenzyl) urea. The direct acting hair dyes are preferably selected from anionic, acidic dyestuffs. In addition to benzylurea and/or benzyl carbamate and/or N-(2-methoxybenzyl) urea compositions further comprise organic solvents as penetration enhancers. Compositions according to the invention has a pH in the range from 1 to 5 and preferably comprises polymeric thickening agents, organic and/or inorganic acids and conditioning agents.Type: GrantFiled: March 2, 2004Date of Patent: November 14, 2006Assignee: KPSS-Kao Professional Salon Services GmbHInventors: Isabel Vega Carrascal, Bernd Nöcker
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Patent number: 7066968Abstract: The present invention relates to a 2-step methods, and compositions for providing more vibrant, natural and long-lasting color to hair and at the same time reducing hair fiber damage associated with alternative current methods. In the first step the hair is contacted for a period of time with a dye precursor mixture containing specific oxidative hair dye precursors under conditions where these dyes are substantially inactive. Color is then developed in a second step by contacting the hair with a mixture of a peroxide compound and a persulfate salt. Surprisingly the 2-step method leads to considerable “lift” or lightening without negatively impacting the coloring ability of the oxidative dye. The invention also relates to kits providing the means to accomplish these steps.Type: GrantFiled: March 2, 2004Date of Patent: June 27, 2006Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Alexander C Chan, Stella Arcella, John Brian Bartolone, Allan Robert Burger
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Patent number: 7041142Abstract: A two step method of coloring hair is described. The hair is first contacted for a period of time with a dye precursor mixture containing an oxidative dye, specific fatty components and one or more water miscible organic solvents. Color is then developed in a second step by contacting the hair with one or more oxidizing agents. Greater color intensity and longevity are achieved when the fatty component in the dye precursor mixture contains at least one fatty amine and the fatty ingredients and organic solvents satisfy the relationship, ?FC<0.037(?OS)2?3.35(?OS)+63, where ?FC and ?OS are respectively the total weight of fatty ingredients and the total weight of water miscible organic solvents in the precursor mixture.Type: GrantFiled: October 12, 2004Date of Patent: May 9, 2006Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Alexander C. Chan, Stella Arcella, John Brian Bartolone
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Patent number: 7037347Abstract: Pretreatment agents for hair colorings with acid dye comprising at least one cationic polymer selected from the group consisting of polymers having amino groups and polymers having quaternary ammonium groups. The pretreatment agents for hair colorings with acid dye are used for improving coloring ability and color fastness of hair colorings with acid dye.Type: GrantFiled: July 12, 2001Date of Patent: May 2, 2006Assignee: Mandom CorporationInventors: Akio Kuzuhara, Mitsuo Sano
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Patent number: 6660048Abstract: The aqueous dye solutions of the composition shown in claim 1 are distinguished by a good storage stability and are suitable for dyeing paper in red color shades.Type: GrantFiled: April 17, 2001Date of Patent: December 9, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Alfred Höhener, Roland Frick, Adolf Kaeser
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Patent number: 6620212Abstract: Provided is a novel method of dyeing a corespun yarn which comprises an inorganic fiber core and at least a first sheath. The method comprises: (a) contacting the corespun yarn with a dye liquor; (b) heating the dye liquor to a dyeing temperature for a time effective to dye the yarn; (c) cooling the dye liquor at a controlled rate; and (d) rinsing the yarn with water or with a mixture comprising the dye liquor and water. The dyed corespun yarn has a strength retention of about 80% or more based on the undyed yarn. The methods in accordance with the invention allow for the formation of uniformly dyed, high strength corespun yarns. Also provided is a dyed, corespun yarn which can be made by the inventive method, a fabric formed from the corespun yarn, as well as a product upholstered with the fabric. The dyed yarns exhibit substantially no “grin through” and little to no yarn strength loss after dyeing.Type: GrantFiled: October 5, 2000Date of Patent: September 16, 2003Assignees: McKinnon-Land, LLC, BASF Corporation, DyStar, L.P.Inventors: Alan C. Handermann, David W. Shaw, William P. Cochran, William R. Bryant, Frank J. Land
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Patent number: 6352563Abstract: A printed cloth in which a dye is deposited in dots on the cloth to form a desired printed pattern. Said dot deposition is formed in a length of 0.05 to 0.3 mm to the longitudinal direction of the fiber in single fiber unit of the yarn constituting said cloth. A fine printed pattern is deposited clearly in good reproducibility. The printed pattern can be formed by using the dyes of the three primary colors or of the three primary colors and black color. It is preferred that Dyes I , II and III having a perceived chromaticity index (a) and (b) defined in the color range [CIE 1976 (L, a, b) space] on the cloth within the following range are used as said dyes of three primary colors and DyeIV is used as said black dye.Type: GrantFiled: February 22, 2000Date of Patent: March 5, 2002Assignee: Kanebo, Ltd.Inventors: Kazuo Kusaki, Toshikazu Fuse, Tohru Morita, Toshihiko Ishihara, Kazuyoshi Morimoto, Kazuo Iwata, Michiyo Nishimura
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Patent number: 6221113Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25° C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.Type: GrantFiled: January 13, 1998Date of Patent: April 24, 2001Assignee: Clariant Finance (BVI) LimitedInventor: Jürgen Geiwiz
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Patent number: 6149549Abstract: The present invention is generally directed to a process for making fabrics containing cotton fibers more aesthetically pleasing and resistant to staining by anionic dyes by derivatising the cotton so that it exhibits a permanent anionic charge. By increasing the anionic charge of the fibers, the fibers become resistant to anionic coloring agents which may undesirably come into contact with the fibers. Furthermore, the negative charges repel each other resulting in a fabric with greater loft and porosity. This results in greater smoothness, better hand, and more comfort. Besides being used to prevent the cross-staining of fabrics, the present invention can also be used to make carpet materials resistant to anionic staining agents. Alternatively, it has also been discovered that an anionic derivative can be used to catalyze permanent press resins onto fabrics containing cellulosic fibers, also resulting in anionic cotton.Type: GrantFiled: September 21, 1998Date of Patent: November 21, 2000Assignee: Syborn Chemicals, Inc.Inventors: Robert B. Login, Otto Bella, Calvin McIntosh Wicker, Jr.
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Patent number: 6086636Abstract: Disclosed is a process for printing fibre material with reactive dyes, which comprises the fibre material to be printed first being treated with an aqueous alkaline liquor, optionally dried and then printed with a print paste comprising at least one reactive dye, a thickener and optionally further additives with the exception of an alkali or an alkali donor.Type: GrantFiled: June 2, 1998Date of Patent: July 11, 2000Assignee: Ciba Specialty Chemicals CorporationInventors: Mickael Mheidle, Peter Scheibli
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Patent number: 6051036Abstract: A printed cloth in which a dye is deposited in dots on the cloth to form a desired printed pattern. Said dot deposition is formed in a length of 0.05 to 0.3 mm to the longitudinal direction of the fiber in single fiber unit of the yarn constituting said cloth. A fine printed pattern is deposited clearly in good reproducibility. The printed pattern can be formed by using the dyes of the three primary colors or of the three primary colors and black color. It is preferred that Dyes I, II and III having a perceived chromaticity index (a) and (b) defined in the color range [CIE 1976 (L, a, b) space] on the cloth within the following range are used as said dyes of three primary colors and DyeIV is used as said black dye.______________________________________ I Yellow: (a) -20.about.0 (b) 50.about.90 II Red: (a) 50.about.70 (b) 0.about.20 III Blue: (a) -50.about.-1 (b) -50.about.-20 IV Black: (a) -6.about.6 (b) -6.about.Type: GrantFiled: June 3, 1997Date of Patent: April 18, 2000Assignee: Kanebo, Ltd.Inventors: Kazuo Kusaki, Toshikazu Fuse, Tohru Morita, Toshihiko Ishihara, Kazuyoshi Morimoto, Kazuo Iwata, Michiyo Nishimura
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Patent number: 5961670Abstract: New sulfur dyes comprising in their preparation at least one sulfur dye intermediate of the formula I ##STR1## wherein R and R.sub.1 are independently nitro, nitroso or amino, are produced by including in their preparation at least one modifying agent selected from the group of: A) an aldehyde; B) urea; C) a benzoquinone or naphthoquinone; and D) monoethanolamine or by treating an already prepared sulfur dye involving such an intermediate in its preparation, with at least one aldehyde, benzoquinone or naphthoquinone or with monoethanolamine.Type: GrantFiled: October 30, 1996Date of Patent: October 5, 1999Assignee: Clariant Finance (BVI) LimitedInventors: Philip N. Cote, Xiangfu Lan, Alex I. Shakhnovich, Manuel Jose Domingo
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Patent number: 5944856Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.Type: GrantFiled: January 13, 1998Date of Patent: August 31, 1999Assignee: Clariant Finanace (BVI) LimitedInventor: Jurgen Geiwiz
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Patent number: 5942010Abstract: Dyeing of cellulosic substrates with reactive dyes in the presence of at least 20 g/l of sodium chloride, employing auxiliaries (E) of levelling activity, which are methylene-bridge-containing and sulpho-group-containing aromatic compounds, obtainable by condensation of defined sulphonation products with formaldehyde resp. formaldehyde-yielding compounds and optionally salt formation; (E)-contaning compositions that further contain at least one hydrotrope (H) and/or at least one sequestering agent (Q); and novel condensation products.Type: GrantFiled: February 23, 1998Date of Patent: August 24, 1999Assignee: Clariant Finance (BVI) LimitedInventor: Hans-Peter Baumann
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Patent number: 5879414Abstract: A long lasting hair-dye composition in solid stick form is described.Type: GrantFiled: March 14, 1997Date of Patent: March 9, 1999Assignee: Solid Products LimitedInventor: Stefano Milazzo
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Patent number: 5851240Abstract: The invention relates to a process for dyeing and finishing cellulosic textile fiber material in one step, which comprises applying to said textile fiber material a liquor comprising (A) at least one dye, (B) a crosslinking agent, (C) a crosslinking catalyst, and (D) choline and subsequently fixing the dye on the textile fiber material.Type: GrantFiled: July 11, 1997Date of Patent: December 22, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Alex Kanzig, Katharina Fritzsche, Peter Scheibli
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Patent number: 5846266Abstract: By using printing pastes containing thiourea dioxide together with finely dispersed calcium, magnesium or zinc hydroxide, present in the paste as such or generated from components in the printing paste during a treatment process, fabric discharge printing processes may be developed which have the advantage of decorating fabric webs, garments or garment panels effectively, even in dry heat conditions, whilst avoiding contamination of such fabrics with undesirable residues, particularly formaldehyde.Type: GrantFiled: October 3, 1996Date of Patent: December 8, 1998Inventor: Ian Durham Rattee
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Patent number: 5705676Abstract: A photothermographic element comprising a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible source of silver;(c) a chromogenic leuco dye reducing agent; and(d) a binder;wherein the chromogenic leuco dye reducing agent is a chromogenic leuco redox-dye-releasing compound of the general formula: ##STR1## wherein: (i) Cp is a coupler group;(ii) N--D is a photographic developer group; and(iii) R.sup.1 is a --C(O)--NH--A--Dye group wherein Dye represents the chromophore of a thermally mobile dye; and A represents a single bond or a divalent linking group of the formula --X--R.sup.5 --L--, wherein R.sup.5 is a divalent hydrocarbon chain containing up to 12 carbon atoms, L is a single bond or a divalent group that binds the chromophore of the thermally mobile dye to R.sup.5, and X represents a single bond or an --SO.sub.2 -- group.Type: GrantFiled: November 16, 1995Date of Patent: January 6, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Raffaella Biavasco, Lori S. Harring, Larry R. Krepski, Daniel E. Mickus, Mark B. Mizen, Sharon M. Simpson, Cristina Soncini, Kim M. Vogel
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Patent number: 5696289Abstract: A photothermographic element containing a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer is provided. The emulsion layer comprises:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible source of silver;(c) a leuco dye reducing agent; and(d) a binder;wherein the leuco dye reducing agent comprises a blocked leuco dye compound of the general formula L-R.sup.1, which is capable of being oxidized to a colored form, wherein:(i) L is a group remaining after removal of a hydrogen from a leuco dye; and(ii) R.sup.1 is a C(O)-NH-SO.sub.2 -R.sup.5 group wherein R.sup.5 is an aliphatic group or an aromatic group.Type: GrantFiled: November 16, 1995Date of Patent: December 9, 1997Assignee: Minnesota Mining And Manufacturing CompanyInventors: Larry R. Krepski, Sharon M. Simpson, Kim M. Vogel
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Patent number: 5630850Abstract: There is disclosed a process for printing fibre material by the direct printing process, which process comprises printing the fibre material with a print paste comprising at least one dye, one cellulose derivative or alginate as thickener as well as further customary assistants and wherein the print paste comprises .ltoreq.5% by weight, based on the print paste, of a homopolymer or copolymer based on acrylamide.The novel process makes it possible to obtain strong patterned prints on a white ground which have good levelness, good fastness properties and sharp contours. The print pastes are distinguished by good homogeneity, good storage stability and simple handling.Type: GrantFiled: May 31, 1996Date of Patent: May 20, 1997Assignee: Ciba-Geigy CorporationInventors: Paul Schafflutzel, Philippe Ouziel
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Patent number: 5490865Abstract: The present invention is a process for producing two-tone or multi-color effects on animal fibers and the products derived from these fibers. Pretreatment of the fibers to increase the affinity of the fiber relative to metallic salts or dyes for is accomplished by treatment with an ethanolamine solution containing varying amounts of mono-, di-, or triethanolamine. A mordant treatment with a metallic salt exposes the pretreated fibers to an aqueous solution of organic acids and a metallic salt mordant having affinity for the pretreated fiber. The two-tone or multi-colored effect is achieved by combining the treated fibers with untreated fiber and dyeing the fibers in a dyestuff having affinity for the treated fiber. The dyeing process may also include placing treated and untreated fibers in a dye bath containing dye stuffs that have affinity to treated fibers and dyestuffs that have an affinity to untreated fibers.Type: GrantFiled: July 25, 1994Date of Patent: February 13, 1996Inventor: Jurg P. Scheiwiller
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Patent number: 5441543Abstract: A synthetic fibers having a melting or softening temperature of 160.degree. C. or more, for example, polyester fibers, are dyed with an organic coloring material having a molecular weight of 370 or more, for example, disperse dye, vat dye and phthalocyanine pigment, at a temperature of 150.degree. C. or more, at a high color depth, and the resultant dyed product exhibits a high color fastness to washing or light.Type: GrantFiled: September 1, 1993Date of Patent: August 15, 1995Assignee: Teijin LimitedInventor: Shigenobu Kobayashi
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Patent number: 5403358Abstract: A color enhancing agent comprising water, urea and a quaternary ammonium compound of the Formula (1): ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 are each independently selected from H and C.sub.1-20 -optionally substituted alkyl or alkylene;R.sup.4 is C.sub.1-20 -optionally substituted alkyl or alkylene; andX.sup.- is an anion,provided that the total number of carbon atoms in the compound of Formula (1) is more than 30. The color enhancing agent can be used in pre-treatment compositions for textile materials prior to ink jet printing with a reactive dye and improves color yields.Type: GrantFiled: September 21, 1992Date of Patent: April 4, 1995Assignee: Imperial Chemical Industries PLCInventors: Sarah O. Aston, John R. Provost
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Patent number: 5378245Abstract: The invention relates to a process for dyeing cellulose fibres such as cotton fibres, comprising successively the steps of (a) bleaching the cellulose fibres with an alkaline bath containing aqueous hydrogen peroxide; (b) neutralizing the residual hydrogen peroxide with a reducing agent; and (c) dyeing the cellulose fibres with a reactive dye sensitive to said reducing agent, wherein, after stage (b) and at the latest at the beginning stage (c), any residual agent is neutralized by a quantity of an alkali or alkaline-earth metal halogenite sufficient to neutralize it, whereby it is possible not to perform any intermediate rinsing between stages (a) and (c).Type: GrantFiled: July 29, 1993Date of Patent: January 3, 1995Assignee: Manufacture de Produits Chimiques ProtexInventor: Jean Balland
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Patent number: 5238464Abstract: Cellulosic fabrics are rendered flame resistant in a two-step procedure by applying first a tetrakis(hydroxymethyl) phosphonium salt/urea precondensate ammoniated to crosslink and form an insoluble phosphorus-containing polymer within the fiber structure followed by treatment with a tetrakis(hydroxymethyl) phosphonium salt. The two-step process using these chemically related phorphorus-containing flame retardants provide sufficient phosphorus in and on the cellulosic fabric to impart a predetermined minimum flame resistance. Cellulosic fabrics, primarily cotton, having flame resistant properties durable to washing yet retaining pliant, nont-stiff hand result.Type: GrantFiled: March 23, 1992Date of Patent: August 24, 1993Assignee: Burlington Industries, Inc.Inventors: James R. Johnson, Randolph L. Finley
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Patent number: 5234466Abstract: A method for the adjustment of pH in textile processing solutions that includes the use of urea sulfate or other strong acid in the presence of a weak base.Type: GrantFiled: July 24, 1992Date of Patent: August 10, 1993Assignee: Peach State Labs, Inc.Inventors: R. Richard Sargent, Jeffrey R. Alender
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Patent number: 5173086Abstract: Aqueous solutions containing, each percentage being based on the weight of the aqueous solution,a) from 5 to 20% by weight of the dye of the formula ##STR1## (calculated as free acid) where cat.sup..sym. is a mixture of cations comprising from 5 to 50 mol % of lithium ions, from 5 to 40 mol % of diethanolammonium ions and from 20 to 90 mol % of triethanolammonium ions, andb) from 0 to 15% of urea, are useful for dyeing paper stock.Type: GrantFiled: September 12, 1991Date of Patent: December 22, 1992Assignee: BASF AktiengesellschaftInventor: Rudolf Bermes
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Patent number: 5143519Abstract: Concentrated dye solutions of dyes of the formula (1) shown in claim are described.The dye solutions are distinguished by a good storage stability and are suitable, in particular, for dyeing paper.Type: GrantFiled: March 29, 1991Date of Patent: September 1, 1992Assignee: Ciba-Geigy CorporationInventor: Willy Stingelin
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Patent number: 5049238Abstract: A method of dyeing paper utilizing dyes suitable for dyeing paper in blue shades having the formula ##STR1## wherein R is hydrogen, --OH, --OR.sup.1 , --NH.sub.2, NHR.sup.1, --NHCOR.sup.1, --NHSO.sub.2 R.sup.1, --NHCONH.sub.2 or --NHCONHR.sup.1, in which R.sup.1 is unsubstituted alkyl or alkyl substituted by C.sub.1 -C.sub.4 -alkoxy, hydroxy-substituted C.sub.1 -C.sub.4 -alkoxy, phenyl, phenoxy or phenylcarbamoyl, in each instance the phenyl moiety being unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxy or phenoxy, R.sup.1 is also unsubstituted phenyl or naphthyl or phenyl or naphthyl which is substituted by sulfo, carboxy, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen, nitro, C.sub.1 -C.sub.4 -alkylcarbonylamino or C.sub.1 -C.sub.4 -alkoxycarbonylamino;X, each independently of the other, is hydrogen, unsubstituted alkyl or alkoxy or alkyl or alkoxy which is substituted by C.sub.1 -C.sub.4 -alkoxy, hydroxy-substituted C.sub.1 -C.sub.Type: GrantFiled: July 19, 1989Date of Patent: September 17, 1991Assignee: Ciba-Geigy CorporationInventor: Adolf Kaser
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Patent number: 4985046Abstract: There is provided by this invention a process for preparing poly(paraphenylene terephthalamide) fibers dyeable with cationic dyes. The process comprises soaking poly(paraphenylene terephthalamide) fibers in sulfuric acid, washing the fibers and dipping the acid soaked fibers or never-dried PPD-T fibers in an aqueous solution of a dye promoting species. The fibers can then be dried and subsequently dyed.Type: GrantFiled: June 9, 1989Date of Patent: January 15, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventor: Jon D. Hartzler
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Patent number: 4886518Abstract: A process for dyeing cellulose fibres or cellulose-containing blend fibres with vat dyes, sulfur dyes, leuco vat ester dyes or azoic dyes by the pad dyeing process without incurring ending, in which an aqueous dyeing liquor is used which, aside from the dye, contains a colorless compound of the formula ##STR1## or of the formula ##STR2## where Q is ##STR3## or .dbd.N--, Y is hydrogen, halogen, cyano, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkylsulfonyl,V and W, independently of each other, are each R.sub.2 --X.sub.2 --, R.sub.3 --X.sub.3 --, hydroxyl C.sub.1 --C.sub.5 alkoxy or an unsubstituted or C.sub.1 --C.sub.5 alkyl-- or C.sub.5 --C.sub.6 cycloalkyl-monosubstituted or --disubstituted amino group, the alkyl radical being unsubstituted or substituted by hydroxyl, cyano, sulfo or sulfato,R.sub.1, R.sub.2 and R.sub.3, independently of one another, are each an aromatic or heteroaromatic radical,X.sub.1, X.sub.2 and X.sub.Type: GrantFiled: September 19, 1988Date of Patent: December 12, 1989Assignee: Ciba-Geigy CorporationInventor: Jean-Marie Sire
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Patent number: 4881942Abstract: A process for the coloration of a union of polyester and cellulosic textile materials which comprises applying thereto a liquor or paste containing a disperse dye and a dye containing a cellulose reactive group having a quaternary nitrogen substituent, or the precursors of such a dye, and thereafter heating the textile material at such a temperature and for such a period as to fix the dye on the textile material, characterized in that the pH of the liquor or paste is from 5.8 to 8.0.Type: GrantFiled: July 7, 1988Date of Patent: November 21, 1989Assignee: Imperial Chemical Industries PLCInventor: Herbert G. Connor
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Patent number: 4833235Abstract: Disazo compounds of the formula ##STR1## and salt thereof, D is the radical of a diazo component of the benzene or naphthalene series.K is the radical of a heterocyclic coupling component of the aminopyrazole-, pyridone- or barbituric acid-series, n is 1 to 4,R.sub.1 is hydrogen, C.sub.1-4 alkyl or substituted C.sub.1-4 alkyl,each of R.sub.2 and R.sub.3 is independently hydrogen, halo, C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy, substituted C.sub.1-4 alkoxy, --NHCO--Rhd 5, amino, substituted amino or a quaternary ammonium group, wherein R.sub.5 is C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy or amino,R.sub.4 is hydrogen, C.sub.1-4 alkyl, C.sub.Type: GrantFiled: October 7, 1987Date of Patent: May 23, 1989Assignee: Sandoz Ltd.Inventor: Reinhard Pedrazzi
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Patent number: 4801303Abstract: Polyester-cotton blend textile substrates are dyed with a disperse dye and then with a sulfur dye from the same dyebath which is maintained at a temperature no higher than 105.degree. C. when the sulfur dye is present therein and which preferably contains glucose as the reducing agent for the sulfur dye.Type: GrantFiled: June 1, 1987Date of Patent: January 31, 1989Assignee: Sandoz Ltd.Inventors: Mark S. Carlough, Laszlo A. Meszaros
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Patent number: 4787912Abstract: An assistant for dyeing or whitening synthetic nitrogen-containing fibre material, which comprises(A) a sulfonated polycarboxylate,(B) an anionic surfactant,(C) a nonionic surfactant, and(D) a water-soluble organic, polar solvent.The assistant is especially useful for dyeing or whitening polyamide fibres.Type: GrantFiled: January 28, 1987Date of Patent: November 29, 1988Assignee: Ciba-Geigy CorporationInventors: Heinz Abel, Helmut Raisin
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Patent number: 4767420Abstract: The transfer sheet or web is intended for the use in a heat transfer printing process of cotton, of cotton-polyester blend or of nitrogen containing textile fibers such as wool, silk or nylon.It comprises on its surface at least one organic impregnating agent which has a melting point between 60.degree. and 230.degree. C. and is no polymer, at least one water insoluble, non-subliming dyestuff, and the minimum amount of a binder. The dyestuff forms a pattern or image which is heat contact printed on said textile substrate without the use of carrier vapors or vacuum. The pattern to be heat transferred may also be prepared in an electrophotographic process using a new toner comprising particles of impregnating agent, binder and dyestuff.The pattern on the transfer support is transferred at a temperature between 160.degree. and 230.degree. C. during 30 to 60 seconds to said textile substrate. The printings obtained have very good light, rubbing and washing fastnesses; the handling is not impaired.Type: GrantFiled: January 23, 1987Date of Patent: August 30, 1988Assignee: Sicpa Holding S.A.Inventors: Wolfgang Mehl, Albert Amon
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Patent number: 4737240Abstract: Black trisazo dyes for cellulosic textiles, leather and especially paper having the structure ##STR1## where A is ##STR2## one of B.sub.1 and B.sub.2 is hydrogen and the other is --SO.sub.3 M or a mixture thereof, and M is hydrogen, sodium, potassium, lithium or --HNR.sub.1 R.sub.2 R.sub.3 wherein R.sub.1, R.sub.2 and R.sub.3 represent the same or different substituents selected from hydrogen, lower alkyl and lower hydroxyalkyl, and stable liquid concentrates of these dyes are described.Type: GrantFiled: June 27, 1986Date of Patent: April 12, 1988Assignee: Ciba-Geigy CorporationInventors: Herbert S. Davis, Roy E. Smith, Mortimer Weiser
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Patent number: 4711642Abstract: Liquid water-containing concentrated reactive dye-stuff preparations of monofluorotriazinyl reactive dye-stuffs with a pH value of at least 8, preferably 8.5-10, are stable on storage and display no noticeable hydrolysis, even after prolonged storage.Type: GrantFiled: September 11, 1986Date of Patent: December 8, 1987Assignee: Bayer AktiengesellschaftInventors: Joachim Wolff, Karlheinz Wolf
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Patent number: 4685933Abstract: Concentrated aqueous solutions of dyestuffs having water-solubilizing groups which contain cyanamides of the formula ##STR1## wherein R.sub.1 =NHCN, NHCONH.sub.2 or NHCONHCH.sub.3 where n=0 andm=1 or n=1 and m=0,have a long shelf life, in particular also in the case of reactive dyestuffs.Type: GrantFiled: June 24, 1985Date of Patent: August 11, 1987Assignee: Bayer AktiengesellschaftInventors: Joachim Wolff, Karlheinz Wolf, Werner Marschner
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Patent number: 4636223Abstract: When silk fabrics, pre-treated with swelling agents, are printed by heat transfer techniques, the fabric will yellow. The invention eliminates yellowing by pre-treating said silk fabrics with a liquid or solid impregnating agent, dissolved or dispersed in water, then drying the fabric, and adding before, during or after the pre-treating an optical brightening agent of the type normally used for polyester.The impregnating agent can alternatively be applied to the fabric in a water-free condition before or during dyestuff transfer, and an optical brightener may be added.It is further contemplated to use easily migrating dyestuffs which are transferred to the fabric at relatively very low temperatures, and to avoid dyestuff migration by pre-treating the silk fabric with solid impregnating agents.All these techniques produce deep and brilliant shades; the prints have excellent fastnesses.Type: GrantFiled: April 4, 1985Date of Patent: January 13, 1987Assignee: Sicpa Holding S.A.Inventors: Wolfgang Mehl, Albert Amon