Hydroxy-containing Patents (Class 8/599)
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Patent number: 8324338Abstract: An oligomer removing agent for polyester-based fiber materials comprises a polyester copolymer which is obtained by polycondensation of a dibasic acid component containing 15-65 mol % of a sulfonate group-containing dibasic acid and a dihydric alcohol component containing polyethylene glycol with a molecular weight of 900-3500, and which has a 200° C. melt viscosity of 5000-23,000 mPa·s and has 10-40 mass % polyoxyethylene chains in the molecule. The oligomer removing agent is able to overcome the problems caused by deposition of polyester oligomers, when added to the dyeing bath in a dyeing step for polyester fiber materials or for fiber materials that are composites thereof with other fiber materials.Type: GrantFiled: January 21, 2011Date of Patent: December 4, 2012Assignee: Nicca Chemical Co., Ltd.Inventors: Masaaki Hosoda, Masatoshi Hayashi
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Patent number: 6814763Abstract: Mediator systems obtainable by mixing one or more salts of a metal capable of forming a plurality of valence states with at least one amino-containing complexing agent (K1) and at least one hydroxyl-containing but amino-devoid complexing agent (K2) in an alkaline aqueous medium, wherefor the complexing agents may be present as salts and the molar ratio of K1 to metal ion is from 0.1:1 to 10:1 and the molar ratio of K2 to metal ion is from 0.1:1 to 5:1 are useful for dyeing cellulosic textile material.Type: GrantFiled: October 15, 2002Date of Patent: November 9, 2004Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Thomas Bechtold, Stefan Mohr, Wolfgang Schrott, Norbert Grund, Wolfgang Hiebsch
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Patent number: 6790241Abstract: Mediator systems obtainable by mixing a salt of an electrochemically active complexing metal (M1) capable of forming a plurality of valence states with a hydroxyl-containing complexing agent, which may likewise be present as salt, and with a salt of an electrochemically inactive complexing metal (M2) in an alkaline aqueous medium, wherefor the molar ratio of metal ion M2 to metal ion M1 is from 0.8:1 to 2:1 are useful for reducing dyes and dyeing cellulosic textile material.Type: GrantFiled: October 15, 2002Date of Patent: September 14, 2004Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Thomas Bechtold, Eduard Burtscher, Wolfgang Schrott, Norbert Grund, Peter Maier, Georg Schnitzer, Franz Sütsch
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Patent number: 6500215Abstract: A process is disclosed for treating textile materials with selected amine oxides in order to change the aesthetics and/or make the materials more receptive to dyes. In particular, the treatment causes cellulosic materials to become more cationic and thus more receptive to anionic dyes with or without stiffening. In a preferred embodiment, the process of the present invention is directed to treating fabrics containing cotton fibers but will work to a useful extent on wool, nylon and polyester. The process is carried out by contacting said fibers or fabric with selected amine oxide compositions. The amine oxide compositions can be padded onto the fabric or printed onto the fabric. If printed onto the fabric according to a particular design, the design then becomes visible on the fabric once dyed.Type: GrantFiled: July 11, 2000Date of Patent: December 31, 2002Assignee: Sybron Chemicals, Inc.Inventors: Robert B. Login, Otto Bella, Calvin McIntosh Wicker, Jr., Lynn Hosie
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Patent number: 6136044Abstract: Micro-particles of transition metals or their compounds can be generated as an integral part of a fiber by first attaching a nucleating agent to the fiber, and then adding a solution of metal ions. The ions are reduced by the nucleating agent in the fiber, and micro-particles are generated in or on the fiber. Because of the strong color signal resulting from a low concentration of metal micro-particles, the method is cost effective even when using gold or titanium ions. Various colors were generated by changing the size and spacing of the micro-particles, the metal or metal complex used, and the characteristics of the fiber. The dyed fibers displayed colors ranging from pink, red, purple, yellow, orange, peach, brown, gold, silver, grey, green, and black. These colors resisted bleaching by either chemicals or light.Type: GrantFiled: February 3, 2000Date of Patent: October 24, 2000Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical CollegeInventor: William J. Todd
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Patent number: 5882936Abstract: The present invention provides an optical fluorescence based sensor for measuring the concentration of a gas (e.g., CO.sub.2 or ammonia) in a medium such as blood which has improved drift stability. In a preferred embodiment, the sensors of the present invention comprise microcompartments of an aqueous phase having a pH sensitive sensing component within a hydrophobic barrier phase. The sensors of the present invention are substantially free of partitioning species other than the analyte of interest which can migrate from one phase to the other in response to a change in pH in the aqueous phase and which substantially affect the concentration dependent signal. In an alternative embodiment, the sensors of the present invention are constructed so as to retard the migration of partitioning species, thus reducing the initial rate of drift.Type: GrantFiled: February 18, 1997Date of Patent: March 16, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: James G. Bentsen, Kenneth B. Wood
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Patent number: 5846266Abstract: By using printing pastes containing thiourea dioxide together with finely dispersed calcium, magnesium or zinc hydroxide, present in the paste as such or generated from components in the printing paste during a treatment process, fabric discharge printing processes may be developed which have the advantage of decorating fabric webs, garments or garment panels effectively, even in dry heat conditions, whilst avoiding contamination of such fabrics with undesirable residues, particularly formaldehyde.Type: GrantFiled: October 3, 1996Date of Patent: December 8, 1998Inventor: Ian Durham Rattee
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Patent number: 5772699Abstract: An aqueous reactive dye composition is disclosed. The aqueous reactive dye composition has improved storage stability and contains a water-soluble reactive dye and a chelating agent. The chelating agent is present in a sufficient concentration to maintain the pH of the aqueous reactive dye composition in the range of about 3.0 to about 7.0 and, preferably, about 5.0 to about 6.5. Desirable chelating agents are dicarboxylic acids, such as succinic acid, or amino carboxylates, such as nitrilotriacetic acid. A method of stabilizing an aqueous reactive dye composition is disclosed and includes the step of dissolving a polycarboxylic acid or an amino carboxylate in an aqueous solution of a water-soluble reactive dye in a sufficient concentration to stabilize the pH of the composition.Type: GrantFiled: February 10, 1997Date of Patent: June 30, 1998Assignee: Crompton & Knowles CorporationInventor: Andrew D. Boyer
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Patent number: 5651795Abstract: A mordant for dyeing fibers is provided comprising an aluminum salt, preferably Al.sub.2 (SO.sub.4).sub.3, potassium or sodium carbonate, preferably the latter, and citric acid, capable of forming an aluminum hydroxide suspension in aqueous media having a pH of about 3.5-4. Methods of use of this composition are also provided. The mordant is useful in commercial dye processes including package dyeing.Type: GrantFiled: September 19, 1996Date of Patent: July 29, 1997Assignee: Allegro Natural Dyes LLCInventor: Sally Gurley
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Patent number: 5613983Abstract: The invention disclosed herein relates to improved methods for decolorizing or fading fabrics with gaseous oxidizing agents. The methods involve tumbling the fabrics in the presence of moisture and a treating agent for delivery of the treating agent to random portions of the fabrics. After tumbling for a sufficient period of time, the fabrics are then oxidized with a gaseous oxidizing agent such as ozone.Type: GrantFiled: February 7, 1995Date of Patent: March 25, 1997Inventors: Raymond Terry, David W. Adcock
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Patent number: 5578088Abstract: Process for dyeing aminated cellulose/polyester blend fabric with fiber-reactive disperse dyestuffs Fiber materials comprising cellulose fibers or a mixture of cellulose and polyester fibers are dyed by first modifying the fiber material with one or more compounds containing amino groups and then dyeing the modified fiber material with a fiber-reactive disperse dyestuff in supercritical CO.sub.2.Type: GrantFiled: June 29, 1995Date of Patent: November 26, 1996Assignee: Hoechst AktiengesellschaftInventors: Andreas Schrell, Werner H. Russ
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Patent number: 5540739Abstract: A process for dyeing textile materials of naturally occurring and synthetic polyamide fibres, in which dyeing is carried out at the boiling point of the dyebath during a short dyeing time which is therefore gentle on the fibres, and level dyeings having good fastness properties are obtained (high temperature rapid dyeing process).The dyeing process is carried out with dyebaths with comprise specific surfactants. A high degree of exhaustion of the dye liquors is achieved, and dyeing from static baths is thus rendered possible.Type: GrantFiled: July 13, 1994Date of Patent: July 30, 1996Assignee: Ciba-Geigy CorporationInventors: Klaus Hannemann, Franz Gruner, Martin Jollenbeck, Jorg Binz
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Patent number: 5356442Abstract: A method is described for dyeing fibrous materials made of or containing wool with anionic dyes, which comprises dyeing these materials in the presence of a wool preservative comprising at least one compound of the formulaR--CH.sub.2 --CH(OH)--CH.sub.2 --Y (I),where the variables are as defined in the claims. Rub-fast level dyeings are obtainable without deterioration in the quality of the wool.Type: GrantFiled: July 30, 1993Date of Patent: October 18, 1994Assignee: Ciba-Geigy CorporationInventors: Philippe Ouziel, Martin Kuhn
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Patent number: 5207800Abstract: Low toxicity, biodegradable salt substitutes for use in dyeing of cotton and cotton blended fabrics. The salt substitutes are solubilized alkaline earth metal-organic complex compositions suitable to promote satisfactory dyeing. Preferably the composition is a mixture of magnesium acetate, magnesium citrate, and magnesium polyacrylate. After dyeing, a shift to alkaline pH in the wastewater treatment process allows for precipitation of the metal and the production of a biodegradable organic anion. The use of the salt compounds of the present invention in place of conventional sodium chloride or sulfate salts prevents the discharge of untreatable toxic wastewater into natural waterways.Type: GrantFiled: October 7, 1991Date of Patent: May 4, 1993Assignee: Burlington Chemical Co., Inc.Inventor: Samuel B. Moore
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Patent number: 5196031Abstract: A process for dyeing a mixed fibrous substrate comprising applying to the substrate,a) at least one disperse dye,b) at least one copper - containing direct or reactive dye, preferably in a sufficient amount to produce a dyeing greater than a 1/1 standard depth;c) a complexing agent having a stability constant (K-value) with the metal of the direct or reactive dye of from 6 to 17 inclusive;d) a lignin sulphonate dispersing agent; ande) an oxidizing agent capable of converting copper (I) to copper (II) at a temperature of 100.degree.-130.degree. C. at a pH of 5-7 in the process for dyeing the mixed substrate.Type: GrantFiled: August 27, 1991Date of Patent: March 23, 1993Assignee: Sandoz Ltd.Inventor: John A. Hook
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Patent number: 5120326Abstract: The present invention relates to a new dye-leveling agent for acid dyes, as well as a blend of the dye-leveling agent with a wetting agent. The acid dye-leveling agent enables polyamide-containing fibers to be evenly dyed without streaking during dyeing of the fibers. The dye-leveling agents are particularly useful with respect to nylon, wool, and silk fibers.Type: GrantFiled: June 30, 1989Date of Patent: June 9, 1992Assignee: Olin CorporationInventors: Thomas C. Hemling, Harry Stitzel
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Patent number: 5074887Abstract: Aqueous dye preparations are described which contain 15-40% by weight of dyes, 3-18% by weight of an anionic dispersant of the formula (1), 1-10% by weight of sodium lactate, 1-10% by weight of glycerol and/or propylene glycol, 0.1-5% by weight of a compound having monomer units of the general formula (2), 3-10% by weight of betaine monohydrate, 0-4% by weight of a compound having monomer units of the general formula (3) and 0.1-15% by weight of customary auxiliaries; preparations of this type have a long shelf life, are highly redispersible and do not form sediments; they are suitable in particular for the continuous dyeing of polyester textile materials or mixtures thereof with cellulose textile materials.Type: GrantFiled: October 23, 1990Date of Patent: December 24, 1991Assignee: Ciba-Geigy CorporationInventor: Zdenek Koci
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Patent number: 5053051Abstract: A mixture for the oxidative dyeing of human or animal hair, which is prepared immediately before application by mixing an oxidant and a dye base in cream, gel or powder form containing at least one oxidative dye and adjusting to a pH in the range of 8.0 to 10.5.The means contains in the freshly-prepared state a microencapsulated, acid-reacting compound in an amount which shifts the pH of the dye into the weakly alkaline (pH.ltoreq.8), neutral or acid range.The encapsulating material for the acid-reacting compound is soluble in the alkaline dye or changeable at least in its strength properties in the sense of a weakening, the wall thickness of the microcapsules being so adjusted that the walls are dissolved or weakened within a period between 10 and 60 minutes to such an extent that the acid-reacting compound is able by itself or upon the exertion of an additional mechanical stress to emerge into the dye.Furthermore, the invention relates to the use of the means for the redyeing of dyed hair.Type: GrantFiled: September 21, 1989Date of Patent: October 1, 1991Assignee: Goldwell GmbHInventors: Jurgen Tennigkeit, Herbert Lorenz, Hirotsugu Segawa
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Patent number: 5045083Abstract: The present invention relates to a process for dyeing polyamide comprisinga) one or more oxanilide U.V. absorbers (hereinafter defined as component a);b) one or more copper complexes, (hereinafter defined as component b); andc) one or more metal-free or metallized acid dyes in particular 1:2 metal complex dyes (hereinafter defined as component c) optionally together with one or more dyeing assistants.Type: GrantFiled: February 22, 1990Date of Patent: September 3, 1991Assignee: Sandoz Ltd.Inventor: Brian Bennett
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Patent number: 4935033Abstract: Natural polyamide fibres, in particular wool, are dyed by means of reactive dyes using the exhaust method in the presence of a dyeing assistant consisting of a combination of (a) quaternized ammonium compounds of polyglycol compounds and (b) of acidic esters or salts thereof derived from at least dibasic oxyacids and from polyglycol compounds, both the quaternary ammonium compounds and the acidic esters being derived from an aliphatic amine having 12 to 24 carbon atoms in the aliphatic moiety. The process comprises carrying out the dyeing in the additional presence of (c) a fatty alcohol/polyalkylene glycol ether of the formulaR-O-(alkylene-O.sub.m H (1)in which R is an aliphatic radical having at least 8 carbon atoms, "alkylene" is an ethylene radical or propylene radical and m is 3 to 25.Type: GrantFiled: September 21, 1988Date of Patent: June 19, 1990Assignee: Ciba-Geigy CorporationInventors: Walter Mosimann, Dieter Mausezahl
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Patent number: 4867919Abstract: A method for preparing a gas sensor includes forming a mixture containing an aqueous buffer solution including a dissolved dye, a polymeric precursor of a cross-linked polymeric material, and a cross-linking agent and reacting the polymeric precursor and the cross-linking agent in the mixture to form a gas sensor including micro-compartments of the aqueous buffer solution dispersed in the cross-linked polymeric material.Type: GrantFiled: January 26, 1989Date of Patent: September 19, 1989Assignee: Minnesota Mining And Manufacturing CompanyInventors: Masao Yafuso, John K. Suzuki
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Patent number: 4813972Abstract: The invention relates to chromium complexes of the formula ##STR1## in which A is the radical of a dicyclically metallizable azo or azomethine dye, B is the radical of a potentially at least bidentate bianionic complexible organic compound which contains no azo or azomethine group, L is a colorless monofunctional ligand, X is a fibre-reactive radical, Ka is a cation, K is 0 or 1, m is 1, 2 or 3, n is 1 or 2, and the X radical and the SO.sub.3.sup..crclbar. Ka group are each bonded to the radicals A and B, to a process for preparing the chromium complexes of the formula (1), and to a combined preparation and dyeing process.Type: GrantFiled: October 7, 1987Date of Patent: March 21, 1989Assignee: Ciba-Geigy CorporationInventors: Hans U. Schutz, Ulrich Schlesinger, Gerhard Back
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Patent number: 4776858Abstract: A composition for coloring bait which comprises (a) at least one biologically acceptable and palatable colorant; (b) a mordant for binding said colorant to live bait; (c) a surfactant or an acidulant; and (d) an aqueous carrier. A kit for coloring live bait to catch fish comprising (a), (b) and (c) of the composition also forms part of the invention.Type: GrantFiled: March 16, 1987Date of Patent: October 11, 1988Inventor: Roy A. P. Mayer
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Patent number: 4752299Abstract: A process for dyeing a mixed fibrous substrate comprising applying to the substrate at least one disperse dye and at least one metal containing direct and/or reactive dye in the presence of a complexing agent having a stability constant K value with the metal of the direct or reactive dye of from 6 to 17 inclusive.Type: GrantFiled: October 23, 1986Date of Patent: June 21, 1988Assignee: Sandoz Ltd.Inventors: Oskar Annen, John A. Hook
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Patent number: 4707161Abstract: A process for improving the lightfastness of dyeings obtained with acid dyes and/or metal complex dyes on polyamide textile materials, by treating the latter with 0.01-1% by weight of a copper hydroxamate before, during or after dyeing.Type: GrantFiled: July 21, 1986Date of Patent: November 17, 1987Assignee: BASF AktiengesellschaftInventors: Michael Thomas, Peter Neumann, Dieter Wegerle, Reinhold Krallmann
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Patent number: 4673410Abstract: The present disclosure is concerned with enhancing the solubility of dispersed anionic dyes upon the dilution of their dispersions with room temperature water. Concentrated dispersions of such dyes with acceptable stability and low shear viscosities are disclosed which are more readily diluted to dissolve the dispersed dyestuff because they contain certain chelating agents are described. These agents have at least one free or appropriately neutralized acid group, with carboxylic acid groups being preferred. The appropriae cations include ammonium or lithium ions. The free acid groups are subsequently neutralized with these appropriae cations so that the final dispersions are preferably about neutral, i.e have pH values about 7. A further improvement to the dilutability by the addition of a surfactant, preferably a non-ionic surfactant, is also discssed.Type: GrantFiled: November 19, 1985Date of Patent: June 16, 1987Assignee: Mobay CorporationInventors: Charles W. Sandefur, Thomas J. Thomas
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Patent number: 4631067Abstract: Disperse dyes are dischargeable to white with a print paste including a thickening agent, lithium hydroxide, an organic acid, a polyethylene glycol compound, a polyoxyethylene sorbitan fatty acid ester and a polyalkyleneglycol ether. The print paste discharges a number of known disperse dyes, some which have been conventionally thought of as being alkali-resistant. A method of discharge printing of synthetic textile materials (e.g. polyester) is also disclosed.Type: GrantFiled: April 8, 1985Date of Patent: December 23, 1986Assignee: Burlington Industries, Inc.Inventor: Samir Hussamy
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Patent number: 4615709Abstract: A cationic compound of the formula [I] below is used for improving the dyeing properties of a textile material by treating therewith the textile material before or after dyeing with an anionic dye. ##STR1## wherein A is a group of the formula [II]: ##STR2## wherein p and q are an integer of 1 to 8, n is an integer of 0 to 2, X is halogen, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are (C1-4) alkyl, OH-- or cyano-substituent-having (C1-4) alkyl or (C1-4) alkenyl, and Q.sub.1, Q.sub.2 and Q.sub.3 are: ##STR3## in which Y is halogen.Type: GrantFiled: December 17, 1984Date of Patent: October 7, 1986Assignee: Ipposha Oil Industries Co., Ltd.Inventor: Katsuaki Nakao
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Patent number: 4613334Abstract: A process for improving the lightfastness of dyeings obtained with acid dyes and/or metal complex dyes on polyamide textile materials, by treating the latter and 0.01-1% by weight of a copper hydroxamate before, during or after dyeing.Type: GrantFiled: July 23, 1984Date of Patent: September 23, 1986Assignee: BASF AktiengesellschaftInventors: Michael Thomas, Peter Neumann, Dieter Wegerle, Reinhold Krallmann
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Patent number: 4526701Abstract: This invention discloses a color stabilized aqueous detergent composition comprising in percent by weight of the composition (a) about 0.25% to about 95% surfactant; (b) about 0.0001% to about 0.5% dye; and (c) about 0.1% to about 5% polyhydroxy carboxylic acid or a salt thereof whereby color fading of said dye in said composition is substantially prevented.Type: GrantFiled: August 31, 1981Date of Patent: July 2, 1985Assignee: Lever Brothers CompanyInventor: Fred K. Rubin
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Patent number: 4384871Abstract: A dyestuff-containing microscopic capsule dispersion for record materials, which comprises at least one methine dyestuff represented by the general formula (I): ##STR1## wherein X means a phenyl, naphthyl, indolyl, .beta.-styryl, pyridyl, pyrimidyl or pyrazinyl group which may optionally be substituted, R.sub.1 -R.sub.6 are individually an amino, substituted amino, lower alkyl, cycloalkyl, lower alkoxy or lower haloalkyl group or a halogen or hydrogen atom, R.sub.7 and R.sub.Type: GrantFiled: February 10, 1982Date of Patent: May 24, 1983Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Makoto Asano, Kiyoharu Hasegawa, Hiroyuki Akahori, Michihiro Tsujimoto
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Patent number: 4300900Abstract: A dye preparation containing at least one dye insoluble or difficultly soluble in water, an anionic or nonionic dispersing agent, at least one metal complex consisting of a polyvalent cation and at least one complexing agent, and optionally further additives, water and/or organic solvent.Type: GrantFiled: June 9, 1980Date of Patent: November 17, 1981Assignee: Ciba-Geigy CorporationInventors: Roland Putzar, Hans Fierz