Nitrile Patents (Class 8/603)
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Publication number: 20110277249Abstract: Colored high-strength fibers of ultra-high-molecular-weight polyolefins and methods of dyeing the high-strength fibers are disclosed herein.Type: ApplicationFiled: May 14, 2010Publication date: November 17, 2011Inventors: Ferass Abuzaina, Ali Irfan
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Publication number: 20100122729Abstract: The present invention relates to a dye compound represented by the following formula (I), or a salt thereof: wherein R1, R2, R3, R4, D1, D2, B, and n are defined the same as the specification, and also relates to a photoelectric component using the same. The dye compound of the present invention is suitable for Dye-Sensitized Solar Cell (DSSC). Hence, the photoelectric characteristics of the DSSC can be improved by using the dye compound of the present invention.Type: ApplicationFiled: January 22, 2009Publication date: May 20, 2010Applicant: Everlight USA, Inc.Inventors: Ming-Si Wu, Wei-Cheng Tang
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Patent number: 7294290Abstract: The invention relates to novel photochromic composition for controlling the transmission of light comprising an organic polymer, photochromic dye, photosensitizer and an electron acceptor. The invention also includes a method for preparing photochromic films.Type: GrantFiled: June 17, 2004Date of Patent: November 13, 2007Assignee: NGX, Inc.Inventor: Ramanujan Srinivasa
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Patent number: 6231622Abstract: The dye composition for fibers, especially keratin-containing fibers, contains at least one indane derivative compound of formula I, or a physiologically compatible, water-soluble salt thereof: wherein R1 is hydrogen, a halogen atom, a cyano group, a hydroxy group, a C1— to C4— alkoxy group, a C1— to C6— alkyl group, a nitro group, an amino group, an alkylamino group, a dialkylamino group, a —C(O)H group, a —COOR3 group, a —SO2R3 or a —C(O)CH3 group, wherein R3 is hydrogen, phenyl or a C1— to C6— alkyl group; and R2 is hydrogen, a C1— to C6— alkyl group or a phenyl group.Type: GrantFiled: October 20, 1999Date of Patent: May 15, 2001Assignee: Wella AktiengesellschaftInventors: Laurent Chassot, Laurence Descloux
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Patent number: 5972044Abstract: An aqueous or aqueous-alcoholic composition for dyeing natural or synthetic fibers, especially hair, contains a combination of at least one cyclic oxo-substituted enediol according to formula I: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and independently of each other represent a hydrogen atom or an alkali metal atom, or R.sub.1 and R.sub.2 together represent an alkaline earth metal atom and n=0, 1, 2 or 3; and at least one member selected from the group consisting of malonic acid dinitrile, maleic acid diaminodinitrile, 2,5-diamino-6-nitropyridine, 1,2,3,4-tetrahydro-6-nitroquinoxaline, 7-amino-3,4-dihydro-6-nitro-2H-1,4-benzoxazine and substituted nitrobenzene compounds; as well as water and at least one cosmetic ingredient including solvents other than water, surfactants, thickeners, care materials and adjuvant materials.Type: GrantFiled: March 23, 1998Date of Patent: October 26, 1999Assignee: Wella AGInventors: Hans-Juergen Braun, Pascal Andre Semadeni
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Patent number: 5962691Abstract: Pyridone dyes of the formula I ##STR1## where X is nitrogen or CH,R.sup.1 is a 5-membered or 6-membered carbocyclic or heterocyclic radical,R.sup.2 is cyano, carbamoyl, C.sub.1 -C.sub.6 -alkoxycarbonyl or C.sub.1 -C.sub.4 -alkanoyl andR.sup.3 is unsubstituted or substituted C.sub.1 -C.sub.13 -alkyl, unsubstituted or substituted phenyl or unsubstituted or substituted amino,a method for their thermal transfer and a method for coloring or printing synthetic materials by means of the novel dyes.The invention concerns pyridone dyes of the formula (I) in which X is nitrogen or CH, R.sup.1 is a five-membered or six-membered carbocyclic or heterocyclic group, R.sup.2 is cyano, carbamoyl, C.sub.1 -C.sub.6 alkoxycarboyl or C.sub.1 -C.sub.4 alkanoyl and R.sup.3 is optionally substituted C.sub.1 -C.sub.13 alkyl, optionally substituted phenyl or optionally substituted amino.Type: GrantFiled: May 9, 1997Date of Patent: October 5, 1999Assignee: BASF AktiengesellschaftInventors: Andreas Johann Schmidt, Rudiger Sens, Karl-Heinz Etzbach
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Patent number: 5879411Abstract: A non-oxidative dye composition for keratin fibers contains an o-benzoquinone compound of formula (I): ##STR1## wherein R1, R2, R3 and R4 are each, independently of each other, hydrogen, chlorine, an alkyl group with from 1 to 5 carbon atoms, an alkoxy group with from 1 to 5 carbon atoms, an alkylenedioxy group with from 1 to 2 carbon atoms or an amino group --NR.sup.5 R.sup.6, wherein R.sup.5 and R.sup.6 are each, independently of each other, hydrogen, an alkyl group having from 1 to 6 carbon atoms or an aryl group; and at least one amino- or hydroxy-compound of formula (II), X--A--Y, wherein X represents a nitro group, a cyano group or a sulfonate group; Y represents a hydroxy group or an amino group --NR.sup.a R.sup.b, wherein R.sup.a and R.sup.Type: GrantFiled: December 16, 1997Date of Patent: March 9, 1999Assignee: Wella AGInventors: Hans-Juergen Braun, Gisela Umbricht
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Patent number: 5865856Abstract: The oxidation hair dye composition is based on a combination of coupler substance and developer substance, and includes, as developer substance, at least one 2,5-diaminobenzonitrile compound of the formula (I), ##STR1## in which R.sup.1 and R.sup.2, independently of each other, are selected from the group consisting of H, alkyl groups having 1 to 6 carbon atoms, hydroxyalkyl groups having 2 to 4 carbon atoms and dihydroxyalkyl groups having 3 to 4 carbon atoms, with the proviso that both of the R.sup.1 and R.sup.2 groups are not both hydrogen at the same time, or a physiologically compatible water-soluble salt thereof. The invention also includes new 2,5-diaminobenzonitrile compounds of formula I.Type: GrantFiled: March 17, 1997Date of Patent: February 2, 1999Assignee: Wella AktiengesellschaftInventors: Helmut Keller, Wolfgang Balzer
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Patent number: 5772699Abstract: An aqueous reactive dye composition is disclosed. The aqueous reactive dye composition has improved storage stability and contains a water-soluble reactive dye and a chelating agent. The chelating agent is present in a sufficient concentration to maintain the pH of the aqueous reactive dye composition in the range of about 3.0 to about 7.0 and, preferably, about 5.0 to about 6.5. Desirable chelating agents are dicarboxylic acids, such as succinic acid, or amino carboxylates, such as nitrilotriacetic acid. A method of stabilizing an aqueous reactive dye composition is disclosed and includes the step of dissolving a polycarboxylic acid or an amino carboxylate in an aqueous solution of a water-soluble reactive dye in a sufficient concentration to stabilize the pH of the composition.Type: GrantFiled: February 10, 1997Date of Patent: June 30, 1998Assignee: Crompton & Knowles CorporationInventor: Andrew D. Boyer
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Patent number: 5746778Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autoclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions.Type: GrantFiled: May 23, 1996Date of Patent: May 5, 1998Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.Inventors: Axel Jankewitz, Gerhard Lugert
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Patent number: 5567206Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group, consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autioclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions. A method for staining wood includes placing the wood into an autoclave composed of non-rust-resistant steel; submerging the wood in the wood stain; and staining the wood under pressure and temperature conditions effective therefor.Type: GrantFiled: July 31, 1995Date of Patent: October 22, 1996Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.Inventors: Axel Jankewitz, Gerhard Lugert
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Patent number: 4841090Abstract: Fluorochemical amine salt compounds containing one or more fluoroaliphatic radicals and one or more salt-forming amino groups which have cyanoalkyl groups as N-substituents groups, such compounds being useful as treating agents for fibrous substrates, such as textiles, e.g., carpet, to modify surface properties thereof, viz., to impart oil and water repellency to the surface of said substrates.Type: GrantFiled: September 29, 1987Date of Patent: June 20, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventor: Kalyanji U. Patel
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Patent number: 4833235Abstract: Disazo compounds of the formula ##STR1## and salt thereof, D is the radical of a diazo component of the benzene or naphthalene series.K is the radical of a heterocyclic coupling component of the aminopyrazole-, pyridone- or barbituric acid-series, n is 1 to 4,R.sub.1 is hydrogen, C.sub.1-4 alkyl or substituted C.sub.1-4 alkyl,each of R.sub.2 and R.sub.3 is independently hydrogen, halo, C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy, substituted C.sub.1-4 alkoxy, --NHCO--Rhd 5, amino, substituted amino or a quaternary ammonium group, wherein R.sub.5 is C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy or amino,R.sub.4 is hydrogen, C.sub.1-4 alkyl, C.sub.Type: GrantFiled: October 7, 1987Date of Patent: May 23, 1989Assignee: Sandoz Ltd.Inventor: Reinhard Pedrazzi
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Patent number: 4787912Abstract: An assistant for dyeing or whitening synthetic nitrogen-containing fibre material, which comprises(A) a sulfonated polycarboxylate,(B) an anionic surfactant,(C) a nonionic surfactant, and(D) a water-soluble organic, polar solvent.The assistant is especially useful for dyeing or whitening polyamide fibres.Type: GrantFiled: January 28, 1987Date of Patent: November 29, 1988Assignee: Ciba-Geigy CorporationInventors: Heinz Abel, Helmut Raisin
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Patent number: 4661116Abstract: Textile fabrics formed at least partially of cationic dyeable polyester fibers are dyed in a continuous process with an aqueous dyebath comprising(a) 0 to 5 g/l of thickener;(b) cationic dyestuffs in an amount sufficient to dye the cationic dyeable polyester fibers to the desired depth of color;(c) 2 to 100 g/l of a partially sulfated adduct of ethylene oxide with an alkyl phenol or C.sub.8 to C.sub.16 fatty alcohols;(d) 2 to 60 g/l of nonionic or anionic surfactants; and(e) 5 to 50 g/l of at least one organic compound selected from the group consisting of aromatic nitrile ethers and ethoxylated chlorophenols.The fabrics are continuously dyed by padding, immersing, spraying or otherwise applying the dyestuffs, steaming the fabrics in their wet condition, and subsequently washing and drying.Type: GrantFiled: January 31, 1985Date of Patent: April 28, 1987Assignee: Collins & Aikman CorporationInventors: Frederick E. Barwick, III, Kyle R. Pearce
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Patent number: 4657558Abstract: Textile fabrics formed at least partially of polyester fibers are dyed with an aqueous dyebath comprising(a) 0 to 5 g/l of thickener;(b) disperse dyestuffs in an amount sufficient to dye the fibers to the desired depth of color;(c) 2 to 100 g/l of a partially sulfated adduct of ethylene oxide with an alkyl phenyl or C.sub.8 to C.sub.16 fatty alcohols;(d) 0 to 60 g/l of nonionic or anionic surfactants; and(e) 5 to 50 g/l of at least one organic compound selected from the group consisting of aromatic nitrile ethers and ethoxylated chlorophenols.The fabrics may be continuously dyed by padding, immersing, spraying or otherwise applying the dyestuffs, steaming the fabrics in their wet condition, and subsequently washing and drying.Type: GrantFiled: September 20, 1984Date of Patent: April 14, 1987Assignee: Collins & Aikman CorporationInventor: Dieter Huxoll
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Patent number: 4453946Abstract: The invention relates to a dyeing assistant comprising at least(A) an O-cyanoethylated compound of the formulaR(O--CH.sub.2 CH.sub.2 CN).sub.n, (1)wherein R is an n-valent aliphatic, cycloaliphatic or araliphatic radical, and n is 1 to 5,(B) an anionic surfactant(C) a non-ionic surfactant and optionally at least one of the following components(D) an aliphatic alcohol containing 5 to 18 carbon atoms, a siloxane-oxyalkylene copolymer or a mixture thereof, and(E) a polar solvent.This assistant is used in particular for dyeing synthetic fibre material, preferably polyester fibres, to improve levelness and crockfastness and to increase the dye yield.Type: GrantFiled: April 22, 1982Date of Patent: June 12, 1984Assignee: Ciba-Geigy CorporationInventors: Heinz Abel, Paul Schafer, Hans-Ulrich Berendt
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Patent number: 4441885Abstract: The invention relates to a novel anticrease finishing composition which comprises at least(A) an O-cyanoethylated compound of the formula(1) R(O--CH.sub.2 CH.sub.2 CN).sub.n,wherein R is an n-valent aliphatic, cycloaliphatic or araliphatic radical, and n is 1 to 5, and(B) a carboxylated polypropylene oxide adduct, or salt thereof, which adduct is obtainable from(a) an aliphatic diol having an average molecular weight of at most 2600,(b) an aliphatic dicarboxylic acid, or anhydride thereof, containing 4 to 10 carbon atoms,(c) an adduct of propylene oxide and an at least trihydric aliphatic alcohol containing 3 to 10 carbon atoms, and(d) a fatty acid containing 8 to 22 carbon atoms, and optionally,(C) an aliphatic alcohol containing 5 to 18 carbon atoms, a siloxane-oxyalkylene copolymer, or a mixture thereof, and/or(D) a polar solvent.The novel composition is used in dyeing or whitening textile material which contains polyester fibres.Type: GrantFiled: April 22, 1982Date of Patent: April 10, 1984Assignee: Ciba-Geigy CorporationInventors: Heinz Abel, Paul Schafer
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Patent number: 4424061Abstract: An agent for improving the color fastness of dyed cotton fibers and textiles to chlorinated water which comprises a specific diamine compound. The combination of the diamine and hydrolyzable tannin further increases the color fastness to chlorinated water. The tannin can be more strongly fixed to the fibers by further treating with a metal salt, whereby an excellent color fastness to chlorinated water can be maintained for a prolonged period of time.Type: GrantFiled: February 17, 1982Date of Patent: January 3, 1984Assignee: Dainippon Pharmaceutical Co., Ltd.Inventors: Yoshiyuki Shimohiro, Akio Murata, Chiyoko Nisioka
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Patent number: 4381185Abstract: Water-fast printing of paper stock using a colorant solution containing water-soluble polymeric dyes is accomplished by a three step process. Step 1 is selecting a paper stock characterized as containing at least 250 ppm by weight of cation, particularly a polyvalent metal cation (especially Ca.sup.2+ or Al.sup.3+). In step 2, a colorant solution is applied to the paper. This solution is water-based, containing up to 30 wt % of an organic paper-penetrating agent (such as an alkanol), and at least 500 ppm of one or more anionic group-possessing polymeric colorants. In step 3, the solvent is exhausted by either evaporation (which may be aided by the application of heat) or diffusion into the paper stock, or by a combination of both.Type: GrantFiled: June 9, 1981Date of Patent: April 26, 1983Assignee: DynapolInventors: Sally A. Swanson, Ned M. Weinshenker, Robert E. Wingard, Jr., Daniel J. Dawson
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Patent number: 4309179Abstract: A method of printing on textile with pigmented aqueous inks using the flexographic printing process. The printing inks contain water soluble acrylic resin, water soluble thermosetting aminoplast, and elastomeric latex polymer as pigment binder. The inks have a viscosity of 3 to 15 poises at infinite shear.Type: GrantFiled: July 24, 1980Date of Patent: January 5, 1982Assignee: Inmont CorporationInventors: Arthur R. Heuser, Richard Bolstad
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Patent number: 4297103Abstract: Process for the continuous one-bath dyeing of pile fabrics made of acrylic fibres in the pile with a cotton base fabric by the pad-steam process with basic and substantive dyestuffs, characterized in that salts of alkyl sulphates of the general formulaR--O--SO.sub.3.sup..crclbar. M.sup..sym.in whichR represents a straight-chain or branched alkyl radical with 10-16 carbon atoms andM represents an alkali metal, alkaline earth metal, ammonium, alkylammonium or alkanolammonium ion,are used as auxiliaries in the dyebath.Type: GrantFiled: October 26, 1979Date of Patent: October 27, 1981Assignee: Bayer AktiengesellschaftInventors: Udo-Winfried Hendricks, Klaus Wollny
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Patent number: 4233028Abstract: Described is a process for the level dyeing of polyacrylonitrile materials of slow, normal and rapid absorptive capacity with an aqueous dye liquor, which process comprises using a liquor containing at least one migrating cationic dye as well as, if required, further additives; and adding to the liquor, before, during or after dyeing, at least one organic cationic migration auxiliary.This process renders possible by the use of organic migration auxiliaries the obtainment of level single-shade and, in particular, combination-shade dyeings at normal dyeing temperatures.Particularly suitable migrating cationic dyestuffs are those having a more or less delocalized positive charge, the cation weight of which dyestuffs is smaller than 310, the parachor smaller than 750 and the log P (relative lipophil property) smaller than 3.6.Particularly suitable organic migration auxiliaries are those of which the cation weight is smaller than 250, the parachor smaller than 700 and the log P smaller than 6.4.Type: GrantFiled: January 24, 1978Date of Patent: November 11, 1980Assignee: Ciba-Geigy CorporationInventors: Josef Koller, Ulrich Horn, Peter Moser, Manfred Motter, Pierre Galafassi