Ketone Patents (Class 8/607)
  • Publication number: 20030028981
    Abstract: An improved method of making a series of bead or microsphere or particle populations characterized by subtle variation in a proportion or ratio of at least two fluorescent dyes distributed within a single bead of each population is provided. These beads, when excited by a single excitation light source are capable of giving off several fluorescent signals simultaneously. A set containing as many as 64 distinct populations of multicolored, fluorescent beads is provided and when combined with analytical reagents bound to the surface of such beads is extremely useful for multiplexed analysis of a plurality of analytes in a single sample. Thus, methods of staining polymeric particles, the particles themselves, and methods of using such particles are claimed.
    Type: Application
    Filed: July 1, 2002
    Publication date: February 13, 2003
    Inventors: Don J. Chandler, Beth A. Lambert, Janet J. Reber, Stacie L. Phipps
  • Patent number: 6514295
    Abstract: An improved method of making a series of bead or microsphere or particle populations characterized by subtle variation in a proportion or ratio of at least two fluorescent dyes distributed within a single bead of each population is provided. These beads, when excited by a single excitation light source are capable of giving off several fluorescent signals simultaneously. A set containing as many as 64 distinct populations of multicolored, fluorescent beads is provided and when combined with analytical reagents bound to the surface of such beads is extremely useful for multiplexed analysis of a plurality of analytes in a single sample. Thus, methods of staining polymeric particles, the particles themselves, and methods of using such particles are claimed.
    Type: Grant
    Filed: April 13, 1999
    Date of Patent: February 4, 2003
    Assignee: Luminex Corporation
    Inventors: Don J. Chandler, Beth A. Lambert, Janet J. Reber, Stacie L. Phipps
  • Publication number: 20020144362
    Abstract: A composition for dyeing material of synthetic aromatic polyamide fibers, said composition containing a mixture of (a) a cationic dye and (b) a cyclohexenone as a dye assistant. Preferably, 2-cyclohexen-1-one,3,5,5-trimethyl is the dye assistant.
    Type: Application
    Filed: February 2, 2001
    Publication date: October 10, 2002
    Inventors: Darrin McBane Guthrie, Harold Kenneth Greeson, Malcolm S. Haith
  • Patent number: 6458168
    Abstract: The present invention relates to the use, for dyeing keratin fibers, of at least one aliphatic cationic amine and of at least one compound chosen from an aldehyde, a ketone, a quinone and a diiminoisoindoline or 3-aminoisoindolone derivative, in order to obtain, by reaction without an oxidizing agent, a coloration of the said keratin fibers. The invention also relates to dye compositions comprising these compounds and to dyeing agents for using them.
    Type: Grant
    Filed: October 25, 2000
    Date of Patent: October 1, 2002
    Assignee: L'Oreal S.A.
    Inventors: Alain Lagrange, Hervé Andrean
  • Patent number: 6451067
    Abstract: The present invention relates to the use, for dyeing keratin fibres, of at least one heterocyclic cationic amine and of at least one compound chosen from an aldehyde, a ketone, a quinone and a diiminoisoindoline or 3-aminoisoindolone derivative, in order to obtain, by reaction without an oxidizing agent, a coloration of the said keratin fibres. The invention also relates to dye compositions comprising these compounds and to dyeing agents for using them.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: September 17, 2002
    Assignee: L'Oreal S.A.
    Inventors: Alain Lagrange, Hervé Andrean
  • Patent number: 6241788
    Abstract: Stabilized metachromatic dyes, especially at application concentrations, comprising metachromatic dyes dissolved in one or more non-aqueous solvents, as well as metachromatic dyes dissolved in pH stabilized aqueous solutions. Also, various combinations of treatments are disclosed for stabilizing metachromatic dyes.
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: June 5, 2001
    Assignee: BetzDearborn Inc.
    Inventors: Kristin E. Buentello, Larry M. Kye, Elizabeth Yibin Zhang, Victoria Rafalovsky, Alan M. Agree
  • Patent number: 6221113
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25° C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: April 24, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Jürgen Geiwiz
  • Patent number: 6136044
    Abstract: Micro-particles of transition metals or their compounds can be generated as an integral part of a fiber by first attaching a nucleating agent to the fiber, and then adding a solution of metal ions. The ions are reduced by the nucleating agent in the fiber, and micro-particles are generated in or on the fiber. Because of the strong color signal resulting from a low concentration of metal micro-particles, the method is cost effective even when using gold or titanium ions. Various colors were generated by changing the size and spacing of the micro-particles, the metal or metal complex used, and the characteristics of the fiber. The dyed fibers displayed colors ranging from pink, red, purple, yellow, orange, peach, brown, gold, silver, grey, green, and black. These colors resisted bleaching by either chemicals or light.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: October 24, 2000
    Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical College
    Inventor: William J. Todd
  • Patent number: 6093221
    Abstract: This invention concerns a process for reducing dyes of the group consisting of sulfur and vat dyes. The reduction is carried out in an aqueous alkali medium using isomaltulose or a mixture containing isomaltulose as the reducing agent.
    Type: Grant
    Filed: July 22, 1999
    Date of Patent: July 25, 2000
    Assignee: Sudzucker Aktiengesellschaft
    Inventors: Dietmar R. Grull, Alireza Haji Begli, Nikolai Kubadinow, Markwart Kunz, Mohammad Munir
  • Patent number: 5972044
    Abstract: An aqueous or aqueous-alcoholic composition for dyeing natural or synthetic fibers, especially hair, contains a combination of at least one cyclic oxo-substituted enediol according to formula I: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and independently of each other represent a hydrogen atom or an alkali metal atom, or R.sub.1 and R.sub.2 together represent an alkaline earth metal atom and n=0, 1, 2 or 3; and at least one member selected from the group consisting of malonic acid dinitrile, maleic acid diaminodinitrile, 2,5-diamino-6-nitropyridine, 1,2,3,4-tetrahydro-6-nitroquinoxaline, 7-amino-3,4-dihydro-6-nitro-2H-1,4-benzoxazine and substituted nitrobenzene compounds; as well as water and at least one cosmetic ingredient including solvents other than water, surfactants, thickeners, care materials and adjuvant materials.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: October 26, 1999
    Assignee: Wella AG
    Inventors: Hans-Juergen Braun, Pascal Andre Semadeni
  • Patent number: 5961670
    Abstract: New sulfur dyes comprising in their preparation at least one sulfur dye intermediate of the formula I ##STR1## wherein R and R.sub.1 are independently nitro, nitroso or amino, are produced by including in their preparation at least one modifying agent selected from the group of: A) an aldehyde; B) urea; C) a benzoquinone or naphthoquinone; and D) monoethanolamine or by treating an already prepared sulfur dye involving such an intermediate in its preparation, with at least one aldehyde, benzoquinone or naphthoquinone or with monoethanolamine.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: October 5, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Philip N. Cote, Xiangfu Lan, Alex I. Shakhnovich, Manuel Jose Domingo
  • Patent number: 5955005
    Abstract: An aqueous dispersion comprising at least one of the UV absorbing compounds of the following formulae I, II or III as below defined: A--B (I); A--C--A (II); or B--A--B (III); wherein in Formula (I) and (II) ##STR1## and in Formula III, A is ##STR2## Y being a direct bond, a substitute C.sub.1-4 alkylene group, ##STR3## and R.sub.1 to R.sub.5 independently of each other are hydrogen; C.sub.4-4 alkyl, the alkyl optionally being substituted; aryl; heterocyclyl; or any two of R.sub.1 to R.sub.5 which are adjacent, together form part of a ring, with the proviso that no more than four of R.sub.1 to R.sub.5 are hydrogen.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: September 21, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Jurg Heller, Jean-Luc Mura
  • Patent number: 5944856
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: August 31, 1999
    Assignee: Clariant Finanace (BVI) Limited
    Inventor: Jurgen Geiwiz
  • Patent number: 5869627
    Abstract: A composition of a water-soluble bis-azo dye of the Formula (1) and an oxidising agent. ##STR1## wherein A is optionally substituted phenyl or optionally substituted naphthyl;B is optionally substituted phenylene or optionally substituted naphthylene;R.sup.1 is H or sulpho;R.sup.2 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted acyl;R.sup.3 is H, optionally substituted aryl, optionally substituted alkyl or a group, -D-E,D is optionally substituted C.sub.2-6 -alkylene; andE is a group of the Formula (1a): ##STR2## R.sup.4 & R.sup.5 each independently is H or optionally substituted alkyl; andR.sup.6 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted acyl.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: February 9, 1999
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Ronald Wynford Kenyon, Paul Wight
  • Patent number: 5804352
    Abstract: A dye solution comprising a laser recordable dye and a solvent for the dye that has (a) a solvent functional group selected from esters, ketones and ethers; and (b) the solvent functional group has as hindering groups (i) at least one t-butyl group on one side thereof or (ii) two groups on opposite sides thereof selected from the group consisting of isoamyl, t-butyl, isobutyl and isopropyl; provided that both groups cannot be isopropyl and (c) the hindering groups are adjacent to the solvent functional group.
    Type: Grant
    Filed: October 14, 1997
    Date of Patent: September 8, 1998
    Assignee: Eastman Kodak Company
    Inventors: Michael Paul Cunningham, Thomas Michael Smith
  • Patent number: 5626634
    Abstract: A liquid dyestuff composition comprising a solvent-soluble dyestuff and a water miscible organic solvent, the composition comprising over 25% by weight of dissolved dyestuff.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: May 6, 1997
    Assignee: Sandoz Ltd.
    Inventors: J urgen Goldmann, Bansi L. Kaul
  • Patent number: 5611818
    Abstract: By reducing a sulphur dye (S) in aqueous medium with a reducing carbonyl compound in the presence of alkali metal hydroxide and optionally alkali metal (bi)sulphite at temperatures above 60.degree. C. and drying the reaction mixture, there are obtained very stable leuco sulphur dyes (L), which are practically free of sulphides and polysulphides, are readily and completely soluble in water and are usable for the dyeing of substrates dyeable with sulphur dyes, by which a disturbing development of H.sub.2 S or a disturbing inorganic sulphide occurrance in the waste water can be efficiently avoided; by spray-drying in a drying time <4 minutes as described there are obtained sulphide-free, stable leuco sulphur dyes (L) readily soluble in water and particularly suitable for sulphide-free dyeing, in particular for the dyeing of polyamidic fibrous substrates, especially of wool.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: March 18, 1997
    Assignee: Sandoz Ltd.
    Inventor: Manuel J. Domingo
  • Patent number: 5558677
    Abstract: A process for dyeing and printing textile materials consisting of cellulose fibers or containing cellulose fibers in a blend with other fibers in an aqueous medium at above pH 12 with vattable dyes in the presence of cyclic compounds which contain at least one instance of the structural unit ##STR1## in the ring of the molecule as reducing agents and finishing the dyeing in a conventional manner.
    Type: Grant
    Filed: February 6, 1995
    Date of Patent: September 24, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Henric Wagenmann, Ulf Baus, Eberhard Beckmann, Erich Kromm
  • Patent number: 5498345
    Abstract: Aqueous stable dispersions of a mixture of sparingly soluble UV absorbers, which comprises(a) 5 to 50% by weight of a mixture of a benzotriazole of formula ##STR1## and a 2-hydroxybenzophenone of formula ##STR2## wherein R is halogen, C.sub.1 -C.sub.12 alkyl, lower alkoxy, lower alkoxycarbonyl, cycloalkyl, aryl, C.sub.1 -C.sub.12 alkylaryl or aralkyl, and the rings A and B, each independently of the other, may be further substituted by halogen, hydroxy, lower alkyl, lower alkoxy or lower alkoxycarbonyl,R.sub.1 is hydrogen, hydroxy, C.sub.1 -C.sub.14 alkoxy or phenoxy,R.sub.2 is hydrogen, halogen or lower alkyl,R.sub.3 is hydrogen, hydroxy or lower alkoxy, andR.sub.4 is hydrogen or hydroxy,(b) 2 to 18% by weight of an anionic compound, and(c) 0 to 10% by weight of a nonionic compound.These dispersions of a mixture of UV absorbers are excellent compositions for enhancing the lightfastness of dyeings on synthetic fibers and, in particular, on polyester fibers or acid-modified fibers.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: March 12, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Jollenbeck, Alfred J. Neukom
  • Patent number: 5470356
    Abstract: A sulfur dye or sulfurized vat dye is treated in an aqueous reducing medium, preferably an aqueous mixture of alkali and reducing sugar, to form a solution which is then oxidized to form particles of the dye having improved characteristics.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: November 28, 1995
    Inventor: Laszlo A. Meszaros
  • Patent number: 5300122
    Abstract: PEKK fiber is dyed with a disperse dye in an organic dye carrier.
    Type: Grant
    Filed: October 1, 1992
    Date of Patent: April 5, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: David J. Rodini
  • Patent number: 5244476
    Abstract: The present invention relates to compounds of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, x and y are defined as in the description, processes for their preparation, their use for improving the light stability of polyester dyeings and a dyeing process and dye preparations.
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: September 14, 1993
    Assignee: Cassella AG
    Inventors: Joachim Schulz, Gunter Bartels
  • Patent number: 5215545
    Abstract: Poly(m-phenyleneisophthalamide) fabrics are printed and optionally flame retarded in a two-step process in which the dye diffusion promoting agent N-octyl-2-pyrrolidone optionally with a flame retardant is applied following by printing and print fixation.
    Type: Grant
    Filed: March 16, 1992
    Date of Patent: June 1, 1993
    Assignees: Burlington Industries, Inc., ProChroma Technologies, Inc.
    Inventors: Barbara J. Cates, Phillip H. Riggins, David R. Kelly
  • Patent number: 5210316
    Abstract: The present invention provides a modified turmeric. The modified turmeric is a phosphorylated turmeric that results in a structure having greatly improved stability in the presence of light, and solubility in the presence of a solution. The invention produces a natural dye for use as a substitute for yelIow dye No. 5.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: May 11, 1993
    Assignee: University of Arkansas
    Inventors: Luoqing Yang, Ron Buescher
  • Patent number: 5181935
    Abstract: Processes for improving the thermal and/or photochemical stability of undyed and dyed polyamide fibers by treatment with an agent from an aqueous bath containing (A) a compound of the formula (I) defined in claim 1 and (B) a UV absorber.
    Type: Grant
    Filed: May 24, 1991
    Date of Patent: January 26, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Francesco Fuso
  • Patent number: 5096459
    Abstract: Aromatic polyamide fibers, which have been dried and/or crystallized, are steam dyed with a water-soluble dye padded onto the surface of fibers, along with a small amount of a carrier.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: March 17, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Hamid M. Ghorashi
  • Patent number: 5080688
    Abstract: A lens reduces eye strain and fatigue due to glare, after images, reflections or other visual noise incident upon an observer of a visual display terminal. The lens includes a light transmitting plastic body having a convex shaped outer surface for deflecting stray angular radiation and a body provided, in combination with, an ultraviolet absorber to block the transmission of ultraviolet radiation, a colored dye to diminish the intensity of any fluorescent light incident upon the lens and to diminish the transmission of either or both green color radiation or yellow color radiation through the lens and a grey dye to reduce the transmission of incident light.
    Type: Grant
    Filed: March 15, 1990
    Date of Patent: January 14, 1992
    Inventor: Michael L. Cohen
  • Patent number: 5074885
    Abstract: A process for the dyeing of wool with anionic dyes is described, wherein the wool is dyed in the presence of a UV absorber and bleached oxidatively and then bleached reductively in a new bath.This process makes it possible to produce very bright, brilliant shades.
    Type: Grant
    Filed: August 31, 1990
    Date of Patent: December 24, 1991
    Assignee: Ciba-Geigy Corporation
    Inventor: Gerhard Reinert
  • Patent number: 5069681
    Abstract: There is disclosed a process for the photochemical stabilization of dyed polyamide fibre materials, which comprises treating the dyed material with an aqueous foamed composition which contains at least a non-dyeing copper complex of bisazomethines, acylhydrazones, semicarbazones or thiosemicarbazones of aromatic aldehydes or ketones or oximes.By means of the process of this invention it is possible to prevent wastewater from being contaminated with copper-containing impurities.
    Type: Grant
    Filed: December 26, 1990
    Date of Patent: December 3, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Thys Bouwknegt, Claude Dietz
  • Patent number: 4990164
    Abstract: A process is described for the photochemical stabilization of undyed and dyed polyamide fibre material, and blends thereof with other fibres, using photochemically stabilizing compositions based on copper compounds of phenols, which process comprises treating the polyamide fibre material with fibre-reactive organic copper complexes of the reaction products of o-hydroxybenzoyl derivatives of the formula ##STR1## wherein R is hydrogen or C.sub.1 -C.sub.4 alkyl and the OH substituent is located in the 3-, 4- or 5-position, with aliphatic diamines or hydroxylamine. The copper complex compounds are distinguished by a high rate of exhaustion on to the polyamide fibre material, a feature which is significant in economic terms because of the low consumption of product.
    Type: Grant
    Filed: September 27, 1989
    Date of Patent: February 5, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Helmut Huber-Emden, Gerhard Reinert
  • Patent number: 4950306
    Abstract: Process for dyeing and printing cellulosic fiber materials with vat dyes in the presence of enediols as reducing agents and alkali, using in addition small amount of organic water-miscible solvents, for example low molecular weight alcohols, when reducing the vat dyes. The vatting of the vat dyes proceeds uniformly and completely within a relatively short time, and the resulting vat dyes are reproducible and notable for high levelness and fastness properties.
    Type: Grant
    Filed: July 27, 1989
    Date of Patent: August 21, 1990
    Assignee: Ciba-Geigy Corporatioin
    Inventors: Walter Marte, Paul Rys
  • Patent number: 4929249
    Abstract: Textile materials made of polyester, triacetate, acetate or polyamide or mixtures thereof are printed by the discharge printing or discharge resist printing technique by using as discharging agent for disperse dyes a 3-aminoreductone of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and each is hydrogen, methyl or ethyl and R.sup.4 is linear or branched alkyl or alkenyl of from 1 to 20 carbon atoms, which may be monosubstituted or polysubstituted by hydroxyl, alkoxy of from 1 to 3 carbon atoms in the alkyl or acetoxy, or is a radical --(CH.sub.2 --CH.sub.2 --O).sub.n H where n is from 1 to 10 and which may be etherified with alkyl of from 1 to 3 carbon atoms or esterified with acetyl, or R.sup.4 together with the N-atom is the radical of an aliphatic .alpha.- or .beta.-amino acid of from 2 to 15 carbon atoms, in which case the carboxyl group may be present in neutralized form as an alkali metal, alkaline earth metal or ammonium salt or in esterified form as a C.sub.1 -c.
    Type: Grant
    Filed: May 4, 1989
    Date of Patent: May 29, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Lechtken, Peter Kutschera
  • Patent number: 4911732
    Abstract: Improved light fastness of dyeings on textile polyester material with disperse dyes is obtainable by dyeing in the presence of certain benzophenone ether esters, some of which are novel.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: March 27, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Neumann, Dieter Wegerle, Reinhold Krallmann
  • Patent number: 4874391
    Abstract: A process for the photochemical stabilization of polyamide fiber material or mixtures thereof with other fiber materials which comprises treating the fiber material with a mixture of (A) a water-soluble copper complex dye or a mixture of copper complex compounds, at least one component being a water-soluble copper complex dye, (B) a light stabilizer and if desired (C) an antioxidant, an agent for carrying out the process and the fiber material treated therewith are described.
    Type: Grant
    Filed: July 20, 1987
    Date of Patent: October 17, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Gerhard Reinert
  • Patent number: 4812139
    Abstract: Photodegradation and light-stabilizing amounts of a combination of an oxalanilide UV absorber and a hindered amine light stabilizer are applied to a dyed polyester fabric providing a lightfastness rating of at least 4 AATCC Gray Scale following 100 hours WeatherOmeter exposure. Fabrics so protected are useful for automotive fabrics and draperies.
    Type: Grant
    Filed: May 4, 1988
    Date of Patent: March 14, 1989
    Assignee: Burlington Industries, Inc.
    Inventor: George L. Brodmann
  • Patent number: 4789382
    Abstract: Textile polyester material is dyed with disperse dyes in the presence of specific benzophenone derivatives, some of which are novel, to improve the light fastness.
    Type: Grant
    Filed: July 10, 1987
    Date of Patent: December 6, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Neumann, Dieter Wegerle, Reinhold Krallmann
  • Patent number: 4775386
    Abstract: A process for the photochemical stabilization of undyed and dyed polyamide fibre material or blends thereof with other fibre materials, which comprises treating the fibre material with a mixture of (A) an organic copper complex, (B) a light stabilizer and, if desired, (C) an antioxidant, an agent for carrying out the process and the fibre material treated with the agent are described.
    Type: Grant
    Filed: April 27, 1987
    Date of Patent: October 4, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Kurt Burdeska
  • Patent number: 4765797
    Abstract: Liquid formulations of mixtures of cationic dyes frequently have a very short storage life. As a consequence, these formulations give rise to customer complaints concerning incorrect dyeing strengths and hues and concerning isoluble constituents. It has now been found according to the invention that powder formulations and in particular liquid formulations of cationic dyes or of mixtures of these dyes can be stabilized by adding selected oxidizing agents.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: August 23, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Sierling Ong, Kurt Hohmann
  • Patent number: 4717646
    Abstract: A method and system are provided for enabling amateurs and non-professionals to restore faded or discolored color photographs and snapshots to their original condition by treating the faded or discolored color photographs and snapshots to clean areas with a remover of anhydrous acetone-free diacetone and coating or coloring the cleaned areas with a color corrective restorer comprising a powdered dye embedded or dispersed in anhydrous diacetone preferably in the relative proportions of 40 grains dye: 30 ml anhydrous diacetone or by using wax cube compositions of alcoholic paraffin or other suitable wax with acetone-free diacetone in the relative proportions of 100 grams wax in alcohol: 1-3 grams powdered dye therein in the optional presence of liquid glycerin and/or lecithin. Procedure and equipment as described for carrying out the invention which is characterized by the slower evaporation rate of diacetone as compared to denatured alcohol to provide adequate time to carry out the process steps.
    Type: Grant
    Filed: September 5, 1986
    Date of Patent: January 5, 1988
    Inventor: Lewis A. Giorgi
  • Patent number: 4680033
    Abstract: In the conventional discharge printing on polyamide fiber materials using acid dyes, above all, the very low wet and light fastness properties of the designs obtained in this manner are frequently an obstacle to the wide expansion of this interesting technique in practice. Applying this known patterning method for wool or nylon to resist prints made with reactive dyes being distinguished by better fastness level, does not always produce satisfactory white resist effects when, for example, sulfite compounds as the resist agent and reactive dyes having esterified .beta.-hydroxyethylsulfonyl groups as the reactive radical are taken into consideration; colored effects having a bright hue are not even possible at all in various cases.
    Type: Grant
    Filed: October 25, 1985
    Date of Patent: July 14, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Bernd Durl, Johannes Bos, Sienling Ong, Peter Raffel, Kurt Brozat
  • Patent number: 4680034
    Abstract: A method is disclosed for patterning a textile substrate by treating the substrate surface in a pattern configuration, for example, using heated air streams, to allow a later-applied solvent to extract dye from the treated areas at a faster rate than from untreated areas. A patterned product is also disclosed.
    Type: Grant
    Filed: April 10, 1985
    Date of Patent: July 14, 1987
    Assignee: Milliken Research Corporation
    Inventor: Robert C. Arnott
  • Patent number: 4655783
    Abstract: A process for photochemical stabilization of non-dyed and dyed polyamide fibre material and mixtures thereof with other fibres which comprises treating the fibre material with a fibre-reactive copper complex of bisazomethines prepared from, for example, salicylaldehydes and aliphatic diamines is described. Some of these copper complexes used are novel compounds. The polyamide fibre material, for example textile material, thus treated largely retains its extensibility and elasticity even after relatively prolonged exposure to light. In addition, a clear improvement in light-fastness is achieved in dyed material by treatment with the metal complex.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: April 7, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Helmut Huber-Emden, Gerhard Back
  • Patent number: 4557730
    Abstract: The invention provides a solution of one or more U.V. absorbers selected from resorcinol monobenzoate, phenyl salicylate and a benzophenone; and an emulsifier in an organic solvent system.The solutions of the invention are useful for providing level dyeings of polyester material particularly for use in the automotive industry.
    Type: Grant
    Filed: May 17, 1984
    Date of Patent: December 10, 1985
    Assignee: Sandoz Ltd.
    Inventors: Brian Bennett, Donald K. Clough
  • Patent number: 4516978
    Abstract: A key button molded of a synthetic resin and having on the top surface thereof a character or symbol printed with a coloring agent comprising a dye and a solvent which is capable of dissolving the dye and the synthetic resin, wherein the character or symbol is durably formed on the top surface by the action of the solvent on the surface and body to cause the dye to permeate the surface and the body.
    Type: Grant
    Filed: September 19, 1983
    Date of Patent: May 14, 1985
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Hideo Goto, Takeo Hosoe, Toshinori Oda, Sosuke Ohtsuka
  • Patent number: 4383835
    Abstract: The light fastness of polyamide dyeings can be improved by treating polyamide fibre materials, before, during or after dyeing, with copper complexes of the reaction products of salicylaldehydes with amines (for example cyclohexylamine), or with copper complexes of o-hydroxybenzophenones.
    Type: Grant
    Filed: October 15, 1981
    Date of Patent: May 17, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reinhard Preuss, Joachim Grutze, Ulrich Beck, Hellmuth Pantke, Karl Vogel
  • Patent number: 4272244
    Abstract: A process for dyeing without shrinkage with a disperse dyestuff or an optical brightening agent a fibrous substrate whose fibres comprise a mixture of polyvinyl chloride and acetalized polyvinyl alcohol, in which the substrate is dyed at a temperature from 60.degree. to 90.degree. C. in the presence of a levelling carrier, this levelling carrier being removable when the dried substrate is subsequently submitted to a dry heat treatment for a period up to 120 seconds and at a temperature from 95.degree. to 135.degree. C.
    Type: Grant
    Filed: March 6, 1979
    Date of Patent: June 9, 1981
    Assignee: Sandoz Ltd.
    Inventor: Bernhard Schlick
  • Patent number: 4256459
    Abstract: An improved process for dyeing closely constructed non-tufted textile materials is provided wherein an effective minor amount of a substantially oil and water repellent fluoropolymer is applied to the textile material. The substantially oil and water repellent fluoropolymer employed can be represented schematically as ##STR1## The textile material can be, if desired, scoured with an aqueous surfactant solution to remove any residual dirt, oil or processing aids present on the textile material and thereafter scoured with an aqueous acidic solution to provide the textile material with an acidic pH prior to application of the fluoropolymer. Further, the back portion of the textile material can be backcoated with an elastomer composition. Once the textile material has been treated using any of the above processing steps, in combination with the application of the fluoropolymer, the resulting polymer-modified textile material is thoroughly dried and cured prior to dyeing.
    Type: Grant
    Filed: June 15, 1978
    Date of Patent: March 17, 1981
    Assignee: Milliken Research Corporation
    Inventors: Edwin L. Russell, Norvin A. Clontz
  • Patent number: 4240792
    Abstract: Dyed or printed synthetic fibers or materials consisting of synthetic fibers or of a mixture of synthetic fibers with other fibers are aftertreated with aqueous solutions which contain from 0.2 to 20 g/l of a mixture of one or more surfactants and a reductonate. The pH of the liquor is brought to above 8 and the aftertreatment is carried out at from 40.degree. to 100.degree. C.
    Type: Grant
    Filed: October 2, 1978
    Date of Patent: December 23, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrich Baumgarte, Sigismund Heimann, Michele Vescia, Johannes Winkler