Ether Patents (Class 8/609)
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Patent number: 5387262Abstract: A process for preparing a dyed fabric material having an increased lightfastness of at least 600 hours. The process includes the steps of immersing the dyed fabric in an aqueous solution of a cinnamate ester, removing the fabric from solution and drying the fabric.Type: GrantFiled: September 25, 1992Date of Patent: February 7, 1995Assignee: Surry ChemicalsInventor: Larry W. Nelson
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Patent number: 5298635Abstract: Tertiary amides useful as low-foam wetting agents in the textile industry have the formula I ##STR1## where R.sup.1 is straight-chain or branched C.sub.5 -C.sub.17 -alkyl or -alkenyl,R.sup.2 is straight-chain or branched C.sub.3 -C.sub.6 -alkyl,R.sup.3, R.sup.4 and R.sup.5 are each independently of the others hydrogen, methyl or ethyl, andn is from 3 to 15.Type: GrantFiled: May 14, 1993Date of Patent: March 29, 1994Assignee: BASF AktiengesellschaftInventors: Eberhard Beckmann, Ralf Brueckmann, Johannes P. Dix, Peter Freyberg, Erich Kromm
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Patent number: 5259849Abstract: The invention relates to compositions, which are stable on storage, of certain benzoquinone and naphthoquinone dyestuffs in an anhydrous solvent containing a non-ionic surface-active agent.Type: GrantFiled: June 10, 1992Date of Patent: November 9, 1993Assignee: L'OrealInventors: Jean F. Grollier, Jean Cotteret
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Patent number: 5244476Abstract: The present invention relates to compounds of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, x and y are defined as in the description, processes for their preparation, their use for improving the light stability of polyester dyeings and a dyeing process and dye preparations.Type: GrantFiled: March 13, 1992Date of Patent: September 14, 1993Assignee: Cassella AGInventors: Joachim Schulz, Gunter Bartels
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Patent number: 5240465Abstract: A process for applying a reactive dye to a cellulosic substrate comprising:(a) adding one or more dyeing assistants selected from the condensation product of sulphonated diphenyl ethers, condensation product of sulphonated ditolyl ethers, condensation products of polydiphenylsulphones with formaldehyde and condensation products of polyditolyl sulphones with formaldehyde (and salts thereof) into an aqueous liquor, optionally together with a salt (hereinafter defined as Process Step a);(b) introducing the substrate into the dyebath and adding one or more reactive dyes, (hereinafter defined as Process Step b) ; and(c) fixing the dyestuff onto the substrate (hereinafter defined as Process Step c).Type: GrantFiled: December 3, 1992Date of Patent: August 31, 1993Assignee: Sandoz Ltd.Inventor: Francis Palacin
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Patent number: 5213583Abstract: To prepare storage-stable, low-dusting dyestuff granules which are readily soluble in plastics, a suspension of the dyestuff containing 0.1-5% by weight of a polyglycol are dried while being granulated.Type: GrantFiled: November 21, 1991Date of Patent: May 25, 1993Assignee: Bayer AktiengesellschaftInventors: Vaclav Kaspar, Horst Brandt, Gottfried Popp
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Patent number: 5211719Abstract: Concentrated aqueous solutions are described comprising specific anionic disazo dyes and polyglycol amines, which are highly suitable as commercial forms.Type: GrantFiled: September 27, 1991Date of Patent: May 18, 1993Assignee: Ciba-Geigy CorporationInventor: Adolf Kaser
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Patent number: 5174791Abstract: Process for dyeing and printing blended fabrics made from polyester and natural fibre materials, characterized in that the dye baths, padding liquors or printing pastes contain compounds of general formula (I). Dye preparations containing one or more compounds of general formula (I).Type: GrantFiled: August 5, 1991Date of Patent: December 29, 1992Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Klaus Hofmann, Hubert Kruse, Jurgen Kuhlwein, Willi Steckelberg
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Patent number: 5145486Abstract: There is disclosed a process for producing non-skittery and level dyeings on wool with reactive dyes in the presence of an auxiliary combination, which process comprises dyeing wool with an aqueous liquor consisting of at least one reactive dye and an auxiliary combination comprising, as component (a), at least one compound of formula ##STR1## and, as component (b), at least one compound of formula ##STR2## wherein R.sub.1 and R.sub.2 are each independently of the other an aliphatic radical of 12 to 24 carbon atoms,Q and Q' are each independently of the other C.sub.1 -C.sub.4 alkyl, --CH.sub.2 --CO--NH.sub.2, ##STR3## A.sup..crclbar. and A'.sup..crclbar. are an anion, Z.sub.1, Z.sub.2, Z'.sub.1 and Z'.sub.2 are each independently of one another hydrogen, SO.sub.3 M or PO.sub.3 M,wherein M is hydrogen, alkali metal or ammonium, t.sub.1 and t.sub.2 are 1 or 0, when t.sub.1 and t.sub.2 are O, Z.sub.1, Z.sub.2, Z'.sub.1 and Z'.sub.2 are hydrogen or one of Z.sub.1, Z.sub.2, Z'.sub.1 and Z'.sub.Type: GrantFiled: February 11, 1991Date of Patent: September 8, 1992Assignee: Ciba-Geigy CorporationInventor: Klaus Hannemann
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Patent number: 5120326Abstract: The present invention relates to a new dye-leveling agent for acid dyes, as well as a blend of the dye-leveling agent with a wetting agent. The acid dye-leveling agent enables polyamide-containing fibers to be evenly dyed without streaking during dyeing of the fibers. The dye-leveling agents are particularly useful with respect to nylon, wool, and silk fibers.Type: GrantFiled: June 30, 1989Date of Patent: June 9, 1992Assignee: Olin CorporationInventors: Thomas C. Hemling, Harry Stitzel
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Patent number: 5015262Abstract: Cloth is dyed using a reactive dye, an alkaline substance and a leveling agent. The leveling agent is one or more substances selected from the group consisting of phospholipids obtained from animals or plants, compounds having the formula I and compounds having the formula II: ##STR1## wherein R.sub.1 and R.sub.3 each denotes alkyl, alkenyl, hydroxyalkyl, or M, with the proviso that both of R.sub.1 and R.sub.3 are not M simultaneously; R.sub.2 denotes alkylene having 2 to 4 carbon atoms; 1 and m each denote 0 or an integer of at least 1; and M denotes alkali metal or hydrogen, ##STR2## wherein R.sub.4 denotes alkyl, alkenyl, hydroxyalkyl, straight chain, hydroxy-substituted alkenyloxy or branched chain, hydroxy-substituted alkenyloxy; X and Y each denote hydrogen, alkoxy, alkyl, or ##STR3## wherein M denotes alkali metal or hydrogen; and n denotes an integer of at least 1.Type: GrantFiled: December 26, 1988Date of Patent: May 14, 1991Assignee: Nihon Surfactant Kogyo K.K.Inventors: Noriaki Ohba, Yujin Tabata, Tateyuki Nagatomi
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Patent number: 5009668Abstract: Mixture of dyeing assistants containing(A) an acid ester, or salts thereof, of an alkylene oxide adduct of the formula ##STR1## in which V is hydrogen or methyl, X is the acid radical of an inorganic acid containing oxygen, or the radical of an organic acid and Y is C.sub.1 -C.sub.12 alkyl, aryl or aralkyl, "alkylene" is the ethylene or propylene radical and m is 1 to 3, m.sub.1 is 1 or 2 and n is 4 to 50,(B) a nonionic surfactant containing polyglycol ether groups, and(C) an aliphatic or aromatic carboxylic acid ester, an alkylbenzene, tetralin or a mixture of these substances.The mixture of assistants is employed in the dyeing of synthetic fibre materials, in particular textile material containing polyester fibres, for increasing the rate of migration of disperse dyes.Type: GrantFiled: February 8, 1990Date of Patent: April 23, 1991Assignee: Ciba-Geigy CorporationInventors: Hans-Ulrich Berendt, Rosemarie Topfl
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Patent number: 4976744Abstract: Concentrated solutions of cationic dyes are prepared by treating the cationic dyes, which contain as the counterions the anions customarily present during their preparation, with alkali metal salts of monocarboxylic acids and with or without complexing agents in an aqueous glycol ether medium, and separating off the organic phase, which contains the dyes in the form of their monocarboxylic acid salts.Type: GrantFiled: September 12, 1989Date of Patent: December 11, 1990Assignee: BASF AktiengesellschaftInventors: Johannes P. Dix, Guenter Hansen, Hellmut Kast
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Patent number: 4943299Abstract: Levelling agents containingI. ethers of the general formula ##STR1## in which R.sub.1 denotes alkyl, alkenyl, cycloalkyl, aryl or aralkyl,R.sub.2 denotes hydrogen or methyl,x denotes 1, 2 or 3 andy denotes 0 to 7, andII. emulsifiers and, if desired,III. carriers for the dyeing of polyesters are used for the high-temperature dyeing of polyester fibres and polyester-containing materials.Type: GrantFiled: September 22, 1988Date of Patent: July 24, 1990Assignee: Bayer AktiengesellschaftInventors: Hans Schulze, Klaus Walz, Frank Bartkowiak, Karlhans Jakobs
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Patent number: 4935033Abstract: Natural polyamide fibres, in particular wool, are dyed by means of reactive dyes using the exhaust method in the presence of a dyeing assistant consisting of a combination of (a) quaternized ammonium compounds of polyglycol compounds and (b) of acidic esters or salts thereof derived from at least dibasic oxyacids and from polyglycol compounds, both the quaternary ammonium compounds and the acidic esters being derived from an aliphatic amine having 12 to 24 carbon atoms in the aliphatic moiety. The process comprises carrying out the dyeing in the additional presence of (c) a fatty alcohol/polyalkylene glycol ether of the formulaR-O-(alkylene-O.sub.m H (1)in which R is an aliphatic radical having at least 8 carbon atoms, "alkylene" is an ethylene radical or propylene radical and m is 3 to 25.Type: GrantFiled: September 21, 1988Date of Patent: June 19, 1990Assignee: Ciba-Geigy CorporationInventors: Walter Mosimann, Dieter Mausezahl
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Patent number: 4895981Abstract: A process is described for improving the photochemical stability of dyeings on polyester fibre materials by means of UV absorbers of the formula ##STR1## in which R is alkyl, alkoxy, halogen or hydroxyl, R.sub.1 is alkyl, R.sub.2 is hydrogen, halogen, alkyl, alkylamino, hydroxyalkylamino, aralkylamino, alkoxyalkylamino, alkenyl, alkoxy, alkoxy which is substituted by hydroxyl, carboxyl or C.sub.2 -C.sub.5 alkoxycarbonyl, alkenyloxy, phenyl or phenyl which is substituted by halogen, alkyl, hydroxy-C.sub.1 -C.sub.4 alkyl, alkenyloxy, alkoxy, hydroxyl or carboxy-C.sub.1 -C.sub.4 alkoxy, m is 0 or 1 and n is 0, 1 or 2, and also novel compounds of the formula (1) in which m and n are both 0 and R.sub.2 is alkylamino, hydroxyalkylamino, aralkylamino or alkoxyalkylamino.Type: GrantFiled: March 24, 1989Date of Patent: January 23, 1990Assignee: Ciba-Geigy CorporationInventors: Gerhard Reinert, Kurt Burdeska
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Patent number: 4833235Abstract: Disazo compounds of the formula ##STR1## and salt thereof, D is the radical of a diazo component of the benzene or naphthalene series.K is the radical of a heterocyclic coupling component of the aminopyrazole-, pyridone- or barbituric acid-series, n is 1 to 4,R.sub.1 is hydrogen, C.sub.1-4 alkyl or substituted C.sub.1-4 alkyl,each of R.sub.2 and R.sub.3 is independently hydrogen, halo, C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy, substituted C.sub.1-4 alkoxy, --NHCO--Rhd 5, amino, substituted amino or a quaternary ammonium group, wherein R.sub.5 is C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy or amino,R.sub.4 is hydrogen, C.sub.1-4 alkyl, C.sub.Type: GrantFiled: October 7, 1987Date of Patent: May 23, 1989Assignee: Sandoz Ltd.Inventor: Reinhard Pedrazzi
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Patent number: 4787912Abstract: An assistant for dyeing or whitening synthetic nitrogen-containing fibre material, which comprises(A) a sulfonated polycarboxylate,(B) an anionic surfactant,(C) a nonionic surfactant, and(D) a water-soluble organic, polar solvent.The assistant is especially useful for dyeing or whitening polyamide fibres.Type: GrantFiled: January 28, 1987Date of Patent: November 29, 1988Assignee: Ciba-Geigy CorporationInventors: Heinz Abel, Helmut Raisin
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Patent number: 4767421Abstract: A method of manufacturing a homogeneous, water-insoluble dye layer on a substrate is provided in which a solution of a cationic or anionic dye in an organic solvent is provided on the substrate, the solvent is removed and the resulting dye layer is treated with an aqueous solution of a salt in which the cation of the anionic dye is exchanged for the cation of the salt or is treated with a salt or acid in which the anion of the cationic dye is exchanged for the anion of the salt or acid. The invention also provides a substrate provided with water insoluble homogeneous dye layer.Type: GrantFiled: June 2, 1987Date of Patent: August 30, 1988Assignee: U.S. Philips Corp.Inventors: Jan van der Veen, Dirk J. Gravesteijn, Cornelis J. Schoot
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Patent number: 4750909Abstract: A liquid dye composition comprising an organic solvent-soluble premetallized azo dyestuff in a volatile organic solvent medium, said composition further containing a finely divided silica thickening agent and/or xylol, toluol, perchlorethylene or mineral spirits or any mixture thereof. A process for coloring a porous substrate, preferably stone, comprising applying thereto a liquid dye composition comprising an organic solvent-soluble premetallized azo dyestuff in a volatile organic solvent medium, said composition being preferably as described above, and allowing the composition to penetrate the substrate, preferably followed by treating the penetrated substrate with an aqueous solution of a copper salt or a polymerizable organic siliconate, and then removing any excess unpenetrated composition from the substrate.Type: GrantFiled: December 29, 1986Date of Patent: June 14, 1988Inventor: Clemens Streck
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Patent number: 4734100Abstract: Textile cellulose material is printed or dyed with reactive dyes with the aid of foam. The foam is applied by applying to the cellulose material a foamed, aqueous prepartion which contains in addition to dye and fixing alkalis(1) a foam-forming agent(2) a homopolymer or copolymer of acrylamide or methacrylamide or preferably a graft polymer which is obtained from an addition product of an alkylene oxide, preferably propylene oxide, on an at least trihydric aliphatic alcohol, e.g. glycerol, and acrylamide or methacrylamide, and(3) the acid ester of a homopolymer of an ethylenically unsaturated aliphatic monocarboxylic or dicarboxylic acid and a polyethylene glycol, a terminal hydroxyl group of the diol having been etherified with an aliphatic monoalcohol having at least 4 carbon atoms, preferably stearyl alcohol, and the homopolymer having a molecular weight of 300 to 3,500.The cellulose material thus treated is then subjected to a heat treatment, for example steaming, to fix the dye.Type: GrantFiled: May 6, 1987Date of Patent: March 29, 1988Assignee: Ciba-Geigy CorporationInventors: Hans-Ulrich Berendt, Martin Kuhn
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Patent number: 4731092Abstract: Textile cellulose material is printed or dyed with reactive dyes with the aid of foam. The foam is applied by applying to the cellulose material a foamed, aqueous preparation which contains in addition to dyes and fixing alkalis(1) a foam-forming agent(2) a homopolymer or copolymer of acrylamide or methacrylamide or preferably a graft polymer which is obtained from an addition product of an alkylene oxide, preferably propylene oxide, on an at least trihydric aliphatic alcohol, e.g. glycerol, and acrylamide or methacrylamide, and(3) an anionic graft polymer which has as grafting base a copolymerization product from (A) an alkyl acrylate or methacrylate, the alkyl radical having at least 8 carbon atoms, with (B) a dicarboxylic acid diester of an ethylenically unsaturated aliphatic dicarboxylic acid and a polyethylene glycol, a terminal hydroxyl group of the diol having been etherified with a C.sub.1 -C.sub.Type: GrantFiled: April 20, 1987Date of Patent: March 15, 1988Assignee: Ciba-Geigy CorporationInventor: Hans-Ulrich Berendt
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Patent number: 4713081Abstract: The invention provides aqueous dyestuff preparations of water-insoluble or sparingly water-soluble dyes which may be used for preparing printing pastes to be used for printing textile material as well as for printing supports for transfer printing. The preparations contain at least 10% by weight of water, 10 to 60% by weight of a finely dispersed water-insoluble or sparingly water-soluble dye, 0.1 to 5% by weight of at least one anionic dispersant, and 0.5 to 5% by weight of a non-ionic copolymer of ethylene oxide and a further olefin oxide, said copolymer having an ethylene oxide content of at least 65% by weight and a molecular weight of more than 12,000, and also, if desired, further ingredients.Type: GrantFiled: April 23, 1979Date of Patent: December 15, 1987Assignee: Ciba-Geigy CorporationInventor: Carl Becker
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Patent number: 4711642Abstract: Liquid water-containing concentrated reactive dye-stuff preparations of monofluorotriazinyl reactive dye-stuffs with a pH value of at least 8, preferably 8.5-10, are stable on storage and display no noticeable hydrolysis, even after prolonged storage.Type: GrantFiled: September 11, 1986Date of Patent: December 8, 1987Assignee: Bayer AktiengesellschaftInventors: Joachim Wolff, Karlheinz Wolf
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Patent number: 4705526Abstract: Water-soluble or water-dispersible graft polymers comprising i) as main chain, (1) a condensate of (A) (1) an aliphatic monoalcohol of 6 to 22 carbon atoms or (2) a fatty acid of 8 to 22 carbon atoms with (B) the reaction product of (a) an adduct of propylene adduct with at least trihydric aliphatic alcohol of 3 to 10 carbon atoms, (b) an aliphatic dicarboxylic acid of 4 to 10 carbon atoms, or an anhydride thereof, and (c) an aliphatic diol having an average molecular weight of not more than 1800 and ii) grafted ethylenically unsaturated polymerisable monomers, preferably acrylic acid or acrylamide, in the form of side chains at individual carbon atoms of said condensate.These graft polymers are particularly suitable for use as anticrease agents for dyeing, whitening, bleaching or washing textile materials, e.g. textiles containing cellulosic fibres, natural or synthetic polyamide fibres, polyacrylonitrile fibres or, in particular, for dyeing or whitening cotton or polyester fibres.Type: GrantFiled: June 19, 1986Date of Patent: November 10, 1987Assignee: Ciba-Geigy CorporationInventors: Heinz Abel, Paul Schafer, Hans-Ulrich Berendt
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Water-soluble or water-dispersible graft polymers, process for their preparation and the use thereof
Patent number: 4705525Abstract: Water-soluble or water-dispersible graft polymers which comprise (a) as main chain, a polyalkylene glycol, in particular polyethylene glycol, which is esterified at the two terminal hydroxyl groups with a long chain fatty acid of 8 to 26, preferably 10 to 22, carbon atoms, and (b) grafted ethylenically unsaturated monomers, preferably acrylic acid or acrylamide, in the form of side chains at individual carbon atoms of the polyalkylene glycol chain.These graft polymers are particularly suitable for use as anticrease agents for dyeing, whitening, bleaching or washing textile materials, e.g. textiles containing cellulosic fibres, natural or synthetic polyamide fibres, polyacrylonitrile fibres or, in particular, for dyeing or whitening cotton or polyester fibres.Type: GrantFiled: June 19, 1986Date of Patent: November 10, 1987Assignee: CIBA-GEIGY CorporationInventors: Heinz Abel, Paul Schafer, Hans-Ulrich Berendt -
Patent number: 4701182Abstract: Hitherto there has been no practical pad-dwell process for wool piece goods which could be carried out without using large amounts of textile assistants. In addition, it has been necessary with all these processes to supply energy. Furthermore, large amounts of urea have always been used, which inevitably resulted in a high degree of waste water pollution. It has now been recognized according to the invention that satisfactory results can be obtained in the dyeing of wool piece goods with reactive dyes by effecting the padding operation with the dye solutions within the pH range from 1.5 to 4 and at room temperature and the subsequent dwell operation to obtain dye fixation without supply of heat. To prevent the formation of a frosting effect and to obtain deeper shades it is expediently possible also to add to the padding liquor nitrogen-containing ethoxylation products, in particular ethoxylated fatty amines, and/or alkyl polyglycol ethers.Type: GrantFiled: November 5, 1986Date of Patent: October 20, 1987Inventors: Hans-Ulrich von der Eltz, Hans-Peter Maier, Karl-Heinz Rostermundt
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Patent number: 4648884Abstract: The invention relates to aqueous/organic or purely organic solutions of anionic dyes, the principal feature of which solutions is that they contain the dye or dyes, dissolved in a C.sub.1 -C.sub.4 monoalkyl ether of propylene glycol, or of butylene glycol, or in a C.sub.1 -C.sub.4 carboxylic acid ester thereof, or in a mixture of these solvents. Such dyestuff solutions are storage stable and are especially suitable for spray dyeing leather.Type: GrantFiled: July 17, 1985Date of Patent: March 10, 1987Assignee: Ciba-Geigy CorporationInventor: Zdenek Koci
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Patent number: 4624678Abstract: The invention describes a process for the preparation of granular dye formulations by mixing a (preferably water-soluble) dye, water, and optionally further assistants with a polyethylene glycol that melts in the range from 40.degree. to 150.degree. C., and drying the resultant solution or suspension in a spray drier or fluidized bed drier. The granular formulations so obtained are permanently dust-free, dissolve rapidly in an aqueous dyebath, and do not cause foaming during dyeing.Type: GrantFiled: April 29, 1985Date of Patent: November 25, 1986Assignee: Ciba-Geigy CorporationInventor: Dieter Schneider
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Patent number: 4604100Abstract: The invention describes a process for the preparation of granular dye formulations by melt granulation, using a polyethylene glycol as melt vehicle. The essential feature of the invention is that a start is made from the dye which contains water, for example from the aqueous filter cake or synthesis solution, and adjusting the moisture content of the granular formulations to 1 to 30% by partial evaporation of water from the dye/polyethylene glycol melt.Type: GrantFiled: March 11, 1985Date of Patent: August 5, 1986Assignee: Ciba-Geigy CorporationInventors: Dieter Schneider, Heinz Knies, Gerhard Kaudela
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Patent number: 4568351Abstract: A textile finishing process in which there is employed, as a pH regulator, a compound or a mixture of compounds of formula I ##STR1## in which p is from 1 to 20,R is hydrogen, C.sub.1-3 alkyl or C.sub.1-3 alkyl substituted by hydroxyR' has independently one of the significances given for R or is --CO--R andA is --CH.sub.2 CH.sub.2 --; --CH.sub.2 --CH.sub.2 --CH.sub.Type: GrantFiled: May 17, 1984Date of Patent: February 4, 1986Assignee: Sandoz Ltd.Inventors: Jose M. Palleiro Cardona, Karl-Heinz Weible
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Patent number: 4523923Abstract: The invention relates to solid disperse dye formulations which do not contain anionic dispersants and which comprise one or more disperse dyes having a particle size of less than 5 .mu.m, and one or more nonionic dispersants selected from the group of the fatty alcohol ethoxylates having a molecular weight of 800 to 2000, of the fatty amine ethoxylates having a molecular weight of 500 to 1000, and of the polyvinylpyrrolidones having a molecular weight of 10,000 to 25,000.These formulations are particularly suitable for preparing organic printing pastes and printing inks which contain synthetic thickeners and which are suitable for textile printing and for transfer printing.Type: GrantFiled: February 16, 1984Date of Patent: June 18, 1985Assignee: Ciba-Geigy CorporationInventors: Urs Buchel, Paul Muther
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Patent number: 4518392Abstract: The invention describes a process for the HT dyeing of polyester fibre material with dyes which are sparingly soluble in water, which process comprises the use of a dyebath which contains at least one block polymer of ethylene oxide and propylene oxide having a molecular weight higher than 5000.The use of such a polymeric non-ionic dispersant ensures, even in low concentration, the stability of the dye dispersion under HT conditions, with at the same time substantial to complete bath exhaustion.Type: GrantFiled: July 8, 1983Date of Patent: May 21, 1985Assignee: Ciba Geigy CorporationInventors: Hans Mollet, Paul Dussy
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Patent number: 4516979Abstract: The invention relates to a method of dyeing or printing a textile substrate with disperse dyes, using as a dyeing assistant the product of polyesterifying an aliphatic polyol or etherpolyol or a disaccharide with benzoic acid or substituted benzoic acid.Type: GrantFiled: December 23, 1982Date of Patent: May 14, 1985Assignee: Sandoz Ltd.Inventor: Hans-Peter Baumann
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Patent number: 4502864Abstract: Liquid concentrate of Direct Yellow 11 based on the crown ether complexes of tetrasodium direct yellow 11, are described as well as these novel soluble chelates of insoluble tetrasodium complexes of Direct Yellow 11.Type: GrantFiled: April 25, 1984Date of Patent: March 5, 1985Assignee: Ciba-Geigy CorporationInventor: Jo Ann Cleverdon
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Patent number: 4487609Abstract: The invention relates to powdered, stably dispersible dye formulations which do not foam on application, and to a process for their preparation. In addition to containing one or more disperse dyes and an anionic dispersant or mixture of dispersants, these formulations contain 0.01 to 10% by weight, based on the final formulation, of a non-ionic reaction product of ethylene oxide and propylene oxide with a low molecular polyol, said reaction product having a molecular weight in the range from 200 to 5000 and a cloud point in the range from -20.degree. to +130.degree. C. The formulations are particularly suitable for dyeing under HT conditions in half-filled dyeing machines.Type: GrantFiled: August 5, 1983Date of Patent: December 11, 1984Assignee: Ciba-Geigy CorporationInventor: Roland Putzar
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Patent number: 4428750Abstract: In order to achieve lighter patterned effects on a background of a deeper color, aqueous printing pastes containing, additionally to thickeners and other conventional printing assistants, assistants which have dissolving properties for the dyestuffs at elevated temperatures and which do not attack the fibers under thermosol conditions, are applied to textile webs which have been dyed in a finished manner with suitable dyestuffs or have only been impregnated therewith, after which the goods treated in this way are subjected to a steaming process or to a dry heat treatment. In accordance with the process it is possible to effect a uniform lightening, "white discharging" or "colored discharging" of dyeings, particularly dyeings of synthetic fibers with disperse dyestuffs and also dyeings of natural fibers or mixtures thereof with disperse dyestuffs, vat dyestuffs, leuco esters thereof and developing dyestuffs.Type: GrantFiled: February 18, 1983Date of Patent: January 31, 1984Assignee: Hoechst AktiengesellschaftInventors: Walter Birke, Hans-Ulrich von der Eltz, Franz Schon, Erich Feess
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Patent number: 4399068Abstract: Salts of acetoacetylamino-arylsulphonic acids, of the formula ##STR1## wherein R denotes an optionally substituted benzene or naphthalene nucleus,Me denotes a protonated, tertiary, hydrophilizing nitrogen base or the lithium cation andm denotes 1,2 or 3are easily obtained by reacting compounds of the formulaH.sub.2 N--R--(SO.sub.3 H).sub.mwherein R and m have the above mentioned meaning, with diketene in an aqueous or aqueous-organic solvent maintaining a pH>3 during the reaction by adding tertiary, hydrophilizing nitrogen bases or a basic lithium salt.The salts can be obtained as concentrated solutions which are easily reacted with diazotized aromatic amines to concentrated solutions of azo dyestuffs.Type: GrantFiled: January 18, 1978Date of Patent: August 16, 1983Assignee: Bayer AktiengesellschaftInventor: Erich Kramer
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Patent number: 4397652Abstract: Described is a process for the production of negligibly dusty preparations of dyes and/or optical brighteners, which process comprises mixing an adhesive as e.g. sorbitol and a dust binding surface active agent into a mixture of dye or optical brightener and, optionally, further additives.Type: GrantFiled: January 18, 1982Date of Patent: August 9, 1983Assignee: Ciba-Geigy CorporationInventor: Konrad Neumann
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Patent number: 4340385Abstract: Compounds of the formula ##STR1## wherein R.sub.1 is C.sub.1-4 alkyl,R.sub.2 is hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,R.sub.3 is hydrogen or C.sub.1-4 alkyl, andM is hydrogen or a monovalent non-chromophoric cation,and mixtures of such compounds, stable, concentrated, aqueous compositions consisting essentially of, by weight,5-20% Compound of said formula in salt form or a mixture thereof2-25% 2-(2-Methoxyethoxy)ethanol0-8% Propylene glycolBalance Water,and the use of such compounds, mixtures and stable, concentrated, aqueous compositions for dyeing and printing anionically dyeable substrates such as natural and synthetic polyamides, especially nylon carpet.Type: GrantFiled: February 23, 1981Date of Patent: July 20, 1982Assignee: Sandoz, Inc.Inventors: Silvio A. Rodriguez, Sigmund C. Catino, deceased
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Patent number: 4336026Abstract: A liquid preparation of an anionic dye of the disazo class, which preparation contains the disazo dye, which in the form of the free acid corresponds to the formula ##STR1## dissolved in a solvent mixture which is miscible with water in any proportion and which consists of N,N,N',N'-tetramethylurea, at least one alkylene glycol ether and water, and alkyl- or alkanolamine in an amount sufficient to bring the pH value of the liquid preparation to 6.5 to 8.5, the dye being in the form of alkyl- or alkanolamine. This novel liquid preparation is a concentrated true solution which is stable in storage over several months at temperatures of between about -10.degree. C. and +60.degree. C., and which is miscible with cold and warm water in any proportion. It is suitable in particular for dyeing and printing paper, including semi-cardboard and cardboard, the dyeing of these materials being possible, for example, in the pulp, or by brushing or immersion.Type: GrantFiled: January 19, 1981Date of Patent: June 22, 1982Assignee: Ciba-Geigy CorporationInventor: Roger Lacroix
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Patent number: 4309180Abstract: There are described new anthraquinone compounds which, in the form of the free acid, correspond to the formula I ##STR1## wherein the X's independently of one another are each a straight-chain or branched-chain alkyl group having 1 to 4 carbon atoms, Y is hydrogen or is the same as X, and wherein the phenyl rings a can also be substituted by one or more halogen atoms, the production and use thereof, and also dye solutions containing a solvent mixture consisting of one or more aprotic solvents, at least one glycol and/or glycol ether, and optionally water and further additives, which solutions contain in each case a mixture of two anthraquinone dyes which, in the form of the free acid, correspond to the formulae I and IV ##STR2## wherein the X's independently of one another are each a straight-chain or branched-chain alkyl group having 1 to 4 carbon atoms, Y is hydrogen or is the same as X, and wherein the phenyl rings a can also be substituted by one or more halogen atoms.Type: GrantFiled: July 1, 1980Date of Patent: January 5, 1982Assignee: Ciba-Geigy CorporationInventors: Roger Lacroix, Jean-Marie Adam, Janos Vincze
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Patent number: 4302202Abstract: A composition useful as a dyeing, fixing and leveling agent for acid dyestuffs on polyamide fibers, as a reserving agent in dyeing of polyamide-cellulosic blends with direct dyes and as an aftertreating agent for improving wet fastness and perspiration resistance of polyamides dyed with an acid dyestuff consists essentially of an aqueous solution of 60-85% by weight of solute of phenolsulfonic acid-formaldehyde condensate and 15-40% by weight of solute of an alkylene glycol of up to 3-10 carbon atoms or a polyoxyethylene or -thio glycol or molecular weight up to 1000.Type: GrantFiled: October 9, 1979Date of Patent: November 24, 1981Assignee: Northwestern Laboratories, Inc.Inventors: Jeffery L. Sumner, Arthur L. Tinsley
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Patent number: 4299994Abstract: The invention relates to novel, polyoxyalkylene condensation products based on mixtures of primary, aliphatic alcohols, at least 70 mol % of which are branched 1-decanols, and to the use of these products as surface active agents.Type: GrantFiled: February 6, 1980Date of Patent: November 10, 1981Assignee: Sandoz, Inc.Inventor: Franklin H. Stahel
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Patent number: 4294579Abstract: Padding liquors or printing pastes which contain at least one compound which is free from ionic groups and possesses one or more glycicyl radicals are used for the one-bath, single-stage dyeing and printing of textile sheet-like structures of cellulose fibres or fibre blends containing cellulose fibres with water-insoluble reactive disperse dyestuffs in the absence of alkalis or alkaline compounds.Type: GrantFiled: August 27, 1979Date of Patent: October 13, 1981Assignee: Bayer AktiengesellschaftInventors: Udo-Winifred Hendricks, Dietrich Hildebrand, Robert Kuth
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Patent number: 4279615Abstract: Polyester fiber materials are colored by contacting them with aqueous compositions containing an organic pigment or a vat dyestuff or both and an oxpropylate of a mono- to hexahydric alkanol of 2 to 6 carbon atoms (containing 20 to 60 propylene oxide units) and fixing in a manner which is common for polyester. The colorations are fast to migration, especially to bleeding into PVC-coatings.Type: GrantFiled: March 27, 1980Date of Patent: July 21, 1981Assignee: Hoechst AktiengesellschaftInventor: Sienling Ong
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Patent number: 4268266Abstract: Padding liquors or printing pastes which contain at least one compound which is free from ionic groups and possesses one or more glycidyl radicals are used for dyeing and printing cellulose fibres or textile materials containing cellulose fibres with water-soluble reactive dyestuffs in the absence of alkalis or alkaline compounds.Type: GrantFiled: August 27, 1979Date of Patent: May 19, 1981Assignee: Bayer AktiengesellschaftInventors: Udo-Winfried Hendricks, Dietrich Hildebrand, Robert Kuth
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Patent number: 4260391Abstract: There is described a stable concentrated solution of a dye of the disazo class, which solution contains 15 to 30 percent by weight of the dye of the formula ##STR1## in the form of the lithium salt, optionally in admixture with up to 75 percent by weight of the sodium, potassium or ammonium salt, dissolved in 5 to 35 percent by weight of water, 2 to 10 percent by weight of pyrrolidone or of N-alkyl-(C.sub.1 -C.sub.4)-pyrrolidone and 35 to 50 percent by weight of a diethylene glycol monoalkyl ether; a process for producing this liquid preparation, and its use for dyeing and printing cellulose and regenerated cellulose, particularly however for dyeing paper.Type: GrantFiled: March 1, 1979Date of Patent: April 7, 1981Assignee: Ciba-Geigy CorporationInventor: Roger Lacroix
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Patent number: 4245990Abstract: A process for producing solutions of salts of water-soluble carboxylic acids of cationic dyes or optical brighteners, the solutions of cationic dye salts or brighteners salts which are obtained by this process and which are miscible with water in any proportion, and the use of these solutions for preparing dye liquors and printing pastes for dyeing, optical brightening and printing of, in particular, synthetic textile materials, which process comprises reacting the halide of a cationic dye or brighteners, in an aqueous or anhydrous medium, with at least one water-soluble carboxylic acid in the presence of an epoxide compound having a minimum of 13 carbon atoms.Type: GrantFiled: December 21, 1978Date of Patent: January 20, 1981Assignee: Ciba-Geigy CorporationInventors: Peter Loew, Walter Lang
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Patent number: 4208183Abstract: The invention relates to storage-stable dyestuff solutions which can be mixed at the time of use with appropriate carriers.These solutions comprise at least one dihydroxyindole of the formula: ##STR1## in which R.sub.1 and R.sub.2 independently of one another denote hydrogen or methyl, or a cosmetically acceptable salt thereof, in an anhydrous solvent chosen from amongst ethyl, isopropyl and tert.-butyl alcohol, ethylene glycol monomethyl, monoethyl and monobutyl ethers and the acetate of ethylene glycol monoethyl ether.Type: GrantFiled: May 9, 1978Date of Patent: June 17, 1980Assignee: L'OrealInventors: Jean F. Grollier, Chantal Fourcadier