Group Iv Metal (sn, Pb, Ge, Ti, Zr, Hf) Patents (Class 8/626)
  • Patent number: 9023116
    Abstract: As associative thickener obtainable by free radical polymerization, the preparation thereof and the use thereof in paper coating slips are described. The associative thickener is formed from (a) acid monomers selected from ethylenically unsaturated C3- to C8-carboxylic acids, (b) associative monomers of the general formula H2C?CR1—COO-(EO)n—(PO)m—R2, in which R1 is hydrogen or methyl, n is a number of at least two, m is a number from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30-alkyl group or a C8-C30-alkaryl group, and (c) nonionic, copolymerizable monomers differing from a) and b), the reaction product having been reacted, after the polymerization, with initiators forming nonionic radicals.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: May 5, 2015
    Assignee: BASF SE
    Inventors: Philipp Zacharias, Hermann Seyffer, Ilshat Gubaydullin, Harutyun Hanciogullari, Marc Bothe
  • Patent number: 8900330
    Abstract: An agent that is capable of improving dye fastness is provided. The agent includes a compound that includes at least one functional group capable of forming at least one interaction or at least one bond with a fiber or a dye molecule. Also, a method for using the agents to improve dye fastness and a dyed article including the agent are provided.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: December 2, 2014
    Assignee: Korea University Research and Business Foundation
    Inventor: Dong Hoon Choi
  • Patent number: 8828101
    Abstract: An agent that is capable of improving dye fastness is provided. The agent includes a compound that includes at least one functional group capable of forming at least one interaction or at least one bond with a fiber or a dye molecule. Also, a method for using the agents to improve dye fastness and a dyed article including the agent are provided.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: September 9, 2014
    Assignee: Korea University Research and Business Foundation
    Inventor: Dong Hoon Choi
  • Patent number: 7686849
    Abstract: An oxidative hair dye system comprises a hair dye, an organometallic compound and an oxidising agent. The organometallic compound is preferably an organotitanate compound, particularly a tetraalkyl titanate or a titanate chelate. Such compounds are also useful for enhancing the substantivity of topical compositions applied to the body, which comprise one or more cosmetic and/or therapeutic benefit agents, a bonding agent having hydrolysable or exchangeable ligands, and a carrier.
    Type: Grant
    Filed: April 6, 2006
    Date of Patent: March 30, 2010
    Assignee: The Boots Company PLC.
    Inventors: Neil Robert Forbes, Edward Galley, Christine Sheard
  • Patent number: 7553339
    Abstract: A method of dyeing or printing textile fiber materials, which comprises bringing the fiber material into contact with (a) at least one reactive dye containing at least one anionic group, (b) at least one compound which reduces the ionic character of the anionic group, and (c) at least one nucleophilic compound, yields dyeings or prints having deep hues and very good fastness properties.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: June 30, 2009
    Assignee: Huntsman International LLC
    Inventors: Jürgen Schmiedl, Wolfgang Mundle
  • Patent number: 7118622
    Abstract: An unsupported platy titanium dioxide pigment containing an organic dye laked thereon. The dyed TiO2 pigment is useful to color cosmetic, food, and drug formulations.
    Type: Grant
    Filed: May 11, 2005
    Date of Patent: October 10, 2006
    Assignee: Engelhard Corporation
    Inventors: Frank A. Mazzella, Gabriel E. Uzunian
  • Patent number: 6997963
    Abstract: The present invention concerns a dye composition for dyeing human keratin fibres such as hair containing, in an appropriate medium for dyeing human keratin fibres, at least one compound chosen from among chromoionophores and fluorionophores, and at least one cosmetic additive other than water. The invention also concerns the use of a compound chosen from among the chromoionophores and fluorionophores as a direct dye for dyeing human keratin fibres, methods for dyeing human keratin fibres and a device or “kit” with several compartments.
    Type: Grant
    Filed: June 27, 2003
    Date of Patent: February 14, 2006
    Assignee: L'Oreal
    Inventor: Frederic Guerin
  • Patent number: 6905520
    Abstract: According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect.
    Type: Grant
    Filed: August 21, 2001
    Date of Patent: June 14, 2005
    Assignee: Stain, Inc.
    Inventor: Stephen B. Auger
  • Patent number: 6136044
    Abstract: Micro-particles of transition metals or their compounds can be generated as an integral part of a fiber by first attaching a nucleating agent to the fiber, and then adding a solution of metal ions. The ions are reduced by the nucleating agent in the fiber, and micro-particles are generated in or on the fiber. Because of the strong color signal resulting from a low concentration of metal micro-particles, the method is cost effective even when using gold or titanium ions. Various colors were generated by changing the size and spacing of the micro-particles, the metal or metal complex used, and the characteristics of the fiber. The dyed fibers displayed colors ranging from pink, red, purple, yellow, orange, peach, brown, gold, silver, grey, green, and black. These colors resisted bleaching by either chemicals or light.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: October 24, 2000
    Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical College
    Inventor: William J. Todd
  • Patent number: 5888251
    Abstract: Hair upon the scalp or eyelashes are treated with hair coloring or mascara compositions in hair or eyelash coloring methods. The hair is typically colored with a mascara brush to achieve streaking and a non-homogenous coloring of the hair upon the scalp or the eyelash. A copaiba resin and a metal containing pigment are combined to obtain the hair coloring product. The resultant product is applied to the hair upon the scalp or the eyelash to effect coloring of the hair upon the scalp or the eyelash.
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: March 30, 1999
    Assignee: Aveda Corporation
    Inventors: Stanley Ray Fogg, Timothy Roland Kapsner
  • Patent number: 5516338
    Abstract: An aqueous dye composition is based upon a mixture of a water-soluble titanium salt, preferably titanium potassium oxalate and a tannin substance, preferably Myrobalan extract. This dye composition may be used to dye either natural fibers, synthetic fibers or blends thereof. The composition is particularly advantageous for either bottom dyeing denim fabric which can then be overdyed with indigo blue dye to provide blue-green hues or as a mordant for a basic dye.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: May 14, 1996
    Inventor: Panemangalore S. Pai
  • Patent number: 5516337
    Abstract: Method for imparting stain resistance to fibers, especially wool, which is adaptable to current wool processing methods. Steps comprise:A. treating fibers with a mordant;B. treatment with a combination of sulfonated or disulphonated surfactant together with a stain resist (e.g., syntan); andC. providing treatment with a fluorochemical in either step A. or B. in an amount sufficient to improve stain resistant properties. The improved method may be undertaken in the liquor remaining in a dye bath after dyeing fiber (spent bath process). Process pH is acid. Advantage: lowers the proportion of stain resist chemical to wool necessary to impart stain resistance. Tip sealing, using polymethacrylic resin and fluorochemical, may be an added step.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: May 14, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Van G. Nguyen
  • Patent number: 5462565
    Abstract: The new process for dyeing polyamide fibers with acid dyestuffs, in which small amounts of metal salts are added to the dyebath, gives dyeings having improved lightfastness.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: October 31, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Rohr, Martin Riegels, Sylvia Lohmann
  • Patent number: 5346509
    Abstract: Process for dyeing human hair by the sequential treatment of the hair with a metal ion and particularly transition metal ion containing composition and with a dye composition containing 5,6-dihydroxyindole-2-carboxylic acid.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: September 13, 1994
    Assignee: Clairol Incorporated
    Inventors: Thomas M. Schultz, Keith C. Brown, Leszek J. Wolfram, Giuseppe Prota
  • Patent number: 5192333
    Abstract: A clear, aqueous, shelf-stable progressive hair coloring composition includes a salt of a metal, a soluble source of sulfur, an amphoteric surfactant and a pH controller that controls the pH of the composition to be within the range of about 7.5 to about 11.0. Preferred metallic salts are salts of lead or bismuth and the preferred sulfur source is sodium thiosufate.
    Type: Grant
    Filed: February 12, 1992
    Date of Patent: March 9, 1993
    Assignee: Combe Incorporated
    Inventor: Herbert Lapidus
  • Patent number: 4812143
    Abstract: Liquid formulations of disperse dyestuffs for dyeing hydrophobic synthetic fiber materials or mixtures of synthetic fiber materials with cellulose fiber material or wool contain from 0.1 to 10% by weight of pulverulent highly disperse inorganic oxides or silicates or mixtures of both said oxides and silicates having a specific surface area (BET) of 20 to 800 m.sup.2 /g.
    Type: Grant
    Filed: December 7, 1987
    Date of Patent: March 14, 1989
    Assignee: Cassella Aktiengesellschaft
    Inventors: Klaus Hofmann, Ulrich Buhler, Erwin Dietz
  • Patent number: 4808191
    Abstract: A process is provided for the pattern dyeing of textile materials wherein dye migration may be inhibited by the in-situ formation of a coordination complex of metal-thickener-dye when the dye-thickener solution is applied to the textile material pretreated with an aqueous solution of a water soluble salt of the metal. The metal is selected from zirconium, hafnium or aluminum. The thickener may be a naturally derived aqueous system thickener, such as guar gum, xanthan gum or other water-soluble gum thickener or may be a synthetically derived aqueous system thickener, such as polyacrylics and polyacrylamides.
    Type: Grant
    Filed: June 4, 1987
    Date of Patent: February 28, 1989
    Assignee: Milliken Research Corporation
    Inventors: Richard V. Gregory, Daniel T. McBride
  • Patent number: 4806128
    Abstract: A process for preparing pigment dyes comprising reducing a colloidal dispersion of an impure dye to form a solution of the leucobase, introducing into this solution a finely divided substrate and, by adding an oxidizing agent, oxidizing the leucobase to form the vat dye, which thereby precipitates and deposits on the substrate.
    Type: Grant
    Filed: October 10, 1986
    Date of Patent: February 21, 1989
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventor: Juan M. Figueras
  • Patent number: 4681596
    Abstract: The invention relates to a process for dyeing natural or synthetic polyamide fibre material levelly from an aqueous liquor, with 1:1 metal complex dyes and at least one metal free dye, all of which contain sulfo groups, in the presence of an alkali metal salt or an ammonium salt and optionally in the presence of an assistant, which comprises carrying out dyeing in the presence of an alkali metal fluoride or ammonium fluoride, or an alkali metal fluorosilicate or ammonium fluorosilicate, or of an alkali metal fluoroborate or ammonium fluoroborate, at a pH in the range from 3 to 7.The process of this invention is suitable for dyeing natural or synthetic polyamide material in level shades of good fastness properties.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: July 21, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Back, Walter Mosimann
  • Patent number: 4458073
    Abstract: There are described a new class of organic dyes containing silane groups, the composite pigments obtainable therefrom by associating them with a substrate (SiO.sub.2, TiO.sub.2, Al.sub.2 O.sub.3), and the processes for preparing same.The silane organic dyes have the formula (I): ##STR1## wherein all substituents are defined later. The silane dyes (I) are utilized per se for dyeing natural fibres, such as wool, and man-made fibres, such as the polyamide, polyester, polyacrylic fibres and the like, while the composite pigments prepared from said dyes by association with an inorganic substrate are employed in paints, air enamels and stoving enamels, in the pigmentation of plastics, in the inks, in the printing of textiles etc.
    Type: Grant
    Filed: January 17, 1983
    Date of Patent: July 3, 1984
    Assignee: Montefluos S.p.A.
    Inventors: Antonio Marraccini, Marcello Pieroni, Antonio Pasquale, Luigi Balducci