Group Vii Metal (mn, Tc, Re) Patents (Class 8/628)
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Patent number: 8828100Abstract: Disclosed and claimed herein are a composition and a kit for coloring keratin fibers, and processes of their use. The composition includes a catechol-based color precursor.Type: GrantFiled: October 14, 2013Date of Patent: September 9, 2014Inventors: John C. Warner, Laura Muollo, Amie Stewart
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Patent number: 8597373Abstract: The invention relates to a process for dyeing keratin fibers, in which said fibers are treated: ? with a composition (A) comprising i) one or more indole or indoline compounds; ii) one or more metal salts; iii) hydrogen peroxide or one or more systems that generate hydrogen peroxide; and then ? with a composition (B) comprising iv) one or more basifying agents. The invention also relates to a hair dyeing process for obtaining better colorations, which are more uniform, chromatic and remanent and which do not impair the cosmetic properties of keratin fibers.Type: GrantFiled: June 13, 2011Date of Patent: December 3, 2013Assignee: L'OrealInventors: Frédéric Guerin, Gilles Genain, Patrick Choisy
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Patent number: 8535391Abstract: The present invention is concerned with a dye system for application to a substrate, the dye system comprising: (a) at least one dye precursor; (b) an oxidizing agent; and (c) a catalyst, wherein the catalyst is a homogeneous catalyst or a heterogeneous catalyst. Preferably, the catalyst comprises at least one metal-containing compound. The invention also envisages a method for the coloration of a substrate, the method comprising treating the substrate with the dye system of the invention. In preferred embodiments of the invention, the substrate comprises human hair, natural or synthetic polymers, or textile fibers. In further preferred embodiments, the at least one dye precursor is an organic precursor, the at least one metal derivative for use as a catalyst comprises at least one inorganic metal compound or at least one metal complex comprising at least one organic ligand, and the oxidizing agent is hydrogen peroxide.Type: GrantFiled: June 30, 2010Date of Patent: September 17, 2013Assignee: University of LeedsInventors: Richard Simon Blackburn, Patrick Columba McGowan, Christopher Martin Pask, Christopher Mark Rayner
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Patent number: 8460399Abstract: The present invention provides compositions and methods which are adapted to impart color to concrete or mineral substrate surfaces. Specifically, the present invention relates to a composition and methods adapted to treat concrete surfaces which have the advantage of using a non-corrosive acid-based solution.Type: GrantFiled: May 10, 2007Date of Patent: June 11, 2013Assignee: Valspar CorporationInventors: Sanford Lee Hertz, Ed Daraskevich, William W. Tao, Jason J. Netherton, Matthew S. Gebhard
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Patent number: 7947090Abstract: An air-oxidation haircolor composition is based: a) water; b) water soluble metal salt as a catalyst; c) etidronic acid (1-hydroxyethane-1,1-diphosphoric acid) as a chelating agent and color deposition enhancer; d) oxidation primary dye intermediates; e) an aromatic triol such as 1,2,4-Benzenetriol; f) auxiliary oxidation dye couplers; g) dye antioxidants and stabilizers; h) optionally, a water soluble surfactant; i) optionally, a water soluble anionic polymer; j) a water soluble solvent system; and k) an alkalizer.Type: GrantFiled: February 4, 2010Date of Patent: May 24, 2011Assignee: Combe IncorporatedInventor: Jack Massoni
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Patent number: 7758659Abstract: An air-oxidation haircolor composition is based: a) water; b) water soluble metal salt as a catalyst; c) etidronic acid (1-hydroxyethane-1,1-diphosphoric acid) as a chelating agent and color deposition enhancer; d) oxidation primary dye intermediates; e) an aromatic triol such as 1,2,4-Benzenetriol; f) auxiliary oxidation dye couplers; g) dye antioxidants and stabilizers; h) optionally, a water soluble surfactant; i) optionally, a water soluble anionic polymer; j) a water soluble solvent system; and k) an alkalizer.Type: GrantFiled: July 30, 2007Date of Patent: July 20, 2010Assignee: Combe IncorporatedInventor: Jack Massoni
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Patent number: 7749286Abstract: A composition for dyeing keratin fibers that contains 0.1 to 30 percent of at least one substantially pure plant dye material obtained using solvent or supercritical CO2 extraction, combined with 0.01 to 5 percent of active metal in a metal or mineral salt capable of acting as a mordant as a two-part hair color system.Type: GrantFiled: May 18, 2009Date of Patent: July 6, 2010Assignee: Advanced Cosmetic Technologies, LLCInventors: Erjena Greaves, Jeffrey T. Greaves
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Patent number: 7704285Abstract: Processes for coloring a keratin material, comprising applying to the keratin material, in the presence of oxygen, at least one component (A) comprising, in a physiologically acceptable medium:—at least one dye precursor chosen from compounds comprising at least one aromatic ring comprising at least two hydroxyl groups borne by two successive carbon atoms of the at least one aromatic ring, and at least one catalytic system comprising at least one first catalyst (1) chosen from Mn(II) and Zn(II) salts and oxides and/or at least one second catalyst (2) chosen from alkali metal hydrogen carbonates and alkaline-earth metal hydrogen carbonates followed by applying at least one component (B) comprising at least one acidic composition to fix the shade and followed by applying at least one component (C) comprising at least one alkaline composition to increase the intensity of the color or to modify the shade and optionally fixing the new color or shade obtained by applying a new application of at least one compositioType: GrantFiled: September 11, 2009Date of Patent: April 27, 2010Assignee: L'Oreal S.A.Inventors: Francis Pruche, Véronique Chevalier
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Patent number: 7682404Abstract: The present invention concerns coloring keratin fibers, especially human hair, with colored metal complexes.Type: GrantFiled: May 3, 2006Date of Patent: March 23, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Nicole End, Kai-Uwe Schöning, Beate Fröhling
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Patent number: 7270685Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.Type: GrantFiled: January 6, 2006Date of Patent: September 18, 2007Assignee: L'OrealInventors: Frank Dreher, Francis Pruche
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Patent number: 7077871Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.Type: GrantFiled: April 9, 2003Date of Patent: July 18, 2006Assignee: L'OrealInventors: Frank Dreher, Francis Pruche
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Patent number: 6997963Abstract: The present invention concerns a dye composition for dyeing human keratin fibres such as hair containing, in an appropriate medium for dyeing human keratin fibres, at least one compound chosen from among chromoionophores and fluorionophores, and at least one cosmetic additive other than water. The invention also concerns the use of a compound chosen from among the chromoionophores and fluorionophores as a direct dye for dyeing human keratin fibres, methods for dyeing human keratin fibres and a device or “kit” with several compartments.Type: GrantFiled: June 27, 2003Date of Patent: February 14, 2006Assignee: L'OrealInventor: Frederic Guerin
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Patent number: 6953486Abstract: Colouring composition, method for obtaining and using same for colouring skin and/or keratin matters.Type: GrantFiled: October 9, 2001Date of Patent: October 11, 2005Assignee: L'OrealInventor: Francis Pruche
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Patent number: 6723136Abstract: A composition for coloring keratin fibers comprises, a physiologically acceptable medium and an efficacious quantity of at least one coloring material precursor selected from the compounds containing at least one aromatic ring having at least two hydroxyl groups borne by two adjacent carbon atoms of the aromatic ring, an efficacious quantity of at least one oxidation base of the para or ortho type selected from the aromatic amines, and an efficacious quantity of a catalytic system comprising a first constituent selected from the group consisting of salts and oxides of Mn(II) and/or Zn(II) and their mixtures, and a second constituent selected from the group consisting of alkali hydrogen carbonates, alkaline earth hydrogen carbonates and their mixtures. Keratin fibers may be colored by the application of this composition thereto.Type: GrantFiled: December 4, 2001Date of Patent: April 20, 2004Assignee: L'OrealInventor: Francis Pruche
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Patent number: 6648925Abstract: The present invention relates to a composition for coloring keratin fibers and a method of using the same. The composition of the present invention contains at least one dye precursor, and one or more clathrate compounds that contain transition metal complexes.Type: GrantFiled: September 25, 2001Date of Patent: November 18, 2003Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)Inventors: Bernd Mayer, Peter Kuhm, Horst Hoeffkes, Gertrud Ewald, Hans-Oscar Stephan, Melita Heller
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Patent number: 6136044Abstract: Micro-particles of transition metals or their compounds can be generated as an integral part of a fiber by first attaching a nucleating agent to the fiber, and then adding a solution of metal ions. The ions are reduced by the nucleating agent in the fiber, and micro-particles are generated in or on the fiber. Because of the strong color signal resulting from a low concentration of metal micro-particles, the method is cost effective even when using gold or titanium ions. Various colors were generated by changing the size and spacing of the micro-particles, the metal or metal complex used, and the characteristics of the fiber. The dyed fibers displayed colors ranging from pink, red, purple, yellow, orange, peach, brown, gold, silver, grey, green, and black. These colors resisted bleaching by either chemicals or light.Type: GrantFiled: February 3, 2000Date of Patent: October 24, 2000Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical CollegeInventor: William J. Todd
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Patent number: 5972049Abstract: Improvements in the disperse dyeing process for hydrophobic textiles by the use of novel dye carrier formulations are disclosed. The carrier composition for use in disperse dyeing of hydrophobic textile material preferably comprises an alkylphthalimide carrier component and a clay dispersing agent. Dye baths and methods of disperse dyeing of a hydrophobic textile material are also disclosed. The use of clay as a dispersing agent allows for the use of carrier compositions with reduced health and environmental hazards without adversely affecting dyeing characteristics.Type: GrantFiled: January 28, 1998Date of Patent: October 26, 1999Assignee: Sybron Chemicals Inc.Inventors: Calvin M. Wicker, Jr., Otto Bello, Ricky C. Phillips, Robert B. Login
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Patent number: 5772696Abstract: An invention is disclosed which pertains to a method for purifying water soluble dyes, such as quinoline, fluoran, and xanthene dyes. The method comprises the steps of A) adding a metal salt to the water soluble dye to form a water insoluble dye salt of the metal; B) isolating the water insoluble dye salt of step A; C) converting the water insoluble dye salt of step B into a water soluble dye solution; and D) isolating the water soluble dye from the solution of step C. The present invention teaches a straight forward, economical, and environmentally sound method for purifying water soluble dyes of FDA certifiable purity and with an aesthetically improved shade.Type: GrantFiled: December 12, 1996Date of Patent: June 30, 1998Assignee: Warner-Jenkinson Company, Inc.Inventor: Puthalath Koroth Sujeeth
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Patent number: 5769902Abstract: Compositions for dyeing keratinous fibers comprising at least one an ortho-diaminopyrazole or an acid addition salt thereof and a manganese salt as well as a dyeing process using these compositions, without any oxidizing agent other than atmospheric oxygen.Type: GrantFiled: June 19, 1996Date of Patent: June 23, 1998Assignee: L'OrealInventor: Henri Samain
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Patent number: 5690697Abstract: A set for dyeing keratinous fibers, a dyeing composition, and a process for dyeing keratinous fibers using this dyeing composition are disclosed. Also disclosed is a multi-compartment device, or kit, one of the compartments of which contains the composition of the invention.Type: GrantFiled: July 20, 1995Date of Patent: November 25, 1997Assignee: L'OrealInventor: Henri Samain
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Patent number: 5525123Abstract: This invention comprises a hair dyeing composition based on oxidation dyestuff precursors which dyes and brightens the hair containing, besides at least one developing and at least one coupling agent, at least one metal salt and at least one ammonium compound selected from the group ammonium chloride, ammonium sulfate, ammonium carbonate, ammonium bicarbonate, and ammonium carbamate, having a pH-value between 8 and 11, preferably from 9 to 10, after admixture with an oxidizing agent in the ready-to-use preparation.Type: GrantFiled: September 8, 1994Date of Patent: June 11, 1996Assignee: Goldwell ACInventors: Heribert Lorenz, Daisuke Misu
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Patent number: 5462565Abstract: The new process for dyeing polyamide fibers with acid dyestuffs, in which small amounts of metal salts are added to the dyebath, gives dyeings having improved lightfastness.Type: GrantFiled: September 8, 1994Date of Patent: October 31, 1995Assignee: Bayer AktiengesellschaftInventors: Jurgen Rohr, Martin Riegels, Sylvia Lohmann
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Patent number: 5368610Abstract: The invention provides methods, compositions and kits for oxidative hair dyeing utilizing an oxidative hair dye precursor, and an alkali metal chlorite together with a water soluble copper, iron, manganese or cobalt salt, a chelate of said salts or a mixture of said salts and chelates.Type: GrantFiled: April 20, 1993Date of Patent: November 29, 1994Assignee: Clairol IncorporatedInventors: Alexander Chan, Gottfried Wenke, Ciuseppe Prota
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Patent number: 5346509Abstract: Process for dyeing human hair by the sequential treatment of the hair with a metal ion and particularly transition metal ion containing composition and with a dye composition containing 5,6-dihydroxyindole-2-carboxylic acid.Type: GrantFiled: April 14, 1993Date of Patent: September 13, 1994Assignee: Clairol IncorporatedInventors: Thomas M. Schultz, Keith C. Brown, Leszek J. Wolfram, Giuseppe Prota
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Patent number: 4776856Abstract: In a process for the oxidative dyeing of human or animal hair, a hair dyeing agent is prepared immediately before use from at least one oxidation dye and an oxidizing agent, applied to the hair to be dyed, and made to act for a given period of time, whereupon the hair dyeing agent is washed out. The hair dyeing agent that is to be used is prepared from an oxidation dye and the oxidizing agent with the concomitant use of manganese dioxide in powder form, while the finished hair dyeing agent is adjusted to a weakly acid pH in the range from 5.9 to 6.9.Type: GrantFiled: April 22, 1987Date of Patent: October 11, 1988Assignee: Goldwell GmbH Chemische Fabrik H. E. DotterInventors: Jurgen Tennigkeit, Herbert Lorenz
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Patent number: 4720422Abstract: A material is, herein disclosed for collecting radionuclides and heavy metals that comprises an acrylic fiber element having MnO.sub.2 and/or ferrocyanide compound of the formula K.sub.2 M.sup.II [Fe(CN).sub.6 ] (wherein M.sup.II is a divalent metal such as cobalt, zirconium, zinc or nickel) supported thereon. The material of the present invention is used in collecting and concentrating radionuclides present in liquid radioactive wastes discharged from nuclear power plants and other facilities using radioisotopes such as hospitals and non-destructive testing laboratories. The material is also used in collecting and concentrating radionuclides and heavy metals present in the seawater, rivers and industrial waste-water.Type: GrantFiled: April 3, 1985Date of Patent: January 19, 1988Assignee: Japan Chemical Analysis CenterInventors: Hideo Higuchi, Nobuhiro Nonaka
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Patent number: 4655785Abstract: A process for the photochemical stabilization of undyed and dyed polyamide or polyurethane fibre material that is characterized in that the fibre material is treated with a water soluble, organic copper, manganese or nickel complex that displays an affinity for the fibres. The polyamide or polyurethane fibre material, e.g., textile, that has been so treated retains its stretch characteristics and elasticity even after prolonged periods of illumination. In addition, in the case of dyed material, treatment with the metal complex results in a marked improvement in light-fastness.Type: GrantFiled: May 21, 1985Date of Patent: April 7, 1987Assignee: Ciba-Geigy CorporationInventors: Gerhard Reinert, Gerhard Back, Helmut Huber-Emden
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Patent number: 4274831Abstract: A process of dyeing or printing of synthetic fiber materials by means of disperse dyes carried out in the presence of at least one derivative of a metal having an atomic number in the range of 24 through 30 to prevent or diminish the degradation of the dye during the dyeing or printing process, and ready-to-use colorant compositions for this process.Type: GrantFiled: June 30, 1978Date of Patent: June 23, 1981Assignee: Produits Chimiques Ugine KuhlmannInventors: Gerard L.A. Belfort, Daniel P. A. Richer