Group Vii Metal (mn, Tc, Re) Patents (Class 8/628)
  • Patent number: 8828100
    Abstract: Disclosed and claimed herein are a composition and a kit for coloring keratin fibers, and processes of their use. The composition includes a catechol-based color precursor.
    Type: Grant
    Filed: October 14, 2013
    Date of Patent: September 9, 2014
    Inventors: John C. Warner, Laura Muollo, Amie Stewart
  • Patent number: 8597373
    Abstract: The invention relates to a process for dyeing keratin fibers, in which said fibers are treated: ? with a composition (A) comprising i) one or more indole or indoline compounds; ii) one or more metal salts; iii) hydrogen peroxide or one or more systems that generate hydrogen peroxide; and then ? with a composition (B) comprising iv) one or more basifying agents. The invention also relates to a hair dyeing process for obtaining better colorations, which are more uniform, chromatic and remanent and which do not impair the cosmetic properties of keratin fibers.
    Type: Grant
    Filed: June 13, 2011
    Date of Patent: December 3, 2013
    Assignee: L'Oreal
    Inventors: Frédéric Guerin, Gilles Genain, Patrick Choisy
  • Patent number: 8535391
    Abstract: The present invention is concerned with a dye system for application to a substrate, the dye system comprising: (a) at least one dye precursor; (b) an oxidizing agent; and (c) a catalyst, wherein the catalyst is a homogeneous catalyst or a heterogeneous catalyst. Preferably, the catalyst comprises at least one metal-containing compound. The invention also envisages a method for the coloration of a substrate, the method comprising treating the substrate with the dye system of the invention. In preferred embodiments of the invention, the substrate comprises human hair, natural or synthetic polymers, or textile fibers. In further preferred embodiments, the at least one dye precursor is an organic precursor, the at least one metal derivative for use as a catalyst comprises at least one inorganic metal compound or at least one metal complex comprising at least one organic ligand, and the oxidizing agent is hydrogen peroxide.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: September 17, 2013
    Assignee: University of Leeds
    Inventors: Richard Simon Blackburn, Patrick Columba McGowan, Christopher Martin Pask, Christopher Mark Rayner
  • Patent number: 8460399
    Abstract: The present invention provides compositions and methods which are adapted to impart color to concrete or mineral substrate surfaces. Specifically, the present invention relates to a composition and methods adapted to treat concrete surfaces which have the advantage of using a non-corrosive acid-based solution.
    Type: Grant
    Filed: May 10, 2007
    Date of Patent: June 11, 2013
    Assignee: Valspar Corporation
    Inventors: Sanford Lee Hertz, Ed Daraskevich, William W. Tao, Jason J. Netherton, Matthew S. Gebhard
  • Patent number: 7947090
    Abstract: An air-oxidation haircolor composition is based: a) water; b) water soluble metal salt as a catalyst; c) etidronic acid (1-hydroxyethane-1,1-diphosphoric acid) as a chelating agent and color deposition enhancer; d) oxidation primary dye intermediates; e) an aromatic triol such as 1,2,4-Benzenetriol; f) auxiliary oxidation dye couplers; g) dye antioxidants and stabilizers; h) optionally, a water soluble surfactant; i) optionally, a water soluble anionic polymer; j) a water soluble solvent system; and k) an alkalizer.
    Type: Grant
    Filed: February 4, 2010
    Date of Patent: May 24, 2011
    Assignee: Combe Incorporated
    Inventor: Jack Massoni
  • Patent number: 7758659
    Abstract: An air-oxidation haircolor composition is based: a) water; b) water soluble metal salt as a catalyst; c) etidronic acid (1-hydroxyethane-1,1-diphosphoric acid) as a chelating agent and color deposition enhancer; d) oxidation primary dye intermediates; e) an aromatic triol such as 1,2,4-Benzenetriol; f) auxiliary oxidation dye couplers; g) dye antioxidants and stabilizers; h) optionally, a water soluble surfactant; i) optionally, a water soluble anionic polymer; j) a water soluble solvent system; and k) an alkalizer.
    Type: Grant
    Filed: July 30, 2007
    Date of Patent: July 20, 2010
    Assignee: Combe Incorporated
    Inventor: Jack Massoni
  • Patent number: 7749286
    Abstract: A composition for dyeing keratin fibers that contains 0.1 to 30 percent of at least one substantially pure plant dye material obtained using solvent or supercritical CO2 extraction, combined with 0.01 to 5 percent of active metal in a metal or mineral salt capable of acting as a mordant as a two-part hair color system.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: July 6, 2010
    Assignee: Advanced Cosmetic Technologies, LLC
    Inventors: Erjena Greaves, Jeffrey T. Greaves
  • Patent number: 7704285
    Abstract: Processes for coloring a keratin material, comprising applying to the keratin material, in the presence of oxygen, at least one component (A) comprising, in a physiologically acceptable medium:—at least one dye precursor chosen from compounds comprising at least one aromatic ring comprising at least two hydroxyl groups borne by two successive carbon atoms of the at least one aromatic ring, and at least one catalytic system comprising at least one first catalyst (1) chosen from Mn(II) and Zn(II) salts and oxides and/or at least one second catalyst (2) chosen from alkali metal hydrogen carbonates and alkaline-earth metal hydrogen carbonates followed by applying at least one component (B) comprising at least one acidic composition to fix the shade and followed by applying at least one component (C) comprising at least one alkaline composition to increase the intensity of the color or to modify the shade and optionally fixing the new color or shade obtained by applying a new application of at least one compositio
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: April 27, 2010
    Assignee: L'Oreal S.A.
    Inventors: Francis Pruche, Véronique Chevalier
  • Patent number: 7682404
    Abstract: The present invention concerns coloring keratin fibers, especially human hair, with colored metal complexes.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: March 23, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Nicole End, Kai-Uwe Schöning, Beate Fröhling
  • Patent number: 7270685
    Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.
    Type: Grant
    Filed: January 6, 2006
    Date of Patent: September 18, 2007
    Assignee: L'Oreal
    Inventors: Frank Dreher, Francis Pruche
  • Patent number: 7077871
    Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: July 18, 2006
    Assignee: L'Oreal
    Inventors: Frank Dreher, Francis Pruche
  • Patent number: 6997963
    Abstract: The present invention concerns a dye composition for dyeing human keratin fibres such as hair containing, in an appropriate medium for dyeing human keratin fibres, at least one compound chosen from among chromoionophores and fluorionophores, and at least one cosmetic additive other than water. The invention also concerns the use of a compound chosen from among the chromoionophores and fluorionophores as a direct dye for dyeing human keratin fibres, methods for dyeing human keratin fibres and a device or “kit” with several compartments.
    Type: Grant
    Filed: June 27, 2003
    Date of Patent: February 14, 2006
    Assignee: L'Oreal
    Inventor: Frederic Guerin
  • Patent number: 6953486
    Abstract: Colouring composition, method for obtaining and using same for colouring skin and/or keratin matters.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: October 11, 2005
    Assignee: L'Oreal
    Inventor: Francis Pruche
  • Patent number: 6723136
    Abstract: A composition for coloring keratin fibers comprises, a physiologically acceptable medium and an efficacious quantity of at least one coloring material precursor selected from the compounds containing at least one aromatic ring having at least two hydroxyl groups borne by two adjacent carbon atoms of the aromatic ring, an efficacious quantity of at least one oxidation base of the para or ortho type selected from the aromatic amines, and an efficacious quantity of a catalytic system comprising a first constituent selected from the group consisting of salts and oxides of Mn(II) and/or Zn(II) and their mixtures, and a second constituent selected from the group consisting of alkali hydrogen carbonates, alkaline earth hydrogen carbonates and their mixtures. Keratin fibers may be colored by the application of this composition thereto.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: April 20, 2004
    Assignee: L'Oreal
    Inventor: Francis Pruche
  • Patent number: 6648925
    Abstract: The present invention relates to a composition for coloring keratin fibers and a method of using the same. The composition of the present invention contains at least one dye precursor, and one or more clathrate compounds that contain transition metal complexes.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: November 18, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
    Inventors: Bernd Mayer, Peter Kuhm, Horst Hoeffkes, Gertrud Ewald, Hans-Oscar Stephan, Melita Heller
  • Patent number: 6136044
    Abstract: Micro-particles of transition metals or their compounds can be generated as an integral part of a fiber by first attaching a nucleating agent to the fiber, and then adding a solution of metal ions. The ions are reduced by the nucleating agent in the fiber, and micro-particles are generated in or on the fiber. Because of the strong color signal resulting from a low concentration of metal micro-particles, the method is cost effective even when using gold or titanium ions. Various colors were generated by changing the size and spacing of the micro-particles, the metal or metal complex used, and the characteristics of the fiber. The dyed fibers displayed colors ranging from pink, red, purple, yellow, orange, peach, brown, gold, silver, grey, green, and black. These colors resisted bleaching by either chemicals or light.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: October 24, 2000
    Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical College
    Inventor: William J. Todd
  • Patent number: 5972049
    Abstract: Improvements in the disperse dyeing process for hydrophobic textiles by the use of novel dye carrier formulations are disclosed. The carrier composition for use in disperse dyeing of hydrophobic textile material preferably comprises an alkylphthalimide carrier component and a clay dispersing agent. Dye baths and methods of disperse dyeing of a hydrophobic textile material are also disclosed. The use of clay as a dispersing agent allows for the use of carrier compositions with reduced health and environmental hazards without adversely affecting dyeing characteristics.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: October 26, 1999
    Assignee: Sybron Chemicals Inc.
    Inventors: Calvin M. Wicker, Jr., Otto Bello, Ricky C. Phillips, Robert B. Login
  • Patent number: 5772696
    Abstract: An invention is disclosed which pertains to a method for purifying water soluble dyes, such as quinoline, fluoran, and xanthene dyes. The method comprises the steps of A) adding a metal salt to the water soluble dye to form a water insoluble dye salt of the metal; B) isolating the water insoluble dye salt of step A; C) converting the water insoluble dye salt of step B into a water soluble dye solution; and D) isolating the water soluble dye from the solution of step C. The present invention teaches a straight forward, economical, and environmentally sound method for purifying water soluble dyes of FDA certifiable purity and with an aesthetically improved shade.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 30, 1998
    Assignee: Warner-Jenkinson Company, Inc.
    Inventor: Puthalath Koroth Sujeeth
  • Patent number: 5769902
    Abstract: Compositions for dyeing keratinous fibers comprising at least one an ortho-diaminopyrazole or an acid addition salt thereof and a manganese salt as well as a dyeing process using these compositions, without any oxidizing agent other than atmospheric oxygen.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: June 23, 1998
    Assignee: L'Oreal
    Inventor: Henri Samain
  • Patent number: 5690697
    Abstract: A set for dyeing keratinous fibers, a dyeing composition, and a process for dyeing keratinous fibers using this dyeing composition are disclosed. Also disclosed is a multi-compartment device, or kit, one of the compartments of which contains the composition of the invention.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: November 25, 1997
    Assignee: L'Oreal
    Inventor: Henri Samain
  • Patent number: 5525123
    Abstract: This invention comprises a hair dyeing composition based on oxidation dyestuff precursors which dyes and brightens the hair containing, besides at least one developing and at least one coupling agent, at least one metal salt and at least one ammonium compound selected from the group ammonium chloride, ammonium sulfate, ammonium carbonate, ammonium bicarbonate, and ammonium carbamate, having a pH-value between 8 and 11, preferably from 9 to 10, after admixture with an oxidizing agent in the ready-to-use preparation.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: June 11, 1996
    Assignee: Goldwell AC
    Inventors: Heribert Lorenz, Daisuke Misu
  • Patent number: 5462565
    Abstract: The new process for dyeing polyamide fibers with acid dyestuffs, in which small amounts of metal salts are added to the dyebath, gives dyeings having improved lightfastness.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: October 31, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Rohr, Martin Riegels, Sylvia Lohmann
  • Patent number: 5368610
    Abstract: The invention provides methods, compositions and kits for oxidative hair dyeing utilizing an oxidative hair dye precursor, and an alkali metal chlorite together with a water soluble copper, iron, manganese or cobalt salt, a chelate of said salts or a mixture of said salts and chelates.
    Type: Grant
    Filed: April 20, 1993
    Date of Patent: November 29, 1994
    Assignee: Clairol Incorporated
    Inventors: Alexander Chan, Gottfried Wenke, Ciuseppe Prota
  • Patent number: 5346509
    Abstract: Process for dyeing human hair by the sequential treatment of the hair with a metal ion and particularly transition metal ion containing composition and with a dye composition containing 5,6-dihydroxyindole-2-carboxylic acid.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: September 13, 1994
    Assignee: Clairol Incorporated
    Inventors: Thomas M. Schultz, Keith C. Brown, Leszek J. Wolfram, Giuseppe Prota
  • Patent number: 4776856
    Abstract: In a process for the oxidative dyeing of human or animal hair, a hair dyeing agent is prepared immediately before use from at least one oxidation dye and an oxidizing agent, applied to the hair to be dyed, and made to act for a given period of time, whereupon the hair dyeing agent is washed out. The hair dyeing agent that is to be used is prepared from an oxidation dye and the oxidizing agent with the concomitant use of manganese dioxide in powder form, while the finished hair dyeing agent is adjusted to a weakly acid pH in the range from 5.9 to 6.9.
    Type: Grant
    Filed: April 22, 1987
    Date of Patent: October 11, 1988
    Assignee: Goldwell GmbH Chemische Fabrik H. E. Dotter
    Inventors: Jurgen Tennigkeit, Herbert Lorenz
  • Patent number: 4720422
    Abstract: A material is, herein disclosed for collecting radionuclides and heavy metals that comprises an acrylic fiber element having MnO.sub.2 and/or ferrocyanide compound of the formula K.sub.2 M.sup.II [Fe(CN).sub.6 ] (wherein M.sup.II is a divalent metal such as cobalt, zirconium, zinc or nickel) supported thereon. The material of the present invention is used in collecting and concentrating radionuclides present in liquid radioactive wastes discharged from nuclear power plants and other facilities using radioisotopes such as hospitals and non-destructive testing laboratories. The material is also used in collecting and concentrating radionuclides and heavy metals present in the seawater, rivers and industrial waste-water.
    Type: Grant
    Filed: April 3, 1985
    Date of Patent: January 19, 1988
    Assignee: Japan Chemical Analysis Center
    Inventors: Hideo Higuchi, Nobuhiro Nonaka
  • Patent number: 4655785
    Abstract: A process for the photochemical stabilization of undyed and dyed polyamide or polyurethane fibre material that is characterized in that the fibre material is treated with a water soluble, organic copper, manganese or nickel complex that displays an affinity for the fibres. The polyamide or polyurethane fibre material, e.g., textile, that has been so treated retains its stretch characteristics and elasticity even after prolonged periods of illumination. In addition, in the case of dyed material, treatment with the metal complex results in a marked improvement in light-fastness.
    Type: Grant
    Filed: May 21, 1985
    Date of Patent: April 7, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Reinert, Gerhard Back, Helmut Huber-Emden
  • Patent number: 4274831
    Abstract: A process of dyeing or printing of synthetic fiber materials by means of disperse dyes carried out in the presence of at least one derivative of a metal having an atomic number in the range of 24 through 30 to prevent or diminish the degradation of the dye during the dyeing or printing process, and ready-to-use colorant compositions for this process.
    Type: Grant
    Filed: June 30, 1978
    Date of Patent: June 23, 1981
    Assignee: Produits Chimiques Ugine Kuhlmann
    Inventors: Gerard L.A. Belfort, Daniel P. A. Richer