Group Iib Metal (zn, Cd, Hg) Patents (Class 8/629)
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Patent number: 9023116Abstract: As associative thickener obtainable by free radical polymerization, the preparation thereof and the use thereof in paper coating slips are described. The associative thickener is formed from (a) acid monomers selected from ethylenically unsaturated C3- to C8-carboxylic acids, (b) associative monomers of the general formula H2C?CR1—COO-(EO)n—(PO)m—R2, in which R1 is hydrogen or methyl, n is a number of at least two, m is a number from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30-alkyl group or a C8-C30-alkaryl group, and (c) nonionic, copolymerizable monomers differing from a) and b), the reaction product having been reacted, after the polymerization, with initiators forming nonionic radicals.Type: GrantFiled: February 1, 2011Date of Patent: May 5, 2015Assignee: BASF SEInventors: Philipp Zacharias, Hermann Seyffer, Ilshat Gubaydullin, Harutyun Hanciogullari, Marc Bothe
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Patent number: 8597373Abstract: The invention relates to a process for dyeing keratin fibers, in which said fibers are treated: ? with a composition (A) comprising i) one or more indole or indoline compounds; ii) one or more metal salts; iii) hydrogen peroxide or one or more systems that generate hydrogen peroxide; and then ? with a composition (B) comprising iv) one or more basifying agents. The invention also relates to a hair dyeing process for obtaining better colorations, which are more uniform, chromatic and remanent and which do not impair the cosmetic properties of keratin fibers.Type: GrantFiled: June 13, 2011Date of Patent: December 3, 2013Assignee: L'OrealInventors: Frédéric Guerin, Gilles Genain, Patrick Choisy
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Patent number: 8535391Abstract: The present invention is concerned with a dye system for application to a substrate, the dye system comprising: (a) at least one dye precursor; (b) an oxidizing agent; and (c) a catalyst, wherein the catalyst is a homogeneous catalyst or a heterogeneous catalyst. Preferably, the catalyst comprises at least one metal-containing compound. The invention also envisages a method for the coloration of a substrate, the method comprising treating the substrate with the dye system of the invention. In preferred embodiments of the invention, the substrate comprises human hair, natural or synthetic polymers, or textile fibers. In further preferred embodiments, the at least one dye precursor is an organic precursor, the at least one metal derivative for use as a catalyst comprises at least one inorganic metal compound or at least one metal complex comprising at least one organic ligand, and the oxidizing agent is hydrogen peroxide.Type: GrantFiled: June 30, 2010Date of Patent: September 17, 2013Assignee: University of LeedsInventors: Richard Simon Blackburn, Patrick Columba McGowan, Christopher Martin Pask, Christopher Mark Rayner
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Patent number: 8518126Abstract: The invention relates to a process for dyeing keratin fibers, such as human keratin fibers, and in particular the hair, comprising the application, to said fibers, of: i) a composition comprising one or more dyes chosen from chromene dyes and chromane dyes, ii) a composition comprising one or more zinc mineral salts, compositions i) and ii) being two distinct compositions or forming a single composition, said process excluding any use of a chemical oxidizing agent other than the oxygen in the air, and also to a composition and to the use thereof.Type: GrantFiled: August 18, 2010Date of Patent: August 27, 2013Assignee: L'OrealInventor: Boris Lalleman
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Patent number: 7857865Abstract: The disclosure relates to a method for dyeing keratinous fibers by applying, to said fibers, i) at least one entity chosen from ortho-diphenol and derivatives thereof, ii) at least one metal salt, iii) hydrogen peroxide or at least one system which generates hydrogen peroxide, and iv) at least one (bi)carbonate, wherein the method for coloring keratinous fibers is carried out in at least two stages, and wherein the at least one (bi)carbonate and the at least one metal salt are applied in separate stages. The disclosure also relates to a ready-to-use cosmetic composition and relates to a multicompartment device comprising from 2 to 5 compartments comprising from 2 to 5 compositions.Type: GrantFiled: December 14, 2009Date of Patent: December 28, 2010Assignee: L'Oreal S.A.Inventors: Frédéric Guerin, Luc Gourlaouen
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Patent number: 7857866Abstract: The disclosure relates to methods for dyeing keratinous fibers by treatment of said fibers with i) at least entity chosen from ortho-diphenol and derivatives thereof, ii) at least one metal salt, iii) hydrogen peroxide or at least one system which generates hydrogen peroxide and iv) at least one (bi)carbonate, said method additionally involving an intermediate wiping and/or drying and/or non rinsing stage.Type: GrantFiled: December 14, 2009Date of Patent: December 28, 2010Assignee: L'Oreal S.A.Inventor: Frédéric Guerin
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Patent number: 7749286Abstract: A composition for dyeing keratin fibers that contains 0.1 to 30 percent of at least one substantially pure plant dye material obtained using solvent or supercritical CO2 extraction, combined with 0.01 to 5 percent of active metal in a metal or mineral salt capable of acting as a mordant as a two-part hair color system.Type: GrantFiled: May 18, 2009Date of Patent: July 6, 2010Assignee: Advanced Cosmetic Technologies, LLCInventors: Erjena Greaves, Jeffrey T. Greaves
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Patent number: 7713310Abstract: The present disclosure relates to a cosmetic process for wash-protecting the color of keratin fibers comprising applying a composition comprising, in a cosmetically acceptable medium, at least one zinc-based compound chosen from zinc-based mineral compounds and zinc-based non-nitrogenous organic compounds to keratin fibers previously dyed. Also disclosed is a cosmetic process for wash-protecting the color of dyed keratin fibers, comprising applying to the keratin fibers, after dyeing, at least one zinc-based compound chosen from zinc-based mineral compounds and zinc-based non-nitrogenous organic compounds. The present disclosure further relates to a process for dyeing keratin fibers comprising applying to the fibers at least one dye composition (A), optionally in the presence of an oxidizing agent, for period of time that is sufficient to develop the color, and applying a composition (B) comprising, in a cosmetically acceptable medium, at least one zinc-based compound as defined herein.Type: GrantFiled: October 26, 2007Date of Patent: May 11, 2010Assignee: L'Oreal S.A.Inventor: Boris Lalleman
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Patent number: 7704285Abstract: Processes for coloring a keratin material, comprising applying to the keratin material, in the presence of oxygen, at least one component (A) comprising, in a physiologically acceptable medium:—at least one dye precursor chosen from compounds comprising at least one aromatic ring comprising at least two hydroxyl groups borne by two successive carbon atoms of the at least one aromatic ring, and at least one catalytic system comprising at least one first catalyst (1) chosen from Mn(II) and Zn(II) salts and oxides and/or at least one second catalyst (2) chosen from alkali metal hydrogen carbonates and alkaline-earth metal hydrogen carbonates followed by applying at least one component (B) comprising at least one acidic composition to fix the shade and followed by applying at least one component (C) comprising at least one alkaline composition to increase the intensity of the color or to modify the shade and optionally fixing the new color or shade obtained by applying a new application of at least one compositioType: GrantFiled: September 11, 2009Date of Patent: April 27, 2010Assignee: L'Oreal S.A.Inventors: Francis Pruche, Véronique Chevalier
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Patent number: 7553339Abstract: A method of dyeing or printing textile fiber materials, which comprises bringing the fiber material into contact with (a) at least one reactive dye containing at least one anionic group, (b) at least one compound which reduces the ionic character of the anionic group, and (c) at least one nucleophilic compound, yields dyeings or prints having deep hues and very good fastness properties.Type: GrantFiled: November 1, 2004Date of Patent: June 30, 2009Assignee: Huntsman International LLCInventors: Jürgen Schmiedl, Wolfgang Mundle
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Patent number: 7550014Abstract: A composition for dyeing keratin fibers that contains 0.1 to 30 percent of at least one substantially pure plant dye material obtained using solvent or supercritical CO2 extraction combined with 0.01 to 5 percent of active metal in a metal or mineral salt capable of acting as a mordant as a two part hair color system. The addition of the encapsulation of one or both components allows the use of the plant dye in combination with the metal or mineral salt in a one part hair color system.Type: GrantFiled: May 1, 2006Date of Patent: June 23, 2009Assignee: Advanced Cosmetic Technologies, LLCInventors: Erjena Greaves, Jeffrey T. Greaves
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Patent number: 7429275Abstract: Disclosed herein is the use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials. Further, disclosed herein is a composition comprising, in a suitable dyeing medium, at least one compound from porphyrin compounds and phthalocyanin compounds as at least one direct dye, and also to a ready-to-use composition comprising this at least one direct dye. Furthermore, disclosed herein is a dyeing process using the composition or the ready-to-use composition, and also to a device for implementing this process. Finally, disclosed herein are phthalocyanin compounds.Type: GrantFiled: December 23, 2005Date of Patent: September 30, 2008Assignee: L'Oreal S.A.Inventors: Leila Hercouet, Alain Lagrange
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Patent number: 7270685Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.Type: GrantFiled: January 6, 2006Date of Patent: September 18, 2007Assignee: L'OrealInventors: Frank Dreher, Francis Pruche
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Patent number: 7153330Abstract: The present invention relates to a composition for the oxidation dyeing of keratin fibers, in particular of human keratin fibers such as the hair, comprising at least one oxidation base chosen from 4,5- or 3,4-diaminopyrazoles and triaminopyrazoles, in combination with at least one selected mineral compound, and also to the dyeing process using this composition with an oxidizing agent.Type: GrantFiled: November 26, 2001Date of Patent: December 26, 2006Assignee: L'OrealInventor: Jean Cotteret
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Patent number: 7077871Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.Type: GrantFiled: April 9, 2003Date of Patent: July 18, 2006Assignee: L'OrealInventors: Frank Dreher, Francis Pruche
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Patent number: 6953486Abstract: Colouring composition, method for obtaining and using same for colouring skin and/or keratin matters.Type: GrantFiled: October 9, 2001Date of Patent: October 11, 2005Assignee: L'OrealInventor: Francis Pruche
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Patent number: 6723136Abstract: A composition for coloring keratin fibers comprises, a physiologically acceptable medium and an efficacious quantity of at least one coloring material precursor selected from the compounds containing at least one aromatic ring having at least two hydroxyl groups borne by two adjacent carbon atoms of the aromatic ring, an efficacious quantity of at least one oxidation base of the para or ortho type selected from the aromatic amines, and an efficacious quantity of a catalytic system comprising a first constituent selected from the group consisting of salts and oxides of Mn(II) and/or Zn(II) and their mixtures, and a second constituent selected from the group consisting of alkali hydrogen carbonates, alkaline earth hydrogen carbonates and their mixtures. Keratin fibers may be colored by the application of this composition thereto.Type: GrantFiled: December 4, 2001Date of Patent: April 20, 2004Assignee: L'OrealInventor: Francis Pruche
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Patent number: 6258928Abstract: A process for improving characteristics such as, whiteness retention, degradation, and dyeability of a polyamide by contacting the polyamide with thiocyanate. A polyamide produced by the process has improved dyed color depth, dyed color uniformity, hue, elimination of light dyeing ends, protection of dye sites from degradation, protection from UV degradation, reduced yellowing or oxidation, and/or resistance to loss of dyeability.Type: GrantFiled: April 6, 2000Date of Patent: July 10, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Bennett Ray Baird, David Malcolm Lewis, Kamleshkumar Chunilal Patel
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Patent number: 5942009Abstract: A method for the same-day permanent waving and coloring of hair ("same-day" meaning during a twenty-four hour period and preferably during a single session of only a few hours), which can provide to the hair improved shape retention, color receptivity, color stability, color retention, color evenness, color depth, shine, strength, softness, luster, and/or elasticity. After initial preparation (shampooing, treating with a pre-wrap, and placing on rods if the hair is to be curled), the hair is processed using a waving agent (e.g., thioglycolate), the excess is preferably removed, contacted with a first composition, the excess preferably removed, optionally but preferably contacted with a second composition, heated to dry the hair, and then contacted with a coloring composition containing an oxidative colorant and an oxidizing agent, the oxidizing agent helping develop the color and rebond the hair. The first and second compositions each contain a biologically acceptable metal (preferably a polyvalent metal, e.Type: GrantFiled: March 28, 1997Date of Patent: August 24, 1999Assignee: BRG, Ltd.Inventor: Michael S. Burns
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Patent number: 5851240Abstract: The invention relates to a process for dyeing and finishing cellulosic textile fiber material in one step, which comprises applying to said textile fiber material a liquor comprising (A) at least one dye, (B) a crosslinking agent, (C) a crosslinking catalyst, and (D) choline and subsequently fixing the dye on the textile fiber material.Type: GrantFiled: July 11, 1997Date of Patent: December 22, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Alex Kanzig, Katharina Fritzsche, Peter Scheibli
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Patent number: 5846266Abstract: By using printing pastes containing thiourea dioxide together with finely dispersed calcium, magnesium or zinc hydroxide, present in the paste as such or generated from components in the printing paste during a treatment process, fabric discharge printing processes may be developed which have the advantage of decorating fabric webs, garments or garment panels effectively, even in dry heat conditions, whilst avoiding contamination of such fabrics with undesirable residues, particularly formaldehyde.Type: GrantFiled: October 3, 1996Date of Patent: December 8, 1998Inventor: Ian Durham Rattee
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Patent number: 5628799Abstract: A process for dyeing hair by preparing and applying to the hair an aqueous reaction medium comprising a dopa species, a reactive direct dye and an oxidant, said aqueous reaction medium optionally containing at least one hair dyeing agent selected from the group consisting of primary intermediates and couplers and also containing a buffer to maintain the pH in the range from 6 to 10 during the reaction, and removing said aqueous reaction medium from the hair within about one hour following its preparation.Type: GrantFiled: June 7, 1995Date of Patent: May 13, 1997Assignee: Clairol IncorporatedInventors: Gottfried Wenke, Giuseppe Prota
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Patent number: 5609650Abstract: An oxidation dye composition for keratin fibers containing component A and component B wherein component A is an oxidation dye precursor indoline derivative of the formula I: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; each of R.sup.4 and R.sup.5 is hydrogen or an alkyl group having from 1 to 4 carbon atoms or together with the oxygen atom to which they are attached represent an alkylenedioxy group containing 1 to 4 carbon atoms; or a salt thereof; and wherein component B is a metal salt having a non-oxidizing anion selected from the group consisting of a lithium, magnesium, calcium, aluminum and a zinc salt.Type: GrantFiled: January 5, 1996Date of Patent: March 11, 1997Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Georg Knuebel, Horst Hoeffkes, Winifried Neuhaus, Edgar Lieske, deceased
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Patent number: 5462565Abstract: The new process for dyeing polyamide fibers with acid dyestuffs, in which small amounts of metal salts are added to the dyebath, gives dyeings having improved lightfastness.Type: GrantFiled: September 8, 1994Date of Patent: October 31, 1995Assignee: Bayer AktiengesellschaftInventors: Jurgen Rohr, Martin Riegels, Sylvia Lohmann
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Methods and compositions to enhance stain resistance of carpet fibers with water-soluble thiocyanate
Patent number: 5152803Abstract: This invention relates to improved methods and compositions to enhance stain resistance of carpet fiber. The improved methods relate to a continuous aftertreatment for dyed carpet fabric and to two-step processes, either batch-batch, batch-continuous or continuous-continuous. The improved compositions are used in the processes to enhance stain resistance of carpet or carpet fiber and to overcome various prior drawbacks, such as, yellowing, oxidation and durability to cleaning. The sulfonated aromatic condensates are used to enhance stain resistance, and can be combined with fluorocarbon compounds for soil resistance, thiocyanates, and/or salts having divalent cations, such as magnesium sulfate. Also various dispersing agents, buffering acids and sequestering agents are disclosed.Type: GrantFiled: March 19, 1991Date of Patent: October 6, 1992Assignee: Allied-Signal Inc.Inventors: Dale A. Hangey, Paul W. Harris, Daniel J. Corcoran, Jr., Michael P. Friedberger, Charles J. Cole, William A. Archie, Roger N. Spitz -
Patent number: 5049159Abstract: This invention is concerned with a process for producing deodorizing cellulose fibers on which a considerable amount of copper hydroxide and/or zinc hydroxide is fixed highly strongly, which process is characterized in that cellulose fibers are allowed to contact with a colloidal solution of copper hydroxide and/or zinc hydroxide prepared by adding an alkaline substance to an aqueous solution of a water-soluble copper compound and/or a water-soluble zinc compound. Deodorizing fibers so obtained are capable of effectively removing malodorous gaseous substances, such as hydrogen sulfide, ammonia, methyl mercaptan, etc., and exhibit excellent deodorizing effects. In addition, the deodorizing fibers, although they can be an excellent deodorizing material as they are, are excellent in workability and hence can be used in the form of a shaped product, including, e.g., granules, sheets, etc. They can therefore be applied to various uses in the field of deordorization.Type: GrantFiled: December 13, 1989Date of Patent: September 17, 1991Assignee: Kohjin Co., Ltd.Inventors: Keizou Yamaji, Natumi Satou, Eiji Morisaki
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Patent number: 4981487Abstract: Shaped organic polymer hydrogels, especially contact lenses, are provided with opaque or translucent coloring so as to be capable of masking effectively any underlying color, e.g. the natural color of the eye. The hydrogel may be rendered opaque by precipitation in situ of a white or yellow water-insoluble, inorganic or organic material e.g. barium sulphate or an optical brightener and then colored with a suitable dyestuff.Type: GrantFiled: April 26, 1985Date of Patent: January 1, 1991Assignee: Igel International Ltd.Inventor: Nicholas M. da Costa
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Patent number: 4904274Abstract: A process for coloring hair in which a functional metal ion and aminoalkyl or aminohydroxyalkyl catechols are used in combination or applied sequentially to dye the hair rapidly.Type: GrantFiled: May 12, 1988Date of Patent: February 27, 1990Assignee: Clairol IncorporatedInventors: Thomas M. Schultz, Leszek J. Wolfram, Keith C. Brown, Giuseppe Prota
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Patent number: 4274831Abstract: A process of dyeing or printing of synthetic fiber materials by means of disperse dyes carried out in the presence of at least one derivative of a metal having an atomic number in the range of 24 through 30 to prevent or diminish the degradation of the dye during the dyeing or printing process, and ready-to-use colorant compositions for this process.Type: GrantFiled: June 30, 1978Date of Patent: June 23, 1981Assignee: Produits Chimiques Ugine KuhlmannInventors: Gerard L.A. Belfort, Daniel P. A. Richer