Group Iib Metal (zn, Cd, Hg) Patents (Class 8/629)
  • Patent number: 9023116
    Abstract: As associative thickener obtainable by free radical polymerization, the preparation thereof and the use thereof in paper coating slips are described. The associative thickener is formed from (a) acid monomers selected from ethylenically unsaturated C3- to C8-carboxylic acids, (b) associative monomers of the general formula H2C?CR1—COO-(EO)n—(PO)m—R2, in which R1 is hydrogen or methyl, n is a number of at least two, m is a number from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30-alkyl group or a C8-C30-alkaryl group, and (c) nonionic, copolymerizable monomers differing from a) and b), the reaction product having been reacted, after the polymerization, with initiators forming nonionic radicals.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: May 5, 2015
    Assignee: BASF SE
    Inventors: Philipp Zacharias, Hermann Seyffer, Ilshat Gubaydullin, Harutyun Hanciogullari, Marc Bothe
  • Patent number: 8597373
    Abstract: The invention relates to a process for dyeing keratin fibers, in which said fibers are treated: ? with a composition (A) comprising i) one or more indole or indoline compounds; ii) one or more metal salts; iii) hydrogen peroxide or one or more systems that generate hydrogen peroxide; and then ? with a composition (B) comprising iv) one or more basifying agents. The invention also relates to a hair dyeing process for obtaining better colorations, which are more uniform, chromatic and remanent and which do not impair the cosmetic properties of keratin fibers.
    Type: Grant
    Filed: June 13, 2011
    Date of Patent: December 3, 2013
    Assignee: L'Oreal
    Inventors: Frédéric Guerin, Gilles Genain, Patrick Choisy
  • Patent number: 8535391
    Abstract: The present invention is concerned with a dye system for application to a substrate, the dye system comprising: (a) at least one dye precursor; (b) an oxidizing agent; and (c) a catalyst, wherein the catalyst is a homogeneous catalyst or a heterogeneous catalyst. Preferably, the catalyst comprises at least one metal-containing compound. The invention also envisages a method for the coloration of a substrate, the method comprising treating the substrate with the dye system of the invention. In preferred embodiments of the invention, the substrate comprises human hair, natural or synthetic polymers, or textile fibers. In further preferred embodiments, the at least one dye precursor is an organic precursor, the at least one metal derivative for use as a catalyst comprises at least one inorganic metal compound or at least one metal complex comprising at least one organic ligand, and the oxidizing agent is hydrogen peroxide.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: September 17, 2013
    Assignee: University of Leeds
    Inventors: Richard Simon Blackburn, Patrick Columba McGowan, Christopher Martin Pask, Christopher Mark Rayner
  • Patent number: 8518126
    Abstract: The invention relates to a process for dyeing keratin fibers, such as human keratin fibers, and in particular the hair, comprising the application, to said fibers, of: i) a composition comprising one or more dyes chosen from chromene dyes and chromane dyes, ii) a composition comprising one or more zinc mineral salts, compositions i) and ii) being two distinct compositions or forming a single composition, said process excluding any use of a chemical oxidizing agent other than the oxygen in the air, and also to a composition and to the use thereof.
    Type: Grant
    Filed: August 18, 2010
    Date of Patent: August 27, 2013
    Assignee: L'Oreal
    Inventor: Boris Lalleman
  • Patent number: 7857865
    Abstract: The disclosure relates to a method for dyeing keratinous fibers by applying, to said fibers, i) at least one entity chosen from ortho-diphenol and derivatives thereof, ii) at least one metal salt, iii) hydrogen peroxide or at least one system which generates hydrogen peroxide, and iv) at least one (bi)carbonate, wherein the method for coloring keratinous fibers is carried out in at least two stages, and wherein the at least one (bi)carbonate and the at least one metal salt are applied in separate stages. The disclosure also relates to a ready-to-use cosmetic composition and relates to a multicompartment device comprising from 2 to 5 compartments comprising from 2 to 5 compositions.
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: December 28, 2010
    Assignee: L'Oreal S.A.
    Inventors: Frédéric Guerin, Luc Gourlaouen
  • Patent number: 7857866
    Abstract: The disclosure relates to methods for dyeing keratinous fibers by treatment of said fibers with i) at least entity chosen from ortho-diphenol and derivatives thereof, ii) at least one metal salt, iii) hydrogen peroxide or at least one system which generates hydrogen peroxide and iv) at least one (bi)carbonate, said method additionally involving an intermediate wiping and/or drying and/or non rinsing stage.
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: December 28, 2010
    Assignee: L'Oreal S.A.
    Inventor: Frédéric Guerin
  • Patent number: 7749286
    Abstract: A composition for dyeing keratin fibers that contains 0.1 to 30 percent of at least one substantially pure plant dye material obtained using solvent or supercritical CO2 extraction, combined with 0.01 to 5 percent of active metal in a metal or mineral salt capable of acting as a mordant as a two-part hair color system.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: July 6, 2010
    Assignee: Advanced Cosmetic Technologies, LLC
    Inventors: Erjena Greaves, Jeffrey T. Greaves
  • Patent number: 7713310
    Abstract: The present disclosure relates to a cosmetic process for wash-protecting the color of keratin fibers comprising applying a composition comprising, in a cosmetically acceptable medium, at least one zinc-based compound chosen from zinc-based mineral compounds and zinc-based non-nitrogenous organic compounds to keratin fibers previously dyed. Also disclosed is a cosmetic process for wash-protecting the color of dyed keratin fibers, comprising applying to the keratin fibers, after dyeing, at least one zinc-based compound chosen from zinc-based mineral compounds and zinc-based non-nitrogenous organic compounds. The present disclosure further relates to a process for dyeing keratin fibers comprising applying to the fibers at least one dye composition (A), optionally in the presence of an oxidizing agent, for period of time that is sufficient to develop the color, and applying a composition (B) comprising, in a cosmetically acceptable medium, at least one zinc-based compound as defined herein.
    Type: Grant
    Filed: October 26, 2007
    Date of Patent: May 11, 2010
    Assignee: L'Oreal S.A.
    Inventor: Boris Lalleman
  • Patent number: 7704285
    Abstract: Processes for coloring a keratin material, comprising applying to the keratin material, in the presence of oxygen, at least one component (A) comprising, in a physiologically acceptable medium:—at least one dye precursor chosen from compounds comprising at least one aromatic ring comprising at least two hydroxyl groups borne by two successive carbon atoms of the at least one aromatic ring, and at least one catalytic system comprising at least one first catalyst (1) chosen from Mn(II) and Zn(II) salts and oxides and/or at least one second catalyst (2) chosen from alkali metal hydrogen carbonates and alkaline-earth metal hydrogen carbonates followed by applying at least one component (B) comprising at least one acidic composition to fix the shade and followed by applying at least one component (C) comprising at least one alkaline composition to increase the intensity of the color or to modify the shade and optionally fixing the new color or shade obtained by applying a new application of at least one compositio
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: April 27, 2010
    Assignee: L'Oreal S.A.
    Inventors: Francis Pruche, Véronique Chevalier
  • Patent number: 7553339
    Abstract: A method of dyeing or printing textile fiber materials, which comprises bringing the fiber material into contact with (a) at least one reactive dye containing at least one anionic group, (b) at least one compound which reduces the ionic character of the anionic group, and (c) at least one nucleophilic compound, yields dyeings or prints having deep hues and very good fastness properties.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: June 30, 2009
    Assignee: Huntsman International LLC
    Inventors: Jürgen Schmiedl, Wolfgang Mundle
  • Patent number: 7550014
    Abstract: A composition for dyeing keratin fibers that contains 0.1 to 30 percent of at least one substantially pure plant dye material obtained using solvent or supercritical CO2 extraction combined with 0.01 to 5 percent of active metal in a metal or mineral salt capable of acting as a mordant as a two part hair color system. The addition of the encapsulation of one or both components allows the use of the plant dye in combination with the metal or mineral salt in a one part hair color system.
    Type: Grant
    Filed: May 1, 2006
    Date of Patent: June 23, 2009
    Assignee: Advanced Cosmetic Technologies, LLC
    Inventors: Erjena Greaves, Jeffrey T. Greaves
  • Patent number: 7429275
    Abstract: Disclosed herein is the use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials. Further, disclosed herein is a composition comprising, in a suitable dyeing medium, at least one compound from porphyrin compounds and phthalocyanin compounds as at least one direct dye, and also to a ready-to-use composition comprising this at least one direct dye. Furthermore, disclosed herein is a dyeing process using the composition or the ready-to-use composition, and also to a device for implementing this process. Finally, disclosed herein are phthalocyanin compounds.
    Type: Grant
    Filed: December 23, 2005
    Date of Patent: September 30, 2008
    Assignee: L'Oreal S.A.
    Inventors: Leila Hercouet, Alain Lagrange
  • Patent number: 7270685
    Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.
    Type: Grant
    Filed: January 6, 2006
    Date of Patent: September 18, 2007
    Assignee: L'Oreal
    Inventors: Frank Dreher, Francis Pruche
  • Patent number: 7153330
    Abstract: The present invention relates to a composition for the oxidation dyeing of keratin fibers, in particular of human keratin fibers such as the hair, comprising at least one oxidation base chosen from 4,5- or 3,4-diaminopyrazoles and triaminopyrazoles, in combination with at least one selected mineral compound, and also to the dyeing process using this composition with an oxidizing agent.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: December 26, 2006
    Assignee: L'Oreal
    Inventor: Jean Cotteret
  • Patent number: 7077871
    Abstract: Described is a method of reducing transcutaneous passage of an orthodiphenol oxidation dye by adding a catalytic system of Mn(II) or Zn(II) salt or oxide and at least one alkaline or alkaline earth hydrogenocarbonate to the orthodiphenol oxidation dye composition.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: July 18, 2006
    Assignee: L'Oreal
    Inventors: Frank Dreher, Francis Pruche
  • Patent number: 6953486
    Abstract: Colouring composition, method for obtaining and using same for colouring skin and/or keratin matters.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: October 11, 2005
    Assignee: L'Oreal
    Inventor: Francis Pruche
  • Patent number: 6723136
    Abstract: A composition for coloring keratin fibers comprises, a physiologically acceptable medium and an efficacious quantity of at least one coloring material precursor selected from the compounds containing at least one aromatic ring having at least two hydroxyl groups borne by two adjacent carbon atoms of the aromatic ring, an efficacious quantity of at least one oxidation base of the para or ortho type selected from the aromatic amines, and an efficacious quantity of a catalytic system comprising a first constituent selected from the group consisting of salts and oxides of Mn(II) and/or Zn(II) and their mixtures, and a second constituent selected from the group consisting of alkali hydrogen carbonates, alkaline earth hydrogen carbonates and their mixtures. Keratin fibers may be colored by the application of this composition thereto.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: April 20, 2004
    Assignee: L'Oreal
    Inventor: Francis Pruche
  • Patent number: 6258928
    Abstract: A process for improving characteristics such as, whiteness retention, degradation, and dyeability of a polyamide by contacting the polyamide with thiocyanate. A polyamide produced by the process has improved dyed color depth, dyed color uniformity, hue, elimination of light dyeing ends, protection of dye sites from degradation, protection from UV degradation, reduced yellowing or oxidation, and/or resistance to loss of dyeability.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: July 10, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Bennett Ray Baird, David Malcolm Lewis, Kamleshkumar Chunilal Patel
  • Patent number: 5942009
    Abstract: A method for the same-day permanent waving and coloring of hair ("same-day" meaning during a twenty-four hour period and preferably during a single session of only a few hours), which can provide to the hair improved shape retention, color receptivity, color stability, color retention, color evenness, color depth, shine, strength, softness, luster, and/or elasticity. After initial preparation (shampooing, treating with a pre-wrap, and placing on rods if the hair is to be curled), the hair is processed using a waving agent (e.g., thioglycolate), the excess is preferably removed, contacted with a first composition, the excess preferably removed, optionally but preferably contacted with a second composition, heated to dry the hair, and then contacted with a coloring composition containing an oxidative colorant and an oxidizing agent, the oxidizing agent helping develop the color and rebond the hair. The first and second compositions each contain a biologically acceptable metal (preferably a polyvalent metal, e.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: August 24, 1999
    Assignee: BRG, Ltd.
    Inventor: Michael S. Burns
  • Patent number: 5851240
    Abstract: The invention relates to a process for dyeing and finishing cellulosic textile fiber material in one step, which comprises applying to said textile fiber material a liquor comprising (A) at least one dye, (B) a crosslinking agent, (C) a crosslinking catalyst, and (D) choline and subsequently fixing the dye on the textile fiber material.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: December 22, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Alex Kanzig, Katharina Fritzsche, Peter Scheibli
  • Patent number: 5846266
    Abstract: By using printing pastes containing thiourea dioxide together with finely dispersed calcium, magnesium or zinc hydroxide, present in the paste as such or generated from components in the printing paste during a treatment process, fabric discharge printing processes may be developed which have the advantage of decorating fabric webs, garments or garment panels effectively, even in dry heat conditions, whilst avoiding contamination of such fabrics with undesirable residues, particularly formaldehyde.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: December 8, 1998
    Inventor: Ian Durham Rattee
  • Patent number: 5628799
    Abstract: A process for dyeing hair by preparing and applying to the hair an aqueous reaction medium comprising a dopa species, a reactive direct dye and an oxidant, said aqueous reaction medium optionally containing at least one hair dyeing agent selected from the group consisting of primary intermediates and couplers and also containing a buffer to maintain the pH in the range from 6 to 10 during the reaction, and removing said aqueous reaction medium from the hair within about one hour following its preparation.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 13, 1997
    Assignee: Clairol Incorporated
    Inventors: Gottfried Wenke, Giuseppe Prota
  • Patent number: 5609650
    Abstract: An oxidation dye composition for keratin fibers containing component A and component B wherein component A is an oxidation dye precursor indoline derivative of the formula I: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; each of R.sup.4 and R.sup.5 is hydrogen or an alkyl group having from 1 to 4 carbon atoms or together with the oxygen atom to which they are attached represent an alkylenedioxy group containing 1 to 4 carbon atoms; or a salt thereof; and wherein component B is a metal salt having a non-oxidizing anion selected from the group consisting of a lithium, magnesium, calcium, aluminum and a zinc salt.
    Type: Grant
    Filed: January 5, 1996
    Date of Patent: March 11, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Georg Knuebel, Horst Hoeffkes, Winifried Neuhaus, Edgar Lieske, deceased
  • Patent number: 5462565
    Abstract: The new process for dyeing polyamide fibers with acid dyestuffs, in which small amounts of metal salts are added to the dyebath, gives dyeings having improved lightfastness.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: October 31, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Rohr, Martin Riegels, Sylvia Lohmann
  • Patent number: 5152803
    Abstract: This invention relates to improved methods and compositions to enhance stain resistance of carpet fiber. The improved methods relate to a continuous aftertreatment for dyed carpet fabric and to two-step processes, either batch-batch, batch-continuous or continuous-continuous. The improved compositions are used in the processes to enhance stain resistance of carpet or carpet fiber and to overcome various prior drawbacks, such as, yellowing, oxidation and durability to cleaning. The sulfonated aromatic condensates are used to enhance stain resistance, and can be combined with fluorocarbon compounds for soil resistance, thiocyanates, and/or salts having divalent cations, such as magnesium sulfate. Also various dispersing agents, buffering acids and sequestering agents are disclosed.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: October 6, 1992
    Assignee: Allied-Signal Inc.
    Inventors: Dale A. Hangey, Paul W. Harris, Daniel J. Corcoran, Jr., Michael P. Friedberger, Charles J. Cole, William A. Archie, Roger N. Spitz
  • Patent number: 5049159
    Abstract: This invention is concerned with a process for producing deodorizing cellulose fibers on which a considerable amount of copper hydroxide and/or zinc hydroxide is fixed highly strongly, which process is characterized in that cellulose fibers are allowed to contact with a colloidal solution of copper hydroxide and/or zinc hydroxide prepared by adding an alkaline substance to an aqueous solution of a water-soluble copper compound and/or a water-soluble zinc compound. Deodorizing fibers so obtained are capable of effectively removing malodorous gaseous substances, such as hydrogen sulfide, ammonia, methyl mercaptan, etc., and exhibit excellent deodorizing effects. In addition, the deodorizing fibers, although they can be an excellent deodorizing material as they are, are excellent in workability and hence can be used in the form of a shaped product, including, e.g., granules, sheets, etc. They can therefore be applied to various uses in the field of deordorization.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: September 17, 1991
    Assignee: Kohjin Co., Ltd.
    Inventors: Keizou Yamaji, Natumi Satou, Eiji Morisaki
  • Patent number: 4981487
    Abstract: Shaped organic polymer hydrogels, especially contact lenses, are provided with opaque or translucent coloring so as to be capable of masking effectively any underlying color, e.g. the natural color of the eye. The hydrogel may be rendered opaque by precipitation in situ of a white or yellow water-insoluble, inorganic or organic material e.g. barium sulphate or an optical brightener and then colored with a suitable dyestuff.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: January 1, 1991
    Assignee: Igel International Ltd.
    Inventor: Nicholas M. da Costa
  • Patent number: 4904274
    Abstract: A process for coloring hair in which a functional metal ion and aminoalkyl or aminohydroxyalkyl catechols are used in combination or applied sequentially to dye the hair rapidly.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: February 27, 1990
    Assignee: Clairol Incorporated
    Inventors: Thomas M. Schultz, Leszek J. Wolfram, Keith C. Brown, Giuseppe Prota
  • Patent number: 4274831
    Abstract: A process of dyeing or printing of synthetic fiber materials by means of disperse dyes carried out in the presence of at least one derivative of a metal having an atomic number in the range of 24 through 30 to prevent or diminish the degradation of the dye during the dyeing or printing process, and ready-to-use colorant compositions for this process.
    Type: Grant
    Filed: June 30, 1978
    Date of Patent: June 23, 1981
    Assignee: Produits Chimiques Ugine Kuhlmann
    Inventors: Gerard L.A. Belfort, Daniel P. A. Richer